JPH01179727A - Production of antimony oxide - Google Patents
Production of antimony oxideInfo
- Publication number
- JPH01179727A JPH01179727A JP262988A JP262988A JPH01179727A JP H01179727 A JPH01179727 A JP H01179727A JP 262988 A JP262988 A JP 262988A JP 262988 A JP262988 A JP 262988A JP H01179727 A JPH01179727 A JP H01179727A
- Authority
- JP
- Japan
- Prior art keywords
- antimony oxide
- droplets
- antimony
- water
- rotating body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910000410 antimony oxide Inorganic materials 0.000 title claims abstract description 9
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 claims abstract description 9
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 7
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 238000002347 injection Methods 0.000 claims 1
- 239000007924 injection Substances 0.000 claims 1
- 230000003647 oxidation Effects 0.000 abstract description 6
- 238000007254 oxidation reaction Methods 0.000 abstract description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004566 building material Substances 0.000 abstract description 2
- 239000000460 chlorine Substances 0.000 abstract description 2
- 229910052801 chlorine Inorganic materials 0.000 abstract description 2
- 239000001301 oxygen Substances 0.000 abstract description 2
- 229910052760 oxygen Inorganic materials 0.000 abstract description 2
- 230000007062 hydrolysis Effects 0.000 abstract 2
- 239000003566 sealing material Substances 0.000 abstract 1
- 239000013078 crystal Substances 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は耐酸化性が高い等軸品構造を有するアンチモン
（Ｓｂｚ（Ｌ＋）の製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a method for producing antimony (Sbz(L+)) having an equiaxed structure with high oxidation resistance.
５ｂｚ０３は難燃剤として建材や集積回路の封止材等に
広く使用されている。従来は転炉で得られる粗５ｂｚＯ
ｓを塩酸に溶解し、１０００〜１５００ｇ／ Ａ程度の
酸化アンチモン水溶液とし、この水溶液を高温の水中へ
注入添加して加水分解反応を行ない５ｂｚＯ３を製造し
ていた。この方法で得られた５ｂ２０３は柱状晶であり
、酸素や塩素等に対する耐酸化性が必ずしも高くなく、
難燃剤としての効果が不十分であるという問題点を有し
ていた。5bz03 is widely used as a flame retardant in building materials and encapsulating materials for integrated circuits. Conventionally, crude 5bzO obtained in a converter
s was dissolved in hydrochloric acid to form an aqueous antimony oxide solution of about 1000 to 1500 g/A, and this aqueous solution was poured into high-temperature water to carry out a hydrolysis reaction to produce 5bzO3. 5b203 obtained by this method is a columnar crystal and does not necessarily have high oxidation resistance against oxygen, chlorine, etc.
The problem was that the effect as a flame retardant was insufficient.
本発明の目的は従来技術の上記問題点を解消するために
、耐酸化性が高い等軸品の５ｂ２０３を得る方法を提供
することにある。An object of the present invention is to provide a method for obtaining equiaxed 5b203 having high oxidation resistance in order to solve the above-mentioned problems of the prior art.
本発明方法は上記問題点を解消するために、塩化アンチ
モン水溶液を水中へ注入添加して加水分解反応を行ない
酸化アンチモンを製造する方法において、前記塩化アン
チモン水溶液を回転体上へ滴下して飛散させ液滴となし
、該液滴を前記水中へ注入添加する点に特徴がある。In order to solve the above problems, the method of the present invention is a method for producing antimony oxide by injecting and adding an antimony chloride aqueous solution into water to perform a hydrolysis reaction, in which the antimony chloride aqueous solution is dropped onto a rotating body and scattered. The method is characterized in that the droplets are formed into droplets and the droplets are injected into the water.
該塩化アンチモン水溶液の濃度は通常用いられる１００
０〜１５００ｇ／ Ａが良い。上記回転体の代表例は円
板である。円板の場合その直径は特に限定されないが約
３０〜３００１ｍが良好であり、且つ該円板の回転数は
滴下する該塩化アンチモン水溶液が該円板の回転する遠
心力により飛散して液滴となればよいのであるが、該円
板の望ましい直径の範囲によっても異なり、約１００〜
５００ｒｐｍが望ましい。回転体の他の例としては下方
に広がる円錐体が挙げられ、前記円板より一層好ましい
効果を」二げる。該円錐体の場合には、底面直径が５０
〜１５０ｍ璽、高さ５〜］、 ＯＯ１ｍのものが望まし
く、回転数は２００〜３００ｒｐｍが望ましい。また、
本発明方法に用いる水の温度は５０〜９５°Ｃが良く、
６０〜７０°Ｃが好適であり、５０°Ｃ未満又は９５°
Ｃを越えると等軸晶の５ｂｚＯａが得られにくくなるの
で良くない。本願発明者の確認によれば、上記のように
して該回転体から飛散した液滴は水中へ添加された途端
に微細に分裂して、等軸晶の５ｂ２ｏ３となる。尚、該
加水分解反応時に攪拌を行えばより均一な粒径を有する
５ｂ２０：＋が得られる。The concentration of the antimony chloride aqueous solution is 100, which is commonly used.
0 to 1500g/A is good. A typical example of the rotating body is a disk. In the case of a disk, its diameter is not particularly limited, but it is preferably about 30 to 3001 m, and the rotation speed of the disk is such that the dropping antimony chloride aqueous solution is scattered by the centrifugal force of the rotating disk and becomes droplets. However, it varies depending on the desired diameter range of the disc, and is about 100 to
500 rpm is desirable. Another example of a rotating body is a downwardly expanding cone, which provides a more favorable effect than the disk. In the case of the cone, the base diameter is 50
~150 m long, height 5 ~], OO1 m is desirable, and the rotation speed is preferably 200 to 300 rpm. Also,
The temperature of the water used in the method of the present invention is preferably 50 to 95°C;
60-70°C is preferred, less than 50°C or 95°
If it exceeds C, it becomes difficult to obtain equiaxed 5bzOa, which is not good. According to the inventor's confirmation, the droplets scattered from the rotating body as described above are finely divided into equiaxed crystals of 5b2o3 as soon as they are added to water. Incidentally, if stirring is performed during the hydrolysis reaction, 5b20:+ having a more uniform particle size can be obtained.
濃度が１３００ｇ／ ｊ２の塩化アンチモン水溶液２０
０ｍ１を、底面直径９０龍、高さ７０龍のポリエチレン
製円錐体の頂部へ６０ｍβ／分の速度で滴下した。円錐
体は２００〜３００ｒｐｍの回転数に保ち、飛散した塩
化アンヂモン水溶液の液滴は６０°Ｃに保った水へ添加
し、加水分解反応を行った。Antimony chloride aqueous solution 20 with a concentration of 1300g/j2
0 ml was dropped onto the top of a polyethylene cone with a bottom diameter of 90 mm and a height of 70 mm at a rate of 60 mβ/min. The rotation speed of the cone was maintained at 200 to 300 rpm, and the scattered droplets of the aqueous anddimon chloride solution were added to water maintained at 60°C to perform a hydrolysis reaction.
尚、上記水中へ攪拌子を入れて２００〜３００ｒｐｍの
攪拌を行った。このようにして、得られた５ｂ２０３を
観察したところ粒径が１９〜１５μｍであり、等軸晶の
結晶構造を有していた。A stirrer was placed in the water and stirred at 200 to 300 rpm. When the 5b203 thus obtained was observed, it was found to have a particle size of 19 to 15 μm and an equiaxed crystal structure.
本発明方法を行うことにより、簡便に耐酸化性が高い等
軸晶の５ｂ２０３を得ることができる。By carrying out the method of the present invention, equiaxed 5b203 having high oxidation resistance can be easily obtained.
特許出願人 住友金属鉱山株式会社Patent applicant: Sumitomo Metal Mining Co., Ltd.
Claims (1)
分解反応を行ない酸化アンチモンを製造する方法におい
て、前記塩化アンチモン水溶液を、回転体上へ滴下して
飛散させ液滴となし、該液滴を前記水中へ注入添加する
ことを特徴とする酸化アンチモンの製造方法。(1) In a method of producing antimony oxide by injecting and adding an antimony chloride aqueous solution into water and performing a hydrolysis reaction, the antimony chloride aqueous solution is dropped onto a rotating body and scattered to form droplets, and the droplets are A method for producing antimony oxide, which comprises adding the antimony oxide by injection into the water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP262988A JPH01179727A (en) | 1988-01-11 | 1988-01-11 | Production of antimony oxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP262988A JPH01179727A (en) | 1988-01-11 | 1988-01-11 | Production of antimony oxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01179727A true JPH01179727A (en) | 1989-07-17 |
Family
ID=11534688
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP262988A Pending JPH01179727A (en) | 1988-01-11 | 1988-01-11 | Production of antimony oxide |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01179727A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0217224U (en) * | 1988-07-12 | 1990-02-05 |
-
1988
- 1988-01-11 JP JP262988A patent/JPH01179727A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0217224U (en) * | 1988-07-12 | 1990-02-05 | ||
| JPH0441929Y2 (en) * | 1988-07-12 | 1992-10-02 |
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