JPH01121443A - Colored building material - Google Patents
Colored building materialInfo
- Publication number
- JPH01121443A JPH01121443A JP62278251A JP27825187A JPH01121443A JP H01121443 A JPH01121443 A JP H01121443A JP 62278251 A JP62278251 A JP 62278251A JP 27825187 A JP27825187 A JP 27825187A JP H01121443 A JPH01121443 A JP H01121443A
- Authority
- JP
- Japan
- Prior art keywords
- colored
- thermal spraying
- glaze
- transparent
- molded object
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004566 building material Substances 0.000 title description 8
- 238000007751 thermal spraying Methods 0.000 claims abstract description 23
- 239000000049 pigment Substances 0.000 claims abstract description 17
- 239000011521 glass Substances 0.000 claims abstract description 16
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 9
- 239000011147 inorganic material Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000011248 coating agent Substances 0.000 claims description 13
- 238000000576 coating method Methods 0.000 claims description 13
- 239000004035 construction material Substances 0.000 claims description 3
- 239000004567 concrete Substances 0.000 abstract description 9
- 238000000465 moulding Methods 0.000 abstract description 6
- 239000000463 material Substances 0.000 abstract description 3
- 239000004568 cement Substances 0.000 description 11
- 238000004040 coloring Methods 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000010304 firing Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910020632 Co Mn Inorganic materials 0.000 description 2
- 229910020678 Co—Mn Inorganic materials 0.000 description 2
- 229910020521 Co—Zn Inorganic materials 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- 150000001642 boronic acid derivatives Chemical class 0.000 description 2
- 239000000378 calcium silicate Substances 0.000 description 2
- 229910052918 calcium silicate Inorganic materials 0.000 description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000011253 protective coating Substances 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 229910018131 Al-Mn Inorganic materials 0.000 description 1
- 229910018461 Al—Mn Inorganic materials 0.000 description 1
- 241000972773 Aulopiformes Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910017061 Fe Co Inorganic materials 0.000 description 1
- 241000692870 Inachis io Species 0.000 description 1
- 229910008329 Si-V Inorganic materials 0.000 description 1
- 229910006768 Si—V Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 229910007727 Zr V Inorganic materials 0.000 description 1
- 239000012615 aggregate Substances 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011083 cement mortar Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical class [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- -1 e-AIPS Chemical class 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 235000019515 salmon Nutrition 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000010454 slate Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、着色された無ｔａ質成形体の表面に溶射によ
り透明又は半透明のガラス被膜が形璃されて成る着色コ
ンクリート等の着色建築材に関する。Detailed Description of the Invention (Industrial Field of Application) The present invention is applicable to colored buildings, such as colored concrete, in which a transparent or translucent glass coating is formed by thermal spraying on the surface of a colored ta-free molded body. Regarding materials.
（従来技術）
従来、セメント製品の表面の化粧として次に列挙するよ
うな技術が公知である。(Prior Art) Conventionally, the following techniques are known for decorating the surface of cement products.
■刷毛、吹き付は等によりセメント製品の表面に塗料を
塗布する。■Apply paint to the surface of cement products by brushing, spraying, etc.
■成形されたセメント製品の表面に釉薬を適用し、釉薬
の溶融温度以上の温度で焼成する（特開昭６１−５８８
７５号参照）。■A glaze is applied to the surface of the formed cement product and fired at a temperature higher than the melting temperature of the glaze (Japanese Patent Laid-Open No. 61-588
(See No. 75).
■溶射により施釉する。■Glaze is applied by thermal spraying.
たと元ば、セメント製品の表面に着色釉薬を用い、溶射
により直接施釉したり（特開昭６１−７１９６４号参照
）、セメント製品の表面に溶射によりガラスの保護被膜
を形成する（特開昭６０−２３５７７５号参照）。For example, colored glazes are applied directly to the surface of cement products by thermal spraying (see JP-A-61-71964), or a protective coating of glass is formed on the surface of cement products by thermal spraying (JP-A-61-71964). -235775).
（発明が解決しようとする問題点） しかし、上記従来技術には、次のような問題があった。(Problem to be solved by the invention) However, the above conventional technology has the following problems.
■刷毛、吹き付は等により塗料を塗布するものでは、塗
料が退色したり、塗装が剥がれたりして外観が損なわれ
る等耐久性、耐候性に問題があった。- Paints that are applied using brushes, sprayers, etc. have problems with durability and weather resistance, such as fading or peeling of the paint, which impairs the appearance.
■釉薬の溶融温度以上の温度で焼成するものでは、焼成
のため多量の熱エネルギを要する他、温度制御が難しく
、さらに使用する窯の大きさにより大型のセメント製品
の施釉ができない等の問題があった。- Items that are fired at temperatures above the melting temperature of the glaze require a large amount of thermal energy for firing, are difficult to control, and have problems such as being unable to glaze large cement products due to the size of the kiln used. there were.
■溶射による施釉技術にも、従来のものでは次のような
問題があった。■ Conventional glazing technology using thermal spraying has the following problems.
着色釉薬をもって溶射により直接施釉しても、溶射時に
非常に高温となＩ）着色釉薬が熱分解し変色するため、
着色状態が不均一となり美観上満足のいくものではなか
った。この着色面の上に溶射によりガラスの保護被膜を
形成しても、下地の着色状態の不均一なことに変わりは
ない。Even if the glaze is applied directly by thermal spraying with a colored glaze, the temperature during thermal spraying will be very high.I) The colored glaze will thermally decompose and change color.
The coloring state was non-uniform and aesthetically unsatisfactory. Even if a glass protective coating is formed by thermal spraying on this colored surface, the colored state of the base will still be non-uniform.
そこで、本発明者は鋭意研究の結果、上記従来技術の問
題点をすべて解消した着色建築材を開発するに到達した
。As a result of intensive research, the inventors of the present invention have developed a colored building material that solves all of the problems of the prior art described above.
その着色建築材は、あらかじめセメント等の無機質材料
に耐熱顔料を添加して着色成形体が成形され、該着色成
形体の着色°を生かして溶射により表面に透明又は半透
明のガラス被膜を形成されて構成されている。The colored building materials are made by adding heat-resistant pigments to an inorganic material such as cement to form a colored molded object, and then thermal spraying to form a transparent or semi-transparent glass coating on the surface by taking advantage of the coloring of the colored molded object. It is composed of
この着色建築材では、ガラス被膜が形成されるので耐候
性・耐久性に優れている。また、窒で焼成して施釉する
ことな（バーナ等で施釉するので、熱エネルギがくわず
低コストでり、大型製品の化粧にも適する。さらに、着
色状態が均一な美麗なものとできる。This colored construction material has excellent weather resistance and durability because it is coated with glass. In addition, the glaze is applied by firing with nitrogen (the glaze is applied with a burner, etc., so the cost is low because it does not waste heat energy, and it is suitable for decoration of large products.Furthermore, it can be colored uniformly and beautifully.
ところで、この着色建築材を種々の条件下で実施してみ
ると、ガラス被膜の表面に亀裂が発生することがある。By the way, when this colored construction material is applied under various conditions, cracks may occur on the surface of the glass coating.
本発明者は、この亀裂の原因が着色形体の表面近傍に存
する水分が溶射の際に蒸発することにあることを見出だ
した。The inventor of the present invention has discovered that the cause of this crack is that water present near the surface of the colored body evaporates during thermal spraying.
本発明の目的は、着色成形体に溶射によりガラス被膜が
形成される際に発生する亀裂を低減した美麗な着色建築
材をを提供することにある。An object of the present invention is to provide a beautiful colored building material in which cracks that occur when a glass coating is formed on a colored molded body by thermal spraying are reduced.
（問題点を解決するための手段）
上記目的を達成するため、本発明に係る着色建築材は、
無機質材料に水と共に耐熱顔料が分散されて着色成形体
が成形された後、該着色成形体が乾燥されてから溶射に
より着色成形体の表面に透明又は半透明のガラス被膜が
形成されて構１！Ｌされている。(Means for solving the problems) In order to achieve the above object, the colored building material according to the present invention:
After a heat-resistant pigment is dispersed in an inorganic material together with water to form a colored molded object, the colored molded object is dried, and then a transparent or translucent glass coating is formed on the surface of the colored molded object by thermal spraying. ! It is L.
着色成形体の表面に溶射によりガラス被膜を形成する前
に、着色成形体を乾燥するのは、着色成形体の表面近傍
に水分があると溶射の際に蒸発して被膜に多数の亀裂が
発生するからである。乾燥には、自然乾燥、溶射予熱専
権々のものがある。Drying the colored molded object before forming a glass coating on the surface of the colored molded object by thermal spraying is because if there is moisture near the surface of the colored molded object, it will evaporate during thermal spraying and cause many cracks in the coating. Because it does. Drying methods include natural drying and thermal spray preheating.
ここで「無機質材料」としては、セメント顕、珪酸カル
シウム、シリカ、石膏、カーボン、スラグ、石灰、マグ
ネシア、アルミナ、酸化鉄、アルミノシリケート、パー
ライト、シラス、粘度、ガラス、アスベスト等から選ば
れた１種又は２種以上の合成品又は天然品を主原料とし
たものである。各種耐火骨材、金属材、繊維等を添加し
てもよい。Here, the "inorganic material" is one selected from cement, calcium silicate, silica, gypsum, carbon, slag, lime, magnesia, alumina, iron oxide, aluminosilicate, pearlite, shirasu, viscosity, glass, asbestos, etc. The main raw materials are seeds or two or more synthetic or natural products. Various refractory aggregates, metal materials, fibers, etc. may be added.
「耐熱顔料」とは、たとえばＺｒ−８ｉ−Ｐｒ系、Ｔｉ
−８ｂ−Ｃｒ系、Ｚｒ Ｖ系、Ｔｉ−Ｃｒ−ＷＩＡｓ
Ｔｉ−３ｂ−Ｃｒ−Ｆｅｌ’、、Ｆｅ−ｇｂ−Ｃｒ−８
ｉｉ、Ｆｅ−Ｃｒ−Ｚｎ系、Ｆｅ−Ｃｒ−Ｚｎ−８ｉ、
１％、Ｆｅ−Ｃｒ−Ｚｎ−Ｍｒ＋ｊ％、Ａｌ−Ｍｎ系、
５ｎ−ＣｒＰ、、Ｓｎ Ｃｒ Ｃｏ１１．。"Heat-resistant pigments" include, for example, Zr-8i-Pr, Ti
-8b-Cr series, Zr V series, Ti-Cr-WIAs
Ti-3b-Cr-Fel', , Fe-gb-Cr-8
ii, Fe-Cr-Zn system, Fe-Cr-Zn-8i,
1%, Fe-Cr-Zn-Mr+j%, Al-Mn system,
5n-CrP, Sn Cr Co11. .
Ｃｏ−Ｚｎ Ｓｉ系、Ｃｏ−８ｉ系、Ｃｏ−Ａｌ−Ｃ
ｒ系、Ｚｒ５ｉ−Ｖ系、Ｃｒ−Ａｌ系、ＣｒＣｏＡｌ−
Ｚｎ系、Ｆｅ−Ｃｒ系、Ｃｒ−Ｆｅ−Ｃｏ−Ｍｎ系、Ｆ
ｅ−ＡＩＰＳ、等の遷移元素酸化物、珪酸塩を含む７リ
ツト又は焼成顔料である。Co-Zn Si system, Co-8i system, Co-Al-C
r series, Zr5i-V series, Cr-Al series, CrCoAl-
Zn series, Fe-Cr series, Cr-Fe-Co-Mn series, F
It is a pigment containing transition element oxides and silicates such as e-AIPS, or calcined pigments.
耐熱顔料の無機質材料に対する配合割合は種類、物性又
は着色の度合等により一様ではないが、無機質材料１０
０重量部に対して
０．５〜５重ｉ部とするのが望ましく、さらに好ましく
は１〜３重量部の範囲である。The blending ratio of heat-resistant pigments to inorganic materials varies depending on the type, physical properties, degree of coloring, etc.;
The amount is preferably 0.5 to 5 parts by weight per 0 parts by weight, and more preferably 1 to 3 parts by weight.
この理由は、配合割合が０．５重量部未満であると着色
効果が期待できず、５重量部を越えると成形体の強度が
低下するからである。The reason for this is that if the blending ratio is less than 0.5 parts by weight, no coloring effect can be expected, and if it exceeds 5 parts by weight, the strength of the molded product will decrease.
無機質材料に耐熱顔料が［分散されて成形され１てとは
、無機質材料の調合段階で着色材の添加操作を加えるこ
とである。たとえば、コンクリートブロックを作成する
一例を挙げると、セメントにシャモット、火山岩、焼成
ムライト、スラグ等の耐熱性骨材、シリカ粉等の補助材
料と共に耐熱顔料を配合した後、水を添加し混合し、成
形する。Dispersing and molding the heat-resistant pigment into the inorganic material means adding a coloring agent during the preparation stage of the inorganic material. For example, to create a concrete block, a heat-resistant pigment is mixed with cement along with heat-resistant aggregates such as chamotte, volcanic rock, calcined mullite, and slag, and auxiliary materials such as silica powder, and then water is added and mixed. Shape.
「着色成形体」は、たとえばセメントコンクリート板、
セメントモルタル板、ＡＬＣ板、石膏板、石綿スレート
板、珪酸カルシウム板又はそれらのブロック等が代表例
として挙げられ、その形状は問わない。"Colored molded bodies" are, for example, cement concrete boards,
Typical examples include a cement mortar board, an ALC board, a gypsum board, an asbestos slate board, a calcium silicate board, or blocks thereof, and the shape thereof is not limited.
溶射による施釉薬は、透明又は半透明なプラス被膜を形
成するものであり、含鉛はう酸塩、無鉛はう酸塩系の７
リツト等が多（使用される。Thermal spraying glaze forms a transparent or semi-transparent plus film, and it can be applied to lead-containing borates, lead-free borates, etc.
Ritsuto etc. are often used.
（実施例） 以下に、本発明の実施例を列挙する。(Example) Examples of the present invention are listed below.
及（鮭１
無機質材料として白色セメント（小野田セメント社製）
１００部、骨材としてシャモット砕１００部、耐熱顔料
としてＴｉ−３ｂ−ＣｒＰＳの黄色陶磁器顔料（日向産
業 Ｇ−４５５）３部及び水３５部を混練し、この混合
物を型枠に装入して着色コンクリートブロック（３００
ｍｍＸ３００ ｍ＋ａＸ ３０ ＋＊１Ｉｌ）を作成し
た。(Salmon 1) White cement (manufactured by Onoda Cement Co., Ltd.) as an inorganic material
100 parts of crushed chamotte as an aggregate, 3 parts of Ti-3b-CrPS yellow ceramic pigment (Hyuga Sangyo G-455) as a heat-resistant pigment, and 35 parts of water were mixed, and this mixture was charged into a mold. Colored concrete blocks (300
mmX300 m+aX 30 +*1Il) was created.
そして、このブロックを自然乾燥した後、溶射匪離３５
０ｍｍ、走査速度３論／分の条件下で、プロパン、酸素
、空気を使用してはう珪酸７リツトを火炎溶射したとこ
ろ、約１００μのガラス被膜の形成された黄色の亀裂の
少ない美麗な化粧板が得られた。After drying this block naturally, the thermal spraying distance was 35 mm.
When 7 liters of silicic acid was flame sprayed using propane, oxygen, and air at a scanning speed of 0 mm and a scanning speed of 3 mol/min, a glass coating of about 100 μm was formed, giving a beautiful yellow finish with few cracks. A board was obtained.
３１燵
実施例１から乾燥工程なしで、他は実施例１と同様にし
て着色建築材を得たところ、表面には多数の亀裂が発生
した。31 When a colored building material was obtained from Example 1 in the same manner as in Example 1 without the drying step, many cracks were generated on the surface.
及（４玄
耐熱顔料としてＦｅ−Ｃｒ−ＺｎＭの陶磁器顔料（日向
産業 Ｍ−１０）を使用した以外は実施例１と同様の操
作で着色コンクリートプロ・ンクを作成した。Colored concrete was prepared in the same manner as in Example 1 except that Fe-Cr-ZnM ceramic pigment (Hyuga Sangyo M-10) was used as the heat-resistant pigment.
−そして、このブロックに実施例１と同様にはう珪酸７
リツトを溶射したところ、１００μのプラス被膜の形成
された栗茶色の亀裂の少ない美麗な化粧板が得られた。- Then, this block was treated with silicic acid 7 as in Example 1.
When the resin was thermally sprayed, a beautiful chestnut-brown decorative board with few cracks was obtained with a 100 μm plus coating.
叉ｍ二」」−
以下に記載した陶磁器顔料（日内産業製）を使用した以
外は実施例１と同様の操作によりコンクリートブロック
を作成し、溶射を施した。Concrete blocks were prepared in the same manner as in Example 1, except that the ceramic pigments described below (manufactured by Nichiuchi Sangyo) were used, and thermal spraying was performed.
実施例 陶磁器顔料 化粧板の色彩３ Ｆ
ｅ−Ｃｒ−Ｗ系（Ｌ−９６） 赤茶色４ Ｔｉ
−ＣｒＪ（Ｔ−９） 赤茶色５ へｌ−Ｍ
ｎ系（８−９００） ピンク６ Ｃｏ−Ｚｎ
−５ｉ系（Ｍ−４７０） ：Ｆパルドブルーア
Ｃｏ−Ｚｎ−Δｌ（Ｍ−９２３） ：ｌパルドブル
ー８ ２ｒ−Ｓｉ−Ｖ系（Ｍ−１７００） ）ル
コプルー９ Ｃｒ−Ｃａ−＾１Ｚｎ系（Ｍ−１２８
）ピーコック１０ Ｆａ−Ｃｒ系（Ｍ−２５２）
灰色１１ Ｃｒ−Ｆｅ−Ｃｏ−Ｍｎ系（Ｍ−６１
７）黒灰色１２’ Ｃｒ−Ｆｅ−Ｃｏ系（Ｍ−７００
） 黒灰色１３Ｚｒ−Ｖ系（Ｍ−５８０） 黄
色１１昨ＬＬ
実施例２で使用した陶磁器ｉ料（Ｍ−１０）を５部に増
量して着色コンクリートブロックを作成した。この着色
はかなり濃いものとなったが、ブロックの曲げ強度は、
陶磁器顔料３部添加における９０ｋｇ／ｃｍ２から８０
ｋｇ／ ｃｍ２に低下した。Example Ceramic pigment Decorative board color 3 F
e-Cr-W series (L-96) Reddish brown 4 Ti
-CrJ (T-9) Reddish brown 5 to l-M
n series (8-900) pink 6 Co-Zn
-5i series (M-470): F Pardo Bluea
Co-Zn-Δl (M-923):l Pardo Blue 8 2r-Si-V system (M-1700) ) Lucoplu 9 Cr-Ca-^1Zn system (M-128
) Peacock 10 Fa-Cr system (M-252)
Gray 11 Cr-Fe-Co-Mn system (M-61
7) Black gray 12' Cr-Fe-Co system (M-700
) Black-gray 13Zr-V series (M-580) Yellow 11-LL Colored concrete blocks were made by increasing the ceramic material (M-10) used in Example 2 to 5 parts. This coloring was quite dark, but the bending strength of the block was
90kg/cm2 to 80 when adding 3 parts of ceramic pigment
kg/cm2.
（発明の効果）
本発明に係る着色建築材では、プラス状の被膜が形成さ
れるので耐候性・耐久性に優れている。(Effects of the Invention) The colored building material according to the present invention has excellent weather resistance and durability because a positive coating is formed.
また、窯で焼成して施釉することなく、バーナ等で施釉
するので、熱エネルギがくわず低コストでり、大型製品
の化粧にも適する。In addition, since the glaze is applied with a burner or the like instead of firing in a kiln, the cost is low because no thermal energy is used, and it is suitable for decoration of large products.
さらに、素材である着色成形体自身が着色されているた
め、着色状態が均一な美麗なものとできる。Furthermore, since the colored molded body itself is colored, the colored state can be uniform and beautiful.
また、着色成形体が乾燥されてから溶射によるガラス被
膜の形成がなされるため、着色成形体中の水分が溶射熱
により蒸発して被膜に多数の亀裂が生じるようなことが
なく、美麗な着色建築材を得ることができる。In addition, since the glass coating is formed by thermal spraying after the colored molded body is dried, the water in the colored molded body does not evaporate due to the thermal spraying heat and many cracks occur in the coating, resulting in beautiful coloring. You can get building materials.
Claims (1)
が成形された後、該着色成形体が乾燥されてから溶射に
より着色成形体の表面に透明又は半透明のガラス被膜が
形成されて成ることを特徴とする着色建築材。After a heat-resistant pigment is dispersed in an inorganic material together with water to form a colored molded object, the colored molded object is dried, and then a transparent or translucent glass coating is formed on the surface of the colored molded object by thermal spraying. Colored construction materials featuring:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62278251A JPH01121443A (en) | 1987-11-05 | 1987-11-05 | Colored building material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62278251A JPH01121443A (en) | 1987-11-05 | 1987-11-05 | Colored building material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01121443A true JPH01121443A (en) | 1989-05-15 |
Family
ID=17594728
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62278251A Pending JPH01121443A (en) | 1987-11-05 | 1987-11-05 | Colored building material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01121443A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57200276A (en) * | 1981-06-03 | 1982-12-08 | Kubota Ltd | Manufacture of enameled cement formed body |
| JPS60137880A (en) * | 1983-12-23 | 1985-07-22 | 株式会社クボタ | Method of coloring inorganic board material |
| JPS62230684A (en) * | 1986-03-29 | 1987-10-09 | 日本化学工業株式会社 | Manufacture of glass coated inorganic formed body |
-
1987
- 1987-11-05 JP JP62278251A patent/JPH01121443A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57200276A (en) * | 1981-06-03 | 1982-12-08 | Kubota Ltd | Manufacture of enameled cement formed body |
| JPS60137880A (en) * | 1983-12-23 | 1985-07-22 | 株式会社クボタ | Method of coloring inorganic board material |
| JPS62230684A (en) * | 1986-03-29 | 1987-10-09 | 日本化学工業株式会社 | Manufacture of glass coated inorganic formed body |
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