JPH01125216A - Production of elastic self-shrinkable tube - Google Patents
Production of elastic self-shrinkable tubeInfo
- Publication number
- JPH01125216A JPH01125216A JP28373287A JP28373287A JPH01125216A JP H01125216 A JPH01125216 A JP H01125216A JP 28373287 A JP28373287 A JP 28373287A JP 28373287 A JP28373287 A JP 28373287A JP H01125216 A JPH01125216 A JP H01125216A
- Authority
- JP
- Japan
- Prior art keywords
- tube
- elastic
- rolled
- frozen
- diameter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 230000002093 peripheral effect Effects 0.000 claims abstract description 12
- 230000008014 freezing Effects 0.000 claims abstract description 10
- 238000007710 freezing Methods 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 230000001105 regulatory effect Effects 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 5
- 238000004804 winding Methods 0.000 claims description 4
- 230000007704 transition Effects 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 9
- 238000007789 sealing Methods 0.000 abstract description 5
- 238000005096 rolling process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 12
- 238000004132 cross linking Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は電線、ケーブルまたはパイプ等の接続部等を簡
便に保護、絶縁被覆することができる弾性自己収縮性チ
ューブの製造方法に関するものである。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a method of manufacturing an elastic self-shrinking tube that can easily protect and insulate connecting parts of electric wires, cables, pipes, etc. .
近年、電線、ケーブルまたはパイプ等の接続部等の保護
、絶縁被覆あるいは補修のために、熱を用いずに収縮で
きる弾性自己収縮性チューブが用いられている。この弾
性自己収縮性チューブは、ゴム状弾性を有する材料から
なる弾性チューブを半径方向に拡大し、そのままの状態
で、除去しうる剛性の中空支持体上に支持させたもので
、例えば前記弾性チューブを内部から圧力気体で拡径し
て、これを外型で減圧吸引して保持した状態でその内部
に中空支持体を挿通した後減圧状態を解除することによ
り支持体上に支持された弾性自己収縮性チューブを得る
方法等が採用されている。In recent years, elastic self-shrinkable tubes that can be shrunk without using heat have been used to protect, insulate, or repair connecting parts of electric wires, cables, pipes, etc. This elastic self-contracting tube is made by expanding an elastic tube made of a material having rubber-like elasticity in the radial direction and supporting it as it is on a rigid hollow support that can be removed. The elastic self supported on the support is expanded by expanding the diameter from the inside with pressurized gas, and holding it under reduced pressure with an outer mold. A method of obtaining a shrinkable tube, etc. has been adopted.
しかしながら上記の方法においては、所望の拡径倍率で
の周心力が減圧吸引力より大きい場合には保持すること
ができず、チューブの材質、断面サイズ及び拡径倍率等
の制約を受ける等の問題があった。またこの方法以外に
機械的に拡径する方法もあるが、拡径された状態で中空
支持体を内部に挿通して簡単に支持できる適当な方法が
なかった。However, in the above method, if the circumferential force at the desired expansion magnification is larger than the vacuum suction force, it cannot be maintained, and there are problems such as being subject to restrictions such as the material of the tube, the cross-sectional size, and the expansion magnification. was there. In addition to this method, there is also a method of mechanically expanding the diameter, but there is no suitable method that allows the hollow support to be easily supported by inserting it inside the hollow support in the expanded diameter state.
本発明は上記の問題点を解決するためになされたもので
ゴム状弾性を有する材料からなる弾性チューブの内部に
液体を加圧封入して半径方向に拡大し、その外面を外径
規制具で所望の外径に規制する外径規制工程と、該規制
工程で所望の外径に規制された前記弾性チューブ内に内
在する液体を冷凍する冷凍工程と、該冷凍工程により冷
凍円柱体上に保持された弾性チューブをその内周面が外
側、外周面が内側となるように前記冷凍円柱体の外周面
において捲り返して積層して巻成体を形成する巻成工程
と、該巻成工程により形成された巻成体を筒状体の外周
へと移行させて支持させる移行工程とを備えていること
を特徴とするものである。The present invention has been made to solve the above-mentioned problems.A liquid is pressurized and sealed inside an elastic tube made of a material having rubber-like elasticity, and the liquid is expanded in the radial direction. an outer diameter regulating step for regulating the outer diameter to a desired outer diameter; a freezing step for freezing the liquid contained within the elastic tube that has been regulated to the desired outer diameter in the regulating step; and a freezing step for holding the liquid on the frozen cylindrical body through the freezing step. a winding step in which the rolled elastic tubes are turned over and stacked on the outer peripheral surface of the frozen cylindrical body so that the inner peripheral surface is on the outside and the outer peripheral surface is on the inside to form a rolled body; The method is characterized by comprising a transition step of transferring the rolled body to the outer periphery of the cylindrical body and supporting it.
以下本発明を第1図ないし第6a図及び第6b図に基づ
いて詳細に説明する。第1図はゴム状弾性からなる弾性
チューブlaの断面図を、示しており、第2図は該弾性
チューブlaの一方の端部に密封部(図示せず)を設け
、他方の端部に加圧水封入孔(図示せず)を設けた状態
で軸線方向に二分割できる外形規制具3の内部に挿入す
る。次いで所望の圧力の加圧水2aを前記封入孔から封
入して前記外形規制具3の内径まで拡径して所望の径の
弾性チューブlbになるように規制し、次いで内在する
加圧水が適宜冷凍され冷凍円柱体2bとされる。第3a
図及び第3b図は上記の工程で外径を規制した外形規制
具3が取外すされ、冷凍円柱体2b上に所望の長さで保
持された弾性チューブ1bから弾性自己収縮性チューブ
6aを製造している状態を示す説明図である。第3a図
は冷凍円柱体2b上に所望の倍率で拡径された状態で破
線で示す弾性チューブlbのその内周面が外側、外周面
が内側となるように前記冷凍円柱体2bの外周面におい
て一方の端部で捲り返して積層して巻成体4aとし、予
め前記冷凍円柱体2bの他端部に同軸的に挿通させてお
いた筒状体5aの外周に前記巻成体4aを移行している
工程を示し、第3b図は上記の工程、により製造された
1個の積層部をもつ巻成体4aからなる弾性自己収縮性
チューブ6aの断面を示している。The present invention will be explained in detail below with reference to FIGS. 1 to 6a and 6b. FIG. 1 shows a cross-sectional view of an elastic tube la made of rubber-like elasticity, and FIG. 2 shows a sealing part (not shown) provided at one end of the elastic tube la, and It is inserted into the outer shape regulating device 3 which can be divided into two in the axial direction with a pressurized water sealing hole (not shown) provided therein. Next, pressurized water 2a at a desired pressure is sealed through the sealing hole and expanded to the inner diameter of the outer shape regulating device 3 to be regulated to form an elastic tube lb with a desired diameter.Then, the pressurized water contained therein is appropriately frozen. It is assumed to be a cylindrical body 2b. 3rd a
Figures 3 and 3b show that the outer shape regulating device 3 that has regulated the outer diameter in the above process is removed, and an elastic self-shrinking tube 6a is manufactured from the elastic tube 1b held at a desired length on the frozen cylindrical body 2b. FIG. FIG. 3a shows the outer circumferential surface of the frozen cylindrical body 2b so that the inner circumferential surface of the elastic tube lb shown by the broken line is on the outside and the outer circumferential surface is on the inside when the elastic tube lb is expanded to a desired magnification on the frozen cylindrical body 2b. The rolled body 4a is turned over at one end and laminated to form a rolled body 4a, and the rolled body 4a is transferred to the outer periphery of a cylindrical body 5a that has been coaxially inserted into the other end of the frozen cylindrical body 2b. FIG. 3b shows a cross-section of an elastic self-shrinking tube 6a made of a wound body 4a having one laminated portion produced by the above-described process.
第4a図乃至第4c図は上記と同様に保持された弾性チ
ューブlbから2つの積層部A、Bをもつ巻成体4cか
らなる弾性自己収縮性チューブ6bを製造している他の
実施例の説明図である。第4a図は冷凍円柱体2b上に
保持された弾性チューブ1bを先ず破線で示す巻成体4
bとなし、次いで前記冷凍円柱体2bに同軸的に挿通さ
せた筒状体5bの外周に、前記弾性チューブ1bの略々
半分の長さに相当する分だけ該を成体4bを巻戻すよう
に移行して積層部Bを配設している状態を示しており、
次いで第4b図のようにもう一方の端部を捲り返して積
層部Aを形成し巻成体4cとなし、筒状体5bに移設し
た後これを冷凍円柱体2bから抜取り第4c図に示すよ
うに前記筒状体5bの外周に配設された2つの積層部A
。Figures 4a to 4c illustrate another embodiment in which an elastic self-shrinking tube 6b consisting of a rolled body 4c having two laminated parts A and B is manufactured from an elastic tube lb held in the same manner as above. It is a diagram. FIG. 4a shows a wound body 4 in which the elastic tube 1b held on the frozen cylindrical body 2b is indicated by a broken line.
b, and then unwind the adult body 4b by an amount corresponding to approximately half the length of the elastic tube 1b around the outer periphery of the cylindrical body 5b coaxially inserted into the frozen cylindrical body 2b. It shows the state where the laminated part B has been arranged after the transition,
Next, as shown in Fig. 4b, the other end is turned over to form a laminated part A to form a rolled body 4c, which is transferred to a cylindrical body 5b and then extracted from the frozen cylindrical body 2b as shown in Fig. 4c. two laminated portions A disposed on the outer periphery of the cylindrical body 5b;
.
Bをもつ弾性自己収縮性チューブ6bが得られる。An elastic self-shrinkable tube 6b with B is obtained.
ここで用いられるゴム状弾性を有する材料からなる弾性
チェープlaは天然ゴム、合成ゴム等のゴム単独あるい
は二種以上の混和物に補強剤、軟化剤、老化防止剤、架
橋剤、架橋助剤等を必要により適宜配合してなる組成物
を所定の形状に成形し、化学架橋、電子線照射架橋等、
適宜の手段で架橋することにより得られるほか、熱可塑
性ゴム、ゴム状の軟質プラスチックを所定の形状に成形
したものから得られる。このようにして得られた弾性チ
ューブ1aの内部に加圧水2aを封入し該弾性チューブ
1aを所望の外径に拡径するには、拡径された弾性チュ
ーブlbの外径を均一に規制する円筒状の外径規制具3
を用いるのが望ましい、この外径規制具3は取外し容易
なように軸線方向に二分割可能な円筒体で剛性のプラス
チックまたは金属から適宜成形されて得られるが、冷凍
する際の熱伝導の点で鉄、アルミ、銅等の金属が好適に
用いられる。このようになされた外径規制具3で規制さ
れた状態で加圧水2aを氷点以下の温度で冷凍して冷凍
円柱体2bとなす温度は、拡径された弾性チュ−ブ1b
が、捲り返して積層して巻成体4a、4cをつくること
ができる程度の柔軟性を保持でき、巻成体4a、4cを
筒状体5a、5bの外周に移行するまで解氷しない程度
の温度が望ましい、また冷凍円柱体2bの外周面で弾性
チューブ1bを捲り返して積層して巻成体4a、 4c
をつくり、該巻成体4a、 4cを筒状体5に移行する
作業工程で前記冷凍円柱体2bの強度が不足する場合に
は予め該冷凍円柱体の略々中心に同軸的に位置するよう
に適宜補強棒を配置しておくことができる。このように
して形成された巻成体4a、4cを移行して支持する筒
状体5はポリエチレン、ポリプロピレン等のポリオレフ
ィン樹脂、ポリ塩化ビニル樹脂等の剛性のプラスチック
等から所望の形状に適宜成形されて得られるが巻成体4
a、4cを被覆物体に移設した後前記筒状体5の除去を
容易とするために予め該筒状°体に切込みを設けて解体
しやすくしておくか衝撃で破砕しやすくしておくのが望
ましい。The elastic chain la used here is made of a material with rubber-like elasticity, and is made of rubber such as natural rubber or synthetic rubber, or a mixture of two or more of them, as well as reinforcing agents, softeners, anti-aging agents, cross-linking agents, and cross-linking aids. A composition obtained by appropriately blending the following is formed into a predetermined shape, and subjected to chemical crosslinking, electron beam irradiation crosslinking, etc.
In addition to being obtained by crosslinking by appropriate means, it can also be obtained by molding thermoplastic rubber or rubber-like soft plastic into a predetermined shape. In order to enclose pressurized water 2a inside the elastic tube 1a obtained in this way and expand the elastic tube 1a to a desired outer diameter, a cylinder is used to uniformly regulate the outer diameter of the expanded elastic tube 1b. shaped outer diameter regulating tool 3
The outer diameter regulating device 3 is a cylindrical body that can be divided into two parts in the axial direction for easy removal, and is obtained by appropriately molding a rigid plastic or metal, but there are some problems in terms of heat conduction during freezing. Metals such as iron, aluminum, and copper are preferably used. The temperature at which the pressurized water 2a is frozen at a temperature below the freezing point while being regulated by the outer diameter regulating device 3 thus formed to form the frozen cylindrical body 2b is as follows:
However, the temperature is such that it can maintain flexibility to the extent that the rolled bodies 4a, 4c can be made by turning and stacking them, and the temperature is such that the ice does not melt until the rolled bodies 4a, 4c are transferred to the outer periphery of the cylindrical bodies 5a, 5b. It is desirable that the elastic tubes 1b are turned over and stacked on the outer peripheral surface of the frozen cylindrical body 2b to form rolled bodies 4a, 4c.
If the strength of the frozen cylindrical body 2b is insufficient in the process of making the rolled bodies 4a, 4c and transferring them to the cylindrical body 5, the frozen cylindrical body 2b should be positioned coaxially approximately at the center of the frozen cylindrical body in advance. Reinforcing rods can be placed as appropriate. The cylindrical body 5 that transfers and supports the wound bodies 4a and 4c thus formed is formed into a desired shape from a polyolefin resin such as polyethylene or polypropylene, or a rigid plastic such as polyvinyl chloride resin. The resulting roll is 4
In order to facilitate the removal of the cylindrical body 5 after transferring a and 4c to the covered object, it is recommended to make cuts in the cylindrical body in advance to make it easier to disassemble or to make it easier to crush by impact. is desirable.
第5a図、第5b図及び第6a図、第6b図は上記のよ
うにして得られた弾性自己収縮性チューブ6a、6bを
被覆物体に被覆している状態を示す断面図である。第5
a図は1つの積層部をもつ巻成体4aからなる弾性自己
収縮性チューブ6aを被覆物体7に配置して巻成体4a
を筒状体5aから矢印の方向に転勤させて前記被覆物体
7上に移設しつつある状態を示しており、第5h図は被
覆物体7上に移設された巻成体4aを巻戻すように展開
して弾性被覆層8を形成している状態を示している。FIGS. 5a, 5b, 6a, and 6b are cross-sectional views showing the state in which the elastic self-shrinking tubes 6a, 6b obtained as described above are coated on a covered object. Fifth
Figure a shows an elastic self-shrinking tube 6a consisting of a rolled body 4a having one laminated portion placed on a covering object 7 to form a rolled body 4a.
Fig. 5h shows a state in which the rolled body 4a is being transferred from the cylindrical body 5a in the direction of the arrow and placed on the covered object 7, and FIG. The state in which the elastic coating layer 8 is formed is shown.
第6a図は2つの積層部をもつ巻成体4Cからなる弾性
自己収縮性チエ−プロbを被覆物体7に配置して先ず一
方の積層部Aを巻戻すように展開して前記被覆物体7上
に移設し、次いで他方の積層部Bを筒状体5b上で巻込
みながら前記被覆物体7上に移設している状態を示して
おり、第6b図は移設された巻成体4dを巻き戻すよう
にして展開して被覆物体7上に弾性被覆層8を形成して
いる状態を示している。FIG. 6a shows an elastic self-shrinking chain member B consisting of a rolled body 4C having two laminated parts, placed on a covered object 7, and first, one laminated part A is unwound and rolled out onto the covered object 7. Fig. 6b shows a state in which the other laminated part B is moved onto the covering object 7 while being rolled up on the cylindrical body 5b. The state in which the elastic coating layer 8 is formed on the coated object 7 by being expanded is shown.
以上述べたように本発明の弾性自己収縮性チューブの製
造方法は弾性チューブをその内周面が外側、外周面が内
側となるように捲り返して積層した巻成体を筒状体の外
周へ支持させた弾性自己収縮性チェープを従来の製造方
法に比べて工程数少なく容易に製造できるものであり、
その工業的価値は極めて大きいものである。As described above, the method for manufacturing an elastic self-shrinking tube of the present invention involves supporting the rolled body on the outer periphery of a cylindrical body by turning over the elastic tube so that the inner peripheral surface is on the outside and the outer peripheral surface is on the inside. Compared to conventional manufacturing methods, the elastic self-shrinkable chain can be manufactured easily with fewer steps.
Its industrial value is extremely large.
第1図は弾性チューブの断面図、第2図は弾性チューブ
を拡径し外径規制した状態を示す断面図、第3a図、第
3b図は1個の積層部をもつ巻成体からなる弾性自己収
縮性チューブの製造方法を説明する断面図、第4a図、
第4b図、第4c図は2個の積層・部をもつ巻成体から
なる弾性自己収縮性チューブの製造方法を説明する断面
図、第5a図、第5b図は1個の積層部を持つ巻成体か
らなる弾性自己収縮性チューブを被覆物体に被覆してい
る状態を示す断面図、第6a図、第6b図は2個の積層
部をもつ巻成体からなる弾性自己収縮性チューブを被覆
物体に被覆している状態を示す断面図である。
la、 1b〜弾性チューブ、 28〜加圧水、 2b
〜冷凍円柱体、 3〜外径規制具、 4a、 4b、
4c。
4d〜巻成体、 5a、5b〜筒状体、 6a、6b〜
弾性自己収縮性チューブ。Figure 1 is a sectional view of the elastic tube, Figure 2 is a sectional view showing the elastic tube expanded in diameter and regulated in outer diameter, and Figures 3a and 3b are elastic tubes consisting of a wound body with one laminated part. A cross-sectional view illustrating a method for manufacturing a self-shrinkable tube, FIG. 4a,
Figures 4b and 4c are cross-sectional views illustrating a method for manufacturing an elastic self-shrinkable tube consisting of a winding body with two laminated parts, and Figures 5a and 5b are cross-sectional views of a winding body with one laminated body. FIGS. 6a and 6b are cross-sectional views showing a state in which a covered object is covered with an elastic self-shrinking tube made of an adult body. FIG. 3 is a cross-sectional view showing a covered state. la, 1b~elastic tube, 28~pressurized water, 2b
~Frozen cylindrical body, 3~Outer diameter regulating device, 4a, 4b,
4c. 4d~rolled body, 5a, 5b~cylindrical body, 6a, 6b~
Elastic self-shrinking tube.
Claims (1)
液体を加圧封入して半径方向に拡大し、その外面を外径
規制具で所望の外径に規制する外径規制工程と、該規制
工程で所望の外径に規制された前記弾性チューブ内に内
在する液体を冷凍する冷凍工程と、該冷凍工程により冷
凍円柱体上に保持された弾性チューブをその内周面が外
側、外周面が内側となるように前記冷凍円柱体の外周面
において捲り返して積層して巻成体を形成する巻成工程
と、該巻成工程により形成された巻成体を筒状体の外周
へと移行させて支持させる移行工程とを備えていること
を特徴とする弾性自己収縮性チューブの製造方法。an outer diameter regulating step in which a liquid is pressurized and sealed inside an elastic tube made of a material having rubber-like elasticity to expand in the radial direction, and the outer surface of the tube is regulated to a desired outer diameter with an outer diameter regulating device; A freezing step of freezing the liquid contained in the elastic tube whose outer diameter is regulated to a desired outer diameter, and a freezing step in which the inner peripheral surface of the elastic tube held on the frozen cylindrical body is on the outside and the outer peripheral surface is on the inside. A winding step of forming a rolled body by turning over and stacking layers on the outer peripheral surface of the frozen cylindrical body so that the rolled body is transferred to the outer periphery of the cylindrical body and supported A method for producing an elastic self-shrinkable tube, comprising a transition step of
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP28373287A JPH01125216A (en) | 1987-11-10 | 1987-11-10 | Production of elastic self-shrinkable tube |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP28373287A JPH01125216A (en) | 1987-11-10 | 1987-11-10 | Production of elastic self-shrinkable tube |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH01125216A true JPH01125216A (en) | 1989-05-17 |
Family
ID=17669380
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP28373287A Pending JPH01125216A (en) | 1987-11-10 | 1987-11-10 | Production of elastic self-shrinkable tube |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH01125216A (en) |
-
1987
- 1987-11-10 JP JP28373287A patent/JPH01125216A/en active Pending
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