JPH0117129B2 - - Google Patents
Info
- Publication number
- JPH0117129B2 JPH0117129B2 JP12254085A JP12254085A JPH0117129B2 JP H0117129 B2 JPH0117129 B2 JP H0117129B2 JP 12254085 A JP12254085 A JP 12254085A JP 12254085 A JP12254085 A JP 12254085A JP H0117129 B2 JPH0117129 B2 JP H0117129B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- acid
- groups
- itaconate
- methacrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 31
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 29
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 22
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 21
- 150000002148 esters Chemical class 0.000 claims description 20
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 17
- 125000003118 aryl group Chemical group 0.000 claims description 16
- 150000005846 sugar alcohols Polymers 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000001153 fluoro group Chemical group F* 0.000 claims description 3
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims 1
- -1 methoxyethoxyethoxycarbonyl Chemical group 0.000 description 25
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 14
- 125000005375 organosiloxane group Chemical group 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- 239000003054 catalyst Substances 0.000 description 10
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical compound [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- ZCYIYBNDJKVCBR-UHFFFAOYSA-N 2-prop-2-enoxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCC=C ZCYIYBNDJKVCBR-UHFFFAOYSA-N 0.000 description 8
- 229910052697 platinum Inorganic materials 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 150000005690 diesters Chemical class 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 230000035699 permeability Effects 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000000178 monomer Substances 0.000 description 5
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 description 4
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- WYGWHHGCAGTUCH-ISLYRVAYSA-N V-65 Substances CC(C)CC(C)(C#N)\N=N\C(C)(C#N)CC(C)C WYGWHHGCAGTUCH-ISLYRVAYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- DDJSWKLBKSLAAZ-UHFFFAOYSA-N cyclotetrasiloxane Chemical compound O1[SiH2]O[SiH2]O[SiH2]O[SiH2]1 DDJSWKLBKSLAAZ-UHFFFAOYSA-N 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- ZQMHJBXHRFJKOT-UHFFFAOYSA-N methyl 2-[(1-methoxy-2-methyl-1-oxopropan-2-yl)diazenyl]-2-methylpropanoate Chemical compound COC(=O)C(C)(C)N=NC(C)(C)C(=O)OC ZQMHJBXHRFJKOT-UHFFFAOYSA-N 0.000 description 3
- 239000012044 organic layer Substances 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000002861 polymer material Substances 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 description 3
- 150000005691 triesters Chemical class 0.000 description 3
- FCBZNZYQLJTCKR-UHFFFAOYSA-N 1-prop-2-enoxyethanol Chemical compound CC(O)OCC=C FCBZNZYQLJTCKR-UHFFFAOYSA-N 0.000 description 2
- ZNJXRXXJPIFFAO-UHFFFAOYSA-N 2,2,3,3,4,4,5,5-octafluoropentyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)C(F)(F)C(F)(F)C(F)F ZNJXRXXJPIFFAO-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- SEQXYBQFKAVTTO-UHFFFAOYSA-N 2-(3-trichlorosilylpropoxy)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCC[Si](Cl)(Cl)Cl SEQXYBQFKAVTTO-UHFFFAOYSA-N 0.000 description 2
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 2
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 description 2
- HCLJOFJIQIJXHS-UHFFFAOYSA-N 2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOCCOC(=O)C=C HCLJOFJIQIJXHS-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 238000005903 acid hydrolysis reaction Methods 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 2
- 239000005052 trichlorosilane Substances 0.000 description 2
- UHUUYVZLXJHWDV-UHFFFAOYSA-N trimethyl(methylsilyloxy)silane Chemical compound C[SiH2]O[Si](C)(C)C UHUUYVZLXJHWDV-UHFFFAOYSA-N 0.000 description 2
- FMQPBWHSNCRVQJ-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-yl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C(F)(F)F)C(F)(F)F FMQPBWHSNCRVQJ-UHFFFAOYSA-N 0.000 description 1
- MNSWITGNWZSAMC-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-yl prop-2-enoate Chemical compound FC(F)(F)C(C(F)(F)F)OC(=O)C=C MNSWITGNWZSAMC-UHFFFAOYSA-N 0.000 description 1
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 1
- VDYWHVQKENANGY-UHFFFAOYSA-N 1,3-Butyleneglycol dimethacrylate Chemical compound CC(=C)C(=O)OC(C)CCOC(=O)C(C)=C VDYWHVQKENANGY-UHFFFAOYSA-N 0.000 description 1
- QTKPMCIBUROOGY-UHFFFAOYSA-N 2,2,2-trifluoroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)F QTKPMCIBUROOGY-UHFFFAOYSA-N 0.000 description 1
- VBHXIMACZBQHPX-UHFFFAOYSA-N 2,2,2-trifluoroethyl prop-2-enoate Chemical compound FC(F)(F)COC(=O)C=C VBHXIMACZBQHPX-UHFFFAOYSA-N 0.000 description 1
- CLISWDZSTWQFNX-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)C(F)(F)F CLISWDZSTWQFNX-UHFFFAOYSA-N 0.000 description 1
- JDVGNKIUXZQTFD-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropyl prop-2-enoate Chemical compound FC(F)(F)C(F)(F)COC(=O)C=C JDVGNKIUXZQTFD-UHFFFAOYSA-N 0.000 description 1
- VIEHKBXCWMMOOU-UHFFFAOYSA-N 2,2,3,3,4,4,4-heptafluorobutyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)C(F)(F)C(F)(F)F VIEHKBXCWMMOOU-UHFFFAOYSA-N 0.000 description 1
- PLXOUIVCSUBZIX-UHFFFAOYSA-N 2,2,3,3,4,4,4-heptafluorobutyl prop-2-enoate Chemical compound FC(F)(F)C(F)(F)C(F)(F)COC(=O)C=C PLXOUIVCSUBZIX-UHFFFAOYSA-N 0.000 description 1
- YSQGYEYXKXGAQA-UHFFFAOYSA-N 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyl prop-2-enoate Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)COC(=O)C=C YSQGYEYXKXGAQA-UHFFFAOYSA-N 0.000 description 1
- RSVZYSKAPMBSMY-UHFFFAOYSA-N 2,2,3,3-tetrafluoropropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)C(F)F RSVZYSKAPMBSMY-UHFFFAOYSA-N 0.000 description 1
- OOHZIRUJZFRULE-UHFFFAOYSA-N 2,2-dimethylpropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(C)(C)C OOHZIRUJZFRULE-UHFFFAOYSA-N 0.000 description 1
- IJLJDZOLZATUFK-UHFFFAOYSA-N 2,2-dimethylpropyl prop-2-enoate Chemical compound CC(C)(C)COC(=O)C=C IJLJDZOLZATUFK-UHFFFAOYSA-N 0.000 description 1
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- OLQFXOWPTQTLDP-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCO OLQFXOWPTQTLDP-UHFFFAOYSA-N 0.000 description 1
- RWXMAAYKJDQVTF-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl prop-2-enoate Chemical compound OCCOCCOC(=O)C=C RWXMAAYKJDQVTF-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- PFHOSZAOXCYAGJ-UHFFFAOYSA-N 2-[(2-cyano-4-methoxy-4-methylpentan-2-yl)diazenyl]-4-methoxy-2,4-dimethylpentanenitrile Chemical compound COC(C)(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)(C)OC PFHOSZAOXCYAGJ-UHFFFAOYSA-N 0.000 description 1
- MZGMQAMKOBOIDR-UHFFFAOYSA-N 2-[2-(2-hydroxyethoxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCO MZGMQAMKOBOIDR-UHFFFAOYSA-N 0.000 description 1
- VETIYACESIPJSO-UHFFFAOYSA-N 2-[2-(2-hydroxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound OCCOCCOCCOC(=O)C=C VETIYACESIPJSO-UHFFFAOYSA-N 0.000 description 1
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 1
- LTHJXDSHSVNJKG-UHFFFAOYSA-N 2-[2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOCCOC(=O)C(C)=C LTHJXDSHSVNJKG-UHFFFAOYSA-N 0.000 description 1
- LOFVSJNCUNFRBZ-UHFFFAOYSA-N 2-[3-(2,4,4,6,6,8,8-heptamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocan-2-yl)propoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCC[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 LOFVSJNCUNFRBZ-UHFFFAOYSA-N 0.000 description 1
- DWBHKNHMULUVLM-UHFFFAOYSA-N 2-[3-(2,4,4,6,6,8,8-heptamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocan-2-yl)propoxy]ethyl prop-2-enoate Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(CCCOCCOC(=O)C=C)O[Si](C)(C)O1 DWBHKNHMULUVLM-UHFFFAOYSA-N 0.000 description 1
- KIDMRVDYDFQLRW-UHFFFAOYSA-N 2-[3-(2,4,4,6-tetramethyl-6,8,8-tripropyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocan-2-yl)propoxy]ethyl 2-methylprop-2-enoate Chemical compound CCC[Si]1(C)O[Si](C)(C)O[Si](C)(CCCOCCOC(=O)C(C)=C)O[Si](CCC)(CCC)O1 KIDMRVDYDFQLRW-UHFFFAOYSA-N 0.000 description 1
- ZDYFQCBKPMLJGH-UHFFFAOYSA-N 2-[3-(2,4,4,6-tetramethyl-6,8,8-tripropyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocan-2-yl)propoxy]ethyl prop-2-enoate Chemical compound CCC[Si]1(C)O[Si](C)(C)O[Si](C)(CCCOCCOC(=O)C=C)O[Si](CCC)(CCC)O1 ZDYFQCBKPMLJGH-UHFFFAOYSA-N 0.000 description 1
- JPZQHXPCLLMMEE-UHFFFAOYSA-N 2-[3-(methyl-phenyl-trimethylsilyloxysilyl)propoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCC[Si](C)(O[Si](C)(C)C)C1=CC=CC=C1 JPZQHXPCLLMMEE-UHFFFAOYSA-N 0.000 description 1
- QUFHGOPBRXWLPV-UHFFFAOYSA-N 2-[3-(methyl-phenyl-trimethylsilyloxysilyl)propoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCC[Si](C)(O[Si](C)(C)C)C1=CC=CC=C1 QUFHGOPBRXWLPV-UHFFFAOYSA-N 0.000 description 1
- IJBCHZAIEFCSJQ-UHFFFAOYSA-N 2-[3-[[[dimethyl(trimethylsilyloxy)silyl]oxy-dimethylsilyl]oxy-methyl-phenylsilyl]propoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCC[Si](C)(O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C)C1=CC=CC=C1 IJBCHZAIEFCSJQ-UHFFFAOYSA-N 0.000 description 1
- GJQPUDBTTKPFQR-UHFFFAOYSA-N 2-[3-[[dimethyl(trimethylsilyloxy)silyl]oxy-dimethylsilyl]propoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCC[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C GJQPUDBTTKPFQR-UHFFFAOYSA-N 0.000 description 1
- ZWKZTILIRRPWSK-UHFFFAOYSA-N 2-[3-[[dimethyl(trimethylsilyloxy)silyl]oxy-dimethylsilyl]propoxy]ethyl prop-2-enoate Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)CCCOCCOC(=O)C=C ZWKZTILIRRPWSK-UHFFFAOYSA-N 0.000 description 1
- WJMZTAHWABUYEE-UHFFFAOYSA-N 2-[3-[[dimethyl(trimethylsilyloxy)silyl]oxy-dipropylsilyl]propoxy]ethyl 2-methylprop-2-enoate Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](CCC)(CCC)CCCOCCOC(=O)C(C)=C WJMZTAHWABUYEE-UHFFFAOYSA-N 0.000 description 1
- LDOQTSPCDHBTNE-UHFFFAOYSA-N 2-[3-[[dimethyl(trimethylsilyloxy)silyl]oxy-dipropylsilyl]propoxy]ethyl prop-2-enoate Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](CCC)(CCC)CCCOCCOC(=O)C=C LDOQTSPCDHBTNE-UHFFFAOYSA-N 0.000 description 1
- VCEMDGWSPNMWJI-UHFFFAOYSA-N 2-[3-[dimethyl(trimethylsilyloxy)silyl]propoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCC[Si](C)(C)O[Si](C)(C)C VCEMDGWSPNMWJI-UHFFFAOYSA-N 0.000 description 1
- HWDSLOGOCOOOBI-UHFFFAOYSA-N 2-[3-[dimethyl(trimethylsilyloxy)silyl]propoxy]ethyl prop-2-enoate Chemical compound C[Si](C)(C)O[Si](C)(C)CCCOCCOC(=O)C=C HWDSLOGOCOOOBI-UHFFFAOYSA-N 0.000 description 1
- VZOFRWAWUHSXOR-UHFFFAOYSA-N 2-[3-[methyl-(2-methylpropyl)-trimethylsilyloxysilyl]propoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(C)C[Si](C)(O[Si](C)(C)C)CCCOCCOC(=O)C(C)=C VZOFRWAWUHSXOR-UHFFFAOYSA-N 0.000 description 1
- OCVBTGVFALKZLL-UHFFFAOYSA-N 2-[3-[methyl-(2-methylpropyl)-trimethylsilyloxysilyl]propoxy]ethyl prop-2-enoate Chemical compound CC(C)C[Si](C)(O[Si](C)(C)C)CCCOCCOC(=O)C=C OCVBTGVFALKZLL-UHFFFAOYSA-N 0.000 description 1
- HVNKAOZRKOCPDJ-UHFFFAOYSA-N 2-[3-[methyl-bis(trimethylsilyloxy)silyl]propoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C HVNKAOZRKOCPDJ-UHFFFAOYSA-N 0.000 description 1
- FQNKYQCIFNCQHT-UHFFFAOYSA-N 2-[3-tris(trimethylsilyloxy)silylpropoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)O[Si](C)(C)C FQNKYQCIFNCQHT-UHFFFAOYSA-N 0.000 description 1
- QCAKNOJNDONVPI-UHFFFAOYSA-N 2-[3-tris(trimethylsilyloxy)silylpropoxy]ethyl prop-2-enoate Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)CCCOCCOC(=O)C=C QCAKNOJNDONVPI-UHFFFAOYSA-N 0.000 description 1
- QKUVHYMCTPIYHI-UHFFFAOYSA-N 2-[3-tris[[cyclohexyl(dimethyl)silyl]oxy]silylpropoxy]ethyl 2-methylprop-2-enoate Chemical compound C1CCCCC1[Si](C)(C)O[Si](O[Si](C)(C)C1CCCCC1)(CCCOCCOC(=O)C(=C)C)O[Si](C)(C)C1CCCCC1 QKUVHYMCTPIYHI-UHFFFAOYSA-N 0.000 description 1
- YWNHLAAYWCFDCQ-UHFFFAOYSA-N 2-[3-tris[[cyclohexyl(dimethyl)silyl]oxy]silylpropoxy]ethyl prop-2-enoate Chemical compound C1CCCCC1[Si](C)(C)O[Si](CCCOCCOC(=O)C=C)(O[Si](C)(C)C1CCCCC1)O[Si](C)(C)C1CCCCC1 YWNHLAAYWCFDCQ-UHFFFAOYSA-N 0.000 description 1
- AOHRINJAARPYIU-UHFFFAOYSA-N 2-[chloro(dimethyl)silyl]ethyl acetate Chemical compound CC(=O)OCC[Si](C)(C)Cl AOHRINJAARPYIU-UHFFFAOYSA-N 0.000 description 1
- KGQJXTALQVMOHW-UHFFFAOYSA-N 2-ethenylphenol;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.OC1=CC=CC=C1C=C KGQJXTALQVMOHW-UHFFFAOYSA-N 0.000 description 1
- DHHJAIQLOYJBKG-UHFFFAOYSA-N 2-ethenylphenol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC1=CC=CC=C1C=C DHHJAIQLOYJBKG-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- IEVADDDOVGMCSI-UHFFFAOYSA-N 2-hydroxybutyl 2-methylprop-2-enoate Chemical compound CCC(O)COC(=O)C(C)=C IEVADDDOVGMCSI-UHFFFAOYSA-N 0.000 description 1
- NJRHMGPRPPEGQL-UHFFFAOYSA-N 2-hydroxybutyl prop-2-enoate Chemical compound CCC(O)COC(=O)C=C NJRHMGPRPPEGQL-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- VHSHLMUCYSAUQU-UHFFFAOYSA-N 2-hydroxypropyl methacrylate Chemical compound CC(O)COC(=O)C(C)=C VHSHLMUCYSAUQU-UHFFFAOYSA-N 0.000 description 1
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 description 1
- TVWBTVJBDFTVOW-UHFFFAOYSA-N 2-methyl-1-(2-methylpropylperoxy)propane Chemical compound CC(C)COOCC(C)C TVWBTVJBDFTVOW-UHFFFAOYSA-N 0.000 description 1
- HBZFBSFGXQBQTB-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F HBZFBSFGXQBQTB-UHFFFAOYSA-N 0.000 description 1
- IATDMJFAERWMOM-UHFFFAOYSA-N 3-(2,2,2-trifluoroethoxycarbonyl)but-3-enoic acid Chemical compound OC(=O)CC(=C)C(=O)OCC(F)(F)F IATDMJFAERWMOM-UHFFFAOYSA-N 0.000 description 1
- ZXYBIZDQLNBZSB-UHFFFAOYSA-N 3-(2,2,3,3,4,4,5,5-octafluoropentoxycarbonyl)but-3-enoic acid Chemical compound OC(=O)CC(=C)C(=O)OCC(F)(F)C(F)(F)C(F)(F)C(F)F ZXYBIZDQLNBZSB-UHFFFAOYSA-N 0.000 description 1
- JCXBZBWDDDEWRF-UHFFFAOYSA-N 3-(2,2,3,3-tetrafluoropropoxycarbonyl)but-3-enoic acid Chemical compound OC(=O)CC(=C)C(=O)OCC(F)(F)C(F)F JCXBZBWDDDEWRF-UHFFFAOYSA-N 0.000 description 1
- ODQFUOWWSROVEB-UHFFFAOYSA-N 3-(2,2-dimethylpropoxycarbonyl)but-3-enoic acid Chemical compound CC(C)(C)COC(=O)C(=C)CC(O)=O ODQFUOWWSROVEB-UHFFFAOYSA-N 0.000 description 1
- WFGDTJSCHCKYOK-UHFFFAOYSA-N 3-(2-ethylhexoxycarbonyl)but-3-enoic acid Chemical compound CCCCC(CC)COC(=O)C(=C)CC(O)=O WFGDTJSCHCKYOK-UHFFFAOYSA-N 0.000 description 1
- NQHWGQCRGNOLOD-UHFFFAOYSA-N 3-cyclohexyloxycarbonylbut-3-enoic acid Chemical compound OC(=O)CC(=C)C(=O)OC1CCCCC1 NQHWGQCRGNOLOD-UHFFFAOYSA-N 0.000 description 1
- ZPLGXBYERWJZGM-UHFFFAOYSA-N 3-hexoxycarbonylbut-3-enoic acid Chemical compound CCCCCCOC(=O)C(=C)CC(O)=O ZPLGXBYERWJZGM-UHFFFAOYSA-N 0.000 description 1
- RTIRICWZVNTCND-UHFFFAOYSA-N 3-pentoxycarbonylbut-3-enoic acid Chemical compound CCCCCOC(=O)C(=C)CC(O)=O RTIRICWZVNTCND-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- FQMIAEWUVYWVNB-UHFFFAOYSA-N 3-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OC(C)CCOC(=O)C=C FQMIAEWUVYWVNB-UHFFFAOYSA-N 0.000 description 1
- YMKQWPNHRBIWBT-UHFFFAOYSA-N 3-propan-2-yloxycarbonylbut-3-enoic acid Chemical compound CC(C)OC(=O)C(=C)CC(O)=O YMKQWPNHRBIWBT-UHFFFAOYSA-N 0.000 description 1
- NEAHVGRDHLQWPP-UHFFFAOYSA-N 3-propoxycarbonylbut-3-enoic acid Chemical compound CCCOC(=O)C(=C)CC(O)=O NEAHVGRDHLQWPP-UHFFFAOYSA-N 0.000 description 1
- XOJWAAUYNWGQAU-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCOC(=O)C(C)=C XOJWAAUYNWGQAU-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- VVAAYFMMXYRORI-UHFFFAOYSA-N 4-butoxy-2-methylidene-4-oxobutanoic acid Chemical compound CCCCOC(=O)CC(=C)C(O)=O VVAAYFMMXYRORI-UHFFFAOYSA-N 0.000 description 1
- RTTAGBVNSDJDTE-UHFFFAOYSA-N 4-ethoxy-2-methylidene-4-oxobutanoic acid Chemical compound CCOC(=O)CC(=C)C(O)=O RTTAGBVNSDJDTE-UHFFFAOYSA-N 0.000 description 1
- OIYTYGOUZOARSH-UHFFFAOYSA-N 4-methoxy-2-methylidene-4-oxobutanoic acid Chemical compound COC(=O)CC(=C)C(O)=O OIYTYGOUZOARSH-UHFFFAOYSA-N 0.000 description 1
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 description 1
- ZLQGITSKRNWIOT-UHFFFAOYSA-N 5-(dimethylamino)furan-2-carbaldehyde Chemical compound CN(C)C1=CC=C(C=O)O1 ZLQGITSKRNWIOT-UHFFFAOYSA-N 0.000 description 1
- SAPGBCWOQLHKKZ-UHFFFAOYSA-N 6-(2-methylprop-2-enoyloxy)hexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCOC(=O)C(C)=C SAPGBCWOQLHKKZ-UHFFFAOYSA-N 0.000 description 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229910015900 BF3 Inorganic materials 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- ICMSFQYICLGHOF-UHFFFAOYSA-N C(C(=C)C)(=O)OCCOCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)CCCCC Chemical compound C(C(=C)C)(=O)OCCOCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)CCCCC ICMSFQYICLGHOF-UHFFFAOYSA-N 0.000 description 1
- VWWRPIROJGBKPR-UHFFFAOYSA-N C(C(=C)C)(=O)OCCOCCC[Si](O[Si](CC1=CC=CC=C1)(CC1=CC=CC=C1)CC1=CC=CC=C1)(CC)CC Chemical compound C(C(=C)C)(=O)OCCOCCC[Si](O[Si](CC1=CC=CC=C1)(CC1=CC=CC=C1)CC1=CC=CC=C1)(CC)CC VWWRPIROJGBKPR-UHFFFAOYSA-N 0.000 description 1
- KXPNCSLALVCIIL-UHFFFAOYSA-N C(C(=C)C)(=O)OCCOCCC[Si](O[Si](CCC(=O)O)(C)C)(O[Si](CCC(=O)O)(C)C)O[Si](C)(C)CCC(=O)O Chemical compound C(C(=C)C)(=O)OCCOCCC[Si](O[Si](CCC(=O)O)(C)C)(O[Si](CCC(=O)O)(C)C)O[Si](C)(C)CCC(=O)O KXPNCSLALVCIIL-UHFFFAOYSA-N 0.000 description 1
- KOJIPWZZNAGREI-UHFFFAOYSA-N C(C=C)(=O)OCCOCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)CCCCC Chemical compound C(C=C)(=O)OCCOCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)CCCCC KOJIPWZZNAGREI-UHFFFAOYSA-N 0.000 description 1
- XGNAEHMQJQAFNE-UHFFFAOYSA-N C(C=C)(=O)OCCOCCC[Si](O[Si](CC1=CC=CC=C1)(CC1=CC=CC=C1)CC1=CC=CC=C1)(CC)CC Chemical compound C(C=C)(=O)OCCOCCC[Si](O[Si](CC1=CC=CC=C1)(CC1=CC=CC=C1)CC1=CC=CC=C1)(CC)CC XGNAEHMQJQAFNE-UHFFFAOYSA-N 0.000 description 1
- BCAJUCSKCNRGPJ-UHFFFAOYSA-N CC(=C)C(=O)OCCOCCC[Si](O[SiH2]C(O[Si](C)(C)C)O[Si](C)(C)C)(O[SiH2]C(O[Si](C)(C)C)O[Si](C)(C)C)O[Si](CCCOCCOC(=O)C(=C)C)(O[SiH2]C(O[Si](C)(C)C)O[Si](C)(C)C)O[SiH2]C(O[Si](C)(C)C)O[Si](C)(C)C Chemical compound CC(=C)C(=O)OCCOCCC[Si](O[SiH2]C(O[Si](C)(C)C)O[Si](C)(C)C)(O[SiH2]C(O[Si](C)(C)C)O[Si](C)(C)C)O[Si](CCCOCCOC(=O)C(=C)C)(O[SiH2]C(O[Si](C)(C)C)O[Si](C)(C)C)O[SiH2]C(O[Si](C)(C)C)O[Si](C)(C)C BCAJUCSKCNRGPJ-UHFFFAOYSA-N 0.000 description 1
- UBIKCLBZCAHUPT-UHFFFAOYSA-N CC(=C)C(=O)OCCOCCC[Si](O[Si](C)(C)CCOC(=O)C)(O[Si](C)(C)CCOC(=O)C)O[Si](C)(C)CCOC(=O)C Chemical compound CC(=C)C(=O)OCCOCCC[Si](O[Si](C)(C)CCOC(=O)C)(O[Si](C)(C)CCOC(=O)C)O[Si](C)(C)CCOC(=O)C UBIKCLBZCAHUPT-UHFFFAOYSA-N 0.000 description 1
- WHURLXPGXRAXOZ-UHFFFAOYSA-N CC(=C)C(=O)OCCOCCC[Si](O[Si](C)(C)CCOC(=O)C)(O[Si](C)(C)CCOC(=O)C)O[Si](CCCOCCOC(=O)C(=C)C)(O[Si](C)(C)CCOC(=O)C)O[Si](C)(C)CCOC(=O)C Chemical compound CC(=C)C(=O)OCCOCCC[Si](O[Si](C)(C)CCOC(=O)C)(O[Si](C)(C)CCOC(=O)C)O[Si](CCCOCCOC(=O)C(=C)C)(O[Si](C)(C)CCOC(=O)C)O[Si](C)(C)CCOC(=O)C WHURLXPGXRAXOZ-UHFFFAOYSA-N 0.000 description 1
- RQMJXMXUBKSSLW-UHFFFAOYSA-N CC(OCCC[Si](C)(CCC(=O)OC(C)(C)OC(=O)C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C)OC(=O)C(=C)C Chemical compound CC(OCCC[Si](C)(CCC(=O)OC(C)(C)OC(=O)C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C)OC(=O)C(=C)C RQMJXMXUBKSSLW-UHFFFAOYSA-N 0.000 description 1
- RZAQZNHGIVXEIO-UHFFFAOYSA-N CC(OCCC[Si](C)(CCCOC(=O)C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C)OC(=O)C(=C)C Chemical compound CC(OCCC[Si](C)(CCCOC(=O)C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C)OC(=O)C(=C)C RZAQZNHGIVXEIO-UHFFFAOYSA-N 0.000 description 1
- CYLIIGWAJTWRGO-UHFFFAOYSA-N C[SiH2]O[SiH](C)C(CCCOCCOC(=O)C=C)(CCCOCCOC(=O)C=C)CCCOCCOC(=O)C=C Chemical compound C[SiH2]O[SiH](C)C(CCCOCCOC(=O)C=C)(CCCOCCOC(=O)C=C)CCCOCCOC(=O)C=C CYLIIGWAJTWRGO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- LXLAVQONMQHKTQ-UHFFFAOYSA-N OC(=O)CC(=C)C(=O)OC(C(F)(F)F)C(F)(F)F Chemical compound OC(=O)CC(=C)C(=O)OC(C(F)(F)F)C(F)(F)F LXLAVQONMQHKTQ-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 239000007877 V-601 Substances 0.000 description 1
- YTEISYFNYGDBRV-UHFFFAOYSA-N [(dimethyl-$l^{3}-silanyl)oxy-dimethylsilyl]oxy-dimethylsilicon Chemical compound C[Si](C)O[Si](C)(C)O[Si](C)C YTEISYFNYGDBRV-UHFFFAOYSA-N 0.000 description 1
- ULQMPOIOSDXIGC-UHFFFAOYSA-N [2,2-dimethyl-3-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(C)(C)COC(=O)C(C)=C ULQMPOIOSDXIGC-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- DTLYZSJVEDZWQX-UHFFFAOYSA-N bis(2,2-dimethylpropyl) 2-methylidenebutanedioate Chemical compound CC(C)(C)COC(=O)CC(=C)C(=O)OCC(C)(C)C DTLYZSJVEDZWQX-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- OGVXYCDTRMDYOG-UHFFFAOYSA-N dibutyl 2-methylidenebutanedioate Chemical compound CCCCOC(=O)CC(=C)C(=O)OCCCC OGVXYCDTRMDYOG-UHFFFAOYSA-N 0.000 description 1
- GFHMGSFDHKDJSG-UHFFFAOYSA-N dicyclohexyl 2-methylidenebutanedioate Chemical compound C1CCCCC1OC(=O)C(=C)CC(=O)OC1CCCCC1 GFHMGSFDHKDJSG-UHFFFAOYSA-N 0.000 description 1
- ZEFVHSWKYCYFFL-UHFFFAOYSA-N diethyl 2-methylidenebutanedioate Chemical compound CCOC(=O)CC(=C)C(=O)OCC ZEFVHSWKYCYFFL-UHFFFAOYSA-N 0.000 description 1
- MHAOABLQRSMPKK-UHFFFAOYSA-N dihexyl 2-methylidenebutanedioate Chemical compound CCCCCCOC(=O)CC(=C)C(=O)OCCCCCC MHAOABLQRSMPKK-UHFFFAOYSA-N 0.000 description 1
- ZWWQRMFIZFPUAA-UHFFFAOYSA-N dimethyl 2-methylidenebutanedioate Chemical compound COC(=O)CC(=C)C(=O)OC ZWWQRMFIZFPUAA-UHFFFAOYSA-N 0.000 description 1
- NJCKCUVRQPTKTF-UHFFFAOYSA-N dipentyl 2-methylidenebutanedioate Chemical compound CCCCCOC(=O)CC(=C)C(=O)OCCCCC NJCKCUVRQPTKTF-UHFFFAOYSA-N 0.000 description 1
- IJBBERPAEBYDJT-UHFFFAOYSA-N dipropan-2-yl 2-methylidenebutanedioate Chemical compound CC(C)OC(=O)CC(=C)C(=O)OC(C)C IJBBERPAEBYDJT-UHFFFAOYSA-N 0.000 description 1
- DFQSWFGKYUFIFW-UHFFFAOYSA-N dipropyl 2-methylidenebutanedioate Chemical compound CCCOC(=O)CC(=C)C(=O)OCCC DFQSWFGKYUFIFW-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
- GYDSPAVLTMAXHT-UHFFFAOYSA-N pentyl 2-methylprop-2-enoate Chemical compound CCCCCOC(=O)C(C)=C GYDSPAVLTMAXHT-UHFFFAOYSA-N 0.000 description 1
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical compound CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical compound C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Eyeglasses (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12254085A JPS61281116A (ja) | 1985-06-07 | 1985-06-07 | コンタクトレンズ材料 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12254085A JPS61281116A (ja) | 1985-06-07 | 1985-06-07 | コンタクトレンズ材料 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61281116A JPS61281116A (ja) | 1986-12-11 |
| JPH0117129B2 true JPH0117129B2 (enrdf_load_stackoverflow) | 1989-03-29 |
Family
ID=14838392
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12254085A Granted JPS61281116A (ja) | 1985-06-07 | 1985-06-07 | コンタクトレンズ材料 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61281116A (enrdf_load_stackoverflow) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5162391A (en) * | 1989-03-10 | 1992-11-10 | Kuraray Co., Ltd. | Oxygen permeable hard contact lens |
| JP4524838B2 (ja) * | 2000-02-07 | 2010-08-18 | 東レ株式会社 | 眼用レンズ |
| ATE433455T1 (de) | 2001-03-30 | 2009-06-15 | Johnson & Johnson Vision Care | Monomer, polymer und jeweils daraus erhaltene okularlinse und kontaktlinse |
| WO2002081532A1 (fr) * | 2001-03-30 | 2002-10-17 | Johnson & Johnson Vision Care, Inc. | Monomeres, polymeres, lentilles ophtalmiques et lentilles de contact fabriquees a l'aide de ces derniers |
| EP1424339A4 (en) * | 2001-08-06 | 2006-08-02 | Johson & Johnson Vision Care I | MONOMERS, POLYMERS AND OPHTHALMIC LENSES |
| US7193023B2 (en) | 2003-12-04 | 2007-03-20 | International Business Machines Corporation | Low activation energy photoresists |
| US7820369B2 (en) | 2003-12-04 | 2010-10-26 | International Business Machines Corporation | Method for patterning a low activation energy photoresist |
| JP5365024B2 (ja) * | 2008-02-19 | 2013-12-11 | 東亞合成株式会社 | シリコーン系グラフト共重合体およびその製造方法 |
| JP2020090580A (ja) * | 2018-12-04 | 2020-06-11 | 信越化学工業株式会社 | ω末端にポリアルキレンオキシド基を有する片末端メタクリル変性オルガノ（ポリ）シロキサン及びその製造方法。 |
-
1985
- 1985-06-07 JP JP12254085A patent/JPS61281116A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61281116A (ja) | 1986-12-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0120408B2 (enrdf_load_stackoverflow) | ||
| US4602074A (en) | Contact lens material | |
| EP0016138B1 (en) | Hydrophilic, soft and oxygen permeable copolymer compositions | |
| JP2894711B2 (ja) | フッ化ポリシロキサン含有組成物 | |
| USRE31406E (en) | Oxygen permeable contact lens composition, methods and article of manufacture | |
| GB2152522A (en) | Contact lens materials | |
| KR20020016922A (ko) | 콘택트 렌즈 재료 | |
| IE62535B1 (en) | Continuous-wear lenses having improved physical properties | |
| GB2117387A (en) | Silicone-containing contact lens material and contact lenses made thereof | |
| JP4144088B2 (ja) | コンタクトレンズ用ポリマーおよびそれを用いたコンタクトレンズ | |
| JPH0117129B2 (enrdf_load_stackoverflow) | ||
| EP0194277A1 (en) | Alkylsilane contact lens and polymer | |
| JPH0160125B2 (enrdf_load_stackoverflow) | ||
| JP2000191730A (ja) | 眼用レンズ用モノマー、眼用レンズ用ポリマーおよびそれを用いたコンタクトレンズ | |
| JPH0160124B2 (enrdf_load_stackoverflow) | ||
| JPH0117128B2 (enrdf_load_stackoverflow) | ||
| JPH0515724B2 (enrdf_load_stackoverflow) | ||
| US4410674A (en) | Silicone-vinyl acetate composition for contact lenses | |
| JPH077157B2 (ja) | 酸素透過性コンタクトレンズ | |
| JP2000212154A (ja) | モノマ―およびそれを用いたポリマ―、プラスチック成形体 | |
| JPS6230613B2 (enrdf_load_stackoverflow) | ||
| WO1986004343A1 (en) | Extended-wear lenses | |
| JPH09221530A (ja) | 眼用レンズ材料 | |
| JPS6230612B2 (enrdf_load_stackoverflow) | ||
| JPH0632791A (ja) | ケイ素含有化合物 |