JPH013036A - Low reflective coated articles - Google Patents
Low reflective coated articlesInfo
- Publication number
- JPH013036A JPH013036A JP63-116789A JP11678988A JPH013036A JP H013036 A JPH013036 A JP H013036A JP 11678988 A JP11678988 A JP 11678988A JP H013036 A JPH013036 A JP H013036A
- Authority
- JP
- Japan
- Prior art keywords
- nickel
- metal alloy
- article
- alloy
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 23
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 20
- 229910052751 metal Inorganic materials 0.000 claims description 16
- 239000002184 metal Substances 0.000 claims description 16
- 239000010935 stainless steel Substances 0.000 claims description 15
- 229910001220 stainless steel Inorganic materials 0.000 claims description 15
- 238000000576 coating method Methods 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- 239000000758 substrate Substances 0.000 claims description 14
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 13
- 239000011521 glass Substances 0.000 claims description 13
- 238000004544 sputter deposition Methods 0.000 claims description 13
- 229910052742 iron Inorganic materials 0.000 claims description 10
- 229910052759 nickel Inorganic materials 0.000 claims description 10
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 9
- 229910052804 chromium Inorganic materials 0.000 claims description 9
- 239000011651 chromium Substances 0.000 claims description 9
- 239000011248 coating agent Substances 0.000 claims description 8
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 6
- 239000012298 atmosphere Substances 0.000 claims description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims description 6
- 150000004706 metal oxides Chemical class 0.000 claims description 6
- 150000002739 metals Chemical class 0.000 claims description 6
- 229910000906 Bronze Inorganic materials 0.000 claims description 5
- 229910045601 alloy Inorganic materials 0.000 claims description 5
- 239000000956 alloy Substances 0.000 claims description 5
- 239000010974 bronze Substances 0.000 claims description 5
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052786 argon Inorganic materials 0.000 claims description 3
- 238000002310 reflectometry Methods 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 239000010955 niobium Substances 0.000 claims description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 239000010410 layer Substances 0.000 description 16
- 230000005540 biological transmission Effects 0.000 description 6
- 230000003750 conditioning effect Effects 0.000 description 5
- 238000002834 transmittance Methods 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 239000005328 architectural glass Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 229910000599 Cr alloy Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000000788 chromium alloy Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910001026 inconel Inorganic materials 0.000 description 2
- 238000001755 magnetron sputter deposition Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- -1 chromium alloys Chemical class 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000005329 float glass Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、透明被覆の分野に関し、特に、建築用のガラ
ス製品に使用するための多層着色透明被覆に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to the field of transparent coatings, and more particularly to multilayer pigmented transparent coatings for use in architectural glass products.
金属及び（又は）金属酸化物膜を有する建築用ガラス製
品は、加熱及び冷却のために必要なエネルギーが次第に
高価になってきているので、重要性を増してきている。Architectural glass products having metal and/or metal oxide films are becoming increasingly important as the energy required for heating and cooling is becoming increasingly expensive.
被覆された建築用ガラス製品は、一般に二つの範鴫、太
陽ニオ・ルギー調節及び高透過性製品と、低放射性被覆
製品とに分類される。 太陽エネルギー調節ガラス製品
は、一般に、屡々着色されているガラス基体に、高反射
性で可視光透過率の低い着色フィルムを被覆したもので
あり、そのフィルムは、窓を通って建物の内部へ入る太
陽エネルギーの透過率を減じ、それによって空調費を少
なくする。これらの製品は暖かい気候の処で最も有効で
あり、最も屡々商業的に製造されているのが見られる。Coated architectural glass products are generally classified into two categories: solar energy control and high transparency products, and low emissivity coated products. Solar energy conditioning glass products generally consist of a glass substrate, often colored, coated with a highly reflective, low visible light transmittance colored film that enters the interior of the building through the window. Reduces solar energy transmission, thereby reducing air conditioning costs. These products are most effective in warm climates and are most often found commercially manufactured.
暖房費が一層大きな関心事になる地方では、特に居住用
建造物中では、建物内部に熱を保持するため赤外線を反
射しながら、内部への可視光の透過率を大きくするため
、高透過性で低放射性の被覆が望ましい、高透過性低放
射性被覆は、典型的には多層フィルムであり、この場合
、銀、金、又は銅の如き赤外線反射性金属が、ビスマス
、インジウム及び（又は）絹の酸化物の如き非反射性金
属酸化物層の間に挟まれている。一方、太陽エネルギー
調節フィルムは、コバルト、鉄、クロム、ニッケル、銅
等の如き金属又はそれら金属の酸化物の一種類以上の高
反射性単−層フイルムであるのが典型的である。In rural areas where heating costs are an even greater concern, especially in residential buildings, high transmissivity is required to reflect infrared rays to retain heat within the building while increasing the transmission of visible light into the interior. Highly transparent, low-emissivity coatings are typically multilayer films in which infrared reflective metals such as silver, gold, or copper are combined with bismuth, indium, and/or silk. sandwiched between non-reflective metal oxide layers, such as oxides of Solar energy control films, on the other hand, are typically highly reflective single-layer films of one or more metals, such as cobalt, iron, chromium, nickel, copper, etc., or oxides of these metals.
太陽エネルギー調節のための金属フィルムを製造するた
めの化Ｔ的湿式法は、米国特許第３．８４６，１５２号
；第４，０９１，１７２号；第３，７２３，１５８号及
び第３，４５７．１３８号により良く知られている。太
陽エネルギー調節のための金属酸化物フィルムを製造す
るための熱分解法は、米国特許第３．６６（１，０６１
号；第３，６５８，５６８号；第３，９７８，２７２号
及び第４．１００，３３０号により良く知られている。Chemical wet processes for producing metal films for solar energy conditioning are described in U.S. Pat. Nos. 3,846,152; 4,091,172; .138 is better known. A pyrolytic process for producing metal oxide films for solar energy conditioning is described in U.S. Pat. No. 3.66 (1,061
No. 3,658,568; No. 3,978,272 and No. 4.100,330.
高透過性低放射性多層被覆のスパッタリングによる製造
方法は、米国特許第４，４６２，８８４号及び第４．５
０８，７８９号に記載されている。太陽エネルギー調節
のためのフィルムを製造するためのスパッタリング法は
、米国特許第４，５１２，８６３号及び第４．５９４，
１３７号に記載されている。Methods for producing high transmission, low emissivity multilayer coatings by sputtering are disclosed in U.S. Pat. Nos. 4,462,884 and 4.5.
No. 08,789. Sputtering methods for producing films for solar energy conditioning are described in U.S. Pat.
It is described in No. 137.
グラブ（Ｇｒｕｂｂ）その他による米国特許第４．０２
２，９４７号には、入射太陽光の大部分を反射しながら
、可視光の希望の部分を透過することができる透明板が
記載されており、又透明金属フィルムを得るために鉄、
ニッケル及びクロム合金をスパッターし、そしてそれら
を又は同様な合金を酸素の存在下で反応的にスパッター
して酸化物フィルムを形成させることによりその板を製
造する方法が記載されている。一つの好ましい態様とし
て、金属フィルムが基体と金属酸化物フィルムとの間に
入れである。他の好ましい態様として、金属酸化物フィ
ルムが基体と金属フィルムとの間に入っている。U.S. Patent No. 4.02 to Grubb et al.
No. 2,947 describes a transparent plate that is capable of transmitting a desired portion of visible light while reflecting a large portion of the incident sunlight, and also uses iron, iron, etc. to obtain a transparent metal film.
A method is described for making the plate by sputtering nickel and chromium alloys and reactively sputtering them or similar alloys in the presence of oxygen to form an oxide film. In one preferred embodiment, a metal film is interposed between the substrate and the metal oxide film. In another preferred embodiment, a metal oxide film is interposed between the substrate and the metal film.
Ｒ，Ｃ，クリス（Ｃｒｉｓ３）により１９８４年１２月
１７日に出願された［界面着色をもつ建築用被覆（Ａｒ
ｃｈｉｔｅｃｔｕｒａｌ Ｃｏａｔｉｎｇ ｗｉｔｈ
Ｉｎｔｅｒｆｅｒａｎｃｅ Ｃｏ１ｏｒｓ）」と題する
米国特許出願Ｓ 、Ｎ 、 ６８２，１３６には、吸収
及び干渉効果の両方により色を示す金属化合物の層と組
み合わさって高度に反射性の金属の層を有する強く着色
した被覆が記載されている。Architectural Coatings with Interfacial Coloring (Ar
chitectural coating with
U.S. Patent Application S.N.682,136 entitled ``Interference Co1ors'' describes a highly colored highly reflective metal layer having a layer of a highly reflective metal in combination with a layer of a metal compound that exhibits color by both absorption and interference effects. The coating is described.
本発明には、陰極スパッタリング、好ましくはマグネト
ロンスパッタリングによりガラスの如き基体上に付着さ
せた低反射性、低透過性ブロンズ色の太陽エネルギー調
節フィルムが含まれる。そのフィルムは、低反射性着色
金属合金酸化物の層と灰色（ｎｅｕｔｒａｌ）金属合金
の層とからなる。金属合金酸化物層は、色及び低反射性
を与え、金属合金層は灰色の低透過性を与える。The present invention includes a low reflectivity, low transmittance bronze colored solar energy management film deposited onto a substrate such as glass by cathodic sputtering, preferably magnetron sputtering. The film consists of a layer of low reflective colored metal alloy oxide and a layer of neutral metal alloy. The metal alloy oxide layer provides color and low reflectivity, and the metal alloy layer provides gray low transmission.
透明基体、好ましくはガラスを陰極スパッタリング、好
ましくはマグネトロンスパッタリングにより被覆し、太
陽エネルギー調節製品を与える。A transparent substrate, preferably glass, is coated by cathodic sputtering, preferably magnetron sputtering, to provide a solar energy conditioning product.
被覆は、ステンレス鋼酸化物の如き着色金属合金酸化物
の少なくとも一つの層と、ニッケル合金の如き灰色低透
過性を与える金属合金の少なくとも一つの層とからなる
。好ましい金属合金はインコネル（ｌｎｃｏｎｅｔ）で
ある。The coating consists of at least one layer of a colored metal alloy oxide, such as a stainless steel oxide, and at least one layer of a metal alloy providing a gray low transparency, such as a nickel alloy. A preferred metal alloy is Inconet.
本発明の好ましい具体例として、ガラス表面をまず、酸
化性反応性雰囲気中でステンレス鋼陰極ターゲットをス
パッターすることにより、ステンレス鋼酸化物の層で被
覆する。ステンレス鋼酸化物で被覆された表面を次に、
アルゴンの如き非反応作立囲気中でニッケル合金ターゲ
ットをスパンターすることにより、灰色金属合金の層で
更に被覆する。それら被覆層の相対的厚さは、種々の視
覚的効果を生ずるように変えることができる。特に、灰
色金属層の厚さは、ガラス側からの反射又は色を実質的
に変えることなく、透過性を増加したり或は低下したり
するように変えることができる。In a preferred embodiment of the invention, the glass surface is first coated with a layer of stainless steel oxide by sputtering a stainless steel cathode target in an oxidizing reactive atmosphere. The stainless steel oxide coated surface is then
The nickel alloy target is further coated with a layer of gray metal alloy by spuntering the nickel alloy target in a non-reactive atmosphere such as argon. The relative thicknesses of the covering layers can be varied to produce various visual effects. In particular, the thickness of the gray metal layer can be varied to increase or decrease transmission without substantially changing the reflection or color from the glass side.
最も好ましい態様として、ステンレス鋼酸化物とインコ
ネル金属合金層を一緒にしてブロンズ色の被覆を生成さ
せる０本発明を次の特別の実施例についての記載から一
層よく理解することかできるであろう。In a most preferred embodiment, a stainless steel oxide and an Inconel metal alloy layer are combined to produce a bronze colored coating.The present invention will be better understood from the following description of specific embodiments.
実施例１
ステンレス鋼酸化物とニッケル金属合金の多層被覆を次
の条件でガラス基体上に、連続した多段陰極の下金−度
通すことにより付着させた。正常なガラス基体は、真空
室中、３ミリトールの圧力の５０％酸素及び５０％アル
ゴンからなる雰囲気中に維持された。約２．７４ｘ ０
．４ｍ （１０６ｘ １５ｉｎ）の大きさのターゲット
表面積をもつステンレス鋼陰極に９８ｋＷの電力を加え
た。２．３６ｍ（９３ｉｎ）／分の線速度で、ステンレ
ス鋼酸化物被覆を、約６ ｒａｍ （１／４ｉｎ）厚の
透明フロートガラス基体に対し透過率を９０％から５９
％へ低下させる厚さに付着させた。この例で用いられた
ステンレス鋼組成物は、６８％の鉄、１７％のクロム、
１２？≦のニッケル及び２．２５９’のモリブデンを含
む３１６合金であった０次にニッケル合金陰極を３ミリ
トールの不活性アルゴン雰囲気中でスパンターした。同
じ線速度及び７ｋＷの電力を用いて、ニッケル合金被覆
をステンレス鋼酸化物被覆の上に１１着させ、更に透過
率を１６．８％へ低下させた。この例で用いられたニッ
ケル６金は、６２．６％のニッケル、２０％のクロム、
６．８５％の鉄、３．９５２６のニオブと、タンタル、
炭素、マンガン、鉄、硫黄、珪素、銅、アルミニウム及
びチタンを微量（１％より少ない）含むインコネル６２
５であった。Example 1 A multilayer coating of stainless steel oxide and nickel metal alloy was deposited on a glass substrate by passing through a series of multi-stage cathodes under the following conditions. Normal glass substrates were maintained in an atmosphere consisting of 50% oxygen and 50% argon at a pressure of 3 mTorr in a vacuum chamber. Approximately 2.74x 0
．． A power of 98 kW was applied to a stainless steel cathode with a target surface area measuring 4 m (106 x 15 in). At a line speed of 2.36 m (93 in)/min, the stainless steel oxide coating was applied to a transparent float glass substrate approximately 6 ram (1/4 in) thick from 90% to 59% transmittance.
The thickness was reduced to %. The stainless steel composition used in this example was 68% iron, 17% chromium,
12? The zero-order nickel alloy cathode, which was a 316 alloy containing <= nickel and 2.259' molybdenum, was spuntered in an inert argon atmosphere of 3 mTorr. Using the same line speed and 7 kW power, 11 nickel alloy coatings were deposited on top of the stainless steel oxide coating, further reducing the transmission to 16.8%. The nickel-6 gold used in this example is 62.6% nickel, 20% chromium,
6.85% iron, 3.9526 niobium, tantalum,
Inconel 62 containing trace amounts (less than 1%) of carbon, manganese, iron, sulfur, silicon, copper, aluminum and titanium
It was 5.
被覆物品を外囲条件に曝すと、ニッケル合金波層表面は
酸化して、わずかに透過率が増大した。被覆した物品は
、ガラス側から見て低反射性ブロンズ色の外観をもって
いた。被覆した物品の光透過率は約２０％で、光反射率
はガラス側から約１４％であった０反射色はブロンズで
、色度座標はＸ−０，３４０１、ｙ＝０．３５１８であ
った。When the coated article was exposed to ambient conditions, the nickel alloy wave layer surface oxidized and the transmittance increased slightly. The coated article had a low reflective bronze appearance when viewed from the glass side. The light transmittance of the coated article was about 20% and the light reflectance was about 14% from the glass side. The 0 reflection color was bronze and the chromaticity coordinates were X-0,3401, y=0.3518. Ta.
上記実゛施例は本発明を例示するためにのみ与えられて
いる。クロム合金の如き他の灰色低反射性金属と共に、
種々の他の着色金属合金酸化物を用いてもよい、どんな
適当な透明保護基体が用いられてもよい０本発明の範囲
は、特許請求の範囲によって定められる６のである。The above examples are given only to illustrate the invention. Along with other gray low reflective metals such as chromium alloys,
Various other colored metal alloy oxides may be used, and any suitable transparent protective substrate may be used. The scope of the invention is defined by the claims.
代 理 人 浅 村 皓手続補正書 昭和６３年８り／ｆ日Written amendment to the legal procedure for the village of Asahi 8th/f day of 1988
Claims (19)
化物の透明なフィルム、 及びｃ、前記金属酸化物フィルム上に付着された低反射
性透明金属合金フィルム、 からなる太陽エネルギー反射性製造物品。(1) a. a transparent substrate; b. a transparent film of a color-indicating metal alloy oxide deposited on the surface of said substrate; and c. a low-reflectivity transparent metal deposited on said metal oxide film. A solar energy reflective manufactured article comprising an alloy film.
ムからなる群から選択された金属の合金からなる請求項
２に記載の製造物品。3. The article of manufacture of claim 2, wherein the low reflective metal alloy film comprises an alloy of metals selected from the group consisting of nickel and chromium.
物品。(4) The manufactured article of claim 3, wherein the metal alloy includes nickel.
求項４に記載の物品。(5) The article of claim 4, wherein the nickel alloy includes nickel, chromium, and iron.
請求項２に記載の物品。(6) The article according to claim 2, wherein the metal alloy oxide film is made of stainless steel.
らなる請求項６に記載の物品。(7) The article of claim 6, wherein the metal alloy oxide film comprises stainless steel oxide.
デンを含む請求項７に記載の物品。(8) The article of claim 7, wherein the stainless steel includes iron, chromium, nickel, and molybdenum.
請求項７に記載の物品。(9) The article of claim 7, wherein the article exhibits a bronze color as reflected from the glass surface.
属がスパッターされたフィルムである請求項１に記載の
物品。(10) The article according to claim 1, which is a transparent film of a metal alloy oxide and a film sputtered with a low reflective metal.
第一透明被覆をスパッターし、そして ｂ、前記金属合金酸化物フィルムの上に低反射性透明金
属合金フィルムをスパッターする、諸工程からなる太陽
エネルギー反射性被覆物品の製造方法。(11) a. sputtering a first transparent coating of a colored metal alloy oxide onto the surface of a substrate; and b. sputtering a low reflective transparent metal alloy film onto the metal alloy oxide film. A method for manufacturing a solar energy reflective coated article comprising the steps of:
進されている請求項１１に記載の方法。(12) The method of claim 11, wherein the substrate is glass and the sputtering is magnetically promoted.
る金属合金をスパッターすることにより付着される請求
項１２に記載の方法。13. The method of claim 12, wherein the metal alloy oxide film is deposited by sputtering a metal alloy comprising stainless steel.
れる請求項１３に記載の方法。(14) The method of claim 13, wherein the stainless steel is sputtered in an oxidizing atmosphere.
らなる群から選択された金属の合金をスパッターするこ
とにより付着される請求項１４に記載の方法。15. The method of claim 14, wherein the metal alloy film is deposited by sputtering an alloy of metals selected from the group consisting of nickel and chromium.
ル合金をスパッターすることにより付着される請求項１
５に記載の方法。(16) Claim 1, wherein the metal alloy film is deposited by sputtering a nickel alloy in an inert atmosphere.
The method described in 5.
ッターされる請求項１６に記載の方法。(17) The method according to claim 16, wherein the nickel alloy is sputtered in an atmosphere containing argon.
請求項１７に記載の方法。(18) The method of claim 17, wherein the nickel alloy includes nickel, chromium, and iron.
ブを含む請求項１８に記載の方法。(19) The method of claim 18, wherein the nickel alloy includes nickel, chromium, iron, and niobium.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US50825 | 1987-05-15 | ||
| US07/050,825 US4847158A (en) | 1987-05-15 | 1987-05-15 | Low reflectance bronze coating |
| US050825 | 1987-05-15 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPS643036A JPS643036A (en) | 1989-01-06 |
| JPH013036A true JPH013036A (en) | 1989-01-06 |
| JP2528937B2 JP2528937B2 (en) | 1996-08-28 |
Family
ID=21967677
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63116789A Expired - Lifetime JP2528937B2 (en) | 1987-05-15 | 1988-05-13 | Low reflective coated article |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US4847158A (en) |
| EP (1) | EP0291010B1 (en) |
| JP (1) | JP2528937B2 (en) |
| KR (1) | KR930006324B1 (en) |
| CN (1) | CN1030101A (en) |
| AT (1) | ATE131939T1 (en) |
| AU (1) | AU584541B2 (en) |
| CA (2) | CA1328090C (en) |
| DE (1) | DE3854798T2 (en) |
| DK (1) | DK264488A (en) |
| ES (1) | ES2083358T3 (en) |
| FI (1) | FI882234A (en) |
| GR (1) | GR3019206T3 (en) |
| HK (1) | HK1000474A1 (en) |
| MY (1) | MY103372A (en) |
| NO (1) | NO882106L (en) |
| NZ (1) | NZ224378A (en) |
| ZA (1) | ZA883009B (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5112693A (en) * | 1988-10-03 | 1992-05-12 | Ppg Industries, Inc. | Low reflectance, highly saturated colored coating for monolithic glazing |
| US5055358A (en) * | 1989-09-29 | 1991-10-08 | Libbey-Owens-Ford Co. | Low reflectance films for transparent substrates |
| US5229194A (en) * | 1991-12-09 | 1993-07-20 | Guardian Industries Corp. | Heat treatable sputter-coated glass systems |
| US5376455A (en) * | 1993-10-05 | 1994-12-27 | Guardian Industries Corp. | Heat-treatment convertible coated glass and method of converting same |
| EP1140720B1 (en) * | 1998-12-22 | 2007-03-28 | Glaverbel | Protective layer for coated substrate |
| US6365284B1 (en) | 1999-06-04 | 2002-04-02 | Crown Operations International, Ltd. | Flexible solar-control laminates |
| US7067195B2 (en) | 2002-04-29 | 2006-06-27 | Cardinal Cg Company | Coatings having low emissivity and low solar reflectance |
| US7122252B2 (en) * | 2002-05-16 | 2006-10-17 | Cardinal Cg Company | High shading performance coatings |
| EP1527028B1 (en) * | 2002-07-31 | 2018-09-12 | Cardinal CG Company | Temperable high shading performance coatings |
| US7807248B2 (en) * | 2007-08-14 | 2010-10-05 | Cardinal Cg Company | Solar control low-emissivity coatings |
| TWI456452B (en) * | 2011-11-25 | 2014-10-11 | Method for manufacturing touch panel with low metallic luster visibility and product thereof | |
| CN103963387B (en) * | 2014-01-15 | 2016-01-20 | 洛阳新晶润工程玻璃有限公司 | A kind of high heat absorption blue film coated glass of low reflection and manufacture method thereof |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE515314A (en) * | 1949-04-18 | |||
| US2676117A (en) * | 1949-04-18 | 1954-04-20 | Libbey Owens Ford Glass Co | Light transmissive electrically conducting optical article |
| DE2256441C3 (en) * | 1972-11-17 | 1978-06-22 | Flachglas Ag Delog-Detag, 8510 Fuerth | Color-neutral, heat-reflecting pane and its use in laminated safety panes and double panes when viewed through and from above |
| FR2218301A1 (en) * | 1973-02-16 | 1974-09-13 | Saint Gobain | Semi-reflecting glaze with semi-conductor layer - of pref tin oxide, indium oxide or titanium nitride applied on film of gold, silver or copper |
| JPS5128091A (en) * | 1974-08-29 | 1976-03-09 | Mizukawa Sangyo Kk | HOSOBAKONOJIDOSHIIRUSOCHI |
| US4022947A (en) * | 1975-11-06 | 1977-05-10 | Airco, Inc. | Transparent panel having high reflectivity for solar radiation and a method for preparing same |
| DE2750500A1 (en) * | 1977-11-11 | 1979-05-17 | Leybold Heraeus Gmbh & Co Kg | Panes with IR reflecting properties - obtd. by sputtering on first an indium oxide-tin oxide layer, then a gold, silver or copper layer |
| DE2924833C3 (en) * | 1979-06-20 | 1982-05-19 | Bfg Glassgroup, Paris | Heat reflecting panel with a color-neutral exterior view and its use as an exterior panel in a multi-panel arrangement |
| JPS5918134A (en) * | 1982-07-16 | 1984-01-30 | Asahi Glass Co Ltd | Manufacture of heat reflecting laminate having oxide film |
| US4462884A (en) * | 1983-07-25 | 1984-07-31 | Ppg Industries, Inc. | Low reflectance, low emissivity sputtered film |
| US4512863A (en) * | 1983-09-09 | 1985-04-23 | Ppg Industries, Inc. | Stainless steel primer for sputtered films |
| US4594137A (en) * | 1983-09-09 | 1986-06-10 | Ppg Industries, Inc. | Stainless steel overcoat for sputtered films |
| AU561315B2 (en) * | 1984-10-29 | 1987-05-07 | Ppg Industries Ohio, Inc. | Sputtering films of metal alloy oxide |
| US4902581A (en) * | 1984-12-17 | 1990-02-20 | Ppg Industries, Inc. | Architectural coating with interference colors |
-
1987
- 1987-05-15 US US07/050,825 patent/US4847158A/en not_active Expired - Lifetime
-
1988
- 1988-04-26 NZ NZ224378A patent/NZ224378A/en unknown
- 1988-04-27 ZA ZA883009A patent/ZA883009B/en unknown
- 1988-05-10 CA CA000566433A patent/CA1328090C/en not_active Expired - Fee Related
- 1988-05-10 EP EP88107482A patent/EP0291010B1/en not_active Expired - Lifetime
- 1988-05-10 ES ES88107482T patent/ES2083358T3/en not_active Expired - Lifetime
- 1988-05-10 DE DE3854798T patent/DE3854798T2/en not_active Expired - Fee Related
- 1988-05-10 CA CA000566432A patent/CA1315461C/en not_active Expired - Fee Related
- 1988-05-10 AT AT88107482T patent/ATE131939T1/en not_active IP Right Cessation
- 1988-05-12 FI FI882234A patent/FI882234A/en not_active IP Right Cessation
- 1988-05-13 DK DK264488A patent/DK264488A/en not_active Application Discontinuation
- 1988-05-13 MY MYPI88000508A patent/MY103372A/en unknown
- 1988-05-13 JP JP63116789A patent/JP2528937B2/en not_active Expired - Lifetime
- 1988-05-13 NO NO882106A patent/NO882106L/en unknown
- 1988-05-13 AU AU16127/88A patent/AU584541B2/en not_active Ceased
- 1988-05-14 KR KR1019880005636A patent/KR930006324B1/en not_active IP Right Cessation
- 1988-05-16 CN CN88102876A patent/CN1030101A/en active Pending
-
1996
- 1996-03-05 GR GR960400610T patent/GR3019206T3/en unknown
-
1997
- 1997-10-23 HK HK97102008A patent/HK1000474A1/en not_active IP Right Cessation
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