JPH01215433A - Manufacture of core for high pressure casting - Google Patents
Manufacture of core for high pressure castingInfo
- Publication number
- JPH01215433A JPH01215433A JP3707188A JP3707188A JPH01215433A JP H01215433 A JPH01215433 A JP H01215433A JP 3707188 A JP3707188 A JP 3707188A JP 3707188 A JP3707188 A JP 3707188A JP H01215433 A JPH01215433 A JP H01215433A
- Authority
- JP
- Japan
- Prior art keywords
- cavity
- core
- mica
- sand
- facing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005266 casting Methods 0.000 title claims description 18
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 239000004576 sand Substances 0.000 claims abstract description 39
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 26
- 239000010445 mica Substances 0.000 claims abstract description 25
- 238000010438 heat treatment Methods 0.000 claims abstract description 9
- 239000011248 coating agent Substances 0.000 claims description 33
- 238000000576 coating method Methods 0.000 claims description 20
- 239000000126 substance Substances 0.000 claims description 20
- 239000011247 coating layer Substances 0.000 claims description 14
- 239000000945 filler Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 abstract description 24
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- 238000000465 moulding Methods 0.000 abstract description 5
- 238000012856 packing Methods 0.000 abstract 5
- 238000010521 absorption reaction Methods 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 37
- 239000000463 material Substances 0.000 description 5
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 235000019353 potassium silicate Nutrition 0.000 description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 238000004512 die casting Methods 0.000 description 2
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052626 biotite Inorganic materials 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052627 muscovite Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229910052628 phlogopite Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Landscapes
- Mold Materials And Core Materials (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は、ダイカスト法等の高圧鋳造法において使用す
る中子を製造する方法に関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to a method for manufacturing a core used in a high pressure casting method such as a die casting method.
(°従来の技術)
鋳造用中子の製造方法として、例えば、模型のキャビテ
ィに充填砂を充填したのち、これを高周波加熱して硬化
させることにより造型する方法が知られている(特開昭
57−156860号、特開昭61−71152号各公
報参照)、これらの造型方法は、模型のキャビティ内面
に水ガラス等の液状塗型剤を霧状に吹付けて塗膜を形成
し、次いで塗膜を形成したキャビティ内に流動性のある
充填砂を充填する。そして、このキャビティ内の充填砂
に高周波を照射して充填砂を加熱硬化させて中子を造型
する方法である。(°Prior art) As a method for producing a casting core, for example, a method is known in which a cavity of a model is filled with filler sand, and then the sand is hardened by high-frequency heating (Japanese Patent Laid-Open No. 57-156860 and Japanese Patent Application Laid-open No. 61-71152), these molding methods involve spraying a liquid coating agent such as water glass in a mist onto the inner surface of the cavity of the model to form a coating film, and then Fluid filling sand is filled into the cavity in which the coating has been formed. Then, the filling sand in the cavity is irradiated with high frequency waves to heat and harden the filling sand, thereby molding the core.
この方法によれば、充填砂として流動砂を、しかも、塗
型剤として無機質の粘結剤を夫々使用しているため、鋳
肌の平滑な鋳物を製造することが可能である。しか□し
ながら、この方法はダイカスト等の高圧鋳造用に使用さ
れる中子を製造するためのものではないため、かかる方
法によって得られた中子を高圧鋳造に使用すると、10
0kg/d程度の加圧力で中子表面の塗型剤層へ溶湯が
浸透してしまうという問題がある。According to this method, since fluidized sand is used as the filling sand and an inorganic binder is used as the mold coating agent, it is possible to produce a casting with a smooth casting surface. However, this method is not intended for manufacturing cores used for high-pressure casting such as die casting, so if the core obtained by this method is used for high-pressure casting, the
There is a problem in that the molten metal permeates into the mold coating layer on the surface of the core with a pressure of about 0 kg/d.
一方、高圧鋳造用中子を製造する方法としては、例えば
、特開昭56−139256号公報、特開昭58−12
8245号公報等に開示されたものが知られている。こ
の方法は、有機粘結剤を用いて砂中子を造型し、この砂
中子表面に耐火物の粉末と水溶性熱硬化樹脂とを混合し
たアルカリ性水溶液からなるスラリーを塗布し、これを
乾燥して第1コーティング層を形成し、更にこの第1コ
ーティング層の表面に合成雲母を含む溶液を塗布し、こ
れを乾燥して第2コーティング層を形成させる方法であ
る。On the other hand, methods for manufacturing cores for high-pressure casting include, for example, JP-A-56-139256 and JP-A-58-12.
One disclosed in Japanese Patent No. 8245 and the like is known. In this method, a sand core is molded using an organic binder, a slurry consisting of an alkaline aqueous solution mixed with refractory powder and a water-soluble thermosetting resin is applied to the surface of the sand core, and this is dried. In this method, a first coating layer is formed, a solution containing synthetic mica is further applied to the surface of the first coating layer, and the solution is dried to form a second coating layer.
この方法によれば、耐圧性に優れた中子が得られ、更に
中子の表面は合成雲母を含む溶液でコーティングされて
いるために、中子の表面にクランク或いは空孔が形成さ
れることが防止される。According to this method, a core with excellent pressure resistance is obtained, and since the surface of the core is coated with a solution containing synthetic mica, cranks or holes are not formed on the surface of the core. is prevented.
(発明が解決しようとする課a)
しかしながら、この方法は2回のコーティング作業を必
要とするために、工程が繁雑になり、製造コストが上昇
するという問題がある。(Problem A to be Solved by the Invention) However, since this method requires two coating operations, there is a problem that the process becomes complicated and the manufacturing cost increases.
本発明は上記従来の課題に鑑みてなされたちので、耐圧
性に優れた中子を簡便な工程で製造することが可能な高
圧鋳造用中子の製造方法を提供することを目的とする。The present invention has been made in view of the above-mentioned conventional problems, and an object of the present invention is to provide a method for manufacturing a core for high-pressure casting, which allows a core with excellent pressure resistance to be manufactured in a simple process.
(課題を解決するための手段)
上記目的を達成するために本発明の高圧鋳造用中子の製
造方法によれば、模型のキャビティ内面に雲母系物質又
は鱗片状物質を含有した水溶性の塗型剤を塗布して塗膜
を形成する工程と、前記キャビティ内に充填砂を充填す
る工程と、前記キャビティの開口に前記充填砂を通過せ
しめない通気性物質を配設して当該開口から前記キャビ
ティ内を減圧吸引する工程と、前記充填砂と塗膜とを高
周波加熱して硬化させることにより、充填砂の硬化体表
面に雲母系物質又は鱗片状物質のコーティング層を形成
させる工程とから構成したものである。(Means for Solving the Problems) In order to achieve the above object, according to the method for manufacturing a high-pressure casting core of the present invention, a water-soluble coating containing a mica-based substance or a scale-like substance is applied to the inner surface of the cavity of the model. a step of applying a molding agent to form a coating film, a step of filling the cavity with filler sand, and arranging an air-permeable substance that does not allow the filler sand to pass through the opening of the cavity, Consisting of a step of suctioning the inside of the cavity under reduced pressure, and a step of forming a coating layer of a mica-based substance or a scaly substance on the surface of the cured body of the filling sand by hardening the filling sand and the coating film by high-frequency heating. This is what I did.
(作用)
キャビティ内に充填砂を充填したのち、キャビキティ開
口から当該キャビティ内を減圧吸引することにより、充
填砂と塗型剤のコーティング層との境界密着強度が向上
する。更に、塗型剤に含有される雲母又は鱗片状物質同
士が密着し、これらの物質が緻密に積層したコーティン
グ層となる。(Function) After filling the cavity with filler sand, the inside of the cavity is vacuum-suctioned through the cavity opening, thereby improving the boundary adhesion strength between the filler sand and the coating layer of the mold coating agent. Furthermore, the mica or scaly substances contained in the mold coating agent adhere to each other, forming a coating layer in which these substances are densely laminated.
(実施例)
以下、本発明の一実施例を添付図面に基づいて詳述する
。(Example) Hereinafter, an example of the present invention will be described in detail based on the accompanying drawings.
第1図(a)乃至(f)は高圧鋳造用中子の各製造工程
を示している。先ず、耐熱性に優れたシリコンゴム等の
樹脂材料により成形された模型1のキャビティ2内に塗
型剤3を流し込む(第1図(a))、この時使用する塗
型剤3は、200メツシユ以下の天然雲母100部に、
1%CMC(カルボキシメチルセルロース)40部と水
ガラス1部とを添加して充分に撹拌して得られた水溶性
塗型剤である。FIGS. 1(a) to 1(f) show each manufacturing process of a core for high-pressure casting. First, the mold coating 3 is poured into the cavity 2 of the model 1 molded from a resin material such as silicone rubber with excellent heat resistance (Fig. 1(a)). 100 parts of natural mica below mesh,
This is a water-soluble coating agent obtained by adding 40 parts of 1% CMC (carboxymethylcellulose) and 1 part of water glass and thoroughly stirring the mixture.
そして、キャビティ2の内面に塗型剤3を一様に付着さ
せたのち余分な塗型剤3を排出する。これによって、雲
母塗膜4が形成される(第1図俤))。After the mold coating agent 3 is uniformly adhered to the inner surface of the cavity 2, the excess mold coating agent 3 is discharged. As a result, a mica coating film 4 is formed (Fig. 1).
続いて、雲母塗膜4が形成されたキャビティ2に充填砂
5を密に充填する(第1図(C))、この充填砂5は7
号珪砂100部に水ガラス3部、水0.3部、発泡剤0
.03部を添加し、ミキサーで混合・発泡させることに
より調製されたもので、流動性を有するものである。Subsequently, the cavity 2 in which the mica coating film 4 has been formed is densely filled with filling sand 5 (FIG. 1(C)).
100 parts of silica sand, 3 parts of water glass, 0.3 parts of water, 0 blowing agent
.. It is prepared by adding 3 parts of 0.03 parts and mixing and foaming with a mixer, and has fluidity.
このようにキャビティ2内に充填砂5を充填したのち、
キャビティ2の開口2aから当8亥キャビティ2内の減
圧吸引を行う(第1図(d))、即ち、キャビティ2の
上部に減圧吸引装置6を接続すると共に、キャビティ2
の開口2aに減圧吸引時に充填砂5を通過せしめないよ
うな通気性物質、具体的には200メツシュ程度の金網
フィルタ7を取り付ける。この工程により、充填砂5が
外部へ放出されることなく、キャビティ2内が減圧吸引
され、雲母塗膜4は充填砂5と高い密着強度で密着する
。又、それと同時に雲母塗膜4において片状の雲母同士
も互いに強固に密着し、緻密な積層体を形成する。従っ
て、この工程において、減圧吸引条件は、雲母塗膜4と
充填砂5との密着強度及び雲母塗膜4の密度が共に向上
するように決定することが必要である。After filling the cavity 2 with the filling sand 5 in this way,
The inside of the cavity 2 is vacuum-suctioned from the opening 2a of the cavity 2 (FIG. 1(d)). That is, the vacuum suction device 6 is connected to the upper part of the cavity 2, and the vacuum suction device 6 is connected to the upper part of the cavity 2.
A breathable material, specifically a wire mesh filter 7 of approximately 200 mesh, is attached to the opening 2a of the opening 2a to prevent the filling sand 5 from passing through during vacuum suction. Through this process, the inside of the cavity 2 is suctioned under reduced pressure without the filling sand 5 being discharged to the outside, and the mica coating film 4 is closely attached to the filling sand 5 with high adhesion strength. At the same time, flaky mica pieces in the mica coating film 4 also adhere firmly to each other, forming a dense laminate. Therefore, in this step, it is necessary to determine the vacuum suction conditions so that both the adhesion strength between the mica coating film 4 and the filling sand 5 and the density of the mica coating film 4 are improved.
しかるのち、模型1を高周波加熱炉8内に収納し、2K
Wの高周波を4分間照射することにより、充填砂5及び
雲母塗膜4を加熱硬化させる(第1図(e))、尚、こ
の高周波加熱工程を、上記した減圧吸引を行いながら実
施してもよい。Afterwards, the model 1 is placed in the high-frequency heating furnace 8 and heated to 2K.
The filling sand 5 and the mica coating film 4 are heated and cured by irradiating the high frequency of W for 4 minutes (Fig. 1(e)). This high frequency heating step is carried out while performing the vacuum suction described above. Good too.
このようにして、第1図(f)に示すような基中子9が
造型される。造型後、模初1から基中子9を取り出す。In this way, the base core 9 as shown in FIG. 1(f) is molded. After the molding, the base core 9 is taken out from the mold base 1.
この基中子9の表面には前記キャビティ2の内面に形成
された雲母塗膜4、つまり雲母系物質よりなるコーティ
ング層IOが形成されている。第2図に拡大して示すよ
うに、このコーティング層10に充填砂5が食い込んだ
状態となって一体化され、極めて高い境界密着強度を有
することが確認された。A mica coating film 4 formed on the inner surface of the cavity 2, that is, a coating layer IO made of a mica-based material is formed on the surface of the base core 9. As shown in an enlarged view in FIG. 2, it was confirmed that the filling sand 5 penetrated into the coating layer 10 and was integrated into the coating layer 10, and had an extremely high boundary adhesion strength.
以上の工程により製造された高圧鋳造用中子を金型にセ
ットし、加圧力500 kg/cd、湯口速度0、1
m/see S溶湯温度700°Cの条件下で加圧鋳造
を行った。この結果、中子折れは皆無であり、中子の表
面が雲母系物質のコーティング層によって平滑であるた
め、砂は振動のみで100%落ちた。The high-pressure casting core manufactured by the above process was set in a mold, and the pressing force was 500 kg/cd and the sprue speed was 0 and 1.
Pressure casting was carried out under conditions where m/see S molten metal temperature was 700°C. As a result, there was no breakage of the core, and since the surface of the core was smooth due to the coating layer of the mica-based material, 100% of the sand was removed by vibration alone.
尚、上記実施例において塗型剤に含有される雲母物質は
、白雲母、金雲母、黒雲母、合成雲母等を用いているが
、雲母物質に限定されるものではなく、例えば、金属薄
片等の鱗片状物質を含有する塗型剤を使用してもよい、
更に、例えば、天然雲母50部、合成雲母50部、水4
0部、スルホコハク酸ナトリウムlO部及び消泡剤数滴
よりなる組成の塗型剤を使用することもできる。In the above examples, the mica substances contained in the coating agent include muscovite, phlogopite, biotite, synthetic mica, etc., but are not limited to mica substances, and include, for example, metal flakes, etc. A coating agent containing a scaly substance may be used.
Furthermore, for example, 50 parts of natural mica, 50 parts of synthetic mica, 4 parts of water
It is also possible to use a coating agent having a composition of 0 parts of sodium sulfosuccinate, 10 parts of sodium sulfosuccinate and a few drops of antifoaming agent.
又、充填砂としては上記した組成のものに限定されず、
例えば、フラタリー珪砂100部と水ガラス3部とを5
分間混練しなから50’Cの温風により乾燥させた混練
砂を用い、これに4KWの高周波を1分間照射すること
としてもよい。In addition, the filling sand is not limited to those having the above composition,
For example, 100 parts of flattery silica sand and 3 parts of water glass are mixed into 5 parts.
It is also possible to use kneaded sand that has been kneaded for a minute and then dried with hot air at 50'C, and then irradiated with a high frequency wave of 4 KW for one minute.
(発明の効果)
以上説明したように本発明の高圧鋳造用中子の製造方法
によれば、模型のキャビティ内面に雲母系物質又は鱗片
状物質を含有した水溶性の塗型剤を塗布して塗膜を形成
する工程と、前記キャビティ内に充填砂を充填する工程
と、前記キャビティの開口に前記充填砂を通過せしめな
い通気性物質を配設して当該開口から前記キャビティ内
を減圧吸引する工程と、前記充填砂と塗膜とを高周波加
熱して硬化させることにより、充填砂の表面に雲母系物
質又は鱗片状物質のコーティング層を形成させる工程と
から構成したので、簡便な工程により、耐圧性に優れ、
鋳造時の加圧力で溶湯が中子の表面に浸透することが防
止された中子を製造することができ、この中子を使用し
て平滑な鋳肌を有する鋳造品を製造することが可能とな
る。(Effects of the Invention) As explained above, according to the method for producing a high-pressure casting core of the present invention, a water-soluble mold coating agent containing a mica-based substance or a scale-like substance is applied to the inner surface of the cavity of the model. a step of forming a coating film, a step of filling the cavity with filler sand, and arranging an air-permeable substance that does not allow the filler sand to pass through the opening of the cavity, and sucking the inside of the cavity under reduced pressure through the opening. and a step of forming a coating layer of a mica-based substance or a scale-like substance on the surface of the filling sand by hardening the filling sand and the coating film by high-frequency heating, so the process is simple. Excellent pressure resistance,
It is possible to manufacture a core that prevents molten metal from penetrating the surface of the core due to the pressure applied during casting, and it is possible to use this core to manufacture cast products with a smooth casting surface. becomes.
第1図は本発明の高圧鋳造用中子の製造方法の一実施例
を示す工程説明図、第2図は得られた中子の表面拡大図
である。
1・・・模型、2・・・キャビティ、3・・・塗型剤、
4・・・塗膜、5・・・充填砂、6・・・減圧吸引装置
、7・・・フィルタ(通気性物質)、8・・・高周波加
熱炉、9・・・基中子、10・・・コーティング層。
出願人 三菱自動車工業株式会社
代理人 弁理士 長 門 侃 二
第1図
(Q) (b) (C)第2
図FIG. 1 is a process explanatory diagram showing one embodiment of the method for producing a high-pressure casting core of the present invention, and FIG. 2 is an enlarged view of the surface of the obtained core. 1... Model, 2... Cavity, 3... Coating agent,
4... Coating film, 5... Filling sand, 6... Decompression suction device, 7... Filter (breathable material), 8... High frequency heating furnace, 9... Base core, 10 ...Coating layer. Applicant Mitsubishi Motors Corporation Agent Patent Attorney Kanji Nagato Figure 1 (Q) (b) (C) 2
figure
Claims (1)
有した水溶性の塗型剤を塗布して塗膜を形成する工程と
、前記キャビティ内に充填砂を充填する工程と、前記キ
ャビティの開口に前記充填砂を通過せしめない通気性、
物質を配設して当該開口から前記キャビティ内を減圧吸
引する工程と、前記充填砂と塗膜とを高周波加熱して硬
化させることにより、充填砂の硬化体表面に雲母系物質
又は鱗片状物質のコーティング層を形成させる工程とか
らなることを特徴とする高圧鋳造用中子の製造方法。A step of applying a water-soluble coating agent containing a mica-based substance or a scale-like substance to the inner surface of the cavity of the model to form a coating film, a step of filling the cavity with filler sand, and a step of filling the opening of the cavity with breathability that does not allow the filling sand to pass through;
A mica-based substance or a scale-like substance is formed on the surface of the cured body of the filling sand by arranging the substance and vacuum suctioning the inside of the cavity through the opening, and hardening the filling sand and the coating film by high-frequency heating. A method for producing a core for high-pressure casting, comprising the step of forming a coating layer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3707188A JPH01215433A (en) | 1988-02-19 | 1988-02-19 | Manufacture of core for high pressure casting |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3707188A JPH01215433A (en) | 1988-02-19 | 1988-02-19 | Manufacture of core for high pressure casting |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH01215433A true JPH01215433A (en) | 1989-08-29 |
Family
ID=12487319
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3707188A Pending JPH01215433A (en) | 1988-02-19 | 1988-02-19 | Manufacture of core for high pressure casting |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH01215433A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998006522A3 (en) * | 1996-08-09 | 1998-06-04 | Vaw Motor Gmbh | Method for the production of core preforms and recycling core sand for foundry |
JP2009039767A (en) * | 2007-08-10 | 2009-02-26 | Kao Corp | Method for making casting mold |
JP2016128368A (en) * | 2015-01-09 | 2016-07-14 | 日立造船株式会社 | Refractory coating method and refractory |
-
1988
- 1988-02-19 JP JP3707188A patent/JPH01215433A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998006522A3 (en) * | 1996-08-09 | 1998-06-04 | Vaw Motor Gmbh | Method for the production of core preforms and recycling core sand for foundry |
JP2009039767A (en) * | 2007-08-10 | 2009-02-26 | Kao Corp | Method for making casting mold |
JP2016128368A (en) * | 2015-01-09 | 2016-07-14 | 日立造船株式会社 | Refractory coating method and refractory |
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