JP6716622B2 - Process for manufacturing processed beans - Google Patents

Process for manufacturing processed beans Download PDF

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JP6716622B2
JP6716622B2 JP2018050904A JP2018050904A JP6716622B2 JP 6716622 B2 JP6716622 B2 JP 6716622B2 JP 2018050904 A JP2018050904 A JP 2018050904A JP 2018050904 A JP2018050904 A JP 2018050904A JP 6716622 B2 JP6716622 B2 JP 6716622B2
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soybeans
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JP2019162052A (en
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達也 小室
達也 小室
達美 小林
達美 小林
渉 稲熊
渉 稲熊
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Fujicco Co Ltd
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Description

本発明は、大豆等の豆類を用いた水煮、蒸し豆、煮豆、煎り豆などの豆類加工食品の風味向上を目的とする製造方法に関する。 The present invention relates to a production method for improving the flavor of processed beans products such as boiled, steamed beans, boiled beans and roasted beans using beans such as soybeans.

豆類は栄養価の高い食品素材であり、たんぱく質、必須アミノ酸を豊富に含み、ビタミンB群、カルシウムなどのミネラル類も多く含んでいる。さらに豆類には、食物繊維、サポニン、ポリフェノール等の機能性成分が多く含まれており、これらの成分が及ぼす健康効果が明らかにされている。 Beans are a highly nutritious food material, which is rich in proteins and essential amino acids, and also contains a lot of minerals such as vitamin B group and calcium. Furthermore, beans contain a large amount of functional components such as dietary fiber, saponin, and polyphenol, and the health effects of these components have been clarified.

一方、豆類に含まれるサポニンやポリフェノール等は有用な機能性成分である反面、味覚に関しては、渋みや苦味、えぐみなどの不快味成分の原因物質であることも知られており、従来から煮豆を製造する場合には、豆を一晩水浸漬した後、水浸漬後の豆を水煮することにより、これらの不快味成分を除去している。 On the other hand, while saponins and polyphenols contained in beans are useful functional ingredients, on the other hand, regarding taste, it is also known to be a causative substance of unpleasant taste ingredients such as astringency, bitterness, and acridness. In the case of producing, the unpleasant taste components are removed by soaking the beans overnight in water and then boiling the beans after soaking in water.

例えば、レトルトパウチ入りの大豆水煮を製造する場合には、一晩水浸漬した大豆を沸騰水中に入れて、20分〜60分程度の水煮処理を行うことで不快味成分を取り除き、水煮処理された大豆をレトルトパウチに充填密封した後、レトルト殺菌処理をして製造している。そのため水煮処理を経て製造された豆類加工食品は、不快味成分が十分に取り除かれているものの、同時に大豆に含まれる糖質やアミノ酸等の好ましい呈味成分も流出してしまい、豆類が本来有する甘味や旨味等の美味しさを味わうことができないという問題があった。 For example, in the case of producing boiled soybeans containing retort pouches, soybeans soaked in water overnight are put into boiling water, and unpleasant taste components are removed by performing a boiling treatment for about 20 to 60 minutes, The boiled soybean is filled in a retort pouch, sealed, and then retort sterilized to produce it. Therefore, in the processed beans produced through the boiled treatment, unpleasant taste components are sufficiently removed, but at the same time, preferred taste components such as sugars and amino acids contained in soybeans also flow out, and beans are originally There is a problem that the deliciousness such as the sweetness and umami possessed cannot be enjoyed.

従来、豆類の不快味成分を低減する手段については、豆乳および豆腐の製造における大豆の不快味成分を低減させる方法として、大豆の水戻し条件について検討されている。非特許文献1、2では、大豆の水戻し方法を60℃で2時間浸漬することにより、大豆の膨潤時間を短縮すると同時に不快味および不快臭を低減できることが記載されている。また、特許文献1では、脱皮大豆を40〜50℃の温水に1〜3時間浸漬処理することにより、青豆臭や喉頭刺激臭が少ない風味の優れた豆乳を得ることができることが記載されている。しかしながら、上記方法についても、大豆の不快味や青豆臭を低減することができるが、好ましい呈味成分については流出を抑制することができず、双方の課題を両立させることは困難であった。 Conventionally, as a means for reducing unpleasant taste components of beans, soybean milk and tofu production, soybean unpleasant taste components have been studied as a method of reconstitution with water. Non-Patent Documents 1 and 2 describe that by soaking the soybean in water for 2 hours at 60° C., the swelling time of the soybean can be shortened, and at the same time, the unpleasant taste and unpleasant odor can be reduced. Further, in Patent Document 1, it is described that by soaking the dehulled soybean in hot water at 40 to 50° C. for 1 to 3 hours, soybean milk with excellent flavor with little green soybean odor and throat irritation odor can be obtained. .. However, even with the above method, the unpleasant taste of soybean and the smell of green soybean can be reduced, but the outflow of the preferable taste component cannot be suppressed, and it is difficult to satisfy both problems.

また、特許文献2では、本願出願人により、豆類加工食品の製法において水煮工程を省き、水煮工程に替えて昇圧工程、蒸煮工程または降圧工程の少なくとも一つの工程において豆類を水洗浄処理することにより、豆類独特の風味や味の呈味成分を損なわせない製法が提案されている。しかしながら、上記方法により大量生産する場合には大型の加圧蒸煮釜が複数必要になり、設備投資コスト面で問題があった。 Further, in Patent Document 2, the applicant of the present application omits the boiling step in the method for producing a processed bean food product, and instead of the boiling step, the beans are washed with water in at least one step of a pressurizing step, a steaming step or a step-down step. As a result, a manufacturing method has been proposed that does not impair the flavor and taste components peculiar to beans. However, in the case of mass production by the above method, a plurality of large-sized pressure steaming pots are required, which is a problem in terms of equipment investment cost.

特開昭61−139354号公報Japanese Patent Laid-Open No. 61-139354 特開平10−295313号公報JP, 10-295313, A

日本食品工業学会誌 第35巻 第12号 p866−874(1988)Journal of the Japan Food Industry Society Vol. 35, No. 12, p866-874 (1988) 日本食品工業学会誌 第38巻 第9号 p770−775(1991)Journal of the Japan Food Industry Society Vol. 38, No. 9, p770-775 (1991)

本発明は、豆類が有する渋みや苦味、えぐみなどの不快味成分を減少させ、且つ、豆類が有する甘味や旨味等の好ましい呈味成分が保持された豆類加工食品の製造方法を提供することを目的とする。 The present invention provides a method for producing a processed food product of beans, which reduces unpleasant taste components such as astringency, bitterness and acridness of beans, and retains preferable taste components such as sweetness and umami of beans. With the goal.

本発明者らは、前記課題を解決すべく鋭意研究を重ねた結果、生豆の豆類を短時間で温水浸漬処理することによって、好ましい呈味成分が保持され、且つ、不快味成分が低減されることを見出し、本発明を完成するに至った。 As a result of intensive studies to solve the above-mentioned problems, the present inventors carried out a process of soaking raw beans in hot water for a short time, thereby retaining a preferable taste component and reducing an unpleasant taste component. It was found that the present invention has been completed.

すなわち、本発明は、以下の発明からなるものである。
[1]工程(a):生豆の豆類を、直ちに50℃以上65℃未満の温水に5〜20分間、温水浸漬処理する工程、
工程(c):30℃以下で水浸漬処理する工程、
工程(b):加熱処理する工程、を順に且つ連続して含み
(但し、生豆を前記温水浸漬処理する工程と、前記加熱処理する工程との間に磨砕処理する工程を含むことを除く。)
前記加熱処理が、焙煎処理、または、工程(c)で水浸漬処理された豆類を容器に充填密封した後、加熱殺菌処理することを特徴とする、豆類加工食品の製造方法に関する。
That is, the present invention comprises the following inventions.
[1] Step (a): Immersing raw beans directly in hot water at 50 ° C. or higher and lower than 65° C. for 5 to 20 minutes,
Step (c): a step of subjecting to water immersion treatment at 30° C. or lower,
Step (b): including a step of heat treatment, sequentially and continuously ,
(However, it does not include a step of grinding treatment between the step of soaking the green beans in the warm water and the step of the heat treatment.)
The above-mentioned heat treatment relates to a method for producing a processed bean food, characterized in that the beans are roasted or filled with water in the step (c) and sealed in a container, and then heat-sterilized .

本発明の方法によれば、豆類が有する不快味成分が減少され、且つ、豆類が有する好ましい呈味成分が保持された風味良好な豆類加工食品が得られる。 According to the method of the present invention, a processed food product of beans having a good taste in which the unpleasant taste components of beans are reduced and the preferable taste components of beans are retained can be obtained.

また、煮豆や水煮豆等の製造方法においては、従来製法では、通常は水煮処理によって豆類の不快味成分の除去および豆類に含まれるでん粉のα化ならびに種皮やタンパク質の軟化を同時に行うところ、本発明においては、不快味成分の除去は短時間の温水浸漬処理で行い、でん粉のα化ならびに種皮等の軟化はレトルト殺菌処理等の最終工程の加熱処理で調整するため、水煮工程を省略することができる。そのため、温水浸漬処理は水煮処理と比べて処理水を加温するために必要な熱エネルギーコストを大幅に削減し、製造時間の短縮化も図ることができる。 Further, in the method for producing boiled beans, boiled beans, etc., in the conventional production method, removal of unpleasant taste components of beans and gelatinization of starch contained in beans and softening of seed coat and protein are usually carried out at the same time, In the present invention, the removal of unpleasant taste components is carried out by a short-time hot water immersion treatment, and the gelatinization of starch and the softening of seed coat etc. are adjusted by the heat treatment of the final step such as retort sterilization treatment, so that the boiling step is omitted. can do. Therefore, the hot water immersion treatment can significantly reduce the heat energy cost required for heating the treated water and shorten the manufacturing time, as compared with the boiling treatment.

さらに、本発明においては、低温で短時間の温水浸漬処理よって、豆類からの糖類等の溶出が減少するため、浸漬処理水に含まれる有機物も少なくなり、工場で製造する際の排水処理負荷を低減することができる。本発明による製造方法は、豆類加工食品の風味の向上を図るだけでなく、製造コスト面および環境面からも優れている。 Furthermore, in the present invention, by the hot water immersion treatment at a low temperature for a short time, the elution of sugars and the like from beans is reduced, so that the organic matter contained in the immersion treatment water is reduced, and the wastewater treatment load at the time of manufacturing in the factory is reduced. It can be reduced. The manufacturing method according to the present invention not only improves the flavor of processed beans, but is also excellent in manufacturing cost and environment.

以下、本発明を実施するための形態について説明する。本発明は、以下の記載に限定されない。 Hereinafter, modes for carrying out the present invention will be described. The present invention is not limited to the description below.

本発明においては、乾燥した生豆を原料に用いる。原料の生豆は、脱皮処理されていてもよいが、収穫後に加熱等の加工処理されたもの、例えば加熱により熱変性や酵素失活したもの、圧編、破砕および粉砕等で組織破壊されたものは除かれる。加熱変性したもの、組織破壊されたものは、浸漬処理時に糖質などの好ましい呈味成分を保持できないため使用できない。 In the present invention, dried green beans are used as a raw material. Raw beans, which are the raw material, may be dehulled, but those that have been processed such as by heating after harvesting, for example, those that have undergone heat denaturation or enzyme deactivation by heating, tissue destruction by pressure knitting, crushing, crushing, etc. Things are excluded. Those that have been heat-denatured and those whose tissue has been destroyed cannot be used because they cannot retain desirable taste components such as sugar during immersion treatment.

本発明における原料としては、豆類であれば特に限定されない。例えば、豆類は、脂質とたんぱく質を主体とするグループと、炭水化物を主体とするグループの二つのグループに大別することができ、本発明においては、いずれのグループの豆類であっても適応することができる。前述グループの豆類は、大豆および落花生であり、大豆系の豆類であれば黄大豆、黒大豆、青大豆、赤大豆、茶豆、鞍掛け豆でもよい。後述グループの豆類は、インゲン系の豆類であり、金時豆、白金時豆、虎豆、うずら豆、白花豆、紫花豆、ひよこ豆、えんどう豆、空豆、小豆、ささげ豆、レンズ豆でもよい。 The raw material in the present invention is not particularly limited as long as it is a legume. For example, beans can be roughly classified into two groups, a group mainly composed of lipids and proteins and a group mainly composed of carbohydrates. In the present invention, beans of any group are applicable. You can Beans in the above group are soybeans and peanuts, and soybean-based beans may be yellow soybeans, black soybeans, green soybeans, red soybeans, tea beans, and saddle beans. Beans in the group described below are kidney beans, and they are Kintoki beans, Shirogane beans, tiger beans, quail beans, white beans, purple beans, chickpeas, peas, beans, adzuki beans, red beans, and lentils. Good.

〔工程(a)〕
本発明の方法においては、まず、生豆の豆類を温水浸漬処理する。該温水浸漬処理は、豆類に含まれる好ましい呈味成分の溶出を抑えつつ、不快味成分を温水中に溶出させて除去することを目的とする。
[Step (a)]
In the method of the present invention, first, raw beans are soaked in warm water. The warm water immersion treatment is intended to elute and remove unpleasant taste components in warm water while suppressing elution of preferable taste components contained in beans.

該温水浸漬処理の条件は、50〜70℃に加温した温水に5〜20分間浸漬することが好ましく、より好ましくは50〜65℃で10〜20分間浸漬することが好ましく、さらに好ましくは50〜55℃で10分間浸漬することが好ましい。 The conditions of the hot water immersion treatment are preferably immersion in warm water heated to 50 to 70° C. for 5 to 20 minutes, more preferably immersion at 50 to 65° C. for 10 to 20 minutes, and further preferably 50. It is preferred to soak for 10 minutes at ˜55° C.

なお、該温水浸漬処理において、処理温度が50℃未満である場合には、豆類に含まれるイソフラボノイドやサポニン等の不快味成分の溶出効率が悪く、不快味成分が除去することができない。また、処理時間が5分未満である場合にも、不快味成分の除去が不十分となり好ましくない。 In the hot water immersion treatment, when the treatment temperature is lower than 50° C., the unpleasant taste components such as isoflavonoids and saponins contained in beans are not efficiently eluted, and the unpleasant taste components cannot be removed. Further, even when the treatment time is less than 5 minutes, the unpleasant taste components are not sufficiently removed, which is not preferable.

一方、該温水浸漬処理が50℃以上であって処理時間が20分間を超える場合には、不快味成分だけでなく、糖質などの好ましい呈味成分も溶出されてしまうため好ましくない。 On the other hand, when the hot water immersion treatment is performed at 50° C. or higher and the treatment time exceeds 20 minutes, not only unpleasant taste components but also preferable taste components such as sugar are eluted, which is not preferable.

また、該温水浸漬処理は複数回行ってもよい。該温水浸漬処理を複数回行うことにより、豆類に含まれる不快味成分の溶出が促進され、不快味成分の除去が効率的に行われるため、特に不快味成分を多く含む原料豆を用いる場合には、該温水浸漬処理を複数回行うことが好ましい。例えば、該温水浸漬処理は、55℃で5分の温水浸漬処理を2〜4回、積算で20分間行ってもよい。 Further, the hot water immersion treatment may be performed plural times. By performing the hot water immersion treatment a plurality of times, elution of the unpleasant taste component contained in the beans is promoted, and the unpleasant taste component is efficiently removed. Therefore, particularly when using raw material beans containing a large amount of the unpleasant taste component It is preferable to perform the hot water immersion treatment a plurality of times. For example, the hot water immersion treatment may be performed by performing hot water immersion treatment at 55° C. for 5 minutes 2 to 4 times for a total of 20 minutes.

なお、該温水浸漬処理の積算時間が20分間を超える場合には、呈味成分の溶出を抑制できないため、目的の風味良好な豆類加工食品が得らない。 In addition, when the cumulative time of the hot water immersion treatment exceeds 20 minutes, elution of the taste component cannot be suppressed, and thus the desired processed bean food product having a good flavor cannot be obtained.

一方、不快味成分の含量が少ない原料豆を用いる場合には、該温水浸漬処理を複数回行う必要はなく、好ましい呈味成分の流出を抑えるために、該温水浸漬処理の回数は1回で行うことが好ましい。 On the other hand, when using raw material beans with a low content of unpleasant taste components, it is not necessary to carry out the hot water immersion treatment a plurality of times, and in order to suppress the outflow of the preferable taste components, the hot water immersion treatment is performed once. It is preferable to carry out.

該温水浸漬処理においては、生豆と温水量の比率は特に限定されず、豆類が温水中に浸かっていればよく、好ましくは生豆の豆類1重量部に対して温水量は1重量部以上、より好ましくは温水量は5重量部以上、さらに好ましくは温水量は10重量部以上とすることが好ましい。温水量が少ない場合には不快味成分の溶出が効率的に行われないため、温水量は多い方が不快味成分が効率的に溶出されるため好ましい。 In the hot water immersion treatment, the ratio of green beans to the amount of hot water is not particularly limited, as long as the beans are soaked in warm water, preferably 1 part by weight or more of hot water is 1 part by weight or more of hot water. More preferably, the amount of hot water is 5 parts by weight or more, and further preferably, the amount of hot water is 10 parts by weight or more. When the amount of hot water is small, the unpleasant taste component is not efficiently eluted. Therefore, the amount of hot water is preferably large because the unpleasant taste component is efficiently eluted.

また、該温水浸漬処理に用いる温水中には、不快味成分を効率的に除去するために、アルコールおよび片栗粉などの澱粉を添加してもよい。 In addition, starch such as alcohol and potato starch may be added to the hot water used for the hot water immersion treatment in order to efficiently remove unpleasant taste components.

また、該温水浸漬処理の方法は、生豆の豆類が至適温度の温水中に常時浸かった状態が維持できればその方法は特に限定されず、バッチ槽内での静水下または流水下での静置浸漬または撹拌浸漬でもよく、流水移送管内での流動浸漬でもよい。 Further, the method of the hot water immersion treatment is not particularly limited as long as it can maintain the state that the beans of raw beans are constantly immersed in hot water of the optimum temperature, and the method is not limited to still water in a batch tank or under running water. It may be stationary immersion, stirring immersion, or fluidized immersion in a flowing water transfer pipe.

〔工程(b)〕
上記工程(a)により、該温水浸漬処理された豆類を、加熱処理する。該温水浸漬処理された豆類は、そのままでは食することができず、保存性がないため、該加熱処理によってでん粉をα化し、保存性を付与し食せる状態に加工することを目的とする。該加熱処理によって、不快味成分が抑制された水分含量の低い豆類加工食品を得ることができる。
[Step (b)]
In the step (a), the beans subjected to the hot water immersion treatment are heat treated. The beans soaked in hot water cannot be eaten as they are and have no preservability. Therefore, the purpose of the present invention is to convert starch into α by the heat treatment and impart preservability to the ready-to-eat state. By the heat treatment, it is possible to obtain a processed bean food product having a low water content in which unpleasant taste components are suppressed.

該加熱処理の方法は、焙煎処理または焼成処理を用いることができるが特に限定されず、その加熱条件についても、目的とする豆類加工食品に適した温度および時間で行えばよく、特に限定されない。 The method of the heat treatment may be roasting treatment or baking treatment, but is not particularly limited, and its heating condition is not particularly limited as long as it is carried out at a temperature and time suitable for the target processed bean food. ..

該加熱処理により得られる水分含量の低い豆類加工食品には、煎り豆、煎り豆茶、打ち豆等が挙げられる。例えば、煎り豆、煎り豆茶を目的とする場合には、該温水浸漬処理された豆を150〜180℃で10〜30分間焙煎処理すればよく、打ち豆を目的とする場合には、該温水浸漬処理された豆を押圧扁平した後、焙煎処理または焼成処理して乾燥させればよい。 Examples of the processed bean food having a low water content obtained by the heat treatment include roasted beans, roasted bean tea, and peas. For example, when aiming at roasted beans or roasted soybean tea, the beans soaked in hot water may be roasted at 150 to 180° C. for 10 to 30 minutes. The beans soaked in hot water may be pressed and flattened, then roasted or baked and dried.

〔工程(a)、工程(c)、工程(b)を順に含む方法〕
上記工程(a)により、該温水浸漬処理された豆類を、水浸漬処理(工程(c))する。該水浸漬処理は、豆類を後工程で加熱処理したときにでん粉をα化および種皮、タンパク質を軟化しやすくするために豆類に水分を十分に吸収、膨潤させて、且つ、豆類に含まれる糖質等の好ましい呈味成分の流出を抑制させることを目的とする。
[Method that sequentially includes step (a), step (c), and step (b)]
The beans subjected to the hot water immersion treatment in the step (a) are subjected to a water immersion treatment (step (c)). The water-immersion treatment allows the beans to sufficiently absorb and swell moisture in order to easily gelatinize the starch and soften the seed coat and protein when the beans are heat-treated in the subsequent step, and the sugar contained in the beans. The purpose is to suppress the outflow of preferable taste components such as quality.

〔工程(c)〕
該水浸漬処理は、水温0〜30℃で5〜48時間、好ましくは水温5〜25℃で6〜36時間、より好ましくは水温10〜20℃で10〜24時間、水浸漬処理することが好ましい。
[Step (c)]
The water immersion treatment may be performed at a water temperature of 0 to 30°C for 5 to 48 hours, preferably at a water temperature of 5 to 25°C for 6 to 36 hours, and more preferably at a water temperature of 10 to 20°C for 10 to 24 hours. preferable.

該水浸漬処理においては、水温が30℃を超えるような場合には、豆類に含まれるショ糖などの好ましい呈味成分の浸漬水中への溶出が始まり、また、微生物が増殖し腐敗しやすくなり、発芽も促進される条件となるため、本発明が目的とする豆類加工食品が得られず好ましくない。 In the water immersion treatment, when the water temperature is higher than 30° C., preferable taste components such as sucrose contained in beans start to elute into the immersion water, and the microorganisms easily proliferate and decompose. However, since the conditions are such that germination is also promoted, the processed bean food intended by the present invention cannot be obtained, which is not preferable.

一方、水温が0℃に近い低温またはこれを下回るような場合には、豆類の水分吸収が遅くなり膨潤が不十分になり、水浸漬する時間も長くなり生産性が悪くなるため、該水浸漬処理条件は、豆類が水分吸収し速やかに膨潤が進み、且つ、微生物による腐敗が生じ難い温度である10〜20℃で行うことが好ましい。 On the other hand, when the water temperature is low temperature close to 0°C or lower, the water absorption of beans becomes slow, the swelling becomes insufficient, the time of water immersion becomes long, and the productivity deteriorates. The treatment conditions are preferably 10 to 20° C., which is a temperature at which beans absorb water and rapidly swell, and microorganisms do not easily spoil.

また、該水浸漬処理における豆類と浸漬水の比率は特に限定されず、豆類が十分に給水、膨潤できればよく、豆類を1とした場合は、浸漬水は2〜10倍量以上とすることが経済的理由から好ましい。 Further, the ratio of beans to immersion water in the water immersion treatment is not particularly limited as long as the beans can be sufficiently supplied with water and swell. When the beans are 1, the amount of immersion water is 2 to 10 times or more. Preferred for economic reasons.

また、生豆の豆類の水分吸水量の目安は、豆類の種類によって異なるが、生豆の豆類の重量を100%とした場合、おおよそ180〜240%程度であり、それぞれの豆類における最大吸水率を100%とした場合、各豆類の吸水率が90%以上、好ましくは95%以上となるように該水浸漬処理の温度と時間を調整する。なお、目的とする豆類加工食品が蒸し豆や煮豆である場合には、吸水率が90%より低い場合には、後工程の加熱処理または加圧加熱処理をした場合であっても、食した際に芯が残る場合があり、製品歩留りも低下するため好ましくない。 In addition, the standard of the water absorption amount of beans of green beans varies depending on the type of beans, but when the weight of beans of green beans is 100%, it is about 180 to 240%, and the maximum water absorption rate of each beans. Is 100%, the temperature and time of the water immersion treatment are adjusted so that the water absorption of each legume is 90% or more, preferably 95% or more. In addition, when the target processed beans product is steamed beans or boiled beans, if the water absorption rate is lower than 90%, it is eaten even if it is subjected to a heat treatment or a pressure heat treatment in a subsequent step. At that time, the core may remain, which lowers the product yield, which is not preferable.

また、該水浸漬処理に用いる浸漬水おいては、味付けを目的として、糖類や食塩等の調味料を添加してもよい。 In the immersion water used for the water immersion treatment, seasonings such as sugar and salt may be added for the purpose of seasoning.

〔工程(b)〕
上記工程(c)により、該水浸漬処理された豆類を、加熱処理(工程(b))する。該水浸漬処理された豆類は、豆類に含まれるレクチンやリポキシゲナーゼ等の酵素が失活しておらず、そのままでは食することができないため、該加熱処理によって豆類に含まれる酵素を失活させることと同時に、でん粉のα化ならびに種皮等の軟化、調味調理、加熱殺菌を行い、該水浸漬処理された豆類を食せる状態に加工することを目的とする。
[Step (b)]
By the step (c), the beans soaked in water are heat-treated (step (b)). In the beans subjected to the water immersion treatment, enzymes such as lectins and lipoxygenase contained in the beans are not inactivated and cannot be eaten as they are. Therefore, the enzymes contained in the beans are inactivated by the heat treatment. At the same time, the purpose of the present invention is to gelatinize starch and soften seed coat, seasoning cooking, and heat sterilization to process the water-immersed beans into a edible state.

該加熱処理の方法は、蒸煮処理、加圧加熱処理、焙煎処理、焼成処理、油調加熱処理、包装後の加熱処理のいずれでもよく、特に限定されないが、目的とする豆類加工食品に応じて適宜選択すればよい。また、その加熱条件についても、目的とする豆類加工食品に適した温度および時間で行えばよく、特に限定されない。 The method of the heat treatment may be any of steaming treatment, pressure heat treatment, roasting treatment, baking treatment, oil-conditioning heat treatment, heat treatment after packaging, and is not particularly limited, but depending on the intended processed legume food. It may be selected as appropriate. Also, the heating condition is not particularly limited as long as it is performed at a temperature and a time suitable for the target processed bean food.

例えば、該水浸漬処理された豆類を加水せずにそのまま加熱する場合には、蒸煮処理、加圧加熱処理、焙煎処理、焼成処理、油調加熱処理のいずれでもよく、これにより得られる豆類加工食品は、蒸煮処理を経て得られる蒸し豆、加圧加熱処理を経て得られる蒸し豆、焙煎処理を経て得られる煎り豆、焼成処理を経て得られる焼き豆、油調加熱処理を経て得られる揚げ豆などが挙げられる。 For example, when the beans soaked in water are heated as they are without adding water, any of steaming treatment, pressure heating treatment, roasting treatment, baking treatment, and oil-conditioning heating treatment may be carried out. Processed foods are steamed beans obtained through steaming treatment, steamed beans obtained through pressure heating treatment, roasted beans obtained through roasting treatment, roasted beans obtained through baking treatment, oil-like heat treatment obtained Examples include fried beans.

また、該水浸漬処理された豆類を加水して加熱する場合には、該水浸漬処理された豆類と水または調味液とを容器に密封した後に該加熱処理をすることにより、該水浸漬処理された豆類に含まれる好ましい呈味成分の流出を防ぐことができる。これにより得られる豆類加工食品は、包装後の加熱処理を経て得られるパウチ入りの水煮豆や煮豆、加圧加熱処理を経て得られるレトルトパウチ入りの水煮豆や煮豆などが挙げられる。 Further, when the beans subjected to the water immersion treatment are heated and heated, the beans subjected to the water immersion treatment and water or a seasoning liquid are sealed in a container and then subjected to the heat treatment, whereby the water immersion treatment is carried out. It is possible to prevent the outflow of preferable taste components contained in the soybeans. Examples of the processed bean food thus obtained include boiled beans and boiled beans containing a pouch obtained by a heat treatment after packaging, and boiled beans and boiled beans containing a retort pouch obtained by a pressure heating treatment.

かくして、本発明の方法によって、豆類が有する不快味成分が除去され、好ましい呈味成分が保持されているため、本発明の方法により得られた豆類加工食品は、苦味や渋み等の不快味がなく、豆類が本来有する甘味や旨味を味わうことができる。 Thus, by the method of the present invention, the unpleasant taste component that the beans have is removed, and since the preferable taste component is retained, the processed beans product obtained by the method of the present invention has an unpleasant taste such as bitterness and astringency. Instead, you can enjoy the sweetness and umami that beans have originally.

以下、実施例により本発明を説明するが、本発明はこれらの実施例に限定されるものではない。 Hereinafter, the present invention will be described with reference to examples, but the present invention is not limited to these examples.

〔工程(a)、工程(c)、工程(b)を順に含む方法に関する実施例〕
実施例1〜9、比較例1〜4: 大豆水煮の検討
温水5L中に生豆の大豆1kgを浸漬し、温水浸漬処理をした。温水浸漬処理の温度および時間は、表3または表4に示す条件で行った。
次に、10℃の水3Lに、温水浸漬処理された大豆を、16時間または14時間、水浸漬処理を行い、水浸漬処理終了後の大豆重量(処理後歩留)を測定した。
次に、表3または表4に示す条件で、水浸漬処理された大豆と充填液とをレトルトパウチに充填し、真空包装した後、115℃30分間レトルト殺菌機で加熱殺菌処理して大豆水煮を得た。なお、使用した充填液は、加熱殺菌処理により過度の軟化を防ぐ目的で塩化カルシウム0.1重量%となるように調整したものを用いた。
次に、得られた大豆水煮の各サンプルを開封し、水切りした後、レトルト殺菌処理後の大豆について、大豆重量と大豆中のショ糖含有率(%)の測定および官能評価を行った。
また、比較例1(対象1、従来製法)として温水浸漬処理を経ずに水浸漬処理した後に100℃20分間水煮処理した大豆、比較例2(対象2)として温水浸漬処理を経ずに水浸漬処理した大豆について、上記同様に充填包装後、レトルト殺菌処理して大豆水煮を得て、同様に分析測定および官能評価を行った。なお、比較例1は、レトルト殺菌後の大豆重量が比較例2と近似するように表3に示す条件で調整した。
大豆水煮の大豆に含まれるショ糖含有率(%)の測定は、水切りした大豆を粉砕処理した後、蒸留水に溶解し、除タンパク処理して得られた抽出物を、高速液体クロマトグラフィー(島津製作所製、機種Prominence UFLC、使用カラム Suger−D)を使用し測定した。
大豆水煮の官能評価は、五味識別検査において味覚優良者として選抜され訓練された嗜好性官能評価パネラー5名によって、不快味(渋み、エグ味、苦味)と好ましい風味(甘み、うま味)の有無と強弱について表1に基づき5段階評価した。各パネラーの評点の平均値を、表2の示す評価基準に従って総合評価した。結果を表3、表4に示す。
[Example relating to method including step (a), step (c) and step (b) in order]
Examples 1 to 9 and Comparative Examples 1 to 4: Examination of soybean boiled Soybean 1 kg of raw beans was immersed in 5 L of warm water and subjected to warm water immersion treatment. The temperature and time of the hot water immersion treatment were performed under the conditions shown in Table 3 or Table 4.
Next, the soybeans soaked in warm water were soaked in 3 L of water at 10° C. for 16 hours or 14 hours, and the weight of soybeans after the water soaking treatment (retention after treatment) was measured.
Next, under the conditions shown in Table 3 or Table 4, soybeans soaked in water and the filling liquid were filled in a retort pouch, vacuum-packed, and then heat-sterilized with a retort sterilizer at 115°C for 30 minutes to obtain soybean water. Got boiled. The filling liquid used was adjusted to have a calcium chloride content of 0.1% by weight for the purpose of preventing excessive softening by heat sterilization.
Next, each of the obtained boiled soybean samples was opened, drained, and then the soybean after retort sterilization treatment was subjected to measurement of soybean weight and sucrose content (%) in soybean, and sensory evaluation.
Further, as Comparative Example 1 (Target 1, conventional production method), soybeans were soaked in water without undergoing hot water immersion treatment and then boiled at 100° C. for 20 minutes, and as Comparative Example 2 (Target 2), without hot water immersion treatment. The soybeans soaked in water were filled and packaged in the same manner as above, and then sterilized by retort to obtain boiled soybeans, and the same analytical measurement and sensory evaluation were performed. In Comparative Example 1, soybean weight after retort sterilization was adjusted under the conditions shown in Table 3 so as to be similar to Comparative Example 2.
The sucrose content (%) contained in soybeans boiled in soybeans was measured by grinding the drained soybeans, dissolving them in distilled water, and deproteinizing the resulting extract to obtain high-performance liquid chromatography. (Manufactured by Shimadzu Corp., model Prominence UFLC, column used: Super-D) was used for measurement.
The sensory evaluation of boiled soybean was carried out by five taste panelists who were selected and trained as excellent tasters in the Gomi taste test, and whether there was an unpleasant taste (astringency, astringency, bitterness) and a favorable flavor (sweetness, umami). Based on Table 1, the strength and weakness were evaluated in five levels. The average value of the scores of each panel was comprehensively evaluated according to the evaluation criteria shown in Table 2. The results are shown in Tables 3 and 4.

Figure 0006716622
Figure 0006716622

Figure 0006716622
Figure 0006716622

Figure 0006716622
Figure 0006716622

Figure 0006716622
Figure 0006716622

〔工程(a)、工程(c)、工程(b)を順に含む方法に関する実施例〕
実施例10、比較例5: 蒸し大豆の検討
50℃の温水5L中に生豆の大豆1kgを10分間浸漬し、温水浸漬処理をした。
次に、10℃の水3Lに、温水浸漬処理された大豆を16時間、水浸漬処理を行い、水浸漬処理終了後の大豆重量(処理後歩留)を測定した。
次に、水浸漬処理された大豆100gをレトルトパウチに充填し、レトルトパウチ内の空気を窒素ガス置換して含気包装した後、115℃30分間レトルト殺菌機で加熱殺菌処理して蒸し大豆を得た。得られた蒸し大豆のサンプルについて、段落〔0044〕大豆水煮の検討と同様にして、大豆中の糖質含含有率(%)の測定および官能評価を行った。
また、比較対象として温水浸漬処理を経ずに水浸漬処理された大豆について、上記同様に充填包装後、加熱殺菌処理して蒸し大豆を得て、同様に分析測定および官能評価を行った。
結果を表5に示す。
[Example relating to method including step (a), step (c) and step (b) in order]
Example 10, Comparative Example 5: Examination of Steamed Soybeans 1 kg of raw soybeans was dipped in 5 L of warm water at 50° C. for 10 minutes to be dipped in hot water.
Next, the soybeans soaked in warm water were soaked in 3 L of water at 10° C. for 16 hours, and the weight of soybeans after the water soaking treatment (retention after treatment) was measured.
Next, 100 g of soybeans treated with water was filled in a retort pouch, the air in the retort pouch was replaced with nitrogen gas and air-filled, and then heat sterilized by a retort sterilizer for 30 minutes at 115°C to steam steamed soybeans. Obtained. With respect to the obtained steamed soybean sample, the sugar content content (%) in soybean was measured and the sensory evaluation was performed in the same manner as in paragraph [0044] Investigation of soybean boiled.
Further, as a comparison object, soybeans that had been subjected to water immersion treatment without undergoing warm water immersion treatment were packed and packaged in the same manner as above, then heat sterilized to obtain steamed soybeans, and the same analytical measurement and sensory evaluation were performed.
The results are shown in Table 5.

Figure 0006716622
Figure 0006716622

〔工程(a)、工程(c)、工程(b)を順に含む方法に関する実施例〕
実施例11、比較例6: 煎り大豆の検討
50℃の温水5L中に生豆の大豆1kgを10分間浸漬し、温水浸漬処理をした。
次に、10℃の水3Lに、温水浸漬処理された大豆を6時間、水浸漬処理をした。
次に、水浸漬処理された大豆を、焙煎機を用いて165℃で20分間焙煎処理して煎り大豆を得て、得られた煎り大豆のサンプルについて、段落〔0044〕大豆水煮の検討と同様にして、官能評価を行った。
また、比較対象として温水浸漬処理を経ずに水浸漬処理された大豆について、上記同様に焙煎処理して煎り大豆を得て、同様に官能評価を行った。
結果を表6に示す。
[Example relating to method including step (a), step (c) and step (b) in order]
Example 11 and Comparative Example 6: Investigation of roasted soybean 1 kg of soybeans of raw beans was immersed in 5 L of warm water at 50° C. for 10 minutes to be immersed in warm water.
Next, the soybean soaked in warm water was soaked in 3 L of water at 10° C. for 6 hours.
Next, the soaked soybeans are roasted at 165° C. for 20 minutes using a roasting machine to obtain roasted soybeans. Sensory evaluation was carried out in the same manner as the examination.
For comparison, soybeans soaked in water without being soaked in warm water were roasted in the same manner as above to obtain roasted soybeans, and the same sensory evaluation was performed.
The results are shown in Table 6.

Figure 0006716622
Figure 0006716622

〔工程(a)、工程(b)を順に含む方法に関する実施例〕
実施例12: 煎り黒大豆の検討
50℃の温水5L中に生豆の黒大豆1kgを20分間浸漬し、温水浸漬処理をした。
次に、温水浸漬処理された黒大豆を焙煎機を用いて165℃で20分間焙煎処理して煎り黒大豆を得た。また、比較対象として10℃の水中に20分間浸漬した後、上記同様に焙煎処理して得られた煎り黒大豆を得た。得られたそれぞれの煎り黒大豆について官能評価をしたところ、温水浸漬処理をして得られた煎り黒大豆は、水浸漬処理したものと比べて、渋みが少なく官能的に優れていた。
また、得られたそれぞれの煎り黒大豆10gを95℃の湯1Lに入れ、5分間放置した後、煎り黒大豆を取り除き、黒豆茶を得た。得られたそれぞれの黒豆茶について官能評価をしたところ、温水浸漬処理を経て得られた黒豆茶は、水浸漬処理を経て得られたものと比べて、渋みが少なく官能的に優れていた。
[Example relating to method including step (a) and step (b) in order]
Example 12: Examination of roasted black soybean 1 kg of black soybean of raw beans was dipped in 5 L of hot water at 50° C. for 20 minutes to be dipped in hot water.
Next, the black soybean subjected to the hot water immersion treatment was roasted at 165° C. for 20 minutes using a roasting machine to obtain roasted black soybean. Moreover, roasted black soybeans obtained by roasting in the same manner as above, after being immersed in water at 10° C. for 20 minutes as a comparison object, were obtained. A sensory evaluation was conducted on the obtained roasted black soybeans. The roasted black soybeans obtained by the hot water soaking treatment were less astringent and organoleptically superior to those obtained by the water soaking treatment.
10 g of each roasted black soybean thus obtained was placed in 1 L of hot water at 95° C. and left for 5 minutes, and then roasted black soybean was removed to obtain black soybean tea. A sensory evaluation of each of the obtained black soybean teas revealed that the black soybean teas obtained through the hot water immersion treatment were less astringent and organoleptically superior to those obtained through the water immersion treatment.

本発明の方法によれば、豆類が有する不快味成分が減少され、且つ、豆類が有する好ましい呈味成分を多く含み、うま味が保持された風味良好な豆類加工食品が得られる。また、豆類から不快味成分を除去する工程が、従来沸騰水による水煮処理から温水浸漬処理となるために必要な熱エネルギーコストを大幅に削減し、製造時間の短縮化も図ることができる。さらに、本発明においては、短時間の温水浸漬処理よって、豆類からの糖類などの溶出が減少するため、浸漬処理水に含まれる有機物も少なくなり、工場で製造する際の排水処理負荷を低減することができる。本発明による製造方法は、豆類加工食品の風味の向上を図るだけでなく、製造コスト面および環境面からも優れている。 According to the method of the present invention, an unpleasant taste component contained in beans is reduced, and a processed food product of legume having a good taste, which contains a large amount of preferable taste components contained in beans and retains umami. Further, the heat energy cost required for the step of removing the unpleasant taste component from the beans to change from the conventional boiling treatment with boiling water to hot water immersion treatment can be significantly reduced, and the manufacturing time can be shortened. Furthermore, in the present invention, since the elution of sugars and the like from beans is reduced by the hot water immersion treatment for a short time, the organic matter contained in the immersion treatment water is also reduced, and the wastewater treatment load at the time of manufacturing in the factory is reduced. be able to. The manufacturing method according to the present invention not only improves the flavor of processed beans, but is also excellent in manufacturing cost and environment.

Claims (1)

工程(a):生豆の豆類を、直ちに50℃以上65℃未満の温水に5〜20分間、温水浸漬処理する工程、
工程(c):30℃以下で水浸漬処理する工程、
工程(b):加熱処理する工程、を順に且つ連続して含み
(但し、生豆を前記温水浸漬処理する工程と、前記加熱処理する工程との間に磨砕処理する工程を含むことを除く。)
前記加熱処理が、焙煎処理、または、工程(c)で水浸漬処理された豆類を容器に充填密封した後、加熱殺菌処理することを特徴とする、豆類加工食品の製造方法。
Step (a): a step of immediately immersing green beans in warm water at 50 ° C. or higher and lower than 65° C. for 5 to 20 minutes,
Step (c): a step of subjecting to water immersion treatment at 30° C. or lower,
Step (b): including a step of heat treatment, sequentially and continuously ,
(However, it does not include a step of grinding treatment between the step of soaking the green beans in the warm water and the step of the heat treatment.)
A method for producing a processed legume food, characterized in that the heat treatment comprises roasting treatment or filling and sealing the beans that have been subjected to the water immersion treatment in step (c) in a container and then heat sterilizing .
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