JPH02104680A - Surface decoration treatment - Google Patents
Surface decoration treatmentInfo
- Publication number
- JPH02104680A JPH02104680A JP88258868A JP25886888A JPH02104680A JP H02104680 A JPH02104680 A JP H02104680A JP 88258868 A JP88258868 A JP 88258868A JP 25886888 A JP25886888 A JP 25886888A JP H02104680 A JPH02104680 A JP H02104680A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- decorative
- metal
- metal layer
- gold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005034 decoration Methods 0.000 title claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims abstract description 26
- 239000002184 metal Substances 0.000 claims abstract description 26
- 239000011248 coating agent Substances 0.000 claims abstract description 10
- 238000000576 coating method Methods 0.000 claims abstract description 10
- 239000007769 metal material Substances 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 11
- 230000000873 masking effect Effects 0.000 claims description 11
- 239000010410 layer Substances 0.000 claims 5
- 239000011247 coating layer Substances 0.000 claims 2
- 238000000151 deposition Methods 0.000 claims 1
- 238000003672 processing method Methods 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 abstract description 11
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052782 aluminium Inorganic materials 0.000 abstract description 2
- 229910052759 nickel Inorganic materials 0.000 abstract description 2
- 229910052709 silver Inorganic materials 0.000 abstract description 2
- 238000004090 dissolution Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 14
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 11
- 239000010931 gold Substances 0.000 description 10
- 229910001020 Au alloy Inorganic materials 0.000 description 9
- 239000003353 gold alloy Substances 0.000 description 9
- 239000002537 cosmetic Substances 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 239000012495 reaction gas Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 101100313003 Rattus norvegicus Tanc1 gene Proteins 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- UQZIWOQVLUASCR-UHFFFAOYSA-N alumane;titanium Chemical compound [AlH3].[Ti] UQZIWOQVLUASCR-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910021385 hard carbon Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- MOFOBJHOKRNACT-UHFFFAOYSA-N nickel silver Chemical compound [Ni].[Ag] MOFOBJHOKRNACT-UHFFFAOYSA-N 0.000 description 1
- 239000010956 nickel silver Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63H—MARINE PROPULSION OR STEERING
- B63H9/00—Marine propulsion provided directly by wind power
- B63H9/04—Marine propulsion provided directly by wind power using sails or like wind-catching surfaces
- B63H9/06—Types of sail; Constructional features of sails; Arrangements thereof on vessels
- B63H9/067—Sails characterised by their construction or manufacturing process
- B63H9/0678—Laminated sails
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63H—MARINE PROPULSION OR STEERING
- B63H9/00—Marine propulsion provided directly by wind power
- B63H9/04—Marine propulsion provided directly by wind power using sails or like wind-catching surfaces
- B63H9/06—Types of sail; Constructional features of sails; Arrangements thereof on vessels
- B63H9/067—Sails characterised by their construction or manufacturing process
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- Ocean & Marine Engineering (AREA)
- Laminated Bodies (AREA)
- ing And Chemical Polishing (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、表面化粧処理方法の改良、詳しくは、硬質化
合物の被膜が呈する非金属色と金や金合金などのごとき
装飾金属が呈する金属色とを金属材料の表面に精密かつ
安定的に層着させることができる実用的な金属材料の表
面化粧処理方法に関し、装飾物の表面加工、眼鏡などの
表面加工に利用することができる。[Detailed Description of the Invention] [Field of Industrial Application] The present invention aims to improve a surface cosmetic treatment method, and more specifically, to improve the nonmetallic color exhibited by a hard compound coating and the metallic color exhibited by decorative metals such as gold and gold alloys. The present invention relates to a practical surface cosmetic treatment method for metal materials that can accurately and stably layer color onto the surface of metal materials, and can be used for surface treatment of decorative objects, glasses, etc.
〔従来の技術、および解決すべき技術的課題〕金属材料
の表面に金または金合金の被膜を施し、その上に耐熱性
マスキング剤により所要パターンのマスキングを施して
から、窒化チタン（Ｔｉｅ）などの硬質化合物をイオン
ブレーティングせしめ、ついで前記マスキング層を剥離
することによって、金属表面を多色調に装飾せしめる表
面処理方法は従来公知である（特公昭５９−２６６６４
号公報参照）。[Prior art and technical issues to be solved] A film of gold or gold alloy is applied to the surface of a metal material, a desired pattern is masked with a heat-resistant masking agent, and then a film of titanium nitride (Tie) or the like is applied. A surface treatment method in which a metal surface is decorated in multiple colors by ion-blating a hard compound and then peeling off the masking layer is known (Japanese Patent Publication No. 59-26664).
(see publication).
しかし、この方法においては、使用するマスキング剤に
耐熱性および耐真空性が要求されるところからマスキン
グ剤選択の範囲が制限、されるのに加え、仕上りの不良
率も高く、しかも硬質化合物層の下に隠蔽されて装飾に
寄与しない部分にまでも高価な金や金合金を被覆するこ
とになるためコスト的に無駄で不経済であるという欠点
があった。However, in this method, the range of masking agent selection is limited because the masking agent used is required to have heat resistance and vacuum resistance, and the defective rate of the finish is also high. Even parts that are hidden underneath and do not contribute to decoration have to be coated with expensive gold or gold alloy, which has the disadvantage of being wasteful and uneconomical in terms of cost.
本発明は、金属表面に金色を含む多色調の化粧を施す従
来の表面処理技術に前述のごとき欠点があったことに鑑
みて為されたもので、硬質化合物の被膜が呈する非金属
色と金（金合金）などの装飾金属が呈する金属色とを金
属材料の表面に精密かつ安定的に層着させることができ
る経済的な表面化粧処理方法を提供することを技術的課
題とするものである。The present invention was made in view of the above-mentioned drawbacks of conventional surface treatment techniques that apply multi-colored makeup including gold to metal surfaces. The technical problem is to provide an economical surface cosmetic treatment method that can precisely and stably layer the metallic color exhibited by decorative metals such as (gold alloy) on the surface of metal materials. .
本発明者が上記技術的課題を解決するために採用した手
段を説明すれば、次の通りである。The means adopted by the present inventor to solve the above technical problem are as follows.
即ち、本発明が提供する表面化粧処理方法は、Ａ、金属
素材の表面に硬質化合物被膜を施すというフＴンデーシ
ーン処理工程；
Ｂ、施された前記被膜層（ファンデージ躇ン層）の上に
装飾金属を層着せしめるという装飾金属層着工程；
Ｃ１この装飾金属層の上に所要パターンのマスキングを
施すという化粧パターン形成工程；Ｄ、これ（化粧対象
物）を剥離液中で溶解して非マスキング部分の装飾金属
層を剥離するというファンデージ■ン層ｎ出・装飾金属
回収工程；
Ｅ、＠記マスキング層を除去することによって硬質被膜
層と装飾金属層とによる装飾４１様を現出せしめる化粧
現出工程；
といった工程的手段を、対象とする金属材料に逐次的に
施すことを要旨とする。That is, the surface cosmetic treatment method provided by the present invention includes: A. a foundation treatment step of applying a hard compound coating to the surface of a metal material; B. a step of applying a hard compound coating to the surface of the metal material; B. Decorative metal layering step of applying a layer of decorative metal; C1. Decorative pattern forming step of masking a desired pattern on the decorative metal layer; D. Dissolving this (the cosmetic object) in a stripping solution to remove the A foundation layer removal/decoration metal recovery process in which the decorative metal layer of the masked area is peeled off; The gist is to sequentially apply process means such as a cosmetic appearance process to the target metal material.
ちなみに、本発明について注釈を加えておくと、まず、
本発明が化粧対象とする金属素材としては、洋白、ステ
ンレス、チタンなど全ての金属を採択できるのであるが
、経済的には比較的に安価なニッケル、アルミ、チタン
、銅、鉄などのごとき卑金属材料（ｂａｓｅ ｆｆ１ｅ
ｔａｘ）や合金材料が適当である。By the way, to add some notes regarding the present invention, first of all,
All metals such as nickel silver, stainless steel, and titanium can be used as the metal materials for which the present invention applies cosmetics, but economically relatively inexpensive materials such as nickel, aluminum, titanium, copper, and iron can be used. Base metal materials (base ff1e
tax) and alloy materials are suitable.
つぎに、上記金属素材の表面に施す硬質化合物被膜の素
材としては、Ｔｉｎ、 ＴｉＣ，ＴｉＡＬＮ、 ＴｉＡ
ＬＮＣ。Next, the materials for the hard compound coating to be applied to the surface of the metal material include Tin, TiC, TiALN, and TiA.
LNC.
ＴｉＡＬＣ，Ｔａｎ、 ＴａＣ，ＴａＮＣ，ＣｒＮ、Ｃ
ｒＣ，ＣｒＮＣ，ＴｉＡＬａＶ６Ｎ、ＴｔＡｔａＶｈＣ
ｌおよびＴｉＡｔ、Ｖ、ＮＣの中から適宜−以上のもの
を選択することができる。TiALC, Tan, TaC, TaNC, CrN, C
rC, CrNC, TiALaV6N, TtAtaVhC
1, TiAt, V, and NC can be selected as appropriate.
また、上記硬質化合物の被膜上に層着せしめる装飾金属
としては、金（金合金）、銀、その他クロム（（”ｙ）
のごとき表面化粧金属材料などを用いることができる。In addition, decorative metals to be layered on the hard compound coating include gold (gold alloy), silver, and other chromium ((''y)
A surface-decorated metallic material such as can be used.
なお、本発明は以下に掲げる実施例に限定されるもので
は決してなく、［特許請求の範囲ｊの記載内において種
々変更することが可能であって、金属素材上に硬質化合
物被膜を形成したり、更にその上に装飾金属を層着する
方法については、イオンブレーティング法だけでなく、
従来周知の被膜形成法が色々と代替適用可能であること
は云うまでもない。It should be noted that the present invention is by no means limited to the embodiments listed below, and may be modified in various ways within the scope of claim j, including forming a hard compound film on a metal material, etc. In addition to the ion-blating method, there are also methods for layering decorative metals on top of the metal.
It goes without saying that the conventionally known film forming methods can be applied in various ways.
以下、本発明方法を実施例をもって、さらに詳しく説明
する。Hereinafter, the method of the present invention will be explained in more detail with reference to Examples.
対象とする金属素材として、チタン（Ｔｉ）とチタンア
ルミ（ＴｉＡυを採択し、また反応ガスとして窒素およ
びアセチレンガスを使用する一方、電源としては直流・
高周波電源を用いた。即ち、反応ガス圧とバイアス電圧
により成膜速度を、約０．０１−０．０２μ／分にコン
トロールし、１０− ” 〜５ Ｘ １０− ”ｔａｂ
ａｒの真空下で約２０〜３０分間イオンブレーティング
を行い、前記各金属素材の表面に厚さ０．３〜０．５μ
のＴｉＣ，Ｔ１ＣＮ、ＴｉＡＬＮ、ＴｉＡＬＣＮ、およ
び硬質カーボンを被膜させたところ、当該硬質化合物の
被膜はブラウン、グレー、ないし黒色といった色彩を呈
した。Titanium (Ti) and titanium aluminum (TiAυ) were selected as the target metal materials, and nitrogen and acetylene gas were used as the reaction gases, while direct current and
A high frequency power source was used. That is, the film formation rate was controlled to about 0.01-0.02 μ/min by the reaction gas pressure and bias voltage, and
Ion blating was performed for about 20 to 30 minutes under an AR vacuum, and a thickness of 0.3 to 0.5μ was applied to the surface of each metal material.
When TiC, T1CN, TiALN, TiALCN, and hard carbon were coated, the hard compound coat exhibited a brown, gray, or black color.
次に、か−る硬質化合物被膜が施された上記金属素材を
、そのま−大気に曝すことなく、上記の反応ガス圧、カ
ソードバイアス電圧により成膜速度を約０．０４μ７分
にコントロールし、ｌｏ−３〜５×ＩＯ−ｔｔｒｂａｒ
の真空下で、それぞれ金または金合金（１８金）を厚さ
０．２μにスパッタ形成させ、ついで、を機器マスキン
グ剤で一定のパターンのマスキングを施した後、シアン
系電解剥離液により金色メツキ層を電解剥離し、さらに
有機溶剤を用いてマスキングを除去した。Next, without exposing the metal material coated with the hard compound film to the atmosphere, the film formation rate was controlled to about 0.04μ7 minutes using the reaction gas pressure and cathode bias voltage. Gold or gold alloy (18K) was sputter-formed to a thickness of 0.2μ under a vacuum of lo-3 to 5×IO-ttrbar, and then masked in a certain pattern with an equipment masking agent. The gold plating layer was electrolytically stripped using a cyan-based electrolytic stripping solution, and the masking was further removed using an organic solvent.
しかるところ、上記各金属素材の表面には、ブラウン、
グレー、黒色の硬質化合物被膜と金色メツキ層とか程良
（調和したコントラストをもって美しいデザインが現出
された。なお、上記電解液および有機溶剤中に分離され
た金（金合金）は別途回収した。However, the surface of each of the metal materials mentioned above has brown,
A beautiful design appeared with a harmonious contrast between the gray and black hard compound coating and the gold plating layer.The gold (gold alloy) separated in the electrolyte and organic solvent was collected separately.
以上実施例をもって説明したとおり、本発明によれば、
マスキング機器の発達した今日、対象とする金属素材の
形状に制約されることなく如何に精緻な態様の多色調装
飾パターンでも表現可能であるうえに、従来方法のよう
に金属表面全体に高価な装飾金Ｒ（例えば、金・金合金
）被膜を施さなくても済むので非常に経済的であるのに
加え、工程は頗る簡素であるので能率的に処理すること
ができるほか、仕上った製品は良質で、しかも安価に加
工できるのであり、その実用上のメリットは頗る大きい
。As explained above using the embodiments, according to the present invention,
Nowadays, with the development of masking equipment, it is possible to express any elaborate multi-colored decorative pattern without being restricted by the shape of the target metal material. It is very economical because it does not require a gold R (e.g., gold/gold alloy) coating, and the process is very simple, so it can be processed efficiently, and the finished product is of high quality. Moreover, it can be processed at low cost, and its practical advantages are extremely large.
Claims (1)
被膜層の上に装飾金属を層着せしめた後、この装飾金属
層の上に所要パターンのマスキングを施し、ついで、こ
れを剥離液中で溶解して非マスキング部分の装飾金属層
を剥離し、然る後、前記マスキング層を除去することに
よって、硬質被膜層と装飾金属層とによる装飾模様を現
出せしめることを特徴とした表面化粧処理方法。After applying a hard compound coating to the surface of the metal material and depositing a decorative metal layer on the applied coating layer, masking in a desired pattern is applied to the decorative metal layer, and then this is placed in a stripping solution. A surface decoration characterized in that a decorative pattern formed by a hard coating layer and a decorative metal layer is revealed by dissolving the decorative metal layer in the non-masking part and then removing the masking layer. Processing method.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP88258868A JPH02104680A (en) | 1988-10-17 | 1988-10-13 | Surface decoration treatment |
| DE3928312A DE3928312C2 (en) | 1988-10-17 | 1989-08-26 | Sails and process for their manufacture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP88258868A JPH02104680A (en) | 1988-10-17 | 1988-10-13 | Surface decoration treatment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02104680A true JPH02104680A (en) | 1990-04-17 |
Family
ID=17326152
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP88258868A Pending JPH02104680A (en) | 1988-10-17 | 1988-10-13 | Surface decoration treatment |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPH02104680A (en) |
| DE (1) | DE3928312C2 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5097783A (en) * | 1988-10-17 | 1992-03-24 | Dimension Polyant Sailcloth, Inc. | Reinforced sailcloth |
| FR2694947B1 (en) * | 1992-08-20 | 1994-08-12 | Rossignol Pascal | A method of making a sail for any machine or device with lift and / or with vélique propulsion. |
| EP1114771A1 (en) * | 1999-12-02 | 2001-07-11 | Rox Sails (Ireland) Limited | Composite material, particularly for sails and the like |
| DE10006100B4 (en) * | 2000-02-11 | 2005-12-29 | Andreas Hermann | sail |
| ITVR20060132A1 (en) * | 2006-08-07 | 2008-02-08 | Umberto Righi | EQUIPMENT FOR APPLYING REINFORCEMENT ELEMENTS TO A SAIL |
| DE102009019807A1 (en) | 2009-05-02 | 2010-11-04 | Dimension-Polyant Gmbh | sailcloth |
| DE102013015669A1 (en) | 2013-09-23 | 2015-03-26 | Dimension-Polyant Gmbh | Non-woven fabric canvas |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2320432A1 (en) * | 1973-04-21 | 1974-11-07 | Ballonfab See Luftausr Gmbh | Air-proof, flexible 3-ply laminate - comprising two textile outer layers and plastics or rubber inter layer |
| JPS52121576A (en) * | 1976-04-05 | 1977-10-13 | Kobunshi Kako Kenkyusho | Manufacture of wideewidth web warp filling laminated cloth |
| FI801415A (en) * | 1979-05-05 | 1980-11-06 | Arthur Britton | ARKMATERIAL |
| DD206546A1 (en) * | 1981-11-03 | 1984-02-01 | Polyfol Markkleeberg Veb | PLASTIC FILMING COMPONENTS TEXTILE FLOORING FOR HIGH-RESILIENT COMPOSITE MATERIALS |
| US4444822A (en) * | 1983-03-21 | 1984-04-24 | Howe & Bainbridge | Sailcloth |
| US4679519A (en) * | 1984-11-26 | 1987-07-14 | Linville James C | Laminated cloth construction |
| US4593639A (en) * | 1984-12-14 | 1986-06-10 | Sobstad Sailmakers, Inc. | Method of stress distribution in a sail and sail construction |
| US4702190A (en) * | 1984-12-14 | 1987-10-27 | Sobstad Sailmakers, Inc. | Structural sail with grid members |
| US4624205A (en) * | 1984-12-14 | 1986-11-25 | Sobstad Sailmakers, Inc. | Method of stress distribution in a sail, a sail embodying the same and sail construction |
| EP0224729A1 (en) * | 1985-11-27 | 1987-06-10 | Bainbridge/Aquabatten, Inc. | A sail |
| US4708080A (en) * | 1986-06-11 | 1987-11-24 | Sobstad Sailmakers, Inc. | Composite thread line sails |
-
1988
- 1988-10-13 JP JP88258868A patent/JPH02104680A/en active Pending
-
1989
- 1989-08-26 DE DE3928312A patent/DE3928312C2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE3928312C2 (en) | 2002-08-14 |
| DE3928312A1 (en) | 1990-04-19 |
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