JPH01132343A - Food additive consisting of starch hydrolyzed saccharide - Google Patents

Food additive consisting of starch hydrolyzed saccharide

Info

Publication number
JPH01132343A
JPH01132343A JP62289696A JP28969687A JPH01132343A JP H01132343 A JPH01132343 A JP H01132343A JP 62289696 A JP62289696 A JP 62289696A JP 28969687 A JP28969687 A JP 28969687A JP H01132343 A JPH01132343 A JP H01132343A
Authority
JP
Japan
Prior art keywords
starch
saccharides
polymerization degree
sugars
food additive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62289696A
Other languages
Japanese (ja)
Other versions
JPH0464664B2 (en
Inventor
Yasuo Namikoshi
浪越 泰男
Yoichi Kinekawa
杵川 洋一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daiichi Kasei Co Ltd
Original Assignee
Daiichi Kasei Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daiichi Kasei Co Ltd filed Critical Daiichi Kasei Co Ltd
Priority to JP62289696A priority Critical patent/JPH01132343A/en
Publication of JPH01132343A publication Critical patent/JPH01132343A/en
Publication of JPH0464664B2 publication Critical patent/JPH0464664B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Fish Paste Products (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Meat, Egg Or Seafood Products (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

PURPOSE:To obtain a food additive excellent in improvement of texture, etc., by containing an adequate amount of a starch hydrolyzed saccharide, negative to iodine starch reaction, completely soluble in 50% ethanol and having a specific value of glucose polymerization degree. CONSTITUTION:Edible starch is saccharified by an acid or enzyme according to a conventional method. The kind of the acid and/or enzyme and other reaction condition are carefully selected or unnecessary parts of ordinary starch hydrolyzed saccharides are limited to specific physical properties by separation and purification, such as chromatography, to produce the above-mentioned starch hydrolyzed saccharide, preferably containing saccharides having <=3 glucose polymerization degree in the amount of <=25% based on the total constituent saccharides and saccharides having >=9 glucose polymerization degree in the total amount of <=30% based on the total constituent saccharides. Furthermore, the afore-mentioned starch hydrolyzed saccharide has the following characteristics. Negative to iodine starch reaction and completely soluble in 50% ethanol. The starch hydrolyzed saccharide having the above-mentioned characteristics is used to afford the aimed food additive.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は、畜肉・水産加工品の水分調整や食感改善など
に使用される、澱粉分解糖からなる食品添加剤に関する
DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a food additive made of starch-decomposed sugar, which is used to adjust the moisture content and improve the texture of processed meat and seafood products.

従来技術 従来より、食品、特に畜肉・水産加工品に、製品の水分
調整、水分活性の低下、離水防止、食感の改善等の目的
で澱粉分解糖(水あめ)を添加することは知られている
。しかし、従来の澱粉分解糖には、次のような問題があ
り、十分な使用は望めなかった。
Prior art It has been known for some time that starch-decomposing sugar (starch syrup) is added to foods, especially processed meat and seafood products, for the purpose of adjusting the moisture content of the product, reducing water activity, preventing syneresis, and improving texture. There is. However, conventional starch-decomposing sugars have the following problems, and cannot be expected to be used satisfactorily.

■ 沃素試薬を変色させ、澱粉を添加していると誤認さ
れる。
■ It causes the iodine reagent to change color and is mistaken for adding starch.

■ 50%エタノールに不溶の糖を含有しているため、
JAS澱粉定量法(畜肉ソーセージ等)で分析した場合
、澱粉として定量されてしまう。
■ Contains sugar that is insoluble in 50% ethanol,
When analyzed using the JAS starch determination method (livestock sausages, etc.), it is determined as starch.

■ 甘味が砂糖の20%以上あるため、多量に添加する
と製品が甘くなる。
■ The sweetness is more than 20% of sugar, so adding a large amount will make the product sweet.

■ 加熱により褐変しやすい。■ Easily browns when heated.

発明が解決しようとする問題点 本発明は、前述の如き、従来の澱粉分解糖の欠点を解消
し、食品加工において水分調整、固形物M調整、水分活
性の低下、離水の防止、保存性の向上、食感改善、歩留
まり向上環の目的で効果的に使用できる添加剤、特に加
熱により変色せず、また、甘味がほどんどなく、沃素試
薬やJAS澱粉定量法によっても澱粉として定量されな
い、澱粉分解糖からなる食品添加剤を提供することを目
的とする。
Problems to be Solved by the Invention The present invention solves the drawbacks of conventional starch-decomposing sugars as described above, and can be used in food processing to adjust moisture content, adjust solid matter M, reduce water activity, prevent syneresis, and improve preservability. Additives that can be effectively used for the purpose of improving texture, improving texture, and improving yield, especially starch that does not change color when heated, has little sweetness, and is not quantified as starch using an iodine reagent or JAS starch determination method. The purpose of the present invention is to provide a food additive made of decomposed sugar.

問題点を解決するための手段 本発明では、澱粉分解糖を特定の物性を有する範囲のも
のに限定して生産することによって、上記目的を達成し
た。
Means for Solving the Problems In the present invention, the above object has been achieved by limiting the production of starch decomposing sugars to those having specific physical properties.

即ち、本発明の食品添加剤は、澱粉分解糖であって、 a、グルコース重合度3以下の糖の合計が、全構成糖の
25%以下であり、 b、グルコース重合度9以上の糖の合計が、全構成等の
30%以下である、 C0沃素澱粉反応に陰性で、 d、50%エタノールに完全に溶解するという糖類から
なることを特徴とする。
That is, the food additive of the present invention is a starch-degrading sugar, and a) the total amount of sugars with a glucose polymerization degree of 3 or less is 25% or less of the total constituent sugars, and b) a sugar with a glucose polymerization degree of 9 or more It is characterized by being composed of saccharides, which make up 30% or less of the total composition, are negative for the C0 iodine starch reaction, and are completely soluble in 50% ethanol.

作用 このような本発明の食品添加剤は、グルコース重合度3
以下の糖が少量であるため、実質的に甘味を呈すること
なく、また加熱により褐変することもない。更に、グル
コース重合度9以上の糖も比較的少ないため、沃素試薬
と反応して、澱粉を含有すると誤認されることはなく、
畜肉ソーセージ等におけるJAS澱粉定量法で、澱粉と
して定量されることもな(、所望に応じて任意の量の添
加が可能となる。
Effect: The food additive of the present invention has a glucose polymerization degree of 3.
Since the amount of sugar below is small, it does not exhibit any sweet taste and does not turn brown when heated. Furthermore, since there are relatively few sugars with a glucose polymerization degree of 9 or higher, they will not react with the iodine reagent and be mistaken as containing starch.
It is not quantified as starch by the JAS starch determination method for meat sausages, etc. (but any amount can be added as desired).

本発明の食品添加剤は、例えば食用澱粉(コーン、ポテ
ト、小麦、タピオカ等)を、酸又は酵素で液化し、糖化
するという、通常の澱粉分解糖(水あめ)の製法に準じ
て製造できるが、直接製造する場合には、上記特性を有
する糖類が得られるように、酸及び/又は酵素の種類、
その他の反応条件を十分厳選して製造する必要がある。
The food additive of the present invention can be produced in accordance with the usual method for producing starch-decomposed sugar (starch syrup), for example, by liquefying edible starch (corn, potato, wheat, tapioca, etc.) with acid or enzymes and saccharifying it. , in the case of direct production, the type of acid and/or enzyme, so that saccharides with the above characteristics are obtained;
It is necessary to carefully select other reaction conditions during production.

また、通常の澱粉分解糖化物の不要部分をクロマト等の
分離精製して製造することもできる。
Moreover, it can also be produced by separating and purifying the unnecessary portions of ordinary starch decomposition and saccharification products using chromatography or the like.

なお、本発明で使用するI!類はグルコース重合度3以
下の糖の合計が全構成糖の25%以下、同重合度9以上
の糖の合計が全構成糖の30%以下であればよいが、グ
ルコース重合度3以下の糖の合計は全構成糖の20%以
下であるのが好ましく、また、同重合度9以上の糖の合
計は全構成糖の25%以下であるのが好ましい。
Note that I! used in the present invention! For class 2, the total amount of sugars with a degree of glucose polymerization of 3 or less is 25% or less of the total sugar composition, and the total amount of sugars with a degree of polymerization of 9 or more is 30% or less of the total sugars, but sugars with a degree of glucose polymerization of 3 or less It is preferable that the total amount of sugars is 20% or less of all the constituent sugars, and it is preferable that the sum of the sugars having a degree of polymerization of 9 or more is 25% or less of the total constituent sugars.

実施例1 コーンスターチを原料として、酵素法で下記の特性を有
する澱粉分解糖を製造した。
Example 1 A starch decomposed sugar having the following properties was produced by an enzymatic method using cornstarch as a raw material.

グルコース重合度3以下の糖の総量  20.2χグル
コ一ス重合度9以下の糖の総量  27.0χD E 
                20.4沃素澱粉反
応            陰性50%エタノール  
      完全溶解砂糖換算甘味         
   約15χ上記分解糖を試料Iとする。
Total amount of sugars with glucose polymerization degree of 3 or less 20.2χ Total amount of sugars with glucose polymerization degree of 9 or less 27.0χD E
20.4 Iodine starch reaction negative 50% ethanol
Completely dissolved sugar equivalent sweetness
About 15χ The above decomposed sugar is designated as Sample I.

この試料■を、下記の組成からなるソーセージ原料に、
5%添加してソーセージを製造した。
This sample ■ is used as a sausage raw material with the following composition.
Sausage was produced by adding 5%.

ソーセージ原料組成 豚ミンチ肉        60部 豚脂肪         25部 氷水          15部 食塩           1.6χ 砂It!            0 、5χ塩漬剤 
         0.4″A調味料        
  0.2χ 乳化剤          0.5χ 得られたソーセージの性状を、下記の市販澱粉分解糖(
従来品)を上記試料1の代わりに使用した結果と比較し
て第1表に記載する。
Sausage ingredients composition Minced pork 60 parts Pork fat 25 parts Ice water 15 parts Salt 1.6χ Sand It! 0, 5χ salting agent
0.4″A seasoning
0.2χ Emulsifier 0.5χ The properties of the obtained sausage were determined using the following commercially available starch-degrading sugar (
The results are shown in Table 1 in comparison with the results obtained when the conventional product) was used in place of Sample 1 above.

市販澱粉分解糖 グルコース重合度3以下の糖の総量  28.3χグル
コ一ス重合度9以下の糖の総量  32.8χDE  
、               23.1沃素澱粉反
応            陽性50%エタノール  
        白濁砂糖換算甘味         
   約22χ第1表 試験方法 水分     JAS法(畜肉ソーセージ)沃素反応 
  沃素試薬直接添加(+)−陽性(−)−陰性 澱粉定量   JAS法(畜肉ソーセージ)N、 D=
0.05%以下 食感・甘味  官能検査 加熱時の状態 フライパンで炒めた状態第1表の結果か
ら、従来の市販品の添加では、沃素澱粉反応が陽性とな
り、澱粉が定量され、甘味や焦げが認められるのに対し
て、本発明に従った試料Iの添加では、沃素澱粉反応は
陰性で、澱粉は定量されず、甘味も変化なく、加熱によ
り焦げも問題になるものではなかった。
Commercially available starch-degrading sugar Total amount of sugars with glucose polymerization degree of 3 or less 28.3χ Total amount of sugars with glucose polymerization degree of 9 or less 32.8χ DE
, 23.1 Iodine starch reaction positive 50% ethanol
Sweetness equivalent to cloudy sugar
Approximately 22χ Table 1 Test method Moisture JAS method (meat sausage) Iodine reaction
Direct addition of iodine reagent (+) - Positive (-) - Negative starch determination JAS method (meat sausage) N, D =
0.05% or less Texture/Sweetness Sensory test Condition when heated Condition stir-fried in a frying pan From the results in Table 1, when adding conventional commercially available products, the iodine starch reaction was positive, the starch was quantified, and sweetness and burntness were reduced. On the other hand, with the addition of Sample I according to the present invention, the iodine-starch reaction was negative, starch was not quantified, sweetness did not change, and burning caused by heating was not a problem.

発明の効果 本発明の製品は、食品加工時の副原料として、製品の水
分調整、固形物量調整、水分活性の低下、離水防止、保
存性の向上、食感の改善、歩留まり向上、等の目的で、
多量に添加することが可能であす、例えばハム・ソーセ
ージ・ベーコン・焼豚等の畜肉加工品や蒲鉾・竹輪等の
水産加工品に多量に添加しても、その風味を害すること
なく、規格に適合した製品を得ることができる。
Effects of the Invention The product of the present invention can be used as an auxiliary raw material during food processing to adjust the moisture content of the product, adjust the amount of solids, reduce water activity, prevent syneresis, improve preservability, improve texture, increase yield, etc. in,
It can be added in large amounts to processed meat products such as ham, sausage, bacon, roasted pork, etc., and processed seafood products such as kamaboko and chikuwa, without impairing the flavor and meeting the standards. You can get the product you want.

Claims (1)

【特許請求の範囲】[Claims] (1)澱粉分解糖であって、 a、グルコース重合度3以下の糖の合計が、全構成糖の
25%以下であり、 b、グルコース重合度9以上の糖の合計が、全構成糖の
30%以下である、 c、沃素澱粉反応に陰性で、 d、50%エタノールに完全に溶解する という特性を有する糖類からなることを特徴とする食品
添加剤。
(1) Starch-degrading sugars, in which a. The total of sugars with a glucose polymerization degree of 3 or less is 25% or less of the total constituent sugars, and b. The total of sugars with a glucose polymerization degree of 9 or higher is 25% or less of the total constituent sugars. A food additive comprising a saccharide having the following properties: 30% or less; c. negative for iodine-starch reaction; and d. completely soluble in 50% ethanol.
JP62289696A 1987-11-16 1987-11-16 Food additive consisting of starch hydrolyzed saccharide Granted JPH01132343A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62289696A JPH01132343A (en) 1987-11-16 1987-11-16 Food additive consisting of starch hydrolyzed saccharide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62289696A JPH01132343A (en) 1987-11-16 1987-11-16 Food additive consisting of starch hydrolyzed saccharide

Publications (2)

Publication Number Publication Date
JPH01132343A true JPH01132343A (en) 1989-05-24
JPH0464664B2 JPH0464664B2 (en) 1992-10-15

Family

ID=17746559

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62289696A Granted JPH01132343A (en) 1987-11-16 1987-11-16 Food additive consisting of starch hydrolyzed saccharide

Country Status (1)

Country Link
JP (1) JPH01132343A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL9401274A (en) * 1993-08-04 1995-03-01 Kortschack Fritz Process for ripening and drying raw sausages, hard sausages and the like in a vacuum-impermeable form or casing.
US5451850A (en) * 1991-10-16 1995-09-19 Fanuc Ltd. Method of correcting a position of a tool center point

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3654082A (en) * 1969-02-10 1972-04-04 Cpc International Inc Production of high maltotetraose syrup
JPS52148655A (en) * 1976-06-02 1977-12-10 Sugyo Kk Method of producing dried fish meat paste product
JPS563016A (en) * 1979-06-23 1981-01-13 Matsushita Electric Ind Co Ltd Controller for rice cooker
JPS59196072A (en) * 1983-04-18 1984-11-07 Sanwa Shoji Kk Production of food
JPS63240784A (en) * 1987-03-28 1988-10-06 Hayashibara Biochem Lab Inc Maltotetraose-producing amylase, its production and use thereof
JPS6439977A (en) * 1987-08-06 1989-02-10 Japan Maize Prod Production of water-soluble powder food

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3654082A (en) * 1969-02-10 1972-04-04 Cpc International Inc Production of high maltotetraose syrup
JPS52148655A (en) * 1976-06-02 1977-12-10 Sugyo Kk Method of producing dried fish meat paste product
JPS563016A (en) * 1979-06-23 1981-01-13 Matsushita Electric Ind Co Ltd Controller for rice cooker
JPS59196072A (en) * 1983-04-18 1984-11-07 Sanwa Shoji Kk Production of food
JPS63240784A (en) * 1987-03-28 1988-10-06 Hayashibara Biochem Lab Inc Maltotetraose-producing amylase, its production and use thereof
JPS6439977A (en) * 1987-08-06 1989-02-10 Japan Maize Prod Production of water-soluble powder food

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5451850A (en) * 1991-10-16 1995-09-19 Fanuc Ltd. Method of correcting a position of a tool center point
NL9401274A (en) * 1993-08-04 1995-03-01 Kortschack Fritz Process for ripening and drying raw sausages, hard sausages and the like in a vacuum-impermeable form or casing.

Also Published As

Publication number Publication date
JPH0464664B2 (en) 1992-10-15

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