JPH01301800A - Detergent composition for bathroom - Google Patents
Detergent composition for bathroomInfo
- Publication number
- JPH01301800A JPH01301800A JP13357088A JP13357088A JPH01301800A JP H01301800 A JPH01301800 A JP H01301800A JP 13357088 A JP13357088 A JP 13357088A JP 13357088 A JP13357088 A JP 13357088A JP H01301800 A JPH01301800 A JP H01301800A
- Authority
- JP
- Japan
- Prior art keywords
- bathroom
- formulas
- formula
- 2cooh
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 239000003599 detergent Substances 0.000 title description 3
- 239000002904 solvent Substances 0.000 claims abstract description 11
- 230000007935 neutral effect Effects 0.000 claims abstract description 9
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims abstract description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 5
- 150000003863 ammonium salts Chemical class 0.000 claims abstract description 4
- 238000004140 cleaning Methods 0.000 claims description 21
- 239000000126 substance Substances 0.000 claims description 7
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 15
- 239000000463 material Substances 0.000 abstract description 8
- 238000002156 mixing Methods 0.000 abstract description 6
- 238000005406 washing Methods 0.000 abstract description 5
- 125000000217 alkyl group Chemical group 0.000 abstract description 3
- 231100000989 no adverse effect Toxicity 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 6
- 239000012459 cleaning agent Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 210000003127 knee Anatomy 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- -1 calcium salts) Chemical class 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 1
- KWYJDIUEHHCHCZ-UHFFFAOYSA-N 3-[2-[bis(2-carboxyethyl)amino]ethyl-(2-carboxyethyl)amino]propanoic acid Chemical compound OC(=O)CCN(CCC(O)=O)CCN(CCC(O)=O)CCC(O)=O KWYJDIUEHHCHCZ-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical compound O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 230000021148 sequestering of metal ion Effects 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、浴室内の浴槽、湯桶、腰掛、すのこ或は洗い
場に付着している汚れ、特に湯垢汚れに対して優れた洗
浄効果を有し、浴室内の材質に対して悪影響のない、マ
イルドな中性の浴室用洗浄剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention has an excellent cleaning effect on stains, especially scale stains, attached to bathtubs, bathtubs, seats, grates, or washing areas in bathrooms. This invention relates to a mild and neutral bathroom cleaning composition that does not have any adverse effects on materials in the bathroom.
従米艮権
浴室内の汚れは、脂肪酸金属塩（主としてカルシウム塩
）、遊離脂肪酸、グリセライド、含窒素化合物等の有機
物や泥等の無機物の混合したものから成っている。Dirt in the bathroom consists of a mixture of organic substances such as fatty acid metal salts (mainly calcium salts), free fatty acids, glycerides, nitrogen-containing compounds, and inorganic substances such as mud.
従来、このような湯垢汚れを除去する洗浄剤としては、
酸物質としてのヒドロキシカルボン酸と界面活性剤およ
び水溶性溶剤とを組合せた酸性洗浄剤（特開昭５２−７
７１１１号公報）や、有機アミンに界面活性剤と溶剤と
を配合したアルカリ洗浄剤（特開昭４９−２９３０３号
公報）が知られている。Conventionally, cleaning agents for removing such scale stains include:
An acidic cleaning agent that combines hydroxycarboxylic acid as an acid substance, a surfactant, and a water-soluble solvent (Japanese Patent Application Laid-Open No. 52-7
7111) and an alkaline cleaning agent containing an organic amine, a surfactant, and a solvent (Japanese Patent Application Laid-open No. 49-29303) are known.
しかしながら、酸性洗浄剤は汚垢除去効果はあるものの
、ホーロー製浴槽、タイル目地、金属などの耐酸性の良
くない浴室内の材質を傷めるという欠点があった。一方
、アルカリ洗浄剤は、汚れの除去効果および材質への影
響の点で不十分であるという欠点があった。However, although acidic cleaning agents have the effect of removing dirt, they have the disadvantage of damaging materials in the bathroom that are not acid resistant, such as enamel bathtubs, tile joints, and metal. On the other hand, alkaline cleaning agents have the drawback of being insufficient in terms of dirt removal effects and effects on materials.
さらに、特開昭５２−７６３０８号公報、同５３−３５
７１０号公報、同５４−１．５８４０９号公報、同５６
−２２３９７号公報、同５７−２８１９９号公報、同６
０−５５０９８号公報、同６０−１４４３９８号公報に
は、界面活性剤とキレ−１〜剤との組合せ、および、界
面活性剤とキレ−１・剤と溶剤を組合せた浴室用洗浄剤
が開示されている。Furthermore, Japanese Patent Application Laid-open No. 52-76308, No. 53-35
No. 710, No. 54-1.58409, No. 56
-22397 Publication, Publication No. 57-28199, Publication No. 6
Publications No. 0-55098 and No. 60-144398 disclose bathroom cleaners containing a combination of a surfactant and a Clean-1 agent, and a combination of a surfactant, a Clean-1 agent, and a solvent. has been done.
しかし、これら公報に示された実施例においては中性で
十分なる組成は見当らず、また、浴室内の材質への影響
を考慮したものではなかった。例えば、特開昭５２−７
６３０８号公報には、界面活性剤、ニトリロトリ酢酸類
、エチレンジアミン四酢酸類および低分子量ポリカルボ
ン酸アルカリ金属塩を含む浴場洗浄組成物が示され、後
３者の相剰的なキレート能向上効果が記載されているが
、中性でも優れた洗浄効果を示す具体的な組成は何ら示
唆されていない。また、特開昭５３−３５７１０号公報
には、エチレンジアミン四酢酸などの金属イオン封鎖剤
、陰イオン界面活性剤、グリコール溶剤を含みｐＨ４，
５〜７．５の浴室用洗浄剤組成物が示されているが、実
施例ではナトリウム塩の形で使用されており、しかもｐ
１１５と酸性領域にある。このような組成物をそのまま
中性洗浄剤として使用しようとしても、満足のいく結果
は得られない。However, in the examples shown in these publications, a sufficiently neutral composition was not found, and the influence on the materials in the bathroom was not taken into consideration. For example, JP-A-52-7
6308 discloses a bath cleaning composition containing a surfactant, a nitrilotriacetic acid, an ethylenediaminetetraacetic acid, and an alkali metal salt of a low molecular weight polycarboxylic acid, and the latter three have a mutually beneficial effect of improving chelating ability. However, there is no suggestion of a specific composition that exhibits an excellent cleaning effect even in neutrality. In addition, JP-A No. 53-35710 discloses a metal ion sequestering agent such as ethylenediaminetetraacetic acid, an anionic surfactant, and a glycol solvent with a pH of 4.
5 to 7.5 are shown, but in the examples they are used in the form of the sodium salt, and p
115, which is in the acidic range. Attempts to use such compositions as they are as neutral detergents do not yield satisfactory results.
明が一決しようとする課題
本発明は、浴槽内の湯垢汚れに対して優れた洗浄力を示
し、しがも、浴室内の材質に対して悪影響のないマイル
１−で中性の浴室用洗浄剤組成物を提供するものである
。Problems to be solved by the present invention The present invention is a neutral bathroom product that exhibits excellent cleaning power against scale stains in bathtubs and has no negative impact on the materials used in bathrooms. A cleaning composition is provided.
発明の構成
本発明の浴室用洗剤組成物は、以下の（Ａ、）および（
Ｂ）成分を含み、中性であることを特徴とする。Structure of the Invention The bathroom detergent composition of the present invention comprises the following (A,) and (
B) component and is characterized by being neutral.
（Ａ）下記一般式（１）〜（ｍ）で表されるアミノカル
ボン酸の少なくとも１つのカルボキシル基がカリウム塩
またはアンモニウム塩である洗浄成分：０．５〜２０重
量％。(A) A cleaning component in which at least one carboxyl group of an aminocarboxylic acid represented by the following general formulas (1) to (m) is a potassium salt or an ammonium salt: 0.5 to 20% by weight.
〔式中、Ａ、Ｂは次のものを示す。[In the formula, A and B represent the following.
Ａ ニーＣＨ２Ｃ０ＯＨまたは−Ｃ２Ｈ４Ｃ００ＨＢニ
ーＣＩ（□Ｃ０ＯＨ，−Ｃ，，Ｈ４０Ｈ１−Ｃ７Ｈ４Ｎ
（ＣＨ２ＣＯＯ１＋）２または
−Ｃ２Ｈ４Ｎ （Ｃ；Ｈ２Ｃ０ＯＨ）Ｃ２Ｈ４Ｎ （Ｃ
Ｈ２ＣＯＯＨ）、、 〕（Ｂ）下記一般式（ＩＶ）で表
わされる溶剤二０．５〜２０重量％。A knee CH2C0OH or -C2H4C00HB knee CI (□C0OH, -C,,H40H1-C7H4N
(CH2COO1+)2 or -C2H4N (C;H2C0OH)C2H4N (C
(B) 0.5 to 20% by weight of a solvent represented by the following general formula (IV).
Ｉ ○ （式中、Ｒは炭素数１〜３のアルキル基を示す。） 以下、本発明についてさらに詳細に説明する。I ○ (In the formula, R represents an alkyl group having 1 to 3 carbon atoms.) The present invention will be explained in more detail below.
（Ａ）成分としては、次の一般式（１）〜（ＴＩＩ）で
表されるアミノカルボン酸のカルボキシル基の少なくと
も１つがカリウム塩またはアンモニウム塩であるものが
、単独あるいは２種以上併用して用いられる。As component (A), aminocarboxylic acids represented by the following general formulas (1) to (TII) in which at least one carboxyl group is a potassium salt or an ammonium salt may be used alone or in combination of two or more. used.
〔式中、Ａ、Ｂは次のものを示す。[In the formula, A and B represent the following.
Ａ ニーＣｔ（、、Ｃ００ｔｌまたは−Ｃ，，１１，ｃ
ＯＯＨＢ ニーＣＩｌ、Ｃ００Ｈ１−Ｃ７Ｈ４０Ｈ，−
Ｃ２Ｈ４Ｎ（ＣＨ７ＣＯＯ１１）２または
−Ｃ、Ｈ４Ｎ（Ｃ１１２ＣＯＯＩイ）ｃ 、＋（４Ｎ
（Ｃｌ ２ｃｏｏＵ ２’Ｊ（Ａ）成分のアミノカルボ
ン酸の代表例としては、エチレンジアミンテトラ酢酸、
ジエチレントリアミンペンタ酢酸、Ｎ−ヒドロキシエチ
ルエチレンジアミントリ酢酸、エチレンジアミンテトラ
プロピオン酸、トリエチレンテ［−ラミンヘキザ酢酸、
エチレングリコールジエチルエーテルシアミンチ１〜う
酢酸、シクロヘキサン−１゜２−シアミンチ１〜う酢酸
などが例示できる。A knee Ct(,,C00tl or -C,,11,c
OOHB Knee CIl, C00H1-C7H40H,-
C2H4N(CH7COO11)2 or -C, H4N(C112COOIi)c, +(4N
(Representative examples of the aminocarboxylic acids of the Cl 2cooU 2'J (A) component include ethylenediaminetetraacetic acid,
diethylenetriaminepentaacetic acid, N-hydroxyethylethylenediaminetriacetic acid, ethylenediaminetetrapropionic acid, triethylenete[-laminhexaacetic acid,
Examples include ethylene glycol diethyl ether cyaminthi-1-acetic acid, and cyclohexane-1°2-cyaminthi-1-acetic acid.
これらアミノカルボン酸は、酸の形で配合したのち、水
酸化カリウムや水酸化アンモニウムなどにより中和して
少なくとも一部を塩とじてもよいし、予めカルボキシル
基の少なくとも１つをカリウム塩またはアンモニウム塩
としたのち配合してもよい。These aminocarboxylic acids may be blended in the form of an acid and then neutralized with potassium hydroxide or ammonium hydroxide to convert at least a portion into a salt, or at least one of the carboxyl groups may be preliminarily converted into a potassium salt or ammonium hydroxide. It may be mixed after being made into salt.
（Ａ）成分は、組成物中に０．５〜２０重量％、好まし
くは」−〜１０重量％含まれるように配合される。この
配合量が０．５重量％未満では洗浄力が不十分であり、
一方、２０重量％を超えて配合しても、著しい配合効果
が認められない。Component (A) is blended so that the composition contains 0.5 to 20% by weight, preferably 10% by weight. If this amount is less than 0.5% by weight, the cleaning power will be insufficient,
On the other hand, even if it is blended in an amount exceeding 20% by weight, no significant blending effect is observed.
（Ｂ）成分の溶剤としては、下記一般式（ＴＶ）で表さ
れるものが、単独であるいは２種以上併用して用いられ
る。As the solvent for component (B), those represented by the following general formula (TV) may be used alone or in combination of two or more.
（式中、Ｒは炭素数１〜３のアルキル基を示す。）
（Ｂ）成分の溶剤は、１，３−ジアルキル−２−イミダ
ゾリジノンであり、代表例として、１゜３−ジメチル−
２−イミダゾリジノン、］−２３＝７−
−ジエチルー２−イミダゾリジノンなどが例示できる。(In the formula, R represents an alkyl group having 1 to 3 carbon atoms.) The solvent of component (B) is 1,3-dialkyl-2-imidazolidinone, and a typical example is 1゜3-dimethyl-
Examples include 2-imidazolidinone, ]-23=7-diethyl-2-imidazolidinone, and the like.
（Ｂ）成分の溶剤は、組成物中に０．５〜２０重量％、
好ましくは１〜１５重量％配合される。The solvent of component (B) is 0.5 to 20% by weight in the composition,
Preferably, it is blended in an amount of 1 to 15% by weight.
この配合量が０．５重量％未満では洗浄力が不十分であ
り、一方、２０重量％を越えて添加しても著しい配合効
果は認められず、組成物の安定性が劣化する。If the blending amount is less than 0.5% by weight, the detergency will be insufficient, while if it is added in excess of 20% by weight, no significant blending effect will be observed and the stability of the composition will deteriorate.
本発明の浴室用洗浄剤組成物は、上記（Ａ）および（Ｂ
）成分を必須成分として配合してｐＨを中性とすること
により得られるが、さらに必要に応じて任意成分を配合
することもできる。The bathroom cleaning composition of the present invention comprises the above (A) and (B).
) can be obtained by blending the components as essential components to make the pH neutral, but optional components can also be further blended as necessary.
これら任意成分としては、界面活性剤、ハイドロトロー
プ剤、殺菌剤、防腐および防カビ剤、色素、香料、紫外
線吸収剤などを挙げることができる。Examples of these optional ingredients include surfactants, hydrotropes, bactericidal agents, antiseptic and antifungal agents, pigments, fragrances, and ultraviolet absorbers.
発明の効果
本発明の浴室用洗浄剤組成物によれば、（Ａ）特定のア
ミノカルボン酸塩と（Ｂ）特定の溶剤とを配合すること
により、これら各成分が相剰的に作用し、浴室内の湯垢
汚れの主成分である脂肪酸金属塩をすみやかに分解し、
被洗物に対する汚垢の付着力を低下させることができ、
浴室内の浴槽、湯桶、腰掛、洗い場等に強固に付着した
湯垢に対して極めて優れた洗浄効果を示す。Effects of the Invention According to the bathroom cleaning composition of the present invention, by blending (A) a specific aminocarboxylic acid salt and (B) a specific solvent, these components act mutually, Quickly decomposes fatty acid metal salts, which are the main components of bathroom scale stains,
It can reduce the adhesion of dirt to the items being washed,
It exhibits an extremely excellent cleaning effect on limescale firmly attached to bathtubs, bathtubs, seats, washing areas, etc. in bathrooms.
しかも、中性領域で優れた相剰効果を発揮するため、ホ
ーロー製浴槽、タイル目地、金属等の耐酸性の良くない
浴室内の材質に悪影響を与えることが防止される。Moreover, since it exhibits an excellent mutual effect in the neutral region, it is prevented from adversely affecting materials in the bathroom that have poor acid resistance, such as enamel bathtubs, tile joints, and metals.
以下、実施例により本発明の効果をより具体的に説明す
るが、それに先だって実施例における洗浄剤組成物の評
価方法について示す。Hereinafter, the effects of the present invention will be explained in more detail with reference to Examples, but first, a method for evaluating the cleaning composition in the Examples will be described.
（１）湯垢汚れに対する洗浄力
こすった程度では容易に除去できない
湯垢汚れが付着したポリプロピレン製の風呂桶（２ケ月
使用品）に、液体洗浄剤組成物（原液）をふりかけ、桶
表面を
約５００ ｇの荷重でウレタン製のスポンジにて５回往
復してこすり、汚れの除去状態を視覚判定する。(1) Cleaning power against scale stains Sprinkle liquid cleaning composition (undiluted solution) on a polypropylene bathtub (used for 2 months) that has scale stains that cannot be easily removed by rubbing, and clean the surface of the bath with approximately 500% cleaning power. Rub it back and forth 5 times with a urethane sponge under a load of 100 g, and visually evaluate the state of dirt removal.
５点：汚れ落ちが非常に良好
４点：汚れ落ちが良好
３点：汚れ落ちにむらがある
２点：若干汚れが落ちる程度
１点：はとんど汚れが落ちない
（２）被洗物に対する影響
浴室のタイル目地および戸の材質であ
るアルミニウムに対する洗浄剤組成物の影響を調べるた
め、目地板（産生セメント■製の白色セメント）および
アルミニウムを洗浄剤組成物に１０分間浸漬し、水洗後
その状態を視覚判定する。5 points: Stain removal is very good 4 points: Stain removal is good 3 points: Stain removal is uneven 2 points: Slight stain removal 1 point: Dirt does not come off very often (2) Item to be washed In order to investigate the effect of a cleaning composition on bathroom tile joints and aluminum, which is the material of doors, joint boards (white cement manufactured by Seishin Cement ■) and aluminum were immersed in the cleaning composition for 10 minutes, and after washing with water. Visually judge the condition.
Ｏ：まったく影響を受けない
△：わずかに溶解するか腐食する
×：溶解し、目地の形がくずれる
実施例１
下表に示す組成の各洗浄剤組成物を調製し、湯垢汚れに
対する洗浄力、被洗物に対する影響を評価した。結果を
表−１に示す。O: Not affected at all △: Slightly dissolved or corroded ×: Dissolved and the shape of the joint is destroyed Example 1 Each cleaning composition having the composition shown in the table below was prepared, and the cleaning power against scale stains, The effect on the items to be washed was evaluated. The results are shown in Table-1.
実施例２
表−２に示す組成の各洗浄剤組成物を調製し、湯垢に対
する洗浄力、被洗物に対する影響を評価した。結果を表
−２に示す。Example 2 Each cleaning agent composition having the composition shown in Table 2 was prepared, and its detergency against hot water scale and its influence on items to be washed were evaluated. The results are shown in Table-2.
（以下余白）(Margin below)
Claims (1)
ノノカルボン酸の少なくとも１つのカルボキ シル基がカリウム塩またはアンモニウム塩 である洗浄成分：０．５〜２０重量％、 ▲数式、化学式、表等があります▼（ I ） ▲数式、化学式、表等があります▼（II） ▲数式、化学式、表等があります▼（III） 〔式中、Ａ、Ｂは次のものを示す。 Ａ：−ＣＨ＿２ＣＯＯＨまたは−Ｃ＿２Ｈ＿４ＣＯＯＨ
Ｂ：−ＣＨ＿２ＣＯＯＨ、−Ｃ＿２Ｈ＿４ＯＨ、−Ｃ＿
２Ｈ＿４Ｎ（ＣＨ＿２ＣＯＯＨ）＿２または −Ｃ＿２Ｈ＿４Ｎ（ＣＨ＿２ＣＯＯＨ）Ｃ＿２Ｈ＿４Ｎ
（ＣＨ＿２ＣＯＯＨ）＿２〕（Ｂ）下記一般式（IV）で
表わされる溶剤：０．５〜２０重量％、 ▲数式、化学式、表等があります▼（IV） （式中、Ｒは炭素数１〜３のアルキル基を 示す。） を含有することを特徴とする中性の浴室用洗浄剤組成物
。[Claims] 1. (A) A cleaning component in which at least one carboxyl group of an aminocarboxylic acid represented by the following general formulas (I) to (III) is a potassium salt or an ammonium salt: 0.5 to 20% by weight, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (I) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (II) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (III) [In the formula, A, B indicates the following. A: -CH_2COOH or -C_2H_4COOH
B: -CH_2COOH, -C_2H_4OH, -C_
2H_4N(CH_2COOH)_2 or -C_2H_4N(CH_2COOH)C_2H_4N
(CH_2COOH)_2] (B) Solvent represented by the following general formula (IV): 0.5 to 20% by weight, ▲ Numerical formulas, chemical formulas, tables, etc. are available ▼ (IV) (In the formula, R has 1 to 1 carbon atoms 3) A neutral bathroom cleaning composition comprising:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13357088A JPH01301800A (en) | 1988-05-31 | 1988-05-31 | Detergent composition for bathroom |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13357088A JPH01301800A (en) | 1988-05-31 | 1988-05-31 | Detergent composition for bathroom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01301800A true JPH01301800A (en) | 1989-12-05 |
Family
ID=15107898
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13357088A Pending JPH01301800A (en) | 1988-05-31 | 1988-05-31 | Detergent composition for bathroom |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01301800A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000129297A (en) * | 1998-10-29 | 2000-05-09 | Lion Corp | Neutral liquid detergent composition |
| JP2001311228A (en) * | 2000-04-27 | 2001-11-09 | Mitsubishi Rayon Co Ltd | Protective material for joint and protective method |
-
1988
- 1988-05-31 JP JP13357088A patent/JPH01301800A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000129297A (en) * | 1998-10-29 | 2000-05-09 | Lion Corp | Neutral liquid detergent composition |
| JP2001311228A (en) * | 2000-04-27 | 2001-11-09 | Mitsubishi Rayon Co Ltd | Protective material for joint and protective method |
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