JPH02104680A - Surface decoration treatment - Google Patents

Surface decoration treatment

Info

Publication number
JPH02104680A
JPH02104680A JP88258868A JP25886888A JPH02104680A JP H02104680 A JPH02104680 A JP H02104680A JP 88258868 A JP88258868 A JP 88258868A JP 25886888 A JP25886888 A JP 25886888A JP H02104680 A JPH02104680 A JP H02104680A
Authority
JP
Japan
Prior art keywords
layer
decorative
metal
metal layer
gold
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP88258868A
Other languages
Japanese (ja)
Inventor
Hiroyuki Aku
安久 寛幸
Yoshizumi Ishikawa
石川 良澄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ISHIKAWA GIKEN KK
Original Assignee
ISHIKAWA GIKEN KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ISHIKAWA GIKEN KK filed Critical ISHIKAWA GIKEN KK
Priority to JP88258868A priority Critical patent/JPH02104680A/en
Priority to DE3928312A priority patent/DE3928312C2/en
Publication of JPH02104680A publication Critical patent/JPH02104680A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63HMARINE PROPULSION OR STEERING
    • B63H9/00Marine propulsion provided directly by wind power
    • B63H9/04Marine propulsion provided directly by wind power using sails or like wind-catching surfaces
    • B63H9/06Types of sail; Constructional features of sails; Arrangements thereof on vessels
    • B63H9/067Sails characterised by their construction or manufacturing process
    • B63H9/0678Laminated sails
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63HMARINE PROPULSION OR STEERING
    • B63H9/00Marine propulsion provided directly by wind power
    • B63H9/04Marine propulsion provided directly by wind power using sails or like wind-catching surfaces
    • B63H9/06Types of sail; Constructional features of sails; Arrangements thereof on vessels
    • B63H9/067Sails characterised by their construction or manufacturing process

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • Ocean & Marine Engineering (AREA)
  • Laminated Bodies (AREA)
  • ing And Chemical Polishing (AREA)

Abstract

PURPOSE:To precisely and stably subject a metal base to surface decoration treatment by successively forming a coating film of a hard compd. and a decorative metal layer on the metal base, sticking a mask having a required pattern on the decorative metal layer and removing the exposed part of the layer by dissolution in a removing soln. CONSTITUTION:A coating film of a hard compd. such as TiN or TaC and a layer of a decorative metal such as Au or Ag are successively formed on the surface of a metal base such as Ni or Al. A mask having a required pattern is stuck on the decorative metal layer, this layer is immersed in a removing soln. to dissolve and remove the exposed part of the layer and then the mask is removed. A decorative pattern consisting of the hard compd. film and the decorative metal layer is precisely and stably formed on the surface of the metal base.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、表面化粧処理方法の改良、詳しくは、硬質化
合物の被膜が呈する非金属色と金や金合金などのごとき
装飾金属が呈する金属色とを金属材料の表面に精密かつ
安定的に層着させることができる実用的な金属材料の表
面化粧処理方法に関し、装飾物の表面加工、眼鏡などの
表面加工に利用することができる。
[Detailed Description of the Invention] [Field of Industrial Application] The present invention aims to improve a surface cosmetic treatment method, and more specifically, to improve the nonmetallic color exhibited by a hard compound coating and the metallic color exhibited by decorative metals such as gold and gold alloys. The present invention relates to a practical surface cosmetic treatment method for metal materials that can accurately and stably layer color onto the surface of metal materials, and can be used for surface treatment of decorative objects, glasses, etc.

〔従来の技術、および解決すべき技術的課題〕金属材料
の表面に金または金合金の被膜を施し、その上に耐熱性
マスキング剤により所要パターンのマスキングを施して
から、窒化チタン(Tie)などの硬質化合物をイオン
ブレーティングせしめ、ついで前記マスキング層を剥離
することによって、金属表面を多色調に装飾せしめる表
面処理方法は従来公知である(特公昭59−26664
号公報参照)。
[Prior art and technical issues to be solved] A film of gold or gold alloy is applied to the surface of a metal material, a desired pattern is masked with a heat-resistant masking agent, and then a film of titanium nitride (Tie) or the like is applied. A surface treatment method in which a metal surface is decorated in multiple colors by ion-blating a hard compound and then peeling off the masking layer is known (Japanese Patent Publication No. 59-26664).
(see publication).

しかし、この方法においては、使用するマスキング剤に
耐熱性および耐真空性が要求されるところからマスキン
グ剤選択の範囲が制限、されるのに加え、仕上りの不良
率も高く、しかも硬質化合物層の下に隠蔽されて装飾に
寄与しない部分にまでも高価な金や金合金を被覆するこ
とになるためコスト的に無駄で不経済であるという欠点
があった。
However, in this method, the range of masking agent selection is limited because the masking agent used is required to have heat resistance and vacuum resistance, and the defective rate of the finish is also high. Even parts that are hidden underneath and do not contribute to decoration have to be coated with expensive gold or gold alloy, which has the disadvantage of being wasteful and uneconomical in terms of cost.

本発明は、金属表面に金色を含む多色調の化粧を施す従
来の表面処理技術に前述のごとき欠点があったことに鑑
みて為されたもので、硬質化合物の被膜が呈する非金属
色と金(金合金)などの装飾金属が呈する金属色とを金
属材料の表面に精密かつ安定的に層着させることができ
る経済的な表面化粧処理方法を提供することを技術的課
題とするものである。
The present invention was made in view of the above-mentioned drawbacks of conventional surface treatment techniques that apply multi-colored makeup including gold to metal surfaces. The technical problem is to provide an economical surface cosmetic treatment method that can precisely and stably layer the metallic color exhibited by decorative metals such as (gold alloy) on the surface of metal materials. .

〔課題解決のために採用した手段〕[Means adopted to solve the problem]

本発明者が上記技術的課題を解決するために採用した手
段を説明すれば、次の通りである。
The means adopted by the present inventor to solve the above technical problem are as follows.

即ち、本発明が提供する表面化粧処理方法は、A、金属
素材の表面に硬質化合物被膜を施すというフTンデーシ
ーン処理工程; B、施された前記被膜層(ファンデージ躇ン層)の上に
装飾金属を層着せしめるという装飾金属層着工程; C1この装飾金属層の上に所要パターンのマスキングを
施すという化粧パターン形成工程;D、これ(化粧対象
物)を剥離液中で溶解して非マスキング部分の装飾金属
層を剥離するというファンデージ■ン層n出・装飾金属
回収工程; E、@記マスキング層を除去することによって硬質被膜
層と装飾金属層とによる装飾41様を現出せしめる化粧
現出工程; といった工程的手段を、対象とする金属材料に逐次的に
施すことを要旨とする。
That is, the surface cosmetic treatment method provided by the present invention includes: A. a foundation treatment step of applying a hard compound coating to the surface of a metal material; B. a step of applying a hard compound coating to the surface of the metal material; B. Decorative metal layering step of applying a layer of decorative metal; C1. Decorative pattern forming step of masking a desired pattern on the decorative metal layer; D. Dissolving this (the cosmetic object) in a stripping solution to remove the A foundation layer removal/decoration metal recovery process in which the decorative metal layer of the masked area is peeled off; The gist is to sequentially apply process means such as a cosmetic appearance process to the target metal material.

ちなみに、本発明について注釈を加えておくと、まず、
本発明が化粧対象とする金属素材としては、洋白、ステ
ンレス、チタンなど全ての金属を採択できるのであるが
、経済的には比較的に安価なニッケル、アルミ、チタン
、銅、鉄などのごとき卑金属材料(base ff1e
tax)や合金材料が適当である。
By the way, to add some notes regarding the present invention, first of all,
All metals such as nickel silver, stainless steel, and titanium can be used as the metal materials for which the present invention applies cosmetics, but economically relatively inexpensive materials such as nickel, aluminum, titanium, copper, and iron can be used. Base metal materials (base ff1e
tax) and alloy materials are suitable.

つぎに、上記金属素材の表面に施す硬質化合物被膜の素
材としては、Tin、 TiC,TiALN、 TiA
LNC。
Next, the materials for the hard compound coating to be applied to the surface of the metal material include Tin, TiC, TiALN, and TiA.
LNC.

TiALC,Tan、 TaC,TaNC,CrN、C
rC,CrNC,TiALaV6N、TtAtaVhC
lおよびTiAt、V、NCの中から適宜−以上のもの
を選択することができる。
TiALC, Tan, TaC, TaNC, CrN, C
rC, CrNC, TiALaV6N, TtAtaVhC
1, TiAt, V, and NC can be selected as appropriate.

また、上記硬質化合物の被膜上に層着せしめる装飾金属
としては、金(金合金)、銀、その他クロム((”y)
のごとき表面化粧金属材料などを用いることができる。
In addition, decorative metals to be layered on the hard compound coating include gold (gold alloy), silver, and other chromium ((''y)
A surface-decorated metallic material such as can be used.

なお、本発明は以下に掲げる実施例に限定されるもので
は決してなく、[特許請求の範囲jの記載内において種
々変更することが可能であって、金属素材上に硬質化合
物被膜を形成したり、更にその上に装飾金属を層着する
方法については、イオンブレーティング法だけでなく、
従来周知の被膜形成法が色々と代替適用可能であること
は云うまでもない。
It should be noted that the present invention is by no means limited to the embodiments listed below, and may be modified in various ways within the scope of claim j, including forming a hard compound film on a metal material, etc. In addition to the ion-blating method, there are also methods for layering decorative metals on top of the metal.
It goes without saying that the conventionally known film forming methods can be applied in various ways.

〔実施例〕〔Example〕

以下、本発明方法を実施例をもって、さらに詳しく説明
する。
Hereinafter, the method of the present invention will be explained in more detail with reference to Examples.

対象とする金属素材として、チタン(Ti)とチタンア
ルミ(TiAυを採択し、また反応ガスとして窒素およ
びアセチレンガスを使用する一方、電源としては直流・
高周波電源を用いた。即ち、反応ガス圧とバイアス電圧
により成膜速度を、約0.01−0.02μ/分にコン
トロールし、10− ” 〜5 X 10− ”tab
arの真空下で約20〜30分間イオンブレーティング
を行い、前記各金属素材の表面に厚さ0.3〜0.5μ
のTiC,T1CN、TiALN、TiALCN、およ
び硬質カーボンを被膜させたところ、当該硬質化合物の
被膜はブラウン、グレー、ないし黒色といった色彩を呈
した。
Titanium (Ti) and titanium aluminum (TiAυ) were selected as the target metal materials, and nitrogen and acetylene gas were used as the reaction gases, while direct current and
A high frequency power source was used. That is, the film formation rate was controlled to about 0.01-0.02 μ/min by the reaction gas pressure and bias voltage, and
Ion blating was performed for about 20 to 30 minutes under an AR vacuum, and a thickness of 0.3 to 0.5μ was applied to the surface of each metal material.
When TiC, T1CN, TiALN, TiALCN, and hard carbon were coated, the hard compound coat exhibited a brown, gray, or black color.

次に、か−る硬質化合物被膜が施された上記金属素材を
、そのま−大気に曝すことなく、上記の反応ガス圧、カ
ソードバイアス電圧により成膜速度を約0.04μ7分
にコントロールし、lo−3〜5×IO−ttrbar の真空下で、それぞれ金または金合金(18金)を厚さ
0.2μにスパッタ形成させ、ついで、を機器マスキン
グ剤で一定のパターンのマスキングを施した後、シアン
系電解剥離液により金色メツキ層を電解剥離し、さらに
有機溶剤を用いてマスキングを除去した。
Next, without exposing the metal material coated with the hard compound film to the atmosphere, the film formation rate was controlled to about 0.04μ7 minutes using the reaction gas pressure and cathode bias voltage. Gold or gold alloy (18K) was sputter-formed to a thickness of 0.2μ under a vacuum of lo-3 to 5×IO-ttrbar, and then masked in a certain pattern with an equipment masking agent. The gold plating layer was electrolytically stripped using a cyan-based electrolytic stripping solution, and the masking was further removed using an organic solvent.

しかるところ、上記各金属素材の表面には、ブラウン、
グレー、黒色の硬質化合物被膜と金色メツキ層とか程良
(調和したコントラストをもって美しいデザインが現出
された。なお、上記電解液および有機溶剤中に分離され
た金(金合金)は別途回収した。
However, the surface of each of the metal materials mentioned above has brown,
A beautiful design appeared with a harmonious contrast between the gray and black hard compound coating and the gold plating layer.The gold (gold alloy) separated in the electrolyte and organic solvent was collected separately.

〔本発明の効果〕[Effects of the present invention]

以上実施例をもって説明したとおり、本発明によれば、
マスキング機器の発達した今日、対象とする金属素材の
形状に制約されることなく如何に精緻な態様の多色調装
飾パターンでも表現可能であるうえに、従来方法のよう
に金属表面全体に高価な装飾金R(例えば、金・金合金
)被膜を施さなくても済むので非常に経済的であるのに
加え、工程は頗る簡素であるので能率的に処理すること
ができるほか、仕上った製品は良質で、しかも安価に加
工できるのであり、その実用上のメリットは頗る大きい
As explained above using the embodiments, according to the present invention,
Nowadays, with the development of masking equipment, it is possible to express any elaborate multi-colored decorative pattern without being restricted by the shape of the target metal material. It is very economical because it does not require a gold R (e.g., gold/gold alloy) coating, and the process is very simple, so it can be processed efficiently, and the finished product is of high quality. Moreover, it can be processed at low cost, and its practical advantages are extremely large.

Claims (1)

【特許請求の範囲】[Claims] 金属素材の表面に硬質化合物被膜を施し、施された前記
被膜層の上に装飾金属を層着せしめた後、この装飾金属
層の上に所要パターンのマスキングを施し、ついで、こ
れを剥離液中で溶解して非マスキング部分の装飾金属層
を剥離し、然る後、前記マスキング層を除去することに
よって、硬質被膜層と装飾金属層とによる装飾模様を現
出せしめることを特徴とした表面化粧処理方法。
After applying a hard compound coating to the surface of the metal material and depositing a decorative metal layer on the applied coating layer, masking in a desired pattern is applied to the decorative metal layer, and then this is placed in a stripping solution. A surface decoration characterized in that a decorative pattern formed by a hard coating layer and a decorative metal layer is revealed by dissolving the decorative metal layer in the non-masking part and then removing the masking layer. Processing method.
JP88258868A 1988-10-17 1988-10-13 Surface decoration treatment Pending JPH02104680A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP88258868A JPH02104680A (en) 1988-10-17 1988-10-13 Surface decoration treatment
DE3928312A DE3928312C2 (en) 1988-10-17 1989-08-26 Sails and process for their manufacture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP88258868A JPH02104680A (en) 1988-10-17 1988-10-13 Surface decoration treatment

Publications (1)

Publication Number Publication Date
JPH02104680A true JPH02104680A (en) 1990-04-17

Family

ID=17326152

Family Applications (1)

Application Number Title Priority Date Filing Date
JP88258868A Pending JPH02104680A (en) 1988-10-17 1988-10-13 Surface decoration treatment

Country Status (2)

Country Link
JP (1) JPH02104680A (en)
DE (1) DE3928312C2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5097783A (en) * 1988-10-17 1992-03-24 Dimension Polyant Sailcloth, Inc. Reinforced sailcloth
FR2694947B1 (en) * 1992-08-20 1994-08-12 Rossignol Pascal A method of making a sail for any machine or device with lift and / or with vélique propulsion.
EP1114771A1 (en) * 1999-12-02 2001-07-11 Rox Sails (Ireland) Limited Composite material, particularly for sails and the like
DE10006100B4 (en) * 2000-02-11 2005-12-29 Andreas Hermann sail
ITVR20060132A1 (en) * 2006-08-07 2008-02-08 Umberto Righi EQUIPMENT FOR APPLYING REINFORCEMENT ELEMENTS TO A SAIL
DE102009019807A1 (en) 2009-05-02 2010-11-04 Dimension-Polyant Gmbh sailcloth
DE102013015669A1 (en) 2013-09-23 2015-03-26 Dimension-Polyant Gmbh Non-woven fabric canvas

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2320432A1 (en) * 1973-04-21 1974-11-07 Ballonfab See Luftausr Gmbh Air-proof, flexible 3-ply laminate - comprising two textile outer layers and plastics or rubber inter layer
JPS52121576A (en) * 1976-04-05 1977-10-13 Kobunshi Kako Kenkyusho Manufacture of wideewidth web warp filling laminated cloth
FI801415A (en) * 1979-05-05 1980-11-06 Arthur Britton ARKMATERIAL
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US4444822A (en) * 1983-03-21 1984-04-24 Howe & Bainbridge Sailcloth
US4679519A (en) * 1984-11-26 1987-07-14 Linville James C Laminated cloth construction
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US4624205A (en) * 1984-12-14 1986-11-25 Sobstad Sailmakers, Inc. Method of stress distribution in a sail, a sail embodying the same and sail construction
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Also Published As

Publication number Publication date
DE3928312C2 (en) 2002-08-14
DE3928312A1 (en) 1990-04-19

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