JPH01292188A - Synthetic leather - Google Patents
Synthetic leatherInfo
- Publication number
- JPH01292188A JPH01292188A JP11985088A JP11985088A JPH01292188A JP H01292188 A JPH01292188 A JP H01292188A JP 11985088 A JP11985088 A JP 11985088A JP 11985088 A JP11985088 A JP 11985088A JP H01292188 A JPH01292188 A JP H01292188A
- Authority
- JP
- Japan
- Prior art keywords
- leather
- resin
- synthetic leather
- hollow particles
- natural leather
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002649 leather substitute Substances 0.000 title claims abstract description 16
- 239000010985 leather Substances 0.000 claims abstract description 22
- 239000002245 particle Substances 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 230000005484 gravity Effects 0.000 claims abstract description 8
- 239000005388 borosilicate glass Substances 0.000 claims abstract description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract description 2
- 238000009413 insulation Methods 0.000 abstract 1
- 229920005749 polyurethane resin Polymers 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 description 5
- 239000004814 polyurethane Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 241000283690 Bos taurus Species 0.000 description 1
- 241000283707 Capra Species 0.000 description 1
- 241000283086 Equidae Species 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 241000975357 Salangichthys microdon Species 0.000 description 1
- 241000282887 Suidae Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、天然皮革の微粉と樹脂を含む合成皮革の改良
に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to the improvement of synthetic leather containing fine powder of natural leather and resin.
上記合成皮革は、肌ざわり、しなやかさ、自然の風合、
吸放湿性、非帯電性などにおいて天然皮革と同等の特性
を備えさせることができ、かつ、耐水性、耐久性、加工
性、耐菌性などにおいて天然皮革よりも優れた特性を備
えさせることができる、有用な素材である。The above synthetic leather has a good feel, suppleness, natural texture,
It is possible to provide properties equivalent to natural leather in terms of moisture absorption and desorption properties, non-static properties, etc., and properties superior to natural leather in terms of water resistance, durability, workability, antibacterial properties, etc. It is a useful material.
従来、天然皮革の微粉とポリウレタンの混合物から成っ
ていた。Traditionally, it consists of a mixture of natural leather fines and polyurethane.
しかし、ポリウレタンの比重が１．２で割合に大きいた
め、天然皮革の微粉とポリウレタンの混合物の嵩比重が
０．３８〜０．５０ｇ／ｃｃ程度となり、衣類などの用
途には、−層軽量化することが要望されていた。However, since the specific gravity of polyurethane is relatively large at 1.2, the bulk specific gravity of the mixture of fine natural leather powder and polyurethane is about 0.38 to 0.50 g/cc, which is not suitable for applications such as clothing. It was requested to do so.
本発明の目的は、天然皮革の微粉と樹脂を含む合成皮革
を、衣類などの用途に好適な十分に軽いものに改良し、
しかも、保温性の向上を併せ図れるようにする点にある
。The purpose of the present invention is to improve synthetic leather containing fine powder of natural leather and resin into a sufficiently light material suitable for use in clothing, etc.
Moreover, it is possible to improve heat retention at the same time.
本発明の特徴構成は、天然皮革の微粉と樹脂の混合物に
微小中空粒子を含有させたことにあり、その作用効果は
次の通りである。The characteristic structure of the present invention is that a mixture of natural leather fine powder and resin contains microscopic hollow particles, and the effects thereof are as follows.
つまり、微小中空粒子の嵩比重は、例えば粒径１０〜２
５０μｍのホウケイ酸ガラス製の場合に０．１５〜０．
１９ｇ／ＣＣ程度というように、天然皮革の微粉とポリ
ウレタンの混合物の嵩比重（０，３８〜０、５０ｇ／ｃ
ｃ程度） よりも十分に小さくできるのであり、したが
って、適量の微小中空粒子を含有させることによって、
天然皮革の微粉と樹脂の混合物の特性を損うこと無く、
合成皮革の軽量化を十分に図れる。In other words, the bulk specific gravity of the micro hollow particles is, for example, a particle size of 10 to 2.
0.15 to 0.0 in the case of 50 μm borosilicate glass.
The bulk specific gravity of the mixture of natural leather fine powder and polyurethane is about 19g/CC (0.38~0.50g/c).
Therefore, by containing an appropriate amount of micro hollow particles,
without impairing the properties of the mixture of natural leather fine powder and resin.
The weight of synthetic leather can be sufficiently reduced.
その上、微小中空粒子に封入されている気体の断熱作用
によって、合成皮革の保温性を十分に向上できる。Furthermore, the heat retention properties of the synthetic leather can be sufficiently improved due to the heat insulating effect of the gas enclosed in the micro hollow particles.
その結果、天然皮革の微粉と樹脂を含む合成皮革の特性
を十分に活かしながら、合成皮革の軽量化と保温性向上
を十分に図れ、衣類などの用途に一段と優れた合成皮革
を提供できるようになった。As a result, we have been able to make full use of the characteristics of synthetic leather, which contains fine powder from natural leather and resin, while sufficiently reducing the weight and improving heat retention of synthetic leather, making it possible to provide synthetic leather that is even better for uses such as clothing. became.
次に実施例を示す。 Next, examples will be shown.
図面に示すように、天然皮革の微粉（１）、樹脂（２）
及び微小中空粒子（３）を十分に分散した状態に混合し
、その混合物を成型して、シート状など適当な形状の合
成皮革を形成しである。As shown in the drawing, natural leather fine powder (1), resin (2)
and fine hollow particles (3) are mixed in a sufficiently dispersed state, and the mixture is molded to form synthetic leather in an appropriate shape such as a sheet shape.
天然皮革は、牛、豚、山羊、羊、馬などの天然皮、又は
、その天然皮をなめし処理して得た革である。Natural leather is the natural hide of cows, pigs, goats, sheep, horses, etc., or the leather obtained by tanning the natural hides.
天然皮革の微粉（１）は、一般に大部分が４０μｍ以下
であり、天然皮革の細片化処理、加熱膨潤処理、乾燥処
理、微粉砕処理などによって造られる。The natural leather fine powder (1) generally has a size of 40 μm or less in most cases, and is produced by processing natural leather into pieces, heating and swelling, drying, pulverizing, etc.
樹脂（２） は、塩化ビニルなどの各種熱可塑性樹脂、
ポリウレタンなどの各種熱硬化性樹脂、その他の適当な
合成樹脂から選択する。Resin (2) is various thermoplastic resins such as vinyl chloride,
Select from various thermosetting resins such as polyurethane and other suitable synthetic resins.
微小中空粒子（３） は、例えば各種のガラス製やシリ
カ等のセラミックス製などの密閉状又は通気性の微小中
空球状粒子から成り、−例を次に示す。The micro hollow particles (3) are made of, for example, airtight or air-permeable micro hollow spherical particles made of various types of glass or ceramics such as silica, examples of which are shown below.
（イ） ホウケイ酸ガラスから成り、嵩比重が０．１５
〜０．１９ｇ／ＣＣ程で、大部分の粒径が１０〜２５０
μｍで、平均壁厚が１．５〜２．０μｍのもの。(a) Made of borosilicate glass and has a bulk specific gravity of 0.15.
〜0.19g/CC, most particle size is 10~250
μm, with an average wall thickness of 1.5 to 2.0 μm.
（０）シラスを原料とし、嵩比重が０．１７〜０．３７
ｇ／ｃｃ程で、大部分の粒径が７５μｍ以下又は２００
μｍ以下のもの。(0) Made from whitebait, bulk specific gravity is 0.17 to 0.37
g/cc, most of the particle size is 75μm or less or 200μm or less
Less than μm.
微小中空粒子（３）の混入は、天然皮革の微粉（１）を
ｌｌｌ！（２）に混入する時点に対して、前又は同時又
は後のいずれでもよい。混合割合は重量比で樹脂（２）
：天然皮革の微粉（１）：微小中空粒子（３）が５：３
：２又は４：３：３程度が一般的である。The fine hollow particles (3) are mixed in with the natural leather fine powder (1)! It may be before, at the same time, or after the time of mixing in (2). The mixing ratio is resin (2) by weight.
: Natural leather fine powder (1): Micro hollow particles (3) 5:3
:2 or about 4:3:3 is common.
混合物の成型は、微小中空粒子（３） の破壊を生じる
ような強い圧縮力や剪断力が作用する成型機を使用しな
いことが望ましく、注型や塗布の後で硬化させるのが良
い。When molding the mixture, it is preferable not to use a molding machine that applies strong compressive force or shearing force that could cause destruction of the micro hollow particles (3), and it is preferable to harden the mixture after casting or coating.
成型品の表面仕上げは適当に実施でき、例えば型押し、
エナメル加工、表面研削などを用途に見合って施し、ま
た、合成皮革の用途はいかなるものでもよい。The surface finishing of the molded product can be done appropriately, such as embossing,
Enamel processing, surface grinding, etc. are applied depending on the purpose, and the synthetic leather can be used for any purpose.
図面は本発明の実施例を示す拡大概念図である。
（１）・・・・・・天然皮革の微粉、（２）・・・・・
・樹脂、（３）・・・・・・微小中空粒子。The drawing is an enlarged conceptual diagram showing an embodiment of the present invention. (1)...Fine powder of natural leather, (2)...
-Resin, (3)...Minute hollow particles.
Claims (1)
中空粒子（３）を含有させてある合成皮革。 ２、前記微小中空粒子（３）はホウケイ酸ガラスから成
り、嵩比重が０．１５〜０．１９ｇ／ｃｃ程で、大部分
の粒径が１０〜２５０μｍである請求項１記載の合成皮
革。[Claims] 1. Synthetic leather in which fine hollow particles (3) are contained in a mixture of natural leather fine powder (1) and resin (2). 2. The synthetic leather according to claim 1, wherein the micro hollow particles (3) are made of borosilicate glass, have a bulk specific gravity of about 0.15 to 0.19 g/cc, and have a majority particle size of 10 to 250 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11985088A JPH01292188A (en) | 1988-05-16 | 1988-05-16 | Synthetic leather |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11985088A JPH01292188A (en) | 1988-05-16 | 1988-05-16 | Synthetic leather |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01292188A true JPH01292188A (en) | 1989-11-24 |
Family
ID=14771819
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11985088A Pending JPH01292188A (en) | 1988-05-16 | 1988-05-16 | Synthetic leather |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01292188A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1329528C (en) * | 2003-06-02 | 2007-08-01 | 罗姆和哈斯公司 | Aqueous leather treatment composition and method of use |
-
1988
- 1988-05-16 JP JP11985088A patent/JPH01292188A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1329528C (en) * | 2003-06-02 | 2007-08-01 | 罗姆和哈斯公司 | Aqueous leather treatment composition and method of use |
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