JPH01292139A - Woven fabric for preventing missed pile - Google Patents
Woven fabric for preventing missed pileInfo
- Publication number
- JPH01292139A JPH01292139A JP63119972A JP11997288A JPH01292139A JP H01292139 A JPH01292139 A JP H01292139A JP 63119972 A JP63119972 A JP 63119972A JP 11997288 A JP11997288 A JP 11997288A JP H01292139 A JPH01292139 A JP H01292139A
- Authority
- JP
- Japan
- Prior art keywords
- pile
- yarn
- heat
- melting point
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002759 woven fabric Substances 0.000 title abstract description 5
- 230000003405 preventing effect Effects 0.000 title abstract description 4
- 239000000835 fiber Substances 0.000 claims abstract description 45
- 239000004744 fabric Substances 0.000 claims abstract description 32
- 238000002844 melting Methods 0.000 claims abstract description 27
- 230000008018 melting Effects 0.000 claims abstract description 20
- 229920000642 polymer Polymers 0.000 claims abstract description 20
- 239000000853 adhesive Substances 0.000 claims description 20
- 230000001070 adhesive effect Effects 0.000 claims description 6
- 230000002265 prevention Effects 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 abstract description 4
- -1 polyethylene Polymers 0.000 abstract description 3
- 238000009941 weaving Methods 0.000 abstract description 3
- 239000004698 Polyethylene Substances 0.000 abstract description 2
- 229920000573 polyethylene Polymers 0.000 abstract description 2
- 238000009987 spinning Methods 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 description 10
- 229920000728 polyester Polymers 0.000 description 10
- 239000002131 composite material Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000000463 material Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、タオル、モケット等の立毛状のパイル糸を有
した織物に関する。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to textiles having napped pile yarns, such as towels and moquettes.
〈従来の技術〉
タオルやモケット等の織物は、−船釣に地糸と呼ばれる
基礎組織とパイル糸と呼ばれる立毛部分より出来ている
。そしてパイル糸は通常、地糸の経糸と緯糸より構成さ
れる空間に固定されている。そしてそのパイル糸の糸抜
けの程度は経糸と緯糸の織密度によって決定される。即
ち経糸と緯糸の空間の大小によって決定される。<Prior Art> Fabrics such as towels and moquettes are made up of a basic structure called ground thread and a raised part called pile thread. The pile yarn is usually fixed in a space formed by the warp and weft of the ground yarn. The degree of shedding of the pile yarn is determined by the weaving density of the warp and weft. That is, it is determined by the size of the space between the warp and weft.
従来よりこのパイル糸の糸抜けに対しているいろの対策
が行なわれている。例えば経糸又は緯糸に熱収縮糸を用
いて織物にしてから、熱処理する事により、この収縮糸
を収縮させて、経糸と緯糸の密度を上げる事によりパイ
ルの糸抜けを防止するかまたはパイル織物にしてから、
織物の裏面に熱硬化性の樹脂等でコーティングして、パ
イル糸と地糸を接着する加工を行なう事によりパイル抜
けを防止する方法がある。Conventionally, various measures have been taken to prevent this pile yarn from falling out. For example, by making a fabric using heat-shrinkable yarn for the warp or weft, and then heat-treating it, you can shrink the shrinkable yarn and increase the density of the warp and weft to prevent yarns from falling out of the pile, or to create a pile fabric. After that,
There is a method of preventing pile shedding by coating the back side of the fabric with a thermosetting resin or the like to bond the pile yarn and ground yarn.
〈発明が解決しようとする課題〉
熱収縮糸を使用したパイル織物は、生地の単位面積当り
の重量が熱処理加工後の収縮糸の収縮により、大きくな
り重たいパイル織物になる。<Problems to be Solved by the Invention> In pile fabrics using heat-shrinkable threads, the weight per unit area of the fabric increases due to shrinkage of the shrinkable threads after heat treatment, resulting in a heavy pile fabric.
また、地糸の経糸と緯糸が緊密な構造となる為、硬い織
物になり、ドレープ性が悪い織物となる。In addition, since the warp and weft of the ground yarn have a tight structure, the fabric becomes stiff and has poor drape properties.
パイル裏面に樹脂接着したものは、洗濯等を幾度も実施
する場合には、樹脂が脱落したり、両面にパイル糸を有
するパイル織物の様なものには使用出来ないという欠点
があった。本発明は、この様なパイル糸の数種の併置を
防止した糸抜け防止の効果によるパイル抜け防止織物を
提供せんとするものである。Those with resin bonded to the back side of the pile have the disadvantage that the resin may fall off when washed many times or the like, and that they cannot be used for items such as pile fabrics that have pile threads on both sides. The present invention aims to provide a fabric that prevents pile yarns from coming out by preventing several types of pile yarns from being juxtaposed.
く課題を解決するための手段〉
本発明は乾熱の180℃以下の温度で少なくとも一部が
溶融する熱接着性繊維を含む紡績糸をパイル織物の地糸
に使用した事を特徴とするパイル抜け防止織物である。Means for Solving the Problems The present invention provides a pile fabric characterized in that a spun yarn containing heat-adhesive fibers that at least partially melts at a dry heat temperature of 180° C. or lower is used as the ground yarn of a pile fabric. It is a fabric that prevents it from coming off.
まず熱接着性繊維は乾熱の180℃以下の温度で一部溶
融することが必須である。これは通常、パイル織物を染
色整理加工する際の加熱処理を考えf二時の一般的な温
度を考慮しkものであり、勿論さらに高温で処理するこ
とら考えられる。但し、その様な温度で処理する時パイ
ル織物の他への悪影響、例えば風合いが硬くなる、染色
堅牢度が低下するなどがもたらされる。好ましくは、9
0℃〜130℃で溶融する部分をもつ繊維である。該熱
接着性繊維は低融点ポリマー100%からなる繊維、ま
たは他のその低融点ポリマーより高い融点のポリマーと
の芯鞘構造(第2図)もしくはサイドバイサイドの構造
(第3図)のものが好ましい。前者の繊維では鞘部に低
融点ポリマーを配する。第2図、第3図中において5は
低融点ポリマー、6は高融点ポリマーを示す。尚このよ
うな繊維としてポリエステル等の未延伸繊維し使用可能
である。この繊維は通常の紡績糸として他の素材と混紡
したり、コアヤーンと呼ばれる芯鞘構造の2重構造糸に
して織物に使用する。First, it is essential that the heat-adhesive fiber is partially melted at a dry heat temperature of 180° C. or lower. This is usually done by taking into consideration the general temperature at f2, considering the heat treatment when dyeing and finishing pile fabrics, and of course, it can be considered that the treatment is performed at an even higher temperature. However, when treated at such temperatures, there are adverse effects on other pile fabrics, such as hardening of the texture and reduction of color fastness. Preferably 9
It is a fiber that has a portion that melts at 0°C to 130°C. The thermoadhesive fibers are preferably fibers made of 100% of a low melting point polymer, or have a core-sheath structure (Figure 2) or a side-by-side structure (Figure 3) with another polymer having a higher melting point than the low melting point polymer. . In the former type of fiber, a low melting point polymer is placed in the sheath. In FIGS. 2 and 3, 5 indicates a low melting point polymer and 6 indicates a high melting point polymer. Incidentally, undrawn fibers such as polyester can be used as such fibers. These fibers are used in textiles by blending them with other materials as ordinary spun yarns, or by making them into core-sheath dual-structure yarns called core yarns.
ここで言うコアヤーンとは複数の高融点繊維と複数の低
融点繊維とが芯鞘構造を形成している複合糸を色味する
。(第5図)
まL熱接着性繊維は、パイル織物の地糸中の2重量%以
上好ましくは15重量%以上含まメtでいることが必要
であり、2重量%以下になるとき、パイル抜け防止効果
が顕著に低下し、その役目を果たさなくなる。また熱接
着性繊維を低混合率で使用する場合には、コアヤーンと
いう紡績糸が好ましい。すなわち芯鞘構造の鞘成分に熱
接着性繊維を使用すれば、低混合率でパイル抜け防止効
果が得られる。この様にして作った紡績糸をパイル織物
の地糸の経糸、緯糸またはその両方に使用する。The core yarn referred to herein is a composite yarn in which a plurality of high-melting point fibers and a plurality of low-melting point fibers form a core-sheath structure. (Fig. 5) It is necessary that the heat-adhesive fibers should be present in a content of 2% by weight or more, preferably 15% by weight or more in the ground yarn of the pile fabric, and when it is 2% by weight or less, the pile fabric The slip-off prevention effect is significantly reduced and it no longer fulfills its role. Moreover, when using thermal adhesive fibers at a low mixing ratio, a spun yarn called core yarn is preferable. In other words, if heat-adhesive fibers are used as the sheath component of the core-sheath structure, the pile shedding prevention effect can be obtained at a low mixing ratio. The spun yarn thus produced is used for the warp, weft, or both of the ground yarns of a pile fabric.
本発明の紡績糸をパイル織物に使用した後、低融点ポリ
マーの融点より高い温度で加熱処理するとき、低融点ポ
リマーが溶融し、パイル糸を構成する繊維の一部と溶融
接着したり、溶融物質がパイル糸の一部に溶融侵入した
り、パイル糸の構成繊維の一部を被覆したり、結果とし
てパイル糸の糸抜け防止が出来る。この場合パイル織物
の地糸の密度は、収縮糸を使用しb場合の様に高密度に
なっておらずドレープ性ら良いし、樹脂接着したときの
様に洗濯処理によっても容易に脱落することらない。尚
、低融点ポリマーとしてはポリエチレン、ポリプロピレ
ン、ポリアミド、ポリエステル等の熟可塑性ポリマーや
それらの改質ポリマーなどが例示されろ。After the spun yarn of the present invention is used in a pile fabric, when it is heat-treated at a temperature higher than the melting point of the low-melting point polymer, the low-melting point polymer melts and may melt and adhere to some of the fibers constituting the pile yarn. The substance melts and penetrates into a part of the pile yarn or covers a part of the constituent fibers of the pile yarn, and as a result, it is possible to prevent the pile yarn from coming off. In this case, the density of the ground yarn of the pile fabric is not as high as in case B, since shrinkable yarn is used, and the drapability is good, and like when bonded with resin, it easily falls off when washed. No. Examples of low melting point polymers include mature plastic polymers such as polyethylene, polypropylene, polyamide, polyester, and modified polymers thereof.
第1図は本発明の織物を示す模式図で、lは熱接着性繊
維、2は非熱接着性繊維、3はこれらの繊維から戸ろ紡
績糸の地糸、4はパイル糸を示す。第2図、第3図は高
融点ポリマーと低融点ポリマーとからなる繊維の芯鞘構
造、サイドバイサイドの構造を示したものである。第4
図、第5図は本発明で用いる紡績糸の断面模式図である
。次に本発明を実施例にて詳細に説明する。FIG. 1 is a schematic diagram showing the woven fabric of the present invention, where 1 is a heat-adhesive fiber, 2 is a non-heat-adhesive fiber, 3 is a base yarn of a toro-spun yarn made from these fibers, and 4 is a pile yarn. FIGS. 2 and 3 show the core-sheath structure and side-by-side structure of a fiber made of a high melting point polymer and a low melting point polymer. Fourth
FIG. 5 is a schematic cross-sectional view of the spun yarn used in the present invention. Next, the present invention will be explained in detail with reference to Examples.
〈実施例〉
実施例1
ポリエステル/変性ポリエステルからなる芯鞘型複合繊
維(熱接着性繊推:接着湿炭130℃、芯鞘比5015
0.3デニール)を鞘糸に、ポリエステルフィラメント
を芯糸に用い几コアヤーン(芯鞘比30/70.10番
手X1本)を緯糸に用い、綿糸(30番手X2本)を経
糸に用い地糸とし、パイル糸に綿糸(40番手X2本)
を用いてタオルを織成した後、100℃×30分て染色
後!30’c〜150°CXI分間乾熱処理した。この
タオル地のパイル引抜き強力は569g/本であり優秀
な強度を示した。尚引抜き強力はパイルにフックを引掛
けてインストロンによりパイルが50mm引抜かれるま
での強力を測定した。<Example> Example 1 Core-sheath type composite fiber made of polyester/modified polyester (heat-adhesive fiber: adhesive wet carbon 130°C, core-sheath ratio 5015)
0.3 denier) as the sheath yarn, polyester filament as the core yarn, core yarn (core/sheath ratio 30/70.10 count x 1 yarn) as the weft, cotton yarn (30 count x 2 yarn) as the warp yarn, Then, add cotton thread to the pile thread (40 count x 2 threads)
After weaving the towel using , dye it at 100℃ for 30 minutes! Dry heat treatment was performed for 30'C to 150CXI minutes. The pile pulling strength of this towel fabric was 569 g/piece, indicating excellent strength. The pulling strength was determined by hooking a hook onto the pile and measuring the strength until the pile was pulled out by 50 mm using an Instron.
実施例2
ポリエステル/変性ポリエステルからなる芯鞘型複合繊
維(熱接着性繊維:接着温度130°C1芯鞘比501
50.3デニール)を鞘糸に、ポリエステル紡績糸を芯
糸に用いたコアヤーン(芯鞘比70/30.10番手X
1本)を緯糸に用い、綿糸(30番手X2本)を経糸に
用い地糸とし、パイル糸に綿糸(40番手X2本)を用
いてタオルを織成した。この後実施例1と同様に処理し
、テストした。このタオル地のパイル引抜き強力は32
6g/本であり良好な強度を示した。Example 2 Core-sheath type composite fiber consisting of polyester/modified polyester (thermally adhesive fiber: bonding temperature 130°C1 core-sheath ratio 501
50.3 denier) as the sheath yarn and polyester spun yarn as the core yarn (core/sheath ratio 70/30.10 count
A towel was woven using a cotton yarn (30 count x 2) as the weft, a cotton thread (30 count x 2) as the warp and ground yarn, and a cotton yarn (40 count x 2) as the pile yarn. Thereafter, it was treated and tested in the same manner as in Example 1. The pile pulling strength of this towel fabric is 32
The weight was 6 g/piece, indicating good strength.
実施例3
ポリエステル/変性ポリエステルからなろ芯鞘型複合繊
維(熱接着性繊成:接着温度130℃、芯鞘比5015
0.3デニール)の紡績糸(10番手X1本)を緯糸に
用い、綿糸(30番手X2本)を経糸に用い地糸とし、
パイル糸に綿糸(40番手X2本)を用いてタオルを織
成した。この後実施例1と同様に処理し、テストした。Example 3 Polyester/modified polyester core-sheath type composite fiber (thermal adhesive fiber composition: bonding temperature 130°C, core-sheath ratio 5015)
0.3 denier) spun yarn (10 count x 1 yarn) was used as the weft, cotton yarn (30 count x 2 yarn) was used as the warp, and the ground yarn was used.
A towel was woven using cotton thread (40 count x 2 threads) as the pile thread. Thereafter, it was treated and tested in the same manner as in Example 1.
このタオル地のパイル引抜き強力は500g/本であり
優秀な強度を示した。The pile pulling strength of this towel fabric was 500 g/piece, indicating excellent strength.
比較例!
綿糸(20番手X1本)を緯糸に用い、綿糸(30番手
X2本)を経糸に用い地糸とし、パイル糸に綿糸(40
番手X2本)を用いてタオルを織成した。この後実施例
1と同様に処理し、テストした。このタオル地のパイル
引抜き強力は68g/本であり、低い強度であった。Comparative example! A cotton thread (20 count x 1 piece) is used for the weft, a cotton thread (30 count x 2 pieces) is used for the warp and ground thread, and a cotton thread (40 count x 1 piece) is used for the pile thread.
A towel was woven using 2 yarns of count X). Thereafter, it was treated and tested in the same manner as in Example 1. The pile pulling strength of this toweling fabric was 68 g/piece, which was low.
〈発明の効果〉
このように本発明の熱接着性繊成を複合した繊維を地糸
に用いて、パイル繊物を作製することによりパイル糸の
抜け難い物性の良好なパイル縁物か得られる。<Effects of the Invention> As described above, by using the composite fiber of the heat-adhesive fiber of the present invention as the ground yarn to produce a pile fabric, a pile edge material with good physical properties that prevents pile yarns from coming off can be obtained. .
第1図は本発明の織物の断面模式図、第2図、第3図は
熱接着性複合繊維の断面模式図、第4図、第5図は使用
する紡績糸の断面模式図である。図中においてlは熱接
着性繊維、2は非熱接着性繊維、3は地糸紡績糸、4は
パイル糸、5は低融点ポリマー、6は高融点ポリマーを
夫々示す。
特許出願人 株式会社 り ラ しFIG. 1 is a schematic cross-sectional view of the woven fabric of the present invention, FIGS. 2 and 3 are schematic cross-sectional views of heat-adhesive composite fibers, and FIGS. 4 and 5 are schematic cross-sectional views of the spun yarn used. In the figure, 1 is a thermoadhesive fiber, 2 is a non-thermal adhesive fiber, 3 is a plain spun yarn, 4 is a pile yarn, 5 is a low melting point polymer, and 6 is a high melting point polymer. Patent applicant RiRa Shi Co., Ltd.
Claims (3)
接着性繊維と非熱接着性繊維よりなり、熱接着性繊維を
2重量%以上含有する紡績糸がパイル織物の地糸の経糸
および/または緯糸を構成し、該接着性繊維の熱処理溶
融によりパイル糸と地糸が接着したことを特徴とするパ
イル抜け防止織物。(1) The spun yarn, which is composed of heat-adhesive fibers and non-thermally-adhesive fibers that are at least partially melted under dry heat of 180°C or lower, and contains 2% or more of heat-adhesive fibers, is used in the warp of the ground yarn of pile fabrics and A pile yarn prevention fabric comprising/or weft yarns, characterized in that pile yarns and ground yarns are bonded to each other by heat treatment and melting of the adhesive fibers.
ヤーンを地糸に使用する請求項(1)記載のパイル抜け
防止織物。(2) The pile-shedding prevention fabric according to claim (1), wherein a core yarn in which the heat-adhesive fiber constitutes a sheath portion of a core-sheath structure is used as the ground yarn.
繊維かまたは低融点ポリマーとそれより融点の高いポリ
マーとからなりそれぞれが芯鞘構造もしくはサイドバイ
サイドの構造を形成している繊維からなる糸を地糸に使
用する事を特徴とする請求項(1)または(2)に記載
のパイル抜け防止織物。(3) The heat-adhesive fibers are fibers made of 100% low-melting point polymers, or yarns made of fibers made of a low-melting point polymer and a polymer with a higher melting point, each forming a core-sheath structure or a side-by-side structure. The pile-shedding prevention fabric according to claim (1) or (2), characterized in that it is used as a base thread.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63119972A JPH01292139A (en) | 1988-05-16 | 1988-05-16 | Woven fabric for preventing missed pile |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63119972A JPH01292139A (en) | 1988-05-16 | 1988-05-16 | Woven fabric for preventing missed pile |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH01292139A true JPH01292139A (en) | 1989-11-24 |
Family
ID=14774754
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP63119972A Pending JPH01292139A (en) | 1988-05-16 | 1988-05-16 | Woven fabric for preventing missed pile |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH01292139A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0728860A1 (en) * | 1995-02-22 | 1996-08-28 | Hoechst Trevira GmbH & Co. KG | Shapable and heat stabilisable textile pile article |
EP0728859A1 (en) * | 1995-02-22 | 1996-08-28 | Hoechst Trevira GmbH & Co. KG | Shapable and heat stabilisable textile loop pile fabric |
WO1997019211A1 (en) * | 1995-11-23 | 1997-05-29 | Impak Marketing Limited | Abrading material |
JP2007330427A (en) * | 2006-06-14 | 2007-12-27 | Chisso Corp | Towel having excellent pile retentivity |
WO2022138903A1 (en) * | 2020-12-25 | 2022-06-30 | 興和株式会社 | High-absorbancy towel |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5795341A (en) * | 1980-11-27 | 1982-06-14 | Toray Industries | Production of knitted fabric having hair |
JPS5930937A (en) * | 1982-08-13 | 1984-02-18 | 株式会社川島織物 | Pile sheet cloth |
JPS61146841A (en) * | 1984-12-19 | 1986-07-04 | 日産自動車株式会社 | Pile cloth |
-
1988
- 1988-05-16 JP JP63119972A patent/JPH01292139A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5795341A (en) * | 1980-11-27 | 1982-06-14 | Toray Industries | Production of knitted fabric having hair |
JPS5930937A (en) * | 1982-08-13 | 1984-02-18 | 株式会社川島織物 | Pile sheet cloth |
JPS61146841A (en) * | 1984-12-19 | 1986-07-04 | 日産自動車株式会社 | Pile cloth |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0728860A1 (en) * | 1995-02-22 | 1996-08-28 | Hoechst Trevira GmbH & Co. KG | Shapable and heat stabilisable textile pile article |
EP0728859A1 (en) * | 1995-02-22 | 1996-08-28 | Hoechst Trevira GmbH & Co. KG | Shapable and heat stabilisable textile loop pile fabric |
US5618624A (en) * | 1995-02-22 | 1997-04-08 | Hoechst Trevira Gmbh & Co. Kg | Formable, heat-stabilizable textile pile material |
US5654067A (en) * | 1995-02-22 | 1997-08-05 | Hoechst Aktiengesellschaft | Formable, heat-stabilizable textile loop pile material |
WO1997019211A1 (en) * | 1995-11-23 | 1997-05-29 | Impak Marketing Limited | Abrading material |
AU700381B2 (en) * | 1995-11-23 | 1999-01-07 | Impak Marketing Limited | Abrading material |
US6210506B1 (en) | 1995-11-23 | 2001-04-03 | Impak Marketing Limited | Abrading material |
JP2007330427A (en) * | 2006-06-14 | 2007-12-27 | Chisso Corp | Towel having excellent pile retentivity |
WO2022138903A1 (en) * | 2020-12-25 | 2022-06-30 | 興和株式会社 | High-absorbancy towel |
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