JPH01215199A - Manufacture of bobbin for voice coil - Google Patents

Manufacture of bobbin for voice coil

Info

Publication number
JPH01215199A
JPH01215199A JP3867088A JP3867088A JPH01215199A JP H01215199 A JPH01215199 A JP H01215199A JP 3867088 A JP3867088 A JP 3867088A JP 3867088 A JP3867088 A JP 3867088A JP H01215199 A JPH01215199 A JP H01215199A
Authority
JP
Japan
Prior art keywords
bobbin
resin
fibers
cylinder
voice coil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3867088A
Other languages
Japanese (ja)
Inventor
Genzo Kimura
木村 源三
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MEISEI SANGYO KK
Original Assignee
MEISEI SANGYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MEISEI SANGYO KK filed Critical MEISEI SANGYO KK
Priority to JP3867088A priority Critical patent/JPH01215199A/en
Publication of JPH01215199A publication Critical patent/JPH01215199A/en
Pending legal-status Critical Current

Links

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  • Audible-Bandwidth Dynamoelectric Transducers Other Than Pickups (AREA)

Abstract

PURPOSE:To keep roundness and to preclude possibility in deformation in a specific direction by applying braiding or cross spiral winding to lots of fibers or thin tapes onto an outer circumference of a core whose cross section is circular and fixing them by a resin to form a cylinder and cutting off the cylinder so as to obtain a bobbin. CONSTITUTION:Lots of fibers 32 or thin tapes are braided or wound crossingly in spiral onto the outer circumference of the core rod 31 whose cross section is circular, they are fixed by a resin 33 to form a cylinder 35, the cylinder 35 is cut off to a required length to obtain a bobbin 43. Thus, the lots of fibers 32 or thin tapes are formed into a cylinder and solidified by the resin 33, then no orientation of the material exists in the state of the bobbin 43. Thus, there is no possibility of deformation in a specific direction and the fibers 32 and the resin 33 are formed as a composite, then strength is obtained and roundness is endured.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、スピーカーのボイスコイルに使用するボビン
の製造方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a method of manufacturing a bobbin used for a voice coil of a speaker.

〔従来技術とその課題〕[Conventional technology and its issues]

スピーカーのボイスコイルは一般に次のようにしそ製造
される。まず図−5Aに示すように筒状治具11の外周
にボビン12を嵌合する。ボビン12は通常、紙製であ
るが、アルミ箔などが使用される場合もある。なお筒状
治具11は、ボイスコイルの製造およびスピーカーへの
組み込みの際に、ボイスコイルの真円度保持、位置決め
などのために使用されるもので、スピニカーへの組み込
み後は抜き取られるものである。次に同図Bに示すよう
にボビン12上に被膜線を整列巻してコイル13を形成
すると共に、そのコイル13のリード部14を軸線方向
に引き出す、その後、同図Cに示すようにコイル13付
近のリード部14を押さえるようにテープ15を接着す
る0以上で、筒状治具11に嵌合された状態のボイスコ
イル16が出来あがる。
The voice coil of a speaker is generally manufactured as follows. First, as shown in FIG. 5A, the bobbin 12 is fitted onto the outer periphery of the cylindrical jig 11. The bobbin 12 is usually made of paper, but aluminum foil or the like may be used in some cases. The cylindrical jig 11 is used to maintain the roundness of the voice coil, position it, etc. when manufacturing the voice coil and assembling it into a speaker, and cannot be removed after it is assembled into the spinaker. be. Next, as shown in Figure B, the coil 13 is formed by winding the coated wire on the bobbin 12 in an aligned manner, and the lead portion 14 of the coil 13 is pulled out in the axial direction. The voice coil 16 fitted into the cylindrical jig 11 is completed by bonding the tape 15 so as to press down the lead part 14 near the lead part 13.

なおボビン12の外周面には予めアルコールに可溶性の
接着剤が塗布されており、そこに、アルコール系溶剤を
塗布した自己融着性の被膜線を巻き付けて、加熱乾燥す
ると、ボビン12とコイル13とが一体化するようにな
っている。
Note that the outer peripheral surface of the bobbin 12 is coated with an alcohol-soluble adhesive in advance, and when a self-bonding coated wire coated with an alcohol-based solvent is wound thereon and dried by heating, the bobbin 12 and the coil 13 are bonded together. are becoming integrated.

さて、このようなボイスコイルに使用されるボビンは従
来、次のようにして製造されている。すなわち図−6に
示すように、2枚のボビン用テ−プ20a・20bを用
い、一方のテープ20aを両側縁が突き合わさるように
らせん巻すると共に、その上に他方のテープ20bを両
側縁の突き合わせ目が半ピツチずれるようにらせん巻し
、両者を接着剤(図示せず)で接着して二重管21を形
成した後・これを必要な長さに切断して1、ボビン12
を得る、という方法である。
Now, the bobbin used for such a voice coil is conventionally manufactured in the following manner. That is, as shown in Figure 6, using two bobbin tapes 20a and 20b, one tape 20a is spirally wound so that both side edges are butted, and the other tape 20b is wrapped on top of it so that both side edges are butted. After spirally winding the butts so that the butts are shifted by half a pitch, and bonding them together with an adhesive (not shown) to form the double tube 21, cut this to the required length and attach the bobbin 12.
This is the method of obtaining.

しかしこのような方法で製造したボビンは、テープが斜
めに巻かれているため方向性があり、特定の方向に変形
しやすい欠点がある。またテープをらせん巻した二重管
を、軸線に垂直に切断するため、テープの切り口が鋭角
になり、その部分が剥がれやすいという欠点もある。
However, the bobbin manufactured by this method has directional properties because the tape is wound diagonally, and has the disadvantage that it is easily deformed in a specific direction. Furthermore, because the double-walled tube with spirally wound tape is cut perpendicular to the axis, the tape ends at an acute angle, which has the disadvantage of making it easy to peel off.

またこのほか、図−7のように打ち抜がれた短冊片22
を、筒状治具(図示せず)の外周に両端縁が突き合わさ
るように巻き付け、その後、図−8のように短冊片22
の両端縁突き合わせ部23を押さえるように接着テープ
24を張り付けて、ボビン12を形成することも行われ
ている。図−7のように四隅を丸めた短冊片を用いるの
は、四隅のめくれを防止するためである。
In addition, there are also 22 punched strips as shown in Figure 7.
Wrap it around the outer periphery of a cylindrical jig (not shown) so that both ends are butted together, and then wrap the strip 22 as shown in Figure 8.
The bobbin 12 is also formed by applying an adhesive tape 24 so as to press down the abutting portions 23 of both ends of the bobbin 12 . The purpose of using a strip with rounded corners as shown in Figure 7 is to prevent the corners from turning up.

しかしこのような方法で製造したボビンは、図−9のよ
うに両端縁突き合わせ部23に軸線方向のズレが生じや
すく、このようなズレが発生すると短冊片の角がめくれ
て不良の原因となる。また短冊片としてアルミ箔などを
使用した場合、単に筒状治具に巻き付けただけでは、細
かい折れ曲がりが発生しやすく、なめらかな円筒形に成
形することが困難であり、このためロール成形などが必
要となり、コスト高になる欠点がある。
However, bobbins manufactured using this method tend to be misaligned in the axial direction at the abutting portions 23 of both ends, as shown in Figure 9, and when such misalignment occurs, the corners of the strips turn over, causing defects. . In addition, when using aluminum foil as a strip, simply wrapping it around a cylindrical jig tends to cause small bends, making it difficult to form into a smooth cylindrical shape, which requires roll forming. This has the disadvantage of high cost.

ボイスコイルはスピーカー内の狭い円筒間隙に配置され
るものであるから、ボビン材のめくれやボビンの変形、
真円度低下はきびしく制限されている。
Since the voice coil is placed in a narrow cylindrical gap inside the speaker, there is a possibility that the bobbin material may turn over or become deformed.
The reduction in roundness is strictly limited.

〔課題の解決手段とその作用〕[Means for solving problems and their effects]

本発明の目的は、上記のような課題を解決するため、新
たなボイスコイル用ボビンの製造方法を堤供することに
ある。
An object of the present invention is to provide a new method for manufacturing a voice coil bobbin in order to solve the above problems.

この目的を達成するため本発明は、断面円形の心棒の外
周に多数本の繊維または細いテープを編組または交差ら
せん巻した後、それを樹脂で固めて筒状体を形成し、そ
の筒状体を必要な長さに切断してボビンを得ることを特
徴とするものである。
In order to achieve this object, the present invention involves braiding or crisscrossing a large number of fibers or thin tape around the outer periphery of a mandrel having a circular cross section, and then hardening it with resin to form a cylindrical body. The bobbin is obtained by cutting the bobbin to the required length.

このようにすると、多数本の繊維または細いテープが交
差した状態で筒状に集合され、樹脂で固められた状態と
なるので、ボビンの状態では材料の方向性がなく、した
がって特定の方向に変形するおそれもない、また繊維と
樹脂の複合体となるので強度もあり、真円度も維持でき
ることになる。
In this way, a large number of fibers or thin tapes are gathered in a cylindrical shape in a criss-crossed state and hardened with resin, so there is no directionality in the material in the bobbin state, so it deforms in a specific direction. Since it is a composite of fibers and resin, it has strength and can maintain roundness.

なお、ここでいう交差らせん巻とは、繊維またはテープ
を内層と外層で交差するように巻くことを意味し、内層
と外層のいずれか一方がらせん巻で、他方が縦添えの場
合を含むものである。
Note that "cross spiral winding" here means winding the fibers or tape in such a way that they intersect with each other between the inner and outer layers, and includes the case where one of the inner and outer layers is spirally wound and the other is longitudinally wound. .

〔実施例〕〔Example〕

以下、本発明の実施例を図面を参照して詳細に説明する
Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.

図−IAないしFは本発明の一実施例を示す。Figures IA to F illustrate an embodiment of the invention.

図において、31は直立させた断面円形の心棒で、その
下部には、外周に多数本の繊維32を編組する部分が設
けられ、その上部には編組されたものに液状の樹脂33
を塗布、含浸する部分が設けられ、その上部には樹脂3
3の付着量を一様にすると共に外径を一定にする絞りダ
イス34が設けられ、その上部には樹脂を加熱固化させ
るヒーター35が設けられている。樹脂が固化すると繊
維と樹脂が一体となった筒状体36が出来あがる。さら
に、その上部には筒状体36の外周に被膜線の接着剤3
7を塗布する部分が設けられ、その上部には接着剤を加
熱乾燥させるヒーター38が設けられ、その上部には、
筒状体36の上端より少し下の部分を把持する下部チャ
ック39と、筒状体36を切断するカッター40と、筒
状体36の上端部付近を把持する上部チャック41が順
次設けられ、さらに筒状体36の軸線の延長上には、製
造されたボビンを装着する筒状治具42が配置されてい
る。
In the figure, reference numeral 31 denotes an upright mandrel with a circular cross section, at its lower part there is provided a part for braiding a large number of fibers 32 around the outer periphery, and at its upper part, liquid resin 33 is applied to the braided material.
There is a part where resin 3 is applied and impregnated, and the upper part is coated with resin 3.
A drawing die 34 is provided to make the amount of resin deposited uniform and to keep the outer diameter constant, and a heater 35 is provided above the drawing die 34 to heat and solidify the resin. When the resin solidifies, a cylindrical body 36 in which fibers and resin are integrated is completed. Further, on the upper part, a coating wire adhesive 3 is applied to the outer periphery of the cylindrical body 36.
7 is provided, a heater 38 for heating and drying the adhesive is provided above the section, and a heater 38 for heating and drying the adhesive is provided above it.
A lower chuck 39 that grips a portion slightly below the upper end of the cylindrical body 36, a cutter 40 that cuts the cylindrical body 36, and an upper chuck 41 that grips the vicinity of the upper end of the cylindrical body 36 are sequentially provided. A cylindrical jig 42 is arranged on the extension of the axis of the cylindrical body 36 to mount the manufactured bobbin thereon.

繊維32としては例えばアラミド繊維(商品名ケブラー
)などが、樹脂33としては例えばポリイミドあるいは
エポキシ樹脂などが使用される。また接着剤37として
は従来と同じアルコールに可溶性の接着剤が使用される
As the fiber 32, for example, aramid fiber (trade name: Kevlar) is used, and as the resin 33, for example, polyimide or epoxy resin is used. Further, as the adhesive 37, the same alcohol-soluble adhesive as the conventional one is used.

図−IAの状態は、下部チャック39で筒状体36を把
持したところで、この状態から下部チャック39と心棒
31を同時に上方へ移動させると共に編組機(図示せず
)を回転させる。これにより繊維32の&I&Ilと、
樹脂33の塗布含浸、絞り、加熱固化と、接着剤37の
塗布、乾燥が同時に行われる。筒状体36がボビン1個
分の長さだけ上昇したところで、下部チャック39およ
び心棒31の上昇と編組機の回転を停止させる。これで
同図Bの状態となる0次に同図Cのように上部チャック
41で筒状体36の上端付近を把持した後、カッター4
0を筒状体36のまわりに回転させて筒状体36を切断
し、ボビン43を得る。また心棒31を同図Aと同じ位
置まで引き下げる。この心棒31の引き下げを容易にす
るため、心棒31には上端にいくほど外径が小さ(なる
僅かなテーパーをつけておくとよい。
In the state shown in FIG. 1A, the lower chuck 39 grips the cylindrical body 36, and from this state, the lower chuck 39 and the mandrel 31 are simultaneously moved upward and the braiding machine (not shown) is rotated. As a result, &I&Il of fiber 32,
Coating, impregnating, squeezing, and heating solidification of the resin 33 and coating and drying of the adhesive 37 are performed simultaneously. When the cylindrical body 36 has risen by the length of one bobbin, the lower chuck 39 and the mandrel 31 are stopped from rising and the braiding machine is stopped from rotating. Now the state is as shown in Figure B. Next, as shown in Figure C, after gripping the upper end of the cylindrical body 36 with the upper chuck 41, the cutter 4
0 is rotated around the cylindrical body 36 and the cylindrical body 36 is cut to obtain a bobbin 43. Also, pull down the mandrel 31 to the same position as A in the figure. In order to facilitate the pulling down of the mandrel 31, it is preferable that the mandrel 31 has a slight taper so that the outer diameter becomes smaller toward the upper end.

次に上部チャック41を上昇させて同図りのようにボビ
ン43を筒状治具42に嵌合すると共に、下部チャック
39を開く、さらに同図Eのように上部チャック41を
開き、かつ下部チャック39を同図Aの位置まで下降さ
せる。次に同図Fのように上部チャック41を同図への
位置まで下降させ、かつ下部チャック39で筒状体36
を把持する。その後、ボビン43を装着した筒状治具4
2を例えば次工程のコイル巻工程に送り、新たな筒状治
具を配置すれば同図Aの状態に戻る。
Next, the upper chuck 41 is raised to fit the bobbin 43 into the cylindrical jig 42 as shown in the figure, and the lower chuck 39 is opened. Furthermore, the upper chuck 41 is opened as shown in the figure E, and the lower chuck 39 to the position A in the figure. Next, as shown in FIG.
grasp. After that, the cylindrical jig 4 equipped with the bobbin 43
2 is sent to the next process, for example, a coil winding process, and a new cylindrical jig is placed, returning the state to A in the figure.

以上のような作業の繰り返しで次々にボビンを製造する
ものである。なお接着剤37の塗布は樹脂が完全に固化
する前、すなわち半固化状態のときに行ってもよい、ま
た接着剤37の塗布、乾燥は必要に応じて行われるもの
で、省略される場合もある。
Bobbins are manufactured one after another by repeating the above operations. Note that the application of the adhesive 37 may be performed before the resin is completely solidified, that is, when it is in a semi-solidified state, and the application and drying of the adhesive 37 may be performed as necessary, and may be omitted. be.

図−2および図−3はそれぞれ本発明の他の実施例を示
す0図−1の実施例では繊維を編組する場合を示したが
、これらの実施例は繊維を交差らせん巻する場合を示す
6図−2の実施例は、まず下部口金45のところで心棒
31に多数本の繊維32を一方向にらせん巻し、次いで
上部心金46のところで同じ繊維32を反対方向にらせ
ん巻する場合であり、図−3の実施例は、まず下部口金
45のところで心棒31の周囲に多数本の繊維32を縦
添えした後、上部心金46のところで繊維32を一方向
にらせん巻する場合である。それ以後の工程は図−1の
実施例と同じである。
Figures 2 and 3 each show other embodiments of the present invention. The embodiment in Figure 1 shows the case where the fibers are braided, but these embodiments show the case where the fibers are cross-spirally wound. In the embodiment shown in Fig. 6-2, a large number of fibers 32 are first spirally wound in one direction around the mandrel 31 at the lower mandrel 45, and then the same fibers 32 are spirally wound in the opposite direction at the upper mandrel 46. In the embodiment shown in FIG. 3, first, a large number of fibers 32 are vertically attached around the mandrel 31 at the lower mandrel 45, and then the fibers 32 are spirally wound in one direction at the upper mandrel 46. . The subsequent steps are the same as the embodiment shown in FIG.

以上の各実施例では、繊維を編組またはらせん巻する場
合を説明したが、繊維の代わりに細いテープを使用する
ことも可能である。
In each of the above embodiments, the fibers are braided or spirally wound, but it is also possible to use a thin tape instead of the fibers.

なお、筒状治具に装着したボビンにコイルを巻いた後、
熱処理を行う場合があるが、このときボビンとコイルの
熱膨張率が異なると、両者の一体性が低下したり変形し
たりすることがあるので、そのおそれのある場合は、図
−4に示すようにボビン43に軸線方向の切れ目47を
入れておくとよい。
In addition, after winding the coil around the bobbin attached to the cylindrical jig,
Heat treatment may be performed, but if the thermal expansion coefficients of the bobbin and coil differ at this time, the integrity of the two may deteriorate or deform. It is preferable to make a cut 47 in the axial direction in the bobbin 43.

このようにすればボビンはコイルの熱膨張に追従できる
ため上記の問題を解消できる0本発明の方法により製造
されたボビンは、樹脂で固められているので、切れ目4
7を入れても変形することはない、切れ目47を入れる
作業は、筒状体から切断されたボビンを筒状治具に装着
するとき(図−ICからDにいくとき)に行うことがで
きる。
In this way, the bobbin can follow the thermal expansion of the coil, so the above problem can be solved. Since the bobbin manufactured by the method of the present invention is hardened with resin, the cut 4
7 will not deform.The work of making the cut 47 can be done when attaching the bobbin cut from the cylindrical body to the cylindrical jig (when going from IC to D in Figure). .

〔発明の効果〕〔Effect of the invention〕

以上説明したように本発明によれば、多数本の繊維また
は細いテープが交差した状態で筒状に集合され、樹脂で
固められた状態のボビンを得ることができ、このボビン
は、樹脂と繊維またはテープとの複合体であるため適度
の強度があり、それ自体で真円度を保持できると共に、
材料の方向性がないため特定の方向に変形するおそれも
ない等、すぐれた利点がある。
As explained above, according to the present invention, it is possible to obtain a bobbin in which a large number of fibers or thin tapes are assembled in a cylindrical shape in a crossed state and hardened with resin, and this bobbin is made of resin and fibers. Or, since it is a composite with tape, it has moderate strength and can maintain its roundness by itself.
It has excellent advantages such as there is no risk of deformation in a specific direction because the material has no directionality.

【図面の簡単な説明】[Brief explanation of the drawing]

図−IA〜Fは本発明の一実施例に係るボイスコイル用
ボビンの製造方法を示す説明図、図−2および図−3は
それぞれ本発明の他の実施例を示す説明図、図−4は本
発明により製造されるボビンの一例を示す斜視図、図−
5A〜Cはボイスコイルの製造方法を示す説明図、図−
6は従来のボイスコイル用ボビンの製造方法の一例を示
す説明図、図−7は従来のボイスコイル用ボビンに使用
される短冊片の平面図、図−8は従来のボイスコイル用
ボビンの一例を示す斜視図、図−9は同ボビンの問題点
を示す斜視図である。 31:心棒、32:繊維、33:樹脂、34:絞りダイ
ス、35:筒状体、37:接着剤、39:下部チャック
、40:カッター、41:上部チャック、42:筒状治
具、43:ボビン。 図−1Δ      図−旧       図−IC図
−10図−IE       図−IE図−2図−3
Figures IA to F are explanatory diagrams showing a method for manufacturing a voice coil bobbin according to one embodiment of the present invention, Figures 2 and 3 are explanatory diagrams showing other embodiments of the present invention, and Figure 4 1 is a perspective view showing an example of a bobbin manufactured according to the present invention,
5A to 5C are explanatory diagrams and diagrams showing the voice coil manufacturing method.
6 is an explanatory diagram showing an example of a method for manufacturing a conventional voice coil bobbin, FIG. 7 is a plan view of a strip used in a conventional voice coil bobbin, and FIG. 8 is an example of a conventional voice coil bobbin. FIG. 9 is a perspective view showing problems with the bobbin. 31: Mandrel, 32: Fiber, 33: Resin, 34: Drawing die, 35: Cylindrical body, 37: Adhesive, 39: Lower chuck, 40: Cutter, 41: Upper chuck, 42: Cylindrical jig, 43 : Bobbin. Figure-1Δ Figure-Old Figure-IC Figure-10 Figure-IE Figure-IE Figure-2 Figure-3

Claims (1)

【特許請求の範囲】 1、断面円形の心棒の外周に多数本の繊維または細いテ
ープを編組または交差らせん巻した後、それを樹脂で固
めて筒状体を形成し、その筒状体を必要な長さに切断し
てボビンを得ることを特徴とするボイスコイル用ボビン
の製造方法。 2、請求項1記載の方法であって、樹脂が固化する前ま
たは後に、コイル用被膜線の接着剤を塗布することを特
徴とするもの。
[Claims] 1. A large number of fibers or thin tapes are braided or crossed spirally wound around the outer periphery of a mandrel with a circular cross section, and then hardened with resin to form a cylindrical body, and the cylindrical body can be used as needed. A method of manufacturing a bobbin for a voice coil, the method comprising obtaining a bobbin by cutting the bobbin to a desired length. 2. The method according to claim 1, characterized in that the adhesive for the coated wire for the coil is applied before or after the resin is solidified.
JP3867088A 1988-02-23 1988-02-23 Manufacture of bobbin for voice coil Pending JPH01215199A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3867088A JPH01215199A (en) 1988-02-23 1988-02-23 Manufacture of bobbin for voice coil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3867088A JPH01215199A (en) 1988-02-23 1988-02-23 Manufacture of bobbin for voice coil

Publications (1)

Publication Number Publication Date
JPH01215199A true JPH01215199A (en) 1989-08-29

Family

ID=12531706

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3867088A Pending JPH01215199A (en) 1988-02-23 1988-02-23 Manufacture of bobbin for voice coil

Country Status (1)

Country Link
JP (1) JPH01215199A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5837298B2 (en) * 1977-12-01 1983-08-15 純郎 勝田 Cyclopropanecarboxylic acid ester derivative, method for producing cyclopropanecarboxylic acid ester derivative, insecticide containing cyclopropanecarboxylic acid ester derivative゜
JPS5943879A (en) * 1982-09-07 1984-03-12 エフ・エム・シ−・コ−ポレ−シヨン Composition for etching print circuit using hydrogen peroxide-containing sulfuric acid solution and method therefor

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5837298B2 (en) * 1977-12-01 1983-08-15 純郎 勝田 Cyclopropanecarboxylic acid ester derivative, method for producing cyclopropanecarboxylic acid ester derivative, insecticide containing cyclopropanecarboxylic acid ester derivative゜
JPS5943879A (en) * 1982-09-07 1984-03-12 エフ・エム・シ−・コ−ポレ−シヨン Composition for etching print circuit using hydrogen peroxide-containing sulfuric acid solution and method therefor

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