JPH0138557B2 - - Google Patents

Info

Publication number
JPH0138557B2
JPH0138557B2 JP8276282A JP8276282A JPH0138557B2 JP H0138557 B2 JPH0138557 B2 JP H0138557B2 JP 8276282 A JP8276282 A JP 8276282A JP 8276282 A JP8276282 A JP 8276282A JP H0138557 B2 JPH0138557 B2 JP H0138557B2
Authority
JP
Japan
Prior art keywords
tank
water
biofilm
ultra
wastewater
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP8276282A
Other languages
Japanese (ja)
Other versions
JPS58199094A (en
Inventor
Kozo Kimura
Norimasa Nonaka
Nariaki Takeda
Tomio Baba
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DIC Corp
Takenaka Komuten Co Ltd
Original Assignee
Takenaka Komuten Co Ltd
Dainippon Ink and Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Takenaka Komuten Co Ltd, Dainippon Ink and Chemicals Co Ltd filed Critical Takenaka Komuten Co Ltd
Priority to JP57082762A priority Critical patent/JPS58199094A/en
Publication of JPS58199094A publication Critical patent/JPS58199094A/en
Publication of JPH0138557B2 publication Critical patent/JPH0138557B2/ja
Granted legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Biological Treatment Of Waste Water (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Description

【発明の詳細な説明】 本発明はビル等の中水道施設に最適な廃水処理
装置に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a wastewater treatment device most suitable for gray water facilities such as buildings.

大規模オフイスビルやホテル、住宅団地等から
出る廃水を処理し、中水として便所洗浄用水、冷
却水、雑用水(散水用水、洗車用水)等に再利用
する廃水処理装置が各種提案されている。
Various wastewater treatment systems have been proposed that treat wastewater from large-scale office buildings, hotels, residential complexes, etc., and reuse it as gray water for toilet flushing, cooling water, miscellaneous water (sprinkling water, car washing water), etc. .

この中水道施設に用いられる代表的な廃水処理
装置として、第1図に示される装置がある。この
装置では原水を調整槽10、曝気槽12及び沈殿
槽14で活性汚泥法により生物化学的に浄化した
後に、ポンプ槽16から砂過槽18、逆洗水槽
20、活性炭吸着塔22、消毒器24で3次処理
するようになつている。
A typical wastewater treatment device used in this gray water facility is the device shown in FIG. 1. In this device, after raw water is biochemically purified by the activated sludge method in an adjustment tank 10, an aeration tank 12, and a settling tank 14, it is transferred from a pump tank 16 to a sand filter tank 18, a backwash water tank 20, an activated carbon adsorption tower 22, and a sterilizer. 24, tertiary processing is performed.

しかしこの処理装置は活性汚泥の運転管理が煩
雑であるため取扱に熟練を要し、また活性汚泥と
処理水の分離のために大型の沈殿槽が必要となつ
て大きな設置スペースを占め、この結果設備費、
運転費が高くなる不具合がありビル内の中水道施
設には不向である。
However, this treatment equipment requires skill to handle because the operation management of activated sludge is complicated, and a large sedimentation tank is required to separate activated sludge and treated water, which occupies a large installation space. equipment costs,
It is unsuitable for gray water facilities inside buildings because of the problem of high operating costs.

またこの他の処理装置として、活性汚泥法と物
理処理法である過法を単一の曝気過装置内で
行う処理装置及び、マイクロスクリーンと限外
過方式を組合わせた処理装置も提案されている
が、前者は曝気槽と過槽を上下に組合わせてい
るので設置場所の有効高さが少くとも4.5m以上
となり、また水逆洗、空気洗浄のために自動弁が
多く故障発生頻度を小さくするための管理が煩雑
である。さらに後者は処理水中の溶解有機物の残
存濃度が高く、生物化学的処理装置又は活性炭吸
着装置との組合せが必要でコストアツプの原因と
なる。
In addition, as other treatment equipment, a treatment equipment that performs an activated sludge method and a filtration method, which is a physical treatment method, in a single aeration filtration equipment, and a treatment equipment that combines a micro screen and an ultrafiltration method have also been proposed. However, the former combines an aeration tank and an overtank above and below, so the effective height of the installation location is at least 4.5 m or more, and there are many automatic valves for water backwashing and air cleaning, reducing the frequency of failures. Management to reduce the size is complicated. Furthermore, the latter method has a high residual concentration of dissolved organic matter in the treated water, and requires combination with a biochemical treatment device or an activated carbon adsorption device, resulting in increased costs.

本発明は上記従来技術に鑑み、設置スペースが
小さく、運転管理が容易で設備費、運転費が低廉
でかつ高品位水質を得ることができる中水道用廃
水処理装置を提供することが目的である。
In view of the above-mentioned prior art, it is an object of the present invention to provide a wastewater treatment device for medium-sized water supplies that requires a small installation space, is easy to operate and manage, has low equipment costs and operating costs, and can obtain high quality water. .

本発明に係る廃水処理装置は、回転円板床、
水没形固定生物膜床、散水床、流動生物
床、などの生物膜床を利用して、生物化学的に
廃水を浄化することにより汚泥の発生量、即ちこ
の場合この工程での処理水中のSS(浮遊物)濃度
を低くすることができ、外圧形多孔質材中空状
チユーブないしは繊維状精密過装置を併せ用い
ることにより、通常生物処理法に必要とされる沈
でん槽を不要となし、かつ循環過(部分過)
を不要とし、低エネルギで全量過を可能として
いる。
The wastewater treatment device according to the present invention includes a rotating disk bed,
By biochemically purifying wastewater using biofilm beds such as submerged fixed biofilm beds, sprinkled beds, and fluidized biofilm beds, the amount of sludge generated, that is, the SS in the treated water in this process. (Suspended matter) concentration can be lowered, and by using an external pressure type porous material hollow tube or fibrous precision filtration device, the sedimentation tank normally required for biological treatment methods is not required, and the circulation Over (partial over)
This eliminates the need for overflow, making it possible to evaporate the entire amount with low energy.

上記の様に工程の簡素化により、設置面積を低
減しかつ運転管理を容易にしている。また生物膜
床を利用しているため生物化学的に高次処理が
可能で、BOD(生物化学的必要酸素量)、COD(化
学的必要酸素量)の高次処理の他NH4 +−N(ア
ンモニア性窒素)のNO3 -−N(硝酸性窒素)へ
転化も容易であり、超精密過を利用することに
より極微細な懸濁物の除去が可能となり良質の処
理水が得られる。通常大腸菌群、その他病源菌、
一般細菌の除菌が十分達成でき、また超精密過
の多孔質材の孔径を十分小さくすることにより
ウイルスの除去も可能となる。従つて上記の様に
工程の簡素化によるメリツトを計りながら、上記
の様な水質の良化を計ることが出来るため処理水
の利用目的の範囲を高めることが本発明の特徴で
ある。
By simplifying the process as described above, the installation area is reduced and operation management is facilitated. In addition, since a biofilm bed is used, high-level biochemical treatment is possible, and in addition to high-level treatment of BOD (biochemical oxygen requirement) and COD (chemical oxygen requirement), NH 4 + -N It is easy to convert (ammoniac nitrogen) to NO 3 - -N (nitrate nitrogen), and by using ultra-precision filtration, it is possible to remove extremely fine suspended matter and obtain high-quality treated water. Usually coliform bacteria, other pathogenic bacteria,
It is possible to sufficiently eliminate general bacteria, and by making the pore diameter of the ultra-precise porous material sufficiently small, it is also possible to remove viruses. Therefore, a feature of the present invention is that it is possible to improve the water quality as described above while taking advantage of the simplification of the process as described above, thereby increasing the range of purposes for which treated water can be used.

また生物膜床の特徴である余剰汚泥生成量の
少いことが保持されており、このことはビル等の
中水設備としては極めて有益である。
In addition, the small amount of excess sludge produced, which is a characteristic of biofilm beds, is maintained, which is extremely useful for gray water facilities such as buildings.

本発明で超精密過の方式として外圧形中空状
チユーブ群ないしは中空状繊維群を用いているの
は、生物膜床槽より流出する処理水中の浮遊物
の粒径は極めて大きいものを含むため、内圧形で
はチユーブないしは繊維内で閉ソクが起り、過
不能となり、また回復のための逆洗などの処理が
取り得ないからである。また平板状にした場合
は、上記内圧形のチユーブないしは繊維状のよう
な不都合はさけられるが、所要の過面積を得る
ために巨大な過装置となり実用的でない他にや
はり回復のための逆洗は外圧形チユーブないしは
繊維状過装置に比して不利である。即ち、外圧
形のチユーブないしは繊維状過装置であること
により、生物膜床槽よりの流出水を直接超精密
過を可能と出来る。
The reason why the external pressure type hollow tube group or hollow fiber group is used as the ultra-precision method in the present invention is because the particle size of suspended matter in the treated water flowing out from the biofilm bed tank is extremely large. This is because in the internal pressure type, sealing occurs within the tube or fibers, resulting in failure, and treatment such as backwashing for recovery cannot be performed. In addition, if it is made into a flat plate, the inconveniences such as the tube or fiber shape of the internal pressure type mentioned above can be avoided, but in order to obtain the required overarea, it becomes a huge overflow device, which is impractical and also requires backwashing for recovery. is disadvantageous compared to external pressure type tube or fibrous filtration devices. That is, by using an external pressure type tube or fibrous filtration device, it is possible to directly perform ultra-precise filtration of the water flowing out from the biofilm bed tank.

以下本発明の実施例を図面に従い説明する。 Embodiments of the present invention will be described below with reference to the drawings.

第2図に示される本実施例の廃水処理装置では
上流から後流に向けて順次配置される調整槽1
0、水没形固定生物膜床槽30、ポンプ槽1
6、超精密過装置32、過水槽34及び、処
理水槽36によつて主要部が構成されている。
In the wastewater treatment apparatus of this embodiment shown in FIG. 2, adjustment tanks 1 are arranged sequentially from upstream to downstream.
0, submerged fixed biofilm bed tank 30, pump tank 1
6. The main part is constituted by an ultra-precision filter device 32, a water filter tank 34, and a treated water tank 36.

調整槽10の上流にはスクリーン38が設けら
れている。このスクリーン38は例えば目巾0.75
mmの重力式であり、原水から大きな浮遊物(SS
分)を除去した後に調整槽10へ投入するように
なつている。
A screen 38 is provided upstream of the adjustment tank 10. This screen 38 has a width of 0.75, for example.
mm gravity type, which removes large suspended objects (SS) from raw water.
After removing the water (min.), the water is poured into the adjustment tank 10.

調整槽10へはブロア40に通ずる散気管4
1、ポンプ42が設けられて予備曝気後の原水を
計量槽44を介して定量づつ水没形固定生物膜
床槽30へ送るようになつている。
A diffuser pipe 4 leading to a blower 40 is connected to the adjustment tank 10.
1. A pump 42 is provided to send the raw water after preliminary aeration to the submerged fixed biofilm bed tank 30 via a metering tank 44 in fixed quantities.

水没形固定生物膜床槽30では第3図に示さ
れる如く、この場合ハニカム体46が軸心を垂直
として浸漬されている。このハニカム体には汚水
流動により表面へ微生物が付着して生物膜を形成
するようになつており、有機質がこの微生物で分
解し、浄化される。またこの生物膜ではBOD(生
物化学的酸素要求量)、COD(化学的酸素要求量)
アンモニア性窒素などの除去率が高く、またSS
(浮遊物質量濃度)を低くできる。従つて従来例
の如く沈殿槽を必要とせず、処理水を直接に超精
密過装置32へ導くことができる。
In the submerged fixed biofilm bed tank 30, as shown in FIG. 3, the honeycomb body 46 is immersed with its axis vertical. Microorganisms adhere to the surface of this honeycomb body due to the flow of sewage and form a biofilm, and the organic matter is decomposed and purified by the microorganisms. In addition, this biofilm has BOD (biochemical oxygen demand) and COD (chemical oxygen demand).
High removal rate of ammonia nitrogen, etc., and SS
(Suspended solids concentration) can be lowered. Therefore, the treated water can be directly led to the ultra-precision filtration device 32 without requiring a settling tank as in the conventional example.

このハニカム体46の下方にはブロアー47に
通ずる散気管48が配置されて槽内の処理水を曝
気し流動させて生物膜へ接触させるようになつて
いる。
An aeration pipe 48 communicating with a blower 47 is disposed below the honeycomb body 46 to aerate and flow the treated water in the tank to bring it into contact with the biological film.

超精密過装置32には一例として第4図に示
される如き中空体50が複数本、配置されてい
る。この中空体50はPVA(ポリビニルアルコー
ル)系中空繊維膜で、半径方向に複数の貫通孔5
2が形成されている。この貫通孔52は粒径1μm
より小さなSS、バクテリア、コロイド等までも
捕捉できる大きさとなつている。第4図中、白丸
はSS、バクテリア、コロイド等を、黒丸は水、
イオン、塩類の粒子を示している。
As an example, a plurality of hollow bodies 50 as shown in FIG. 4 are arranged in the ultra-precision passing device 32. This hollow body 50 is a PVA (polyvinyl alcohol)-based hollow fiber membrane, and has a plurality of through holes 5 in the radial direction.
2 is formed. This through hole 52 has a particle size of 1 μm.
It is large enough to capture even smaller SS, bacteria, colloids, etc. In Figure 4, white circles represent SS, bacteria, colloids, etc., black circles represent water,
Shows ions and salt particles.

またこれらの中空体50は筒状体(図示省略)
内へ封入され、この筒状体内が高圧(1〜3Kg/
cm2)とされることにより中空体50の外部から処
理水が貫通孔52を通つて過され、内部から
過後の処理水が過水槽34へ取り出される構造
である。このように超精密過装置32では処理
水が中空体50の外側から内側へ過される構造
のため、ポンプ槽16から供給される処理水中に
含まれる微粒子が貫通孔52へ閉塞しても逆洗に
より容易に除去できる。
Moreover, these hollow bodies 50 are cylindrical bodies (not shown).
The inside of this cylindrical body is under high pressure (1~3Kg/
cm 2 ), the treated water is passed from the outside of the hollow body 50 through the through hole 52, and the treated water is taken out from the inside to the water tank 34. In this way, the ultra-precision filtering device 32 has a structure in which the treated water is passed from the outside to the inside of the hollow body 50, so even if the fine particles contained in the treated water supplied from the pump tank 16 clog the through hole 52, it will not be reversed. It can be easily removed by washing.

このように構成された本実施例の作用を説明す
ると、原水がスクリーン38で一次処理され粗大
物が除去された後に調整槽10へと送られる。こ
の調整槽10のブロアー40より通ずる散気管4
1で予備曝気された後に水没形固定生物膜床槽
30へ送られ二次処理される。
To explain the operation of this embodiment configured in this way, raw water is primarily treated with the screen 38 to remove coarse substances, and then sent to the adjustment tank 10. Aeration pipe 4 leading from the blower 40 of this adjustment tank 10
After being pre-aerated in step 1, it is sent to a submerged fixed biofilm bed tank 30 for secondary treatment.

この水没形固定生物膜床槽30ではブロアー
47に通ずる散気管48によつて廃水が流動しな
がらハニカム体46の生物膜へ接触し、廃水が浄
化される。
In this submerged fixed biofilm bed tank 30, wastewater flows through a diffuser pipe 48 leading to a blower 47 and comes into contact with the biofilm of the honeycomb body 46, thereby purifying the wastewater.

水没形固定生物膜床で浄化後の処理水はその
全量が超精密過装置32で固液分離の三次処理
がなされた後に、消毒器24で消毒され、中水と
して再使用される。
The entire amount of treated water purified by the submerged fixed biofilm bed is subjected to tertiary treatment of solid-liquid separation in an ultra-precision filtration device 32, then disinfected in a sterilizer 24, and reused as gray water.

なお、超精密過装置32は目詰り防止のため
に定期的に水逆洗及び空気逆洗を行い、水逆洗の
洗浄廃水は調整槽10へ返送するか、下水道へ放
流する。
The ultra-precision filtering device 32 periodically performs water backwashing and air backwashing to prevent clogging, and the cleaning wastewater from the water backwashing is returned to the adjustment tank 10 or discharged to the sewer.

なお上記実施例では、水没形固定生物膜床槽
30へハニカム体46を用いた構造を示したが、
本発明は微生物が付着し生物膜を形成し、廃水が
この微生物膜へ接触しながら流動浄化する構成で
あればよい。一般に生物膜着生せしめる床に用
いる材ないしは支持体は、ハニカム体の他次の
ものが利用されているが、いづれも本発明の生物
膜床に適用可能である。
In addition, in the above embodiment, a structure is shown in which the honeycomb body 46 is used in the submerged fixed biofilm bed tank 30.
The present invention may be configured as long as microorganisms are attached to form a biofilm, and wastewater is fluidly purified while coming into contact with this microbial film. In addition to honeycombs, the following materials or supports are generally used for beds on which biofilms are deposited, and any of them can be applied to the biofilm bed of the present invention.

(i) 粒状ろ材…砂、砂利、砕石、〓火石、活性
炭、コークス、石炭ガラ、カキガラ、プラスチ
ツク片、コルク片、木片、繊維くずなど。
(i) Granular filter media: sand, gravel, crushed stone, flint, activated carbon, coke, coal husk, persimmon husk, plastic pieces, cork pieces, wood pieces, fiber waste, etc.

(ii) 成形粒状ろ材…インタロツクスサドル、ラシ
ヒリング、パイプ片、変形パイプ片(レユース
Y)、テラレツテ、ポールリングなど。
(ii) Molded granular filter media: interlock saddles, Raschig rings, pipe pieces, deformed pipe pieces (Reuse Y), terrarettes, pole rings, etc.

(iii) 棒状・ひも状ろ材…木棒、竹ざさ、多環ひ
も、(リングレース)など。
(iii) Rod-shaped and string-shaped filter media: wooden sticks, bamboo strips, multi-ring strings, (ring lace), etc.

(iv) 平板状・波板状ろ材…石綿板、木板、プラス
チツク片、プラスチツク網、波板など。
(iv) Flat/corrugated filter media: asbestos boards, wood boards, plastic pieces, plastic nets, corrugated boards, etc.

(v) 有孔体状ろ材…多孔性円筒、ハニカムチユー
ブ、ヘチマロンなど。
(v) Porous filter media: porous cylinders, honeycomb tubes, loofahs, etc.

本例では、水没形固定生物床を利用した場合
を掲げたが、この他に、回転円板床、散水
床、流動床、などの好気性の生物膜床であれ
ばすべて本発明に利用可能である。
Although this example uses a submerged fixed biological bed, any other aerobic biofilm beds such as rotating disk beds, sprinkled beds, fluidized beds, etc. can be used in the present invention. be.

また上記実施例では、超精密過装置として多
孔質中空体を用いたが、本発明は所望の粒径の多
孔質過体であれば全て適用可能である。
Further, in the above embodiments, a porous hollow body was used as the ultra-precision filtration device, but the present invention can be applied to any porous filtration body having a desired particle size.

以上説明した如く、本発明に係る廃水処理装置
では生物膜床槽と超精密過装置とを用いるの
で沈殿槽が不要となつて設置スペースが減少し運
転管理が容易かつ系外の排出する余剰汚泥が極め
て少ないので設備費、運転費を低下させることが
できると同時に高品位の水質を(低コストで多量
に)得ることができる。
As explained above, the wastewater treatment device according to the present invention uses a biofilm bed tank and an ultra-precision filtration device, so a settling tank is not required, the installation space is reduced, operation management is easy, and excess sludge is discharged outside the system. Since the amount of water is extremely small, equipment costs and operating costs can be reduced, and at the same time, high quality water can be obtained (at low cost and in large quantities).

【図面の簡単な説明】[Brief explanation of drawings]

第1図は従来の廃水処理装置を示す流れ図、第
2図は本発明の廃水処理装置の実施例を示す流れ
図、第3図は接触酸化槽の内部構造を示す斜視
図、第4図は超精密過装置の中空体を示す断面
図である。 10……調整槽、30……接触酸化槽、32…
…超精密過装置、46……ハニカム体、50…
…中空体、52……貫通孔。
Fig. 1 is a flowchart showing a conventional wastewater treatment device, Fig. 2 is a flowchart showing an embodiment of the wastewater treatment device of the present invention, Fig. 3 is a perspective view showing the internal structure of a contact oxidation tank, and Fig. 4 is a flowchart showing an embodiment of the wastewater treatment device of the present invention. FIG. 3 is a sectional view showing a hollow body of the precision passing device. 10...Adjustment tank, 30...Contact oxidation tank, 32...
...Ultra precision device, 46...Honeycomb body, 50...
...Hollow body, 52...Through hole.

Claims (1)

【特許請求の範囲】[Claims] 1 廃水が生物膜へ接触しながら流動して清浄化
される好気性生物膜床の後流へ、固液分離のた
めの沈でん槽、浮上槽を介することなく、粒径
1μm以下の粒子を捕捉し得る多孔質材を備えた
超精密過装置を配置し、この超精密過装置は
前記多孔質材を中空状のチユーブ群ないしは繊
維群で構成しこのチユーブないしは繊維の外部か
ら内部へ加圧し全量過する廃水処理装置。
1. The wastewater is flowed and purified while contacting the biofilm to the downstream of the aerobic biofilm bed, where particle size
An ultra-precision filtration device equipped with a porous material capable of capturing particles of 1 μm or less is arranged, and the ultra-precision filtration device consists of a group of hollow tubes or a group of fibers. A wastewater treatment device that pressurizes the inside and passes the entire amount through.
JP57082762A 1982-05-17 1982-05-17 Device for treating waste water Granted JPS58199094A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57082762A JPS58199094A (en) 1982-05-17 1982-05-17 Device for treating waste water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57082762A JPS58199094A (en) 1982-05-17 1982-05-17 Device for treating waste water

Publications (2)

Publication Number Publication Date
JPS58199094A JPS58199094A (en) 1983-11-19
JPH0138557B2 true JPH0138557B2 (en) 1989-08-15

Family

ID=13783450

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57082762A Granted JPS58199094A (en) 1982-05-17 1982-05-17 Device for treating waste water

Country Status (1)

Country Link
JP (1) JPS58199094A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019107612A (en) * 2017-12-19 2019-07-04 ダイセン・メンブレン・システムズ株式会社 Wastewater treatment method and wastewater recycling method

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0368497A (en) * 1989-08-07 1991-03-25 Arita Bussan Kk Method and device for purifying water
CN113772912B (en) * 2021-11-11 2022-03-22 临沂朝日电子有限公司 Environmental protection sludge separation device
JP7298785B1 (en) * 2022-03-28 2023-06-27 中国電力株式会社 Sewage purification equipment

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019107612A (en) * 2017-12-19 2019-07-04 ダイセン・メンブレン・システムズ株式会社 Wastewater treatment method and wastewater recycling method

Also Published As

Publication number Publication date
JPS58199094A (en) 1983-11-19

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