JPH01201577A - Treatment of polyester fiber cloth - Google Patents
Treatment of polyester fiber clothInfo
- Publication number
- JPH01201577A JPH01201577A JP2257788A JP2257788A JPH01201577A JP H01201577 A JPH01201577 A JP H01201577A JP 2257788 A JP2257788 A JP 2257788A JP 2257788 A JP2257788 A JP 2257788A JP H01201577 A JPH01201577 A JP H01201577A
- Authority
- JP
- Japan
- Prior art keywords
- swelling
- treatment
- fiber
- fabric
- cloth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 45
- 239000004744 fabric Substances 0.000 title claims abstract description 25
- 229920000728 polyester Polymers 0.000 title claims abstract description 25
- 238000011282 treatment Methods 0.000 title claims abstract description 25
- 206010042674 Swelling Diseases 0.000 claims abstract description 31
- 230000008961 swelling Effects 0.000 claims abstract description 27
- 230000009477 glass transition Effects 0.000 claims abstract description 12
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 claims abstract description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000126 substance Substances 0.000 claims abstract 3
- 238000000034 method Methods 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 7
- 230000002522 swelling effect Effects 0.000 claims description 7
- 239000003814 drug Substances 0.000 claims description 5
- 229940079593 drug Drugs 0.000 claims description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000008096 xylene Substances 0.000 claims description 3
- 239000005711 Benzoic acid Substances 0.000 claims description 2
- 235000010233 benzoic acid Nutrition 0.000 claims description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 claims description 2
- 239000006260 foam Substances 0.000 claims 2
- 239000002075 main ingredient Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 abstract description 8
- -1 xylene- Chemical compound 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- UDHRWDDXQGMAHB-UHFFFAOYSA-N chlorobenzene 2-phenylphenol Chemical compound ClC1=CC=CC=C1.OC1=CC=CC=C1C1=CC=CC=C1 UDHRWDDXQGMAHB-UHFFFAOYSA-N 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- BIIBYWQGRFWQKM-JVVROLKMSA-N (2S)-N-[4-(cyclopropylamino)-3,4-dioxo-1-[(3S)-2-oxopyrrolidin-3-yl]butan-2-yl]-2-[[(E)-3-(2,4-dichlorophenyl)prop-2-enoyl]amino]-4,4-dimethylpentanamide Chemical compound CC(C)(C)C[C@@H](C(NC(C[C@H](CCN1)C1=O)C(C(NC1CC1)=O)=O)=O)NC(/C=C/C(C=CC(Cl)=C1)=C1Cl)=O BIIBYWQGRFWQKM-JVVROLKMSA-N 0.000 description 2
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- DWKNOLCXIFYNFV-HSZRJFAPSA-N 2-[[(2r)-1-[1-[(4-chloro-3-methylphenyl)methyl]piperidin-4-yl]-5-oxopyrrolidine-2-carbonyl]amino]-n,n,6-trimethylpyridine-4-carboxamide Chemical compound CN(C)C(=O)C1=CC(C)=NC(NC(=O)[C@@H]2N(C(=O)CC2)C2CCN(CC=3C=C(C)C(Cl)=CC=3)CC2)=C1 DWKNOLCXIFYNFV-HSZRJFAPSA-N 0.000 description 2
- HFGHRUCCKVYFKL-UHFFFAOYSA-N 4-ethoxy-2-piperazin-1-yl-7-pyridin-4-yl-5h-pyrimido[5,4-b]indole Chemical compound C1=C2NC=3C(OCC)=NC(N4CCNCC4)=NC=3C2=CC=C1C1=CC=NC=C1 HFGHRUCCKVYFKL-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000009998 heat setting Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 1
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- MMINFSMURORWKH-UHFFFAOYSA-N 3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical group O=C1OCCOC(=O)C2=CC=C1C=C2 MMINFSMURORWKH-UHFFFAOYSA-N 0.000 description 1
- WSQZNZLOZXSBHA-UHFFFAOYSA-N 3,8-dioxabicyclo[8.2.2]tetradeca-1(12),10,13-triene-2,9-dione Chemical group O=C1OCCCCOC(=O)C2=CC=C1C=C2 WSQZNZLOZXSBHA-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- XULSCZPZVQIMFM-IPZQJPLYSA-N odevixibat Chemical compound C12=CC(SC)=C(OCC(=O)N[C@@H](C(=O)N[C@@H](CC)C(O)=O)C=3C=CC(O)=CC=3)C=C2S(=O)(=O)NC(CCCC)(CCCC)CN1C1=CC=CC=C1 XULSCZPZVQIMFM-IPZQJPLYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- KMIOJWCYOHBUJS-HAKPAVFJSA-N vorolanib Chemical compound C1N(C(=O)N(C)C)CC[C@@H]1NC(=O)C1=C(C)NC(\C=C/2C3=CC(F)=CC=C3NC\2=O)=C1C KMIOJWCYOHBUJS-HAKPAVFJSA-N 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はポリエステル系繊維布帛の膨潤加工技術に関す
るもので、特に、天然繊維に付与される優れた風合を示
すポリエステル系繊維布帛に関するものである。Detailed Description of the Invention (Field of Industrial Application) The present invention relates to swelling processing technology for polyester fiber fabrics, and in particular to polyester fiber fabrics that exhibit the excellent texture imparted to natural fibers. be.
（発明が解決しようとする問題点）
ポリエステル系繊維は、その優れた消費性能から産業資
材用から一般衣料用まで極めて広範囲に用いられている
。しかしながら一般衣料用としての性能としては、例え
ば発色性ワキシー感など数々の欠点を有しており、それ
らの欠点に関しては例えば繊維表面に無数の超ミクロク
レータ−を形成させたり、或いはプラズマによりエツチ
ングしたりする事によシ解決されている。しかし彦から
まだまだ未解決の欠点も多く残されている。(Problems to be Solved by the Invention) Polyester fibers are used in a wide range of applications from industrial materials to general clothing because of their excellent consumption performance. However, in terms of performance for general clothing, it has a number of drawbacks, such as color development and a waxy feel, and these drawbacks include, for example, the formation of countless ultra-micro craters on the fiber surface, or etching by plasma. This has been solved by doing this. However, there are still many unresolved shortcomings left by Hiko.
の変化により生ずる天然繊維独特の風合に代表される繊
維性能の付与は、今日に到っても未だ解決されていない
課題の一つである。Imparting fiber performance, typified by the unique texture of natural fibers caused by changes in fiber properties, is one of the issues that remains unsolved to this day.
ここで木綿などに示される膨潤、脱膨潤による効果とは
、第１図の概念図で示−されるように、膨潤、脱膨潤に
よ〕織又は編組織にウェーブ立ちによるルーズな空間が
形成されることに起因する効果である。Here, the effect of swelling and de-swelling shown in cotton etc. is the formation of loose spaces due to waves in the woven or knitted structure due to swelling and de-swelling, as shown in the conceptual diagram in Figure 1. This is an effect caused by the fact that
本発明者らは、ポリエステル系繊維の持つ優れた性能を
損うことなく上記性能を付与すべく鋭意研究の結果本発
明に到ったものである。The present inventors have arrived at the present invention as a result of intensive research in order to provide the above-mentioned performance without impairing the excellent performance of polyester fibers.
（問題点を解決するための手段）
即ち、少くとも３０チがポリエステル系繊維により構成
さ）する布帛を、該ポリエステル系繊維に対して膨潤性
を有する薬剤により膨潤させ、これを脱膨口させる膨潤
処理を行なう事により、天然繊維の持つ膨潤脱膨潤によ
る独特の風合を付与するというものである。(Means for solving the problem) In other words, a fabric made of at least 30 pieces of polyester fibers is swollen with a drug that has swelling properties for the polyester fibers, and the fabric is deflated. By performing the swelling treatment, a unique texture due to the swelling and de-swelling of natural fibers is imparted.
本発明によれば、布帛の織又は輸組織のウェーブが立ち
、天然繊維より成る布帛の風合により近づけることが可
能となるのである。又本方法によれば、ポリエステル系
繊維の持つウオツシュアンドウェア−性等の好ましい特
性を何等損うことはないのである。According to the present invention, the weave or transfusion structure of the fabric has waves, making it possible to have a texture closer to that of a fabric made of natural fibers. Furthermore, according to this method, the desirable properties of polyester fibers such as wash and wear properties are not impaired in any way.
本発明において、ポリエステル系線維の布帛中での割合
は、少くとも３０チ以上である事が、その効果を発現さ
せる上で必要である。３０４以下であると、他の繊維の
効果にかくれて本発明の効果が減殺されてしまうからで
ある。In the present invention, it is necessary that the proportion of polyester fibers in the fabric be at least 30% or more in order to exhibit the effect. This is because if it is less than 304, the effects of the present invention will be diminished by the effects of other fibers.
もちろん、本発明でいうポリエステル系繊維に対して膨
潤性を有する薬剤にょる膨■性を有する繊維との組合せ
の場合には、さらに効果が相乗効果を持って発現する事
が期待される。Of course, when polyester fibers in the present invention are combined with swelling fibers using a swelling agent, it is expected that even more synergistic effects will be produced.
本発明者らは、ポリエステル系繊維に対して膨潤性を有
する薬剤について鋭意研究の結果、安息香酸系、キシレ
ン系、メチルナフタレン系、フェニルフェノール系、ク
ロルベンゼン系の薬剤カ好ましい事を見出した。前四者
の系とけ、各々の異性体例えばオルト、バラ、メタ等の
集合をいい、クロルベンゼン系とはモノ及びジ、トリク
ロルベンゼンの各々の異性体の集合をいう。As a result of extensive research into drugs that have swelling properties for polyester fibers, the present inventors found that benzoic acid-based, xylene-based, methylnaphthalene-based, phenylphenol-based, and chlorobenzene-based drugs are preferable. The former four systems refer to the collection of each isomer such as ortho, rose, meta, etc., and the chlorobenzene system refers to the collection of each isomer of mono, di, and trichlorobenzene.
尚キシレン系は爆発の危険があり、相応の設備を用いる
事が必要である。又、フェノールは膨潤性は著しく良好
であるが、残留した場合の毒性から適尚ではないのであ
る。又、この際テトラクロルエタン等の助剤を、併用す
る事も有効である。Note that xylene has the danger of explosion, so it is necessary to use appropriate equipment. Furthermore, although phenol has extremely good swelling properties, it is not suitable because of its toxicity if it remains. Further, at this time, it is also effective to use an auxiliary agent such as tetrachloroethane.
さらに本発明者らは、ポリエステル系繊維と膨潤性を有
する薬剤との量比について鋭意研究の結果、ポリエステ
ル系繊維に対して、薬剤を３０重量（以下ｗｔと略）憾
以上用いることが、好ましいことを見出した。３０ ｗ
ｔ％未満では、本発明の目的とする風合機能の付与が不
十分なものとなってしまうのである。Furthermore, as a result of intensive research on the ratio of the amount of the agent having swelling properties to the polyester fiber, the present inventors found that it is preferable to use 30 weight (hereinafter abbreviated as "wt") or more of the agent to the polyester fiber. I discovered that. 30w
If it is less than t%, the hand-feeling function that is the object of the present invention will not be imparted sufficiently.
さらに本発明者らは膨潤処理を実施する際の処理温度に
ついて検討するに当り、用いるポリエステル系線維のガ
ラス転移点温度以上、１４５℃以Ｆが好昔しいことを見
出した。Furthermore, the present inventors, when considering the treatment temperature when carrying out the swelling treatment, found that a temperature higher than the glass transition temperature of the polyester fiber used, 145° C. or lower, is preferable.
ガラス転移点より低い温度で処理を行ってもその効果は
発現しに＜＜、膨潤性を有する薬剤の瞳を・画のて′４
量に要するばかりか、その効果も不十分なものとなって
しまうのである。また処理湯度が１４５℃を越えると、
＋１維物性（ポリマー物性）の大１】な氏上をきたし
、布帛の消費性能を損う結果となるのである。Even if the treatment is performed at a temperature lower than the glass transition point, the effect will not be expressed.
Not only is the quantity required, but the effect is also insufficient. Also, if the temperature of the treated water exceeds 145℃,
This results in a +1 increase in fiber physical properties (polymer physical properties) and impairs the consumption performance of the fabric.
さらに本発明者らは、ポリエステル系繊維の熱履歴と膨
潤性の関係について研究した結果、ガラス転移点（℃，
） ＋８３ ’（、以上の熱処理を受けていないことが
より好ましいことが明らかとした。さらに好ましくは、
ガラス転移点（℃） ＋ ６５ ｎ以上の熱処理を受け
ていないことである。Furthermore, as a result of researching the relationship between the thermal history and swelling properties of polyester fibers, the present inventors found that the glass transition point (℃,
)+83'(, It has become clear that it is more preferable that the material is not subjected to heat treatment. More preferably
The glass transition point (°C) must not have been subjected to heat treatment above +65 nm.
これは、ポリエステル系繊維は紡糸された後、布帛とな
り膨潤処理するまでの間に、種々の熱処理を受けるが、
その工程は、繊維（分子）の配向及び結晶化を促がし、
従って結晶化度が上昇し、膨潤処理を受けにくくなるた
めである。結晶化度の上昇は、処理温度に比例してその
速度が上昇するために、より低温での熱処理が好ましい
ことになるのである。さらには、省略可能な熱処理は本
発明を実施するに当ってはできる限シ省略することが好
ましい結果をもたらすこととなるのである。This is because after polyester fibers are spun, they undergo various heat treatments before turning into fabric and undergoing swelling treatment.
The process promotes fiber (molecule) orientation and crystallization,
This is because the degree of crystallinity increases, making it difficult to undergo swelling treatment. Since the rate of increase in crystallinity increases in proportion to the treatment temperature, heat treatment at a lower temperature is preferable. Furthermore, it is preferable to omit the omissible heat treatment as much as possible when carrying out the present invention.
もちろん膨潤処理後は必要に応じて適当な熱処理を加え
ることは可能である。Of course, after the swelling treatment, it is possible to apply an appropriate heat treatment if necessary.
膜膨潤させる方法としては、前述の如き温度下での膨潤
をさせた場合、常温、常圧下にもどすのみでほとんどの
場合脱膨潤をする。この様な場合以外の場合には脱薬剤
によシ脱膨潤処理が必要となる。この処理には溶剤によ
る抽出、乾熱加熱、減圧等があげられ、これらの組合せ
も有効である。As a method for swelling the membrane, in most cases, when the membrane is swollen at the temperature described above, it is simply returned to normal temperature and pressure to deswell. In cases other than this, a deswelling treatment using a chemical-removal agent is required. This treatment includes extraction with a solvent, dry heat heating, reduced pressure, etc., and combinations of these are also effective.
本発明に用いられるポリエステル系繊維とは、構成単位
の残基８０モルチ以上が、エチレンテレフタレート残基
又はブチレンテレフタレート残基により構成されるポリ
エステルにより形成される繊維をいう。もちろん該ポリ
エステルに艶消剤としての酸化チタンや、その他の無機
粒子、例えば硫酸バリウム粒子を含んでいても良く、マ
た、着色剤としての染料や顔料、酸化防止剤や紫外線吸
収剤を含んでいても良く、改質剤としてのポリアルキレ
ングリコール等を含有していても良い。The polyester fiber used in the present invention refers to a fiber formed from a polyester in which 80 moles or more of residues of structural units are ethylene terephthalate residues or butylene terephthalate residues. Of course, the polyester may contain titanium oxide as a matting agent, other inorganic particles such as barium sulfate particles, and may also contain dyes and pigments as colorants, antioxidants, and ultraviolet absorbers. It may also contain polyalkylene glycol or the like as a modifier.
以下実施例により、詳しく説明する。This will be explained in detail below using examples.
実施例−１〜９、比較例−１〜６及び対照常法によりポ
リエチレンテレフタレート（ガラス転移点６８℃、固有
粘度０．６９）を紡糸シフ、続いてローラープレート延
伸機により、ローラー温度７５°Ｃ，プレート温度は表
−１中に記載の温度条件により延伸を行い、７５デニー
ル、３６フイラメントの延伸糸を得た。この各々を用い
てそれぞわ羽二重とした。ついで常法による糊抜きリラ
ックス精練を行い、続いて表−１中に記す条件（処理な
しを含む）によりヒートセットを行った後、表−１中に
記載の条件により水分散又は水溶液系において膨潤処理
を実施した。これを通常工程によりヒートセット処理ま
で実施したものを対照としてこれを１と１７、最も好ま
しいものを５として、５段階評価した。また繊維の劣化
等の不都合を生じた場合は評価を×とした。これらを実
施例−１〜９、比較例−１〜６とし表−１に記載した。Examples 1 to 9, Comparative Examples 1 to 6, and Control Polyethylene terephthalate (glass transition point: 68°C, intrinsic viscosity: 0.69) was spun using a conventional method, and then the roller temperature was 75°C using a roller plate drawing machine. The plate temperature was as shown in Table 1 to obtain a drawn yarn of 75 denier and 36 filaments. Each of these was used to make Habutae. Next, the desizing is relaxed and refined by a conventional method, followed by heat setting under the conditions listed in Table 1 (including no treatment), and then swollen in an aqueous dispersion or aqueous solution system according to the conditions listed in Table 1. Processing was carried out. This was evaluated on a five-point scale, with 1 and 17 being the most preferable, and 5 being the most preferable, using as a control one that had been subjected to heat setting treatment in the normal process. In addition, when inconveniences such as fiber deterioration occurred, the evaluation was given as ×. These are listed in Table 1 as Examples 1 to 9 and Comparative Examples 1 to 6.
比１！２例−１，４にはガラス転移点（６８℃）＋８３
℃−１５１″Ｃを越えた熱処理を受けた場合、比較例−
２には、膨潤処理温度が１４５℃を越え九場合、比較例
−３には膨潤剤の使用量が３０％以下の場合、比較例−
４，５には膨潤処理温度がガラス転移点以下のｆＪＩＪ
合を示した。Ratio 1!2 cases - 1 and 4 have glass transition point (68℃) +83
Comparative example-
In Comparative Example 2, when the swelling treatment temperature exceeds 145°C, in Comparative Example 3, when the amount of swelling agent used is 30% or less, and in Comparative Example -
4 and 5 are fJIJ whose swelling treatment temperature is below the glass transition point.
It showed that
実施例−１０，比較例−７
ポリブチレンテレフタレート［維（ガラス転移点３９℃
）を実施例−１と同様に紡糸し、表−１に記載の条件に
より延伸し、７５デニール３６フイラメントの延伸糸と
した。以後前記実施例と同様にして評価した結果を表−
１に実施例−１０及び比較例−７として示す。Example-10, Comparative Example-7 Polybutylene terephthalate [fiber (glass transition point 39°C
) was spun in the same manner as in Example 1 and drawn under the conditions listed in Table 1 to obtain a drawn yarn of 75 denier and 36 filaments. Thereafter, the results of the evaluation in the same manner as in the above examples are shown in the table below.
1 as Example-10 and Comparative Example-7.
実施例−１１、比較例−８
実施例−１に用いたポリブチレンテレフタレートｆＲ維
を経糸と１〜．７５デニール相当の綿糸を緯糸として羽
二重とし、これ表−１に示す条件により評価した。また
経糸も実施例−１１に用いた綿糸を用いて、同様に評価
した。これを実施例−１１及び比較例−８として表−１
に示す。Example 11, Comparative Example 8 The polybutylene terephthalate fR fibers used in Example 1 were used as warp yarns and 1 to 1. A cotton yarn equivalent to 75 denier was used as a weft to form a habutae, and was evaluated under the conditions shown in Table 1. In addition, the warp yarns were also evaluated in the same manner using the cotton yarns used in Example-11. Table 1 shows this as Example-11 and Comparative Example-8.
Shown below.
以下余白Margin below
第１図は、膨潤、脱膨潤による織組織の変化、即ち、ウ
ェーブ立ち効果を、概念的に説明した説明図。
特許出願人 株式会社 り ラ しFIG. 1 is an explanatory diagram conceptually explaining the change in the texture due to swelling and de-swelling, that is, the waving effect. Patent applicant RiRa Shi Co., Ltd.
Claims (6)
成される布帛を、該ポリエステル系繊維に対して膨潤性
を有する薬剤により、膨潤処理することを特徴とする布
帛の処理方法(1) A method for treating a fabric, which comprises swelling a fabric made up of at least 30% polyester fibers with a drug that has swelling properties for the polyester fibers.
、メチルナフタレン系、フェニルフェノール系、クロル
ベンゼン系の薬剤少なくとも一種を主成分とする薬剤で
ある特許請求の範囲第１項記載の布帛の処理方法(2) The fabric according to claim 1, wherein the swelling agent is a drug whose main ingredient is at least one of benzoic acid, xylene, methylnaphthalene, phenylphenol, and chlorobenzene agents. How to process
に対し、膨潤性を有する薬剤を３０ｗｔ％以上用いるこ
とを特徴とする、特許請求の範囲第１項あるいは第２項
記載の布帛の処理方法(3) A method for treating a fabric according to claim 1 or 2, characterized in that in carrying out the swelling treatment, 30 wt% or more of a swelling agent is used for the polyester fibers.
１４５℃以下の温度範囲で実施することを特徴とする、
特許請求の範囲第１項乃至第３項のいずれか記載の布帛
の処理方法(4) When carrying out the swelling treatment, above the glass transition point,
characterized by being carried out in a temperature range of 145°C or less,
A method for treating a fabric according to any one of claims 1 to 3.
＋８３℃以上の熱処理を受けていない布帛を用いること
を特徴とする、特許請求の範囲第１項乃至第４項のいず
れか記載の布帛の処理方法(5) When carrying out swelling treatment, glass transition point (°C)
A method for treating a fabric according to any one of claims 1 to 4, which uses a fabric that has not been heat-treated at +83°C or higher.
を泡状とし、布帛に付着せしめて膨潤させる事を特徴と
する、特許請求の範囲第１項乃至第５項のいずれか記載
の布帛の処理方法(6) The method according to any one of claims 1 to 5, characterized in that, in carrying out the swelling treatment, a chemical solution having swelling properties is made into a foam, and the foam is applied to the fabric to cause the fabric to swell. Fabric treatment method
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2257788A JPH01201577A (en) | 1988-02-01 | 1988-02-01 | Treatment of polyester fiber cloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2257788A JPH01201577A (en) | 1988-02-01 | 1988-02-01 | Treatment of polyester fiber cloth |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01201577A true JPH01201577A (en) | 1989-08-14 |
Family
ID=12086721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2257788A Pending JPH01201577A (en) | 1988-02-01 | 1988-02-01 | Treatment of polyester fiber cloth |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01201577A (en) |
-
1988
- 1988-02-01 JP JP2257788A patent/JPH01201577A/en active Pending
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