JPH0118704B2 - - Google Patents

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Publication number
JPH0118704B2
JPH0118704B2 JP56171738A JP17173881A JPH0118704B2 JP H0118704 B2 JPH0118704 B2 JP H0118704B2 JP 56171738 A JP56171738 A JP 56171738A JP 17173881 A JP17173881 A JP 17173881A JP H0118704 B2 JPH0118704 B2 JP H0118704B2
Authority
JP
Japan
Prior art keywords
soybean
soybeans
odor
lipoxygenase
soybean odor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP56171738A
Other languages
Japanese (ja)
Other versions
JPS5871859A (en
Inventor
Shiro Kudo
Megumi Mukoyama
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahimatsu Foods Co Ltd
Original Assignee
Asahimatsu Foods Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahimatsu Foods Co Ltd filed Critical Asahimatsu Foods Co Ltd
Priority to JP56171738A priority Critical patent/JPS5871859A/en
Publication of JPS5871859A publication Critical patent/JPS5871859A/en
Publication of JPH0118704B2 publication Critical patent/JPH0118704B2/ja
Granted legal-status Critical Current

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Description

【発明の詳細な説明】 本発明は丸大豆(加工前の割れ豆や、脱皮大豆
も当然含まれる)を利用して、大豆加工食品を作
る場合大きな問題となる大豆臭の発生を防止する
方法に関するものである。
[Detailed Description of the Invention] The present invention is a method for preventing the occurrence of soybean odor, which is a major problem when making soybean processed foods using whole soybeans (which naturally includes unprocessed cracked soybeans and dehulled soybeans). It is related to.

一般に大豆は栄養的には非常にすぐれており、
また農産物原料として、特に蛋白質、脂肪が多
く、将来的に予想される食糧危機に備えて非常に
注目すべき原料の1つとして考えられている。
In general, soybeans are very nutritionally superior.
In addition, as an agricultural raw material, it is especially high in protein and fat, and is considered to be one of the raw materials that deserves attention in preparation for the food crisis expected in the future.

しかし加工方法によつては大豆臭が問題となつ
て現在でも大豆のもつ潜在的食品としての価値は
認められながらも充分活用されているとはいいが
たい。
However, depending on the processing method, soybean odor becomes a problem, and even though soybean's potential value as a food is recognized, it is difficult to say that it is fully utilized.

この大豆臭の問題については過去何十年の長き
にわたり、幾多の先人が、いろいろの角度から検
討を行い、これに関する提案も種々なされてい
る。
Over the past several decades, many predecessors have investigated the problem of soybean odor from various angles, and various proposals have been made regarding this problem.

そしてこれらの提案に係る方法を大きく分ける
と、大豆臭除去法に関するものと、大豆臭発生防
止に関するものとに大別出来る。前者は大豆臭は
もともと大豆にあるものである、あるいはその加
工上どうしても発生するからそれを除去しようと
する考え方であつたが、研究の進展と共に大豆臭
なるものの本体が明かにされ、後者の考え方へと
移り変つてきている。このように過去5〜10年の
大豆臭の問題についての進歩はかなり大きなもの
があり、同時に大豆の食品への高度利用も大きく
発展しつつつある。
The methods related to these proposals can be broadly divided into those related to soybean odor removal methods and those related to soybean odor prevention. The former idea was that soybean odor is originally present in soybeans, or that it inevitably occurs during soybean processing, and that it should be removed, but as research progressed, the true nature of soybean odor was revealed, and the latter idea was adopted. It is starting to change. As described above, considerable progress has been made in the past 5 to 10 years regarding the problem of soybean odor, and at the same time, the advanced use of soybeans in foods is making great progress.

現在は大豆臭をいかに未然に防ぐか、いかに発
生させないかが研究の中心であり、その発生の機
作などについても殆んど明らかにされている。即
ち大豆臭発生の主原因はリポキシゲナーゼにあ
り、このリポキシゲナーゼの性質、分布状態等に
ついてもかなりのところまで明らかにされてきた
現在では、大豆臭発生防止の唯一確実な方法とし
ては、このリポキシゲナーゼが大豆中の脂肪酸と
酸化反応を起し、大豆臭を発生させる前にいかに
して完全に失活させるかにあるとされている。こ
れに関しては一つの定石がある。即ち酵素は熱で
失活する。したがつて加熱すれば失活出来るはず
であるし、事実これは証明もされている。問題は
この加熱の仕方であり、出来れば大豆中の蛋白等
は出来るだけ変性させずにリポキシゲナーゼのみ
を失活させる事が理想である。
Currently, research is focused on how to prevent soybean odor from occurring or how to prevent it from occurring, and most of the mechanisms behind its occurrence have also been clarified. In other words, the main cause of soybean odor is lipoxygenase, and now that the properties and distribution of this lipoxygenase have been clarified to a great extent, the only sure way to prevent soybean odor is to use lipoxygenase to prevent soybean odor. The key is to completely deactivate the soybean before it undergoes an oxidation reaction with the fatty acids inside, producing a soybean odor. There is one standard regarding this. That is, the enzyme is inactivated by heat. Therefore, it should be possible to deactivate it by heating, and this has been proven. The problem is how to heat the soybean, and if possible, it would be ideal to deactivate only the lipoxygenase without denaturing the proteins in the soybean as much as possible.

現在行なわれているこのための主な方法として
は、大豆を蒸煮する、煮る、レンジにかける、熱
湯と共に粉砕する、PHとの関係を上記方法と組
合せる等である。しかしこれらの方法は大豆中蛋
白の変性の点で問題があり、そこで本発明者はこ
のリポキシゲナーゼの失活について種々の角度か
ら検討した結果以下に述べる方法が非常にすぐれ
ている事を見い出した。
The main methods currently used for this purpose include steaming soybeans, boiling them, microwaving them, grinding them with boiling water, and combining the above methods with respect to pH. However, these methods have a problem in terms of denaturation of the protein in soybeans, so the present inventor investigated the deactivation of lipoxygenase from various angles and found that the method described below is extremely superior.

このことを以下に述べると、まず大豆臭発生の
要因となるリポキシゲナーゼは80℃でほとんど瞬
時に失活するとされている。しかし大豆の細胞中
に存在しているリポキシゲナーゼをそのままの状
態で失活させるためには、大豆全体を80℃以上に
まで加熱する必要があり、リポキシゲナーゼは完
全に失活するものの、大豆蛋白の変性もかなり進
むことになつてしまう。したがつて、リポキシゲ
ナーゼの失活は充分行なうが、大豆蛋白の変性を
生ずることは出来るだけ押えるために、前記リポ
キシゲナーゼの失活に必要かつ十分の加熱を与え
ることが大豆臭発生防止法の方法として理想的と
言うことができるのである。
To explain this below, first of all, lipoxygenase, which is the cause of soybean odor, is said to be deactivated almost instantly at 80°C. However, in order to deactivate the lipoxygenase present in soybean cells, it is necessary to heat the whole soybean to a temperature of 80°C or higher. I ended up making quite a bit of progress. Therefore, while lipoxygenase is sufficiently inactivated, in order to suppress denaturation of soybean protein as much as possible, a method for preventing soybean odor is to apply heat necessary and sufficient to inactivate the lipoxygenase. It can be said that it is ideal.

ところで、本発明者は前述した大豆臭発生防止
法とは直接関係をもつものではないが、豆類等か
ら繊維状食品素材を得る製造法を特公昭56−9099
号公報、特開昭55−24号公報によつて提案してい
るが、本発明は思想的には全く異なるこの既提案
製造法に係る手法を利用するとにより好適な大豆
臭発生防止法を開発したものである。
By the way, although the present inventor is not directly related to the above-mentioned method for preventing the occurrence of soybean odor, the present inventor published a method for producing fibrous food materials from beans etc. in Japanese Patent Publication No. 56-9099.
However, the present invention has developed a more suitable method for preventing soybean odor by utilizing the method related to this already proposed production method, which is conceptually completely different. This is what I did.

即ち、既提案の製造方法は、要するに豆類等を
原料とし、その含有水分を30〜60重量%に調節
し、しかる後これをコロイドミルで磨砕して繊維
状にすることを特徴とする繊維状食品素材の製造
法を内容とするものであるが、本発明はあらかじ
め丸大豆にある程度の水分を含ませておいてか
ら、高速で回転する29枚の砥石版(石臼と同様な
機構)の小さな間隙を粉砕(磨砕)しながら通過
させるという前記手法において、回転数と関隙と
大豆中の水分によつて生ずる摩擦熱が異なつてく
るので、対象とする大豆により回転数と関隙を調
整することにより磨砕時の温度を80℃前後に保つ
ようにしたのである。この利点は粉砕と同時にリ
ポキシゲナーゼの失活が出来るので大豆臭の心配
が全くない事、粉砕よる摩擦熱を利用するので外
部から熱を与える必要がないこと、間隙1mm以下
望ましくは0から0.05mm位程度の間を通過させる
ために大豆は関隙を通過している状態は極めてう
すい皮膜状となつて通過していくために熱効率が
極めて良く、したがつて丸大豆から粉砕されてリ
ポキシゲナーゼが完全に失活するまで5秒以下で
終了してしまうため大豆蛋白の変性の影響を可及
的小ならしめることができる点にある。出てくる
粉砕物は80℃前後に加熱されているので対象とす
るものによつては、粉砕されて出てくると同時に
水の中に受け入れ急冷してリポキシゲナーゼは完
全に失活し、かつ他の蛋白類はほとんど変性を受
けないで無臭の大豆ペーストを得ることがでるよ
うにしてもよい。
In other words, the previously proposed production method essentially uses beans or the like as a raw material, adjusts the water content to 30 to 60% by weight, and then grinds it in a colloid mill to form fibers. The content of this invention is a method for manufacturing food materials, and the present invention involves soaking whole soybeans in advance with a certain amount of moisture, and then grinding them using 29 grinding stones (a mechanism similar to a stone mill) that rotates at high speed. In the above-mentioned method of passing through a small gap while crushing (grinding), the number of rotations, the gap, and the frictional heat generated by the moisture in the soybeans vary, so the rotation speed and gap may vary depending on the target soybean. By making adjustments, the temperature during grinding was maintained at around 80°C. The advantages of this method are that lipoxygenase can be deactivated at the same time as crushing, so there is no need to worry about soybean odor; frictional heat from crushing is used, so there is no need to apply external heat; and the gap is less than 1 mm, preferably between 0 and 0.05 mm. When soybeans pass through the barrier, they pass through the gap in the form of an extremely thin film, which has extremely high thermal efficiency. Since deactivation takes less than 5 seconds, the influence of denaturation of soybean protein can be minimized as much as possible. The crushed product that comes out is heated to around 80°C, so depending on the target, it may be placed in water as soon as it comes out and quickly cooled to completely deactivate the lipoxygenase, and other products. The proteins may be hardly denatured so that an odorless soybean paste can be obtained.

而して本発明の要旨は丸大豆を含水分30〜
60wt%の範囲に調整し、これを80℃以下の温度
に予備加熱し、又は予備加熱することなしに、相
対回転する対向砥石盤の微小間隙を通過させなが
ら、80℃前後の温度で粉砕処理することを特徴と
する大豆臭発生防止法にある。
Therefore, the gist of the present invention is to reduce the moisture content of whole soybeans from 30 to 30%.
It is adjusted to a range of 60wt% and is preheated to a temperature of 80℃ or less, or is crushed at a temperature of around 80℃ while passing through a minute gap between relatively rotating opposed grinding wheels without preheating. The method for preventing soybean odor is characterized by:

なお、発明者の実験よれば、丸大豆の含水分が
30〜60wt%望ましくは40〜55wt%位が最も熱効
率よく、リポキシゲナーゼを失活する事が出来る
事を知つた。水分が多くなると、その水をあたた
めるのに余分なエネルギーを必要とするし、粉砕
と同時に液状の状態となり間隙通過の時間も少な
く、砥石と大豆との摩擦係数も小さくなり、リポ
キシゲナーゼの失活がむづかしくなるからであ
る。また水分が少なすぎても熱伝導が悪くなり必
ずしも良い結果ではなかつた。また丸大豆をあら
かじめ生蒸気等で予備加熱しておき、同様に行な
つても良いが丸大豆で加熱が充分行なわれた場
合、一般に言われる大豆臭(beang flavour)と
は別の煮豆臭的なものが発生するので、予備加熱
する場合は実用上この点注意する必要がある。一
方乾物で予備加熱する場合も度が過ぎると、いわ
ゆる”きな粉”臭が発生するからこれも注意しな
ければならない。
According to the inventor's experiments, the moisture content of whole soybeans is
It has been found that 30 to 60 wt%, preferably 40 to 55 wt%, can deactivate lipoxygenase with the highest thermal efficiency. When the water content increases, extra energy is required to heat the water, and the soybean becomes liquid at the same time as it is crushed, reducing the amount of time it takes to pass through the gap.The coefficient of friction between the grinding wheel and the soybean also decreases, and the deactivation of lipoxygenase is reduced. This is because it becomes difficult. Also, if the moisture content was too low, heat conduction would be poor, and the results were not necessarily good. You can also pre-heat whole soybeans with live steam or the like and do the same thing, but if the whole soybeans are sufficiently heated, you will notice a boiled bean odor that is different from the generally known beang flavour. When preheating, it is necessary to be careful about this point in practice. On the other hand, when preheating dry foods, if the temperature is too high, a so-called "soybean flour" odor will occur, so care must be taken.

以下本発明の実施例つき説明するが、本発明は
これら実施例のものに限定される趣旨のものでな
いことは当然である。
The present invention will be described below with reference to examples, but it is obvious that the present invention is not limited to these examples.

実施例 1 10Kgの丸大豆を水で洗浄後水浸漬し、水分を約
50%した後水を切つた大豆をスーパーマイクロレ
フアイナー(増幸産業製)で回転数1500r.p.m、
関隙0.02mmで温度80℃前後に保ち粉砕して約17Kg
のかなり湿潤した粉状物を得た。これのリポキシ
ゲナーゼ活性を測定したところ完全に失活してい
た。同時に官能テストでも大豆臭は全く感じなか
つた。これに全固形分約18%位になる様に水、必
要に応じて油、多少の調味料を加えて強制分散機
にかけて、全粒利用の豆乳としたところ、おから
成分も完全に粉砕されているため口あたりもなめ
らかであり、くせのない豆乳が出来た。
Example 1 10Kg of whole soybeans were washed with water and soaked in water to remove moisture.
The soybeans, which had been reduced to 50% and drained, were heated at a rotation speed of 1500 r.pm using a Super Micro Refineer (manufactured by Masuko Sangyo).
Approximately 17Kg after being crushed by keeping the temperature around 80℃ with a gap of 0.02mm.
A fairly wet powder was obtained. When the lipoxygenase activity of this product was measured, it was found to be completely inactivated. At the same time, in a sensory test, there was no soybean odor at all. When we added water, oil if necessary, and some seasonings to this so that the total solid content was about 18%, and passed it through a forced dispersion machine to make soymilk using whole grains, the okara ingredients were completely crushed. Because of this, the soy milk has a smooth texture and no bitter taste.

実施例 2 10Kgの丸大豆を水で洗浄後水浸漬し水分を約50
%にした後、生蒸気(100℃常圧)で約20秒蒸煮
してから、ただちに実施例1と同様の条件で粉砕
した。粉砕したものをPH7.6のBuffer溶液に投入
し約3分boil後遠心分離して、おから成分を除
き、最終的にPH6.5前後全固形分約13%になる様
に調整し豆乳とした。必要に応じ多少の調味を行
つた。大豆臭は全くなく、くせのないすばらしい
豆乳となつた。またこの豆乳で常法により生大豆
腐を試作し、市販の物と比較したところ大豆臭の
差は90%以上の人が認めた。
Example 2 10Kg of whole soybeans were washed with water and soaked in water to reduce the water content to about 50%.
%, steamed with live steam (100° C. and normal pressure) for about 20 seconds, and immediately crushed under the same conditions as in Example 1. The pulverized material was poured into a buffer solution with a pH of 7.6, boiled for about 3 minutes, centrifuged, the okara components removed, and finally adjusted to a total solid content of about 13% around pH 6.5, and mixed with soy milk. did. Added some seasoning as needed. There was no soy odor at all, and the result was a wonderful soy milk with no bitterness. In addition, when we prototyped raw soybean curd using this soymilk using a conventional method and compared it with commercially available products, more than 90% of people recognized the difference in soybean odor.

実施例 3 実施例2と同様に予備加熱した大豆約17Kgを3
mmのダイスをつけたチヨツパーにて予備粉砕し
てから実施例1と同様の条件で粉砕し粉状の製品
を得た。これに水分約65%になる様に水を加え、
更に乾物あたり約60%になる様に砂糖を加え良く
混合し餡を作つたところ大豆が原料である事が全
く判断出来ない程くせのない製菓原料として充分
利用出来る大豆餡となつた。
Example 3 Approximately 17 kg of soybeans preheated in the same manner as in Example 2 were
The mixture was pre-pulverized using a chopper equipped with a mm die, and then crushed under the same conditions as in Example 1 to obtain a powdered product. Add water to this to make it about 65% moisture,
Furthermore, when we added sugar to a ratio of about 60% based on dry matter and mixed well to make a bean paste, we found that the soy bean paste was so smooth that it was impossible to tell that it was made from soybeans, and that it could be used as a confectionery raw material.

実施例 4 丸大豆5Kgを焙せん器等で予備乾燥をしてから
粗粉砕をしておく。この粗粉砕物に水分が約40%
になる様に添加しながら実施例1と同様の方法で
粉砕し、約8.5Kgの粉状物を得た。リポキシゲナ
ーゼの活性は完全に失われており、官能テストで
も大豆臭はほとんど認められなかつた。
Example 4 5 kg of whole soybeans are pre-dried using a roaster and then coarsely ground. This coarsely ground material has a moisture content of approximately 40%.
The powder was crushed in the same manner as in Example 1 while adding the powder so as to give about 8.5 kg of powder. The activity of lipoxygenase was completely lost, and almost no soybean odor was observed in the sensory test.

以上実施例の一部を説明したが、こうして得ら
れた大豆素材は大豆臭がない事、おから成分も完
全に微粉砕されているため、上記実施例のみなら
ず、たまごやきの増量剤、オムレツ、パン、うど
ん、植蛋として利用している各種食品の素材とし
て充分その機能特性も発揮出来るものであり、そ
の用途範囲はかなり広範なものである。
Some of the examples have been explained above, but since the soybean material obtained in this way has no soy odor and the okara component is completely finely ground, it can be used not only as a filler for egg rolls but also as a filler for egg rolls. It can fully exhibit its functional properties as a material for various foods such as omelets, bread, udon noodles, and vegetable eggs, and its range of uses is quite wide.

Claims (1)

【特許請求の範囲】[Claims] 1 丸大豆を含水分30〜60wt%の範囲に調整し、
これを80℃以下の温度に予備加熱し、又は予備加
熱することなしに、相対回転する対向砥石盤の微
小間隙を通過させながら80℃前後の温度で粉砕処
理することを特徴とする大豆臭発生防止法。
1 Adjust the moisture content of whole soybeans to a range of 30 to 60 wt%,
Soybean odor generation characterized by preheating to a temperature of 80°C or less, or grinding at a temperature of around 80°C while passing through a minute gap between relatively rotating opposed grinding wheels without preheating. Prevention method.
JP56171738A 1981-10-27 1981-10-27 Preventing method for generation of soybean smell Granted JPS5871859A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56171738A JPS5871859A (en) 1981-10-27 1981-10-27 Preventing method for generation of soybean smell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56171738A JPS5871859A (en) 1981-10-27 1981-10-27 Preventing method for generation of soybean smell

Publications (2)

Publication Number Publication Date
JPS5871859A JPS5871859A (en) 1983-04-28
JPH0118704B2 true JPH0118704B2 (en) 1989-04-06

Family

ID=15928761

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56171738A Granted JPS5871859A (en) 1981-10-27 1981-10-27 Preventing method for generation of soybean smell

Country Status (1)

Country Link
JP (1) JPS5871859A (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH657252A5 (en) * 1984-05-22 1986-08-29 Buehler Ag Geb METHOD FOR PRODUCING A SOY PRODUCT.
JP2544626B2 (en) * 1987-06-05 1996-10-16 太子食品工業株式会社 Soy food manufacturing method
US4943441A (en) * 1989-03-03 1990-07-24 Nestec S.A. Method of producing simulated meat product from whole soybeans
WO2006109404A1 (en) * 2005-04-07 2006-10-19 Isobe, Junsho Process for preparation of plant tissues of processed beans, grains, nuts/seeds, vegetables or fruits, plant tissues of processed beans, grains, nuts/seeds, vegetables or fruits, and processed food prepared using the plant tissues
JP6716622B2 (en) * 2018-03-19 2020-07-01 フジッコ株式会社 Process for manufacturing processed beans

Also Published As

Publication number Publication date
JPS5871859A (en) 1983-04-28

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