JPH01219048A - Solar heat absorptive heat insulating additive - Google Patents

Solar heat absorptive heat insulating additive

Info

Publication number
JPH01219048A
JPH01219048A JP4549188A JP4549188A JPH01219048A JP H01219048 A JPH01219048 A JP H01219048A JP 4549188 A JP4549188 A JP 4549188A JP 4549188 A JP4549188 A JP 4549188A JP H01219048 A JPH01219048 A JP H01219048A
Authority
JP
Japan
Prior art keywords
heat
solar heat
powder
additive
carbide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP4549188A
Other languages
Japanese (ja)
Inventor
Shunsaku Oji
蔭地 駿作
Masanori Fujimoto
昌則 藤本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DESANTO KK
Descente Ltd
Original Assignee
DESANTO KK
Descente Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DESANTO KK, Descente Ltd filed Critical DESANTO KK
Priority to JP4549188A priority Critical patent/JPH01219048A/en
Publication of JPH01219048A publication Critical patent/JPH01219048A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To obtain a solar heat absorptive heat insulating additive which effectively absorbs solar heat and is little in loss due to heat radiation and excellent in heat insulating properties by constituting it of carbide of transition metal belonging to group IV of the periodic table or the mixture of this carbide and Al. CONSTITUTION:A solar heat absorptive heat insulating additive is constituted of carbide of transition metal belonging to group IV of the periodic table, e.g., TiC, ZrC and HFC, etc., especially perferably ZrC or granules of the mixture of these carbides and Al. This additive is mixed with powdery building material such as cement, plaster or the other powder such as powdery interior material utilized for the walls at proper amount and used. Therefore a plane body can be constituted by applying cement or plaster on a surface to be coated. In the coated state, emissivity in an infrared region is controlled by 0.3-2.0mum wavelength of solar spectrum being characteristics of carbide of the above- mentioned transition metal and thereby solar heat selective absorptive heat insulating effect for reducing heat loss due to radiation, is exhibited.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は太陽熱選択吸収技術に係り、太陽熱を効果的に
吸収し、且つ熱放射による損失が少なく保温性に優れた
太陽熱吸収性保温添加材に関するものである。
[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to solar heat selective absorption technology, and provides a solar heat absorbing thermal insulation additive that effectively absorbs solar heat, has little loss due to thermal radiation, and has excellent heat retention properties. It is related to.

〔従来の技術〕[Conventional technology]

従来より太陽熱エネルギーの利用技術が注目されており
、金属・誘電体多層膜或は半導体反射防止膜のような多
膜系の材料が太陽熱選択吸収材として開発され、熱発電
装置などに利用されようとしている。
Technology to utilize solar thermal energy has been attracting attention for some time, and multi-layer materials such as metal/dielectric multilayer films or semiconductor anti-reflection films have been developed as solar heat selective absorbers and will be used in thermal power generation devices. It is said that

太陽放射スペクトルは、0.5μm付近にピークを持っ
ており、0.3乃至2.0μmの間に全エネルギーの9
5%を含んでいる。このため、太陽熱を選択的に吸収さ
せる物質としては0.3乃至2.0μmの波長域で吸収
が大きく、且つ2゜0μm以上の赤外域の放射率が小さ
く熱の放射損失が少ないことという条件が必要となるが
、上記金属・誘電体多層膜或は半導体反射防止膜のよう
な多膜系の太陽熱選択吸収材はこの条件を満足するもの
として使用されてきた。
The solar radiation spectrum has a peak around 0.5 μm, and 9 of the total energy is between 0.3 and 2.0 μm.
Contains 5%. For this reason, a material that selectively absorbs solar heat must have large absorption in the wavelength range of 0.3 to 2.0 μm, low emissivity in the infrared region of 2.0 μm or more, and little radiation loss of heat. However, multi-film selective solar heat absorption materials such as the metal/dielectric multilayer film or semiconductor antireflection film have been used as satisfying this condition.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

しかし上記従来の多膜系の太陽熱選択吸収材は、皮膜を
形成する工程が複雑であり、生産コストが高騰するばか
りでなく、膜面の恒久維持が困難であるため多様性に乏
しく一般工業製品への導入が難かしいものであった。殊
に構造が膜体であるため、他の粉粒体に混入して使用す
るなどの応用が不能であった。
However, the conventional multi-film selective solar heat absorbing material described above has a complicated process of forming the film, which not only increases production costs but also makes it difficult to permanently maintain the film surface, resulting in a lack of versatility and general industrial products. It was difficult to introduce it into the In particular, since it has a membrane structure, it has been impossible to use it by mixing it with other powder or granules.

本発明は上記問題に鑑み、低コストになると共に、多層
膜のような膜構造を持たない太陽熱選択吸収材として粒
状複合物質を形成し、該太陽熱選択吸収粒状複合物質を
粉粒体建築材料または粉粒体内装材料等の粉粒体と適量
を混合して使用する太陽熱吸収性保温添加材を提供する
ことを目的とするものである。
In view of the above problems, the present invention forms a granular composite material as a solar heat selective absorption material that is low in cost and does not have a membrane structure like a multilayer film, and uses the solar heat selective absorption granular composite material as a powder building material or The object of the present invention is to provide a solar heat-absorbing heat-retaining additive that can be used by mixing an appropriate amount with a powder or granule material such as a powder interior material.

〔課題を解決するための手段〕[Means to solve the problem]

即ち、本発明の太陽熱吸収性保温添加材は、周期律表第
■族に属する遷移金属の炭化物またはこの炭化物とアル
ミニウムの混合物の粒状体から成るものであり、セメン
ト等の粉粒体建築材料、またはしっくいく漆喰〉や京壁
等の粉粒体内装材料等の粉粒体と適量を混成して使用す
ることを要旨とするものである。
That is, the solar heat-absorbing heat-retaining additive of the present invention is made of a granular material of a carbide of a transition metal belonging to Group I of the periodic table or a mixture of this carbide and aluminum, and is suitable for use in granular building materials such as cement, Alternatively, the gist is to use it in an appropriate amount by mixing it with powder and granular materials such as stucco and powder interior materials such as plaster walls.

また上記他の粒状体はその粒度を比較的大きくすること
によって、遊技用砂場の砂に混入したり。
Furthermore, by making the particle size of the other granules relatively large, they can be mixed into the sand of a game sandbox.

石焼き芋用の石或は焼き栗用砂利に混入して使用するこ
とができる。
It can be used by mixing it with stones for stone-roasted sweet potatoes or gravel for roasted chestnuts.

上記周期律表第■族に属する遷移金属の炭化物としては
、TiC,ZrC,HfC等が利用でき、殊にZrCが
有用である。
As the carbide of the transition metal belonging to Group 1 of the periodic table, TiC, ZrC, HfC, etc. can be used, and ZrC is particularly useful.

〔作用〕[Effect]

本発明に係る太陽熱吸収性保温添加材は、TiC,Zr
C,HfC等の周期律表第■族に属する遷移金属の炭化
物またはこの炭化物とアルミニウムの混合粒体を、セメ
ント等の粉粒体建築材料。
The solar heat-absorbing heat-retaining additive according to the present invention includes TiC, Zr
Carbides of transition metals belonging to Group Ⅰ of the periodic table, such as C and HfC, or mixed granules of these carbides and aluminum are used as powder building materials such as cement.

または漆喰や京壁等の粉粒体内装材料等の他の粉粒体と
適量を混合して使用するものであるため、セメントや漆
喰を施工面に塗着することによって面状体を構成するこ
とができる。従って塗着した状態では、該周期律表第■
族に属する遷移金属の炭化物の特性である太陽放射スペ
クトルの0.3乃至2.0μmの波長域で大きな吸収性
能を発揮し、且つ2.0μm以上の赤外域の放射率を抑
制して熱の放射損失の減少を図るように作用する太陽熱
選択吸収保温効果を発揮する。
Alternatively, since it is used by mixing an appropriate amount with other powder and granular materials such as powder interior materials such as plaster and Kyoto walls, a planar body can be constructed by applying cement or plaster to the construction surface. be able to. Therefore, in the painted state, the periodic table ■
It exhibits great absorption performance in the wavelength range of 0.3 to 2.0 μm in the solar radiation spectrum, which is a characteristic of carbides of transition metals belonging to the group, and suppresses the emissivity in the infrared region of 2.0 μm or more. It exhibits a thermal insulation effect by selectively absorbing solar heat, which works to reduce radiation loss.

図面はZrCを薄膜状にして延展したときの光学特性曲
線であり、この膜の太陽光の吸収率は92%、赤外域の
反射率は93%であることを示している。
The drawing shows an optical characteristic curve when ZrC is spread in the form of a thin film, and shows that the absorption rate of sunlight of this film is 92% and the reflectance in the infrared region is 93%.

従って上記構成の太陽熱吸収性保温添加材は、他の粉粒
体と混合して他の構造物に被着した状態では、含有する
ZrC等の周期律表第■族に属する遷移金属の炭化物の
粒子が面状に広がることになり、上記光学特性しこ近似
した太陽熱吸収性と保温性を持つ。
Therefore, when the solar heat absorbing thermal insulation additive having the above structure is mixed with other powder and granules and applied to other structures, the carbides of transition metals belonging to Group Ⅰ of the periodic table, such as ZrC, contained therein. The particles are spread out in a planar shape, and have solar heat absorption and heat retention properties that closely approximate the optical properties described above.

〔実施例〕〔Example〕

以下、本発明に係る太陽熱吸収性保温添加材の具体的な
実施例を説明する。
Hereinafter, specific examples of the solar heat-absorbing heat-retaining additive according to the present invention will be described.

去1舛−」2 0保温セメント セメント100重量部と太陽熱吸収性保温添加材混合粉
末30重量部を混合する。
100 parts by weight of the 20 heat insulation cement and 30 parts by weight of the solar heat absorbing heat insulation additive mixed powder were mixed.

太陽熱吸収性保温添加材混合粉末は、粒径3〜5μmの
ZrC粉末5部と、粒径1〜3μmのA1粉末3部を配
合して混練したものを使用する。
The solar heat-absorbing heat-retaining additive mixed powder is a mixture of 5 parts of ZrC powder with a particle size of 3 to 5 μm and 3 parts of A1 powder with a particle size of 1 to 3 μm and kneaded together.

O保温モルタル セメント100重量部に対して川砂70重量部と太陽熱
吸収性保温添加材混合粉末を30重量部混合する。
70 parts by weight of river sand and 30 parts by weight of a solar heat-absorbing heat-insulating additive mixed powder are mixed with 100 parts by weight of O thermal insulation mortar cement.

太陽熱吸収性保温添加材混合粉末は、粒径3〜5μmの
ZrC粉末5部と、粒径1〜3μmのA1粉末3部を配
合したものを使用する。
The solar heat-absorbing thermal additive mixed powder is a mixture of 5 parts of ZrC powder with a particle size of 3 to 5 μm and 3 parts of A1 powder with a particle size of 1 to 3 μm.

上記構成のセメント又はモルタルは、製造工場または施
工現場で、必要に応じて増量材や凍結防止剤等の種々の
添加材を加えることができるものであり、川砂利を加え
てコンクリートとしても構成することができる。
Cement or mortar with the above structure can be added with various additives such as bulking agents and anti-freezing agents as needed at the manufacturing plant or construction site, and can also be made into concrete by adding river gravel. be able to.

去1」L−影 O保温壁材 合成樹脂着色粉末と和紙屑粉末の混合体から成る合成京
壁粒子100重量部に対して、糊粉末5重量部と太陽熱
吸収性保温添加材粉末20重量部を充分に混合する。
1" L-Shadow O thermal insulation wall material 5 parts by weight of glue powder and 20 parts by weight of solar heat-absorbing thermal insulation additive powder for 100 parts by weight of synthetic Kyo-wall particles made of a mixture of synthetic resin colored powder and Japanese paper waste powder. Mix thoroughly.

太陽熱吸収性保温添加材混合粉末は1粒径3μm以下の
ZrC粉末5部と、粒径3μm以下のA1粉末5部を配
合したものを使用する。
The solar heat-absorbing heat-retaining additive mixed powder is a mixture of 5 parts of ZrC powder with a grain size of 3 μm or less and 5 parts of A1 powder with a grain size of 3 μm or less.

○しっくいく漆喰〉保温壁 石灰100重量部に対して砂80重量部、フノリ10重
量部、麻すさ(繊維を適当な長さに切断したもの)20
重量部と太陽熱吸収性保温添加材粉末20重量部を混合
する。
○Stucco Stucco> Heat insulation wall 100 parts by weight of lime, 80 parts by weight of sand, 10 parts by weight of french, 20 parts by weight of hemp (fibers cut into appropriate lengths)
parts by weight and 20 parts by weight of solar heat-absorbing thermal additive powder.

太陽熱吸収性保温添加材混合粉末は、粒径3μm以下の
ZrC粉末5部と、粒径3μm以下のAI粉末5部を配
合したものを使用する。
The solar heat absorbing thermal additive mixed powder is a mixture of 5 parts of ZrC powder with a particle size of 3 μm or less and 5 parts of AI powder with a particle size of 3 μm or less.

俺μJl隊 大径の太陽熱吸収性保温添加材を使用するものについて
、その例を列挙する。
Here are some examples of things that use large-diameter solar heat-absorbing heat-retaining additives.

O砂風呂 所謂砂に身体を埋めて砂浴するための砂材であり、天然
砂と略同粒度のZrC粒子と、A1粒子を適量配合した
ものを使用する。
O sand bath is a sand material used to bury one's body in sand and take a sand bath, and uses a mixture of ZrC particles, which have approximately the same particle size as natural sand, and an appropriate amount of A1 particles.

0石焼き芋用加熱石 適量のZrC粒子と、A1粒子を天然石と一緒に釜に入
れ、芋の周りに散在せしめるようにして使用する。
0 stone Heating stone for roasted sweet potatoes A suitable amount of ZrC particles and A1 particles are placed in a pot together with natural stones and used by scattering them around the potatoes.

0焼き栗用焼き砂 適量のZrC粒子と、A1粒子を焼き砂(小砂利)と−
緒に鍋に入れ、栗と一緒に攪拌しながら使用する。
0 Roasting sand for roasted chestnuts Appropriate amount of ZrC particles and A1 particles are mixed with roasted sand (small gravel) -
Put them in a pot and stir together with the chestnuts.

O遊技用加温砂 遊園地等の砂と略同粒度のZrC粒子を適量配合して使
用する。
Heated sand for games Use an appropriate amount of ZrC particles having approximately the same particle size as the sand used in amusement parks.

上記砂風呂1石焼き芋用加熱石、焼き栗用焼き砂または
遊技用加温砂に使用しである太陽熱吸収性保温添加材は
、ZrCの特性である、2.0μm以上の赤外域の放射
率を抑制して熱の放射損失の減少を図るように作用によ
り、遠赤外線による加温効果を発揮する。
The solar heat-absorbing heat-retaining additive used in the one-stone sand bath heating stone for roasting sweet potatoes, roasting sand for roasting chestnuts, or heating sand for games has an emissivity in the infrared region of 2.0 μm or more, which is a characteristic of ZrC. By suppressing heat radiation loss and reducing heat radiation loss, it exerts a warming effect using far infrared rays.

尚、本発明に係る太陽熱吸収性保温添加材について具体
的な実施例を説明したが、周期律表第■族に属する遷移
金属の炭化物としては、ZrCだけでなく、TiC,H
fC等も利用できることはいうまでもない。
Although specific examples have been described for the solar heat absorbing thermal insulation additive according to the present invention, carbides of transition metals belonging to Group Ⅰ of the periodic table include not only ZrC but also TiC, H
Needless to say, fC etc. can also be used.

〔発明の効果〕〔Effect of the invention〕

以上述べたように1本発明に係る太陽熱吸収性保温添加
材は、TiC,ZrC,HfC等の周期律表第■族に属
する遷移金属の炭化物またはこの炭化物とアルミニウム
の混合物を、他の粉粒体と適量を混合して使用するもの
であるため、他の粉粒体と一緒に塗着することによって
面方向に広がる太陽熱吸収性保温添加材を構成し、太陽
熱吸収性と保温性を有するものであり、本発明実施後の
効果は極めて大きい。
As described above, the solar heat-absorbing heat-retaining additive according to the present invention combines a carbide of a transition metal belonging to Group Ⅰ of the periodic table, such as TiC, ZrC, and HfC, or a mixture of this carbide and aluminum with other powder particles. Since it is used by mixing an appropriate amount with the body, it forms a solar heat-absorbing heat-retaining additive that spreads in the surface direction by applying it together with other powder and granules, and has solar heat-absorbing and heat-retaining properties. Therefore, the effects after implementing the present invention are extremely large.

【図面の簡単な説明】[Brief explanation of the drawing]

図面は薄膜状ZrCの各波長に対する熱吸収率を表した
光学特性を示すグラフである。
The drawing is a graph showing the optical characteristics of thin film ZrC showing the heat absorption rate for each wavelength.

Claims (4)

【特許請求の範囲】[Claims] (1)周期律表第IV族に属する遷移金属の炭化物または
この炭化物とアルミニウムの混合物からなり、他の粉粒
体建築材料または粉粒体内装材料等の粉粒体と適量を混
成して使用する太陽熱吸収性保温添加材。
(1) Consisting of a carbide of a transition metal belonging to Group IV of the Periodic Table or a mixture of this carbide and aluminum, used in an appropriate amount mixed with other powder or granule construction materials or powder or granule interior materials, etc. A thermal additive that absorbs solar heat.
(2)周期律表第IV族に属する遷移金属の炭化物がTi
CまたはZrCまたはHfCである請求項1記載の太陽
熱吸収性保温添加材。
(2) The transition metal carbide belonging to Group IV of the periodic table is Ti.
The solar heat absorbing thermal insulation additive according to claim 1, which is C, ZrC or HfC.
(3)粉粒体建築材料がセメントである請求項1記載の
太陽熱吸収性保温添加材。
(3) The solar heat-absorbing heat-retaining additive material according to claim 1, wherein the granular building material is cement.
(4)粉粒体内装材料がしっくい、砂壁または人工壁粉
材である太陽熱吸収性保温添加材。
(4) A solar heat absorbing thermal insulation additive whose powder interior material is plaster, sand wall, or artificial wall powder.
JP4549188A 1988-02-27 1988-02-27 Solar heat absorptive heat insulating additive Pending JPH01219048A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4549188A JPH01219048A (en) 1988-02-27 1988-02-27 Solar heat absorptive heat insulating additive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4549188A JPH01219048A (en) 1988-02-27 1988-02-27 Solar heat absorptive heat insulating additive

Publications (1)

Publication Number Publication Date
JPH01219048A true JPH01219048A (en) 1989-09-01

Family

ID=12720870

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4549188A Pending JPH01219048A (en) 1988-02-27 1988-02-27 Solar heat absorptive heat insulating additive

Country Status (1)

Country Link
JP (1) JPH01219048A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5849654A (en) * 1981-09-17 1983-03-23 日本酸素株式会社 Heat insulating molded body made from calcium silicate as main component
JPS58145652A (en) * 1982-02-24 1983-08-30 三菱化学株式会社 Calcium silicate formed body
JPS62113745A (en) * 1985-11-12 1987-05-25 前川 嘉治 Manufacture of calcium silicate formed body
JPS62143854A (en) * 1985-12-17 1987-06-27 日本インシュレーション株式会社 Manufacture of calcium silicate base formed body

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5849654A (en) * 1981-09-17 1983-03-23 日本酸素株式会社 Heat insulating molded body made from calcium silicate as main component
JPS58145652A (en) * 1982-02-24 1983-08-30 三菱化学株式会社 Calcium silicate formed body
JPS62113745A (en) * 1985-11-12 1987-05-25 前川 嘉治 Manufacture of calcium silicate formed body
JPS62143854A (en) * 1985-12-17 1987-06-27 日本インシュレーション株式会社 Manufacture of calcium silicate base formed body

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