JPH01204987A - Sound insulating putty - Google Patents

Sound insulating putty

Info

Publication number
JPH01204987A
JPH01204987A JP3151888A JP3151888A JPH01204987A JP H01204987 A JPH01204987 A JP H01204987A JP 3151888 A JP3151888 A JP 3151888A JP 3151888 A JP3151888 A JP 3151888A JP H01204987 A JPH01204987 A JP H01204987A
Authority
JP
Japan
Prior art keywords
flame
putty
sound insulating
sound insulation
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3151888A
Other languages
Japanese (ja)
Inventor
Shuichi Tsurumaru
鶴丸 秀一
Koichi Okumura
孝一 奥村
Takeshi Yamazaki
猛 山崎
Jun Nakajima
潤 中島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tatsuta Electric Wire and Cable Co Ltd
Original Assignee
Tatsuta Electric Wire and Cable Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tatsuta Electric Wire and Cable Co Ltd filed Critical Tatsuta Electric Wire and Cable Co Ltd
Priority to JP3151888A priority Critical patent/JPH01204987A/en
Publication of JPH01204987A publication Critical patent/JPH01204987A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain a sound insulating putty having excellent fire resistance and a high sound insulating effect, by incorporating 200-1,300pts.wt. iron concentrate slag and a flame-retardant organic fiber into a liquid chloroprene rubber. CONSTITUTION:This sound insulating putty is prepared by incorporating 200-1,300pts.wt. iron concentrate slag and 0.5-40pts.wt. flame-retardant organic fiber into 100pts.wt. liquid chloroprene rubber. As the liquid chloroprene rubber, those usually available on the market can be used; however, one which has terminal OH groups, a viscosity at 25 deg.C of (3-8)X10<4>cps and a molecular weight distribution of 1,500-2,800 is preferably used. The slag is a by-product in a copper smelting process. Examples of the flame retardant organic fibers include phenol/formaldehyde resin fibers and carbon fibers, which will be carbonized when exposed to a flame. The length of the fibers is preferably 1-10mm.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、壁や床等の各種ボードの突き合わせ部分、電
線ケーブルや配管の貫通部分等に充填するシール用の遮
音パテに関する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a sound insulating putty for sealing, which is filled into the butting parts of various boards such as walls and floors, the penetrating parts of electric cables and piping, and the like.

[従来の技術] 上記の用途に用いる遮音パテとしては、高比重物質をバ
インダー樹脂に配合して遮音効果を高めたものが知られ
ている(例えば、特開昭57−187379号)。この
ような高比重物質としては、高比重の無機質粒子が用い
られている。
[Prior Art] As a sound insulation putty used for the above-mentioned applications, one is known in which a high specific gravity substance is blended with a binder resin to enhance the sound insulation effect (for example, JP-A-57-187379). As such a high specific gravity substance, high specific gravity inorganic particles are used.

[発明が解決しようとする課題] しかしながら、これまでに知られている遮音パテは、た
とえ丈ぐれた遮音性を有していても、耐火性において満
足できるものではない。すなわち、火炎にさらされた場
合に、バインダー樹脂が溶融して脱落したり、クラック
が発生するため、遮音パテの部分からの火炎の伝播は防
ぐことができない。特に、高比重の無機質粒子を多量に
混入して遮音パテの比重を大きくした場合には、火炎に
さらされたときに、溶融したバインダー樹脂が、高比重
の無機質粒子を保持できずに容易に脱落し、そこがらの
火炎の伝播が著しい。
[Problems to be Solved by the Invention] However, even if the sound insulation putty known so far has excellent sound insulation properties, it is not satisfactory in terms of fire resistance. That is, when exposed to flame, the binder resin melts and falls off, or cracks occur, making it impossible to prevent the flame from spreading from the sound-insulating putty. In particular, when the specific gravity of sound insulation putty is increased by mixing a large amount of high specific gravity inorganic particles, when exposed to flame, the molten binder resin cannot hold the high specific gravity inorganic particles and easily It fell off and the flame spread was significant.

本発明は、このような問題点を解決し、優れた耐火性を
有する遮音効果の高い遮音パテを提供するものである。
The present invention solves these problems and provides a sound insulating putty with excellent fire resistance and a high sound insulating effect.

[課題を解決するための手段] 本発明の遮音パテは、液状クロロプレンゴム100重量
部に対して、鉄精鉱スラグ200〜1300重量部と、
有機難燃繊維0.5〜40重量部とを、配合してなるも
のである。
[Means for Solving the Problems] The sound insulation putty of the present invention contains 200 to 1300 parts by weight of iron concentrate slag to 100 parts by weight of liquid chloroprene rubber,
It is made by blending 0.5 to 40 parts by weight of organic flame retardant fiber.

すなわち、本発明によれば、上記組成で遮音パテを構成
することにより、通常のパテに要求される充填作業性や
垂れ下がり防止性を損うことなく、すぐれた延焼防止効
果と遮音効果とを具備した遮音パテが得られる。
That is, according to the present invention, by forming the sound insulating putty with the above composition, it has excellent fire spread prevention effect and sound insulating effect without impairing the filling workability and sagging prevention properties required of ordinary putty. A sound-insulating putty is obtained.

本発明に用いる液状クロロプレンゴムとしては、通常市
販されているものを用い得るが、末端に一〇H基を有し
、25℃における粘度が(3〜8) X 10’ cp
sで、分子量分布が1500〜2800のものが好まし
い。
As the liquid chloroprene rubber used in the present invention, normally commercially available ones can be used, but those having a terminal 10H group and a viscosity at 25°C of (3 to 8) x 10' cp
s with a molecular weight distribution of 1,500 to 2,800.

本発明に用いる鉄精鉱スラグは、銅製錬工程で得られる
副生物であり、銅製錬工程の自溶炉から得られるマット
に、転炉で二酸化ケイ素と酸素とを添加して、シリケー
ト化と酸化を行なった後、生成するスラグを磁選し、得
られたスラグを浮遊選鉱して銅精鉱を回収した後の残物
を脱水して得られるものである。この鉄精鉱スラグの化
学組成例は、2FeO−8iO3(Feoとして40〜
50重量%、S I O2として15〜30重量%)、
Fe20410〜30重量%、Fe2O,5重量%、M
g05重量%以下であって、CaOはほとんど含有して
いない。
The iron concentrate slag used in the present invention is a by-product obtained in the copper smelting process, and silicon dioxide and oxygen are added to the matte obtained from the flash furnace in the copper smelting process in a converter to convert it into silicate. After oxidation, the resulting slag is subjected to magnetic separation, and the resulting slag is floated to recover copper concentrate, which is obtained by dehydrating the residue. An example of the chemical composition of this iron concentrate slag is 2FeO-8iO3 (Feo: 40~
50% by weight, 15-30% by weight as S I O2),
Fe204 10-30% by weight, Fe2O, 5% by weight, M
g05% by weight or less, and contains almost no CaO.

この鉄精鉱スラグは、上記のように、銅製錬工程で得ら
れる副生物であるから、安価であり、大量に生産される
。しかも浮遊選鉱を経たものであり、好都合にも破砕粒
子である。また、この鉄精鉱スラグのかさ密度は3〜4
であり、比重は4〜4.2であるから遮音効果を高める
ための充填剤として好ましいものである。この発明で使
用する鉄精鉱スラグの粒度は、100メツシユ以下が好
ましく、特に200メツシユ以下がより好ましい。
As described above, this iron concentrate slag is a by-product obtained in the copper smelting process, so it is inexpensive and produced in large quantities. Furthermore, it has undergone flotation and is conveniently crushed particles. In addition, the bulk density of this iron concentrate slag is 3 to 4.
Since it has a specific gravity of 4 to 4.2, it is preferable as a filler for enhancing the sound insulation effect. The particle size of the iron concentrate slag used in this invention is preferably 100 mesh or less, particularly preferably 200 mesh or less.

鉄精鉱スラグの配合量が液状クロロプレンゴム100重
量部に対して200重量部より少ない時は、高比重とな
らず十分な遮音効果が得られない。又、1300重量部
より多い時は、垂れ下がったり、粘着性が低下したり、
充填作業性が低下したり、混線加工性の面で大巾に低下
したりするので、いずれも好ましくない。より良いもの
を得るために、かかる鉄精鉱スラグは、700〜120
0重量部配合すること配合ましい。
When the amount of iron concentrate slag blended is less than 200 parts by weight per 100 parts by weight of liquid chloroprene rubber, the specific gravity will not be high and a sufficient sound insulation effect will not be obtained. Also, if it exceeds 1300 parts by weight, it may sag or the adhesiveness may decrease.
Both of these are undesirable, since the filling workability is lowered and the cross-wire workability is significantly lowered. In order to get better, such iron concentrate slag should be made from 700 to 120
It is preferable to add 0 parts by weight.

本発明において使用する有機難燃繊維とは、火炎に接し
た場合、該繊維が炭化するような、たとえばフェノール
ホルムアルデヒド樹脂系の繊維、カーボン系の繊維等が
これに該当する。
The organic flame-retardant fibers used in the present invention include, for example, phenol-formaldehyde resin-based fibers, carbon-based fibers, etc., which are carbonized when exposed to flame.

その繊維長は1〜10IIIIIのものを用いることが
好ましい。
It is preferable to use a fiber having a fiber length of 1 to 10III.

有機難燃繊維を配合することにより、遮音パテの垂れ下
がりを防止するとともに、火災時におけるバインダー樹
脂の溶融脱落を有効に防止する。
By blending organic flame-retardant fibers, the sound insulation putty is prevented from sagging, and the binder resin is effectively prevented from melting and falling off in the event of a fire.

有機難燃繊維の配合量が、液状クロロプレンゴム100
重量部に対して、0.5重量部より少ない時は、高比重
となる本発明の遮音パテの垂れ下がりを防止する作用が
不十分となり、さらに、延焼防止効果面でも寄与しなく
なる。逆に40重量部より多い場合には、混練加工性や
、充填作業性に劣ることになる。なお、繊維長にもよる
が、通常、1〜30重量部配合配合ことが好ましい。
The amount of organic flame retardant fiber is liquid chloroprene rubber 100%
When the amount is less than 0.5 part by weight, the effect of preventing the sound insulating putty of the present invention, which has a high specific gravity, from sagging will be insufficient, and furthermore, it will not contribute to the fire spread prevention effect. On the other hand, if the amount is more than 40 parts by weight, the kneading processability and filling workability will be poor. Although it depends on the fiber length, it is usually preferable to mix 1 to 30 parts by weight.

本発明の遮音パ、テにおいては、必要に応じ適宜、難燃
剤、可塑剤、充填剤、安定剤、酸化防止剤、滑剤、着色
剤等が配合されうる。
In the sound insulation pads and pads of the present invention, flame retardants, plasticizers, fillers, stabilizers, antioxidants, lubricants, colorants, etc. may be blended as appropriate.

難燃剤としては、従来公知のアンチモン酸化物、ジルコ
ニウム酸化物、ホウ素化合物の如き無機難燃剤や、ドデ
カクロロドデカヒドロジメタノジベンゾシクロオクテン
、1.2−ビス(2,3,4,5,6−ペンタブロモフ
ェノキシ)エタン、°デカブロモフェニルオキサイドの
如き有機難燃剤等が挙げられる。
Examples of flame retardants include conventionally known inorganic flame retardants such as antimony oxide, zirconium oxide, and boron compounds, as well as dodecachlorododecahydrodimethanodibenzocyclooctene, 1,2-bis(2,3,4,5,6 Examples include organic flame retardants such as -pentabromophenoxy)ethane and decabromophenyl oxide.

可塑剤としては、遮音パテの難燃効果を高める上で、ト
リメチル・ホスフェート、クレジルφジフェニル・ホス
フェート、トリクレジルφホスフェート、トリフェニル
φホスフェート等のリン酸系の可塑剤を用いることが好
ましい。
As the plasticizer, it is preferable to use a phosphoric acid-based plasticizer such as trimethyl phosphate, cresyl φ diphenyl phosphate, tricresyl φ phosphate, triphenyl φ phosphate, etc., in order to enhance the flame retardant effect of the sound insulation putty.

又、充填剤としては、焼成りレー、炭酸カルシウム、炭
酸マグネシウム、水酸化アルミニウム、珪酸アルミニウ
ム、珪酸マグネシウム等が挙げられる。
Further, examples of the filler include calcined clay, calcium carbonate, magnesium carbonate, aluminum hydroxide, aluminum silicate, magnesium silicate, and the like.

[発明の効果] 本発明の遮音パテは、火炎にさらされてもバインダー樹
脂が溶融脱落せず、優れた耐火性能及び延焼防止効果を
発揮する。
[Effects of the Invention] In the sound insulation putty of the present invention, the binder resin does not melt and fall off even when exposed to flame, and exhibits excellent fire resistance and fire spread prevention effect.

更に、本発明の遮音パテは、高比重であり優れた遮音効
果を発揮する。
Furthermore, the sound insulation putty of the present invention has a high specific gravity and exhibits an excellent sound insulation effect.

また、充填作業も容易であり、充填後に変形、収縮、垂
れ下がり等も生じない。
In addition, the filling operation is easy, and no deformation, shrinkage, sagging, etc. occur after filling.

[実施例] ゛ 次に、実施例および比較例により本発明をさらに詳細に
説明するが、本発明はこのような実施例のみに限定され
るものではない。
[Examples] Next, the present invention will be explained in more detail with reference to Examples and Comparative Examples, but the present invention is not limited to these Examples.

実施例1〜4、比較例1〜3 前述した配合材料を第1表に示す割合(重量部)で配合
し、バンバリーミキサで混練した。
Examples 1 to 4, Comparative Examples 1 to 3 The above-mentioned compounding materials were compounded in the proportions (parts by weight) shown in Table 1, and kneaded in a Banbury mixer.

得られた遮音パテについて以下の諸特性を測定し、その
結果を第1表に併記した。
The following properties of the obtained sound insulation putty were measured, and the results are also listed in Table 1.

(1)遮音性 遮音性は比重に大きく依存するので、遮音パテの比重を
JIS  K  0061 3.3項の第1法により、
」1定し、その値により遮音性の評価をした。
(1) Sound insulation The sound insulation is highly dependent on the specific gravity, so the specific gravity of the sound insulation putty was determined according to method 1 of JIS K 0061 Section 3.3.
”1, and the sound insulation properties were evaluated based on that value.

(2)難燃性 遮音パテにおける酸素指数を測定して評価した。数値が
大きい程難燃性が優れている。
(2) The oxygen index of the flame-retardant sound insulation putty was measured and evaluated. The larger the value, the better the flame retardancy.

酸素指数の測定はJIS  K  7201により行な
った。
The oxygen index was measured according to JIS K 7201.

(3)充填作業性 直径50III111長さ200 +uのバイブに遮音
パテを手で詰め込み、その充填作業性を検討した。円滑
に作業のできたものを○とし、そうでなかったものを×
とした。
(3) Filling workability A vibrator with a diameter of 50III, 111 and a length of 200+U was filled with sound insulating putty by hand, and its filling workability was examined. Mark ○ if the work was done smoothly, mark × if it was not.
And so.

(4)垂れ下がり性 JIS  A  5752.5.5項に準拠した方法で
711定した。すなわち、パーライト板(断熱材)によ
り長さ150mm、内幅10mm。
(4) Sagging property 711 was determined by a method based on JIS A 5752.5.5. That is, the pearlite board (insulating material) has a length of 150 mm and an inner width of 10 mm.

深さ25m+sの溝型を形成したものに遮音パテを詰め
、これを20℃の恒温空気槽に24時間懸垂放置し、次
いで60℃の恒温空気槽に24時間懸垂放置した時、容
器の下端から垂れ下がった遮音パテの長さを測定した。
A groove with a depth of 25m+s was filled with sound insulating putty, and when it was suspended in a constant temperature air tank at 20℃ for 24 hours, and then in a constant temperature air bath at 60℃ for 24 hours, the sound from the bottom of the container was The length of the hanging sound insulation putty was measured.

(以下余白) 表から明らかなように、実施例1〜4の遮音パテは、い
ずれも優れた特性を有するものであった。
(The following is a blank space) As is clear from the table, the sound insulation putty of Examples 1 to 4 all had excellent characteristics.

一方、比較例1の遮音パテにおいては、フェノールホル
ムアルデヒド樹脂繊維が配合されていないため、難燃性
に劣るとともに、垂れ下がり性が大きかった。更に、本
比較例においては、液状クロロプレンゴムが遮音パテ内
に占める割合が大゛きいため、遮音パテがべとつき、充
填作業性が悪かった。
On the other hand, in the sound insulation putty of Comparative Example 1, since the phenol formaldehyde resin fiber was not blended, the flame retardance was inferior and the sagging property was large. Furthermore, in this comparative example, the proportion of liquid chloroprene rubber in the sound insulation putty was large, so the sound insulation putty became sticky and the filling workability was poor.

比較例2の遮音パテにおいては、鉄精鉱スラグの配合量
が多すぎるため、垂れ下がり性が大きくなるとともに、
遮音パテがかたくなって充填作業性が悪かった。
In the sound insulation putty of Comparative Example 2, since the amount of iron concentrate slag blended was too large, the sagging property increased, and
The sound insulation putty became hard and the filling workability was poor.

比較例3の遮音パテにおいては、フェノールホルムアル
デヒド樹脂繊維の配合量が多すぎるため、遮音パテがか
たくなって充填作業性が悪かった。
In the sound insulation putty of Comparative Example 3, since the amount of phenol formaldehyde resin fibers was too large, the sound insulation putty became hard and the filling workability was poor.

Claims (1)

【特許請求の範囲】[Claims] 1、液状クロロプレンゴム100重量部に対して、鉄精
鉱スラグ200〜1300重量部と、有機難燃繊維0.
5〜40重量部とを、配合してなる遮音パテ。
1. 100 parts by weight of liquid chloroprene rubber, 200 to 1300 parts by weight of iron concentrate slag, and 0.0 parts by weight of organic flame retardant fiber.
A sound insulating putty made by blending 5 to 40 parts by weight.
JP3151888A 1988-02-12 1988-02-12 Sound insulating putty Pending JPH01204987A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3151888A JPH01204987A (en) 1988-02-12 1988-02-12 Sound insulating putty

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3151888A JPH01204987A (en) 1988-02-12 1988-02-12 Sound insulating putty

Publications (1)

Publication Number Publication Date
JPH01204987A true JPH01204987A (en) 1989-08-17

Family

ID=12333419

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3151888A Pending JPH01204987A (en) 1988-02-12 1988-02-12 Sound insulating putty

Country Status (1)

Country Link
JP (1) JPH01204987A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5066451B2 (en) * 2005-12-09 2012-11-07 電気化学工業株式会社 Adhesive composition and adhesive using the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5066451B2 (en) * 2005-12-09 2012-11-07 電気化学工業株式会社 Adhesive composition and adhesive using the same

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