JPH0140657B2 - - Google Patents

Info

Publication number
JPH0140657B2
JPH0140657B2 JP56025589A JP2558981A JPH0140657B2 JP H0140657 B2 JPH0140657 B2 JP H0140657B2 JP 56025589 A JP56025589 A JP 56025589A JP 2558981 A JP2558981 A JP 2558981A JP H0140657 B2 JPH0140657 B2 JP H0140657B2
Authority
JP
Japan
Prior art keywords
zeolite
zsm
weight
toluene
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP56025589A
Other languages
English (en)
Japanese (ja)
Other versions
JPS5710337A (en
Inventor
Chiun Chuu Chin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of JPS5710337A publication Critical patent/JPS5710337A/ja
Publication of JPH0140657B2 publication Critical patent/JPH0140657B2/ja
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2558981A 1980-05-23 1981-02-25 Catalyst composition containing periodic law table 3 b group metal denatured crystalline zeolite and organic compound inverting method using said composition Granted JPS5710337A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/152,939 US4276437A (en) 1980-05-23 1980-05-23 Shape selective reactions involving zeolite catalyst modified with group IIIB metal

Publications (2)

Publication Number Publication Date
JPS5710337A JPS5710337A (en) 1982-01-19
JPH0140657B2 true JPH0140657B2 (en, 2012) 1989-08-30

Family

ID=22545093

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2558981A Granted JPS5710337A (en) 1980-05-23 1981-02-25 Catalyst composition containing periodic law table 3 b group metal denatured crystalline zeolite and organic compound inverting method using said composition

Country Status (8)

Country Link
US (1) US4276437A (en, 2012)
EP (1) EP0040900B1 (en, 2012)
JP (1) JPS5710337A (en, 2012)
AU (1) AU544380B2 (en, 2012)
CA (1) CA1153746A (en, 2012)
DE (1) DE3168843D1 (en, 2012)
NZ (1) NZ196842A (en, 2012)
ZA (1) ZA812917B (en, 2012)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4302621A (en) * 1980-10-29 1981-11-24 Mobil Oil Corporation Shape selective reactions utilizing zeolites modified with Group V A metals
US4302620A (en) * 1980-10-29 1981-11-24 Mobil Oil Corporation Reactions involving zeolite catalysts modified with group IV A metals
US4302622A (en) * 1980-12-02 1981-11-24 Mobil Oil Corporation Shape selective reactions utilizing group III a metal-modified zeolite catalyst
US4460698A (en) * 1981-11-13 1984-07-17 Standard Oil Company (Indiana) Hydrocarbon conversion catalyst
US4686312A (en) * 1981-12-23 1987-08-11 Mobil Oil Corporation Aromatics production
US4491678A (en) * 1982-10-19 1985-01-01 Idemitsu Kosan Company Limited Process for the production of para-xylene
GB8306532D0 (en) * 1983-03-09 1983-04-13 British Petroleum Co Plc Catalytic activity of aluminosilicate zeolites
FI76005C (fi) * 1983-10-17 1988-09-09 Neste Oy Aluminium-bor-silikatkatalysator, foerfarande foer framstaellning av denna och alkyleringsprocess.
CA1251436A (en) * 1985-01-02 1989-03-21 Clarence D. Chang Preparation of gallosilicate zeolites
US4968650A (en) * 1985-09-17 1990-11-06 Mobil Oil Corporation ZSM-5 catalysts having predominantly framework gallium, methods of their preparation, and use thereof
US4636483A (en) * 1985-12-09 1987-01-13 Uop Inc. Phosphorus containing alumina catalyst for the production of aromatics
JPH02500434A (ja) * 1986-08-22 1990-02-15 リサーチ　コーポレーション　リミテッド ゼオライトの改良
GB9008038D0 (en) * 1990-04-09 1990-06-06 Univ Manchester Gallium zeolites
US6486373B1 (en) 1996-11-05 2002-11-26 Mobil Oil Corporation Shape selective zeolite catalyst and its use in aromatic compound conversion
US6008423A (en) * 1997-12-08 1999-12-28 Uop Llc Selective aromatics disproportionation/transalkylation
US6383967B1 (en) 1997-12-08 2002-05-07 Uop Llc Selective aromatics disproportionation/transalkylation catalyst
US6079408A (en) * 1998-03-30 2000-06-27 Honda Giken Kogyo Kabushiki Kaisha Sun-ray tracking system
EP1063013B1 (en) 1999-06-24 2005-10-12 ENI S.p.A. Catalytic composition for the aromatization of hydrocarbons
US7368619B1 (en) 2004-06-15 2008-05-06 Uop Llc Process for the production of diesel and aromatic compounds
CN100368362C (zh) * 2004-07-12 2008-02-13 中国石油化工股份有限公司 制备对二异丙苯的方法
US7154014B1 (en) * 2004-09-22 2006-12-26 Uop Llc Alumina guard bed for aromatics transalkylation process
US7271303B1 (en) 2004-09-22 2007-09-18 Uop Llc Multi-zone process for the production of diesel and aromatic compounds
US9193642B2 (en) 2013-06-20 2015-11-24 Uop Llc Process for production of dialkylbenzenes
WO2017109640A1 (en) 2015-12-22 2017-06-29 Sabic Global Technologies B.V. Methods for producing ethylene and propylene from naphtha

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3716596A (en) * 1968-04-18 1973-02-13 Mobil Oil Corp Alkylation and dealkylation of aromatics in the presence of crystalline aluminosilicates
CA1006495A (en) * 1972-01-05 1977-03-08 Julius Scherzer Exchanged faujasite
US4002697A (en) * 1973-12-03 1977-01-11 Mobil Oil Corporation Selective production of para-xylene
US3965208A (en) * 1975-01-06 1976-06-22 Mobil Oil Corporation Methylation of toluene
US3972832A (en) * 1974-09-23 1976-08-03 Mobil Oil Corporation Phosphorus-containing zeolite catalyst
US4046826A (en) * 1974-12-06 1977-09-06 N L Industries, Inc. Process for alkylating aromatic hydrocarbons with synthetic hectorite-type clay catalyst
US3979472A (en) * 1975-03-28 1976-09-07 Mobil Oil Corporation Process for manufacturing hydrocarbons
US4052476A (en) * 1975-04-24 1977-10-04 Mobil Oil Corporation Toluene disproportionation over zeolite catalyst
US4034053A (en) * 1975-12-08 1977-07-05 Mobil Oil Corporation Selective production of para-xylene
US4029716A (en) * 1975-12-08 1977-06-14 Mobil Oil Corporation Selective production of para-xylene
US4117026A (en) * 1976-05-12 1978-09-26 Mobil Oil Corporation Selective production of para dialkyl substituted benzenes
US4137195A (en) * 1976-10-21 1979-01-30 Mobil Oil Corporation Catalyst for disproportionation of toluene
US4107195A (en) * 1977-04-22 1978-08-15 Mobil Oil Corporation Preparation of zeolite ZSM-35
US4139600A (en) * 1977-04-22 1979-02-13 Mobil Oil Corporation Synthesis of zeolite ZSM-5
US4101597A (en) * 1977-06-23 1978-07-18 Mobil Oil Corporation Recovery of p-xylene and benzene from eight carbon atom aromatic fractions
US4128592A (en) * 1977-11-23 1978-12-05 Mobil Oil Corporation Selective production of para dialkyl benzene
GB2033358B (en) * 1978-11-06 1983-03-02 Mobil Oil Corp Crystalline zeolite composition

Also Published As

Publication number Publication date
US4276437A (en) 1981-06-30
AU544380B2 (en) 1985-05-23
AU6977181A (en) 1981-11-26
ZA812917B (en) 1982-12-29
EP0040900A1 (en) 1981-12-02
JPS5710337A (en) 1982-01-19
EP0040900B1 (en) 1985-02-13
NZ196842A (en) 1984-05-31
DE3168843D1 (en) 1985-03-28
CA1153746A (en) 1983-09-13

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