JPH01261317A - Gelatinous composition - Google Patents

Gelatinous composition

Info

Publication number
JPH01261317A
JPH01261317A JP8733588A JP8733588A JPH01261317A JP H01261317 A JPH01261317 A JP H01261317A JP 8733588 A JP8733588 A JP 8733588A JP 8733588 A JP8733588 A JP 8733588A JP H01261317 A JPH01261317 A JP H01261317A
Authority
JP
Japan
Prior art keywords
composition
water
hydrogenated
surfactant
gelatinous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP8733588A
Other languages
Japanese (ja)
Other versions
JP2660540B2 (en
Inventor
Takeshi Kondo
健 近藤
Noboru Naito
昇 内藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobayashi Kose Co Ltd
Original Assignee
Kobayashi Kose Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kobayashi Kose Co Ltd filed Critical Kobayashi Kose Co Ltd
Priority to JP63087335A priority Critical patent/JP2660540B2/en
Publication of JPH01261317A publication Critical patent/JPH01261317A/en
Application granted granted Critical
Publication of JP2660540B2 publication Critical patent/JP2660540B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q13/00Formulations or additives for perfume preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55Phosphorus compounds
    • A61K8/553Phospholipids, e.g. lecithin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/24Thermal properties
    • A61K2800/244Endothermic; Cooling; Cooling sensation

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Biophysics (AREA)
  • Molecular Biology (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

PURPOSE:To obtain the title composition extremely effective as a base material for cosmetic, etc., having excellent stability with time, characteristics of organic function such as touch in use, containing a hydrogenated phospholipid, a specific surfactant and water as active ingredients. CONSTITUTION:A gelatinous composition containing (A) a hydrogenated phospholipid (preferably one having 0-40 iodine value, most suitably phosphatidyl choline), (B) one or more surfactants selected from polyoxyethylene alkyl ether surfactant having <=12 HLB value and polyoxyethylene hardened castor oil surfactant having <=8 HLB value and (C) water. The blending ratio is >=1.0wt.%, preferably 2-10wt.% component A calculated as final concentration, >=0.1wt.%, preferably 0.5-10wt.% component B calculated as final concentration and when used, the three components are blended while stirring and made into a uniform gelatinous state to prepare a gelatinous composition.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、水素添加リン脂質、特定の界面活性剤及び水
を含有するゲル状組成物に関し、更に詳しくは、経時安
定性が良く、使用感触等の官能特性に優れ、化粧料等の
基材として好適なグル状組成物に関する。
Detailed Description of the Invention [Field of Industrial Application] The present invention relates to a gel composition containing a hydrogenated phospholipid, a specific surfactant, and water, and more specifically, it has good stability over time and is easy to use. The present invention relates to a glue-like composition that has excellent sensory properties such as feel and is suitable as a base material for cosmetics and the like.

〔従来の技術〕[Conventional technology]

リン脂質(レシチン)は、生体膜の構成成分として知ら
れており、皮膚への親和性が良く、安全性の高い天然系
の界面活性剤として利用され、特にその界面活性能から
乳化剤や、 増粘、グル化剤として用いられてきた。し
かしながら、通常リン脂質は不飽和力旨肪酸の含有量が
多いため、酸化や熱に対して不安定であったり、乳化能
やグル化能が充分でないことから、リン脂質に水素添加
した水素添加リン脂質が用いられるようになってきた。
Phospholipids (lecithin) are known as constituents of biological membranes, have good affinity for the skin, and are used as highly safe natural surfactants.In particular, due to their surfactant ability, they are used as emulsifiers and additives. It has been used as a sticky and gluing agent. However, because phospholipids usually have a high content of unsaturated fatty acids, they are unstable against oxidation and heat, and do not have sufficient emulsifying or gluing ability. Added phospholipids have come into use.

このような、水素添加リン脂質を化粧品等の基剤として
用いることに関しても種々研究がなされており、そのよ
うな研究の一例としては、水素添加リン脂質により水を
グル化して得た基剤(特開昭62−93239号)が挙
げられる。
Various studies have been conducted on the use of such hydrogenated phospholipids as bases for cosmetics, etc., and one example of such research is the use of hydrogenated phospholipids in bases obtained by gluing water with hydrogenated phospholipids ( JP-A No. 62-93239).

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

しかしながら、単に水素添加リン脂質を用いて水をグル
化する場合にはいくつかの問題がアシ、満足できるもの
ではなかった。すなわち、水素添加リン脂質と水だけで
ゲル状組成物を調製するには、通常多量の水素添加リン
脂質が必要となシ、このため例えば膜厚感やべたつきな
どリン脂質そのものの感触が強く現われ、使用感上好ま
しくなかった。また、水素添加リン脂質の使用量を減ら
すと、高純度のフオスファテゾルコリンでなければ良好
なグル状組成物が得難いという欠点がるり、さらに高温
下では安定性が悪く、粘度が低下してしまう等の欠点が
あった。このため、安定性が良く、使用感が良好で官能
特性に優れたグル状組成物の開発が望まれていた。
However, when gluing water simply using hydrogenated phospholipids, there were several problems and the results were not satisfactory. In other words, in order to prepare a gel-like composition using only hydrogenated phospholipids and water, a large amount of hydrogenated phospholipids is usually required, and therefore, the texture of the phospholipids themselves, such as a thick film or stickiness, may appear strongly. , the feeling of use was not favorable. In addition, reducing the amount of hydrogenated phospholipid used has the disadvantage that it is difficult to obtain a good glue-like composition unless it is highly purified phosphatezolcholine, and it also has poor stability and lower viscosity at high temperatures. It had some drawbacks such as being stowed away. For this reason, there has been a desire to develop a glue-like composition that has good stability, feels good in use, and has excellent organoleptic properties.

〔課題を解決するための手段〕[Means to solve the problem]

斯る実情において、本発明者らは鋭意研究を行った結果
、水素添7JO!Jン脂質、水及び特定の界面活性剤を
組み合せて用いれば、ゲル状組成物を容易に得ることが
でき、また、このグル状組成物は安定性及び使用感が良
好で、官能特性の拡がりが可能であり、化粧料等の基材
として有用であることを見出し、本発明を完成した。
Under such circumstances, the inventors of the present invention conducted intensive research and found that hydrogenated 7JO! By using a combination of lipids, water, and a specific surfactant, a gel-like composition can be easily obtained, and this gel-like composition has good stability and feeling when used, and has a wide range of sensory properties. The present invention was completed based on the discovery that the present invention is possible and useful as a base material for cosmetics and the like.

すなわち、本発明は、次の成分(6)、(ロ)及びC) (8)水素添加リン脂質、 (B) HLB値12以下のポリオキシエチレンアルキ
ルエーテル系界面活性剤及び)LB値8以下の?リオキ
シエチレン硬化とマシ油系界面活性剤から選ばれる一種
または二種以上、1c)水 を含有することを特徴とするグル状組成物を提供するも
のである。
That is, the present invention provides the following components (6), (b) and C) (8) hydrogenated phospholipid, (B) polyoxyethylene alkyl ether surfactant with HLB value of 12 or less, and) LB value of 8 or less. of? The present invention provides a glue-like composition characterized by containing one or more selected from lyoxyethylene-cured and mustard oil-based surfactants, and 1c) water.

本発明の囚成分である水素添加リン脂質としては、ヨウ
素価が0〜40のものが好ましく、例えば大豆、卵黄な
どから抽出した天然レシチンを常法に従って水素添加し
たものの他、ホスファチゾルコリン、ホスファチゾルエ
タノールアミン、ホスファチゾルイノシトール、ホスフ
ァチゾルセリン、中性リン脂質等を水素添加したものな
どが挙げられ、これらの一種または二種以上を組み合わ
せて使用することができる。特に、ホスファチゾルコリ
ン(以下「PC」 と略称することがある)が高含有量
となると、良好な結果を与えるので望ましい。本発明品
において、水素添加リン脂質は、最終濃度で1.0重量
%以上、好ましくは2〜10重量%配合される。
The hydrogenated phospholipid that is the active ingredient of the present invention preferably has an iodine value of 0 to 40. For example, in addition to hydrogenated natural lecithin extracted from soybeans, egg yolks, etc. according to a conventional method, phosphatisolcholine, Examples include hydrogenated phosphatisolethanolamine, phosphatisol inositol, phosphatisolserine, and neutral phospholipids, and one type or a combination of two or more of these can be used. In particular, a high content of phosphatisolcholine (hereinafter sometimes abbreviated as "PC") is desirable because it gives good results. In the product of the present invention, the final concentration of the hydrogenated phospholipid is 1.0% by weight or more, preferably 2 to 10% by weight.

本発明のの)成分であるポリオキシエチレンアルキルエ
ーテル系もしくは、?リオキシエテレン硬化ヒマシ油系
界面活性剤は、?リオキシエチレン付加型のものであり
、前記アルキル基は、炭素数12以上の飽和又は不飽和
の、直鎖状又は分岐状のもので、例えばラクリル、ミリ
スチル、ステアリル、オレイル、インステアリル、ベヘ
ニル基などが挙げられる。これらの)成分のうち、ポリ
オキシエチレンアルキルエーテル系界面活性剤はHLB
値が12以下、?リオキシエチレン硬化ヒマシ油系界面
活性剤はHLB値が8以下のものがそれぞれ用いられ、
これらの界面活性剤の中から一種または二種以上を選択
して使用することができる。これら界面活性剤は、グル
状組成物中に最終濃度で0.1重量%以上、好ましくは
0.5〜lO重菫%配合される。
Polyoxyethylene alkyl ether which is a component of the present invention or? What is rioxyethylene hydrogenated castor oil surfactant? It is a lyoxyethylene addition type, and the alkyl group is a saturated or unsaturated, linear or branched one having 12 or more carbon atoms, such as lacryl, myristyl, stearyl, oleyl, instearyl, behenyl group. Examples include. Among these) components, polyoxyethylene alkyl ether surfactants are HLB
The value is 12 or less? The lyoxyethylene hydrogenated castor oil surfactant used has an HLB value of 8 or less,
One or more of these surfactants can be selected and used. These surfactants are incorporated into the glue-like composition at a final concentration of 0.1% by weight or more, preferably 0.5 to 10% by weight.

本発明のグル状組成物は、水素添加リン脂質と界面活性
剤及び水を攪拌混合することにより、均一なグル状の組
成として調製でき、化粧品等の外用基材として好適に用
いることができる。
The glue-like composition of the present invention can be prepared as a uniform glue-like composition by stirring and mixing hydrogenated phospholipids, surfactants, and water, and can be suitably used as an external base material for cosmetics and the like.

本発明のゲル状組成物は、そのまま外用として用いるこ
とができるが、上記必須成分の他に、*常外用に使用可
能な成分、例えば油剤、界面活性剤(前記以外)、水溶
性高分子、多価アルコール、香料、粉体、防g剤、保湿
剤、紫外線吸収剤、薬剤、美肌用成分などを必要に応じ
て適宜配合して皮膚用1頭髪用とし、用いることもでき
る。
The gel composition of the present invention can be used externally as it is, but in addition to the above-mentioned essential ingredients, *components that can be used externally, such as oils, surfactants (other than the above), water-soluble polymers, It can also be used for skin and hair by appropriately blending polyhydric alcohol, fragrance, powder, anti-glycemic agents, humectants, ultraviolet absorbers, drugs, ingredients for skin beautification, etc. as necessary.

〔実施例〕〔Example〕

実施例1 第1表に示す組成のグル状組成物を調製し。 Example 1 A glue composition having the composition shown in Table 1 was prepared.

各々について粘度、状態(性状、グル生成)及び使用感
を評価した。なお、各グル状組成物は成分α)〜(4)
を混合して75〜85℃に加温し、ホモミキサーで10
分間攪拌した後冷却することによりs造した。結果を第
1表に示す。
The viscosity, condition (properties, glue formation), and feeling of use were evaluated for each. In addition, each glue-like composition contains components α) to (4).
Mix and heat to 75-85℃, and mix with a homomixer for 10 minutes.
The product was prepared by stirring for a minute and then cooling. The results are shown in Table 1.

以下余白 第1表から明らかな如く、本発明のゲル状組成物は、容
易にグル化ができ、安定性も良好で、しかも使用後に膜
厚感が感じられず、しつとりしており、便用感に優れた
ものであった。
As is clear from Table 1 below, the gel composition of the present invention can be easily glued, has good stability, and does not feel thick after use, and is moist. It was excellent in convenience.

実施例2 実施例1の製法に準じて、次の組成のゲル状組成物をV
@裂した。
Example 2 According to the manufacturing method of Example 1, a gel composition having the following composition was prepared by V
@Ripped.

(2) 1 、3−ブチレングリコール       
 10.0(3)グリセリン            
10.0(4)ゾメチル?リシロキサン       
     0.5(5)スクワラン         
   2.0(6)酢酸dj−α−トコフェロール  
      0.1(7)ノ9ラペン        
   適量(8)香 料       適量 0υ加水分解コラーゲン          0.10
2精製水       残量 実施例3 予じめ成分(8)を(9)で中和した以外は実施例1に
準じて、次の組成のゲル状組成物を調製した。
(2) 1,3-butylene glycol
10.0(3) Glycerin
10.0 (4) Zomethyl? resiloxane
0.5 (5) Squalane
2.0(6) dj-α-tocopherol acetate
0.1 (7) no 9 lapen
Appropriate amount (8) Fragrance Appropriate amount 0υ Hydrolyzed collagen 0.10
2 Purified Water Remaining Amount Example 3 A gel composition having the following composition was prepared according to Example 1 except that component (8) was neutralized with (9) in advance.

(2)グリセリン            5.0(3
)ゾメテル?リシロキサン        0.5(4
)ホホバ油             0.5(5)ノ
Qラベン            適量(6)香   
料                  1lifI 
 量?リオキシエチレン(2)オレイルエーテル   
 5.0(7)()LB1直7.5) (8)カルボキシビニル?リマー(1%溶fi)   
 10.0(9)水酸化ナトリウム(1%溶g)   
       3.0Ql棺製氷       残量 以上のダル状組成物は、使用感触が良く、使用後にしつ
とり感を付与でき、さらに経時安定性も良好で、品質的
に優れたものであった。
(2) Glycerin 5.0 (3
)Zometel? Resiloxane 0.5 (4
) Jojoba oil 0.5 (5) NoQ Laben appropriate amount (6) Incense
Fee 1lifI
amount? Lyoxyethylene (2) oleyl ether
5.0 (7) () LB1 straight 7.5) (8) Carboxyvinyl? Rimmer (1% soluble fi)
10.0(9) Sodium hydroxide (1% solution g)
3.0 Ql Coffin Ice Making The dul-like composition in excess of the remaining amount had a good feel in use, provided a moist feeling after use, had good stability over time, and was excellent in quality.

〔発明の効果〕〔Effect of the invention〕

本発明のダル状組成物は、ゲル生成性に優れ、安定性及
び使用感の良好なものでるる。
The dal-like composition of the present invention has excellent gel-forming properties, and has good stability and feel when used.

従って、本発明のダル状組成物は化粧品等の基材として
極めて好適に用いることができ、従来にも増して官能特
性に優れ、拡がシのある製品の提供が可能となった。
Therefore, the dal-like composition of the present invention can be very suitably used as a base material for cosmetics, etc., and it has become possible to provide a product with better sensory properties and spreadability than ever before.

以上 代理人 弁理士 有 賀 三 幸11、。that's all Agent: Patent attorney Miyuki Yuga 11.

l hl リ」 弁理士 小 野 信 夫「  ゛ し    −−1J 昭和63年6月10日l hl り」 Patent attorney Nobuo Kono “゛ し    --1J June 10, 1986

Claims (1)

【特許請求の範囲】 1、次の成分(A)、(B)及び(C) (A)水素添加リン脂質、 (B)HLB値12以下のポリオキシエチレンアルキル
エーテル系界面活性剤存びHLB値8以下のポリオキシ
エチレン硬化ヒマシ油系界 面活性剤から選ばれる一種または二種以上、(C)水 を含有することを特徴とするゲル状組成物。
[Claims] 1. The following components (A), (B) and (C) (A) hydrogenated phospholipid, (B) a polyoxyethylene alkyl ether surfactant with an HLB value of 12 or less; A gel composition characterized by containing one or more selected from polyoxyethylene hydrogenated castor oil surfactants having a value of 8 or less, and (C) water.
JP63087335A 1988-04-11 1988-04-11 Gel composition Expired - Lifetime JP2660540B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63087335A JP2660540B2 (en) 1988-04-11 1988-04-11 Gel composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63087335A JP2660540B2 (en) 1988-04-11 1988-04-11 Gel composition

Publications (2)

Publication Number Publication Date
JPH01261317A true JPH01261317A (en) 1989-10-18
JP2660540B2 JP2660540B2 (en) 1997-10-08

Family

ID=13912003

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63087335A Expired - Lifetime JP2660540B2 (en) 1988-04-11 1988-04-11 Gel composition

Country Status (1)

Country Link
JP (1) JP2660540B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010229109A (en) * 2009-03-27 2010-10-14 Kose Corp Skin care preparation or cosmetic

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS624214A (en) * 1985-07-01 1987-01-10 Shiseido Co Ltd Cosmetic

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS624214A (en) * 1985-07-01 1987-01-10 Shiseido Co Ltd Cosmetic

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010229109A (en) * 2009-03-27 2010-10-14 Kose Corp Skin care preparation or cosmetic

Also Published As

Publication number Publication date
JP2660540B2 (en) 1997-10-08

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