JPH0133002B2 - - Google Patents
Info
- Publication number
- JPH0133002B2 JPH0133002B2 JP16860682A JP16860682A JPH0133002B2 JP H0133002 B2 JPH0133002 B2 JP H0133002B2 JP 16860682 A JP16860682 A JP 16860682A JP 16860682 A JP16860682 A JP 16860682A JP H0133002 B2 JPH0133002 B2 JP H0133002B2
- Authority
- JP
- Japan
- Prior art keywords
- electrode
- ionic
- electrode material
- association
- heteropolyacid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007772 electrode material Substances 0.000 claims description 36
- 239000011964 heteropoly acid Substances 0.000 claims description 21
- 150000002894 organic compounds Chemical class 0.000 claims description 17
- 150000002902 organometallic compounds Chemical class 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 9
- 125000005842 heteroatom Chemical group 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000000243 solution Substances 0.000 description 18
- 150000002500 ions Chemical class 0.000 description 13
- 239000000463 material Substances 0.000 description 11
- 229960000907 methylthioninium chloride Drugs 0.000 description 11
- 239000002202 Polyethylene glycol Substances 0.000 description 10
- 229920001223 polyethylene glycol Polymers 0.000 description 10
- 239000002244 precipitate Substances 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 238000002484 cyclic voltammetry Methods 0.000 description 8
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 7
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- DHRLEVQXOMLTIM-UHFFFAOYSA-N phosphoric acid;trioxomolybdenum Chemical compound O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O DHRLEVQXOMLTIM-UHFFFAOYSA-N 0.000 description 7
- 238000006479 redox reaction Methods 0.000 description 7
- 239000002585 base Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000002441 reversible effect Effects 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 229910021397 glassy carbon Inorganic materials 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 125000004076 pyridyl group Chemical group 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- 229910006404 SnO 2 Inorganic materials 0.000 description 3
- 239000003929 acidic solution Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000003487 electrochemical reaction Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- IYDGMDWEHDFVQI-UHFFFAOYSA-N phosphoric acid;trioxotungsten Chemical compound O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.OP(O)(O)=O IYDGMDWEHDFVQI-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000005518 polymer electrolyte Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- MWVTWFVJZLCBMC-UHFFFAOYSA-N 4,4'-bipyridine Chemical group C1=NC=CC(C=2C=CN=CC=2)=C1 MWVTWFVJZLCBMC-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000003411 electrode reaction Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- 108091006149 Electron carriers Proteins 0.000 description 1
- 239000004721 Polyphenylene oxide Chemical class 0.000 description 1
- 241001168730 Simo Species 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 229930013930 alkaloid Natural products 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- -1 cationic porphyrin compounds Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 150000003983 crown ethers Chemical class 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 229940097362 cyclodextrins Drugs 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- ZHNUHDYFZUAESO-UHFFFAOYSA-N formamide Substances NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000003100 immobilizing effect Effects 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical class N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229930188006 polyphyllin Natural products 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 229940043267 rhodamine b Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Non-Insulated Conductors (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16860682A JPS5960818A (ja) | 1982-09-29 | 1982-09-29 | 電極材料 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16860682A JPS5960818A (ja) | 1982-09-29 | 1982-09-29 | 電極材料 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5960818A JPS5960818A (ja) | 1984-04-06 |
| JPH0133002B2 true JPH0133002B2 (https=) | 1989-07-11 |
Family
ID=15871170
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16860682A Granted JPS5960818A (ja) | 1982-09-29 | 1982-09-29 | 電極材料 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5960818A (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2573779B1 (fr) * | 1984-11-28 | 1987-08-28 | Centre Nat Rech Scient | Nouvelles electrodes activees a l'aide d'heteropolyacides, leur preparation et leur application, notamment comme cathodes pour l'electrolyse de l'eau en milieu acide |
| GB8500729D0 (en) * | 1985-01-11 | 1985-02-13 | Hill H A O | Surface-modified electrode |
| US4633372A (en) * | 1985-08-26 | 1986-12-30 | The Standard Oil Company | Polyoxometalate-modified carbon electrodes and uses therefor in capacitors |
| JP5128238B2 (ja) * | 2007-10-30 | 2013-01-23 | 国立大学法人佐賀大学 | 貴金属微粒子の製造方法、その方法に用いられる光触媒及び廃棄物からの貴金属の回収方法 |
| US8771876B2 (en) | 2009-04-22 | 2014-07-08 | Sony Corporation | Positive electrode active material, method for manufacturing positive electrode active material and nonaqueous electrolyte battery |
| WO2010147236A1 (ja) | 2009-06-17 | 2010-12-23 | ソニー株式会社 | 非水電解質電池、非電解質電池用正極、非水電解質電池用負極、非電解質電池用セパレータ、非水電解質用電解質および非電解質電池用セパレータの製造方法 |
| JP5273124B2 (ja) | 2009-11-05 | 2013-08-28 | ソニー株式会社 | 正極および非水電解質電池 |
| JP5471598B2 (ja) | 2010-03-02 | 2014-04-16 | ソニー株式会社 | 非水電解質電池 |
| JP5463957B2 (ja) | 2010-03-02 | 2014-04-09 | ソニー株式会社 | 非水電解液および電池 |
| JP5533035B2 (ja) | 2010-03-02 | 2014-06-25 | ソニー株式会社 | 非水電解質組成物、および非水電解質電池 |
-
1982
- 1982-09-29 JP JP16860682A patent/JPS5960818A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5960818A (ja) | 1984-04-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Mao et al. | Electronically conductive anion exchange polymers based on polypyrrole: Preparation, characterization, electrostatic binding of ferrocyanide and electrocatalysis of ascorbic acid oxidation | |
| JP3288044B2 (ja) | 酸化還元酵素に対するメディエータ | |
| CN1620462B (zh) | 具有(吡啶基)咪唑配体的过渡金属络合物 | |
| Itaya et al. | Chemically modified polymer electrodes: synthetic approach employing poly (methacryl chloride) anchors | |
| Narayanan et al. | A comparative study of the electrocatalytic activities of some metal hexacyanoferrates for the oxidation of hydrazine | |
| CN108362750B (zh) | 一种基于金纳米粒子掺杂共价有机骨架复合材料电极的制备方法 | |
| Brahim et al. | Electroconductive hydrogels: Electrical and electrochemical properties of polypyrrole‐poly (HEMA) composites | |
| CA2072224C (en) | Electrically conductive polymer composition, method of making same and device incorporating same | |
| Pournaghi-Azar et al. | Electrochemistry and electrocatalytic activity of polypyrrole/ferrocyanide films on a glassy carbon electrode | |
| Cosnier et al. | Alkylammonium and pyridinium group-containing polypyrroles, a new class of electronically conducting anion-exchange polymers | |
| DE60211213T2 (de) | Elektrode für aktive sauerstoffspezies und die elektrode verwendender sensor | |
| Degrand et al. | Voltammetric properties of electrodes modified by poly-[N-(9, 10-anthraquinone-2-carbonyl) ethylenimine] and used in aqueous solution | |
| Forster et al. | Modulating the redox properties of an osmium-containing metallopolymer through the supporting electrolyte and cross-linking | |
| JPH0133002B2 (https=) | ||
| Shaojun et al. | Researches on chemically modified electrodes: Part XV. Preparation and electrochromism of the vanadium hexacyanoferrate film modified electrode | |
| Geno et al. | Chemically modified carbon paste electrodes: Part IV. Electrostatic binding and electrocatalysis at poly (4-vinylpyridine)-containing electrodes | |
| EP0757246A2 (en) | Conducting paste, electrodes, sensors and electrochemical reactors containing said paste, and their manufacturing method | |
| Komura et al. | Coupled Electron‐Proton Transport in Electropolymerized Methylene Blue and the Influences of Its Protonation Level on the Rate of Electron Exchange with β‐Nicotinamide Adenine Dinucleotide | |
| Hassanzadeh et al. | Selective electrochemical sensing of dopamine and ascorbic acid using carbon paste electrode modified with cobalt Schiff Base complex and a surfactant | |
| JPH01252666A (ja) | ヘテロポリアニオンを添加した電子伝導重合体、その調製方法並びに化学及び電気化学触媒 | |
| Bettelheim et al. | Application of a polymer solid electrolyte for the vapor-phase electrocatalysis of dioxygen reduction by some cobalt porphyrins | |
| FI96141C (fi) | Ioniselektiivinen elektrodi ja menetelmä ioniselektiivisen elektrodin valmistamiseksi | |
| Palmore et al. | pH-Dependent rectification in redox polymers: Characterization of electrode-confined siloxane polymers containing naphthoquinone and benzylviologen subunits | |
| JP2907131B2 (ja) | 導電性高分子とこれを用いた固体電解コンデンサ、およびその製造方法 | |
| Collomb-Dunand-Sauthier et al. | Electrochemistry of cis-diaquo ruthenium (II) complexes with substituted 2, 2′-bipyridine ligands in a non-coordinating solvent. Application to the elaboration of corresponding functionalized polypyrrole films |