JPH01258615A - Hair rinse agent composition - Google Patents
Hair rinse agent compositionInfo
- Publication number
- JPH01258615A JPH01258615A JP8753288A JP8753288A JPH01258615A JP H01258615 A JPH01258615 A JP H01258615A JP 8753288 A JP8753288 A JP 8753288A JP 8753288 A JP8753288 A JP 8753288A JP H01258615 A JPH01258615 A JP H01258615A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- formula
- hair rinse
- rinse agent
- agent composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 16
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 7
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 5
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
- 239000004094 surface-active agent Substances 0.000 claims abstract description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 3
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims abstract description 3
- 125000005843 halogen group Chemical group 0.000 claims abstract description 3
- 229930195734 saturated hydrocarbon Natural products 0.000 claims abstract description 3
- -1 phosphate ester Chemical class 0.000 claims description 10
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 12
- 230000003750 conditioning effect Effects 0.000 abstract description 9
- 239000004615 ingredient Substances 0.000 abstract description 4
- 150000001875 compounds Chemical class 0.000 abstract description 3
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 abstract description 2
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 abstract description 2
- LBXBOGYPNZUTSD-UHFFFAOYSA-M sodium;2-[2-hydroxydodecyl(methyl)amino]ethyl hydrogen phosphate Chemical compound [Na+].CCCCCCCCCCC(O)CN(C)CCOP(O)([O-])=O LBXBOGYPNZUTSD-UHFFFAOYSA-M 0.000 abstract description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 230000003766 combability Effects 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- DNVVFIHQZGZOSI-UHFFFAOYSA-N 2-[2-hydroxydodecyl(methyl)amino]ethyl dihydrogen phosphate Chemical compound CCCCCCCCCCC(O)CN(C)CCOP(O)(O)=O DNVVFIHQZGZOSI-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 206010044625 Trichorrhexis Diseases 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- ZJXZSIYSNXKHEA-UHFFFAOYSA-N ethyl dihydrogen phosphate Chemical compound CCOP(O)(O)=O ZJXZSIYSNXKHEA-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000003700 hair damage Effects 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- QMGPXBPMUADRMC-UHFFFAOYSA-M heptyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCC[N+](C)(C)C QMGPXBPMUADRMC-UHFFFAOYSA-M 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、ヘアーリンス剤に関し更に詳しくは、使用時
のぬめり感及びのびを大幅に改善するとともに、毛髪コ
ンディショニング効果に優れたヘアーリンス剤組成物に
関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a hair rinse agent, and more specifically, the present invention provides a hair rinse agent composition that significantly improves the sliminess and spreadability during use and has an excellent hair conditioning effect. relating to things.
（従来技術）
毛髪の汚れを除去するために、アニオン界面活性剤を主
成分とするシャンプーで洗髪すると毛髪の汚れのほか毛
髪表面を保護している油分も同時に除去され、毛髪の柔
軟性が失なわれ、艶のない、くし通りの悪い髪となり、
毛髪の損傷、枝毛、切毛が発生し易くなる。(Prior art) When hair is washed with a shampoo containing an anionic surfactant as a main ingredient to remove dirt from the hair, not only the dirt but also the oil that protects the hair surface is removed, causing the hair to lose its flexibility. Hair becomes curly, lackluster, and difficult to comb.
Hair damage, split ends, and cut hair are more likely to occur.
これらの弊害を防ぐ目的で、カチオン界面活性剤である
第４級アンモニウム塩を有効成分とするヘアーリンス剤
が使用されている。In order to prevent these harmful effects, hair rinses containing quaternary ammonium salts, which are cationic surfactants, as an active ingredient are used.
ヘアーリンス剤は、毛髪にコンディショニング効果（柔
軟性、しっとり感、なめらかさ、くシ通り性）を付与す
ることを目的とするものである。Hair rinse agents are intended to impart conditioning effects (softness, moisturizing, smoothness, and combability) to hair.
しかし、第４級アンモニウム塩のみでは柔軟性。However, quaternary ammonium salt alone is not flexible.
なめらかさに関し、充分な効果が得られない。従って、
従来のへアーリンス剤にはこれらの欠点を改善するため
に、高級アルコール、グリセライド。A sufficient effect cannot be obtained regarding smoothness. Therefore,
In order to improve these drawbacks, conventional hair rinse agents contain higher alcohols and glycerides.
流動パラフィン等の油脂類を配合することが従案さねて
いる。しかし、これらの方法も未だ満足のゆくものは得
られず、特に毛髪のなめらかさについては不充分であっ
た。また、リンス使用時のぬめり感、のびについても使
用感が劣り、そのため使用量が多くなり、経済性の面か
らも好ましくない。It has not been proposed to incorporate oils and fats such as liquid paraffin. However, these methods have not yet yielded satisfactory results, particularly in terms of smoothness of the hair. Furthermore, the rinsing agent has a poor feeling of sliminess and spreadability during use, which results in a large amount of use, which is unfavorable from an economic point of view.
（発明が解決しようとする課題）
そこで、本発明考は、優れた毛髪コンディショニング効
果を有するとともに、使用感（ぬめり感。(Problems to be Solved by the Invention) Therefore, the idea of the present invention not only has an excellent hair conditioning effect but also reduces the feeling of use (slimy feeling).
のび）を大幅に改善するヘアーリンス剤を得る目的で鋭
意研究した結果、第４級アンモニウム塩と、凌記特定の
両性リン酸エステル系活性剤とを必須成分として、各々
特定量含有してなるヘアーリンス剤は、上記目的を達成
しうろことを見出し、本発明を完成した。As a result of intensive research with the aim of obtaining a hair rinse agent that significantly improves the hair's elasticity, we have found a product that contains a quaternary ammonium salt and a specific amphoteric phosphate ester active agent as essential ingredients, each in a specific amount. It was discovered that a hair rinse agent can achieve the above objectives, and the present invention was completed.
即ち、本発明の目的は、優れた毛髪コンディショニング
効果（柔軟性、しっとり感、なめらかさ。That is, the purpose of the present invention is to provide excellent hair conditioning effects (softness, moisturization, and smoothness).
くし通り性）を有すると共に、使用感（ぬめり感。It has good combability) as well as a feeling of use (slimy feeling).
のび）を大幅に改善するヘアーリンス剤を従供すること
にある。An object of the present invention is to provide a hair rinse agent that significantly improves the hair's elasticity.
（課題を解決するための手段）
本発明は、
（Ａ）一般式
〔式中、Ｒ，、Ｒ工、Ｒ５，及びＲ４の１〜２個は炭素
数１２〜２４の長鎖アルキル基を示し、残余は炭素数１
〜３のアルキル基、ベンジル基を示し、Ｘはハロゲン原
子を示す、〕
で表わされる第４級アンモニウム塩０．３〜６重量％と
、
（Ｂ）−船式
％式％
〔式中Ｒ５は平均炭素数８〜１８の直鎖又は分岐鎖の飽
和炭化水素基で、Ｍ、はアルカリ金属。(Means for Solving the Problems) The present invention has the following characteristics: , the remainder has 1 carbon number
~3 represents an alkyl group or a benzyl group, and X represents a halogen atom.] 0.3 to 6% by weight of a quaternary ammonium salt represented by A linear or branched saturated hydrocarbon group having an average of 8 to 18 carbon atoms, and M is an alkali metal.
アンモニウム又はトリエタノールアミンを示す、〕で表
わされる、両性リン酸エステル系界面活性剤０、１〜３
重景重量を含有するヘアーリンス剤組成物である。ammonium or triethanolamine, ampholytic phosphate ester surfactants 0, 1 to 3
This is a hair rinse composition containing heavy weight.
本発明の＜Ａ）成分である前記カチオン界面活性剤は、
一種または二種以上の混合物が適用され、ｉｍ常のへア
ーリンス剤等に配合され得るすべてのものが使用される
。例えば、ジステアリルジメチルアンモニウムクロライ
ド、ステアリルトリメチルアンモニウムクロライド、ス
テアリルジメチルベンジルアンモニウムクロライド、七
チルトリメチルアンモニウムクロライド、ベヘニルトリ
メチルアンモニウムクロライド、などが挙げられる。The cationic surfactant which is component <A) of the present invention is:
One or a mixture of two or more may be applied, and all those which can be incorporated into conventional hair rinses etc. are used. Examples include distearyldimethylammonium chloride, stearyltrimethylammonium chloride, stearyldimethylbenzylammonium chloride, heptyltrimethylammonium chloride, behenyltrimethylammonium chloride, and the like.
本発明のへアーリンス剤組成物には、これらのカチオン
界面活性剤の一種または二種以上の混合物を＆ｇ量を基
準として０，３〜６重量％（以下ｗｔ％と略記する）、
好ましくは０．５〜４ｗｔ％配合される。また配合量が
Ｑ、 ３ ｗ ｔ％未満では、毛髪コンディショニング
効果に良好な結果が得られず、５ｗｔ％を超えると毛髪
にべたつきが生じ好ましくない。The hair rinse agent composition of the present invention contains 0.3 to 6% by weight (hereinafter abbreviated as wt%) of one or a mixture of two or more of these cationic surfactants, based on the amount of &g;
Preferably, it is blended in an amount of 0.5 to 4 wt%. If the amount is less than 3 wt%, no good hair conditioning effect will be obtained, and if it exceeds 5 wt%, the hair will become sticky, which is undesirable.
本発明の（Ｂ）成分である両性リン酸エステル系活性剤
は、特開昭６１−１４１７９８公報に記載されている２
−（２−ヒドロキシ−Ｎ−メチルドデシルアミノ）エチ
ルリン酸エステルモノナトリウム、２− （２−ヒドロ
キシ−Ｎ−メチルミリスチルアミノ）エチルリン酸エス
テルトリエタノールアミン、２−（２−ヒドロキシ−Ｎ
−メチルドデシルアミノ）エチルリン酸エステルトリエ
タノールアミン、２−（２−ヒドロキシ−Ｎ−メチルバ
ルミチｌレアミノ）エチルリン酸エステルモノナトリウ
ム、２− （２−ヒドロキシ−Ｎ−メチルステアリルア
ミノ）エチルリン酸エステルトリエタノールアミン等々
で１、公知の製造法により得る事ができる。The amphoteric phosphate ester activator which is the component (B) of the present invention is 2
-(2-hydroxy-N-methyldodecylamino)ethyl phosphate monosodium, 2-(2-hydroxy-N-methylmyristylamino)ethyl phosphate triethanolamine, 2-(2-hydroxy-N
-Methyldodecylamino)ethyl phosphate ester triethanolamine, 2-(2-hydroxy-N-methylvalmityleamino)ethyl phosphate monosodium, 2-(2-hydroxy-N-methylstearylamino)ethyl phosphate ester triethanolamine etc. 1. It can be obtained by a known manufacturing method.
この化合物の一種または二種以上の混合物を聡星を基ｉ
ｔとしてＯ，１〜３ｗｔ％、好ましくは０．１〜２ Ｗ
ｔ ％配合される。また配合量が０． Ｉ Ｗ ｔ％
束焉では、毛髪コンディショニング効果及び使用時のぬ
めり感、のびに良好な結果が得られず、３ｗｔ％を超え
るとし髪にべたつきが生じ好ましくない。Based on Satosei, one or a mixture of two or more of these compounds
t is O, 1 to 3 wt%, preferably 0.1 to 2 W
t% is added. Also, the blending amount is 0. I W t%
In the case of curly hair, it is difficult to obtain good results in terms of hair conditioning effect, slimy feeling during use, and smoothness, and if it exceeds 3 wt%, the hair becomes sticky, which is undesirable.
一ト発明のヘアーリンス剤耕成物は、上述した２成分を
必須の構成成分とするが、これらの（Ａ）。The hair rinse composition of the present invention has the above-mentioned two components as essential components, and these (A).
（Ｂ）２成分の配合重量比は、
（Ａ）： （Ｂ）＝２８１〜６ａｔ
が好ましい、また、当該組成物には、本発明の目的を達
成する範囲で、他の成分を適宜配合することができる。(B) The blending weight ratio of the two components is preferably (A): (B) = 281 to 6 at. In addition, other components may be appropriately blended into the composition within a range that achieves the purpose of the present invention. be able to.
即ち、流動パラフィン、ワセリン、スクワラン等の炭化
水素、イソプロピルミリステート、イソプロピルパルミ
テート等のエステル油、ツバキ油１−ｔリーブ油、アボ
ガド油等の植物油、ポリグリセリン脂肪酸エステル、ポ
リオキシエチレンソルビタンモノラウレート、等の非イ
オン界面活性剤、メチルセルロース。ヒドロキシエチル
セルロース。Namely, hydrocarbons such as liquid paraffin, vaseline, and squalane, ester oils such as isopropyl myristate and isopropyl palmitate, vegetable oils such as camellia oil, 1-t leave oil, and avocado oil, polyglycerin fatty acid esters, and polyoxyethylene sorbitan monomers. rate, nonionic surfactants such as methylcellulose. Hydroxyethylcellulose.
カチオン化セルロース等のセルロース誘導体、エチレン
グリコール、プロピレングリコール、グリセリン等の保
湿剤、ポリベブヂド、その他殺菌剤。Cellulose derivatives such as cationized cellulose, humectants such as ethylene glycol, propylene glycol, and glycerin, polybebidide, and other fungicides.
フケ取り剤、キレート剤、紫外線吸収剤１着色剤。Dandruff remover, chelating agent, UV absorber 1 coloring agent.
香料などが挙げられこれらの一種または二種以上を配合
することができる。Flavors and the like can be mentioned, and one or more of these can be blended.
（実施例）
次に実施例を挙げ本発明を説明するが、本発明はこれら
実施例に限定されるものではなし・。(Examples) Next, the present invention will be explained with reference to Examples, but the present invention is not limited to these Examples.
なお、本実施例中で用いた試験方法は、下記のとおりで
ある。The test method used in this example is as follows.
Ｉｌｌ 使用域（ぬめり感、のび）及び毛髪コンディ
ショニング効果。Ill Usage area (sliminess, spreadability) and hair conditioning effect.
各側における「ぬめり惑」、「のび」、「髪の柔軟性」
、「髪のしっとり怒」、［髪のなめらかさＪ、ｒ＜Ｌ通
り性Ｊを女性２０名の専門パネラ−により官能的に比較
し、下記基準で評価を行なった。“Slimy”, “grow”, and “hair flexibility” on each side
, "moist hair", "hair smoothness J", "hair smoothness J", "r<L straightness J" were sensually compared by a panel of 20 female experts, and evaluated according to the following criteria.
◎；良いと答えた人が１８Å以上の場合○；
が１４〜１７人の場合△； が ８〜
１３人の場合×； が １Å以下の場合実
施例１〜３．比較例１〜２
第−表に示す配合組成のヘアーリンス剤を通常の方法で
調製し、各必須成分の効果を調べ第−表実施例４〜７．
比較例３〜４
第二表に示す配合組成のヘアーリンス剤を通常の方法で
調製し、各必須成分の効果を調べ第二表、（特 性）
実施例１〜７より明らかなように、本発明のへアーリン
ス剤組成物は、いずれも優れた性能を示している。◎; If the person who answered good is 18 Å or more, ○;
If there are 14 to 17 people, △; is 8 to 17 people.
In the case of 13 people ×; In the case of 1 Å or less Examples 1 to 3. Comparative Examples 1 to 2 Hair rinses having the formulations shown in Table 1 were prepared in a conventional manner, and the effects of each essential component were investigated.
Comparative Examples 3 to 4 Hair rinses having the composition shown in Table 2 were prepared in a conventional manner, and the effects of each essential ingredient were examined. All of the hair rinse agent compositions of the present invention exhibit excellent performance.
（発明の効果）
以上記載のごとく、本発明は毛髪コンディショニング効
果（柔軟性、しっとり感、なめらかさ。(Effects of the Invention) As described above, the present invention has hair conditioning effects (softness, moist feeling, smoothness).
くし通り性）及び使用感（ぬめり惑、のび）に優れた有
用なるヘアーリンス剤組成物を提供することは明らかで
ある。It is clear that the present invention provides a useful hair rinse composition that is excellent in combability) and feeling of use (sliminess and spreadability).
Claims (1)
個は炭素数１２〜２４の長鎖アルキル基を示し、残余は
炭素数１〜３のアルキル基、ベンジル基を示し、Ｘはハ
ロゲン原子を示す。〕 で表わされる第４級アンモニウム塩０．３〜６重量％と （Ｂ）一般式 ▲数式、化学式、表等があります▼ 〔式中Ｒ＿１は平均炭素数８〜１８の直鎖又は分岐鎖の
飽和炭化水素基で、Ｍ＿１はアルカリ金属、アンモニウ
ム又はトリエタノールアミンを示す。〕で表わされる、
両性リン酸エステル系界面活性剤０．１〜３重量％とを
含有することを特徴とするヘアーリンス剤組成物。[Claims] (A) General formula ▲ Numerical formula, chemical formula, table, etc. ▼ [In the formula, R_1, R_2, R_3, and R_4 1 to 2
Each represents a long-chain alkyl group having 12 to 24 carbon atoms, the remainder represents an alkyl group having 1 to 3 carbon atoms or a benzyl group, and X represents a halogen atom. ] 0.3 to 6% by weight of a quaternary ammonium salt represented by (B) General formula ▲ Numerical formula, chemical formula, table, etc. In the saturated hydrocarbon group, M_1 represents an alkali metal, ammonium or triethanolamine. ] Represented by
A hair rinse composition comprising 0.1 to 3% by weight of an amphoteric phosphate ester surfactant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8753288A JP2607439B2 (en) | 1988-04-08 | 1988-04-08 | Hair rinse composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8753288A JP2607439B2 (en) | 1988-04-08 | 1988-04-08 | Hair rinse composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01258615A true JPH01258615A (en) | 1989-10-16 |
| JP2607439B2 JP2607439B2 (en) | 1997-05-07 |
Family
ID=13917599
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8753288A Expired - Lifetime JP2607439B2 (en) | 1988-04-08 | 1988-04-08 | Hair rinse composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2607439B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03176415A (en) * | 1989-12-04 | 1991-07-31 | Kanebo Ltd | Hair rinse composition |
-
1988
- 1988-04-08 JP JP8753288A patent/JP2607439B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03176415A (en) * | 1989-12-04 | 1991-07-31 | Kanebo Ltd | Hair rinse composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2607439B2 (en) | 1997-05-07 |
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