JPH01257710A - Exhaust gas purifying device for alcohol fuel engine - Google Patents

Exhaust gas purifying device for alcohol fuel engine

Info

Publication number
JPH01257710A
JPH01257710A JP63084487A JP8448788A JPH01257710A JP H01257710 A JPH01257710 A JP H01257710A JP 63084487 A JP63084487 A JP 63084487A JP 8448788 A JP8448788 A JP 8448788A JP H01257710 A JPH01257710 A JP H01257710A
Authority
JP
Japan
Prior art keywords
exhaust gas
exhaust
catalyst
catalyst device
exhaust passage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP63084487A
Other languages
Japanese (ja)
Inventor
Nobuhiro Ando
安藤 伸広
Ichiro Yamagata
山縣 一郎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mazda Motor Corp
Original Assignee
Mazda Motor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mazda Motor Corp filed Critical Mazda Motor Corp
Priority to JP63084487A priority Critical patent/JPH01257710A/en
Publication of JPH01257710A publication Critical patent/JPH01257710A/en
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0871Regulation of absorbents or adsorbents, e.g. purging
    • F01N3/0878Bypassing absorbents or adsorbents
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2250/00Combinations of different methods of purification
    • F01N2250/12Combinations of different methods of purification absorption or adsorption, and catalytic conversion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2410/00By-passing, at least partially, exhaust from inlet to outlet of apparatus, to atmosphere or to other device
    • F01N2410/12By-passing, at least partially, exhaust from inlet to outlet of apparatus, to atmosphere or to other device in case of absorption, adsorption or desorption of exhaust gas constituents
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Abstract

PURPOSE:To aim at purification of exhaust gas by providing an exhaust gas passage for a low temperature which is branched from the upper stream side of a catalyst device to introduce the exhaust gas to the catalyst device via an adsorption chamber. CONSTITUTION:An adsorption chamber 9 is provided at the outer circumference of a catalyst device 8. An exhaust passage 13 for a low temperature, is provided, which is branched from the upper stream side of the catalyst device 8 to introduce exhaust gas to the catalyst device via an adsorption chamber 9. An exhaust gas passage 6 and the exhaust gas passage 13 for a low temperature are switched over by a change valve 14. Accordingly, aldehyde and uncombusted methanol are removed even during a cold engine state so that the exhaust gas can be purified.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、アルコールまたはアルコール系の燃料を使用
するアルコール燃料エンジンンより排出される排気ガス
の浄化装置に関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a device for purifying exhaust gas discharged from an alcohol fuel engine that uses alcohol or alcohol-based fuel.

(従来の技術) 近年においては、ガソリンエンジンより排出される排気
ガスによる環境汚染の改善ならびに石油資源の温存、更
には、ガソリンエンジンに比べて着火性およびノッキン
グ対策のうえでも有利なアルコールまたはアルコール系
の燃料、例えばメタノール等を使用するアルコール燃料
エンジンが開発されている。
(Prior art) In recent years, alcohol or alcohol-based alcohols have been used to improve environmental pollution caused by exhaust gas emitted from gasoline engines, to conserve petroleum resources, and to improve ignitability and prevent knocking compared to gasoline engines. Alcohol-fueled engines have been developed that use fuels such as methanol.

そして、この種アルコール燃料エンジンにおいても排気
ガスの浄化対策が講じられており、一般的には、排気管
の途中に触媒を設けて該触媒によりアルコール燃料エン
ジンより排出される排気ガスを浄化するように構成され
ているのであるが、上記触媒が排気ガスにより暖められ
て所定の温度以上に達するまでは該触媒による排気ガス
に対する浄化作用が良好に行われず、このため、特に工
ンジン始動直後等の冷間期、即ち、上記触媒が所定の温
度以上に暖められるまでの間に排出されるる排気ガスの
浄化を良好に行うことが困難となっていた。
Measures are taken to purify the exhaust gas in this type of alcohol fuel engine as well, and generally a catalyst is installed in the middle of the exhaust pipe and the catalyst purifies the exhaust gas discharged from the alcohol fuel engine. However, until the catalyst is warmed by the exhaust gas and reaches a predetermined temperature or higher, the catalyst does not purify the exhaust gas satisfactorily. It has been difficult to effectively purify the exhaust gas discharged during the cold period, that is, until the catalyst is warmed to a predetermined temperature or higher.

そこで、例えば特開昭61−200315号公報によれ
は、アルコール燃料エンジンより排出される排気ガスを
浄化すべく触媒ケーシング内に保持された触媒の前方ま
たは前後に分割された触媒間に予加熱装置を設けること
により、エンジンの始動に先立って上記触媒を余熱した
り、あるいはまたエンジンの始動と同時に上記触媒を加
熱することにより、該触媒を速やかに所定の温度以上に
暖めてエンジンの冷間期においても該エンジンより排出
される排気カスの浄化を良好に行い得るように構成され
ている。
For example, Japanese Patent Application Laid-Open No. 61-200315 discloses a preheating device in front of a catalyst held in a catalyst casing or between catalysts divided into front and rear parts in order to purify exhaust gas discharged from an alcohol fuel engine. By providing a preheating device, the catalyst can be preheated before starting the engine, or by heating the catalyst at the same time as the engine is started, the catalyst can be quickly warmed to a predetermined temperature or higher, and the engine can be cooled during the cold period. The engine is also configured to be able to effectively purify the exhaust scum discharged from the engine.

(発明が解決しようとする課題) ところで、上記従来技術においては、予加熱装置を用い
て触媒自体を速やかに所定の温度以上に達するまで予加
熱することにより、該触媒により排気カスを良好に浄化
するように構成されたちのであるが、エンジンの始動と
同時に上記触媒を加熱する場合には、エンジンの始動に
伴って排気カスが排出され初めてから加熱装置により触
媒を所定の温度以上に達するまで加熱する間に時間的な
遅れが生じ、この間に排出される排気ガスを確実に浄化
することができなかった。そのため、エンジン冷間期に
おいては排気ガス中に含有されるアルデヒドもしくはメ
タノールを燃料として使用した場合における未燃メタノ
ール等の特に問題となる所定の成分を除去することが困
難となっていた。また、エンジンの始動に先立って触媒
を余熱する場合には、当然のことながら、エンジンの始
動前に余熱装置を作動させなければならす極めて不経済
であった。
(Problems to be Solved by the Invention) By the way, in the above-mentioned conventional technology, by preheating the catalyst itself using a preheating device until it quickly reaches a predetermined temperature or higher, the exhaust gas is effectively purified by the catalyst. However, when heating the catalyst at the same time as the engine starts, the heating device heats the catalyst until it reaches a predetermined temperature from the time exhaust scum is discharged with the engine starting. There was a time delay during this time, and the exhaust gas emitted during this time could not be reliably purified. Therefore, during the cold period of the engine, it has been difficult to remove certain components that are particularly problematic, such as unburned methanol when aldehyde or methanol contained in the exhaust gas is used as fuel. Furthermore, when preheating the catalyst prior to starting the engine, the preheating device must be operated before starting the engine, which is extremely uneconomical.

そこで本発明は、アルコールまたはアルコール系の燃料
を使用するアルコール燃料エンジンにおいて、特にエン
ジン冷開期に排出される排気カスを良好に浄化して該排
気ガス中に含まれるアルデヒド等の特に問題となる成分
を確実に除去し得るアルコール燃料エンジンの排気カス
浄化装置を提供することを目的とする。
Therefore, in an alcohol fuel engine that uses alcohol or alcohol-based fuel, the present invention satisfactorily purifies the exhaust gas emitted especially during the engine cold opening period, and eliminates the problems such as aldehydes contained in the exhaust gas. An object of the present invention is to provide an exhaust gas purification device for an alcohol fuel engine that can reliably remove components.

(課題を解決するための手段) 上記の目的を達成するなめに、本発明は次のように構成
したことを特徴とする。
(Means for Solving the Problems) In order to achieve the above object, the present invention is characterized by the following configuration.

即ち、アルコールまたはアルコール系の燃料を使用する
アルコール燃料エンジンの排気ガス浄化装置において、
上記エンジン本体に接続された排気通路の途中に設けら
れて排気ガスを浄化する触媒装置と、該触媒装置の外周
囲に設けられて排気ガス中の所定成分を吸着除去する吸
着材が充填された吸着室と、上記排気通路における触媒
装置の上流側より分岐してと上記吸着室を経て触媒装置
に排気ガスを導入する低温用排気通路と、該低温用排気
通路分岐部の下流側であって上記触媒装置の上流側にお
ける排気通路に設けられて排気カス低温時に該M[気通
路を閉して低温用排気通路にのみ排気カスを導入する切
替バルブとを設けたことを特徴とする。
That is, in an exhaust gas purification device for an alcohol fuel engine that uses alcohol or alcohol-based fuel,
A catalyst device is provided in the middle of an exhaust passage connected to the engine body to purify exhaust gas, and an adsorbent is provided around the outside of the catalyst device and is filled with an adsorbent to adsorb and remove predetermined components in the exhaust gas. an adsorption chamber, a low-temperature exhaust passage that branches from the upstream side of the catalyst device in the exhaust passage and introduces exhaust gas into the catalyst device through the adsorption chamber, and a low-temperature exhaust passage downstream of the branched part of the low-temperature exhaust passage. The present invention is characterized in that a switching valve is provided in the exhaust passage on the upstream side of the catalyst device to close the air passage and introduce exhaust scum only into the low-temperature exhaust passage when the exhaust scum is at a low temperature.

(作   用) 上記の構成によれば、エンジン始動直後等の冷開期にお
いて該エンジンより排出される排気カスの低温時には、
切替バルブが切り替えられることにより排気通路におけ
る触媒装置の上流側より分岐して吸着材が充填された吸
着室を経て触媒装置に排気ガスを導入する低温用排気通
路に排気ガスが導入されることになって、これにより、
上記吸着室内に充填された吸着材により排気ガス中に含
まれるアルデヒドもしくはメタノールを燃料として使用
した場合における未燃メタノール等の特に問題となる所
定の成分が確実に吸着除去されることになる。しかも、
該低温用排気通路を介して吸着室に導入された排気ガス
により上記触媒装置が周囲から暖められて排気ガスに対
する浄化作用を良好に発揮する所定の温度以上に速やか
に加熱されることになる。そして、上記低温用排気通路
より吸着室を経て触媒装置に導入される排気ガスが所定
の温度に達した場合には、上記切替バルブが切り替えら
れて排気ガスが排気通路より直接触媒装置に導入さて浄
化されることになる。これにより、エンジンの高負荷時
あるいは高速時等における排圧上昇を招くことなく確実
に排気ガスを浄化することが可能となる。
(Function) According to the above configuration, when the exhaust gas discharged from the engine is at a low temperature during the cold opening period, such as immediately after the engine starts,
By switching the switching valve, exhaust gas is introduced into the low-temperature exhaust passage that branches from the upstream side of the catalyst device in the exhaust passage and introduces exhaust gas into the catalyst device through an adsorption chamber filled with adsorbent. As a result,
The adsorbent filled in the adsorption chamber reliably adsorbs and removes certain components that are particularly problematic, such as unburned methanol when aldehyde or methanol contained in exhaust gas is used as fuel. Moreover,
The exhaust gas introduced into the adsorption chamber via the low-temperature exhaust passage warms the catalyst device from its surroundings and quickly heats it above a predetermined temperature at which it can satisfactorily exert a purifying effect on the exhaust gas. When the exhaust gas introduced into the catalyst device from the low-temperature exhaust passage via the adsorption chamber reaches a predetermined temperature, the switching valve is switched and the exhaust gas is introduced directly into the catalyst device from the exhaust passage. It will be purified. This makes it possible to reliably purify exhaust gas without causing an increase in exhaust pressure when the engine is under high load or at high speed.

(実 施 例) 以下、本発明の実施例を図面に基づいて説明する。(Example) Embodiments of the present invention will be described below based on the drawings.

第1図に示すように、本実施例に係るエンジン1は、ア
ルコールまたはアルコール系の燃料を使用するアルコー
ル燃料エンジンであって、該エンジン1における複数の
排気ポート(図示せず)に連通される排気マニホルド2
には、該マニホルド2を介してエンジン1より排出され
る排気ガスを外部に放出するための排気管3が接続され
ている。また、この排気管3の途中には、上記排気ガス
を浄化するための排気ガス浄化装置4が設けられている
と共に、同じく該排気管3における上記排気ガス浄化装
置4の下流側には消音器5が接続されている。
As shown in FIG. 1, the engine 1 according to this embodiment is an alcohol fuel engine that uses alcohol or alcohol-based fuel, and is connected to a plurality of exhaust ports (not shown) in the engine 1. Exhaust manifold 2
An exhaust pipe 3 is connected to the engine 1 through the manifold 2 for discharging exhaust gas from the engine 1 to the outside. Further, an exhaust gas purification device 4 for purifying the exhaust gas is provided in the middle of the exhaust pipe 3, and a muffler is also provided on the downstream side of the exhaust gas purification device 4 in the exhaust pipe 3. 5 is connected.

そして、本実施例においては、上記排気ガス浄化装置4
が、次のように構成されている。
In this embodiment, the exhaust gas purification device 4
is structured as follows.

即ち、該排気ガス浄化装置4は、第2.3図に示すよう
に、排気管3に一端が接続されて該排気管3と連続する
排気通路6を形成すると共に、該排気通路6内に導入さ
れる排気ガスを浄化する触媒7が介装された触媒装置本
体8と、該触媒装置本体8の外周囲に配設された吸着室
9と、この吸着室9内において上記触媒装置本体8の外
周囲を取り囲むようにして充填されて排気ガス中に含有
される所定の成分、例えばアルデヒドあるいはメタノー
ルを燃料として使用した場合には、未燃メタノール等の
特に問題となる成分を吸着除去する吸着材10と、上記
排気通路6における触媒7の上流側より分岐して上記吸
着室9と、複数の連通孔11a ・llaが設けられた
仕切板11と、触媒装置本体8の外周囲に配設された連
通室12とを経て複数の開口部8a、8aより触媒7に
排気ガスを導入する低温用排気通路13.13と、該低
温用排気通路13.13の分岐部13a、13aの下流
側であって上記触媒7の上流側における排気通路6に設
けられて、排気ガス低温時に上記低温用排気通路13.
13にのみ排気ガスを導入するように切り替えられる切
替バルブ14と、上記触媒7を通過する排気ガスの温度
を検出する温度センサ15と、該温度センサ15がらの
出力信号aが入力され、且つ該出力信号aに基づいて上
記触媒7を通過する排気ガスの温度が予め設定された所
定の温度以上であるとか判定された場合に出力信号すを
出力することにより、上記切替バルブ14を切り替える
ように制御するコントローラ16とを有する。従って、
上記排気管3より排気通路6内に導かれた排気ガスが、
触媒7を通過して浄化されたのち外部に排出されると共
に、排気ガスの温度が所定の温度以下であれば上記コン
トローラ16より出力される出力信号すに基づいて切り
替えバルブ14が切り替えられて上記排気ガスが低温用
排気通路13.13内に導入されるように構成されてい
る。
That is, as shown in FIG. 2.3, the exhaust gas purification device 4 has one end connected to the exhaust pipe 3 to form an exhaust passage 6 that is continuous with the exhaust pipe 3, and also has an exhaust passage 6 in the exhaust passage 6. A catalyst device main body 8 in which a catalyst 7 for purifying introduced exhaust gas is interposed, an adsorption chamber 9 disposed around the outer periphery of the catalyst device main body 8, and a catalyst device main body 8 in the adsorption chamber 9. When a specific component contained in the exhaust gas, such as aldehyde or methanol, is used as a fuel, adsorption is used to adsorb and remove particularly problematic components such as unburned methanol. 10, a partition plate 11 which branches from the upstream side of the catalyst 7 in the exhaust passage 6 and connects to the adsorption chamber 9, a partition plate 11 provided with a plurality of communication holes 11a and 11a, and a partition plate 11 disposed around the outer periphery of the catalyst device main body 8. A low-temperature exhaust passage 13.13 that introduces exhaust gas into the catalyst 7 through a plurality of openings 8a, 8a through the communication chamber 12, and a downstream side of the branch parts 13a, 13a of the low-temperature exhaust passage 13.13. The low-temperature exhaust passage 13 is provided in the exhaust passage 6 on the upstream side of the catalyst 7 and is used when the exhaust gas is at a low temperature.
A switching valve 14 that can be switched to introduce exhaust gas only into the catalyst 13, a temperature sensor 15 that detects the temperature of the exhaust gas passing through the catalyst 7, and an output signal a from the temperature sensor 15 is input, and When it is determined based on the output signal a that the temperature of the exhaust gas passing through the catalyst 7 is equal to or higher than a predetermined temperature, the switching valve 14 is switched by outputting an output signal A. It has a controller 16 for controlling. Therefore,
The exhaust gas guided into the exhaust passage 6 from the exhaust pipe 3 is
After passing through the catalyst 7 and being purified, the exhaust gas is discharged to the outside, and if the temperature of the exhaust gas is below a predetermined temperature, the switching valve 14 is switched based on the output signal outputted from the controller 16. The exhaust gas is arranged to be introduced into the cold exhaust passage 13.13.

なお、本実施例においては、図示のように、上記低温用
排気通路13.13および開口部8a、8aを夫々2箇
所づつ設けたけれども、必要におうじて適宜それらの数
を増加させても良い。また、上記吸着室9内に充填され
る吸着材1oとしては、例えば金属繊維等が考えられる
In this embodiment, as shown in the figure, the low-temperature exhaust passages 13.13 and the openings 8a, 8a are provided at two locations each, but the number may be increased as necessary. . Further, as the adsorbent 1o filled in the adsorption chamber 9, for example, metal fibers or the like can be considered.

上記の構成によれば、エンジン始動直後等の冷間期にお
いて該エンジン1より排出される排気ガスの低温時には
、切替バルブ14が第2図に実線で示す状態に切り替え
られることにより、排気通路6における触媒7の上流側
より分岐して吸着材・10が充填された吸着室9および
連通室12を経て触媒7に排気ガスを導入する低温用排
気通路13.13にのみ排気ガスが導入されることにな
って、これにより、上記吸着室9内に充填された吸着材
10により排気ガス中に含まれるアルデヒドもしくはメ
タノールを燃料として使用した場合における未燃メタノ
ール等の特に問題となる所定の成分が確実に吸着除去さ
れることになる。しがも、該低温用排気通路13.13
を介して上記吸着室9および連通室12に導入された排
気ガスにより上記触媒7が周囲から暖められて排気ガス
に対する浄化作用を良好に発揮する所定の温度以上に速
やかに加熱されることになる。そし7て、上記−10= 低温用排気通路13.13より吸着室9および連通室1
2を経て触媒7に導入される排気カスの温度か、温度セ
ンサ15により所定の温度以上に達したことか検出され
た場合には、上記切替ハルツ14が、コントローラ16
より出力される出力信号すに応して切り替えられて、第
2図に鎖線て示ず状態となり排気ガスが排気通路6より
直接触媒7に導入されて該排気カスか浄化されると共に
、旦 一奄上記吸着材]Oにより補足されたアルデヒドもしく
は未燃メタノール等か」1記触媒7の温度上昇に伴って
吸着材10より脱気して該触媒7により確実に浄化され
ることになる。これにより、エンジン1の高負荷時ある
いは高速時等における排圧上昇を招くことなく確実に排
気ガスを浄fヒすることが可能となる。
According to the above configuration, when the exhaust gas discharged from the engine 1 is at a low temperature in a cold period such as immediately after engine startup, the switching valve 14 is switched to the state shown by the solid line in FIG. The exhaust gas is introduced only into the low temperature exhaust passage 13.13 which branches from the upstream side of the catalyst 7 and introduces the exhaust gas into the catalyst 7 through the adsorption chamber 9 filled with adsorbent 10 and the communication chamber 12. As a result, the adsorbent 10 filled in the adsorption chamber 9 removes certain components that are particularly problematic, such as unburned methanol when aldehyde or methanol contained in the exhaust gas is used as fuel. It will definitely be removed by adsorption. However, the low temperature exhaust passage 13.13
The catalyst 7 is warmed from its surroundings by the exhaust gas introduced into the adsorption chamber 9 and the communication chamber 12 through the catalyst 7, and is quickly heated to a predetermined temperature or higher at which the exhaust gas purifying effect is effectively exerted. . 7, above -10 = adsorption chamber 9 and communication chamber 1 from low temperature exhaust passage 13.13
When it is detected by the temperature sensor 15 that the temperature of the exhaust gas introduced into the catalyst 7 via the controller 16 has reached a predetermined temperature or higher,
The switch is made in response to the output signal outputted from the converter, and a state not shown by the chain line in FIG. 1. As the temperature of the catalyst 7 increases, the adsorbent 10 degass the aldehyde or unburned methanol supplemented by O, and is reliably purified by the catalyst 7. This makes it possible to reliably purify exhaust gas without causing an increase in exhaust pressure when the engine 1 is under high load or at high speed.

(発明の効果) 以」二のように、本発明に係るアルコール燃料エンジン
の排気ガス浄化装置によれば、エンジン始動時あるいは
低負荷時等のエンジン冷間期において排出される排気カ
ス中に含有されるアルデヒドもしくは未燃メタノール等
の特に問題となる所定の成分を確実に除去できると共に
、エンジン高負荷時においても排気圧力の上昇を招くこ
となく確実に排気ガスを良好に浄化することか可能とな
る。
(Effects of the Invention) As described in Part 2 below, according to the exhaust gas purification device for an alcohol-fueled engine according to the present invention, the exhaust gas contained in the exhaust gas emitted during the cold period of the engine such as when starting the engine or during low load is reduced. It is possible to reliably remove specific components that are particularly problematic, such as aldehydes or unburned methanol, and to purify exhaust gas reliably without causing an increase in exhaust pressure even when the engine is under high load. Become.

【図面の簡単な説明】[Brief explanation of the drawing]

図面は本発明の実施例を示すものて、第1図は本実施例
に係る排気ガス浄1ヒ装置が備えちれたアルコール燃料
エンジンの概略側面図、第2図は該実施例の排気ガス浄
化装置を示す拡大縦断面図、第3図は第2図におけるl
−111切断線よりみた排気カス浄化装置の要部断面図
である。 1・・アルコール燃料エンジン、3・・・排気管、4・
・・排気ガス浄化装置、6 排気通路、7触媒、8・・
触媒装置(触媒装置本体)、9吸着室、10・吸着材、
13 低温用排気通路、14・切替バルブ。
The drawings show an embodiment of the present invention; FIG. 1 is a schematic side view of an alcohol fuel engine equipped with an exhaust gas purification device according to the embodiment, and FIG. An enlarged vertical cross-sectional view showing the purification device, FIG. 3 is the l in FIG.
It is a sectional view of the main part of the exhaust gas purification device as seen from the -111 cutting line. 1. Alcohol fuel engine, 3. Exhaust pipe, 4.
・・Exhaust gas purification device, 6 exhaust passage, 7 catalyst, 8・・
Catalyst device (catalyst device main body), 9 adsorption chamber, 10 adsorbent,
13 Low temperature exhaust passage, 14 switching valve.

Claims (1)

【特許請求の範囲】[Claims] (1)アルコールまたはアルコール系の燃料を使用する
アルコール燃料エンジンの排気ガス浄化装置であって、
上記エンジン本体に接続された排気通路の途中に設けら
れて排気ガスを浄化する触媒装置と、該触媒装置の外周
囲に設けられて排気ガス中の所定成分を吸着除去する吸
着材が充填された吸着室と、上記排気通路における触媒
装置の上流側より分岐して上記吸着室を経て触媒装置に
排気ガスを導入する低温用排気通路と、該低温用排気通
路分岐部の下流側であって上記触媒装置の上流側におけ
る排気通路に設けられて排気ガス低温時に該排気通路を
閉じて低温用排気通路にのみ排気ガスを導入する切替バ
ルブとが備えられていることを特徴とするアルコール燃
料エンジンの排気ガス浄化装置。
(1) An exhaust gas purification device for an alcohol fuel engine that uses alcohol or alcohol-based fuel,
A catalyst device is provided in the middle of an exhaust passage connected to the engine body to purify exhaust gas, and an adsorbent is provided around the outside of the catalyst device and is filled with an adsorbent to adsorb and remove predetermined components in the exhaust gas. an adsorption chamber, a low-temperature exhaust passage that branches from the upstream side of the catalyst device in the exhaust passage and introduces exhaust gas into the catalyst device through the adsorption chamber, and a low-temperature exhaust passage that is downstream of the branched part of the low-temperature exhaust passage and that An alcohol fuel engine characterized in that the switching valve is provided in the exhaust passage on the upstream side of the catalyst device and closes the exhaust passage when the exhaust gas is at a low temperature and introduces the exhaust gas only into the low-temperature exhaust passage. Exhaust gas purification device.
JP63084487A 1988-04-05 1988-04-05 Exhaust gas purifying device for alcohol fuel engine Pending JPH01257710A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63084487A JPH01257710A (en) 1988-04-05 1988-04-05 Exhaust gas purifying device for alcohol fuel engine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63084487A JPH01257710A (en) 1988-04-05 1988-04-05 Exhaust gas purifying device for alcohol fuel engine

Publications (1)

Publication Number Publication Date
JPH01257710A true JPH01257710A (en) 1989-10-13

Family

ID=13832009

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63084487A Pending JPH01257710A (en) 1988-04-05 1988-04-05 Exhaust gas purifying device for alcohol fuel engine

Country Status (1)

Country Link
JP (1) JPH01257710A (en)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH041617U (en) * 1989-12-27 1992-01-08
US5303547A (en) * 1992-04-15 1994-04-19 Amoco Corporation Emissions control system and method
US5315824A (en) * 1991-08-29 1994-05-31 Toyota Jidosha Kabushiki Kaisha Cold HC adsorption and removal apparatus for an internal combustion engine
US5335492A (en) * 1991-03-21 1994-08-09 Schwaebische Huettenwerke Gmbh Exhaust gas filter and/or a catalytic converter
US5388405A (en) * 1991-09-30 1995-02-14 Hitachi, Ltd. System for purifying exhaust gas for use in an automobile
JPH07189670A (en) * 1993-12-24 1995-07-28 Agency Of Ind Science & Technol Exhaust emission control method for methanol mixed fuel for automobile
US5490382A (en) * 1992-09-25 1996-02-13 Sanshin Kogyo Kabushiki Kaisha Catalyzer support system for exhaust cleaning of outboard motor
US5497619A (en) * 1993-07-06 1996-03-12 Nippon Soken, Inc. Exhaust gas purification apparatus
EP0718479A1 (en) * 1994-12-19 1996-06-26 Automobiles Peugeot Device to treat the exhaust gases of a diesel engine comprising a catalytic converter and an adsorber of hydrocarbons, placed in the interior of an exhaust manifold
EP0718478A1 (en) * 1994-12-19 1996-06-26 Automobiles Peugeot Device to treat the exhaust gases of a diesel engine comprising a catalytic converter and an adsorber of nitrogen oxydes, placed in the exhaust manifold
US5738832A (en) * 1993-02-15 1998-04-14 Mitsubishi Jidosha Kogyo Kabushiki Kaisha Exhaust gas purifying apparatus
US5787707A (en) * 1994-08-02 1998-08-04 Corning Incorporated In-line adsorber system
US5934069A (en) * 1995-06-08 1999-08-10 Corning Incorporated In-line adsorber system
EP1013902A2 (en) * 1998-12-22 2000-06-28 Toyota Jidosha Kabushiki Kaisha Emission control apparatus of an internal combustion engine and method of control therefor
US6089014A (en) * 1990-06-08 2000-07-18 Corning Incorporated Engine exhaust system with reduced hydrocarbon emissions
US6171556B1 (en) 1992-11-12 2001-01-09 Engelhard Corporation Method and apparatus for treating an engine exhaust gas stream
US6321530B1 (en) 1999-04-20 2001-11-27 Toyota Jidosha Kabushiki Kaisha Exhaust gas purifier and method of purifying exhaust gas for a hybrid vehicle

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH041617U (en) * 1989-12-27 1992-01-08
US6089014A (en) * 1990-06-08 2000-07-18 Corning Incorporated Engine exhaust system with reduced hydrocarbon emissions
US5335492A (en) * 1991-03-21 1994-08-09 Schwaebische Huettenwerke Gmbh Exhaust gas filter and/or a catalytic converter
US5315824A (en) * 1991-08-29 1994-05-31 Toyota Jidosha Kabushiki Kaisha Cold HC adsorption and removal apparatus for an internal combustion engine
US5937637A (en) * 1991-09-30 1999-08-17 Hitachi, Ltd. System for purifying exhaust gas for use in an automobile
US5388405A (en) * 1991-09-30 1995-02-14 Hitachi, Ltd. System for purifying exhaust gas for use in an automobile
US5560201A (en) * 1991-09-30 1996-10-01 Hitachi, Ltd. System for purifying exhaust gas for use in an automobile
US5303547A (en) * 1992-04-15 1994-04-19 Amoco Corporation Emissions control system and method
US5609832A (en) * 1992-04-15 1997-03-11 Amoco Corporation Emissions control system and method
US5660800A (en) * 1992-04-15 1997-08-26 Amoco Corporation Emissions control system and method
US5490382A (en) * 1992-09-25 1996-02-13 Sanshin Kogyo Kabushiki Kaisha Catalyzer support system for exhaust cleaning of outboard motor
US6171556B1 (en) 1992-11-12 2001-01-09 Engelhard Corporation Method and apparatus for treating an engine exhaust gas stream
US5738832A (en) * 1993-02-15 1998-04-14 Mitsubishi Jidosha Kogyo Kabushiki Kaisha Exhaust gas purifying apparatus
US5497619A (en) * 1993-07-06 1996-03-12 Nippon Soken, Inc. Exhaust gas purification apparatus
JPH07189670A (en) * 1993-12-24 1995-07-28 Agency Of Ind Science & Technol Exhaust emission control method for methanol mixed fuel for automobile
US5787707A (en) * 1994-08-02 1998-08-04 Corning Incorporated In-line adsorber system
EP0718478A1 (en) * 1994-12-19 1996-06-26 Automobiles Peugeot Device to treat the exhaust gases of a diesel engine comprising a catalytic converter and an adsorber of nitrogen oxydes, placed in the exhaust manifold
EP0718479A1 (en) * 1994-12-19 1996-06-26 Automobiles Peugeot Device to treat the exhaust gases of a diesel engine comprising a catalytic converter and an adsorber of hydrocarbons, placed in the interior of an exhaust manifold
US5934069A (en) * 1995-06-08 1999-08-10 Corning Incorporated In-line adsorber system
EP1013902A2 (en) * 1998-12-22 2000-06-28 Toyota Jidosha Kabushiki Kaisha Emission control apparatus of an internal combustion engine and method of control therefor
US6397586B1 (en) 1998-12-22 2002-06-04 Toyota Jidosha Kabushiki Kaisha Emission control apparatus and method of internal combustion engine
EP1013902A3 (en) * 1998-12-22 2003-01-22 Toyota Jidosha Kabushiki Kaisha Emission control apparatus of an internal combustion engine and method of control therefor
US6321530B1 (en) 1999-04-20 2001-11-27 Toyota Jidosha Kabushiki Kaisha Exhaust gas purifier and method of purifying exhaust gas for a hybrid vehicle

Similar Documents

Publication Publication Date Title
JPH01257710A (en) Exhaust gas purifying device for alcohol fuel engine
EP0846491A3 (en) Method and system for exhaust gas purification
JPH05231138A (en) Exhaust emission control device for automobile
JPS6368713A (en) Exhaust emission control device for engine
US3808806A (en) Exhaust gas purifying device
SE501464C2 (en) Device for catalytic cleaning of exhaust gases from IC engine - comprises first catalyser placed downstream of engine, an HC trap, and second catalyser arranged in connection with HC trap
JPH1089054A (en) Exhaust emission control device foe diesel engine
US4202173A (en) Secondary air supplying device of an internal combustion engine
JPS5979024A (en) Exhaust-gas purifying apparatus for diesel engine
JPS62189309A (en) Unburnt fuel purifier for alcohol fuel vehicle
JPH06137141A (en) Exhaust gas purifying device for engine
JP3218672B2 (en) Exhaust gas purification device for internal combustion engine
JP3629953B2 (en) Exhaust gas purification device for internal combustion engine
JP3685809B2 (en) Engine exhaust purification system
JPS58140432A (en) Number of cylinder control engine
JPH0286910A (en) Exhaust gas purification device for internal combustion engine using alcohol
JPH0742538A (en) Exhaust emission control device for vehicle
JPH0544447A (en) Exhaust gas purifying device and exhaust gas purifying method for engine
JP2007056756A (en) Exhaust emission control system for internal combustion engine
KR0149401B1 (en) Exhaust system of an automotive engine
JPH0511294Y2 (en)
KR100379307B1 (en) Exhausting system for gasoline engine
JPS62191609A (en) Unburnt fuel purifing device of alcohol fuel vehicle
JPS6024898Y2 (en) Engine secondary air control device
JPH05321654A (en) Exhaust emission control device for engine