JPH02117602A - Agent and method for controlling termite - Google Patents
Agent and method for controlling termiteInfo
- Publication number
- JPH02117602A JPH02117602A JP27039688A JP27039688A JPH02117602A JP H02117602 A JPH02117602 A JP H02117602A JP 27039688 A JP27039688 A JP 27039688A JP 27039688 A JP27039688 A JP 27039688A JP H02117602 A JPH02117602 A JP H02117602A
- Authority
- JP
- Japan
- Prior art keywords
- humidity
- termite
- sepiolite
- control agent
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 241000256602 Isoptera Species 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 45
- 239000008187 granular material Substances 0.000 claims abstract description 41
- 239000004113 Sepiolite Substances 0.000 claims abstract description 22
- 239000004927 clay Substances 0.000 claims abstract description 22
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 22
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 22
- 239000002245 particle Substances 0.000 claims description 32
- 229960000892 attapulgite Drugs 0.000 claims description 11
- 229910052625 palygorskite Inorganic materials 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 9
- 239000003906 humectant Substances 0.000 claims 1
- 239000002917 insecticide Substances 0.000 abstract description 14
- 229910001583 allophane Inorganic materials 0.000 abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 7
- 239000004615 ingredient Substances 0.000 abstract description 4
- 239000000839 emulsion Substances 0.000 abstract description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 abstract description 2
- 230000001580 bacterial effect Effects 0.000 abstract 1
- 239000002775 capsule Substances 0.000 abstract 1
- 230000008602 contraction Effects 0.000 abstract 1
- 230000009545 invasion Effects 0.000 abstract 1
- 239000002728 pyrethroid Substances 0.000 abstract 1
- ATROHALUCMTWTB-OWBHPGMISA-N phoxim Chemical compound CCOP(=S)(OCC)O\N=C(\C#N)C1=CC=CC=C1 ATROHALUCMTWTB-OWBHPGMISA-N 0.000 description 24
- 229950001664 phoxim Drugs 0.000 description 24
- 239000003208 petroleum Substances 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 8
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 6
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 6
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 6
- -1 flowables Substances 0.000 description 5
- 239000008262 pumice Substances 0.000 description 5
- 241000607479 Yersinia pestis Species 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 241000233866 Fungi Species 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- 229960001591 cyfluthrin Drugs 0.000 description 3
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000002424 termiticide Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 239000002734 clay mineral Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 235000014380 magnesium carbonate Nutrition 0.000 description 2
- 239000003094 microcapsule Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 1
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 239000005944 Chlorpyrifos Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 108010082455 Sebelipase alfa Proteins 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 229940024113 allethrin Drugs 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 208000006673 asthma Diseases 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000000073 carbamate insecticide Substances 0.000 description 1
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000007799 cork Substances 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 1
- DIRFUJHNVNOBMY-UHFFFAOYSA-N fenobucarb Chemical compound CCC(C)C1=CC=CC=C1OC(=O)NC DIRFUJHNVNOBMY-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- HOQADATXFBOEGG-UHFFFAOYSA-N isofenphos Chemical compound CCOP(=S)(NC(C)C)OC1=CC=CC=C1C(=O)OC(C)C HOQADATXFBOEGG-UHFFFAOYSA-N 0.000 description 1
- SDMSCIWHRZJSRN-UHFFFAOYSA-N isoxathion Chemical compound O1N=C(OP(=S)(OCC)OCC)C=C1C1=CC=CC=C1 SDMSCIWHRZJSRN-UHFFFAOYSA-N 0.000 description 1
- 229940041615 kanuma Drugs 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical class OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- FITIWKDOCAUBQD-UHFFFAOYSA-N prothiofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(Cl)C=C1Cl FITIWKDOCAUBQD-UHFFFAOYSA-N 0.000 description 1
- CXJSOEPQXUCJSA-UHFFFAOYSA-N pyridaphenthion Chemical compound N1=C(OP(=S)(OCC)OCC)C=CC(=O)N1C1=CC=CC=C1 CXJSOEPQXUCJSA-UHFFFAOYSA-N 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- CXBMCYHAMVGWJQ-UHFFFAOYSA-N tetramethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
Abstract
Description
【発明の詳細な説明】
及ス上９上罪１里
本発明は、シロアリ防除剤及びシロアリ防除方法に関し
、詳しくは、特に、家屋床下に施用する際に、床下に高
湿度化を招くことがなく、更に、施用した後も、床下に
侵入する水分や湿気に対して調湿機能を有するシロアリ
防除剤粒剤に関する。[Detailed Description of the Invention] The present invention relates to a termite control agent and a termite control method, and more particularly, when applied under the floor of a house, it may cause high humidity under the floor. Furthermore, the present invention relates to a termite control agent granule that has a humidity control function against water and humidity that enters under the floor even after application.
また、本発明は、かかる調湿機能を有するシロアリ防除
剤を用いるシロアリ防除方法に関する。The present invention also relates to a termite control method using a termite control agent having such a humidity control function.
従来■肢血
従来、木造建築物のシロアリによる被害を防ぐために、
種々のシロアリ防除剤が用いられている。Conventional ■ Extremity Blood Conventionally, to prevent termite damage to wooden buildings,
Various termite control agents are used.
このようなシロアリ防除剤は、多くは、乳剤、フロアブ
ル剤又はマイクロカプセル剤の形態を有し、これを水で
希釈し、３〜５１．／ｒｒｆ程度の割合にて家屋床下に
散布することによって施用される。従って、従来、シロ
アリ防除剤の施用に際しては、家屋床下は高湿度となり
、カビ、腐朽菌等が発生するのみならず、床下の高湿度
環境は、居住空間にも及んで、カビの発生を招く。この
ようなカビの発生は、喘息やアレルギー性疾患の大きい
原因の一つであることが明らかにされており、快適で健
康な居住性を損なうこととなると共に、腐朽菌は、家屋
木材を害し、構造上の著しい強度低下をもたらす。Such termite control agents often have the form of emulsions, flowables, or microcapsules, which are diluted with water and mixed with 3 to 51. It is applied by spraying it under the floors of houses at a rate of about /rrf. Therefore, conventionally, when applying termite control agents, the underfloor of the house becomes highly humid, which not only causes mold and rotting fungi to grow, but also the high humidity environment under the floor extends to the living space, leading to the growth of mold. . The growth of mold has been shown to be one of the major causes of asthma and allergic diseases, impairing a comfortable and healthy living environment, and rotting fungi can also damage the wood of houses. , resulting in a significant decrease in structural strength.
そこで、例えば、特開昭５６−１０５０４２号公報には
、シロアリ防除剤に軽石、パーライト、石灰及び生石前
の粉粒体を混合し、これを家屋床下に散布する方法も提
案されているが、調湿機能が未だ十分ではなく、しかも
、石灰を用いることから、利用し得る殺蟻成分が限定さ
れる。Therefore, for example, JP-A-56-105042 proposes a method of mixing termite control agents with pumice, perlite, lime, and raw stone powder, and spraying this under the floors of houses. The humidity control function is still insufficient, and since lime is used, the usable anticide ingredients are limited.
このほか、施用に際して、水を用いない粒剤や粉剤も知
られているが、殆どの場合、製剤が調湿機能を有してお
らず、また、有していても、極めて僅かであるので、家
屋床下の水分や湿気に対して、作動な調湿機能を果たす
には至らない。In addition, granules and powders that do not require water are also known, but in most cases, the formulations do not have a humidity control function, and even if they do, the amount is extremely small. However, it cannot function effectively to control moisture and humidity under the floor of a house.
■が”しよ゛とする晋 ・
本発明は、従来のシロアリ防除における上記した問題を
解決するためになされたものであって、家屋床下に施用
する際に、水の使用による床下の高湿度化がなく、更に
、施用した後も、床下に侵入する水分や湿気に対して調
湿機能を有するシロアリ防除剤粒剤を提供することを目
的とし、また、かかる調湿機能を有するシロアリ防除剤
粒剤を用いる防除方法を提供することを目的とする。・The present invention was made to solve the above-mentioned problems in conventional termite control. The purpose of the present invention is to provide a termite control agent granule that does not cause any oxidation and has a humidity control function against water and humidity that enters under the floor even after application, and also has a termite control agent that has such a humidity control function. The purpose is to provide a pest control method using granules.
１ を”するための
本発明による第１のシロアリ防除剤は、セピオライト、
アタパルジャイト及びアロフェンよりなる群から選ばれ
る少なくとも１種の粘土性多孔質粒子からなる担体に殺
蟻成分を担持させてなることを特徴とする。1. The first termite control agent according to the present invention is sepiolite,
It is characterized in that an anticide component is supported on a carrier made of at least one kind of clay porous particles selected from the group consisting of attapulgite and allophane.
本発明において、担体として用いる上記粘土性多孔質粒
子は、環境の湿度条件に応じて、調湿機能を有する。即
ち、高湿度下では、湿気を吸収し、乾燥条件下では、吸
収した水分を放出する。In the present invention, the above-mentioned clay porous particles used as a carrier have a humidity control function depending on the humidity conditions of the environment. That is, under high humidity conditions, it absorbs moisture, and under dry conditions, it releases the absorbed moisture.
上記のうち、セピオライト及びアタパルジャイトは山皮
とも呼ばれていて、表面に多数の活性水酸基を有する粘
土性鉱物である。セピオライトは、含水ケイ酸マグネシ
ウムであり、アタパルジャイトは、含水ケイ酸マグネシ
ウムアルミニウムである。これらはまた、マウンテン・
コルク、マウンテン・レザー、マウンテン・ウッド等と
呼ばれている。本発明において用いるセピオライト又は
アタパルジヤイトには、カルサイト、ドロマイト、マグ
ネサイト、塩基性炭酸マグネシウム、ケイ酸成分等が含
まれていてもよい。アロフェンも粘土性鉱物の一種であ
って、アルミニウムのケイ酸塩である。アロフェンの一
例として、鹿沼土を挙げることができる。Among the above, sepiolite and attapulgite are also called mountain bark, and are clay minerals having a large number of active hydroxyl groups on the surface. Sepiolite is a hydrous magnesium silicate and attapulgite is a hydrous magnesium aluminum silicate. These are also mountain
It is called cork, mountain leather, mountain wood, etc. The sepiolite or attapulgite used in the present invention may contain calcite, dolomite, magnesite, basic magnesium carbonate, silicic acid components, and the like. Allophane is also a type of clay mineral and is a silicate of aluminum. Kanuma soil can be mentioned as an example of allophane.
本発明において、殺蟻成分としては、有機リン系、カル
バメート系又はピレスリン系殺虫剤が用いられる。有機
リン系殺虫剤としては、例えば、ホキシム、クロルピリ
ホス、フェニトロチオン、ピリダフェンチオン、イソフ
ェンホス、プロチオホス、イソキサチオン、ビラクロホ
ス等を挙げることができ、カルバメート系殺虫剤として
は、例えば、バッサ、プロポキサ−等を挙げることがで
きる。また、ピレスリン系殺虫剤としては、例えば、ア
レスリン、フタルスリン、レスメトリン、ペルメトリン
、ジベルメトリン、デカメトリン、シフルトリン、トラ
ロメトリン、ジハロメトリン、フルトリネート、フルパ
リネート等の合成ピレスリン系殺虫剤を挙げることがで
きる。これ以外にも、ピレスリン系殺虫剤には、フェン
バレレート等のフェニル酢酸エステル誘導体や、また、
エトフエンブロックス等のように、殺虫効果において、
合成ピレスリン系殺虫剤と同じ挙動を示す広義の合成ピ
レスリン系殺虫剤も含まれるものとする。In the present invention, an organophosphorus-based, carbamate-based, or pyrethrin-based insecticide is used as the anticide component. Examples of organophosphorus insecticides include phoxim, chlorpyrifos, fenitrothion, pyridafenthion, isofenphos, prothiophos, isoxathion, and viraclofos; examples of carbamate insecticides include bassa, propoxa, and the like. can. Examples of pyrethrin insecticides include synthetic pyrethrin insecticides such as allethrin, phthalthrin, resmethrin, permethrin, dibermethrin, decametrin, cyfluthrin, tralomethrin, dihalomethrin, fluthrinate, and fluparinate. In addition to this, pyrethrin insecticides include phenylacetate derivatives such as fenvalerate, and
In terms of insecticidal effect, such as etofenbrox, etc.
A broad definition of synthetic pyrethrin insecticides that exhibit the same behavior as synthetic pyrethrin insecticides is also included.
本発明による第１のシロアリ防除剤は、殺蟻成分として
のかかる殺虫剤を前述した粘土性多孔質粒子からなる担
体に担持させてなる粒剤である。The first termite control agent according to the present invention is a granule in which such an insecticide as a termiticide component is supported on a carrier made of the above-mentioned clay porous particles.
担体としての上記粘土性多孔質粒子のなかでも、本発明
においては、調湿機能にすぐれるところから、特に、セ
ピオライト又はアタパルジャイトが好ましく用いられる
。これら粘土性多孔質粒子は、粒子径が０．２〜２０ｆ
ｆＩＩ１１の範囲にあることが好適である。Among the above-mentioned clay porous particles as a carrier, sepiolite or attapulgite is particularly preferably used in the present invention because of their excellent humidity control function. These clay porous particles have a particle size of 0.2 to 20 f.
It is preferable that the fII is in the range of 11.
本発明による第２のシロアリ防除剤は、以上に説明した
セピオライト、アタパルジヤイト及びアロフェンよりな
る群から選ばれる少なくとも１種の粘土性多孔質粒子か
らなる担体に殺蟻成分を担持させてなるシロアリ防除剤
成分と、セピオライト、アタパルジャイト及びアロフェ
ンよりなる群から選ばれる少なくとも１種の粘土性多孔
質粒子からなる調湿剤との混合物とからなることを特徴
とする。The second termite control agent according to the present invention is a termite control agent in which a termiticide component is supported on a carrier consisting of at least one kind of clay porous particles selected from the group consisting of sepiolite, attapulgiaite, and allophane explained above. and a humidity conditioner consisting of at least one clay porous particle selected from the group consisting of sepiolite, attapulgite, and allophane.
即ち、この第２のシロアリ防除剤においては、第１のシ
ロアリ防除剤の担体として用いた粘土性多孔質粒子を調
湿剤として用いる。また、粘土性多孔質粒子は、粒剤中
の殺虫剤量を調整するのにも役立つ。That is, in this second termite control agent, the clay porous particles used as the carrier of the first termite control agent are used as a humidity conditioner. Clay porous particles also help control the amount of pesticide in the granules.
粘土性多孔質粒子からなる調湿剤は、特に限定されるも
のではないが、通常、防除剤において、１０〜９９重景
％の範囲で用いられる。A humidity control agent made of clay porous particles is not particularly limited, but is usually used in a pest control agent in a range of 10 to 99% by weight.
更に、本発明による第３のシロアリ防除剤は、殺蟻成分
を含有する粒剤又は粉剤と、セピオライト、アタパルジ
ャイト及びアロフェンよりなる群から選ばれる少なくと
も１種の粘土性多孔質粒子からなる調湿剤成分との混合
物とからなることを特徴とする。Furthermore, the third termite control agent according to the present invention is a humidity conditioner comprising a granule or powder containing a termicidal component and at least one clay porous particle selected from the group consisting of sepiolite, attapulgite, and allophane. It is characterized by consisting of a mixture of ingredients.
ここに、上記殺蟻成分を含有する粒剤又は粉剤とは、先
に説明した粘土性多孔質粒子に殺蟻成分を担持させてな
る粒剤以外の通常の粒剤又は粉剤を意味し、従来より知
られている任意の粒剤又は粉剤を用いることができる。Here, the granules or powders containing the above-mentioned anticide component mean ordinary granules or powders other than the above-mentioned granules made of clay porous particles supporting an anticide component. Any of the more known granules or powders can be used.
例えば、担体として、天然軽石等を用いることができる
。この第３のシロアリ防除剤においても、上記粘土性多
孔質粒子からなる調湿剤成分は、粒子径が０．２〜２０
薗の範囲であることが好ましく、また、特に限定される
ものではないが、通常、防除剤において、１０〜９９重
量％の範囲で用いられる。For example, natural pumice or the like can be used as the carrier. Also in this third termite control agent, the humidity conditioner component made of the clay porous particles has a particle size of 0.2 to 20
Although not particularly limited, it is usually used in a range of 10 to 99% by weight in a pest control agent.
本発明によるシロアリ防除剤において、殺虫剤量は、用
いる殺虫剤、担体の粒子径、施用の際の散布厚み等によ
って、適宜に選択されるが、通常、粒剤において、０．
０１〜５０重量％の範囲であり、好ましくは、０．１〜
２０重量％の範囲である。In the termite control agent according to the present invention, the amount of insecticide is appropriately selected depending on the insecticide used, the particle size of the carrier, the thickness of spraying during application, etc., but usually in granules, 0.
The range is from 0.01 to 50% by weight, preferably from 0.1 to 50% by weight.
It is in the range of 20% by weight.
本発明によるシロアリ防除剤は、前記殺虫剤と共に、必
要に応じて、種々の添加剤を含有していてもよい。かか
る添加剤としては、例えば、アルコール類、芳香族炭化
水素、脂肪族炭化水素、脂環式炭化水素、グリコールエ
ーテル類、ケトン類、エステル等の溶剤、有効成分の溶
出を調整するためのアルキド樹脂、アクリル樹脂、ウレ
タン樹脂、石油樹脂等の樹脂、１．１．１．２，７．８
，８．８−オクタクロロ−４−オキサヘプタン、ピペロ
ニルブトキシド等の効力増強剤、忌避剤、酸化防止剤、
紫外線吸収剤等の安定剤、着色剤、顔料等を挙げること
ができる。The termite control agent according to the present invention may contain various additives, if necessary, along with the insecticide. Examples of such additives include solvents such as alcohols, aromatic hydrocarbons, aliphatic hydrocarbons, alicyclic hydrocarbons, glycol ethers, ketones, and esters, and alkyd resins for adjusting the elution of active ingredients. , resins such as acrylic resins, urethane resins, petroleum resins, 1.1.1.2, 7.8
, 8. Efficacy enhancers such as 8-octachloro-4-oxaheptane and piperonyl butoxide, repellents, antioxidants,
Stabilizers such as ultraviolet absorbers, colorants, pigments, etc. can be mentioned.
本発明によるシロアリ防除剤は、その製造方法において
何ら限定されるものではなく、例えば、コーティング・
パンのような製剤化装置を用いて、前記殺虫剤及び担体
、及び必要に応じて添加剤等を混合し、担体に殺虫剤を
含浸させ１．乾燥させることによって製造することがで
きる。また、調湿剤を含有するシロアリ防除剤は、上記
のようにして粒剤を製造した後、これに調湿剤を混合す
ることによって得ることができる。The termite control agent according to the present invention is not limited in any way in its manufacturing method, and for example, coating,
1. Using a formulation device such as a pan, mix the insecticide, carrier, and optionally additives, and impregnate the carrier with the insecticide. It can be manufactured by drying. Furthermore, a termite control agent containing a humidity conditioning agent can be obtained by producing granules as described above and then mixing the moisture conditioning agent therein.
本発明によるシロアリ防除剤は、特に、家屋床下に高湿
度化をもたらすことなく、施用することができ、更に、
施用した後も、床下に侵入する水分や湿気に対して調湿
機能を有せしめるのに好適に用いられる。施用は、例え
ば、家屋床下にブロアにて厚み１〜５０ｍｍ程度に散布
すればよい。In particular, the termite control agent according to the present invention can be applied without causing high humidity under the floor of a house, and further,
Even after application, it is suitably used to provide a humidity control function against moisture and humidity that enter under the floor. For application, for example, it may be sprayed under the floor of a house using a blower to a thickness of about 1 to 50 mm.
本発明によるシロアリ防除剤の施用態様は、特に、上記
例示に限定されるものではないが、しかし、前述した第
３の発明による防除剤の施用に際しては、殺蟻成分を含
有する粒剤又は粉剤と、セピオライト、アタパルジヤイ
ト及びアロフェンよりなる群から選ばれる少なくとも１
種の粘土性多孔質粒子からなる調湿剤成分とを同時に家
屋の床下に散布してもよく、或いはいずれかを先に、他
を後に、即ち、時間的な間隔をおいて、散布してもよい
。この場合も、調湿剤成分は、特に限定されるものでは
ないが、通常、防除剤において、１０〜９９重量％の範
囲となるように散布すればよい。粒剤又は粉剤と調湿剤
成分とを同時に散布する場合には、予めこれらを混合し
、散布してもよい。The mode of application of the termite control agent according to the present invention is not particularly limited to the above-mentioned examples. and at least one selected from the group consisting of sepiolite, attapulgite, and allophane.
The moisture conditioner component consisting of porous clay particles of seeds may be sprayed under the floor of the house at the same time, or one of them may be sprayed first and the other after, that is, at intervals of time. Good too. In this case as well, the humidity conditioner component is not particularly limited, but it is generally sufficient to spray it in a range of 10 to 99% by weight in the pest control agent. When spraying the granules or powder and the humidity conditioner component at the same time, they may be mixed in advance and sprayed.
発ｙしυ卵果
以上のように、本発明によるシロアリ防除剤は、粒剤で
あって、その施用時に、水を用いないので、床下及び居
住空間の高湿度化をもたらすことがなく、しかも、施用
後も、床下に侵入する水分や湿気に対して調湿機能を有
して、家屋床下や居住空間でのカビや腐朽菌の発生を有
効に防止することができる。As described above, the termite control agent according to the present invention is a granule and does not use water when applied, so it does not cause high humidity under the floor or in the living space. Even after application, it has a humidity control function against water and humidity that enters under the floor, and can effectively prevent the growth of mold and rotting fungi under the floor of the house and in the living space.
更に、本発明によるシロアリ防除剤によれば、従来、乳
剤、フロアブル剤、マイクロカプセル剤では、アルカリ
安定性が低いために、施用できなかった床下コンクリー
ト上にも施用することができ、かくして、乾燥収縮によ
る剥離又はクラック部からのシロアリの侵入をも効果的
に防止することができる。Furthermore, according to the termite control agent of the present invention, it can be applied to subfloor concrete, where conventional emulsions, flowable agents, and microcapsules could not be applied due to their low alkali stability. It is also possible to effectively prevent termites from peeling off due to shrinkage or from entering through cracks.
去施開
以下に実施例を挙げて本発明を説明するが、本発明はこ
れら実施例により何ら限定されるものではない。尚、以
下において部は重量部を示す。EXAMPLES The present invention will be explained below with reference to Examples, but the present invention is not limited to these Examples in any way. Note that in the following, parts indicate parts by weight.
実施例１
粒子径２．４〜４．８ ｒｍのセピオライト９５部、ホ
キシム５部及び芳香族系石油溶剤３部を混合した後、乾
燥して、ホキシム粒剤１００部を得た。この粒剤は、ホ
キシム５重量％を含有する。Example 1 95 parts of sepiolite having a particle size of 2.4 to 4.8 rm, 5 parts of phoxim and 3 parts of an aromatic petroleum solvent were mixed and dried to obtain 100 parts of phoxim granules. The granules contain 5% by weight of Phoxim.
実施例２
粒子径２．４〜４．８閣のセピオライト９５部、シフル
トリン５部及び芳香族系石油溶剤５部を混合した後、乾
燥して、シフルトリン粒剤１００部を得た。この粒剤は
、シフシト９フ５重世％を含有する。Example 2 95 parts of sepiolite having a particle size of 2.4 to 4.8 mm, 5 parts of cyfluthrin, and 5 parts of an aromatic petroleum solvent were mixed and dried to obtain 100 parts of cyfluthrin granules. This granule contains 9% 5% Sifucyto.
実施例３
粒子径２．４〜４．８ ｍｍのアタパルジヤイト９５部
、ホキシム５部及び芳香族系石油溶剤３部を混合した後
、乾燥して、ホキシム粒剤１００部を得た。Example 3 95 parts of attapulgite having a particle size of 2.4 to 4.8 mm, 5 parts of phoxim, and 3 parts of an aromatic petroleum solvent were mixed and dried to obtain 100 parts of phoxim granules.
この粒剤は、ホキシム５重量％を含有する。The granules contain 5% by weight of Phoxim.
実施例４
粒子径２．４〜４．８ ｍのアロフェン９５部、ホキシ
ム５部及び芳香族系石油溶剤３部を混合した後、乾燥し
て、ホキシム粒剤１００部を得た。この粒剤は、ホキシ
ム５重量％を含有する。Example 4 After mixing 95 parts of allophane with a particle size of 2.4 to 4.8 m, 5 parts of Phoxim, and 3 parts of an aromatic petroleum solvent, the mixture was dried to obtain 100 parts of Phoxim granules. The granules contain 5% by weight of Phoxim.
実施例５
粒子径２．４〜４．８ ｍｍのセピオライト９０部、ホ
キシム１０部及び芳香族系石油溶剤６部を混合した後、
乾燥して、ホキシム粒剤１００部を得た。Example 5 After mixing 90 parts of sepiolite with a particle size of 2.4 to 4.8 mm, 10 parts of phoxim, and 6 parts of an aromatic petroleum solvent,
After drying, 100 parts of Phoxim granules were obtained.
この粒剤５０部を粒子径２．４〜４．８ ｍｍのセピオ
ライト５０部と混合して、ホキシム粒剤１００部を得た
。この粒剤は、ホキシム５重量％を含有する。Fifty parts of this granule was mixed with 50 parts of sepiolite having a particle size of 2.4 to 4.8 mm to obtain 100 parts of Phoxim granule. The granules contain 5% by weight of Phoxim.
実施例６
粒子径２．４ ＝、 ４．８ ｍｍの天然軽石９０部、
ホキシム１０部及び芳香族系石油溶剤６部を混合した後
、乾燥して、ホキシム粒剤１００部を得た。この粒剤５
０部を粒子径２．４〜４．８皿のセピオライト５０部と
混合して、ホキシム粒剤１００部を得た。Example 6 90 parts of natural pumice with a particle size of 2.4 = 4.8 mm,
After mixing 10 parts of Phoxim and 6 parts of an aromatic petroleum solvent, the mixture was dried to obtain 100 parts of Phoxim granules. This granule 5
0 part was mixed with 50 parts of sepiolite having a particle size of 2.4 to 4.8 plates to obtain 100 parts of Phoxim granules.
この粒剤は、ホキシム５重量％を含有する。The granules contain 5% by weight of Phoxim.
比較例１
粒子径２．４〜４．８１１ｎの天然軽石９５部、ホキシ
ム５部及び芳香族系石油溶剤３部を混合した後、乾燥し
て、ホキシム粒剤１００部を得た。この粒剤は、ホキシ
ム５重量％を含有する。Comparative Example 1 After mixing 95 parts of natural pumice with a particle size of 2.4 to 4.811 nm, 5 parts of Phoxim, and 3 parts of an aromatic petroleum solvent, the mixture was dried to obtain 100 parts of Phoxim granules. The granules contain 5% by weight of Phoxim.
比較例２
粒子径２．４〜４．８ ｍｍの活性炭９５部、ホキシム
５部及び芳香族系石油溶剤３部を混合した後、乾燥して
、ホキシム粒剤１００部を得た。この粒剤は、ホキシム
５重量％を含有する。Comparative Example 2 95 parts of activated carbon having a particle size of 2.4 to 4.8 mm, 5 parts of Phoxim, and 3 parts of an aromatic petroleum solvent were mixed and dried to obtain 100 parts of Phoxim granules. The granules contain 5% by weight of Phoxim.
試験例１
上記実施例及び比較例にて調製した粒剤のそれぞれにつ
いて、（社）日本しろあり対策協会によって定められた
室内試験方法（ＪＷＰＡＳ−第１３号、土壌処理用防蟻
剤の防蟻力効力試験方法）に準拠して、効力試験を行な
った。結果を第１表に示す。Test Example 1 Each of the granules prepared in the above Examples and Comparative Examples was tested using the indoor test method (JWPAS-No. 13, termite prevention ability of soil treatment termiticides) specified by the Japan White Ant Countermeasures Association. Efficacy testing was conducted in accordance with the Efficacy Test Method. The results are shown in Table 1.
また、セピオライト、アタパルジャイト、アロフェン又
は軽石のみを同様に用いた場合の結果も併せて示す。こ
の結果から、本発明によるシロアリ防除剤が高い殺蟻効
果を有することが示される。Also shown are the results when only sepiolite, attapulgite, allophane, or pumice were used in the same way. This result shows that the termite control agent according to the present invention has a high termicidal effect.
試験例２
上記実施例及び比較例において調製したそれぞれの製剤
を温度４０’Ｃ１相対湿度１００％及び温度２５“Ｃ１
相対湿度６０％の条件下にそれぞれ２４時間ごとに反復
保存し、２４時間ごとに重量を測定して、その調湿Ｎ能
を調べた。結果を第２表に示す。この結果から、本発明
によるシロアリ防除剤がＭＦＥＪ 湿機能にすぐれるこ
とが示される。Test Example 2 Each formulation prepared in the above Examples and Comparative Examples was heated at a temperature of 40'C1 with a relative humidity of 100% and a temperature of 25'C1.
Each sample was repeatedly stored every 24 hours under conditions of relative humidity of 60%, and its weight was measured every 24 hours to examine its humidity conditioning N ability. The results are shown in Table 2. This result shows that the termite control agent according to the present invention has excellent MFEJ moisture function.
特許出願人 武田薬品工業株式会社 代理人 弁理士 牧 野 逸 部Patent applicant: Takeda Pharmaceutical Company Limited Agent Patent Attorney Makino Ittobu
Claims (4)
よりなる群から選ばれる少なくとも１種の粘土性多孔質
粒子からなる担体に殺蟻成分を担持させてなることを特
徴とするシロアリ防除剤。(1) A termite control agent comprising an anticide component supported on a carrier consisting of at least one type of clay porous particles selected from the group consisting of sepiolite, attapulgiaite, and allofene.
よりなる群から選ばれる少なくとも１種の粘土性多孔質
粒子からなる担体に殺蟻成分を担持させてなるシロアリ
防除剤成分と、セピオライト、アタパルジヤイト及びア
ロフエンよりなる群から選ばれる少なくとも１種の粘土
性多孔質粒子からなる調湿剤成分との混合物とからなる
ことを特徴とするシロアリ防除剤。(2) A termite control agent component comprising an anticide component supported on a carrier consisting of at least one type of clay porous particles selected from the group consisting of sepiolite, attapulgiaite, and allofuene, and a group consisting of sepiolite, attapulgite, and allofuene. 1. A termite control agent comprising a mixture of at least one selected clay porous particle and a humidity conditioner component.
ト、アタパルジヤイト及びアロフエンよりなる群から選
ばれる少なくとも１種の粘土性多孔質粒子からなる調湿
剤成分との混合物とからなることを特徴とするシロアリ
防除剤。(3) It is characterized by consisting of a mixture of granules or powder containing an anticide component and a humectant component consisting of at least one kind of clay porous particles selected from the group consisting of sepiolite, attapulgiaite, and allofene. termite control agent.
ト、アタパルジヤイト及びアロフエンよりなる群から選
ばれる少なくとも１種の粘土性多孔質粒子からなる調湿
剤成分とを家屋の床下に散布することを特徴とする家屋
の床下のシロアリ防除方法。(4) Spreading a granule or powder containing an anticide component and a humidity conditioner component consisting of at least one type of clay porous particle selected from the group consisting of sepiolite, attapulgiaite, and allofene under the floor of a house. A method for controlling termites under the floor of a house, which is characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27039688A JPH02117602A (en) | 1988-10-26 | 1988-10-26 | Agent and method for controlling termite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27039688A JPH02117602A (en) | 1988-10-26 | 1988-10-26 | Agent and method for controlling termite |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02117602A true JPH02117602A (en) | 1990-05-02 |
Family
ID=17485677
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP27039688A Pending JPH02117602A (en) | 1988-10-26 | 1988-10-26 | Agent and method for controlling termite |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02117602A (en) |
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| WO2003003828A1 (en) * | 2001-07-03 | 2003-01-16 | Topics Co., Ltd. | Material for improving living environment, and building material, laying material and spraying agent using the same |
| WO2003056920A1 (en) * | 2001-12-28 | 2003-07-17 | Topics Co., Ltd. | Method for producing hinokitiol-containing material for improving living environment |
| WO2003103391A1 (en) * | 2002-06-06 | 2003-12-18 | Kotai Laszlo | Carrier material for mosquito-larvae killing pesticides |
| WO2006036387A3 (en) * | 2004-08-25 | 2006-10-26 | Bayer Cropscience Lp | Method of controlling termites |
| JP2010018527A (en) * | 2008-07-09 | 2010-01-28 | Hokko Chem Ind Co Ltd | Agrochemical granule |
| FR3019441A1 (en) * | 2014-04-07 | 2015-10-09 | Ab7 Innovation | MICROPARTICLES CHARGED WITH LIPOPHILIC ACTIVE COMPOSITION MADE OF DIRECTLY DISPERSIBLE WET POWDER IN AQUEOUS MEDIUM AND PROCESS FOR OBTAINING THE SAME |
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| JPS55100301A (en) * | 1979-01-26 | 1980-07-31 | Koichi Morimoto | Insecticidal and preservative material containing obsidian as the major component |
| JPS56105042A (en) * | 1980-01-25 | 1981-08-21 | Yoshinobu Aoyama | Moistureproof and ant preventing agent for building |
| JPS61118138A (en) * | 1984-11-12 | 1986-06-05 | Toyota Central Res & Dev Lab Inc | Humidity conditioning material and its manufacture |
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| WO2003003828A1 (en) * | 2001-07-03 | 2003-01-16 | Topics Co., Ltd. | Material for improving living environment, and building material, laying material and spraying agent using the same |
| WO2003056920A1 (en) * | 2001-12-28 | 2003-07-17 | Topics Co., Ltd. | Method for producing hinokitiol-containing material for improving living environment |
| WO2003103391A1 (en) * | 2002-06-06 | 2003-12-18 | Kotai Laszlo | Carrier material for mosquito-larvae killing pesticides |
| WO2006036387A3 (en) * | 2004-08-25 | 2006-10-26 | Bayer Cropscience Lp | Method of controlling termites |
| JP2008510818A (en) * | 2004-08-25 | 2008-04-10 | バイエル・クロツプサイエンス・エル・ピー | Termite control |
| JP2010018527A (en) * | 2008-07-09 | 2010-01-28 | Hokko Chem Ind Co Ltd | Agrochemical granule |
| FR3019441A1 (en) * | 2014-04-07 | 2015-10-09 | Ab7 Innovation | MICROPARTICLES CHARGED WITH LIPOPHILIC ACTIVE COMPOSITION MADE OF DIRECTLY DISPERSIBLE WET POWDER IN AQUEOUS MEDIUM AND PROCESS FOR OBTAINING THE SAME |
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