JPH01175917A - Lipophilic type emulsified cosmetic - Google Patents

Lipophilic type emulsified cosmetic

Info

Publication number
JPH01175917A
JPH01175917A JP33321687A JP33321687A JPH01175917A JP H01175917 A JPH01175917 A JP H01175917A JP 33321687 A JP33321687 A JP 33321687A JP 33321687 A JP33321687 A JP 33321687A JP H01175917 A JPH01175917 A JP H01175917A
Authority
JP
Japan
Prior art keywords
stirring
oil
lipophilic
cosmetic
ambient temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP33321687A
Other languages
Japanese (ja)
Other versions
JP2581941B2 (en
Inventor
Yoichi Yashiro
洋一 八代
Toshiyuki Kobayashi
利行 小林
Satoru Nakada
悟 中田
Hiroaki Konishi
宏明 小西
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nonogawa Shoji Ltd
Original Assignee
Nonogawa Shoji Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nonogawa Shoji Ltd filed Critical Nonogawa Shoji Ltd
Priority to JP33321687A priority Critical patent/JP2581941B2/en
Publication of JPH01175917A publication Critical patent/JPH01175917A/en
Application granted granted Critical
Publication of JP2581941B2 publication Critical patent/JP2581941B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • A61K8/375Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Colloid Chemistry (AREA)

Abstract

PURPOSE:To obtain the title cosmetic, having improved stability and excellent feeling of use, by successively adding an amino acid-containing aqueous solution, metallic soap-containing oily phase and water to a lipophilic type nonionic surfactant at ambient temperature while stirring. CONSTITUTION:A lipophilic type emulsified cosmetic obtained by adding (B) an aqueous solution containing an amino acid and/or salt thereof, preferably L-serine or glutamic acid to (A) a lipophilic type nonionic surfactant (e.g., glyceryl monoisostearate) at ambient temperature (1-45 deg.C) while stirring, adding (C) a metallic soap (preferably zinc stearate) and an oily phase containing an oil (e.g., liquid paraffin) which is a liquid at ambient temperature and a volatile oil to the resultant solution while stirring and further adding water thereto while stirring. The above-mentioned cosmetic is capable of increasing the amount of blended aqueous phase components and blending a large amount of the volatile oil, further stable blending of a substance readily damaged by heat and emulsifying a liquid oil unstable to heat.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は安定で使用感触に優れた親油型乳化化粧料に間
する。更に詳しくは、室温で調製することにより、水相
成分の配合量を増加し、揮発性油分を多量に配合するこ
とを可能とした、安定性が良好で且つ使用感に優れ、嫌
熱物質の安定配合および、熱に不安定な液状油の乳化さ
えも可能な親油型乳化化粧料に間する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention provides a lipophilic emulsified cosmetic that is stable and has an excellent feel when used. More specifically, by preparing at room temperature, it is possible to increase the amount of aqueous phase components and incorporate a large amount of volatile oil, and it has good stability and ease of use. To create a lipophilic emulsified cosmetic that can be stably blended and even emulsify heat-labile liquid oils.

[従来の技術] 従来、乳化組成物の調製法は、水相および油相をそれぞ
れ70℃〜90℃といった高温にまで昇温後それぞれを
混合し保温攪拌を経て冷却に至るといフた方法が一般的
である。
[Prior Art] Conventionally, the method for preparing an emulsified composition has been to raise the temperature of the aqueous phase and oil phase to a high temperature of 70°C to 90°C, mix them, and then cool them through heat-retaining stirring. Common.

また、親油型乳化化粧料は、肌表面をまんべんなく薄膜
状に覆うことができ、保湿性やエモリエント性に使れ、
肌荒れ等を防ぐのに効果が高いとされている。
In addition, lipophilic emulsified cosmetics can evenly cover the skin surface in a thin film, and can be used for moisturizing and emollient properties.
It is said to be highly effective in preventing skin irritation.

また、メークアップ化粧料としてその温水性に由来して
、化粧くずれを極力抑えられるという特徴を有している
In addition, as a makeup cosmetic, it has the characteristic of minimizing makeup fading due to its warm water properties.

[発明が解決しようとする問題点コ しかしながら、親油型乳化化粧料は使用感としての皮膚
表面での延びの悪さ、重さ、また使用時の外観上におけ
るベタつき、ギラつきなとの欠点を有していた。加えて
、安定な親油型乳化化粧料を得るには、使用性を多少犠
牲にしても硬度を高くせざるをえない状況であった。
[Problems to be Solved by the Invention] However, lipophilic emulsified cosmetics have disadvantages such as poor spreadability on the skin surface, weight, and stickiness and glare when used. had. In addition, in order to obtain a stable lipophilic emulsified cosmetic, it is necessary to increase the hardness even at the expense of some usability.

また、嫌熱物質は化粧料に配合する際、乳化時の加熱に
より分解、変質、変性等が起こり配合が困難であった。
Furthermore, when blending thermophobic substances into cosmetics, it has been difficult to blend them into cosmetics because they are subject to decomposition, deterioration, denaturation, etc. due to heating during emulsification.

また、分解、変質、変性等を避ける為、冷却過程での低
温時における添加を行っても、分散が不均一であったり
、安定配合が困難であったりした。
Furthermore, even if the additive is added at a low temperature during the cooling process in order to avoid decomposition, deterioration, denaturation, etc., the dispersion may be non-uniform or it may be difficult to achieve stable blending.

[問題点を解決するための手段] 本発明者らは、これらの諸問題に対し解決すべく手段を
検討した結果、室温において、親油型非イオン界面活性
剤にアミノ酸および/またはアミノ酸塩水溶液を攪拌し
ながら添加し、これに金属石けんと室温で液体である油
分および/または揮発性油分を含有する油相を攪拌しな
がら添加し、更に水を攪拌しながら添加することにより
得られた親油型乳化化粧料が、安定性の高いことを見い
だし、本発明を完成するに至った。しかも、本発明の親
油型乳化化粧料は、揮発性シリコーン油および水相成分
を多量に配合できるため、従来の親油型乳化化粧料には
なかった、さっばりとした使用感触を持ち、良好な使用
感触を得ることができる。
[Means for Solving the Problems] As a result of studying the means to solve these problems, the present inventors found that an aqueous solution of an amino acid and/or an amino acid salt was added to a lipophilic nonionic surfactant at room temperature. to which a metal soap and an oil phase containing an oil and/or volatile oil that is liquid at room temperature are added with stirring, and then water is added with stirring. It was discovered that oil-type emulsified cosmetics have high stability, and the present invention was completed. Moreover, since the lipophilic emulsified cosmetic of the present invention can contain a large amount of volatile silicone oil and aqueous phase components, it has a light feel when used, which conventional lipophilic emulsified cosmetics did not have. A good feeling of use can be obtained.

本発明で用いられる親油型非イオン界面活性剤は、グリ
セリルモノイソステアレート、ジグリセリルモノステア
レートであり、これらの界面活性剤は液状油およびシリ
コーン油を含む油相を1’C〜30℃といった室温にお
いて、ゲル化および/または乳化して親油型乳化化粧料
を得ることができる。
The lipophilic nonionic surfactants used in the present invention are glyceryl monoisostearate and diglyceryl monostearate. A lipophilic emulsified cosmetic can be obtained by gelling and/or emulsifying at room temperature such as °C.

さらに本発明で用いられるアミノ酸および/またはアミ
ノ酸塩類は通常化粧品製造に使用されるものならば何で
もよいが、具体的にはアスパラギン酸、グルタミン酸、
セリン、アルギニン、トレオニン、トリプトファン、グ
リシン、アラニン、メチオニン、リジン等であるが、好
ましくは、L−セリン、グルタミン酸および/またはそ
の塩類である。
Furthermore, the amino acids and/or amino acid salts used in the present invention may be of any type as long as they are normally used in the production of cosmetics, but specific examples include aspartic acid, glutamic acid,
These include serine, arginine, threonine, tryptophan, glycine, alanine, methionine, lysine, etc., but preferably L-serine, glutamic acid and/or salts thereof.

また金°属石けんとしては、ステアリン酸アルミニウム
、ステアリン酸マグネシウム、ステアリン酸亜鉛、ステ
アリン酸カルシウム、ウンデシレン酸亜鉛等が挙げられ
るが、好ましくはステアリン酸亜鉛もしくはウンデシレ
ン酸亜鉛である。
Examples of the metal soap include aluminum stearate, magnesium stearate, zinc stearate, calcium stearate, zinc undecylenate, etc., and zinc stearate or zinc undecylenate is preferred.

油分は、化粧品原料に用いられる室温で渣状を呈する油
分であれば何でも良いが、好ましくは流動パラフィン、
スクワラン等の炭化水素である。
The oil may be any oil that is used as a cosmetic raw material and forms a residue at room temperature, but preferably liquid paraffin,
Hydrocarbons such as squalane.

なお、本発明において室温とは1℃〜40℃を言う。In addition, in this invention, room temperature refers to 1 degreeC - 40 degreeC.

また、本発明で用いられる揮発性油分は従来用いられる
もので良いが、具体的には、オクタメチルシクロテトラ
シロキサン、デカメチルシクロペンタシロキサン、オク
タメチルシクロオクタシロキサンなどの揮発性シリコー
ン油が好ましい。
Further, the volatile oil used in the present invention may be any conventionally used volatile oil, but specifically, volatile silicone oils such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and octamethylcyclooctasiloxane are preferred.

本発明で用いられる非イオン界面活性剤の量は1−10
%、好ましくは3〜7%である。1%以下では、乳化が
困難で、10%以上でも、油の浸出、分離等が起こり好
ましくない。
The amount of nonionic surfactant used in the present invention is 1-10
%, preferably 3 to 7%. If it is less than 1%, emulsification is difficult, and even if it is more than 10%, oil leaching, separation, etc. may occur, which is not preferable.

また、アミノ酸の配合量は0.1〜10%、好ましくは
1〜5%である。0.1%以下では、乳化の安定性が悪
く、またlO%以上配合しても効果の増強が無く不経済
である。
Further, the blending amount of amino acids is 0.1 to 10%, preferably 1 to 5%. If it is less than 0.1%, the stability of emulsification is poor, and even if it is added more than 10%, the effect will not be enhanced and it is uneconomical.

金属石けんの配合量は0.01〜10%、好ましくは 
0.1〜4%である。0.01%以下では乳化が安定せ
ず、10%以上の配合も効果の増強は無く不経済である
The amount of metal soap blended is 0.01 to 10%, preferably
It is 0.1 to 4%. If it is less than 0.01%, the emulsification will not be stable, and if it is more than 10%, the effect will not be enhanced and it is uneconomical.

さらに、揮発性シリコーン油の配合量は0.1〜40%
である。
Furthermore, the amount of volatile silicone oil is 0.1 to 40%.
It is.

目的とする使用感触により、上記範囲の閏で、処方を変
化することができる。
The formulation can be varied within the above range depending on the intended feeling of use.

またゲル化および/または乳化を行う一連の過程から終
了までの表記化粧料の温度は、1℃〜50℃、好ましく
は10℃〜30℃である。
Further, the temperature of the described cosmetic from the series of gelling and/or emulsifying processes to the end is 1°C to 50°C, preferably 10°C to 30°C.

また、本発明の親油型乳化化粧料には、本発明の効果を
損なわない範囲で、一般に化粧料に用いられる成分を配
合することができる0例えば、水相成分として、ヒアル
ロン酸ナトリウム、ピロリドンカルボン酸、酸性ムコ多
糖類、水溶性コラーゲン、増粘物置等、油相成分として
熱に不安定な液状油、その他、必要があれば、無機顔料
や有機顔料等の色材、紫外線吸収剤、紫外線遮断剤、カ
チオン性界面活性剤、アニオン性界面活性剤、非イオン
性界面活性剤、両性界面活性剤等の界面活性剤、ビタミ
ン、グリチルリチン誘導体等の薬剤、収れん剤、酸化防
止剤、防腐剤、香料、pH調整剤、熱に不安定な有効添
加物等を本発明の親油型乳化化粧料に配合添加すること
ができる。
In addition, the lipophilic emulsified cosmetic composition of the present invention may contain ingredients generally used in cosmetics within a range that does not impair the effects of the present invention. For example, as aqueous phase components, sodium hyaluronate, pyrrolidone Carboxylic acids, acidic mucopolysaccharides, water-soluble collagen, thickeners, etc., liquid oils that are unstable to heat as oil phase components, and if necessary, coloring materials such as inorganic pigments and organic pigments, ultraviolet absorbers, Surfactants such as ultraviolet blockers, cationic surfactants, anionic surfactants, nonionic surfactants, and amphoteric surfactants, vitamins, drugs such as glycyrrhizin derivatives, astringents, antioxidants, and preservatives. , fragrances, pH adjusters, heat-unstable effective additives, etc. can be added to the lipophilic emulsified cosmetic composition of the present invention.

[実施例] 本発明を実施例により詳細に説明するが、本発明は実施
例に限定されるものではない、実施例中の配合量は!量
%である。
[Example] The present invention will be explained in detail by examples, but the present invention is not limited to the examples. The amount is %.

実施例1 乳化ファンデーション ■グリセリルモノイソステアレート5.0■L−グルタ
ミン酸ナトリウム     2.0■流動パラフイン(
70cs)       5.0オクタメチル シクロテトラシロキサン 12.0 ■ステアリン酸亜鉛          2.0■混合
顔料 (実施例1の製造方法) ■を一部のWa水に溶解し、攪拌をしなから■に添加す
る。これに■および■を攪拌しながら添加し、残りの■
に■を分散したものを更に攪拌しながら添加し、乳化分
散し、目的の乳化ファンデーションを得る。
Example 1 Emulsified foundation ■ Glyceryl monoisostearate 5.0 ■ Sodium L-glutamate 2.0 ■ Liquid paraffin (
70cs) 5.0 Octamethylcyclotetrasiloxane 12.0 ■ Zinc stearate 2.0 ■ Mixed pigment (manufacturing method of Example 1) Dissolve ■ in some Wa water and add to ■ while stirring. do. Add ■ and ■ to this while stirring, and leave the remaining ■
A mixture of (1) and (2) dispersed therein is further added while stirring to emulsify and disperse to obtain the desired emulsified foundation.

(結果) 実施例1において得られた乳化ファンデーションは、化
粧持ち、のび、さっばり感等において良好な使用感触、
および良好な経時安定性を示した。
(Results) The emulsified foundation obtained in Example 1 had good makeup feel, spreadability, light feel, etc.
and showed good stability over time.

実施例2 クリーム ■グリセリルモノイソステアレート   3.0■し一
グルタミン酸ナトリウム     4.0実施例3 乳
液 実施例4 サンスクリーン Lジグリセリルモノステアレート   2.0■ジグリ
セリルモノステアレート    6.0■L−セリン 
            4.0■堰合顔料 〈実施r142〜5の製造方法) ■を■の一部の精製水に溶解し、攪拌をしなから■に添
加する。これに■を攪拌しながら添加し、残りの■を更
に攪拌しながら添加し、目的の乳化組成物を得る。
Example 2 Cream ■ Glyceryl monoisostearate 3.0 ■ Sodium monoglutamate 4.0 Example 3 Emulsion Example 4 Sunscreen L diglyceryl monostearate 2.0 ■ Diglyceryl monostearate 6.0 ■ L -Serine
4.0■ Weir pigment (manufacturing method of implementation r142-5) Dissolve (1) in part of the purified water of (2), and add to (2) while stirring. Add (1) to this while stirring, and then add the remaining (2) while stirring to obtain the desired emulsified composition.

く結果) 実施例2〜5についても、良好な使用感触と経時安定性
を示す、良好な乳化化粧料を得た。
(Results) In Examples 2 to 5 as well, good emulsified cosmetics were obtained that exhibited good feeling in use and stability over time.

[発明の効果] 本発明により製造した親油型乳化化粧料は、低温でゲル
化または乳化するため、不安定な揮発性シリコーン油お
よび水相成分を多量に配合できることも特徴のひとつで
あり、このため、さっばりとした使用感触を持ち、従来
の乳化法による親油型乳化化粧料に比して良好な使用感
触を得ることができる。
[Effects of the Invention] Since the lipophilic emulsified cosmetic produced by the present invention gels or emulsifies at low temperatures, one of its features is that it can contain a large amount of unstable volatile silicone oil and aqueous phase components. Therefore, it has a light feel when used, and can provide a better feel when used compared to lipophilic emulsified cosmetics produced by conventional emulsification methods.

以下に本発明の効果を実験例により詳細に説明する。実
験例は実施例1と、以下に示す4個の比較例について、
安定性および使用感触について行った。実験の結果につ
いては、安定性の結果を表1に、使用感触の結果を表2
に示した。
The effects of the present invention will be explained in detail below using experimental examples. The experimental examples are Example 1 and the four comparative examples shown below.
The stability and feeling of use were examined. Regarding the results of the experiment, the stability results are shown in Table 1, and the results of the feeling of use are shown in Table 2.
It was shown to.

[比較例] 比較例中の配合量は重量%である。比較例に先立ち採用
した評価方法を説明する。
[Comparative Example] The blending amounts in Comparative Examples are weight %. The evaluation method adopted prior to the comparative example will be explained.

(安定性) 作製した親油型乳化化粧料を5℃、室温、40℃の恒温
槽内に放置し、一定期間後の安定性を、下記の評価基準
にしたがい評価を行った。
(Stability) The prepared lipophilic emulsified cosmetic was left in a constant temperature bath at 5°C, room temperature, and 40°C, and its stability after a certain period of time was evaluated according to the following evaluation criteria.

良  好                     
       O油または水の侵出が見られる    
6分  離                    
      ×(使用感触) 男性および女性パネル15名を用いて、使用感触を、下
記の評価基準にしたがい評価を行った。
Good
O Oil or water leakage is seen.
6 separation
× (Feel in use) Using 15 male and female panels, the feel in use was evaluated according to the following evaluation criteria.

従来のものより良好と答えた人数が 10名以上            06名〜9名  
          65名以下          
   ×比較例1 揮発性油分を含まない親油型乳化フ
ァンデーション ■グリセリルモノイソステアレート   5.0■L−
グルタミン酸ナトリウム     2.00流動パラフ
イン(70c s)      15.0■ステアリン
酸亜鉛          2.00混合顔料 (製法) 実施例1の方法に準じて、乳化ファンデーションを作製
した。
10 or more people answered that it was better than the conventional one 06 to 9 people
65 people or less
× Comparative Example 1 Lipophilic emulsified foundation containing no volatile oil ■ Glyceryl monoisostearate 5.0 ■ L-
Sodium glutamate 2.00 Liquid paraffin (70 cs) 15.0 ■ Zinc stearate 2.00 Mixed pigment (manufacturing method) According to the method of Example 1, an emulsified foundation was prepared.

比較例2 金属石けん類を含まない親油型乳化ファノア
ーンヨン ■グリセリルモノイソステアレート   5.0■L−
グルタミン酸ナトリウム     2.0■混合顔料 (1m法) ■を一部の精製水に溶解し、攪拌をしながら■に添加す
る。これに■を攪拌しながら添加し、残りの■に■を分
散したものを更に攪拌しながら添加、乳化分散し、目的
の乳化ファンデーションを得る。
Comparative Example 2 Lipophilic emulsified fano-anion containing no metal soap ■Glyceryl monoisostearate 5.0 ■L-
Sodium glutamate 2.0 ■Mixed pigment (1m method) Dissolve (1) in some purified water and add to (2) while stirring. Add (2) to this while stirring, and add (2) dispersed in the remaining (2) with further stirring to emulsify and disperse to obtain the desired emulsified foundation.

比較例3 アミノ酸およびその塩類を含まない親油型乳
化ファンデーション ■グリセリルモノイソステアレート5.0L   シク
ロテトラシロキサン  12.0■混合顔料 (製法) ■を一部の精製水に溶解し、80℃まで加熱攪拌し、8
0℃にまで加熱した■に添加する。これに80℃まで加
熱した■を攪拌しながら添加し、残りの■に■を分散し
80℃まで加熱したものを更に攪拌しながら添加し、乳
化分散する。その後、30℃まで攪拌冷却して目的の乳
化ファンデーションを得る。
Comparative Example 3 Lipophilic emulsified foundation that does not contain amino acids and their salts ■ Glyceryl monoisostearate 5.0 L cyclotetrasiloxane 12.0 ■ Mixed pigment (manufacturing method) ■ Dissolved in some purified water and heated to 80 ° C. Heat and stir, 8
Add to (2) heated to 0°C. 2 heated to 80° C. is added to this while stirring, 2 is dispersed in the remaining 2, and the mixture heated to 80° C. is further added with stirring to emulsify and disperse. Thereafter, the mixture is stirred and cooled to 30° C. to obtain the desired emulsified foundation.

比較例4 M水型乳化ファンデーション■ステアリン酸
             2.0■セタノール   
           2.00流動パラフイン(70
cs)      20.0■POE (20)ソルビ
タン モノオレート   2.0 ■グリセリルモノオレート       2.0■モン
モリロナイト           0.50トリエタ
ノールアミン         1.5■混合顔料 (%1法) ■〜■を80℃まで加熱攪拌した油相に、■〜■までを
80℃まで加熱攪拌した水相を更に攪拌しながら添加し
、乳化する。その後、30℃まで攪拌冷却して目的の乳
化ファンデーションを得る。
Comparative Example 4 M water type emulsion foundation ■Stearic acid 2.0■Cetanol
2.00 liquid paraffin (70
cs) 20.0■POE (20) Sorbitan monooleate 2.0 ■Glyceryl monooleate 2.0■Montmorillonite 0.50 Triethanolamine 1.5■Mixed pigment (%1 method) Heat ■~■ to 80℃ The aqueous phase obtained by heating and stirring ① to ② to 80°C is added to the stirred oil phase with further stirring, and emulsified. Thereafter, the mixture is stirred and cooled to 30° C. to obtain the desired emulsified foundation.

表1 安定性の結果 表2 使用感触の結果 比較例1に示される揮発性油分を含まない親油型乳化フ
ァンデーションは、安定性に間しては間8舞いが、使用
感触において、のびが悪く、さっばり感に欠は親油型乳
1ヒフアンプージョンの欠点が顕著に現れてしまう。
Table 1 Stability Results Table 2 Results of Feeling in Use The lipophilic emulsified foundation that does not contain volatile oil shown in Comparative Example 1 has a stability of 8-8, but the feeling in use shows that it does not spread well. However, the drawbacks of lipophilic milk 1-hyphenate pusion become more obvious due to the lack of lightness.

比較例2に示される金属石けん類を含まない親油型乳化
ファンデーションおよび比較例3に示されろアミノ酸お
よびその塩類を含まない親油型乳化ファンデーションは
、使用感触においてはやや実施例1に劣るだけであるが
、安定性においては、経時的に劣化していくのが観察さ
れた。
The lipophilic emulsified foundation that does not contain metal soaps shown in Comparative Example 2 and the lipophilic emulsified foundation that does not contain amino acids and their salts shown in Comparative Example 3 are only slightly inferior to Example 1 in terms of feel when used. However, it was observed that the stability deteriorated over time.

比較例4に示される親水型乳化ファンデーションは安定
性においては実施例1に明らかに劣り、使用感触におい
てはさっばり感で良好な結果を示すものの、のび、フィ
ツト悪および化粧の持続性において実施例1に劣ること
が明らかであった。
The hydrophilic emulsion foundation shown in Comparative Example 4 is clearly inferior to Example 1 in terms of stability, and although it shows good results with a light feeling in use, it is inferior to Example 1 in terms of spreadability, poor fit, and makeup durability. It was clear that it was inferior to 1.

一方、本発明の実施例1では、安定性、使用感触ともに
申し分のない結果が得られた。
On the other hand, in Example 1 of the present invention, satisfactory results were obtained in both stability and feel during use.

特許出願人  有限会社 野々川商事Patent applicant: Nonokawa Shoji Ltd.

Claims (1)

【特許請求の範囲】[Claims] 室温において、親油型非イオン界面活性剤に、アミノ酸
および/またはアミノ酸塩含有水溶液を、攪拌しながら
添加し、これに金属石けんと室温で液状を呈する油分お
よび揮発性油分を含む油相を撹拌しながら添加し、更に
水を撹拌しながら添加することにより得られた親油型乳
化化粧料。
At room temperature, an aqueous solution containing an amino acid and/or an amino acid salt is added to a lipophilic nonionic surfactant while stirring, and an oil phase containing a metal soap, an oil that is liquid at room temperature, and a volatile oil is stirred. A lipophilic emulsified cosmetic obtained by adding water while stirring and then adding water while stirring.
JP33321687A 1987-12-28 1987-12-28 Lipophilic emulsion cosmetic Expired - Fee Related JP2581941B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP33321687A JP2581941B2 (en) 1987-12-28 1987-12-28 Lipophilic emulsion cosmetic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP33321687A JP2581941B2 (en) 1987-12-28 1987-12-28 Lipophilic emulsion cosmetic

Publications (2)

Publication Number Publication Date
JPH01175917A true JPH01175917A (en) 1989-07-12
JP2581941B2 JP2581941B2 (en) 1997-02-19

Family

ID=18263612

Family Applications (1)

Application Number Title Priority Date Filing Date
JP33321687A Expired - Fee Related JP2581941B2 (en) 1987-12-28 1987-12-28 Lipophilic emulsion cosmetic

Country Status (1)

Country Link
JP (1) JP2581941B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10194923A (en) * 1997-01-13 1998-07-28 Nippon Zetotsuku Kk Emulsified composition
US5853711A (en) * 1995-09-29 1998-12-29 Shiseido Company, Ltd Water-in-oil emulsion cosmetic composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5853711A (en) * 1995-09-29 1998-12-29 Shiseido Company, Ltd Water-in-oil emulsion cosmetic composition
JPH10194923A (en) * 1997-01-13 1998-07-28 Nippon Zetotsuku Kk Emulsified composition

Also Published As

Publication number Publication date
JP2581941B2 (en) 1997-02-19

Similar Documents

Publication Publication Date Title
JP2665951B2 (en) Solid water-in-oil emulsified cosmetic
JPS63250311A (en) Water-in-oil type cosmetic
JP2010270066A (en) Hairdressing cosmetic
JP2000119166A (en) Viscous or solid aqueous cosmetic
JPS60190705A (en) Cosmetic compounded with pigment surface-treated with hydrogenated lecithin
JP2996410B2 (en) Solid water-in-oil emulsified cosmetic
JPH0415762B2 (en)
JPS61293904A (en) Water-in-oil type emulsion cosmetic
JPH09278644A (en) Cosmetic of o/w-type emulsion
JPS61100513A (en) Long life cosmetic
CN106580758B (en) A kind of oil-control water-setting cream and preparation method thereof
JP4209568B2 (en) Water-containing powder cosmetic
JPH08268832A (en) Emulsified cosmetic
JPH03279319A (en) Solid-like oil-in water type make-up cosmetic
JPH01175917A (en) Lipophilic type emulsified cosmetic
JP3763564B2 (en) Water-in-oil emulsified cosmetic
JP3835392B2 (en) Exothermic composition and warm cosmetic
JP2003176210A (en) Emulsion type cosmetic
JP4171388B2 (en) Cosmetics
JP2001206817A (en) Oil-in-polyhydric alcohol type thermal substrate
KR20220094711A (en) Oil-in-water cosmetic composition comprising oil gelling agent and process of the preparation thereof
JPH04217612A (en) Gel-like hair cosmetic
JPH10167948A (en) Cosmetic
JP2002053425A (en) Solid water-in-oil type emulsified cosmetic
JPH0377167B2 (en)

Legal Events

Date Code Title Description
S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313111

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees