JPH01260084A - Deinking method for waste of printed coated paper - Google Patents

Deinking method for waste of printed coated paper

Info

Publication number
JPH01260084A
JPH01260084A JP63077993A JP7799388A JPH01260084A JP H01260084 A JPH01260084 A JP H01260084A JP 63077993 A JP63077993 A JP 63077993A JP 7799388 A JP7799388 A JP 7799388A JP H01260084 A JPH01260084 A JP H01260084A
Authority
JP
Japan
Prior art keywords
soaking
flotation
paper
raw material
deinking
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP63077993A
Other languages
Japanese (ja)
Other versions
JP2645303B2 (en
Inventor
Kazuo Ogawa
和夫 小川
Toshiharu Yatomi
弥富 俊治
Yasuyoshi Suzuki
康義 鈴木
Masahisa Okamura
岡村 昌久
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honshu Paper Co Ltd
Original Assignee
Honshu Paper Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honshu Paper Co Ltd filed Critical Honshu Paper Co Ltd
Priority to JP7799388A priority Critical patent/JP2645303B2/en
Publication of JPH01260084A publication Critical patent/JPH01260084A/en
Application granted granted Critical
Publication of JP2645303B2 publication Critical patent/JP2645303B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/64Paper recycling

Abstract

PURPOSE:To perform deinking of waste printed paper such as newspaper to give a high-quality product having improved whiteness and low bluish color, by disaggregating and roughly selecting waste printed paper and subjecting the paper to flotation and then soaking, thereby removing ink particles in high efficiency. CONSTITUTION:Waste printed paper containing printed coated paper is subjected to disaggregation, rough selection, flotation and soaking to effect the deinking of the waste paper. Preferably, the soaked material is kneaded while keeping high concentration of the raw material (i.e., >=15%) and again subjected to flotation. The soaking process is preferably carried out at a raw material concen tration of >=15% of >=1hr.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明はコート印刷故紙を脱墨再生する際に、より効率
良くイゾキ粒子を除去する方法に関する。
DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a method for more efficiently removing Izoki particles when deinking and recycling coated printing waste paper.

従来より資源の有効利用の見地から、新聞、雑誌、一般
印刷物等の印刷故紙を脱墨し、利用することが行われて
おシ、各種の脱墨方法が知られている。近年これらの印
刷故紙の中で、コート印刷故紙の増加が著しい。
BACKGROUND ART Conventionally, from the viewpoint of effective resource utilization, waste printed paper such as newspapers, magazines, and general printed matter has been deinked and used, and various deinking methods are known. In recent years, among these types of printed waste paper, there has been a remarkable increase in coated printed waste paper.

(従来の技術) 従来故紙の脱墨は、離解・粗選する工程、脱水する工程
、ソーキングする工程、離解しフローテーション又は洗
浄する工程、精選・晒等を行う工程を、この順序で行う
方法が常法であり、いずれにしてもフローテーションは
ソーキングによりインキを繊維から剥離した後、浮上し
てきたインキをフロスとして系外に排出するものであっ
た。
(Prior art) Conventionally, waste paper is deinked by performing the following steps in this order: disintegration and rough selection, dehydration, soaking, disintegration and flotation or washing, and selection and bleaching. is a conventional method, and in any case, flotation involves separating ink from fibers by soaking, and then discharging the floating ink from the system as floss.

(発明が解決しようとする問題点) しかしながらコート印刷故紙を従来の方法で脱墨すると 1)フローテーション時のインキ粒子が微細化している
ために、フローテーションの効率が低下する。
(Problems to be Solved by the Invention) However, when coated printed waste paper is deinked by the conventional method, 1) the ink particles during flotation become finer, so the flotation efficiency decreases;

2)インキ粒子の繊維表面への再付着が起り、繊維のく
すみが増える。
2) Redeposition of ink particles to the fiber surface occurs, increasing dullness of the fiber.

3)ソーキングに使用する脱墨剤、NaOH等の量が多
いため、排水のCOD負荷が高い。
3) Because the amount of deinking agent, NaOH, etc. used in soaking is large, the COD load of the wastewater is high.

等の問題がある。There are other problems.

本発明は上記したような問題を解消させ、従来よりも白
色度が高く、かつインキスペックの少ない脱墨バルブを
提供することを目的とする。
It is an object of the present invention to solve the above-mentioned problems and to provide a deinking valve that has higher whiteness and smaller ink specs than conventional ones.

(問題点を解決するための手段) すなわち本発明はコート印刷故紙を含有した印刷故紙を
離解し、粗選するA工程、離解粗選后の原料をフローテ
ーシヨンするB工程、フローテーション后の原料をソー
キングするC工程をこの順序で含むことを特徴とする、
コート印刷故紙の脱墨方法に関するものである。
(Means for Solving the Problems) That is, the present invention comprises a step A in which printed waste paper containing coated printed waste paper is disintegrated and roughly sorted, a step B in which the raw material after the disintegration and rough sorting is floated, and a step B after flotation is carried out. characterized by including step C of soaking the raw materials in this order,
This paper relates to a method for deinking coated printed waste paper.

本発明はまた、前記離解・粗選工程(人工程)、フロー
テーション工程(B工程)、ソーキング工程(C工程)
の後に、更にフローテーション工程を有するコート印刷
故紙の脱墨方法に関するものである。
The present invention also provides the above-mentioned defibration/rough selection process (human process), flotation process (B process), and soaking process (C process).
The present invention also relates to a method for deinking coated printed waste paper, which further includes a flotation step.

本発明はまた、前記離解・粗選工程(人工程)、フロー
テーション工程(B工程)、ソーキング工程(C工程)
の後に、原料濃度15qb(絶乾重量係、以下同じ)以
上の高濃度のまゝニーデイングを行う二−ディング工程
を有する、コート印刷故紙の脱墨方法に関するものであ
る。
The present invention also provides the above-mentioned defibration/rough selection process (human process), flotation process (B process), and soaking process (C process).
The present invention relates to a method for deinking coated printed waste paper, which has a subsequent step of kneading at a high raw material concentration of 15 qb (absolute dry weight) or higher (the same applies hereinafter).

更にま九本発明は前記離解・粗選工程(人工程)、フロ
ーテーション工程(B工程)、ソーキング工程(C工程
)の後に原料濃度15%以上の高濃度のまゝニーデイン
グを行う二−ディング工程と、その後にフローテーシヨ
ン工程を有するコート印刷故紙の脱墨方法に関するもの
である。
Furthermore, the present invention provides a second process in which kneading is performed while maintaining the raw material concentration at a high concentration of 15% or more after the disintegration/rough selection process (manual process), flotation process (B process), and soaking process (C process). The present invention relates to a method for deinking coated printed waste paper, which has a process followed by a flotation process.

本発明は上記したように、従来常識であったソーキング
后のフローテーシヨンを、ソーキング前に行うことに特
徴があシ、この方法は印刷されたコート紙の脱墨にこそ
有効なものである。
As mentioned above, the present invention is characterized by performing floatation after soaking, which was conventionally common knowledge, before soaking, and this method is effective only for deinking printed coated paper. .

コート紙は通常基材である紙の上に、顔料とバインダー
を主成分とする塗料を塗布乾燥したものであシ、コート
紙に印刷されたインキは基材である紙の繊維に付着する
よシも、コート層に固着している割合が多い。従ってこ
のようなコート紙を離解した場合、インキ粒子は微細化
せずに塗料に付着して、比較的大きな粒子のままで存在
するものが多い。
Coated paper is usually made by coating a base paper with a paint containing pigments and a binder and drying it.The ink printed on coated paper adheres to the fibers of the base paper. There is also a large proportion of silica that is fixed to the coating layer. Therefore, when such coated paper is disintegrated, the ink particles often adhere to the paint without becoming fine and remain relatively large particles.

常法によると、この原料をソーキングするが、ソーキン
グは苛性ソーダ、ケイ酸ソーダ、界面活性剤等の脱墨薬
品の存在下で行われ、繊維表面や塗料からインキを剥離
すると同時にインキを微細化する。こうして微細化され
九インキをフローテーション処理している。
According to the conventional method, this raw material is soaked, but soaking is performed in the presence of deinking chemicals such as caustic soda, sodium silicate, and surfactants, which strips the ink from the fiber surface and paint and at the same time makes the ink fine. . In this way, the finely divided ink is subjected to flotation treatment.

本発明者らは常法とは全く異なり、離解によって剥離し
た比較的大きいインキ粒子ftまづフローテーションで
取シ除くと後段の脱墨負荷を著しく軽減出来ると共に、
インキ粒子をよシ効率的に除去出来ることをみいだして
本発明を行ったものである。
The present inventors have discovered that, in a completely different way from the conventional method, by first removing relatively large ink particles peeled off by flotation by flotation, it is possible to significantly reduce the deinking load in the subsequent stage.
The present invention was developed based on the discovery that ink particles can be removed more efficiently.

本発明は離解、フローテーション、ソーキングをこの順
序で行えば足り、この他に常法で用いられる各種の操作
たとえばソーキング前の脱水、高濃度でのソーキング、
ソーキング后の高濃度でのニーディング、洗滌、晒等を
行うことはもちろんさしつかえなく、更に残存する未剥
離のインキを後段のソーキングによって完全に繊維から
剥離し、もう−度フローテーションを行うことももちろ
ん有効である。
In the present invention, it is sufficient to perform disintegration, flotation, and soaking in this order, and in addition, various operations used in conventional methods such as dehydration before soaking, soaking at a high concentration,
After soaking, it is of course possible to perform high-concentration kneading, washing, bleaching, etc., and it is also possible to completely remove the remaining unremoved ink from the fibers by subsequent soaking, and then perform flotation again. Of course it is valid.

本発明において人工程の離解け、濃度の限定は表い。一
般的には10%以下の濃度、好ましくは5qb程度で行
われることが多いが、10%をこえた濃度で行うことも
可能である。離解時には薬品の添加は必須の要件ではな
い。しかしながら要求される品質により、通常知られた
薬品を加えることはもちろん可能である。
In the present invention, there are no limitations on the disintegration and concentration of the human process. Generally, it is often carried out at a concentration of 10% or less, preferably about 5 qb, but it is also possible to carry out at a concentration exceeding 10%. Addition of chemicals is not an essential requirement during disintegration. However, depending on the quality required, it is of course possible to add commonly known chemicals.

本発明においてB工程のフローテーションは、粗選后の
原料を高速離解機で処理した后、希釈して通常知られ九
条件で行う。好ましい濃度は約1係である。処理時間は
要求される品質により異なるが10〜60分である。
In the present invention, the flotation in step B is carried out under nine commonly known conditions by treating the roughly selected raw material with a high-speed disintegrator and then diluting it. The preferred concentration is about 1 part. The processing time varies depending on the quality required, but is 10 to 60 minutes.

本発明におけるC工程のソーキングは、原料Q度15%
以上で1時間以上行うが、20時間以上の長時間処理を
行うのが好ましい。この工程における薬品添加は、通常
知られた薬品の種類、添加量他の条件がすべて使用可能
であるが、例示すると濃度25%の原料にNaOH2重
量係、40 Be’硅酸ソーダ2.6重量%’に添加し
、70℃で24時間ソーキングする。場合によっては硅
酸ソーダを加えないこともある。
The soaking in step C in the present invention has a raw material Q degree of 15%.
Although the above treatment is carried out for one hour or more, it is preferable to carry out a long-time treatment of 20 hours or more. For the addition of chemicals in this process, all the commonly known types of chemicals, amounts added, and other conditions can be used, but for example, NaOH 2 parts by weight, 40 Be'sodium silicate 2.6 parts by weight, and 25% concentration raw materials. %' and soak for 24 hours at 70°C. In some cases, sodium silicate may not be added.

本発明においては必要により、C工程のあとに二−ディ
ング工程を設けても良い。その場合、原料濃度15係以
上で行うことが望ましい。
In the present invention, a seconding step may be provided after the C step if necessary. In that case, it is desirable to carry out at a raw material concentration of 15 parts or higher.

更にまた本発明は必要に応じ、C工程のあとにもう一度
フローテーション工程を設けても良い。その場合の条件
は、B工程の条件と同一でも良いし、異なっても良い。
Furthermore, in the present invention, another flotation step may be provided after step C, if necessary. The conditions in that case may be the same as or different from those of the B step.

(実施例) 以下本発明を実施例によシ説明する。(Example) The present invention will be explained below using examples.

実施例1 コート印刷故紙100%の故紙をパルパーに仕込み、原
料濃度5係で離解した。離解原料を1%に希釈し、フロ
ーテーションにかけた。フローテーションは5分間行つ
九。
Example 1 100% coated printed waste paper was charged into a pulper and disintegrated at a raw material concentration of 5 parts. The disintegrated raw material was diluted to 1% and subjected to flotation. Floatation should be done for 5 minutes.9.

続いて原料濃度25%に脱水し、絶乾原料当りNaOH
2%、40 Be’硅酸ソーダ1.94 t−添加して
濃度20係で70℃、24時間ソーキングを行った。
Subsequently, the raw material concentration was dehydrated to 25%, and NaOH was added per bone dry raw material.
1.94 t of 2%, 40 Be'sodium silicate was added and soaked at 70° C. for 24 hours at a concentration of 20%.

ソーキングを行つ几原料を再び4%に希釈し、フローテ
ーションを行い、12%に脱水した。
The raw material to be soaked was diluted again to 4%, subjected to flotation, and dehydrated to 12%.

この原料を1009/rr?に手抄きを行い、インキ捕
集性、色差、紙の白色度、を以下の方法で測定した。
1009/rr for this raw material? The paper was made by hand, and the ink collection ability, color difference, and whiteness of the paper were measured using the following methods.

インキ捕集性:画像解析装置によるインキの(スペック
インデックス) 面積1!を測定した。
Ink collection ability: Ink (spec index) area according to image analysis device 1! was measured.

(C■粒度分布測定装置) 色差:  村上色差計(■300)で測定した。(C ■ Particle size distribution measuring device) Color difference: Measured with a Murakami color difference meter (■300).

紙の白色度:ホトボルト白色度針で測定した。Paper whiteness: Measured with a photovolt whiteness needle.

実施例2 実施例1のソーキング薬品をNaOH1%のみとした以
外は実施(H’vf’同じテストを行った。
Example 2 The same test as in Example 1 was carried out except that the soaking chemical was changed to 1% NaOH (H'vf').

実施例3 ソーキング后のフローテーションを行わず、ソーキング
后の原料を1%に希釈し、12%に脱水した以外は実施
例1と同様のテストを行った。
Example 3 A test similar to Example 1 was conducted except that flotation was not performed after soaking, and the raw material after soaking was diluted to 1% and dehydrated to 12%.

比較例1 ソーキング后のフローテーシヨンを行わないこと以外は
実施例1と同様にしてテストを行った。
Comparative Example 1 A test was conducted in the same manner as in Example 1 except that floatation after soaking was not performed.

以上の結果を第−表に示す。The above results are shown in Table 1.

第−表 (発明の効果) 以上の結果から明らかな通り、本発明の方法は従来法と
比較して 1)インキ粒子が微細化しないうちにフローテーシヨン
を行うため、インキの捕集性が良^。
Table 1 (Effects of the Invention) As is clear from the above results, the method of the present invention is superior to the conventional method in that: 1) Since flotation is performed before the ink particles become fine, the ink collection performance is improved; Good ^.

2)製品はインキによる青味が少なく、よシ良質である
2) The product has little blue tint due to the ink and is of good quality.

3)製品白色度が4ポイント程度向上する。3) Product whiteness improves by about 4 points.

4)ソーキング薬品が同じでも持込む有沓°性汚濁物が
減るため、排水の■D負負荷約10%程度減少する。
4) Even if the soaking chemicals are the same, the amount of excretory pollutants brought in is reduced, so the ■D negative load on the wastewater is reduced by about 10%.

又、同等の品質のものを得るために必要な薬品も減少す
るので、COD負荷が大巾に減少する。
Also, fewer chemicals are required to obtain the same quality, resulting in a significant reduction in COD load.

等の効果があり、脱墨方法としてきわめてすぐれたもの
である。
It has the following effects and is an extremely excellent deinking method.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は従来法の主要工程を示す工程図、第2図は本発
明の主要工程を示す工程図である。 第3〜5図は別の態様を示す本発明の工程図である。 特許出願人   本州製紙株式会社 第1図 第2図 第3図 第4図 第5図 手続補正書 昭和63年 4月26日 2、発明の名称 コート印刷故紙の脱墨方法 3、補正をする者 事件との関係 特許出願人 〒 104 住所東京都中央区銀座五丁目12番8号自   発 5、補正の対象 6、補正の内容 (1)明細書第7ページ14行目及び第8ページ12行
目のr40Be’硅酸ソーダ」を「硅酸ソーダ」と訂正
する。 (2)明細書第9ページ15行目の 「ソーキング后」を「ソーキング前」と訂正する。 以   上
FIG. 1 is a process chart showing the main steps of the conventional method, and FIG. 2 is a process chart showing the main steps of the present invention. 3 to 5 are process diagrams of the present invention showing another embodiment. Patent applicant Honshu Paper Co., Ltd. Figure 1 Figure 2 Figure 3 Figure 4 Figure 5 Procedural amendment April 26, 1988 2. Name of the invention Method for deinking coated printed waste paper 3. Person making the amendment Relationship to the case Patent applicant Address: 5-12-8 Ginza, Chuo-ku, Tokyo 104 Publication number 5 Subject of amendment 6 Contents of amendment (1) Specification, page 7, line 14 and page 8, line 12 Correct r40Be'Sodium Silicate' to 'Sodium Silicate'. (2) "After soaking" on page 9, line 15 of the specification is corrected to "before soaking."that's all

Claims (1)

【特許請求の範囲】 1)コート印刷故紙を含有した印刷故紙を離解し、粗選
するA工程、離解粗選后の原料をフローテーシヨンする
B工程、フローテーシヨン后の原料をソーキングするC
工程をこの順序で含むことを特徴とするコート印刷故紙
の脱墨方法。 2)ソーキング工程(C工程)の後に、更にフローテー
シヨン工程を有する特許請求の範囲第1項に記載の方法
。 3)ソーキング工程(C工程)の後に、原料濃度15%
以上の高濃度のまゝニーデイングを行うニーデイング工
程を有する、特許請求の範囲第1項記載の方法。 4)ソーキング工程(C工程)の後に原料濃度15%以
上の高濃度のまゝニーデイングを行うニーデイング工程
と、更にその後にフローテーシヨン工程を有する、特許
請求の範囲第1項記載の方法。 5)ソーキング工程(C工程)は、原料濃度15%以上
で1時間以上行う、特許請求の範囲 第1項ないし第4項に記載のいずれかの方法。
[Scope of Claims] 1) Step A of disintegrating and roughly sorting the printed waste paper containing coated printed waste paper, Step B of floatation of the raw material after disintegration and rough sorting, and Step C of soaking the raw material after flotation.
A method for deinking coated printed waste paper, comprising the steps in this order. 2) The method according to claim 1, further comprising a flotation step after the soaking step (C step). 3) After the soaking process (C process), the raw material concentration is 15%.
The method according to claim 1, comprising a kneading step of performing kneading while maintaining the high concentration. 4) The method according to claim 1, further comprising a kneading step in which kneading is performed at a high raw material concentration of 15% or more after the soaking step (C step), and a flotation step thereafter. 5) The method according to any one of claims 1 to 4, wherein the soaking step (C step) is performed at a raw material concentration of 15% or more for 1 hour or more.
JP7799388A 1988-04-01 1988-04-01 Deinking method of coated printing waste paper Expired - Lifetime JP2645303B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7799388A JP2645303B2 (en) 1988-04-01 1988-04-01 Deinking method of coated printing waste paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7799388A JP2645303B2 (en) 1988-04-01 1988-04-01 Deinking method of coated printing waste paper

Publications (2)

Publication Number Publication Date
JPH01260084A true JPH01260084A (en) 1989-10-17
JP2645303B2 JP2645303B2 (en) 1997-08-25

Family

ID=13649344

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7799388A Expired - Lifetime JP2645303B2 (en) 1988-04-01 1988-04-01 Deinking method of coated printing waste paper

Country Status (1)

Country Link
JP (1) JP2645303B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05263384A (en) * 1992-03-10 1993-10-12 Nippon Paper Ind Co Ltd Production of regenerated paper excellent in dimensional stability
JP2009256808A (en) * 2008-04-11 2009-11-05 Toppan Printing Co Ltd Method for recycling waste printed paper
WO2018014237A1 (en) * 2016-07-19 2018-01-25 乐国强 Apparatus for pre-processing, sorting, and recycling paper waste
CN112703233A (en) * 2020-08-17 2021-04-23 福建华峰运动用品科技有限公司 Recycled fiber coating slurry containing waste cloth, coating and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5119803A (en) * 1974-08-09 1976-02-17 Mitsui Mining & Smelting Co Horiramineetoshino shoriho
JPS60199992A (en) * 1984-03-23 1985-10-09 森實 美津夫 Pretreatment of used paper

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5119803A (en) * 1974-08-09 1976-02-17 Mitsui Mining & Smelting Co Horiramineetoshino shoriho
JPS60199992A (en) * 1984-03-23 1985-10-09 森實 美津夫 Pretreatment of used paper

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05263384A (en) * 1992-03-10 1993-10-12 Nippon Paper Ind Co Ltd Production of regenerated paper excellent in dimensional stability
JP2009256808A (en) * 2008-04-11 2009-11-05 Toppan Printing Co Ltd Method for recycling waste printed paper
WO2018014237A1 (en) * 2016-07-19 2018-01-25 乐国强 Apparatus for pre-processing, sorting, and recycling paper waste
CN112703233A (en) * 2020-08-17 2021-04-23 福建华峰运动用品科技有限公司 Recycled fiber coating slurry containing waste cloth, coating and preparation method thereof

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