JPH02112686A - Scroll type compressor - Google Patents
Scroll type compressorInfo
- Publication number
- JPH02112686A JPH02112686A JP26460788A JP26460788A JPH02112686A JP H02112686 A JPH02112686 A JP H02112686A JP 26460788 A JP26460788 A JP 26460788A JP 26460788 A JP26460788 A JP 26460788A JP H02112686 A JPH02112686 A JP H02112686A
- Authority
- JP
- Japan
- Prior art keywords
- scroll
- resin composition
- resin
- forming
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 9
- 239000004917 carbon fiber Substances 0.000 claims abstract description 9
- 230000006835 compression Effects 0.000 claims abstract description 9
- 238000007906 compression Methods 0.000 claims abstract description 9
- 239000011342 resin composition Substances 0.000 claims abstract description 9
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000010998 test method Methods 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 abstract description 8
- 239000011347 resin Substances 0.000 abstract description 8
- 238000005299 abrasion Methods 0.000 abstract description 5
- 238000000748 compression moulding Methods 0.000 abstract description 4
- 238000001746 injection moulding Methods 0.000 abstract description 4
- 239000000314 lubricant Substances 0.000 abstract description 3
- 239000004615 ingredient Substances 0.000 abstract 2
- 238000010099 solid forming Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- 239000004696 Poly ether ether ketone Substances 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910003481 amorphous carbon Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920002530 polyetherether ketone Polymers 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 239000013585 weight reducing agent Substances 0.000 description 2
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004697 Polyetherimide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 229910021383 artificial graphite Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000011549 displacement method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04C—ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
- F04C18/00—Rotary-piston pumps specially adapted for elastic fluids
- F04C18/02—Rotary-piston pumps specially adapted for elastic fluids of arcuate-engagement type, i.e. with circular translatory movement of co-operating members, each member having the same number of teeth or tooth-equivalents
- F04C18/0207—Rotary-piston pumps specially adapted for elastic fluids of arcuate-engagement type, i.e. with circular translatory movement of co-operating members, each member having the same number of teeth or tooth-equivalents both members having co-operating elements in spiral form
- F04C18/0246—Details concerning the involute wraps or their base, e.g. geometry
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04C—ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
- F04C2230/00—Manufacture
- F04C2230/20—Manufacture essentially without removing material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05B—INDEXING SCHEME RELATING TO WIND, SPRING, WEIGHT, INERTIA OR LIKE MOTORS, TO MACHINES OR ENGINES FOR LIQUIDS COVERED BY SUBCLASSES F03B, F03D AND F03G
- F05B2230/00—Manufacture
- F05B2230/20—Manufacture essentially without removing material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05B—INDEXING SCHEME RELATING TO WIND, SPRING, WEIGHT, INERTIA OR LIKE MOTORS, TO MACHINES OR ENGINES FOR LIQUIDS COVERED BY SUBCLASSES F03B, F03D AND F03G
- F05B2280/00—Materials; Properties thereof
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05C—INDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
- F05C2251/00—Material properties
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Rotary Pumps (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、冷凍・空調等の各分野で使用される圧縮機の
一つで、固定のスクロールと駆動軸の回転によって揺動
するスクロールを備え、媒体を圧縮するスクロール型圧
縮機に関するものである。[Detailed Description of the Invention] <Industrial Application Field> The present invention is one of the compressors used in various fields such as refrigeration and air conditioning. The present invention relates to a scroll type compressor for compressing a medium.
〈従来の技術〉
一般に用いられている気体、液体等の媒体を圧縮するス
クロール型圧縮機の圧縮部である固定スクロール及びそ
れに対向して駆動軸の回転によって揺動する揺動スクロ
ールの構成は、ともに鋳鉄系材料での形成及びアルミ系
材料で形成するか、若しくはそれらの組合わせによる構
成を採っている。<Prior Art> The configuration of a fixed scroll, which is the compression part of a commonly used scroll compressor that compresses media such as gas and liquid, and an oscillating scroll that swings in opposition to the fixed scroll by the rotation of a drive shaft is as follows. Both are made of cast iron material, aluminum material, or a combination thereof.
これ等材料による欠点としては、スクロール部の加工コ
ストの高費につながっている。更に、圧縮機の効率に関
して、揺動スクロールの重量がエネルギーロスを発生す
ると共に、揺動スクロールの高重量は駆動軸、軸受に大
きな応力を発生し長期間の安定した運転の信頼性にも欠
けるものとなる。A disadvantage of these materials is that they lead to high processing costs for the scroll portion. Furthermore, regarding the efficiency of the compressor, the weight of the oscillating scroll causes energy loss, and the high weight of the oscillating scroll causes large stress on the drive shaft and bearings, making it unreliable for long-term stable operation. Become something.
〈発明が解決しようとする課題〉
即ち、従来技術においては、圧縮機の高効率化及び高速
・高荷重での運転に対し充分な信頼性を確保していると
はいえない。また、スクロール部の加工のコスト高など
の問題点があり、解決課題となっていた。<Problems to be Solved by the Invention> In other words, in the conventional technology, it cannot be said that sufficient reliability is ensured for increasing the efficiency of the compressor and for operation at high speed and high load. In addition, there are other problems such as the high cost of processing the scroll portion, which remains to be solved.
本発明は上記実状に鑑み、固定スクロール及び揺動スク
ロールの加工ロスの低減と軽量化による高品質のスクロ
ール型圧縮機を提供することを目的としたものである。In view of the above-mentioned circumstances, the present invention aims to provide a high-quality scroll compressor by reducing processing loss and weight reduction of fixed scrolls and oscillating scrolls.
く課題を解決するための手段〉
本発明は、スクロール型圧縮機の圧縮部を構成する固定
スクロール及び揺動スクロール部を、炭素繊維及び炭素
粉末を必須成分として、試験法ASTM−D648で決
定される熱変形温度が200℃以上を有する樹脂組成物
をもって、射出成形、圧縮成形などにより一体形成され
たスクロール部を構成する手段を用いるものである。Means for Solving the Problems> The present invention provides a fixed scroll and an oscillating scroll part constituting the compression part of a scroll compressor, which contain carbon fiber and carbon powder as essential components, and which are determined by test method ASTM-D648. In this method, the scroll portion is integrally formed by injection molding, compression molding, etc. using a resin composition having a heat deformation temperature of 200° C. or higher.
〈作用〉
上記のような、固定スクロールと揺動スクロールを形成
する樹脂組成物の必須成分として、樹脂機械的強度を高
めると共に、線膨張係数を小さくする炭素繊維及び自己
潤滑剤で樹脂の耐摩耗性向上となる炭素粉末を用いる。<Function> As an essential component of the resin composition that forms the fixed scroll and the orbiting scroll as described above, carbon fiber and self-lubricating agent that increase the mechanical strength of the resin and reduce the coefficient of linear expansion improve the wear resistance of the resin. Uses carbon powder that improves properties.
これにより圧縮部での高温に十分耐え得るものとなり、
固定スクロールに対向して揺動するスクロールを共に樹
脂で形成することから熱膨張率をを同じにで、また駆動
軸との摺動部及び対向するスクロール部の摺動部での耐
摩耗性が優れ、且つ軽量となる。また、このスクロール
は通常の射出成形、圧縮成形によりスクロール部の一体
成型ができ金属系材料のような切削加工が不要となる。This allows it to withstand high temperatures in the compression section.
Since the scroll that swings in opposition to the fixed scroll is both made of resin, the coefficient of thermal expansion is the same, and the abrasion resistance of the sliding part with the drive shaft and the sliding part of the opposing scroll part is improved. Excellent and lightweight. In addition, the scroll portion of this scroll can be integrally molded by ordinary injection molding or compression molding, eliminating the need for cutting work required for metal-based materials.
この場合、本発明で使用される樹脂組成物について述べ
れば、この樹脂マトリックスは、■ポリエーテルエーテ
ルケトン
■ポリイミド
■ポリアミドイミド
■ポリフェニレンサルファイド
■芳香族ポリエステル
■ポリエーテルスルホン
■ポリエーテルイミド
などが好ましい。In this case, regarding the resin composition used in the present invention, the resin matrix is preferably 1) polyetheretherketone, 2) polyimide, 2) polyamideimide, 2) polyphenylene sulfide, 2) aromatic polyester, 2) polyether sulfone, and 3) polyetherimide.
また、本発明で必須成分とする炭素繊維はアクリル繊維
、ピッチなどを原料とした繊維長0.1〜10關のもの
が好ましい。この炭素繊維は樹脂マトリックスとの接着
性向上のため、エポキシ樹脂、ポリアミド樹脂な・どで
表面処理を施したものが好ましいが、特に、これに限定
しなくてもよい。一方、本発明でもう一つの必須成分で
ある炭素粉末は完全な黒鉛構造を有するもの、及び無定
形炭素であっても使用可能であり、黒鉛の場合は、天然
黒鉛1人造黒鉛のいずれでも良い。また、無定形炭素は
コークス。Further, the carbon fiber which is an essential component in the present invention is preferably one made of acrylic fiber, pitch, etc. and having a fiber length of about 0.1 to 10. The carbon fibers are preferably surface-treated with epoxy resin, polyamide resin, etc. in order to improve adhesion to the resin matrix, but the carbon fibers are not particularly limited thereto. On the other hand, the carbon powder, which is another essential component in the present invention, can be used even if it has a complete graphite structure or is amorphous carbon. In the case of graphite, it can be either natural graphite or artificial graphite. . Also, amorphous carbon is coke.
ガスカーボン、カーボンブラックなどカーボン状物質は
いずれも使用することが可能であり、その平均粒径は2
〜100μmが好ましい。なお、樹脂組成物において、
発明の主目的を阻害しない範囲で二硫化モリブデン、フ
ッ素樹脂。Any carbon-like substance such as gas carbon or carbon black can be used, and the average particle size is 2.
~100 μm is preferred. In addition, in the resin composition,
Molybdenum disulfide and fluororesin within a range that does not impede the main purpose of the invention.
ガラス繊維、ホウ素繊維、炭化ケイ素繊維、ガラスクロ
スなどの補強材を配合しても良い。Reinforcing materials such as glass fiber, boron fiber, silicon carbide fiber, and glass cloth may also be blended.
〈実施例〉
以下、本発明を実施例の図面に基ずいて説明すれば、次
の通りである。<Example> The present invention will be described below based on the drawings of the example.
先ず、第1図A、Bはスクロール型圧縮機の圧縮部を示
す断面図及び固定スクロールと揺動スクロールのスクロ
ール歯部組合わせ説明図であり、1は高圧室(図示せず
)に臨む所定の渦巻き形状のスクロール歯部1aを下向
き突出の固定スクロールで、該固定スクロール1に対し
同様の渦巻き形状のスクロール歯部2aを上向きに突出
の揺動スクロール2を嵌め合わせ圧縮部を構成する。3
は動揺動スクロール2を偏心回転するためのクランクシ
ャフトである。First, FIGS. 1A and 1B are cross-sectional views showing the compression section of a scroll compressor and explanatory views of the combination of scroll teeth of a fixed scroll and an oscillating scroll, and 1 is a predetermined position facing a high pressure chamber (not shown). A fixed scroll having a spiral-shaped scroll tooth portion 1a projecting downwardly is fitted to the fixed scroll 1, and an oscillating scroll 2 having a similar spiral-shaped scroll tooth portion 2a projecting upwardly is fitted to the fixed scroll 1 to form a compression section. 3
is a crankshaft for eccentrically rotating the oscillating scroll 2.
ここにおいて、この固定スクロール1及び揺動スクロー
ル2を構成する樹脂組成物の実施例及び比較例を第1表
に示す。Table 1 shows examples and comparative examples of resin compositions constituting the fixed scroll 1 and the orbiting scroll 2.
同表の実施例1及び2は、夫々固定及び揺動スクロール
を樹脂マトリックスがポリエーテルエーテルケトンから
なる組成物及び樹脂マトリックスがポリイミドからなる
組成物で製作したものである。また、比較例1及び2は
夫々鋳鉄系材料及び熱処理したアルミ材料である。In Examples 1 and 2 in the same table, the fixed scroll and the oscillating scroll were manufactured using a composition in which the resin matrix was made of polyetheretherketone, and a composition in which the resin matrix was made of polyimide, respectively. Moreover, Comparative Examples 1 and 2 are cast iron-based materials and heat-treated aluminum materials, respectively.
ここで試験方法について述べる。密度は水中置換法によ
り測定する。また、摺動特性は荷重65kg、回転数7
4 Orp*により潤滑下(スニソ4GSD10%+フ
レオン90%)の条件において、摺動時間2時間とした
ときのアムスラー型摩耗試験機による確認を行った。こ
のアムスラー型摩耗試験機の測定原理の概略図を第2図
に示す。軸4に摺接する軸受5に荷重りを負荷し、油滴
下位置Pに潤滑液を滴下して矢印方向に軸4を回転させ
たときの摩耗の程度について、はとんど摩耗なしく同表
、0印)、やや摩耗する(△印)、異常摩耗又はロック
現象を生じたもの(×印)の3段階にわけて評価した。The test method will now be described. Density is measured by the underwater displacement method. In addition, the sliding characteristics are as follows: load 65kg, rotation speed 7
Confirmation was performed using an Amsler type wear tester under the conditions of lubrication (Suniso 4GSD 10% + Freon 90%) using 4 Orp* and a sliding time of 2 hours. A schematic diagram of the measurement principle of this Amsler type abrasion tester is shown in Fig. 2. Regarding the degree of wear when the shaft 4 is rotated in the direction of the arrow with a load applied to the bearing 5 that slides on the shaft 4 and lubricant is dripped at the oil dripping position P, there is almost no wear as shown in the table below. , 0 mark), slight wear (△ mark), and abnormal wear or locking phenomenon (x mark).
熱的性質としては、角柱試験片を試料とし、TMA法(
熱機械的分析装置を用いて、室温〜150℃における試
料の膨張量を11P1定する方法)によって線膨張係数
を求めた。また、熱変形温度はASTM−D648にお
ける18.5kg/C−の荷重下において求めた。Thermal properties were measured using the TMA method (
Using a thermomechanical analyzer, the coefficient of linear expansion was determined by the 11P1 method of determining the amount of expansion of a sample between room temperature and 150°C. Further, the heat distortion temperature was determined under a load of 18.5 kg/C- according to ASTM-D648.
第1表から明らかのように同実施例1,2はいずれも比
較例1及び2より密度が低く軽量化につながる。また、
諸特性においても優れていることかわかる。As is clear from Table 1, both Examples 1 and 2 have lower densities than Comparative Examples 1 and 2, leading to weight reduction. Also,
It can be seen that it has excellent properties as well.
〈発明の効果〉
上述のように本発明のスクロール型圧縮機の圧縮部を、
炭素繊維及び炭素粉末を必須成分とした樹脂組成物で形
成したことにより、軽量化による効率向上、振動低減及
び信頼性の向上が可能となる。また、一体金型成形によ
り、加工が不必要となり、初期の目的を達成するもので
ある。<Effects of the Invention> As described above, the compression section of the scroll compressor of the present invention is
By forming it from a resin composition containing carbon fiber and carbon powder as essential components, it is possible to improve efficiency by reducing weight, reduce vibration, and improve reliability. In addition, integral molding eliminates the need for processing, achieving the initial objective.
図面は本発明の実施例を示すもので、第1図Aはスクロ
ール型圧縮機の圧縮部の断面概略図、第1図Bは同固定
スクロールと揺動スクロールのスクロール歯部の組合わ
せ説明図、第2図はアムスラー型摩耗試験機の試験説明
図である。
1・・・固定スクロール、2・・・揺動スクロール、4
・・・軸、5・・・軸受。
第1図(A)
第1図(B)The drawings show an embodiment of the present invention, and FIG. 1A is a schematic cross-sectional view of the compression section of a scroll compressor, and FIG. 1B is an explanatory diagram of the combination of the fixed scroll and the scroll teeth of the oscillating scroll. , FIG. 2 is an explanatory diagram of a test using an Amsler type abrasion tester. 1... Fixed scroll, 2... Oscillating scroll, 4
...shaft, 5...bearing. Figure 1 (A) Figure 1 (B)
Claims (1)
ロール及び揺動スクロール部を、炭素繊維及び炭素系粉
末を必須成分として試験法ASTM−D648で決定さ
れる熱変形温度が200℃以上の樹脂組成物から形成し
たことを特徴とするスクロール型圧縮機。1. The fixed scroll and the oscillating scroll part that constitute the compression part of a scroll compressor are made of a resin composition containing carbon fiber and carbon-based powder as essential components and having a heat distortion temperature of 200°C or higher as determined by test method ASTM-D648. A scroll type compressor characterized by the following:
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26460788A JPH02112686A (en) | 1988-10-20 | 1988-10-20 | Scroll type compressor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26460788A JPH02112686A (en) | 1988-10-20 | 1988-10-20 | Scroll type compressor |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH02112686A true JPH02112686A (en) | 1990-04-25 |
Family
ID=17405671
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP26460788A Pending JPH02112686A (en) | 1988-10-20 | 1988-10-20 | Scroll type compressor |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH02112686A (en) |
-
1988
- 1988-10-20 JP JP26460788A patent/JPH02112686A/en active Pending
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