JPH011733A - Method of manufacturing laminates - Google Patents
Method of manufacturing laminatesInfo
- Publication number
- JPH011733A JPH011733A JP62-158364A JP15836487A JPH011733A JP H011733 A JPH011733 A JP H011733A JP 15836487 A JP15836487 A JP 15836487A JP H011733 A JPH011733 A JP H011733A
- Authority
- JP
- Japan
- Prior art keywords
- glass cloth
- laminate
- manufacturing
- impregnated
- binder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000004744 fabric Substances 0.000 claims description 20
- 239000011521 glass Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 10
- 229920005989 resin Polymers 0.000 claims description 10
- 239000002966 varnish Substances 0.000 claims description 7
- 238000009832 plasma treatment Methods 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 description 7
- 238000007747 plating Methods 0.000 description 4
- 238000004381 surface treatment Methods 0.000 description 4
- 239000007822 coupling agent Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- PARWUHTVGZSQPD-UHFFFAOYSA-N phenylsilane Chemical class [SiH3]C1=CC=CC=C1 PARWUHTVGZSQPD-UHFFFAOYSA-N 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
本発明はがラスクロスのバインダーを除去して樹脂クロ
スとの密着性を向上させる技術に関する。The present invention relates to a technique for removing the binder from lath cloth to improve its adhesion to resin cloth.
ガラスクロスは溶融原料を押し出し、次いで集束様で束
ねｒこ後紡糸され織られて製造されているが、集束する
際に澱粉、油脂などが配合された有機組成物であるバイ
ンダーを使用しており、このバインダーはガラスクロス
と樹脂ワニスとの密着性をＭｌなわせるので、従来にあ
っては、第３図に示すようにロール状に巻取られたがラ
スクロス１を巻き戻しながら約３００〜４５０℃に昇温
された電気炉７内を通してバインダーが焼去されている
が、この方法では、バインダーを確実に除去できなかっ
た。このため、第４図に示すようにロール状に巻取られ
たガラスクロス１を、電気炉７内に配置し、約３００〜
４５０℃で、２４〜７２時間かけて、バインダーを焼去
している。この方法であると、エネルギー消費量が莫大
となり、しかも生産性が極めて低いものであった。Glass cloth is manufactured by extruding a molten raw material, then bundling it into bundles, spinning it and weaving it, but when bundling it, a binder, which is an organic composition containing starch, oil, etc., is used. Since this binder improves the adhesion between the glass cloth and the resin varnish, conventionally it was wound up into a roll as shown in Fig. 3, but as the lath cloth 1 was unwound, it Although the binder was burnt off through the electric furnace 7 heated to 0.degree. C., the binder could not be removed reliably with this method. For this purpose, as shown in FIG. 4, a glass cloth 1 wound into a roll is placed in an electric furnace 7 and
The binder is burned off at 450° C. for 24 to 72 hours. This method consumes a huge amount of energy and has extremely low productivity.
本発明は上記事情に鑑みて為されたものであり、その目
的とするところは、積層板の製造方法においてがラスク
ロスのバインダーを短時間で確実に除去でき、生産性を
著しく高めることにある。The present invention has been made in view of the above circumstances, and its purpose is to make it possible to reliably remove the lath cross binder in a short time in a method for manufacturing a laminate, thereby significantly increasing productivity.
本発明の積層板の製造方法は、ガラスクロス１に樹脂ワ
ニスを含浸後乾燥させてプリプレグを形成し、このプリ
プレグを複数枚積層成形する４１１１／ｆ４板の製造方
法において、樹脂ワニスを含浸させる前にガラスクロス
１にプラズマ処理を施すことを特徴とするものであり、
この構成により上記目的が達成されたものである。即ち
、プラズマにより、バイングーが瞬時に破壊されるもの
である。
本発明において使用するガラスクロス１は従来と同じも
のであり、溶融原料を押し出し、澱粉、油脂などが配合
された有機組成物であるバイングーを使用して集束機で
束ねた後、紡糸され、織られて製造されたものである。
このガラスクロス１はロール状に巻取られ、第１図に示
すように巻戻されながら横型の処理室炉２内に通されろ
。処理室２内にはＣＦ４と０２の混合気体が充填されて
おり、減圧下、高周波パワーが与えられてプラズマが発
生しており、高励起状態にあるフリーラジカルによって
バイングーのＣ＝Ｃ結合が瞬時に破壊され、バイングー
が除去される。
混合気体中のＣＦ４と０２の体積比は１７１５〜２７３
で、高周波パワーは５００１ＩＩ〜ｌ０ＫＷ程度であり
、処理時間はＣＦ、と０□の体積比及び高周波パワーと
関係するが、通常５〜６０分である。このプラズマ処理
により分解揮散する（イ、０、ｉＦ、 Ｃｏ２は、高圧
水洗で除去できる。
このようにしてバイングーが除去されたガラスクロス１
には表面処理が施される。表面処理は、例えばシラン系
カンプリング剤により行う。このカップリング剤として
は、γ−アミ／プロピルトリエトキシシラン、Ｎ−（β
−７ミ／エチル）−γ−アミ７プロビルトリメトキシシ
ラン、Ｎ−（β−アミ／エチル）−γ−アミ／プロビル
メチルノメトキシシランなどの７ミノシラン系、γ−グ
リシドキシプロビルトリメトキシシラン、γ−メタクリ
ロキシプロピルトリメトキシシランなどのエポキシシラ
ン系、その他力チオニックシラン系、フェニルシラン系
など採用できる。この表面処理はカップリング剤３に浸
漬したり、第２図に示すようにコンベア４で搬送しなが
らスプレー５によりカップリング剤３を塗布し、この後
乾燥機６で乾燥させる。
このガラスクロス１は樹脂ワニス槽に浸漬され樹脂が含
浸され乾燥させてプリプレグが形成される。このように
して形成したプリプレグを複数枚積み重ねてその片面又
は両面に金Ｉｆ＆箔を重ねて、このものを−組として、
熱盤間に複数組み配置し、加熱加圧成形により一体化さ
せて積層板が製造される。
この積層板からは常法によりプリント配線板が製造され
る。例えば、サブトラクティブ法であれば、孔明け、活
性化処理、無電解銅めっき、スクリーン印刷、電解銅め
っき、電解半田めっき（エツチングレノスト）、めっき
レノスト剥離、エツチング、ヒユー７ング、ンルグーレ
ノスト印刷といった工程を経てプリント配線板が製ｉさ
れる。The method for manufacturing a laminate of the present invention is a method for manufacturing a 4111/f4 board in which a glass cloth 1 is impregnated with a resin varnish and then dried to form a prepreg, and a plurality of prepregs are laminated and molded. It is characterized by subjecting the glass cloth 1 to plasma treatment,
This configuration achieves the above object. That is, the banhgu is instantly destroyed by the plasma. The glass cloth 1 used in the present invention is the same as the conventional one, and is made by extruding a molten raw material, bundling it with a bundler using baingu, which is an organic composition containing starch, oil, etc., and then spinning and weaving it. It was manufactured using This glass cloth 1 is wound up into a roll and passed through a horizontal processing chamber furnace 2 while being unwound as shown in FIG. The processing chamber 2 is filled with a mixed gas of CF4 and 02, and high-frequency power is applied under reduced pressure to generate plasma, and the highly excited free radicals instantly break the C=C bond of banhgu. It is destroyed and Bangu is removed. The volume ratio of CF4 and 02 in the mixed gas is 1715-273
The high frequency power is about 5001 II to 10 KW, and the processing time is usually 5 to 60 minutes, although it is related to the volume ratio of CF to 0□ and the high frequency power. This plasma treatment decomposes and volatilizes (i, 0, iF, and Co2, which can be removed by high-pressure water washing.
is subjected to surface treatment. The surface treatment is performed using, for example, a silane camping agent. Coupling agents include γ-ami/propyltriethoxysilane, N-(β
7minosilanes such as -7mi/ethyl)-γ-ami7propyltrimethoxysilane, N-(β-ami/ethyl)-γ-amino/propylmethylnomethoxysilane, and γ-glycidoxypropylene. Epoxysilanes such as trimethoxysilane and γ-methacryloxypropyltrimethoxysilane, other thionic silanes, and phenylsilanes can be used. This surface treatment can be carried out by dipping it in a coupling agent 3, or by applying the coupling agent 3 with a spray 5 while conveying it on a conveyor 4 as shown in FIG. 2, and then drying it with a dryer 6. This glass cloth 1 is immersed in a resin varnish bath, impregnated with resin, and dried to form a prepreg. A plurality of prepregs formed in this way are stacked and gold If & foil is layered on one or both sides, and this is made into a set.
A laminate is manufactured by arranging a plurality of sets between hot platens and integrating them by heating and pressure forming. A printed wiring board is manufactured from this laminate by a conventional method. For example, subtractive methods include drilling, activation treatment, electroless copper plating, screen printing, electrolytic copper plating, electrolytic solder plating (etching lenses), plating stripping, etching, drying, etching printing, etc. A printed wiring board is manufactured through the steps.
本発明にあっては、ガラスクロスに樹脂ワニスを含浸後
乾燥させてプリプレグを形成し、このプリプレグを複数
枚積層成形するｆｆｆ層板の製造方法において、樹脂ワ
ニスを含浸させる前にガラスクロスにプラズマ処理を施
すので、プラズマにより、ガラスクロスのバイングーが
瞬時に破壊され、生産性が向上すると共に積層板におけ
るがラスクロスと樹脂との密着性が損なわれることがな
いものである。In the present invention, in the method for producing an fff laminate in which a glass cloth is impregnated with a resin varnish and then dried to form a prepreg, and a plurality of prepregs are laminated and molded, the glass cloth is heated with plasma before being impregnated with the resin varnish. Since the treatment is carried out, the glass cloth glass cloth is instantly destroyed by the plasma, which improves productivity and does not impair the adhesion between the glass cloth and the resin in the laminate.
ｆｊＳ１図は本発明の方法を実施するための装置の一例
を示す概略図、第２図はガラスクロスの表面処理工程を
実施するための装置の一例を示す概略図、第３図及び第
４図はそれぞれ従来の方法を実施するための装置を示す
概略図であって、１はガラスクロス、２は処理室である
。
代理人 弁理士 石 １）艮 七Fig. fjS1 is a schematic diagram showing an example of an apparatus for carrying out the method of the present invention, Fig. 2 is a schematic diagram showing an example of an apparatus for carrying out the surface treatment process of glass cloth, and Figs. 3 and 4. 1 and 2 are schematic diagrams showing apparatuses for carrying out conventional methods, respectively, in which 1 is a glass cloth and 2 is a processing chamber. Agent Patent Attorney Ishi 1) Ai Shichi
Claims (1)
リプレグを形成し、このプリプレグを複数枚積層成形す
る積層板の製造方法において、樹脂ワニスを含浸させる
前にガラスクロスにプラズマ処理を施すことを特徴とす
る積層板の製造方法。(1) In a method for manufacturing a laminate in which a glass cloth is impregnated with a resin varnish and then dried to form a prepreg, and a plurality of prepregs are laminated and molded, the glass cloth is subjected to plasma treatment before being impregnated with the resin varnish. Characteristic manufacturing method for laminates.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62158364A JPS641733A (en) | 1987-06-25 | 1987-06-25 | Production of laminated board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62158364A JPS641733A (en) | 1987-06-25 | 1987-06-25 | Production of laminated board |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH011733A true JPH011733A (en) | 1989-01-06 |
| JPS641733A JPS641733A (en) | 1989-01-06 |
Family
ID=15670067
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62158364A Pending JPS641733A (en) | 1987-06-25 | 1987-06-25 | Production of laminated board |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS641733A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5585147A (en) * | 1994-06-28 | 1996-12-17 | Matsushita Electric Works, Ltd. | Process for a surface treatment of a glass fabric |
| FR2899224B1 (en) * | 2006-03-31 | 2009-12-04 | Saint Gobain Vetrotex | METHOD FOR FUNCTIONALIZATION OF A GLAZED REINFORCEMENT FOR COMPOSITE MATERIAL |
-
1987
- 1987-06-25 JP JP62158364A patent/JPS641733A/en active Pending
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