JPH01187912A - Forming method for end face electrode of electronic component - Google Patents

Forming method for end face electrode of electronic component

Info

Publication number
JPH01187912A
JPH01187912A JP63013411A JP1341188A JPH01187912A JP H01187912 A JPH01187912 A JP H01187912A JP 63013411 A JP63013411 A JP 63013411A JP 1341188 A JP1341188 A JP 1341188A JP H01187912 A JPH01187912 A JP H01187912A
Authority
JP
Japan
Prior art keywords
face
electronic component
electrode
temperature
sputtering
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP63013411A
Other languages
Japanese (ja)
Other versions
JPH0787161B2 (en
Inventor
Tanejiro Ikeda
池田 種次郎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP63013411A priority Critical patent/JPH0787161B2/en
Publication of JPH01187912A publication Critical patent/JPH01187912A/en
Publication of JPH0787161B2 publication Critical patent/JPH0787161B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

PURPOSE:To obtain a forming method for end face electrodes having excellent electric characteristics and no problem in quality stability by reversely sputtering the end face of an electronic component at the heat resistance temperature or lower of the component by a low temperature sputtering device having an electrode structure of a magnetron type to etch the end face, and then forming a metallized film at the heat resistance temperature or lower. CONSTITUTION:The end face of an electronic component 15 is reversely sputtered with reverse sputtering gas containing 30at% or oxygen at the heat resistance temperature or lower of the component 12 by means of a low temperature sputtering device having an electrode structure of a magnetron type to etch the end face, a metallized film is formed at the heat resistance temperature or lower of the component 15 to form an end face electrode. For example, a substrate holder 13 is mounted oppositely to a magnetron type cathode 12 in a vacuum bell-jar 11, a target 14 of an end face electrode material is mounted on the cathode 12, and the end face of the component 15 is mounted oppositely to the target 14 on the holder 13. The holder 13 is connected to a high frequency power source 16, the cathode 12 is connected to a DC power source 17, and the above sputtering is conducted.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は、電子部品、特に金属化フィルムコンデンサ、
セラミックコンデンサなどの小型チップ形電子部品の端
面電極形成方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to electronic components, in particular metallized film capacitors,
The present invention relates to a method for forming end face electrodes of small chip type electronic components such as ceramic capacitors.

従来の技術 一般に、コンデンサは誘電体層と対向電極層を交互に重
ね合わせた構造の素子端面に、対向電極各層の導電化を
目的とし、かつリード端との接続を目的として端面電極
を形成している。
Conventional technology In general, a capacitor has a structure in which dielectric layers and counter electrode layers are stacked alternately, and an end face electrode is formed on the end face of the element in order to make each of the counter electrode layers electrically conductive and to connect with the lead ends. ing.

一方、近年の電子部品の小形化要求が強くなるにつれ、
誘電体層の′R膜化とチップ化が急速に進められようと
している。
On the other hand, as the demand for miniaturization of electronic components has become stronger in recent years,
The conversion of dielectric layers to 'R' films and chips is rapidly progressing.

発明が解決しようとする課題 そこで、端面ta形成法として、従来の金属化フィルム
コンデンサではメタリコン(金属溶射法)が、またセラ
ミックコンデンサではAg/Pdの印刷焼成(デイツプ
)よたは、無電解メッキが限界にきつつある。つまり、
チップ形電子部品は第4図に示すように、シート状誘T
h体層1を対向電極層2を交互に重ねた後、スリット、
断裁などにより単体チップ化し、端面に電極を形成する
ため、端面Th極影形成面凸凹のないフラットな面にな
る。
Problems to be Solved by the Invention Therefore, as a method for forming the end surface TA, metallicon (metal spraying method) is used for conventional metallized film capacitors, and Ag/Pd printing and firing (dip) or electroless plating is used for ceramic capacitors. is reaching its limit. In other words,
As shown in Figure 4, chip-shaped electronic components are
After alternately stacking the h-body layers 1 and the counter electrode layers 2, slits,
Since it is made into a single chip by cutting etc. and electrodes are formed on the end face, the end face Th pole shadow forming surface becomes a flat surface with no unevenness.

したがって、メタリコンでは、その機械的付着メカニズ
ムの基本的欠陥として、くい込みがなく、付着強度の弱
い、電気特性の劣る電極となるという間コを有していた
。一方セラミックスコンデンサで用いられているP d
 / A gの印刷焼成でも全く同様の理由で、不充分
な電極となる上、Pdを添加しないとAgのマイグレー
ションが発生し、コスト上および品質上での問題も含ん
でいた。無電解メッキも前処理工程として一般に知られ
ているPdの置換処理を必要とし、複雑でコスト高にな
る上、品質の安定に問題があった。
Therefore, metallicon has a basic defect in its mechanical adhesion mechanism, which is that it does not penetrate, resulting in an electrode with weak adhesion strength and poor electrical properties. On the other hand, P d used in ceramic capacitors
/Ag printing/firing also resulted in an insufficient electrode for exactly the same reason, and if Pd was not added, migration of Ag occurred, which also included cost and quality problems. Electroless plating also requires a generally known Pd substitution process as a pretreatment process, which is complicated and costly, and there are problems with quality stability.

本発明は上記従来の問題を解決するもので、電気特性の
優れた品質安定上問題のない電子部品の端面電極形成方
法を提供することを目的とするしのである。
The present invention is intended to solve the above-mentioned conventional problems, and aims to provide a method for forming end-face electrodes of electronic components that have excellent electrical characteristics and are free from problems in terms of quality stability.

課題を解決するための手段 上記課題を解決するために本発明の電子部品の端面電極
形成方法は、電子部品の端面に、マグネトロン型にs′
If1m造を有する低温スパッタリング装置により、前
記電子部品の耐熱温度以下でかつ酸素を30at%以上
含む逆スパッタガスを使用した逆スパッタを施して、前
記端面をエツチングした後、前記電子部品の耐熱温度以
下で金属化被膜を施し端面電極を形成するものである。
Means for Solving the Problems In order to solve the above problems, the present invention provides a method for forming an end face electrode of an electronic component.
After etching the end face by performing reverse sputtering using a reverse sputtering gas that is below the heat-resistant temperature of the electronic component and containing 30 at% or more of oxygen, using a low-temperature sputtering device having an If1m structure, the end face is etched. Then, a metallized film is applied to form an end face electrode.

さらに、電子部品の端面に、マグネトロン型にt!#A
楕遣を有する低温スパッタリング装置により、電子部品
の耐熱温度以下でかつ逆スパッタを施して、前記端面を
エツチングした後、前記電子部品の耐熱温度以下でニッ
ケルを含む金属化被膜を施し端面電極を形成するもので
ある。
Furthermore, a magnetron-shaped t! #A
After etching the end face by performing reverse sputtering at a temperature below the heat resistant temperature of the electronic component using a low temperature sputtering device having an ellipse, a metallized film containing nickel is applied at a temperature below the heat resistant temperature of the electronic component to form an end face electrode. It is something to do.

さらに、ニッケルを含む金属化被膜の上に、半田付は性
を良くするために、ニッケルの無電解メッキを施して導
電層を形成し、または、鉛、錫などの半田合金およびそ
の構成金属の少なくとも1種を含む半田容易層としての
導電層を形成するものである。
Furthermore, in order to improve soldering properties, nickel is electrolessly plated to form a conductive layer on top of the nickel-containing metallized film, or solder alloys such as lead and tin and their constituent metals are applied. A conductive layer as an easy-to-solder layer containing at least one kind is formed.

作用 上記方法により、逆スパッタガス中に純Arに代えて、
酸素を添加していくと、電子部品の誘電体層の有機物、
たとえば、フィルム、セラミック用バインダがCO2と
して化学反応を起こし、Arだけのスパッタリング効果
を一層増長する。したがって、逆スパッタガス中の酸素
量が増すほど電子部品のtanδ(接触抵抗)が低下し
、電子部品の電気特性を向上させることができる。
Effect: By the above method, instead of pure Ar in the reverse sputtering gas,
As oxygen is added, organic matter in the dielectric layer of electronic components,
For example, binders for films and ceramics cause a chemical reaction as CO2, further increasing the sputtering effect of Ar alone. Therefore, as the amount of oxygen in the reverse sputtering gas increases, the tan δ (contact resistance) of the electronic component decreases, and the electrical characteristics of the electronic component can be improved.

さらに、電子部品の端面電極に、半田くわれが少なく耐
蝕性に潰れたニッケルを含む金属材料を用いることによ
り、電子部品の耐蝕性、耐候性を飛躍的に向上させ、そ
の寿命を延ばすことかてできる。
Furthermore, by using a metal material containing corrosion-resistant nickel for the end-face electrodes of electronic components, we can dramatically improve the corrosion resistance and weather resistance of electronic components and extend their lifespan. I can do it.

実施例 以下、本発明の一実施例について図面を参照しながら説
明する。
EXAMPLE Hereinafter, an example of the present invention will be described with reference to the drawings.

第1図は本発明の一実施例の電子部品の端面電極形成方
法を実施する装置の構成図である。第1図において、真
空ペルジャー11内に、マグネトロン型カソード12と
対向させてサブストホルダ13を設置し、このカソード
12上に端面電極材料のターゲット14を取付け、また
、サブストホルダ13上には電子部品15の端面電極を
形成すべき端面をターゲット14に対向させて取付け、
サブストホルダ13を高周波型′R16に接続し、カソ
ード12を直流電源17に接続する。また、真空ペルジ
ャー11は真空排気ポンプ18に連結され、ガス導入口
19.20を有している。
FIG. 1 is a block diagram of an apparatus for carrying out a method for forming end face electrodes of electronic components according to an embodiment of the present invention. In FIG. 1, a substrate holder 13 is installed in a vacuum pelger 11 facing a magnetron type cathode 12, a target 14 of an end electrode material is attached on the cathode 12, and an electronic component is placed on the substrate holder 13. Attach the end face on which the 15 end face electrodes are to be formed to face the target 14,
The substrate holder 13 is connected to a high frequency type 'R16, and the cathode 12 is connected to a DC power source 17. Further, the vacuum pelger 11 is connected to a vacuum evacuation pump 18 and has a gas inlet 19,20.

次に上記装置を用いた端面電極形成方法の一実施例を説
明する。
Next, an example of a method for forming end face electrodes using the above-mentioned apparatus will be described.

実施例1 真空ポンプ18によって、真空ペルジャー11内を2 
x 10’Torrにした後、ガス導入口19からAr
と02 を02が50at%になるよう混合した逆スパ
ッタガスを1 x 1O−1Torrで入れ、電子部品
15の耐熱温度以下で、かつ高周波電源16を用いて0
.5w/ ciのパワーで2分間逆スパッタエツチング
し、その後高周波電源16を切り、再度2 x 10’
Torrまで真空排気ポンプ18により真空引きした後
、ガス導入口20がArを3 x 10’Torrテ入
れ、電子部品15ノ素子端面にそれぞれNlの金属化被
膜を3μmずつ、電子部品15の耐熱温度以下で、かつ
直流電源17を用いて低温スパッタリングにより析出さ
せて端面電極を形成させた後、直流電源17を切り、常
圧に戻して電子部品15の素子を取出す。
Example 1 The inside of the vacuum pelger 11 is pumped by the vacuum pump 18.
x 10'Torr, then Ar from the gas inlet 19
A reverse sputtering gas containing 50 at% of 02 and 02 was introduced at 1 x 1 O-1 Torr, and the temperature was lower than the heat resistance temperature of the electronic component 15 and using the high-frequency power source 16.
.. Reverse sputter etching was performed for 2 minutes with a power of 5 W/ci, then the high frequency power supply 16 was turned off, and the 2 x 10'
After evacuation to Torr using the evacuation pump 18, the gas inlet 20 is filled with Ar to 3 x 10'Torr, and a 3 μm Nl metallized film is applied to each element end face of the electronic component 15 to meet the heat resistance temperature of the electronic component 15. Below, after depositing by low-temperature sputtering using the DC power source 17 to form an end face electrode, the DC power source 17 is turned off, the pressure is returned to normal pressure, and the element of the electronic component 15 is taken out.

このように、逆スパッタ時に純Arに変えて、0□ を
添加していくと、第2図に示すように、0□量が増すに
つれて電子部品15のtanδ(接触抵抗)が低下する
。これは、誘電体層の有機物(たとえば、フィルム、セ
ラミック用バインダ)がCO2として、化学反応を起こ
し、Arだけのスパッタリング効果をさらに増長するた
めと考えられる。さらに、端面電極の金属材料を検討し
た結果Cuよりも半田くわれが少なく耐蝕性に優れたN
1合金を見出した。つまり、半田くわれは、Agが最も
多いが、Cuも実験により3μ程度あることと判明した
。それに対し、N1は半田くわれがCuに比べて173
以下で膜厚が1μでも充分であることがわかった。さら
に、金属化波JIWとしてのN1にCr、Ti、Wを添
加すると、第3図に示すように、耐蝕性(耐候性すなわ
ち寿命)が良くなることも判明した。このように、電子
部品15の端面i8極としての金属化被膜は少なくとも
Nlを含み、その組成比が33at%以上のNi合金で
あることが必要である。
In this way, when 0□ is added instead of pure Ar during reverse sputtering, the tan δ (contact resistance) of the electronic component 15 decreases as the amount of 0□ increases, as shown in FIG. This is considered to be because the organic matter (eg, film, ceramic binder) in the dielectric layer causes a chemical reaction as CO2, further increasing the sputtering effect of Ar alone. Furthermore, after considering the metal material for the end electrodes, we found that N was superior in corrosion resistance with fewer solder cracks than Cu.
1 alloy was discovered. In other words, although the solder joints have the most Ag, it has been found through experiments that there is also about 3 μm of Cu. On the other hand, N1 has a solder joint of 173% compared to Cu.
It was found that a film thickness of 1 μm is sufficient as shown below. Furthermore, it has been found that when Cr, Ti, and W are added to N1 as the metallized wave JIW, the corrosion resistance (weather resistance, ie, life span) is improved, as shown in FIG. In this way, the metallized coating as the end face i8 pole of the electronic component 15 must contain at least Nl and be a Ni alloy with a composition ratio of 33 at % or more.

実施例2 実施例1と同様の手順で、逆スパッタエツチングして、
高周波電源16を切り、真空引きした後、Arを3 x
 10’Torrで入れ、電子部品15の素子端面にそ
れぞれN160%、T i 40%のき金の金属化被膜
を3μmずつ、低温スパッタリングにより析出させて端
面電極を形成させた後、直流電源17を切り、常圧に戻
して電子部品15の素子を取出す。
Example 2 Reverse sputter etching was performed in the same manner as in Example 1,
After turning off the high frequency power supply 16 and evacuation, apply 3x Ar
After depositing a metallized film of 3 μm each of 160% N and 40% Ti on the element end face of the electronic component 15 by low-temperature sputtering to form an end face electrode, the DC power source 17 is turned on. Then, the pressure is returned to normal and the element of the electronic component 15 is taken out.

実施例3 実施例1と同様の手順で、逆スパッタエツチングし、高
周波電源16を切り、真空引きした後、Arを2 X 
10’Torrで入れ、セラミックチップ型コンデンサ
の素子端面にそれぞれN185%/ Cr15%の合金
の金属化被膜をは2μmずつ低温スパッタリングにより
析出させて端面電極を形成させた後、直流電源17を切
り、常圧に戻して電子部品15の素子を取出し、次に、
これをバレル型メッキ治具に入れ、Ni/Pの!J!l
:電解メッキ浴に投入し、回転させながら10μmの皮
膜を析出させ、よく水洗の後、さらに、S n / P
 dの半田メッキを2.5μm析出させ、水洗の後、乾
燥させる。
Example 3 In the same manner as in Example 1, reverse sputter etching was performed, the high frequency power supply 16 was turned off, the vacuum was drawn, and then Ar was applied at 2×
A metallized film of 185% N/15% Cr was deposited on each end face of the element of the ceramic chip capacitor by low-temperature sputtering to form an end face electrode, and then the DC power supply 17 was turned off. Return to normal pressure, take out the element of the electronic component 15, and then
Put this into a barrel-shaped plating jig and use Ni/P! J! l
: Placed in an electrolytic plating bath, deposited a 10 μm film while rotating, washed thoroughly with water, and then S n / P
The solder plating of d is deposited to a thickness of 2.5 μm, washed with water, and then dried.

fif&に半田などのSn、Pb系の合金をコーティン
グしたものは、特に半田付は性が向上し、半田付は不良
に悩むユーザの期待に応えるものである。
A fif& coated with a Sn or Pb alloy such as solder has particularly improved soldering properties and meets the expectations of users who are troubled by soldering defects.

以上のように、逆スパッタガスに0□ガスを混入し、そ
の量が30at%以上で、逆スパッタエツチングした後
、低温スパッタにより端面tiを形成した電子部品はt
anδ(接触抵抗)の低減、つまり、素子の電気特性を
向上させることができる。
As described above, after performing reverse sputter etching by mixing 0□ gas into the reverse sputtering gas in an amount of 30 at% or more, an electronic component in which an end face ti is formed by low-temperature sputtering is produced.
It is possible to reduce an δ (contact resistance), that is, to improve the electrical characteristics of the element.

また、低温スパッタリングした端面電極にN1およびそ
の合金を用いると、耐蝕性、耐候性が向上し、寿命が延
びるとともに、外装レス化が期待できる。
In addition, when N1 and its alloys are used for low-temperature sputtered end electrodes, corrosion resistance and weather resistance are improved, the lifespan is extended, and it is expected that there will be no need for an exterior.

発明の効果 以・上のように本発明によれば、電子部品の端面に、マ
グネトロン型に電極構造を有する低温スパッタリング装
置により、電子部品の耐熱温度以下でかつ酸素を30a
t%以上含む逆スパッタガスを使用して逆スパッタを施
して端面をエツチングした後、電子部品の端面に、その
耐熱温度以下で金属化被膜を維して端面電極を形成する
ことにより電0子部品の電気特性を向上させることがで
き、特に接触抵抗を低下させることができる。
Effects of the Invention As described above, according to the present invention, oxygen is applied to the end face of an electronic component at a temperature below the heat-resistant temperature of the electronic component and at a temperature of 30 μm using a low-temperature sputtering device having a magnetron-type electrode structure.
After etching the end face by reverse sputtering using a reverse sputtering gas containing t% or more, a metallized film is maintained on the end face of the electronic component at a temperature below its heat resistant temperature to form an end face electrode. The electrical properties of the component can be improved, and in particular the contact resistance can be reduced.

また、端面な極としての金属化被膜に、Niを含む合金
を用いることにより、電子部品の耐蝕性、耐候性を飛躍
的に向上させ、その寿命を延ばすことができる。
Further, by using an alloy containing Ni for the metallized film serving as the end face electrode, the corrosion resistance and weather resistance of the electronic component can be dramatically improved, and the life of the electronic component can be extended.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、本発明の一実施例の電子部品の端面電極形成
方法を実施する装置の構成図、第2図は同電子部品の端
面電極形成方法における逆スパッタガスの酸素分圧と 
tanδ(接触抵抗)の電気特性を示すグラフ、第3図
は同電子部品の端面電極形成方法における端面ti材料
と耐候性を示す棒グラフ、第4図はチップ型コンデンサ
を作る工程における誘″eh木層と電極層の積み重ね状
態を示す図である。 11・・・真空ペルジャー、12・・・カソード、13
・・・サブストホルダ、14・・・ターゲット、15・
・・電子部品、16・・・高周波電源、17・・・直流
電源、18・・・真空排気ポンプ、19.20・・・ガ
ス導入口。 代理人   森  本  義  弘 第を図 第4図 【
FIG. 1 is a block diagram of an apparatus for carrying out a method for forming end surface electrodes of electronic components according to an embodiment of the present invention, and FIG. 2 shows the oxygen partial pressure of reverse sputtering gas in the method for forming end surface electrodes of electronic components.
A graph showing the electrical characteristics of tan δ (contact resistance), Fig. 3 is a bar graph showing the end face Ti material and weather resistance in the method of forming end face electrodes of the same electronic component, and Fig. 4 is a bar graph showing the weather resistance in the process of making chip-type capacitors. It is a diagram showing a stacked state of layers and electrode layers. 11... Vacuum Pelger, 12... Cathode, 13
...Subst holder, 14...Target, 15.
...Electronic components, 16..High frequency power supply, 17..DC power supply, 18..Vacuum pump, 19.20..Gas inlet. Figure 4: Agent Yoshihiro Morimoto

Claims (4)

【特許請求の範囲】[Claims] 1.電子部品の端面に、マグネトロン型に電極構造を有
する低温スパッタリング装置により、前記電子部品の耐
熱温度以下でかつ酸素を30at%以上含む逆スパッタ
ガスを使用した逆スパッタを施して、前記端面をエッチ
ングした後、前記電子部品の耐熱温度以下で金属化被膜
を施し端面電極を形成する電子部品の端面電極形成方法
1. The end surface of the electronic component was etched by performing reverse sputtering using a reverse sputtering gas that is below the heat-resistant temperature of the electronic component and containing 30 at% or more of oxygen using a low-temperature sputtering device having a magnetron-type electrode structure. A method for forming an end face electrode of an electronic component, wherein the end face electrode is formed by applying a metallized film at a temperature below the allowable temperature limit of the electronic component.
2.電子部品の端面に、マグネトロン型に電極構造を有
する低温スパッタリング装置により、電子部品の耐熱温
度以下でかつ逆スパッタを施して、前記端面をエッチン
グした後、前記電子部品の耐熱温度以下でニッケルを含
む金属化被膜を施し端面電極を形成する電子部品の端面
電極形成方法。
2. After etching the end face of the electronic component by performing reverse sputtering at a temperature below the heat-resistant temperature of the electronic component using a low-temperature sputtering device having a magnetron-type electrode structure, the end face is etched at a temperature below the heat-resistant temperature of the electronic component containing nickel. A method for forming an end face electrode of an electronic component by applying a metallized film to form an end face electrode.
3.端面電極としての金属化被膜の上に、ニッケルの無
電解メッキを施して導電層を形成した請求項2記載の電
子部品の端面電極形成方法。
3. 3. The method of forming an end face electrode of an electronic component according to claim 2, wherein the conductive layer is formed by electroless plating of nickel on the metallized film serving as the end face electrode.
4.端面電極としての金属化被膜の上に、鉛、錫などの
半田合金およびその構成金属の少なくとも1種を含む半
田容易層としての導電層を形成する請求項2記載の電子
部品の端面電極形成方法。
4. 3. The method for forming an end electrode of an electronic component according to claim 2, wherein a conductive layer as an easy-to-solder layer containing at least one of a solder alloy such as lead and tin and its constituent metal is formed on the metallized film as the end electrode. .
JP63013411A 1988-01-22 1988-01-22 Method for forming end face electrodes of electronic parts Expired - Lifetime JPH0787161B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63013411A JPH0787161B2 (en) 1988-01-22 1988-01-22 Method for forming end face electrodes of electronic parts

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63013411A JPH0787161B2 (en) 1988-01-22 1988-01-22 Method for forming end face electrodes of electronic parts

Publications (2)

Publication Number Publication Date
JPH01187912A true JPH01187912A (en) 1989-07-27
JPH0787161B2 JPH0787161B2 (en) 1995-09-20

Family

ID=11832393

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63013411A Expired - Lifetime JPH0787161B2 (en) 1988-01-22 1988-01-22 Method for forming end face electrodes of electronic parts

Country Status (1)

Country Link
JP (1) JPH0787161B2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06295644A (en) * 1993-04-08 1994-10-21 Nippon Steel Corp Vacuum arc treatment method and pre-treatment method
JP2000299514A (en) * 1999-04-15 2000-10-24 Murata Mfg Co Ltd Electronic component and manufacture thereof
JP2018067569A (en) * 2016-10-17 2018-04-26 太陽誘電株式会社 Ceramic electronic component and method of manufacturing the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06295644A (en) * 1993-04-08 1994-10-21 Nippon Steel Corp Vacuum arc treatment method and pre-treatment method
JP2000299514A (en) * 1999-04-15 2000-10-24 Murata Mfg Co Ltd Electronic component and manufacture thereof
JP2018067569A (en) * 2016-10-17 2018-04-26 太陽誘電株式会社 Ceramic electronic component and method of manufacturing the same

Also Published As

Publication number Publication date
JPH0787161B2 (en) 1995-09-20

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