JPH01130715A - Adsorption and desorption device - Google Patents

Adsorption and desorption device

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Publication number
JPH01130715A
JPH01130715A JP62289783A JP28978387A JPH01130715A JP H01130715 A JPH01130715 A JP H01130715A JP 62289783 A JP62289783 A JP 62289783A JP 28978387 A JP28978387 A JP 28978387A JP H01130715 A JPH01130715 A JP H01130715A
Authority
JP
Japan
Prior art keywords
desorption
solvent
gas
adsorption
activated carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62289783A
Other languages
Japanese (ja)
Other versions
JPH0369567B2 (en
Inventor
Hiroshi Murata
村田 廣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toho Chemical Engineering and Construction Co Ltd
Original Assignee
Toho Chemical Engineering and Construction Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toho Chemical Engineering and Construction Co Ltd filed Critical Toho Chemical Engineering and Construction Co Ltd
Priority to JP62289783A priority Critical patent/JPH01130715A/en
Publication of JPH01130715A publication Critical patent/JPH01130715A/en
Publication of JPH0369567B2 publication Critical patent/JPH0369567B2/ja
Granted legal-status Critical Current

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  • Separation Of Gases By Adsorption (AREA)

Abstract

PURPOSE:To prevent the cylinder mechanism from corrosion by disposing a desorbing gas discharge pipe under a three way change-over valve mechanism and a solvent contg. gas supply pipe above said valve, and changing-over adsorbing and desorbing operations by moving a valve plate with a cylinder rod. CONSTITUTION:A supplied solvent contg. gas is passed through an activated carbon layer 22 where the solvent is adsorbed, and is discharged as a clean gas from a clean gas discharge pipe 23 to the outside of the system. Then, in desorption, the valve plate 26 of the three way change-over mechanism 25 is lifted up by the cylinder rod 27, and the activated carbon layer 22 is desorbed by the heating gas supplied from a desorption gas supply pipe 24, and the desorption gas is discharged through the three way change-over mechanism 25. Thus, as the desorption gas of high temp. and high concn. is not brought into contact with the cylinder rod, the corrosion is prevented.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、活性炭を吸着材とした溶剤の吸脱着装dに関
するちのである。更に詳しくは、腐蝕の問題を生じるこ
とのない弁機構を備えた腐蝕性溶剤回収に好適に使用で
きる吸脱着装置に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a solvent adsorption/desorption device d using activated carbon as an adsorbent. More specifically, the present invention relates to an adsorption/desorption device that is equipped with a valve mechanism that does not cause corrosion problems and can be suitably used for recovering corrosive solvents.

〔従来技術と問題点〕[Conventional technology and problems]

従来、活性炭を吸@材として揮発性布a溶媒を回収する
装置が広く実用化されている。
BACKGROUND ART Conventionally, devices for recovering volatile cloth a solvent using activated carbon as an absorption material have been widely put into practical use.

この装置は、基本的には、活性炭を充填した吸着塔と、
この吸着塔に配管された有機溶剤含有ガスの供給・排出
管、および、脱着用水蒸気の供給・排出管からなり、切
り替え弁機構を介して吸着と脱着とを交互に行いつつ、
排出ガス中の有機溶媒を回収する機構になっている。こ
のような有機溶剤の回収装置としては、特開昭    
′52−120973号公報によって提案されたもの等
が知られている。
This equipment basically consists of an adsorption tower filled with activated carbon,
It consists of a supply/discharge pipe for organic solvent-containing gas and a supply/discharge pipe for water vapor for desorption, which are piped to this adsorption tower, and adsorption and desorption are performed alternately via a switching valve mechanism.
The mechanism is to recover organic solvents from exhaust gas. As a recovery device for such organic solvents,
The one proposed in '52-120973 is known.

従来の溶剤回収装置は、溶剤含有ガスの供給管と脱着ガ
ス排出管とを有し、配管を簡素化するために3方切り替
え弁機構を備えている。
A conventional solvent recovery device has a supply pipe for a solvent-containing gas and a desorption gas discharge pipe, and is equipped with a three-way switching valve mechanism to simplify the piping.

この従来の溶剤回収機構を図面によって説明する。This conventional solvent recovery mechanism will be explained with reference to the drawings.

この機構の例を図面にて示すと第1図の通りである。第
1図において、11は吸着・脱着塔であり、ここには活
性炭12が充填されている。この吸着・脱着塔11は、
清浄ガス排出管13および脱着用加熱ガス供給管14を
有する。15は3方切り替え弁機構を示し、16は弁板
、11はシリンダーロッド、18はシリンダーをそれぞ
れ示す。
An example of this mechanism is shown in FIG. 1. In FIG. 1, 11 is an adsorption/desorption tower, which is filled with activated carbon 12. This adsorption/desorption tower 11 is
It has a clean gas discharge pipe 13 and a heated gas supply pipe 14 for desorption. 15 indicates a three-way switching valve mechanism, 16 indicates a valve plate, 11 indicates a cylinder rod, and 18 indicates a cylinder.

第2図は、第1図の従来装置におけるシリンダーのシー
ル構造を断面図にて示したものである。第2図において
、1はワイパーリング、2は弁ケーシング、3は7ラン
ジ、4はロッドパツキン、5はシリンダーロッドカバー
、6はブツシュ、7はシリンダーチューブをそれぞれ示
す。
FIG. 2 is a sectional view showing the seal structure of the cylinder in the conventional device shown in FIG. In FIG. 2, 1 is a wiper ring, 2 is a valve casing, 3 is a 7-lunge, 4 is a rod packing, 5 is a cylinder rod cover, 6 is a bushing, and 7 is a cylinder tube.

第1図に示した前記従来装置において、実線で示した弁
板1Gは脱着ガスの排出系を示し、点線で示した弁板1
6′は溶剤含有ガス供給系を示す。
In the conventional device shown in FIG. 1, the valve plate 1G shown in solid lines indicates the desorption gas exhaust system, and the valve plate 1G shown in dotted lines
6' indicates a solvent-containing gas supply system.

このような従来装置において、供給された溶剤含有ガス
は、活性炭層12を通り溶剤は吸着され清浄ガスとして
清浄ガス排出管13から系外に排出される。このとき弁
板は点線の位置にある。
In such a conventional device, the supplied solvent-containing gas passes through the activated carbon layer 12, the solvent is adsorbed, and the gas is discharged out of the system from the clean gas discharge pipe 13 as a clean gas. At this time, the valve plate is at the position indicated by the dotted line.

一方、活性炭の吸着能が低下したら、清浄ガス排出管1
3は閉鎖され脱着用ガス供給管14から加熱された脱着
用ガスが塔内に供給される。
On the other hand, if the adsorption capacity of activated carbon decreases, clean gas exhaust pipe 1
3 is closed, and heated desorption gas is supplied into the column from the desorption gas supply pipe 14.

供給された脱着用ガスは活性炭層12を通り吸着されて
いる溶剤を脱4後溶剤脱着ガスとして3方切り替え弁機
構15を介して塔外に排出され、冷却等により溶剤が分
離回収される。このとき弁板16は実線の位置にある。
The supplied desorption gas passes through the activated carbon layer 12, desorbs the adsorbed solvent, and is then discharged as a solvent desorption gas to the outside of the column via the three-way switching valve mechanism 15, where the solvent is separated and recovered by cooling or the like. At this time, the valve plate 16 is in the position indicated by the solid line.

このとぎ排出される脱着ガスは、高濃度で溶剤を含み且
つ高温であり、このものが工程切り替え時にシリンダー
ロッド17に接触、4号着して、ワイパーリング1、ロ
ッドパツキン4、ブツシュ 6、特にワイパーリング1
、ロッドパツキン4に接触し、順次通過して、シリンダ
ーチューブ内に入るため、各部品を非常に早く劣化させ
てシリンダー機構を腐蝕し操業の安定性を損う結果とな
る。
The desorption gas discharged by this process contains a high concentration of solvent and is at a high temperature, and this gas comes into contact with the cylinder rod 17 at the time of process changeover, and is deposited on the cylinder rod 17 and is attached to the wiper ring 1, the rod packing 4, the bushing 6, and especially the cylinder rod 17. wiper ring 1
, contacts the rod packing 4, passes sequentially, and enters the cylinder tube, which causes each part to deteriorate very quickly, corrodes the cylinder mechanism, and impairs operational stability.

特に、繊維状活性炭を使用した溶剤回収装置においては
、吸着・脱着が速やかに行われる関係上、吸着・脱着の
切り酵え時間が短いためにシリンダー機構の腐蝕を速め
る結果となる。
In particular, in a solvent recovery device using fibrous activated carbon, since adsorption and desorption occur quickly, the time required for adsorption and desorption to take place is short, resulting in accelerated corrosion of the cylinder mechanism.

更に、脱着ガスとして水蒸気を使用して塩素系溶剤を脱
着した場合、水と溶剤との複合作用で腐蝕効宋を増大さ
せ、操業の安定性を著しく10なう結果となる。
Furthermore, when water vapor is used as a desorption gas to desorb chlorinated solvents, the combined effect of water and solvent increases the corrosion effect, resulting in a significant decrease in operational stability.

また、脱着ガスとして水蒸気を使用した場合、弁機構の
中において溶剤を含むドレンが凝縮し弁板のパツキンを
腐蝕させる結果となる。
Furthermore, when water vapor is used as the desorption gas, drain containing solvent condenses in the valve mechanism and corrodes the seal of the valve plate.

〔発明の目的、構成および作用〕[Object, structure, and operation of the invention]

本発明は、このような問題を解決しようとするものであ
る。
The present invention attempts to solve such problems.

排出管と溶剤含有ガス供給管との3方切り替え弁機構l
を備えた溶剤の吸JIR!装置において、3方切り替え
弁機構の下方に脱着ガスの排出管と、上方に溶剤含有ガ
ス供給管を配設し、脱着時は3方切り替え弁機構の弁板
をシリンダーロッドによって引き揚げて脱着ガスの排出
管を開口すると共に溶剤含有ガス供給管を閉口させて脱
着操作系となし、吸着時は3方切り替え弁機構の弁板を
シリンダーロッドによって押し下げて脱着ガスの排出管
を閉口すると共に溶剤含有ガス供給管を開口させて吸着
操作系となすことを特徴とする3方切り替え弁機構を備
えた溶剤の吸脱着装置。
Three-way switching valve mechanism between the discharge pipe and the solvent-containing gas supply pipe
Solvent absorption JIR equipped with! In the equipment, a desorption gas exhaust pipe is installed below the 3-way switching valve mechanism, and a solvent-containing gas supply pipe is installed above the 3-way switching valve mechanism. During desorption, the valve plate of the 3-way switching valve mechanism is pulled up by a cylinder rod to release the desorption gas. The exhaust pipe is opened and the solvent-containing gas supply pipe is closed to form a desorption operation system. During adsorption, the valve plate of the three-way switching valve mechanism is pushed down by the cylinder rod to close the desorption gas discharge pipe and remove the solvent-containing gas. A solvent adsorption/desorption device equipped with a three-way switching valve mechanism, characterized in that an adsorption operation system is created by opening a supply pipe.

このような本発明装置は、シリンダーロッドが高濃度且
つ高温の脱着ガスと接触することがなく腐蝕の問題が生
じないため、弁機構の部品交換頻麿が減少し、操業の安
定性を確保することができる。
In the device of the present invention, the cylinder rod does not come into contact with high-concentration and high-temperature desorption gas, so there is no corrosion problem, reducing the frequency of replacing parts of the valve mechanism and ensuring operational stability. be able to.

本発明装置は、特に、塩化メチレン等の塩素系溶剤、ア
ルコール類、ケトン類等の轡→→溶剤の吸脱着に有効で
ある。
The apparatus of the present invention is particularly effective for adsorption and desorption of chlorinated solvents such as methylene chloride, alcohols, ketones, and other solvents.

本発明を図面によって説明する。The present invention will be explained with reference to the drawings.

第3図は本発明吸脱着装置例の概念図を示したものであ
る。第3図において、21は吸着・脱着塔であり、ここ
には活性炭22が充填されている。活性炭としては粒状
活性炭、繊維状活性炭等であり、繊維状活性炭としては
、既知の繊維状活性炭、例えばアクリル系、フェノール
系、レーヨン系、ピッチ系等の繊維状活性炭が使用され
る。
FIG. 3 shows a conceptual diagram of an example of the adsorption/desorption device of the present invention. In FIG. 3, 21 is an adsorption/desorption tower, which is filled with activated carbon 22. The activated carbon includes granular activated carbon, fibrous activated carbon, etc., and the fibrous activated carbon used includes known fibrous activated carbons such as acrylic, phenol, rayon, and pitch-based fibrous activated carbons.

この吸着・脱着塔21は、清浄ガス排出管23および1
112着用加熱ガス供給管24を右する。脱着用加熱ガ
スとしては、水蒸気、空気、窒素等が通常用いられ、濡
麿は約100℃以上で吸着溶媒の熱分@温度以下の範囲
である。
This adsorption/desorption tower 21 has clean gas discharge pipes 23 and 1
112 Wear heating gas supply pipe 24 to the right. As the heating gas for desorption, water vapor, air, nitrogen, etc. are usually used, and the wet temperature is in the range of about 100° C. or more and below the heat content of the adsorbing solvent@temperature.

25は3方切り替え弁機構を示す。26は弁板でありL
は弁板2Gの作動長を示す。27はシリンダーロッド、
28はシリンダーをそれぞれ示す。
25 indicates a three-way switching valve mechanism. 26 is the valve plate L
indicates the operating length of the valve plate 2G. 27 is the cylinder rod,
28 each indicates a cylinder.

この第3図に示した本発明装置例において、実線で示し
た弁板26は脱着ガスの排出系を示し、点線で示した弁
板26−は溶剤含有ガス供給系を示している。
In the example of the apparatus of the present invention shown in FIG. 3, the valve plate 26 indicated by a solid line indicates a desorption gas exhaust system, and the valve plate 26- indicated by a dotted line indicates a solvent-containing gas supply system.

このような装置において、供給された溶剤含有ガスは、
活性炭層22を通り溶剤は吸着され清浄ガスとして清浄
ガス排出管23から系外に排出される。このとき弁板は
点線の位置にある。−方、活性炭の吸着能が低下したら
、清浄ガス排出管23は閉鎖され!脱着用ガス供給管2
4から加熱された+1!12着用ガスが場内に供給され
る。
In such equipment, the supplied solvent-containing gas is
The solvent is adsorbed through the activated carbon layer 22 and discharged as clean gas from the clean gas discharge pipe 23 to the outside of the system. At this time, the valve plate is at the position indicated by the dotted line. - On the other hand, when the adsorption capacity of activated carbon decreases, the clean gas discharge pipe 23 is closed! Desorption gas supply pipe 2
+1!12 donning gas heated from 4 to 4 is supplied into the venue.

供給された脱着用ガスは、活性炭層22を通り吸着され
ている溶剤を脱着後溶剤脱着ガスとして3方切り替え弁
機構25を介して塔外に排出され、冷却等により溶剤が
分離回収される。このとき弁板は実線の位置にある。
The supplied desorption gas passes through the activated carbon layer 22 and desorbs the adsorbed solvent, and then is discharged to the outside of the column via the three-way switching valve mechanism 25 as a solvent desorption gas, and the solvent is separated and recovered by cooling or the like. At this time, the valve plate is at the position indicated by the solid line.

弁板2Gは、その作動長さしの範囲を往復し実線で示し
た状態のときに脱着ガス排出が行われる。この状態にお
いてシリンダーロッドは高濃度の溶剤を含む高温の脱着
ガスに接触することはない。
The valve plate 2G reciprocates within its operating length and discharges the desorbed gas when it is in the state shown by the solid line. In this state, the cylinder rod does not come into contact with the high temperature desorption gas containing a high concentration of solvent.

一方、清浄ガスの排出においては、弁板26は点線の位
置にあるためシリンダーロッドは露出しているが、接触
するガスは低温且つ低111Ifのため腐蝕等の問題は
生じない。また、脱着操作から吸着操作への切り番え時
、吸着塔内の残留脱着ガスが直接系外に排出されないた
め好都合である。
On the other hand, when discharging clean gas, the cylinder rod is exposed because the valve plate 26 is at the position indicated by the dotted line, but problems such as corrosion do not occur because the gas in contact is at a low temperature and low 111If. Furthermore, when switching from desorption operation to adsorption operation, the residual desorption gas in the adsorption tower is not directly discharged to the outside of the system, which is convenient.

本発明の溶剤回収装置にて回収される溶剤としては、特
に制限はなく、メタノール、エタノールなどのアルコー
ル類およびアセトンなどのケトン類のほかに、好適には
、塩化メチレンなどの腐蝕性溶剤も含まれる。
The solvent recovered by the solvent recovery device of the present invention is not particularly limited, and preferably includes alcohols such as methanol and ethanol, and ketones such as acetone, as well as corrosive solvents such as methylene chloride. It will be done.

〔発明の効果〕〔Effect of the invention〕

本発明装置によると、シリンダーロッドに高温の高濃度
脱着ガスが接触しないため、シリンダー内に溶剤が持ち
込まれることがない。この結果、シリンダー内部品の使
用期間が長くなり、実際上、シリンダーロッドカバー、
シリンダーチューブ等の腐蝕による交換の必要がない。
According to the apparatus of the present invention, since the high-temperature, highly concentrated desorption gas does not come into contact with the cylinder rod, no solvent is brought into the cylinder. This results in a longer service life for the cylinder internal parts, and in practice, the cylinder rod cover,
There is no need to replace cylinder tubes etc. due to corrosion.

活性炭に吸着した溶剤の脱着には水蒸気が多く使われる
が、水蒸気脱着の場合にも、脱着ガスを3方切り替え弁
機構25の下方向に排出することによって、3方切り替
え弁機構25内で凝縮した少量のドレンも常に排出され
る。このため弁板のパツキンが高温のドレンと接触しな
いため、パツキンの使用期間も長くなる。
Water vapor is often used for desorption of solvents adsorbed on activated carbon, but even in the case of steam desorption, the desorption gas can be condensed within the three-way switching valve mechanism 25 by discharging it downward into the three-way switching valve mechanism 25. A small amount of condensate is also constantly discharged. For this reason, the seal of the valve plate does not come into contact with the high-temperature drain, so the period of use of the seal becomes longer.

(実施例および比較例) 実施例1 比表面Ff11500m ” 7gの繊維状活性炭を5
0kQ充填した第3図に示した本発明装置例着装置に、
溶剤として塩化メチレンを16.000ppm含む溶剤
含有空気を22m ” 7分にて供給して該溶剤を繊維
状活性炭に吸着させ、清浄空気を排出した。
(Examples and Comparative Examples) Example 1 Specific surface Ff 11500 m 7g of fibrous activated carbon was
In the example device of the present invention shown in FIG. 3 filled with 0kQ,
Solvent-containing air containing 16.000 ppm of methylene chloride as a solvent was supplied for 22 m''7 minutes to adsorb the solvent on the fibrous activated carbon, and the clean air was discharged.

7介接排出空気中に塩化メチレンが50ppm検出され
たので、溶剤含有空気の供給を止め、130℃の水蒸気
を3.2kg/分で6分間供給し脱着操作を行った。
7. Since 50 ppm of methylene chloride was detected in the discharged air, the supply of solvent-containing air was stopped and water vapor at 130° C. was supplied at a rate of 3.2 kg/min for 6 minutes to carry out a desorption operation.

上記操作を48,000回繰り返し、塩化メチレンの回
収を行ったが、シリンダ一部品の交換の必要はなく円滑
な操業ができた。
The above operation was repeated 48,000 times to recover methylene chloride, but there was no need to replace any part of the cylinder, and smooth operation was possible.

比較例1 第1図に示した従来装置にて、実施例1と同様に操作を
行った結果、8000回の繰返でロットパツキン、ワイ
パーリングの交換が必要となり、+a、ooo回の操作
でシリンダー−式の交換が必要であった。
Comparative Example 1 As a result of performing the same operations as in Example 1 using the conventional device shown in Fig. 1, the rod packing and wiper ring had to be replaced after 8,000 repetitions, and after +a, ooo operations. It was necessary to replace the cylinder type.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、従来の3方切り替え弁機構を有する吸脱着装
置の概念図、第2図は、第1図の従来装置におけるシリ
ンダーのシール構造の拡大断面図である。 第3図は、本発明の3方切り替え弁機構を有する吸脱着
装置1例の概念図、第4図は、第3図の本発明装置にお
けるシリンダーのシール構造例の拡大断面図である。 21:吸着・脱着塔、22:活性炭、23:清浄ガスI
F出管、24:脱着用加熱ガス供給管、25: 3方切
り替え弁機構、26.26′:弁板 @  イ 図 第 2 図
FIG. 1 is a conceptual diagram of a conventional adsorption/desorption device having a three-way switching valve mechanism, and FIG. 2 is an enlarged sectional view of a cylinder seal structure in the conventional device of FIG. FIG. 3 is a conceptual diagram of an example of an adsorption/desorption device having the three-way switching valve mechanism of the present invention, and FIG. 4 is an enlarged sectional view of an example of the cylinder seal structure in the device of the present invention shown in FIG. 21: Adsorption/desorption tower, 22: Activated carbon, 23: Clean gas I
F outlet pipe, 24: Heating gas supply pipe for removal/desorption, 25: 3-way switching valve mechanism, 26.26': Valve plate @ A Figure 2

Claims (2)

【特許請求の範囲】[Claims] (1)活性炭を充填した吸着塔と、該吸着塔に接続した
脱着ガス排出管と、溶剤含有ガス供給管との3方切り替
え弁機構を備えた溶剤の吸脱着装置にお いて、3方切り替え弁機構の下方に脱着ガスの排出管と
、上方に溶剤含有ガス供給管を配設し、脱着時は3方切
り替え弁機構の弁板をシリンダーロッドによって引き揚
げて脱着ガスの排出管を開口すると共に溶剤含有ガス供
給管を閉口させて脱着操作系となし、吸着時は3方切り
替え弁機構の弁板をシリンダーロッドによって押し下げ
て脱着ガスの排出管を閉口すると共に溶剤含有ガス供給
管を開口させて吸着操作系となすことを特徴とする3方
切り替え弁機構を備えた溶剤の吸脱着装置。
(1) In a solvent adsorption/desorption device equipped with a three-way switching valve mechanism including an adsorption tower filled with activated carbon, a desorption gas discharge pipe connected to the adsorption tower, and a solvent-containing gas supply pipe, the three-way switching valve mechanism A desorption gas exhaust pipe is provided below and a solvent-containing gas supply pipe is installed above. During desorption, the valve plate of the 3-way switching valve mechanism is pulled up using a cylinder rod to open the desorption gas discharge pipe and the solvent-containing gas is The gas supply pipe is closed to form a desorption operation system, and during adsorption, the valve plate of the three-way switching valve mechanism is pushed down by the cylinder rod to close the desorption gas discharge pipe and the solvent-containing gas supply pipe is opened for adsorption operation. A solvent adsorption/desorption device equipped with a three-way switching valve mechanism.
(2)活性炭が繊維状活性炭である特許請求の範囲(1
)記載の溶剤の吸脱着装置。
(2) Claims (1) in which the activated carbon is fibrous activated carbon
) The solvent adsorption/desorption device described in ).
JP62289783A 1987-11-17 1987-11-17 Adsorption and desorption device Granted JPH01130715A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62289783A JPH01130715A (en) 1987-11-17 1987-11-17 Adsorption and desorption device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62289783A JPH01130715A (en) 1987-11-17 1987-11-17 Adsorption and desorption device

Publications (2)

Publication Number Publication Date
JPH01130715A true JPH01130715A (en) 1989-05-23
JPH0369567B2 JPH0369567B2 (en) 1991-11-01

Family

ID=17747710

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62289783A Granted JPH01130715A (en) 1987-11-17 1987-11-17 Adsorption and desorption device

Country Status (1)

Country Link
JP (1) JPH01130715A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108730679A (en) * 2018-08-09 2018-11-02 国电环境保护研究院有限公司 A kind of anticorrosion parsing gas discharge system

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108730679A (en) * 2018-08-09 2018-11-02 国电环境保护研究院有限公司 A kind of anticorrosion parsing gas discharge system
CN108730679B (en) * 2018-08-09 2023-12-08 国电环境保护研究院有限公司 Corrosion-resistant analysis gas exhaust system

Also Published As

Publication number Publication date
JPH0369567B2 (en) 1991-11-01

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