JPH01223416A - Electrode plate for display device and its production - Google Patents

Electrode plate for display device and its production

Info

Publication number
JPH01223416A
JPH01223416A JP63050355A JP5035588A JPH01223416A JP H01223416 A JPH01223416 A JP H01223416A JP 63050355 A JP63050355 A JP 63050355A JP 5035588 A JP5035588 A JP 5035588A JP H01223416 A JPH01223416 A JP H01223416A
Authority
JP
Japan
Prior art keywords
laminating
transparent
display device
coupling agent
order
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP63050355A
Other languages
Japanese (ja)
Inventor
Kenzo Fukuyoshi
健蔵 福吉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toppan Inc
Original Assignee
Toppan Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toppan Printing Co Ltd filed Critical Toppan Printing Co Ltd
Priority to JP63050355A priority Critical patent/JPH01223416A/en
Publication of JPH01223416A publication Critical patent/JPH01223416A/en
Pending legal-status Critical Current

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  • Liquid Crystal (AREA)

Abstract

PURPOSE:To prevent generation of wrinkling and blistering by laminating a transparent substrate, color filters, an over coat layer on which a coupling agent is provided, and a transparent electrode in this order. CONSTITUTION:The color filters 6 of three colors; green (G), red (R), blue (B) is formed on the transparent substrate of float glass having 1mm thickness. A photosensitive resin which is epoxy is coated on these color filters 6 so as to attain about 1mum film thickness after drying. After the coating is exposed by UV rays, the unexposed part is developed and removed by an aq. 1% sodium carbonate soln. and the protective layer 2 is formed by patterning to a rectangular shape so as to cover nearly the entire surface of the color filters. The aminosilane coupling agent is thereafter spin-coated by a spinner thereon. The transparent electrode 4 is then formed by sputtering and nickel, aluminum, chromium, and ITO are patterned in this order by the wet process etching used for laminating a thin metallic film 5, by which the electrodes of the display device for a color liquid crystal are formed. The generation of the wrinkling and blistering is thereby prevented.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 本発明はカラー液晶デイスプレィを用いた表示入力装置
などに用いられる表示装置用電極板の製造方法に関する
DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a method of manufacturing an electrode plate for a display device used in a display input device using a color liquid crystal display.

〈従来の技術〉 液晶デイスプレィは、高密度表示のため画素や端子部の
ピッチが1100I1付近まで要求されるようになって
きている。同時に大画面化しつつある。
<Prior Art> In order to display high-density liquid crystal displays, pitches of pixels and terminal parts are required to be around 1100I1. At the same time, screens are becoming larger.

従って、液晶駆動の観点から透明電極の低抵抗化と、薄
型化という観点から駆動用ICとの表面実装という2つ
の要求が特に強くなってきている。
Therefore, two demands are becoming particularly strong: low resistance of transparent electrodes from the viewpoint of driving liquid crystals, and surface mounting with driving ICs from the viewpoint of thinning.

これら要求を満足させるため、透明電極の一部に低抵抗
化のための補助導体として、数十μm幅の金属薄膜の細
線パターンを設け、あるいは液晶パネルの端子部に、金
属薄膜を形成し、表面実装用途に対応することは公知の
技術である。
In order to satisfy these demands, a fine line pattern of a thin metal film with a width of several tens of micrometers is provided on a part of the transparent electrode as an auxiliary conductor to reduce resistance, or a thin metal film is formed on the terminal part of the liquid crystal panel. It is a known technology to accommodate surface mount applications.

カラー液晶デイスプレィにおいて、カラーフィルターの
上に透明電極を形成したものより液晶駆動の点及び表示
品位の点で格段に優れている。透明電極をエツチングに
よりパタニングするため・カラーフィルターに耐酸性を
付与する目的でカラーフィルターと透明電極の間に有機
樹脂の保護層を設けることは一般に行われている。
In color liquid crystal displays, this display is significantly superior to those in which transparent electrodes are formed on color filters in terms of liquid crystal driving and display quality. In order to pattern the transparent electrode by etching and for the purpose of imparting acid resistance to the color filter, a protective layer of organic resin is generally provided between the color filter and the transparent electrode.

〈発明が解決しようとする課題〉 印刷や染色により形成されたカラーフィルターの上に有
機樹脂の保護層を形成して後、さらに該保護層の上に透
明電極を形成した電極板は、後工程の熱処理でシワやフ
クレを発生する欠点があった。
<Problems to be Solved by the Invention> An electrode plate in which a protective layer of organic resin is formed on a color filter formed by printing or dyeing, and then a transparent electrode is further formed on the protective layer, can be produced in a subsequent process. It has the disadvantage of causing wrinkles and blisters during heat treatment.

それに対してポリイミドやシリコン系の樹脂は耐熱性が
あるものの、きわめて高価であり保護層材料として採用
できない、また、これら耐熱性樹脂をカラーフィルター
電極板全面にコーティングしては、電極板端部からの電
気的接続に問題が生じてしまう、それは、透明電極と基
板の間に樹脂層があるため、上からの圧力で透明電極に
傷をつけ易いためである。
On the other hand, although polyimide and silicone resins are heat resistant, they are extremely expensive and cannot be used as protective layer materials; A problem arises in the electrical connection of the transparent electrode because there is a resin layer between the transparent electrode and the substrate, and the transparent electrode is easily damaged by pressure from above.

本発明者は上記の問題を解決するためグリユー、ゼラチ
ンやカゼインなどポリペプチド感光性樹脂もしくは、フ
ェノールボラック系エポキシ樹脂骨格とする感光性樹脂
を保護層として用いた、新規な電極板を提案した。しか
しながら、この電極板はほぼ実用レベルにあるものの、
一部に透明電極と、保護層やガラスの透明基板との接着
力が弱いものがあった。また、ゼラチンなどペプチド樹
脂の保護層との接着力を高めるため、この保護層表面を
逆スパツタ処理する事で、スパッタリングによる表面ク
リーニング及び重合度の促進させる必要があった。しか
し、逆スパツタの機構は装置コストを高めるとともに、
その処理は電極板の生産能力を低下させる欠点があった
0本発明は、逆スパツタ処理によらない保護層表面を処
理する方法及び物を、提供しようとするものである。
In order to solve the above-mentioned problems, the present inventor proposed a new electrode plate using a polypeptide photosensitive resin such as gris, gelatin, or casein, or a photosensitive resin with a phenol borac epoxy resin skeleton as a protective layer. . However, although this electrode plate is almost at a practical level,
In some cases, the adhesion between the transparent electrode and the protective layer or glass transparent substrate was weak. In addition, in order to increase the adhesion to the protective layer of peptide resin such as gelatin, it was necessary to perform reverse sputtering on the surface of this protective layer to promote surface cleaning and polymerization by sputtering. However, the reverse sputtering mechanism not only increases the equipment cost, but also
This treatment has the disadvantage of reducing the production capacity of electrode plates.The present invention seeks to provide a method and product for treating the surface of a protective layer without using reverse sputtering.

〈課題を解決するための手段〉 本発明は、透明な基板にカラーフィルターと、オーバー
コート層と、透明電極とをこの順で積層する表示装置用
電極板の製造方法において、オーバーコート層の表面を
カップリング剤で表面処理して後、透明電極を形成する
ことを特徴とする表示装置用電極板およびその製造方法
である0本発明は、使用される表示装置の種類に応じて
、さらに透明電極の上に一部重畳するように金属薄膜を
形成しても良い、また、必要に応じて不純物が表面に付
着しないように、オーバーコート層と透明電極との間に
無機酸化物層を挿入しても良い。
<Means for Solving the Problems> The present invention provides a method for manufacturing an electrode plate for a display device in which a color filter, an overcoat layer, and a transparent electrode are laminated in this order on a transparent substrate. The present invention relates to an electrode plate for a display device and a method for manufacturing the same, which is characterized in that a transparent electrode is formed after surface treatment with a coupling agent. A thin metal film may be formed to partially overlap the electrode, and if necessary, an inorganic oxide layer may be inserted between the overcoat layer and the transparent electrode to prevent impurities from adhering to the surface. You may do so.

尚、本発明に用いるカラーフィルターは、フォトグラフ
ィの手法で形成したもの、印刷により形成したものなど
方法、材料は限定するものでない。
Note that the color filter used in the present invention may be formed by a photography method or by printing, and the method and material thereof are not limited.

オーバーコート層材料は150℃以上の耐熱性があるこ
とが望ましいが、透明な有機材料であれば良い、先述し
たペプチド樹脂、エポキシ樹脂の他、ポリイミド、シリ
コンも使用可能であるオーバーコート層の厚みは数百人
〜数十μの範囲内が実用的である。透明電極は、透明な
良導体であれば良く無機・有機の材料を問わない、また
、本発明に用いるカップリング剤はシランカップリング
剤、カラオニックシラン、ロチオニツクシラン、シリル
イソシアネート化合物、アルミニウム系・チタネート系
・ジルコネート系カップリング剤等下地であるオーバー
コート層の材料や表面状態によって使い分けることが必
要で特に限定するものでない。また、金属薄膜は透明電
極の低抵抗化のための補助導体として、また、電極板端
部で液晶駆動用のICなどの表面実装やコネクターとの
電気的接続を取るために形成するものであり、これら目
的に合う材料であれば良い、また、金属薄膜は電極板の
使用条件によっては形成しなくとも良い。
It is desirable that the overcoat layer material has heat resistance of 150°C or higher, but any transparent organic material is sufficient. In addition to the aforementioned peptide resins and epoxy resins, polyimide and silicone can also be used. Thickness of the overcoat layer It is practical to range from several hundred to several tens of microns. The transparent electrode may be made of any inorganic or organic material as long as it is transparent and has good conductivity.The coupling agent used in the present invention may be a silane coupling agent, a coloronic silane, a rotionic silane, a silyl isocyanate compound, or an aluminum-based material. - Titanate-based/zirconate-based coupling agents, etc. It is necessary to use them depending on the material and surface condition of the underlying overcoat layer, and there are no particular limitations. In addition, the metal thin film is formed as an auxiliary conductor to reduce the resistance of the transparent electrode, and to make electrical connections with surface mounting devices such as LCD drive ICs and connectors at the ends of the electrode plates. , any material may be used as long as it meets these purposes, and the metal thin film may not be formed depending on the usage conditions of the electrode plate.

さらに、本発明はカラーフィルターやオーバーコート材
料からの不純物の液晶中への溶出を避けるためSiO□
、Ti0z、−go、A1.0.などの無機酸化物層を
オーバーコート層の上に積層しても良いる無機酸化物層
は透明な材料であれば良く、特に限定する必要もない、
また、電極板の使用条件によっては形成しなくとも良い
0本発明を実施例に基き詳細に説明する。
Furthermore, in order to avoid elution of impurities from color filters and overcoat materials into liquid crystal, the present invention uses
, Ti0z, -go, A1.0. An inorganic oxide layer such as may be laminated on the overcoat layer.The inorganic oxide layer may be made of a transparent material and does not need to be particularly limited.
Further, the present invention, which may not be formed depending on the usage conditions of the electrode plate, will be described in detail based on examples.

〈実施例〉 第1図は、本発明による液晶表示装置用を掻板の模式断
面図である。厚さlamのフロートガラス(青板)であ
る透明な基板(1)に、公知の技術である印刷力によっ
て緑(G)、赤(R)、青(B) と順次3色のカラー
フィルター(6)を形成した。厚みは約2μmである。
<Example> FIG. 1 is a schematic cross-sectional view of a scraping plate for a liquid crystal display device according to the present invention. Color filters of three colors (green (G), red (R), blue (B)) are sequentially applied to a transparent substrate (1), which is a lam-thick float glass (blue plate), using a known printing technique. 6) was formed. The thickness is approximately 2 μm.

このカラーフィルター(6)上に、フェノールノボラッ
ク系エポキシの感光性樹脂を乾燥後の膜厚で約ll1m
になるようコーティングした0次に、紫外線で露光後、
未露光部を炭酸ナトリウム1%水溶液で現像除去し、カ
ラーフィルターをほぼ全面覆うよう矩形状にパタニング
形成し保護層(2)とした。この後、日本チバガイギー
製のアミノシランカップリング剤(商品名QZ3289
/3290)をスピナーにて回転塗布した0次にスパッ
タリングの手法で800人、ITOとよばれる透明電極
(4)を、蒸着によりクロムを800人、アルミニウム
を1400人、ニッケルを800人として金属薄膜(5
)を積層した公知の湿式のエツチングにより、ニッケル
、アルミニウム、クロム、ITOをこの順でパタニング
を行ない、カラー液晶用の表示装置用電極とした。
On this color filter (6), a photosensitive resin of phenol novolac type epoxy is applied with a film thickness of approximately 11 m after drying.
After being exposed to ultraviolet light,
The unexposed areas were developed and removed with a 1% sodium carbonate aqueous solution, and a rectangular pattern was formed to cover almost the entire color filter to form a protective layer (2). After this, an aminosilane coupling agent (product name QZ3289 manufactured by Nippon Ciba Geigy) was applied.
A transparent electrode called ITO (4) was made by vapor deposition using 800 layers of chromium, 1400 layers of aluminum, and 800 layers of nickel using a zero-order sputtering method using a spinner. (5
) were laminated and patterned with nickel, aluminum, chromium, and ITO in this order by known wet etching to obtain an electrode for a color liquid crystal display device.

以上の実施例に於いて、カラーフィルターの形成を印刷
にて行った例を示したが、フォトリソグラフィの手法で
顔料カラーフィルターや染色カラーフィルターを形成し
たものでも良い、また、オーバーコート材料はカゼイン
やゼラチンでも可能である。また、ペプチド樹脂でオー
バーコート層を形成する場合は、該オーバーコート層の
上に無機酸化物層を形成した方が、平坦化の点では有利
である。また、金属薄膜は上記の材料の他、銅、銀、金
なのどの良導体が好ましく、また合金の薄膜でも良い、
ra部にめっきにて形成することも可能である。加えて
、小型の液晶デイスプレィの場合、金属薄膜の形成を省
略しても良い。
In the above embodiments, the color filters were formed by printing, but pigment color filters or dyed color filters may also be formed by photolithography.Also, the overcoat material may be casein. It is also possible to use gelatin. Further, when an overcoat layer is formed using a peptide resin, it is advantageous in terms of planarization to form an inorganic oxide layer on the overcoat layer. In addition to the above-mentioned materials, the metal thin film is preferably a good conductor such as copper, silver, or gold, and may also be an alloy thin film.
It is also possible to form the ra portion by plating. Additionally, in the case of a small liquid crystal display, the formation of a metal thin film may be omitted.

〈発明の効果〉 本発明は、透明電極や無機酸化物層の積層前にカップリ
ング剤にてオーバーコート層や透明な基板の表面を表面
処理するため、透明電極のや無機酸化物層との接着力が
格段に向上する。従来、液晶パネルシール後のセル折り
プロセスで生じていた透明電極や、無機酸化物層の膜ハ
ガレを本発明により解消し得た。また、従来必要であっ
た逆スパツタ処理も必要でなくなり、生産性を向上でき
た。加えて、カップリング剤をコーティングすることに
より、基板表面の平滑化も若干向上し、透明電極の抵抗
値が10%〜30%程度改善するという副次効果が得ら
れた。
<Effects of the Invention> In the present invention, the overcoat layer and the surface of the transparent substrate are surface-treated with a coupling agent before laminating the transparent electrode and the inorganic oxide layer. Adhesive strength is significantly improved. The present invention can eliminate the peeling of transparent electrodes and inorganic oxide layers that conventionally occurred during the cell folding process after sealing a liquid crystal panel. In addition, the conventionally necessary reverse sputtering process is no longer necessary, improving productivity. In addition, by coating with the coupling agent, the smoothness of the substrate surface was slightly improved, and the secondary effect was that the resistance value of the transparent electrode was improved by about 10% to 30%.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明による表示装置用電極板の模式断面図で
ある。 ■・・・透明基板 2・・・保護層 4・・・透明電極 5・・・金属薄膜°層 特  許  出  願  人 凸版印刷株式会社 代表者 鈴木和夫
FIG. 1 is a schematic cross-sectional view of an electrode plate for a display device according to the present invention. ■...Transparent substrate 2...Protective layer 4...Transparent electrode 5...Metal thin film layer Patent application Person Toppan Printing Co., Ltd. Representative Kazuo Suzuki

Claims (1)

【特許請求の範囲】 1)透明基板と、カラーフィルターと、表面にカップリ
ング剤が設けられているオーバーコート層と、透明電極
とがこの順で積層されている表示装置用電極板。 2)順に、透明基板にカラーフィルターを積層する工程
と、オーバーコート層を積層する工程と、オーバーコー
ト層の表面をカップリング剤で表面処理する工程と、透
明電極を積層する工程と、によりなる表示装置用電極板
の製造方法。 3)透明基板と、カラーフィルターと、表面にカップリ
ング剤が設けられているオーバーコート層と、透明電極
と、透明電極と一部重畳する金属薄膜と、がこの順で積
層されている表示装置用電極板。 4)順に、透明基板にカラーフィルターを積層する工程
と、オーバーコート層を積層する工程と、オーバーコー
ト層の表面をカップリング剤で表面処理する工程と、透
明電極を積層する工程と、透明電極と一部重畳する金属
薄膜を積層する工程と、によりなる表示装置用電極板の
製造方法。 5)透明基板と、カラーフィルターと、表面にカップリ
ング剤が設けられているオーバーコート層と、無機酸化
物層と、透明電極とがこの順で積層されている表示装置
用電極板。6)順に、透明基板にカラーフィルターを積
層する工程と、オーバーコート層を積層する工程と、オ
ーバーコート層の表面をカップリング剤で表面処理する
工程と、無機酸化物層を積層する工程と、透明電極を積
層する工程と、によりなる表示装置用電極板の製造方法
。 7)透明基板と、カラーフィルターと、表面にカップリ
ング剤が設けられているオーバーコート層と、無機酸化
物層と、透明電極とがこの順で積層されている表示装置
用電極板。8)順に、透明基板にカラーフィルターを積
層する工程と、オーバーコート層を積層する工程と、オ
ーバーコート層の表面をカップリング剤で表面処理する
工程と、無機酸化物層を積層する工程と、透明電極を積
層する工程と、によりなる表示装置用電極板の製造方法
[Scope of Claims] 1) An electrode plate for a display device, in which a transparent substrate, a color filter, an overcoat layer whose surface is provided with a coupling agent, and a transparent electrode are laminated in this order. 2) Consists of, in order, a step of laminating a color filter on a transparent substrate, a step of laminating an overcoat layer, a step of surface treating the surface of the overcoat layer with a coupling agent, and a step of laminating a transparent electrode. A method for manufacturing an electrode plate for a display device. 3) A display device in which a transparent substrate, a color filter, an overcoat layer whose surface is provided with a coupling agent, a transparent electrode, and a metal thin film partially overlapping the transparent electrode are laminated in this order. Electrode plate for use. 4) In order, a step of laminating a color filter on a transparent substrate, a step of laminating an overcoat layer, a step of surface treating the surface of the overcoat layer with a coupling agent, a step of laminating a transparent electrode, and a step of laminating a transparent electrode. A method for manufacturing an electrode plate for a display device, comprising the steps of: laminating a metal thin film that partially overlaps the above. 5) An electrode plate for a display device, in which a transparent substrate, a color filter, an overcoat layer whose surface is provided with a coupling agent, an inorganic oxide layer, and a transparent electrode are laminated in this order. 6) In order, a step of laminating a color filter on a transparent substrate, a step of laminating an overcoat layer, a step of surface treating the surface of the overcoat layer with a coupling agent, a step of laminating an inorganic oxide layer, A method for manufacturing an electrode plate for a display device, comprising a step of laminating transparent electrodes. 7) An electrode plate for a display device, in which a transparent substrate, a color filter, an overcoat layer whose surface is provided with a coupling agent, an inorganic oxide layer, and a transparent electrode are laminated in this order. 8) In order, a step of laminating a color filter on a transparent substrate, a step of laminating an overcoat layer, a step of surface treating the surface of the overcoat layer with a coupling agent, a step of laminating an inorganic oxide layer, A method for manufacturing an electrode plate for a display device, comprising a step of laminating transparent electrodes.
JP63050355A 1988-03-03 1988-03-03 Electrode plate for display device and its production Pending JPH01223416A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63050355A JPH01223416A (en) 1988-03-03 1988-03-03 Electrode plate for display device and its production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63050355A JPH01223416A (en) 1988-03-03 1988-03-03 Electrode plate for display device and its production

Publications (1)

Publication Number Publication Date
JPH01223416A true JPH01223416A (en) 1989-09-06

Family

ID=12856592

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63050355A Pending JPH01223416A (en) 1988-03-03 1988-03-03 Electrode plate for display device and its production

Country Status (1)

Country Link
JP (1) JPH01223416A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04326328A (en) * 1991-04-26 1992-11-16 Nec Corp Liquid crystal display device and color filter substrate
JP2003066215A (en) * 2001-08-23 2003-03-05 Sumitomo Chem Co Ltd Color filter with protective film
US6559066B2 (en) 1996-08-02 2003-05-06 Sharp Kabushiki Kaisha Substrate for use in display element, method of manufacturing the same, and apparatus for manufacturing the same

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Publication number Priority date Publication date Assignee Title
JPS5579413A (en) * 1978-12-11 1980-06-14 Seiko Epson Corp Liquid crystal display body
JPS613121A (en) * 1984-06-15 1986-01-09 Nec Corp Liquid crystal cell
JPS61123578A (en) * 1984-11-20 1986-06-11 Toppan Printing Co Ltd Production of decorative board
JPS6344628A (en) * 1986-08-12 1988-02-25 Citizen Watch Co Ltd Manufacture of color liquid crystal panel
JPS6344627A (en) * 1986-08-12 1988-02-25 Citizen Watch Co Ltd Color liquid crystal panel

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5579413A (en) * 1978-12-11 1980-06-14 Seiko Epson Corp Liquid crystal display body
JPS613121A (en) * 1984-06-15 1986-01-09 Nec Corp Liquid crystal cell
JPS61123578A (en) * 1984-11-20 1986-06-11 Toppan Printing Co Ltd Production of decorative board
JPS6344628A (en) * 1986-08-12 1988-02-25 Citizen Watch Co Ltd Manufacture of color liquid crystal panel
JPS6344627A (en) * 1986-08-12 1988-02-25 Citizen Watch Co Ltd Color liquid crystal panel

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04326328A (en) * 1991-04-26 1992-11-16 Nec Corp Liquid crystal display device and color filter substrate
US6559066B2 (en) 1996-08-02 2003-05-06 Sharp Kabushiki Kaisha Substrate for use in display element, method of manufacturing the same, and apparatus for manufacturing the same
JP2003066215A (en) * 2001-08-23 2003-03-05 Sumitomo Chem Co Ltd Color filter with protective film

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