KR910003653B1 - Method of silk fabrics modification - Google Patents
Method of silk fabrics modification Download PDFInfo
- Publication number
- KR910003653B1 KR910003653B1 KR1019890004492A KR890004492A KR910003653B1 KR 910003653 B1 KR910003653 B1 KR 910003653B1 KR 1019890004492 A KR1019890004492 A KR 1019890004492A KR 890004492 A KR890004492 A KR 890004492A KR 910003653 B1 KR910003653 B1 KR 910003653B1
- Authority
- KR
- South Korea
- Prior art keywords
- silk fiber
- silk
- fiber
- alkali metal
- metal salt
- Prior art date
Links
- 238000000034 method Methods 0.000 title description 7
- 239000004744 fabric Substances 0.000 title description 4
- 238000012986 modification Methods 0.000 title description 3
- 230000004048 modification Effects 0.000 title description 3
- 239000000835 fiber Substances 0.000 claims abstract description 28
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000007864 aqueous solution Substances 0.000 claims description 9
- -1 alkali metal salt Chemical class 0.000 claims description 6
- 150000003961 organosilicon compounds Chemical class 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 abstract description 3
- 239000012266 salt solution Substances 0.000 abstract description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 230000000051 modifying effect Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 230000007547 defect Effects 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000012209 synthetic fiber Substances 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000006187 pill Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002715 modification method Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
본 발명은 담요용 견섬유 개질방법에 관한 것으로, 견섬유를 담요(Blanket)용으로 적합하게 필링성(Pilling)과 융털의 형태 안정성을 개선시키는 견섬유 가공방법에 관한 것이다.The present invention relates to a method for modifying a silk fiber for a blanket, and relates to a silk fiber processing method for improving the peeling properties and shape stability of the fleece to suit the silk fiber for a blanket.
종래의 담요는 주로 아크릴과 폴리에스테르와 같은 합성섬유나, 양모를 주소재(主素材)로 하였으나 양모의 경우 원료비가 고가이고, 아크릴과 폴리스에스테르와 같은 합성섬유의 경우 흡수성이 떨어지며 정전기가 발생하고 촉감이 좋지 않는 등의 결점이 있었다.Conventional blankets are mainly made of synthetic fibers such as acrylic and polyester or wool as the main material, but raw materials are expensive for wool, and synthetic fibers such as acrylic and polyester have low absorbency and generate static electricity. There was a defect such as poor touch.
따라서 합성섬유제 담요의 결점을 개선하기 위하여 견섬유 담요를 제조할 경우 촉감, 보온성 및 흡습성이 우수할 뿐 아니라 드레이프(Drape)성이 우수하고 경량감이 있어 아주 좋은 결과를 얻을 수 있으나, 견섬유는 일반적으로 세 섬유이고 강도가 높기 때문에 종래의 견섬유로 담요를 제조하였을 때 필링성과 융털의 형태 안정성이 큰 문제점으로 대두되고 있는 것이다.Therefore, in order to improve the defects of synthetic fiber blankets, the silk fiber blankets are not only excellent in touch, heat retention, and hygroscopicity, but also have excellent drape and light weight. Since the fiber is high in strength and when the blanket is manufactured from conventional silk fibers, the peeling properties and the shape stability of the fleece are emerging as a big problem.
따라서 본 발명자들은 견섬유 개질을 위한 연구를 거듭한 결과 견섬유의 고유한 특성을 살리며 담요용으로 적합한 본 발명을 하게 된 것이다.Therefore, the present inventors have made the present invention suitable for the blanket while utilizing the unique properties of the silk fiber as a result of repeated studies for the modification of the silk fiber.
일반적으로 종래의 견섬유 개질방법으로서, 유기단량체를 견섬유 내부에 그래프팅(grafting)시키는 방법과 가교제에 의한 가교결합방식 외에 견섬유 표면에 레진을 코오팅하는 방법이 알려져 왔으나, 이와같은 개질방법은 견섬유의 촉감을 손상시키고, 황변화시키며, 흡습성을 감소시키는 결함이 있을 뿐만 아니라 염색성을 저하시키는 문제점이 있으며 담요 특성에 적합하지 않는 결과를 가져오는 개질 방법인 것이다.In general, as a conventional method of modifying the silk fiber, a method of grafting an organic monomer into the silk fiber and a method of coating a resin on the surface of the silk fiber in addition to the crosslinking method by a crosslinking agent have been known. In addition to the defects that impair touch, yellowing, and reduce hygroscopicity, there is a problem of lowering the dyeability and is a modification method that results in unsuitable blanket characteristics.
본 발명은 상기와 같은 문제점을 해결하기 위하여 견섬유를 알카리 금속염의 수용액으로 우선 처리하고 이를 온수로서 수세한 다음 탄산염 수용액으로 일정시간 알맞는 온도를 유지하면서 잔류염을 제거하고 이를 다시 충분히 수세한 다음, 유기 규소 화합물로서 처리하여 촉감 및 광택을 향상시킴을 특징으로 하는 견섬유 개질 방법인 것이다.In order to solve the above problems, the silk fiber is first treated with an aqueous solution of an alkali metal salt and washed with hot water, followed by removing the residual salt while maintaining a suitable temperature for a predetermined time with an aqueous solution of carbonate, followed by washing with water sufficiently. It is a method for modifying silk fibers characterized by treating as an organosilicon compound to improve the feel and gloss.
이하 본 발명을 구체적으로 설명하면 견섬유를 농도 30-65중량%의 알카리 금속염의 수용액으로 온도 50-80℃를 유지하면서 2-10분간 처리한후 40-70℃의 온수로수세하고 이를 1-10중량%의 탄산염 수용액에서 온도 70-90℃를 유지하면서 2-10분간 처리함으로서 잔류하는 염을 완전 제거하여 견섬유의 황변화를 방지시키는 것이다.Hereinafter, the present invention will be described in detail, the silk fiber is treated with an aqueous solution of an alkali metal salt having a concentration of 30-65% by weight for 2-10 minutes while maintaining a temperature of 50-80 ° C, and then washed with warm water at 40-70 ° C. It is to prevent the sulfur change of the silk fiber by completely removing the remaining salt by treating for 2-10 minutes while maintaining the temperature of 70-90 ℃ in weight% aqueous solution of carbonate.
그리고 이와같이하여 얻은 견섬유는 유기 규소화합물 2-20중량% 농도의 처리액에 통과시켜 우아한 촉감과 광택을 부여하게 되는 것이다.And the silk fiber obtained in this way is passed through the treatment liquid of 2-20 weight% of organosilicon compound, and gives an elegant touch and gloss.
본 발명중 알카리 금속염의 수용액 처리는 견 섬유의 섬도를 증가시키게 되고, 강도 및 굴곡마찰강도를 저하시키고 신장회복율이 증가하므로 가공된 견직물은 필(pill)형성이 억제되거나 또는 발생된 필(pill)이 쉽게 탈락하게 된다. 이 경우 알카리 금속염의 수용액 농도를 65중량% 이상이거나 30중량% 이하일 경우에는 견섬유가 용해하거나, 촉감이 딱딱하게 되어 부적합하게 된다.The aqueous solution treatment of the alkali metal salt in the present invention increases the fineness of the silk fiber, decreases the strength and flexural friction strength, and increases the elongation recovery rate, so that the processed silk fabric is suppressed from pill formation or generated pill. This is easily eliminated. In this case, when the aqueous solution concentration of the alkali metal salt is 65% by weight or more or 30% by weight or less, the silk fibers are dissolved or the touch becomes hard, which is not suitable.
따라서 본 발명에 의하여 개질된 견섬유로써 제직된 담요는 융털의 형태 안정성이 증가하며, 항필링(Antipilling)성이 향상된 우아한 촉감과 염색성이 뛰어난 담요를 얻게 되는 것이다.Accordingly, the blanket woven from the modified silk fiber according to the present invention increases the shape stability of the fleece, and obtains an elegant touch and dyeing blanket having improved anti-pilling property.
본 발명 견섬유 개질방법은 그 처리방법이 간단하고 공정시간이 짧은 것은 물론 개질효과가 뛰어나 개질후에도 견의 고유한 특성을 그대로 오래도록 유지할수 있어서 담요용 이외에도 많은 새로운 용도가 필요로 되어진다.In the present invention, the method for modifying the silk fiber is not only simple but also short in processing time, and excellent in modifying effect, so that the unique characteristics of the silk can be maintained for a long time after modification.
이하 본 발명을 실시예에 따라 구체적으로 상술한다.Hereinafter, the present invention will be described in detail with reference to Examples.
실시예 및 비교예를 아래 "표 1" 및 "표 2"에서 나타내었다. "표 1"은 알카리 금속염 및 탄산염 수용액에 대한 농도, 처리온도 및 처리시간과 욕비에 대한 조건과 유기화합물의 농도에 대한 조건이고, "표 2"는 상기 각 처리조건에 따른 견섬유의 물성과 견직물의 물성 비교표인 것이다.Examples and comparative examples are shown below in "Table 1" and "Table 2". "Table 1" is a condition for the concentration, treatment temperature and treatment time and bath ratio for the alkali metal salt and carbonate aqueous solution, and the conditions for the concentration of the organic compound, "Table 2" is the physical properties and silk fabric of the silk fiber according to each treatment condition It is a comparison table of physical properties.
[표 1]TABLE 1
실시예 및 비교예의 가공조건Processing conditions of Examples and Comparative Examples
* 각 실시예 및 비교예에서 알카리 금속염 수용액은 욕비 50 : 1로 한 것임.* In each Example and Comparative Example, the aqueous alkali metal salt solution was set to a bath ratio of 50: 1.
[표 2]TABLE 2
견섬유 및 견직물(견담요)에 대한 물성 비교표Comparison of Properties for Silk Fibers and Silk Fabrics
범례 : ○ : 양호, △ : 보통, × : 불량.Legend: ○: Good, △: Normal, ×: Poor.
실시예 1-8에서와 같이 알카리 금속염 수용액으로 적정조건하에서 처리된 견섬유의 물성은 섬도와 신장회복율 증가하였고 강도와 굴곡마모강도가 저하 하였으며 이것으로 제직한 담요는 종래 섬유로 제조된 담요에 비하여 촉감과 염색성은 비슷하나 필링성과 융털의 형태 안정성이 개선되었음을 알 수 있다. 그러나 적정조건을 벗어난 범위에서 처리된 경우(비교예 1 내지 비교예 2)는 견섬유 자체가 손상되거나 황변하여 촉감이 딱딱해져 담요로서의 특성에 적합하지 않음을 알 수 있는 것이다.As in Example 1-8, the physical properties of the silk fiber treated with an aqueous alkali metal salt solution under appropriate conditions increased the fineness and elongation recovery rate, and the strength and flexural wear strength were lowered. The dyeing and dyeing properties were similar, but the peeling properties and the morphological stability of the fleece were improved. However, when treated in a range outside the appropriate conditions (Comparative Examples 1 to 2) it can be seen that the silk fiber itself is damaged or yellowed and the feel is hard to fit the characteristics as a blanket.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019890004492A KR910003653B1 (en) | 1989-04-04 | 1989-04-04 | Method of silk fabrics modification |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019890004492A KR910003653B1 (en) | 1989-04-04 | 1989-04-04 | Method of silk fabrics modification |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR900016539A KR900016539A (en) | 1990-11-13 |
| KR910003653B1 true KR910003653B1 (en) | 1991-06-08 |
Family
ID=19285128
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019890004492A KR910003653B1 (en) | 1989-04-04 | 1989-04-04 | Method of silk fabrics modification |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR910003653B1 (en) |
-
1989
- 1989-04-04 KR KR1019890004492A patent/KR910003653B1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR900016539A (en) | 1990-11-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2726133A (en) | Effect threads | |
| KR910003653B1 (en) | Method of silk fabrics modification | |
| US3144300A (en) | Treatment of keratinous fibers | |
| JP2000256960A (en) | Processing of refined cellulose fiber woven and knitting fabric | |
| CN114703683A (en) | Bio-based knitted fabric and dyeing and finishing process thereof | |
| KR101573642B1 (en) | Process of producing high-density polyester fabrics having exellent antistatic property and color depth | |
| US4472166A (en) | Method for reforming cellulose fiber cloth | |
| KR920005899B1 (en) | Dyeing process of conjugated fiber structure | |
| KR940011474B1 (en) | Making method of water repellent fabric | |
| JPS6364551B2 (en) | ||
| JPH06240534A (en) | Lightweight woven or knit fabric | |
| KR910009703B1 (en) | The finishing method of silk fabric enhanced the pill resistance | |
| KR100476538B1 (en) | Manufacturing method of polyester fabric with excellent water repellent durability and antistatic property | |
| KR100211455B1 (en) | The conjugated fiber of the polyester/polyamide | |
| KR960001899B1 (en) | Preparation method of water repellent and oil-repellent fabric | |
| KR930000365B1 (en) | Process for manufacturing a super water repellency woven | |
| KR0120171B1 (en) | Weight loss treating method of modified polyester fiber and weight loss treated fiber | |
| JP2855505B2 (en) | Polyester fiber weight loss accelerator and alkali weight loss treatment method | |
| US3173803A (en) | Shrink resistance of wool by coating with fibrous boehmite | |
| KR980009573A (en) | A method for manufacturing a natural-texture suede fabric having excellent elasticity | |
| JPS58120872A (en) | Modification of polyester fiber | |
| JPS5966572A (en) | Wash-and-wear process of knitted fabric | |
| CN117449090A (en) | Processing technology for antigen fibrillation of lyocell fabric | |
| KR920002508B1 (en) | Manufacture method of polyester fabric | |
| JP2004315990A (en) | Moisture-absorbing exothermic cellulosic fiber product having wind-breaking property and method for producing the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| G160 | Decision to publish patent application | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 19950719 Year of fee payment: 6 |
|
| LAPS | Lapse due to unpaid annual fee |