JPH0196383A - Method for plating transparent conductive film pattern - Google Patents

Method for plating transparent conductive film pattern

Info

Publication number
JPH0196383A
JPH0196383A JP25315887A JP25315887A JPH0196383A JP H0196383 A JPH0196383 A JP H0196383A JP 25315887 A JP25315887 A JP 25315887A JP 25315887 A JP25315887 A JP 25315887A JP H0196383 A JPH0196383 A JP H0196383A
Authority
JP
Japan
Prior art keywords
substrate
transparent conductive
conductive film
plating
transparent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP25315887A
Other languages
Japanese (ja)
Inventor
Teruo Suzuki
輝夫 鈴木
Hiroshi Takashio
高塩 博
Seiji Yahagi
矢作 誠治
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Seiko Instruments Inc
Original Assignee
Seiko Instruments Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Seiko Instruments Inc filed Critical Seiko Instruments Inc
Priority to JP25315887A priority Critical patent/JPH0196383A/en
Publication of JPH0196383A publication Critical patent/JPH0196383A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1603Process or apparatus coating on selected surface areas
    • C23C18/1605Process or apparatus coating on selected surface areas by masking
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1646Characteristics of the product obtained
    • C23C18/165Multilayered product
    • C23C18/1653Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18Pretreatment of the material to be coated
    • C23C18/1851Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material
    • C23C18/1872Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material by chemical pretreatment
    • C23C18/1875Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material by chemical pretreatment only one step pretreatment
    • C23C18/1879Use of metal, e.g. activation, sensitisation with noble metals
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18Pretreatment of the material to be coated
    • C23C18/1851Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material
    • C23C18/1896Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material by electrochemical pretreatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Liquid Crystal (AREA)
  • Chemically Coating (AREA)
  • Manufacturing Of Electric Cables (AREA)

Abstract

PURPOSE:To selectively form and electroless plating film without damaging a substrate by electrolytically depositing Pd on the specified part of the transparent conductive film pattern on the transparent insulating substrate, and applying electroless plating. CONSTITUTION:The upper surface of the transparent insulating substrate 1 (glass substrate) is patterned with a transparent conductive film 2 (ITO film), and the part not to be metallized is masked with a masking agent 4. The substrate 1 is then degreased, pickled, and then washed with water, and Pd is electrolytically deposited on the substrate 1 in the active soln. consisting essentially of palladium chloride. The substrate is further washed with water and electroless-plated to selectively form a coating film, the terminal 5 is cut off, the masking agent 4 is removed, and the substrate is heat-treated. As a result, an excellent plating film is formed on the specified part of the transparent electrode pattern, and the substrate 1 is not damaged.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、液晶パネルなど透明な無機ガラス、有機フィ
ルム上に形成される透明導電膜パターン上へ選択的にめ
っきを施す方法に関するものである。
[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a method for selectively plating a transparent conductive film pattern formed on a transparent inorganic glass or organic film such as a liquid crystal panel. .

〔発明の概要〕[Summary of the invention]

透明導電膜パターン上の所定部分をパラジウムを含む活
性液で陽極電解しパラジウムイオンを析出させた後、無
電解めっきを行うことにより、所望とする透明導電膜パ
ターン上へ選択的にめっきを形成する方法を提供するも
のである。
A predetermined portion of the transparent conductive film pattern is anodically electrolyzed with an active solution containing palladium to deposit palladium ions, and then electroless plating is performed to selectively form plating on the desired transparent conductive film pattern. The present invention provides a method.

〔従来の技術〕[Conventional technology]

液晶パネルにおいては、大型化、高密度化に伴い高信頼
性実装法として、端子部のメタライズがなされている。
In liquid crystal panels, metallization of terminal portions is being used as a highly reliable mounting method as the size and density of liquid crystal panels increases.

従来液晶パネル基板としては、ソーダガラス、硬質ガラ
スなどの無機材料、ポリエステル、ポリエーテルサルフ
ォン樹脂等の有機材料がある。このような基板上に酸化
スズ又は、ITOなどの透明導電膜は、スパッタ、蒸着
、CVD法などより形成された後、フォトリソグラフィ
ーにより所定のパターンにエツチングされる0次に透明
導電膜上にメタライズする方法としては、蒸着、スパッ
タなどのドライめっき法と、ウェットめっき法がある。
Conventional liquid crystal panel substrates include inorganic materials such as soda glass and hard glass, and organic materials such as polyester and polyether sulfone resin. A transparent conductive film such as tin oxide or ITO is formed on such a substrate by sputtering, vapor deposition, CVD, etc., and then metalized on the zero-order transparent conductive film that is etched into a predetermined pattern by photolithography. Methods for this include dry plating methods such as vapor deposition and sputtering, and wet plating methods.

しかし、ドライめっき法は、装置が高価なものとなり、
またバッチ処理のため量産性に欠けるなどの問題がある
。一般的には処理コストが安価で自由形状のものにメタ
ライズ可能なウェットめワき法がとられている。ガラス
基板上に形成された透明導電股上のウェットめっきは、
めっき性。
However, dry plating requires expensive equipment and
In addition, there are problems such as a lack of mass productivity due to batch processing. In general, a wet finishing method is used, which has low processing costs and allows metallization into free-form shapes. The wet plating on the transparent conductive crotch formed on the glass substrate is
Plating properties.

密着性などの点で優れている無電解めっきが採用されて
いる。これらの無電解めっき法は、被めっき物を樹脂、
酸洗い後、塩化スズ、塩化パラジウムを含む触媒付与液
に浸漬しその後、フン化物を含む活性液へ浸漬する。こ
の活性液の浸漬は、ガラス基板および透明導電膜上に付
着した触媒(パラジウム)を活性化させる他、ガラス基
板に付着した触媒をNWdさせるものである。その後、
無電解ニッケルめっき、無電解銅めっきを施すことによ
り透明導電股上のみに選択的にめっきがなされるもので
あった。
Electroless plating is used because it has excellent adhesion. In these electroless plating methods, the object to be plated is resin,
After pickling, it is immersed in a catalyst-imparting solution containing tin chloride and palladium chloride, and then in an activation solution containing fluoride. This immersion in the active liquid activates the catalyst (palladium) attached to the glass substrate and the transparent conductive film, and also causes the catalyst attached to the glass substrate to become NWd. after that,
By applying electroless nickel plating and electroless copper plating, only the transparent conductive crotch was selectively plated.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

しかし、これら一連の工程の中で、選択性を出す活性液
は、フン化物が含有されているためガラス基板を浸す問
題があった。また、耐薬品性のある硬質ガラス基板では
、ガラス面にもめっきが析出してしまうなど選択性の点
で問題があった0本発明は、これら問題点を解決するた
めに行われたものである。
However, in this series of steps, the active liquid that provides selectivity contains fluoride, which has the problem of immersing the glass substrate. In addition, with chemical-resistant hard glass substrates, there were problems with selectivity, such as plating depositing on the glass surface.The present invention was made to solve these problems. be.

〔問題点を解決するための手段〕[Means for solving problems]

本発明は、上記問題点を解決するため、透明導電膜パタ
ーンの所定部分を塩化パラジウムを含む活性液中で陽極
添加電解を行い、活性液中のパラジウムイオンを透明導
電膜(酸化スズ、ITOなど)上にパラジウムを完全に
析出させた後、無電解めっきを行うことにより、ガラス
基板をいためずかつ、選択性良好な透明導電膜上へのめ
っきを形成する方法を見出したものである。
In order to solve the above-mentioned problems, the present invention performs anodic electrolysis on a predetermined portion of a transparent conductive film pattern in an active solution containing palladium chloride, and transfers palladium ions in the active solution to a transparent conductive film (such as tin oxide, ITO, etc.). ) We have discovered a method for forming plating on a transparent conductive film with good selectivity without damaging the glass substrate by performing electroless plating after completely depositing palladium on the glass substrate.

〔実施例〕〔Example〕

以下、本発明の実施について第1図をもとに説明する。 Hereinafter, implementation of the present invention will be explained based on FIG.

第1図は、液晶パネルの外部端子部分の斜視図である。FIG. 1 is a perspective view of an external terminal portion of a liquid crystal panel.

1は硬質ガラス基板、2は硬質ガラス上に蒸着法で形成
された複数のITO透明電極膜、3は半田付は接合する
ためのメタライズ端子部分、4はめっき析出防止のため
のマスキング剤、5は透明電極端子間を短絡させるため
のITO透明導電膜である。
1 is a hard glass substrate, 2 is a plurality of ITO transparent electrode films formed by vapor deposition on hard glass, 3 is a metallized terminal part for soldering, 4 is a masking agent for preventing plating precipitation, 5 is an ITO transparent conductive film for short-circuiting between transparent electrode terminals.

まず、ガラス基板l上に透明導電膜2をパターニングし
、メタライズ不要部分をマスキング剤4によりマスクし
、次いでこれらを脱脂、酸洗いし水洗後、塩化パラジウ
ムを主成分とする活性液(カニゼン社製レソドシューマ
)中で透明電極を陽極に電解処理した。
First, a transparent conductive film 2 is patterned on a glass substrate 1, and parts that do not require metallization are masked with a masking agent 4, and then these are degreased, pickled, and washed with water. The transparent electrode was electrolytically treated as an anode in a resodosummer.

〔処理条件〕[Processing conditions]

電解電圧    1.5〜3■ 温   度     室温 時   間      1〜3分 陰  極    カーボン 次に水洗後、無電解ニッケルめっき(カニゼン社製品S
−680)50℃、7分間のめっきして約0.5ミクロ
ンのNi −P被膜を透明電極上に選択的に形成した。
Electrolytic voltage: 1.5 to 3 ■ Temperature: Room temperature time: 1 to 3 minutes Cathode electrode Carbon, then washed with water, electroless nickel plating (Kanigen product S
-680) A Ni-P film of about 0.5 micron was selectively formed on the transparent electrode by plating at 50° C. for 7 minutes.

その後、透明電極間を繋ぐ端子5を切断し、マスキング
剤を除去した後、250℃、30分の熱処理を行った。
Thereafter, the terminal 5 connecting the transparent electrodes was cut, the masking agent was removed, and then heat treatment was performed at 250° C. for 30 minutes.

このようにして得られた無電解めっきは、透明電極パタ
ーンの所定部分に良好なめっき被膜を形成し、また、ガ
ラス基板の損傷も全く見られなかった。
The electroless plating thus obtained formed a good plating film on a predetermined portion of the transparent electrode pattern, and no damage to the glass substrate was observed.

本発明の実施例では、透明絶縁基板に硬質ガラスを用い
たが、ソーダガラス、石英ガラス9.などの無機材料、
また、ポリエステルなどの有機フィルムであっても同様
な効果を得ることが可能である。
In the embodiment of the present invention, hard glass was used for the transparent insulating substrate, but soda glass, quartz glass, etc. Inorganic materials such as
Further, the same effect can be obtained even with an organic film such as polyester.

〔発明の効果〕〔Effect of the invention〕

以上詳述したように、本発明によれば、所望とする透明
R電膜パターン上のメタライズをする場合、透明R電膜
パターン部分を塩化パラジウムを含む活性液中で陽極電
解処理を行いパラジウムを付着させた後無電解めっきを
施すことにより、処理によるガラス基板に損傷を与える
ことなく、選択的な無電解めっき被膜を形成することが
でき、信軌性の高い液晶パネルなどの実装を可能とした
ものでその効果は大きい。
As detailed above, according to the present invention, when metallizing a desired transparent R electrical film pattern, the transparent R electrical film pattern is subjected to anodic electrolysis treatment in an active solution containing palladium chloride to remove palladium. By applying electroless plating after adhesion, a selective electroless plating film can be formed without damaging the glass substrate during processing, making it possible to mount high-fidelity liquid crystal panels, etc. The effect is great.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は液晶パネル外部端子部の斜視図である。 l・・・ガラス基板(透明絶縁基板) 2・・・透明電極(ITO膜) 3・・・透明電極メタライズ必要部分 4・・・マスキング剤 5・・・透明電極間を結ぶ端子(ITO膜)以上 出願人 セイコー電子工業株式会社 81図 FIG. 1 is a perspective view of the external terminal section of the liquid crystal panel. l...Glass substrate (transparent insulating substrate) 2...Transparent electrode (ITO film) 3... Part where transparent electrode metallization is required 4... Masking agent 5... Terminal (ITO film) connecting between transparent electrodes or more Applicant: Seiko Electronics Industries Co., Ltd. Figure 81

Claims (1)

【特許請求の範囲】[Claims] 透明絶縁基板上に形成される透明導電膜パターンの所定
部分を、パラジウムを含む活性液中で電解処理を行いパ
ラジウムを付着させた後、無電解めっき液を施すことを
特徴とする透明導電膜パターン上へのめっき方法。
A transparent conductive film pattern formed on a transparent insulating substrate, wherein a predetermined portion of the transparent conductive film pattern is electrolytically treated in an active solution containing palladium to adhere palladium, and then an electroless plating solution is applied. Top plating method.
JP25315887A 1987-10-07 1987-10-07 Method for plating transparent conductive film pattern Pending JPH0196383A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP25315887A JPH0196383A (en) 1987-10-07 1987-10-07 Method for plating transparent conductive film pattern

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP25315887A JPH0196383A (en) 1987-10-07 1987-10-07 Method for plating transparent conductive film pattern

Publications (1)

Publication Number Publication Date
JPH0196383A true JPH0196383A (en) 1989-04-14

Family

ID=17247338

Family Applications (1)

Application Number Title Priority Date Filing Date
JP25315887A Pending JPH0196383A (en) 1987-10-07 1987-10-07 Method for plating transparent conductive film pattern

Country Status (1)

Country Link
JP (1) JPH0196383A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6720211B2 (en) 1999-05-18 2004-04-13 Sharp Kabushiki Kaisha Method for fabricating electric interconnections and interconnection substrate having electric interconnections fabricated by the same method

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58119111A (en) * 1981-12-31 1983-07-15 エヌ ベー フイリップス フルーイランペンフアブリケン Method of metallizing partly electrically conductive nonmetallic pattern
JPS62134990A (en) * 1985-12-06 1987-06-18 シチズン時計株式会社 Surface treatment of circuit substrate

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58119111A (en) * 1981-12-31 1983-07-15 エヌ ベー フイリップス フルーイランペンフアブリケン Method of metallizing partly electrically conductive nonmetallic pattern
JPS62134990A (en) * 1985-12-06 1987-06-18 シチズン時計株式会社 Surface treatment of circuit substrate

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6720211B2 (en) 1999-05-18 2004-04-13 Sharp Kabushiki Kaisha Method for fabricating electric interconnections and interconnection substrate having electric interconnections fabricated by the same method
US6750475B1 (en) 1999-05-18 2004-06-15 Sharp Kabushiki Kaisha Method for fabricating electric interconnections and interconnection substrate having electric interconnections fabricated by the same method

Similar Documents

Publication Publication Date Title
US4633035A (en) Microwave circuit boards
US4913784A (en) Process for metallizing a ceramic substrate
US4144118A (en) Method of providing printed circuits
EP0114943B1 (en) Process of plating on anodized aluminium substrates
EP0083458B1 (en) Method of partially metallising electrically conductive non-metallic patterns
JP3093219B2 (en) Nickel electroless plating method
EP0079356B1 (en) A method for chemically stripping platings including palladium and at least one of the metals copper and nickel and a bath intended to be used for the method
GB2112023A (en) Pretreating ceramics for metal coating
US5368717A (en) Metallization of electronic insulators
JPH05271986A (en) Aluminum-organic polymer laminate
IE50821B1 (en) Process for the selective chemical deposition and/or electrodeposition of metal coatings,especially for the production of printed circuits
US4525247A (en) Microwave circuit boards and method of manufacture thereof
JPH0196383A (en) Method for plating transparent conductive film pattern
JPH0196384A (en) Method for plating transparent conductive film pattern
JPH06260759A (en) Manufacture of printed circuit board
CA1055882A (en) Process for the electrolytic recovery of gallium and/or alkali metals
US6003225A (en) Fabrication of aluminum-backed printed wiring boards with plated holes therein
US3205155A (en) Method of fabricating thin film resistive elements
JPH01294311A (en) Plating method for transparent conductive membrane pattern
US4980197A (en) Method of producing metallic structures on inorganic non-conductors
US4882233A (en) Selectively deposited electrodes onto a substrate
JP2002302778A (en) Method of forming electroconductive part on anodic- oxidized film of aluminum alloy
SU367746A1 (en) Contact-chemical method for metal deposition
JPH0382187A (en) Manufacture of high corrosion-resistant printed wiring board
CN106242314A (en) A kind of glass copper-plating technique