JPH01109778A - Formation of low reflectivity edge face of optical element - Google Patents

Formation of low reflectivity edge face of optical element

Info

Publication number
JPH01109778A
JPH01109778A JP62268431A JP26843187A JPH01109778A JP H01109778 A JPH01109778 A JP H01109778A JP 62268431 A JP62268431 A JP 62268431A JP 26843187 A JP26843187 A JP 26843187A JP H01109778 A JPH01109778 A JP H01109778A
Authority
JP
Japan
Prior art keywords
groove
face
layer
active layer
optical element
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP62268431A
Other languages
Japanese (ja)
Inventor
Katsuhiko Goto
勝彦 後藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Electric Corp
Original Assignee
Mitsubishi Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Electric Corp filed Critical Mitsubishi Electric Corp
Priority to JP62268431A priority Critical patent/JPH01109778A/en
Publication of JPH01109778A publication Critical patent/JPH01109778A/en
Pending legal-status Critical Current

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  • Semiconductor Lasers (AREA)
  • Led Devices (AREA)

Abstract

PURPOSE:To improve reliability, by epitaxially growing a lower clad layer, an active layer and an upper clad layer on a substrate, in which a deep groove is formed by etching, cleaving the device at the center of the groove in parallel with the groove, and isolating elements. CONSTITUTION:A groove 5 is formed in a semiconductor substrate 1 by etching. Thereafter, at least a lower clad layer 2, an active layer 3 and an upper clad layer 4 are epitaxially grown sequentially on the semiconductor substrate 1. The device is cleaved at the center of the groove 5 in parallel with the groove, and elements are isolated. Therefore the surface of an epitaxial layer 6 is inclined at the end surface of the extended flat part of the active layer 3. Thus a very low reflectivity is obtained. Since the vicinity of the edge face becomes a window structure, deterioration of the edge face due to the absorption of light is hard to occur. In this way, a highly reliable optical element can be obtained.

Description

【発明の詳細な説明】 〔産業上の利用分腎〕 この発明は、端面発光型LED、LDなどの光素子の低
反射率端面形成方法に関するものである、。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Applications] The present invention relates to a method for forming low reflectance end faces of optical elements such as edge-emitting LEDs and LDs.

〔従来の技術〕[Conventional technology]

端面発光型光素子において、低反射率・の端面を形成す
る方法として従来は、端面に無反射コーティングを施す
方法がとられている。
In an edge-emitting optical element, a conventional method for forming an end face with a low reflectance is to apply a non-reflective coating to the end face.

第2図は端面に無反射コーテイング膜を形成した端面発
光型光素子の断面図である。
FIG. 2 is a cross-sectional view of an edge-emitting type optical device in which a non-reflection coating film is formed on the edge surface.

この図において、1はn−InP基板、2はn−−1n
P下クワクラッド3はI nG aA sP活性層(以
下、単に活性層という。他の符号についても同称とする
)、4はp−InP上クラッド層、7は無反射コーテイ
ング膜である。
In this figure, 1 is an n-InP substrate, 2 is an n--1n
The P lower quail cladding 3 is an InGaA sP active layer (hereinafter simply referred to as an active layer. The same names apply to other symbols), 4 is a p-InP upper cladding layer, and 7 is a non-reflection coating film.

無反射コーテイング膜7 let S i O、、S 
i N 、 。
Anti-reflection coating film 7 let S i O,,S
iN,.

2.0.などを電子ビーム蒸着やスパッタなどにJ:り
活性層3で生じる光の波長λに対してλ/4の厚さに形
成する。す開端面にこのような無反射コーテイング膜7
を形成することによってlo−3程度の低反射率の端面
を得ることができる、。
2.0. The active layer 3 is formed with a thickness of λ/4 relative to the wavelength λ of the light generated in the active layer 3 by electron beam evaporation or sputtering. Such an anti-reflection coating film 7 is applied to the open end surface.
By forming this, it is possible to obtain an end face with a low reflectance of about lo-3.

また、低反射率の端面を形成する他の方法と17で、第
3図のように、端面をエツチングにより斜めに形成する
方法がある。すなわち、第3図においで、8はエツチン
グ端面であり、その他は第2図と同じものである。エツ
チングされた側の活性層3の端面ば斜めになっており、
また、鏡面ではないので活性J83を伝播してきた光は
端面において乱反射される。このため、エツチング端面
における反射率は10−4程度の低反射率が得られる。
Another method for forming end faces with low reflectivity is to form the end faces obliquely by etching as shown in FIG. That is, in FIG. 3, 8 is an etched end face, and the other parts are the same as in FIG. 2. The end surface of the active layer 3 on the etched side is oblique,
Furthermore, since the active J83 is not a mirror surface, the light propagating through the active J83 is diffusely reflected at the end face. Therefore, a low reflectance of about 10@-4 can be obtained at the etched end face.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

上記のように構成された端面発光型光素子、例えば端面
発光LEDでは、−40℃の低温においてもレーザ発振
しないことが必要である。−40℃において、レーザ発
振を抑えるためには、一方の端面の反射率を10−4程
度以下にする必要がある。ところが、第2図のように、
劈開端面に無反射コーチ7Cング膜7を形成する方法で
は、反射率(よL 0−31¥i度であり、101以下
の低反射率を実現することば困難である。
The edge-emitting optical element configured as described above, such as an edge-emitting LED, must not emit laser even at a low temperature of -40°C. In order to suppress laser oscillation at −40° C., it is necessary to reduce the reflectance of one end face to about 10 −4 or less. However, as shown in Figure 2,
In the method of forming the non-reflection coating film 7 on the cleaved end face, the reflectance (L) is 0-31\i degrees, and it is difficult to realize a low reflectance of 101 or less.

一方、第3図のように、端面をエツチングして低反射率
にする方法では、エツチング端面は七開端直に比べて非
発光再結合中心が多いため、端直りS化を生じ易いとい
う問題点があった。
On the other hand, as shown in Fig. 3, the method of etching the end face to reduce the reflectance has the problem that the etched end face has more non-radiative recombination centers than the straight seven-opening end face, so it is more likely to cause the straight edge to become S. was there.

この発明は、上記のような間;壇点を解消するためにな
されたもので、10−’程度以下の極めて低い反射率を
実現できるとともに、端面劣化を生じず信頼性の高い光
素子の低反射率端面形成方法を提供することを目的とす
る1、 〔問題点を解決するための手段〕 この発明に係る光素子の低反射率端面形成方法は、半導
体基板にエツチングにより溝を形成した後、半導体基板
上に少なくとも下クラッド層、活性層、上りシッド層を
含む層をエピタキシャル層長し、その後、活性層の平坦
部の延長上の端面が傾斜した成長層表面となるように溝
の中心で、かつこの溝に平行に劈開して素子分離を行う
ものである。
This invention was made in order to solve the above-mentioned problem, and it is possible to realize an extremely low reflectance of about 10-' or less, and also to create a highly reliable optical element that does not cause end face deterioration. 1. [Means for solving the problem] A method for forming a low reflectance end face of an optical element according to the present invention is to provide a method for forming a reflectance end face by etching a semiconductor substrate, and then forming a groove. , a layer including at least a lower cladding layer, an active layer, and an upper cladding layer is epitaxially lengthened on the semiconductor substrate, and then the center of the groove is formed so that the end face on the extension of the flat part of the active layer becomes an inclined surface of the growth layer. The device is then cleaved parallel to this groove to perform element isolation.

〔作用〕[Effect]

この発明においては、エツチングにより深い溝を形成し
た基板上に下クラ・ソド層、活性層、上クラッド層をエ
ピタキシャル成長し、溝の中心で溝に平行に劈開して素
子分離することにより、活性層の平坦部の延長上の端面
が、傾斜したエピタキシャル層表面となり、端面劣化が
生じにくい。
In this invention, a lower cladding layer, an active layer, and an upper cladding layer are epitaxially grown on a substrate in which a deep groove is formed by etching, and the active layer is separated by cleavage parallel to the groove at the center of the groove. The end face on the extension of the flat part becomes the inclined surface of the epitaxial layer, making it difficult for end face deterioration to occur.

〔実施例〕〔Example〕

以下、この発明の一実施例を第1図(a)〜(C)につ
いて説明する。
An embodiment of the present invention will be described below with reference to FIGS. 1(a) to 1(C).

第1図(a)〜(C)はこの発明の光素子の低反射率端
面形成方法を説明する工程断面図である。なお、この図
で第2図と同一符号は同じものを示す。
FIGS. 1A to 1C are cross-sectional views illustrating a method for forming a low reflectance end face of an optical element according to the present invention. In this figure, the same reference numerals as in FIG. 2 indicate the same parts.

まず、第1図(a)に示すように、基板1に深さ20μ
I’l+程度2幅40μm程度の溝5をエツチングによ
り形成する。次に、第1図(b)に示すように、下クラ
ッド層2.活性層3.上クラッド層4を順次成長する。
First, as shown in FIG.
A groove 5 having a width of approximately 40 μm is formed by etching. Next, as shown in FIG. 1(b), the lower cladding layer 2. Active layer 3. The upper cladding layer 4 is grown sequentially.

この時、溝5の部分では活性層3゜上クラッド層4,7
45は図示のように湾曲し、溝5は埋まりきらず、表面
は傾斜面となる。1次に、第1図(C)に示す、ように
、溝5の中心部で溝5に平行に劈開し素子分離する3゜ 以上のような製造方法により作製された端面発光型光素
子で(、t1活性層3は劈開された溝の部分で湾曲して
おり、活性層3の平坦部の延長上の端面ば傾斜したエピ
タキシャル層6表向になっている。したがって、活性層
3内を導波されてきた光にとってζ、t1溝側の端面の
手前で光導波機構が消失した構造となっており、また、
端面は傾斜していて光は乱反射されるため、溝側の端面
における反射率は極めて低(なり、10−4程度の反射
率は容易に得られる。。
At this time, in the groove 5 part, the cladding layers 4 and 7 are 3 degrees above the active layer.
45 is curved as shown, the groove 5 is not completely filled, and the surface becomes an inclined surface. First, as shown in FIG. 1(C), an edge-emitting optical device manufactured by a manufacturing method in which the groove 5 is cleaved parallel to the groove 5 to separate the elements by an angle of 3° or more is used. (, t1 The active layer 3 is curved at the cleaved groove part, and the end face on the extension of the flat part of the active layer 3 faces the inclined epitaxial layer 6. Therefore, the inside of the active layer 3 is curved. For the guided light, the structure is such that the optical waveguide mechanism disappears before the end face on the ζ and t1 groove side, and
Since the end face is inclined and light is diffusely reflected, the reflectance at the end face on the groove side is extremely low (and a reflectance of about 10 −4 can be easily obtained).

また、端面ばエピタキシャル層6表面であるため、エツ
チングにより形成された端面」:りも非発光再結合中心
が少ない。その上、活性層3を導波されてきた光は端面
近傍で、活性層3よりもバンドギャップの大きい上クラ
ッド層4に進むので、光の吸収が起きない。したがって
、端面近傍では、光の吸収による端面劣化が生じにり(
、信頼性の高い光素子が得られる。
Furthermore, since the end face is the surface of the epitaxial layer 6, there are fewer non-radiative recombination centers on the end face formed by etching. Moreover, since the light guided through the active layer 3 travels to the upper cladding layer 4, which has a larger band gap than the active layer 3, near the end face, no light absorption occurs. Therefore, near the end face, end face deterioration due to light absorption is likely to occur (
, a highly reliable optical device can be obtained.

〔発明の効果〕〔Effect of the invention〕

以上説明したように、この発明は、半導体基板にエツチ
ングにより溝を形成した後、半導体基板上に、少な(と
も下クラッド層、活性層、上クラッド層を順次エピタキ
シャル層長し、溝の中心でこの溝に平行に劈開して素子
分離を行うようにしたので、活性層の平坦部の延長上の
端面が傾斜したエピタキシャル1d表面となって権めて
低い反射率が実現でき、また、端面近傍が窓構造となる
ため、尤の吸収による端面劣化が生じに(<、シたかっ
て、信頼性の高い光素子が得られる効果がある、。
As explained above, in the present invention, after forming a groove in a semiconductor substrate by etching, epitaxial layer lengths (lower cladding layer, active layer, and upper cladding layer) are sequentially formed on the semiconductor substrate to form a groove in the center of the groove. Since the device is separated by cleavage parallel to this groove, the end face on the extension of the flat part of the active layer becomes an inclined epitaxial 1d surface, which makes it possible to achieve extremely low reflectance. Since it has a window structure, end face deterioration due to excessive absorption occurs (<, which has the effect of obtaining a highly reliable optical element.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図(a)〜(C)はこの発明の一実施例の光素子の
低反射率端面形成方法を示す工程断面図、第2図は従来
の無反射コーテイング膜を施した光素子の低反射率端面
形成方法を説明する断面図、第3図は従来の端面エツチ
ングによる光素子の低反射率形成方法を説明する断面図
である。 図において、1はn−1nP基板、2 +、in −I
nP下クラ・ソド層、3はInG aA sP活性層、
4ばp−InP上クワクラッド層は溝、6はエビクキシ
ャル層である。 なお、各図中の同一符号は同一また(よ相当部分を示す
。 代理人 大 岩 増 m(外2名) 第1図 第2図
1(a) to (C) are process cross-sectional views showing a method for forming a low reflectance end face of an optical device according to an embodiment of the present invention, and FIG. FIG. 3 is a sectional view illustrating a method of forming a reflectance end face. FIG. 3 is a sectional view illustrating a method of forming a low reflectance of an optical element by conventional end face etching. In the figure, 1 is an n-1nP substrate, 2 +, in -I
nP lower Cla-Sodo layer, 3 is InGaA sP active layer,
4 is a groove on the p-InP cladding layer, and 6 is an evixial layer. The same reference numerals in each figure indicate the same or corresponding parts. Agent Masu Oiwa (2 others) Figure 1 Figure 2

Claims (1)

【特許請求の範囲】[Claims]  半導体基板にエッチングにより溝を形成する工程、前
記半導体基板上に少なくとも下クラッド層、活性層、上
クラッド層を含む層をエピタキシャル成長する工程、前
記活性層の平坦部の延長上の端面が傾斜した成長層表面
となるように前記溝の中心で、かつこの溝に平行に劈開
して素子分離を行う工程を含むことを特徴とする光素子
の低反射率端面形成方法。
A step of forming a groove in a semiconductor substrate by etching, a step of epitaxially growing a layer including at least a lower cladding layer, an active layer, and an upper cladding layer on the semiconductor substrate, and a step of growing an end face on an extension of a flat portion of the active layer with a slope. A method for forming a low reflectance end face of an optical element, the method comprising the step of separating the elements by cleaving at the center of the groove and parallel to the groove so as to form a layer surface.
JP62268431A 1987-10-22 1987-10-22 Formation of low reflectivity edge face of optical element Pending JPH01109778A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62268431A JPH01109778A (en) 1987-10-22 1987-10-22 Formation of low reflectivity edge face of optical element

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62268431A JPH01109778A (en) 1987-10-22 1987-10-22 Formation of low reflectivity edge face of optical element

Publications (1)

Publication Number Publication Date
JPH01109778A true JPH01109778A (en) 1989-04-26

Family

ID=17458395

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62268431A Pending JPH01109778A (en) 1987-10-22 1987-10-22 Formation of low reflectivity edge face of optical element

Country Status (1)

Country Link
JP (1) JPH01109778A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103050584A (en) * 2011-10-17 2013-04-17 上海蓝光科技有限公司 Method for preparing light-emitting diode chip

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103050584A (en) * 2011-10-17 2013-04-17 上海蓝光科技有限公司 Method for preparing light-emitting diode chip

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