JP7524260B2 - Packaged frozen food composition - Google Patents

Packaged frozen food composition Download PDF

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JP7524260B2
JP7524260B2 JP2022140276A JP2022140276A JP7524260B2 JP 7524260 B2 JP7524260 B2 JP 7524260B2 JP 2022140276 A JP2022140276 A JP 2022140276A JP 2022140276 A JP2022140276 A JP 2022140276A JP 7524260 B2 JP7524260 B2 JP 7524260B2
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frozen food
seasoning
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剛大 根岸
茂樹 里見
平井 弘子
慎一 岩畑
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House Foods Corp
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/04Freezing; Subsequent thawing; Cooling
    • A23B7/05Freezing; Subsequent thawing; Cooling with addition of chemicals or treatment with chemicals other than cryogenics, before or during cooling, e.g. in the form of an ice coating or frozen block
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/36Freezing; Subsequent thawing; Cooling
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L35/00Food or foodstuffs not provided for in groups A23L5/00 – A23L33/00; Preparation or treatment thereof

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Seasonings (AREA)
  • Freezing, Cooling And Drying Of Foods (AREA)
  • Edible Oils And Fats (AREA)
  • Seeds, Soups, And Other Foods (AREA)
  • Storage Of Fruits Or Vegetables (AREA)

Description

本発明は、容器入り冷凍食品組成物、及びその製造方法に関する。 The present invention relates to a containerized frozen food composition and a method for producing the same.

冷凍食品は、食材の長期保存を可能とするとともに、電子レンジ等を用いた加熱処理により簡単に喫食可能となるものであり、今日では様々な食材について冷凍食品が開発されており、人気を博している。 Frozen foods allow food ingredients to be stored for long periods and can be easily eaten by heating them in a microwave oven or other device. Today, frozen foods have been developed for a wide variety of food ingredients and are gaining in popularity.

従来、様々な冷凍食品が開発され、報告されている。
特許文献1には、容器の下部に米飯及び/又は麺類が置かれ、米飯及び/又は麺類の上に肉及び/又は野菜が置かれ、25℃における粘度が5~75mPa・sであるソースが、肉及び/又は野菜を実質上覆っている耐熱容器に入れられた冷凍食品が開示されている。
Conventionally, various frozen foods have been developed and reported.
Patent Document 1 discloses a frozen food contained in a heat-resistant container in which cooked rice and/or noodles are placed in the lower part of the container, meat and/or vegetables are placed on top of the cooked rice and/or noodles, and the meat and/or vegetables are substantially covered with a sauce having a viscosity of 5 to 75 mPa·s at 25°C.

特許文献2には、ポリグリセリン脂肪酸エステルとレシチンを含む乳化剤を添加してなる油脂を食品の表面に接触処理した後、該食品を冷凍することを特徴とする冷凍食品の製造方法が開示されている。 Patent Document 2 discloses a method for producing frozen foods, which comprises contacting the surface of a food with an oil or fat containing an emulsifier containing polyglycerol fatty acid ester and lecithin, and then freezing the food.

特許文献3には、冷凍保存に耐え得る、食品素材を融点33℃以上の食用油脂と共に加熱して得られる加熱調理臭のある食品素材および前記加熱に用いた食用油脂を含んでなり、粉粒体状の前記食品素材をペースト状の前記食用油脂に分散状態に保持させてなるペースト状オイル調味料が開示されている。 Patent Document 3 discloses a paste-like oil seasoning that contains a food material that can withstand freezing and has a cooked odor obtained by heating the food material together with edible oils and fats with a melting point of 33°C or higher, and the edible oils and fats used in the heating, and in which the powder-like food material is dispersed in the paste-like edible oils and fats.

特許文献4には、冷凍耐性を有する、煮汁を含む具材入り惣菜または、ペースト状惣菜に、ジェランガム0.3~1.5%(重量)及び澱粉1.0~5.0%(重量)を添加、分散、加熱、溶解してゲル化したことを特徴とするゲル化食品が開示されている。 Patent Document 4 discloses a gelled food product that is characterized by adding 0.3 to 1.5% (by weight) gellan gum and 1.0 to 5.0% (by weight) starch to a freeze-resistant side dish containing ingredients and broth or a paste-like side dish, dispersing, heating, dissolving and gelling the mixture.

特開2005-171号公報JP 2005-171 A 特許第4933719号公報Patent No. 4933719 特開2001-008620号公報JP 2001-008620 A 特開平10-215797号公報Japanese Patent Application Publication No. 10-215797

従来の冷凍食品の多くは、冷凍により硬化してしまい、容器より当該食品を取り出すこと、特に、必要な分を取り分け、取り出すことは、非常に困難である場合があった。また、完全に硬化した冷凍食品は加熱処理に付した場合に加熱ムラを生じやすく、均一な食感が得られない場合があった。 Many conventional frozen foods become hardened when frozen, making it very difficult to remove the food from the container, especially when taking out only the portion you need. In addition, completely hardened frozen foods are prone to uneven heating when heated, and may not provide a uniform texture.

さらに、従来の冷凍食品の多くは、加熱処理した場合に、冷凍された食品特有のいやな臭いや、ドリップを生じる場合があり、これらは味や品質の低下等を引き起こす要因となっていた。 Furthermore, many conventional frozen foods can produce unpleasant odors and drips that are characteristic of frozen foods when heated, which can lead to a deterioration in taste and quality.

そこで本発明は、冷凍により完全に硬化することなく、手で容易にほぐすことが可能な冷凍食品を提供することを目的とする。 Therefore, the present invention aims to provide a frozen food that does not harden completely when frozen and can be easily loosened by hand.

また、本発明は、加熱処理した場合における、冷凍された食品特有のいやな臭いや、ドリップの発生が低減され、味や品質の低下等を抑制することが可能な冷凍食品を提供することを目的とする。 The present invention also aims to provide frozen foods that, when heated, reduce the unpleasant odor and dripping that are characteristic of frozen foods, and can prevent deterioration in taste and quality.

本発明者らは上記課題を解決すべく鋭意検討した結果、全量100質量%に対して15質量%超の油脂と15質量%未満の水、及び調味料とを含み、25℃及びせん断速度1(1/s)における粘度が120mPa・s超である、冷凍食材用調味料組成物を、食材と混合して冷凍して得られた冷凍食品が、冷凍により完全に硬化することなく、手で容易にほぐすことが可能であり、それによって加熱ムラを低減して、加熱処理できることを見出した。 As a result of intensive research by the inventors to solve the above problems, they have found that a frozen food obtained by mixing a seasoning composition for frozen food ingredients, which contains more than 15% by mass of fats and oils, less than 15% by mass of water, and seasonings, relative to a total amount of 100% by mass, and has a viscosity of more than 120 mPa·s at 25°C and a shear rate of 1 (1/s), with food ingredients and freezing the mixture, can be easily loosened by hand without completely hardening due to freezing, and thus can be heat-treated with reduced unevenness in heating.

また、当該冷凍食材用調味料組成物と混合して得られた冷凍食品、又は当該冷凍食材用調味料組成物と混合した冷凍食材は、加熱処理に付すことにより、調味料に由来する良好な風味や味が感じられ、冷凍された食品特有のいやな臭いが低減されており、またドリップの発生も抑制されていることを見出した。
本発明はこれらの知見に基づくものであり、以下の発明を包含する。
[1] 冷凍食品組成物が容器に収納されている、容器入り冷凍食品組成物であって、
前記冷凍食品組成物は、常温のときに液体である液部を含み、
前記液部が、前記液部100質量%に対して15質量%超の油脂と15質量%未満~0質量%以上の水、及び調味料とを含み、25℃及びせん断速度1(1/s)における粘度が120mPa・s超である、容器入り冷凍食品組成物。
[2] 前記油脂が、極度硬化油脂を含み、前記極度硬化油脂を前記液部100質量%に対して2質量%超の量で含む、[1]の容器入り冷凍食品組成物。
[3] 前記液部100質量%に対して、前記調味料が4質量%超の量で含まれる、[1]又は[2]の容器入り冷凍食品組成物。
[4]前記液部が、食材100gに対して、2~100gとなる混合比にて含まれる、[1]~[3]のいずれかの容器入り冷凍食品組成物。
[5] 冷凍食材用調味料組成物であって、前記組成物100質量%に対して15質量%超の油脂と15質量%未満~0質量%以上の水、及び調味料とを含み、
25℃及びせん断速度1(1/s)における粘度が120mPa・s超である、冷凍食材用調味料組成物。
[6] 前記油脂が、極度硬化油脂を含み、前記極度硬化油脂を前記組成物100質量%に対して2質量%超の量で含む、[5]の冷凍食材用調味料組成物。
[7] 前記組成物100質量%に対して、前記調味料が4質量%超の量で含まれる、[5]又は[6]の冷凍食材用調味料組成物。
[8] 冷凍食材用調味料組成物の製造方法であって、前記組成物100質量%に対して15質量%超の油脂と15質量%未満~0質量%以上の水、及び調味料とを混合すること、ならびに、
前記組成物の25℃及びせん断速度1(1/s)における粘度が120mPa・s超とすること、
を含む、製造方法。
[9] 前記油脂が、極度硬化油脂を含み、前記極度硬化油脂を前記組成物100質量%に対して2質量%超の量で含む、[8]の製造方法。
[10] 前記組成物100質量%に対して、前記調味料を4質量%超の量で混合する、[8]又は[9]の製造方法。
[11] 容器入り冷凍食品組成物の製造方法であって、食材と冷凍食材用調味料組成物を混合し、得られた混合物を冷凍する工程を含み、
前記冷凍食材用調味料組成物が、前記冷凍食材用調味料組成物100質量%に対して15質量%超の油脂と15質量%未満~0質量%以上の水、及び調味料とを含み、25℃及びせん断速度1(1/s)における粘度が120mPa・s超である、製造方法。
[12] 前記油脂が、極度硬化油脂を含み、前記極度硬化油脂を前記組成物100質量%に対して2質量%超の量で含む、[11]の製造方法。
[13] 前記冷凍食材用調味料組成物100質量%に対して、前記調味料が4質量%超の量で含まれる、[11]又は[12]の製造方法。
[14] 前記得られた混合物を、容器に収納した後に冷凍する、[11]~[13]のいずれかの製造方法。
They also found that by subjecting a frozen food obtained by mixing the seasoning composition for frozen food ingredients, or a frozen food ingredient mixed with the seasoning composition for frozen food ingredients, to a heat treatment, the good flavor and taste derived from the seasoning can be felt, the unpleasant odor specific to frozen foods is reduced, and the occurrence of dripping is also suppressed.
The present invention is based on these findings and includes the following inventions.
[1] A container-packed frozen food composition, comprising a container containing the frozen food composition,
The frozen food composition comprises a liquid portion that is liquid at room temperature,
The liquid portion contains more than 15% by mass of fats and oils, less than 15% by mass to 0% by mass or more of water, and a seasoning, relative to 100% by mass of the liquid portion, and has a viscosity of more than 120 mPa·s at 25°C and a shear rate of 1 (1/s).
[2] The container-packed frozen food composition according to [1], wherein the oil or fat comprises extremely hardened oil or fat, and the oil or fat comprises more than 2% by mass of the extremely hardened oil or fat relative to 100% by mass of the liquid portion.
[3] The container-packed frozen food composition according to [1] or [2], wherein the seasoning is contained in an amount of more than 4% by mass relative to 100% by mass of the liquid portion.
[4] The container-packed frozen food composition according to any one of [1] to [3], wherein the liquid portion is contained in a mixing ratio of 2 to 100 g per 100 g of food material.
[5] A seasoning composition for frozen food materials, comprising more than 15% by mass of fats and oils, less than 15% by mass to 0% by mass or more of water, and a seasoning, based on 100% by mass of the composition;
A seasoning composition for frozen food materials, having a viscosity of more than 120 mPa·s at 25°C and a shear rate of 1 (1/s).
[6] The seasoning composition for frozen food materials according to [5], wherein the oil or fat comprises extremely hardened oil or fat, and the oil or fat comprises the extremely hardened oil or fat in an amount of more than 2% by mass relative to 100% by mass of the composition.
[7] The seasoning composition for frozen food materials according to [5] or [6], wherein the seasoning is contained in an amount of more than 4% by mass relative to 100% by mass of the composition.
[8] A method for producing a seasoning composition for frozen food materials, comprising mixing more than 15% by mass of fats and oils, less than 15% by mass to 0% by mass or more of water, and a seasoning, relative to 100% by mass of the composition; and
The viscosity of the composition at 25° C. and a shear rate of 1 (1/s) is greater than 120 mPa·s;
A manufacturing method comprising:
[9] The method according to [8], wherein the oil or fat contains extremely hardened oil or fat, and the extremely hardened oil or fat is contained in an amount of more than 2% by mass relative to 100% by mass of the composition.
[10] The method according to [8] or [9], wherein the seasoning is mixed in an amount of more than 4% by mass relative to 100% by mass of the composition.
[11] A method for producing a packaged frozen food composition, comprising the steps of mixing a food material with a seasoning composition for frozen food materials and freezing the resulting mixture,
The seasoning composition for frozen food ingredients contains more than 15% by mass of fats and oils, less than 15% by mass to 0% by mass or more of water, and a seasoning, relative to 100% by mass of the seasoning composition for frozen food ingredients, and has a viscosity of more than 120 mPa·s at 25° C. and a shear rate of 1 (1/s).
[12] The method according to [11], wherein the oil or fat comprises extremely hardened oil or fat, and the oil or fat comprises an amount of the extremely hardened oil or fat greater than 2% by mass relative to 100% by mass of the composition.
[13] The method according to [11] or [12], wherein the seasoning is contained in an amount of more than 4% by mass relative to 100% by mass of the seasoning composition for frozen food materials.
[14] The method according to any one of [11] to [13], further comprising storing the mixture in a container and then freezing the mixture.

本発明によれば、冷凍により完全に硬化することなく、手で容易にほぐすことが可能な冷凍食品を提供することができる。 The present invention provides a frozen food that does not harden completely when frozen and can be easily broken down by hand.

また、本発明によれば、加熱処理した場合に、冷凍された食品特有のいやな臭いや、ドリップの発生が低減され、味や品質の低下等を抑制することが可能な冷凍食品を提供することができる。 In addition, the present invention can provide frozen foods that, when heated, reduce the unpleasant odor and dripping that are characteristic of frozen foods, and can prevent deterioration in taste and quality.

1.容器入り冷凍食品組成物
本発明は、冷凍食品組成物が容器に収納されてなる、容器入り冷凍食品組成物に関するものである。
1. Containerized Frozen Food Composition The present invention relates to a containerized frozen food composition, which is a frozen food composition contained in a container.

本発明における冷凍食品組成物には食材と共に、常温のときに液体である液部が含まれ、当該液部は食材に満遍なく行き渡り付着し、食材と共に冷凍されている。 The frozen food composition of the present invention contains food ingredients as well as a liquid portion that is liquid at room temperature, and this liquid portion spreads evenly over and adheres to the food ingredients and is frozen together with the food ingredients.

本発明において「液部」は、油脂、調味料、必要に応じて水を含んでなり、25℃及びせん断速度1(1/s)における粘度が120mPa・s超であることを特徴とするものである。本発明において「常温のときに液体である」とは、上記所定の粘度を有する限り、常温のときに液体の形態、あるいは、ゾル及びゲル等の半固体/半液体の形態が含まれる。「液部」が、上記所定の粘度及び形態を有することによって、食材と混合させた場合に、当該液部を当該食材に満遍なく行き渡らせ、付着させることができる。 In the present invention, the "liquid portion" comprises fats and oils, seasonings, and water as necessary, and is characterized by having a viscosity of more than 120 mPa·s at 25°C and a shear rate of 1 (1/s). In the present invention, "being liquid at room temperature" includes being in a liquid form at room temperature, or in a semi-solid/semi-liquid form such as sol and gel, so long as it has the above-mentioned specified viscosity. When the "liquid portion" has the above-mentioned specified viscosity and form, when it is mixed with food ingredients, the liquid portion can be distributed evenly over and adhere to the food ingredients.

なお、本明細書中、前記「液部」のことを「冷凍食材用調味料組成物」と記載する場合があるが、本明細書中これらの用語は相互互換的に用いることができる。 In this specification, the "liquid portion" may be referred to as the "seasoning composition for frozen food materials," and these terms may be used interchangeably.

本発明において「油脂」とは食用油脂であり、例えば、植物由来の油脂(例えば、キャノーラ油、菜種白絞油、菜種サラダ油、大豆油、コーン油、綿実油、落花生油、ゴマ油、米油、米糠油、ツバキ油、ベニバナ油、オリーブ油、アマニ油、シソ油、エゴマ油、ヒマワリ油、パーム油、茶油、ヤシ油、アボガド油、ククイナッツ油、グレープシード油、ココアバター、ココナッツ油、小麦胚芽油、アーモンド油、月見草油、ひまし油、ヘーゼルナッツ油、マカダミアナッツ油、ローズヒップ油、ブドウ油、カカオ油、ホホバ油、パーム核油、モクロウ、キャンデリラロウ、カルナバロウ等)、動物由来の油脂(牛脂、豚油、豚脂、ラノリン、スクワレン、スクワラン、ミツロウ、鯨ロウ等)、及びこれらの極度硬化油脂、エステル交換油脂等を挙げることができる(これらに限定はされない)。好ましくは、上昇融点が30℃未満の液状油脂を用いる。 In the present invention, "oils and fats" refers to edible oils and fats, and includes, for example, vegetable-derived oils and fats (e.g., canola oil, rapeseed white oil, rapeseed salad oil, soybean oil, corn oil, cottonseed oil, peanut oil, sesame oil, rice oil, rice bran oil, camellia oil, safflower oil, olive oil, linseed oil, perilla oil, perilla oil, sunflower oil, palm oil, tea oil, coconut oil, avocado oil, kukui nut oil, grapeseed oil, cocoa butter, coconut oil, wheat germ oil, Examples of suitable oils include, but are not limited to, almond oil, evening primrose oil, castor oil, hazelnut oil, macadamia nut oil, rosehip oil, grape oil, cacao oil, jojoba oil, palm kernel oil, Japan wax, candelilla wax, carnauba wax, etc.), animal-derived oils and fats (beef tallow, lard, lard, lanolin, squalene, squalane, beeswax, whale wax, etc.), and their extremely hardened oils and fats, transesterified oils and fats. Preferably, a liquid oil and fat with an ascending melting point of less than 30°C is used.

本発明において、油脂はいずれか単独で用いてもよいし、異なる油脂を組み合わせて用いてもよい。異なる油脂を組み合わせる場合はそれぞれの油脂を任意の量で含めることができ、その量は本発明の冷凍食品組成物に含まれる液部の粘度が後述する所望の値となる範囲になるように適宜調整することができる。 In the present invention, any one of the oils and fats may be used alone, or different oils and fats may be used in combination. When different oils and fats are combined, each oil and fat may be included in any amount, and the amount may be appropriately adjusted so that the viscosity of the liquid portion contained in the frozen food composition of the present invention falls within the range of the desired value described below.

本発明において、油脂は前記液部100質量%(常温時)に対して、15質量%超の量で含まれる。油脂を前記液部に対して15質量%超の量で含めることによって、冷凍前の前記液部に滑らかさを付与することができ、食材と混合した際に、食材に満遍なく行き渡らせることができる。油脂は前記液部100質量%に対して、15質量%超、例えば、20質量%以上、25質量%以上、30質量%以上、35質量%以上、40質量%以上、45質量%以上、50質量%以上、55質量%以上、60質量%以上、65質量%以上、70質量%以上、75質量%以上、80質量%以上、又は85質量%以上の量で含まれ、その上限は特に限定されるものではないが、例えば、95質量%以下、90質量%以下、85質量%以下、80質量%以下、75質量%以下、又は70質量%以下とすることができる。本発明における油脂の量の範囲は前記下限及び上限の数値よりそれぞれ選択される2つの数値を用いて表すことができ、例えば、油脂は前記液部100質量%に対して、15質量%超~95質量%以下、20質量%以上~90質量%以下、25質量%以上~85質量%以下、30質量%以上~80質量%以下の範囲より適宜選択される量にて含めることができる。 In the present invention, the fats and oils are contained in an amount of more than 15% by mass relative to 100% by mass of the liquid portion (at room temperature). By containing fats and oils in an amount of more than 15% by mass relative to the liquid portion, it is possible to impart smoothness to the liquid portion before freezing, and when mixed with food materials, it is possible to distribute the fats and oils evenly throughout the food materials. The fats and oils are contained in an amount of more than 15% by mass relative to 100% by mass of the liquid portion, for example, 20% by mass or more, 25% by mass or more, 30% by mass or more, 35% by mass or more, 40% by mass or more, 45% by mass or more, 50% by mass or more, 55% by mass or more, 60% by mass or more, 65% by mass or more, 70% by mass or more, 75% by mass or more, 80% by mass or more, or 85% by mass or more, and the upper limit is not particularly limited, but can be, for example, 95% by mass or less, 90% by mass or less, 85% by mass or less, 80% by mass or less, 75% by mass or less, or 70% by mass or less. The range of the amount of fats and oils in the present invention can be expressed using two numerical values selected from the lower and upper numerical values, respectively. For example, the amount of fats and oils can be appropriately selected from the ranges of more than 15% by mass to 95% by mass or less, 20% by mass to 90% by mass or less, 25% by mass to 85% by mass or less, and 30% by mass to 80% by mass or less, relative to 100% by mass of the liquid portion.

本発明に利用する油脂には、極度硬化油脂を含めることができる。「極度硬化油脂」とは、不飽和脂肪酸がほとんど存在しなくなるまで、すなわちヨウ素価が実質的に0(通常は2~3以下)になるまで水素添加を施した油脂であって、硬度が高く、融点も50~70℃と高い固形油脂を意味する。このような極度硬化油脂としては、例えば、菜種油、大豆油、コーン油、サフラワー油、ヒマワリ油、オリーブ油、米ぬか油、綿実油、パーム油、パーム分別油、からし油、ラード、牛脂等(これらに限定はされない)から選択される油脂から調製された極度硬化油脂が挙げられる。 The oils and fats used in the present invention may include extremely hydrogenated oils and fats. "Extremely hydrogenated oils and fats" refers to oils and fats that have been hydrogenated until there is almost no unsaturated fatty acid present, i.e., until the iodine value is substantially 0 (usually 2 to 3 or less), and that have a high hardness and a high melting point of 50 to 70°C. Examples of such extremely hydrogenated oils and fats include extremely hydrogenated oils and fats prepared from oils and fats selected from the group consisting of rapeseed oil, soybean oil, corn oil, safflower oil, sunflower oil, olive oil, rice bran oil, cottonseed oil, palm oil, palm fractionated oil, mustard oil, lard, beef tallow, etc. (but are not limited to these).

本発明において、極度硬化油脂は前記液部の粘度が上記所定の範囲内となる限りにおいて、任意の量で含むことができ、用いる油脂の種類に応じて適宜選択し得るが、例えば、前記液部100質量%(常温時)に対して、2質量%超、3質量%以上、好ましくは4質量%以上(例えば、5質量%以上)、より好ましくは6質量%以上の量で含み、その上限は特に限定されるものではないが、例えば、90質量%以下、80質量%以下、70質量%以下、60質量%以下、50質量%以下、40質量%以下、30質量%以下、20質量%以下、又は10質量%以下とすることができる。本発明における極度硬化油脂の量の範囲は前記下限及び上限の数値よりそれぞれ選択される2つの数値を用いて表すことができ、例えば、極度硬化油脂は前記液部100質量%に対して、2質量%超~90質量%以下、3質量%以上~90質量%以下、好ましくは4質量%以上~80質量%以下、より好ましくは6質量%以上~70質量%以下の範囲より適宜選択される量にて含めることができる。本発明において、極度硬化油脂を含めることによって、前記液部の粘度を調整することができる。 In the present invention, the extremely hydrogenated oils and fats may be contained in any amount as long as the viscosity of the liquid portion is within the above-mentioned specified range, and may be appropriately selected depending on the type of oil and fat used. For example, the amount may be more than 2% by mass, 3% by mass or more, preferably 4% by mass or more (e.g., 5% by mass or more), and more preferably 6% by mass or more, relative to 100% by mass of the liquid portion (at room temperature). The upper limit is not particularly limited, and may be, for example, 90% by mass or less, 80% by mass or less, 70% by mass or less, 60% by mass or less, 50% by mass or less, 40% by mass or less, 30% by mass or less, 20% by mass or less, or 10% by mass or less. The range of the amount of extremely hardened oils and fats in the present invention can be expressed using two numerical values selected from the above lower and upper limits, and for example, the extremely hardened oils and fats can be included in an amount appropriately selected from the range of more than 2% by mass to 90% by mass or less, 3% by mass to 90% by mass or less, preferably 4% by mass to 80% by mass or less, and more preferably 6% by mass to 70% by mass or less, relative to 100% by mass of the liquid portion. In the present invention, the viscosity of the liquid portion can be adjusted by including the extremely hardened oils and fats.

「調味料」とは、飲食品の製造において、食材の風味付けや味付けに用いられる一般的な材料を意味し、本発明においては、冷凍食品組成物の所望の形態(風味付けや味付け)に応じて、適当な調味料を適宜選択することができる。「調味料」としては例えば、食塩、水溶性デキストリン、グルタミン酸ソーダ、ブドウ糖、グラニュー糖、上白糖、クエン酸、造粒塩、岩塩、イノシン酸、グアニル酸、味噌、醤油、酢、香辛料(例えば、アジョワン、アニス、エシャロット、オールスパイス、オニオン、オレガノ、カファライム、カホクザンショウ(花椒)、カルダモン、カレーリーフ、キャラウェイ、クミン、グリーンペッパー、クローブ、ゴマ、コショウ、コリアンダー(パクチー)、サフラン、山椒、シソ、シナモン、生姜、スターアニス、セージ、タイム、ターメリック、タデ、タラゴン、チンピ、ディル、トウガラシ、ナツメグ、ニラ、ニンニク、ネギ、バジル、パセリ、バニラ、パプリカ、ハラペーニョ、フェヌグリーク、フェンネル、ホースラディッシュ、マージョラム、マスタード、ミカン、ミント、ラディッシュ、レモン、レモングラス、ローズマリー、ローリエ、ワサビ、五香粉、ガラムマサラ、カレー粉、七味唐辛子、柚子胡椒(柚子唐辛子))、甘味料(例えば、アスパルテーム、アセスルファムカリウム、カンゾウ抽出物、キシリトール、サッカリン、サッカリンナトリウム、ステビア、D-ソルビトール等)、酸味料(例えば、アジピン酸、クエン酸、コハク酸、氷酢酸、酢酸ナトリウム、酒石酸、フマル酸、フマル酸ナトリウム等)、苦味料(カフェイン、ナリンジン、ニガヨモギ抽出物)等が挙げられるが、これらに限定はされない。調味料はいずれか単独で用いてもよいし、異なる調味料を組み合わせて用いてもよい。 "Seasoning" refers to a common ingredient used to flavor or season ingredients in the production of food and beverages. In the present invention, an appropriate seasoning can be selected depending on the desired form (flavoring or seasoning) of the frozen food composition. Examples of "seasonings" include salt, water-soluble dextrin, monosodium glutamate, glucose, granulated sugar, white sugar, citric acid, granulated salt, rock salt, inosinic acid, guanylic acid, miso, soy sauce, vinegar, spices (e.g., ajowan, anise, shallot, allspice, onion, oregano, kaffir lime, Chinese pepper, cardamom, curry leaves, caraway, cumin, green pepper, cloves, sesame, pepper, coriander, saffron, Japanese pepper, shiso, cinnamon, ginger, star anise, sage, thyme, turmeric, knotweed, tarragon, chimpi, dill, chili pepper, nutmeg, chives, garlic, green onions, basil, parsley, vanilla, paprika) , jalapeno, fenugreek, fennel, horseradish, marjoram, mustard, mandarin orange, mint, radish, lemon, lemongrass, rosemary, bay leaf, wasabi, five-spice powder, garam masala, curry powder, shichimi pepper, yuzu pepper (yuzu pepper)), sweeteners (e.g., aspartame, acesulfame potassium, licorice extract, xylitol, saccharin, saccharin sodium, stevia, D-sorbitol, etc.), acidulants (e.g., adipic acid, citric acid, succinic acid, glacial acetic acid, sodium acetate, tartaric acid, fumaric acid, sodium fumarate, etc.), bittering agents (caffeine, naringin, wormwood extract), etc., but are not limited to these. Any of the seasonings may be used alone, or different seasonings may be used in combination.

本発明において「調味料」は、食材へ所望の風味付けや味付けを行うことが可能な任意の量で含むことができ、利用する食材や調味料の種類等の要因に応じて適宜選択し得るものであり、特に限定されるものではないが、例えば、前記液部100質量%(常温時)に対して、4質量%超、好ましくは5質量%以上、より好ましくは6質量%以上、例えば、10質量%以上、20質量%以上、30質量%以上、40質量%以上、50質量%以上、又は60質量%以上の量で含み、その上限は特に限定されるものではないが、例えば、90質量%以下、85質量%以下、80質量%以下、又は70質量%以下とすることができる。本発明における調味料の量の範囲は前記下限及び上限の数値よりそれぞれ選択される2つの数値を用いて表すことができ、例えば、調味料は前記液部100質量%に対して、4質量%超~90質量%以下、好ましくは5質量%以上~90質量%以下、より好ましくは6質量%以上~90質量%以下、例えば、10質量%以上~80質量%以下、又は20質量%以上~70質量%以下の範囲より適宜選択される量にて含めることができる。 In the present invention, "seasoning" can be included in any amount that is capable of imparting the desired flavor or seasoning to the food material, and can be appropriately selected depending on factors such as the type of food material and seasoning used. It is not particularly limited, but for example, it can be included in an amount of more than 4% by mass, preferably 5% by mass or more, more preferably 6% by mass or more, for example, 10% by mass or more, 20% by mass or more, 30% by mass or more, 40% by mass or more, 50% by mass or more, or 60% by mass or more, relative to 100% by mass of the liquid portion (at room temperature). The upper limit is not particularly limited, but can be, for example, 90% by mass or less, 85% by mass or less, 80% by mass or less, or 70% by mass or less. The range of the amount of seasoning in the present invention can be expressed using two numerical values selected from the lower and upper numerical values, respectively. For example, the seasoning can be included in an amount appropriately selected from the range of more than 4% by mass to 90% by mass or less, preferably 5% by mass to 90% by mass or less, more preferably 6% by mass to 90% by mass or less, for example, 10% by mass to 80% by mass or less, or 20% by mass to 70% by mass or less, relative to 100% by mass of the liquid portion.

本発明において、「水」は前記液部の粘度が上記所定の範囲内となる限りにおいて、任意の量で含むことができ、例えば、前記液部100質量%(常温時)に対して、15質量%未満、例えば、10質量%以下、9質量%以下、8質量%以下、7質量%以下、又は6質量%以下の量で含み、その下限は特に限定されるものではないが、例えば、0質量%以上(「0質量%又はそれを超える量」を意味し、「0質量%」の場合は、水を含まないことを意味する)、1質量%以上、2質量%以上、3質量%以上、4質量%以上、又は5質量%以上とすることができる。本発明における水の量の範囲は前記上限及び下限の数値よりそれぞれ選択される2つの数値を用いて表すことができ、例えば、水は前記液部100質量%に対して、0質量%以上~15質量%未満、0質量%以上~10質量%以下、0質量%以上~8質量%以下、0質量%以上~6質量%以下、1質量%以上~10質量%以下、2質量%以上~9質量%以下、又は3質量%以上~8質量%以下の範囲より適宜選択される量にて含めることができる。水を前記液部100質量%に対して、15質量%以上の量で含む場合には、前記液部について、上記所望の粘度を得ることができない場合があり、また油脂と水の分離を生じ、食材との混合において当該食材に満遍なく行き渡らせ付着させることが困難となる場合がある。 In the present invention, "water" can be included in any amount so long as the viscosity of the liquid portion is within the above-mentioned specified range, and for example, the amount is less than 15% by mass, for example, 10% by mass or less, 9% by mass or less, 8% by mass or less, 7% by mass or less, or 6% by mass or less, relative to 100% by mass of the liquid portion (at room temperature). The lower limit is not particularly limited, and can be, for example, 0% by mass or more (meaning "0% by mass or more", and "0% by mass" means that no water is included), 1% by mass or more, 2% by mass or more, 3% by mass or more, 4% by mass or more, or 5% by mass or more. The range of the amount of water in the present invention can be expressed using two numerical values selected from the upper and lower numerical values, respectively. For example, water can be included in an amount appropriately selected from the range of 0% by mass or more to less than 15% by mass, 0% by mass or more to 10% by mass or less, 0% by mass or more to 8% by mass or less, 0% by mass or more to 6% by mass or less, 1% by mass or more to 10% by mass or less, 2% by mass or more to 9% by mass or less, or 3% by mass or more to 8% by mass or less, relative to 100% by mass of the liquid portion. If water is included in an amount of 15% by mass or more relative to 100% by mass of the liquid portion, it may not be possible to obtain the desired viscosity for the liquid portion, and separation of the oil and water may occur, making it difficult to distribute and adhere evenly to the food material when mixed with the food material.

本発明において、前記液部の粘度は、25℃及びせん断速度1(1/s)における値が120mPa・s超、例えば、200mPa以上、300mPa以上、400mPa以上、500mPa以上、又は600mPa以上、好ましくは700mPa以上、より好ましくは800mPa・s以上(例えば、900mPa以上)、さらに好ましくは1Pa・s以上(例えば、1.2Pa・s以上、1.4Pa・s以上、1.6Pa・s以上、1.8Pa・s以上、2Pa・s以上、4Pa・s以上、6Pa・s以上、又は8Pa・s以上)、よりさらに好ましくは10Pa・s以上(例えば、15Pa・s以上、20Pa・s以上、25Pa・s以上、又は30Pa・s以上)であり、その上限は特に限定されるものではないが、例えば、800Pa・s以下、700Pa・s以下、600Pa・s以下、500Pa・s以下、400Pa・s以下、300Pa・s以下、又は200Pa・s以下とすることができる。前記条件における前記液部の粘度は、前記上限及び下限の数値よりそれぞれ選択される2つの数値を用いて表すことができ、例えば、120mPa・s超~800Pa・s以下、好ましくは700mPa・s超~800Pa・s以下、より好ましくは800mPa・s以上~700Pa・s以下、さらに好ましくは1Pa・s以上~600Pa・s以下、よりさらに好ましくは10Pa・s以上~400Pa・s以下の範囲より適宜選択される値とすることができる。前記液部に一定の粘性を付与する事で、食材と混合させた場合に、当該食材に前記液部を満遍なく行き渡らせることができ、これにより凍結後の冷凍食品組成物を手で容易にほぐすことを可能とし、また冷凍食品組成物を加熱処理した場合に、冷凍焼け(乾燥)を防ぐことができ、またドリップの発生を抑えることができ、また食材にムラなく風味付けや味付けをすることができ、また冷凍された食品特有のいやな臭いを低減することができる。 In the present invention, the viscosity of the liquid portion at 25°C and a shear rate of 1 (1/s) is greater than 120 mPa·s, for example, 200 mPa or more, 300 mPa or more, 400 mPa or more, 500 mPa or more, or 600 mPa or more, preferably 700 mPa or more, more preferably 800 mPa·s or more (for example, 900 mPa or more), and even more preferably 1 Pa·s or more (for example, 1.2 Pa·s or more, 1.4 Pa·s or more, 1.6 Pa·s or more, 1.8 Pa·s or more). , 2 Pa·s or more, 4 Pa·s or more, 6 Pa·s or more, or 8 Pa·s or more), and even more preferably 10 Pa·s or more (for example, 15 Pa·s or more, 20 Pa·s or more, 25 Pa·s or more, or 30 Pa·s or more), and the upper limit is not particularly limited, but can be, for example, 800 Pa·s or less, 700 Pa·s or less, 600 Pa·s or less, 500 Pa·s or less, 400 Pa·s or less, 300 Pa·s or less, or 200 Pa·s or less. The viscosity of the liquid portion under the above conditions can be expressed using two values selected from the upper and lower limit values, and can be, for example, a value appropriately selected from the range of more than 120 mPa·s to 800 Pa·s, preferably more than 700 mPa·s to 800 Pa·s, more preferably 800 mPa·s to 700 Pa·s, even more preferably 1 Pa·s to 600 Pa·s, and even more preferably 10 Pa·s to 400 Pa·s. By imparting a certain viscosity to the liquid portion, when mixed with foodstuffs, the liquid portion can be evenly distributed over the foodstuffs, which makes it possible to easily loosen the frozen food composition by hand after freezing, and when the frozen food composition is heat-treated, freezer burn (drying) can be prevented, drips can be suppressed, foodstuffs can be evenly flavored and seasoned, and the unpleasant odors peculiar to frozen foods can be reduced.

前記粘度は、直径1mmの粒子を超えるサイズを有する固体を取り除いたサンプルを、回転式粘弾性測定装置(Anton Paar社製MCR102)を用いCYLINDER B-CC25のボブシリンダー、25℃にて、ずり速度0.1s-1から31s-1までの間を低ずり速度側から測定することにより測定することができる。 The viscosity can be measured by removing solid particles having a diameter exceeding 1 mm from a sample, using a rotational viscoelasticity measuring device (MCR102 manufactured by Anton Paar) with a CYLINDER B-CC25 bob cylinder at 25° C., and measuring the viscosity from the low shear rate side at shear rates between 0.1 s and 31 s.

前記液部の粘度は、油脂(特に、極度硬化油脂)の配合によって調整することができる。ならびに/あるいは、前記液部の粘度は、油系増粘剤をさらに配合することによって調整してもよい。「油系増粘剤」とは、液状の油脂に添加して溶解することにより、当該油脂を増粘、固化、及び/又はゾル・ゲル化することが可能な物質を意味する。このような油系増粘剤としては、脂肪酸とポリグリセリンとを構成成分として含む、ポリグリセリン脂肪酸エステルを好適に用いることができる。 The viscosity of the liquid portion can be adjusted by blending fats and oils (particularly, highly hydrogenated fats and oils). And/or the viscosity of the liquid portion can be adjusted by further blending an oil-based thickener. An "oil-based thickener" refers to a substance that can thicken, solidify, and/or sol-gel a liquid fat and oil by being added to and dissolved in the liquid fat and oil. As such an oil-based thickener, a polyglycerin fatty acid ester, which contains fatty acids and polyglycerin as constituents, can be suitably used.

油系増粘剤のポリグリセリン脂肪酸エステルを構成する脂肪酸(以下、「構成脂肪酸」と記載する)については、全構成脂肪酸の内、炭素数16~18の直鎖脂肪酸が分子数として45%以上含まれる場合に高い粘度を得ることができる。この割合は、全構成脂肪酸のモル数に対する炭素数16~18の直鎖脂肪酸のモル数の割合を示す。 With regard to the fatty acids constituting the polyglycerol fatty acid ester of the oil-based thickener (hereinafter referred to as "constituent fatty acids"), high viscosity can be obtained when linear fatty acids with 16 to 18 carbon atoms make up 45% or more of the total constituent fatty acids in terms of molecular number. This ratio indicates the ratio of the number of moles of linear fatty acids with 16 to 18 carbon atoms to the number of moles of all constituent fatty acids.

構成脂肪酸には、炭素数8~14の直鎖脂肪酸、炭素数18~22の分岐脂肪酸及び炭素数18~22の不飽和脂肪酸のいずれかを含む事が好ましい。 The constituent fatty acids preferably include any of straight-chain fatty acids having 8 to 14 carbon atoms, branched fatty acids having 18 to 22 carbon atoms, and unsaturated fatty acids having 18 to 22 carbon atoms.

構成脂肪酸として、(a)炭素数16~22の直鎖飽和脂肪酸を少なくとも1種以上、(b)炭素数8~14の直鎖飽和脂肪酸、炭素数18~22の分岐脂肪酸及び炭素数18~22の不飽和脂肪酸からなる群より選択される少なくとも1種以上が挙げられる。構成脂肪酸における脂肪酸(a)と脂肪酸(b)の比率をモル比にして、0.91:0.09~0.99:0.01とするとき、低添加量にて粘度が高く、長期間油脂の分離を抑えることができる。 The constituent fatty acids include (a) at least one type of linear saturated fatty acid having 16 to 22 carbon atoms, and (b) at least one type selected from the group consisting of linear saturated fatty acids having 8 to 14 carbon atoms, branched fatty acids having 18 to 22 carbon atoms, and unsaturated fatty acids having 18 to 22 carbon atoms. When the molar ratio of fatty acid (a) to fatty acid (b) in the constituent fatty acids is 0.91:0.09 to 0.99:0.01, the viscosity is high even with a small amount added, and separation of oils and fats can be suppressed for a long period of time.

脂肪酸(a)としては、パルミチン酸、ステアリン酸、アラキジン酸、ベヘン酸等が挙げられるが、これらに限定されるものではない。脂肪酸(b)としては、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、オレイン酸、エルカ酸、イソステアリン酸等が挙げられるが、これらに限定されるものではない。 Fatty acids (a) include, but are not limited to, palmitic acid, stearic acid, arachidic acid, behenic acid, etc. Fatty acids (b) include, but are not limited to, caprylic acid, capric acid, lauric acid, myristic acid, oleic acid, erucic acid, isostearic acid, etc.

ポリグリセリン脂肪酸エステルを構成するポリグリセリンについては、水酸基価に基づく平均重合度が10以上のものを用いるのが好ましい。平均重合度が10未満であるポリグリセリンを用いた場合、十分な粘度は得られず、長期間油脂の分離を抑えることができない場合がある。より好ましくは、ポリグリセリンの平均重合度は20以上であり、さらに好ましくは30以上、よりさらに好ましくは40以上であり、平均重合度が高い程、粘度が高くなり、低添加量で固化を達成することができる。 The polyglycerin constituting the polyglycerin fatty acid ester preferably has an average degree of polymerization based on the hydroxyl value of 10 or more. If a polyglycerin with an average degree of polymerization of less than 10 is used, sufficient viscosity cannot be obtained, and separation of oils and fats may not be suppressed for a long period of time. More preferably, the average degree of polymerization of polyglycerin is 20 or more, even more preferably 30 or more, and even more preferably 40 or more. The higher the average degree of polymerization, the higher the viscosity, and solidification can be achieved with a small amount added.

ポリグリセリンの水酸基価に基づく平均重合度は、従来公知の手法(特開2018-42550号公報)にしたがって、末端基分析法、水酸基価は社団法人日本油化学会編「日本油化学会制定 基準油脂分析試験法(I)1996年度版」に準じて算出することができる。 The average degree of polymerization of polyglycerol based on the hydroxyl value can be calculated according to the terminal group analysis method and the hydroxyl value according to the 1996 edition of the Standard Methods for Analysis of Fats, Oils and Related Materials (I) Established by the Japan Oil Chemists' Society, edited by the Japan Oil Chemists' Society.

ポリグリセリン脂肪酸エステルのエステル化率は、70%以上であることが好ましい。エステル化率が70%未満である場合、十分な粘度は得られず、長期間油脂の分離を抑えることができない場合がある。より好ましくは、ポリグリセリン脂肪酸エステルのエステル化率は80%以上であり、さらに好ましくは90%以上であり、エステル化率が高い程、粘度が高くなり、低添加量で固化を達成することができる。 The esterification rate of the polyglycerol fatty acid ester is preferably 70% or more. If the esterification rate is less than 70%, sufficient viscosity cannot be obtained, and separation of oils and fats may not be suppressed for a long period of time. More preferably, the esterification rate of the polyglycerol fatty acid ester is 80% or more, and even more preferably 90% or more. The higher the esterification rate, the higher the viscosity, and solidification can be achieved with a small amount added.

エステル化率は、従来公知の手法(特開2018-42550号公報)にしたがって算出することができる。 The esterification rate can be calculated according to a conventional method (JP Patent Publication No. 2018-42550).

本発明においてポリグリセリン脂肪酸エステルは常法にしたがって製造されたものを用いることができ、より詳細には、上記の各成分を、上記条件を満たすような組成で仕込み、水酸化ナトリウム等の触媒を加えて、常圧又は減圧下におけるエステル化反応に付すことにより製造されたものを用いることができる。また、本発明においてポリグリセリン脂肪酸エステルは市販品を利用してもよく、例えば、TAISET AD(太陽化学株式会社)、TAISET50(太陽化学株式会社)、リョートーポリグリエステルB-100D(三菱化学フーズ株式会社)等を好適に用いることができる。 In the present invention, the polyglycerol fatty acid ester may be one produced according to a conventional method, and more specifically, one produced by charging the above-mentioned components in a composition that satisfies the above-mentioned conditions, adding a catalyst such as sodium hydroxide, and subjecting the mixture to an esterification reaction under normal pressure or reduced pressure may be used. In addition, the polyglycerol fatty acid ester may be a commercially available product, and for example, TAISET AD (Taiyo Kagaku Co., Ltd.), TAISET 50 (Taiyo Kagaku Co., Ltd.), Ryoto Polyglycerol B-100D (Mitsubishi Chemical Foods Co., Ltd.), etc. may be suitably used.

本発明において、前記液部には必要に応じてさらに、飲食品の製造において通常用いられている、賦形剤、滑沢剤、結合剤、崩壊剤等の添加剤を含めることができる。 In the present invention, the liquid portion may further contain additives, such as excipients, lubricants, binders, and disintegrants, that are commonly used in the manufacture of foods and beverages, as necessary.

賦形剤としては、例えば、乳糖、白糖、D-マンニトール、D-ソルビトール、デンプン、α化デンプン、デキストリン、ブドウ糖、コーンスターチ、結晶セルロース、低置換度ヒドロキシプロピルセルロース、カルボキシメチルセルロースナトリウム、アラビアゴム、プルラン、軽質無水ケイ酸、合成ケイ酸アルミニウム、メタケイ酸アルミン酸マグネシウム等が挙げられる。 Examples of excipients include lactose, sucrose, D-mannitol, D-sorbitol, starch, pregelatinized starch, dextrin, glucose, corn starch, crystalline cellulose, low-substituted hydroxypropyl cellulose, sodium carboxymethylcellulose, gum arabic, pullulan, light anhydrous silicic acid, synthetic aluminum silicate, magnesium aluminometasilicate, etc.

滑沢剤としては、例えば、ショ糖脂肪酸エステル等のシュガーエステル類、ステアリン酸カルシウム、ステアリン酸マグネシウム、ステアリン酸、ステアリルアルコール、サラシミツロウ等のロウ類、タルク、ケイ酸、ケイ素等が挙げられる。 Examples of lubricants include sugar esters such as sucrose fatty acid esters, calcium stearate, magnesium stearate, stearic acid, stearyl alcohol, waxes such as white beeswax, talc, silicic acid, silicon, etc.

結合剤としては、例えば、α化デンプン、ショ糖、ゼラチン、アラビアゴム、メチルセルロース、カルボキシメチルセルロース、カルボキシメチルセルロースナトリウム、結晶セルロース、白糖、D-マンニトール、トレハロース、デキストリン、プルラン、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、ポリビニルピロリドン等が挙げられる。 Binders include, for example, pregelatinized starch, sucrose, gelatin, gum arabic, methylcellulose, carboxymethylcellulose, sodium carboxymethylcellulose, crystalline cellulose, sucrose, D-mannitol, trehalose, dextrin, pullulan, hydroxypropylcellulose, hydroxypropylmethylcellulose, polyvinylpyrrolidone, etc.

崩壊剤としては、例えば、乳糖、白糖、デンプン、カルボキシメチルセルロース、カルボキシメチルセルロースカルシウム、クロスカルメロースナトリウム、カルボキシメチルスターチナトリウム、軽質無水ケイ酸、低置換度ヒドロキシプロピルセルロース等が挙げられる。 Examples of disintegrants include lactose, sucrose, starch, carboxymethylcellulose, calcium carboxymethylcellulose, croscarmellose sodium, sodium carboxymethylstarch, light anhydrous silicic acid, and low-substituted hydroxypropylcellulose.

また、本発明において、前記液部には、必要に応じてさらに、飲食品の製造において通常用いられている、アミノ酸(例えばグルタミン、システイン、ロイシン、アルギニン等)、多価アルコール(例えばエチレングリコール、ポリエチレングリコール、プロピレングリコール、グリセリン、糖アルコール等)、天然高分子(例えば、レシチン、澱粉、デキストリン等)、ビタミン(例えばビタミンC、ビタミンB群等)、ミネラル(例えばカルシウム、マグネシウム、亜鉛、鉄等)、食物繊維(例えばマンナン、ペクチン、ヘミセルロース等)、界面活性剤(例えばソルビタン脂肪酸エステル等)、希釈剤、安定化剤、等張化剤、pH調製剤、緩衝剤、湿潤剤、溶解補助剤、懸濁化剤、着色剤、矯味剤、矯臭剤、香料、酸化防止剤等のその他の成分を適宜含めることができる。 In addition, in the present invention, the liquid portion may further contain other ingredients, as necessary, that are commonly used in the manufacture of foods and beverages, such as amino acids (e.g., glutamine, cysteine, leucine, arginine, etc.), polyhydric alcohols (e.g., ethylene glycol, polyethylene glycol, propylene glycol, glycerin, sugar alcohols, etc.), natural polymers (e.g., lecithin, starch, dextrin, etc.), vitamins (e.g., vitamin C, B vitamins, etc.), minerals (e.g., calcium, magnesium, zinc, iron, etc.), dietary fiber (e.g., mannan, pectin, hemicellulose, etc.), surfactants (e.g., sorbitan fatty acid esters, etc.), diluents, stabilizers, isotonicity agents, pH adjusters, buffers, wetting agents, solubilizers, suspending agents, colorants, flavorings, odorants, fragrances, antioxidants, etc.

本発明において、前記液部には賦形剤、滑沢剤、結合剤、崩壊剤等の添加剤やその他の成分を、前記液部の上記所定の粘度や形態、所望される効果を妨げない範囲の量で適宜配合することができる。 In the present invention, additives such as excipients, lubricants, binders, disintegrants, and other components can be appropriately blended into the liquid portion in amounts that do not interfere with the above-mentioned specified viscosity, form, or desired effect of the liquid portion.

本発明の容器入り冷凍食品組成物は、食材と前記液部(又は後述の「冷凍食材用調味料組成物」)を混合し、得られた混合物を冷凍する工程を含む製造方法により得ることができる。 The containerized frozen food composition of the present invention can be obtained by a manufacturing method including the steps of mixing food ingredients with the liquid portion (or the "seasoning composition for frozen food ingredients" described below) and freezing the resulting mixture.

「食材」は、冷凍食品組成物の所望の形態に応じて適宜選択することができ、例えば、野菜類、肉類、魚類、豆類、穀類、卵類等の一又は複数を含めることができ、食材は下処理済みのもの、加熱済みのもの、調理済みのものや、加工品等であってもよいし、あるいは未調理、未加熱のもの等であってもよく、あるいはそれらの加熱品、冷凍品等であってもよい。好ましくは「食材」は、前記液部(又は冷凍食材用調味料組成物)により風味付けや味付けが可能な素材又は素材に近いものである。 The "foodstuff" can be appropriately selected depending on the desired form of the frozen food composition, and can include, for example, one or more of vegetables, meat, fish, beans, grains, eggs, etc., and the foodstuff may be pre-processed, heated, cooked, processed, etc., or uncooked, uncooked, etc., or may be a heated or frozen product thereof. Preferably, the "foodstuff" is a material or a material similar to a material that can be flavored or seasoned with the liquid portion (or the seasoning composition for frozen foodstuffs).

食材と前記液部との混合において、両者の混合比は特に限定されず、すべての食材の全体に前記液部が満遍なく行き渡ることが可能な量であればよく、食材の種類、形態、量等の要因に応じて適宜選択することができる。例えば、本発明の容器入り冷凍食品組成物において、食材100gに対して、前記液部が2~100g、好ましくは5~80g、好ましくは8~60g、より好ましくは10~50gとなる混合比(重量比)にて含まれる量にて、両者を混合することができる(これらに限定はされない)。混合は常温で行ってもよいし、0~10℃の冷蔵条件下、-1℃以下の冷凍条件下で行ってもよい。 When mixing the food ingredients with the liquid portion, the mixing ratio of the two is not particularly limited, and any amount that allows the liquid portion to be evenly distributed throughout all of the food ingredients can be selected appropriately depending on factors such as the type, form, and amount of the food ingredients. For example, in the containerized frozen food composition of the present invention, the two can be mixed in a mixing ratio (weight ratio) such that 2 to 100 g, preferably 5 to 80 g, preferably 8 to 60 g, and more preferably 10 to 50 g of the liquid portion per 100 g of food ingredients (this is not limited to these amounts). Mixing may be performed at room temperature, under refrigerated conditions of 0 to 10°C, or under frozen conditions of -1°C or below.

得られた混合物(すなわち、食品組成物)は容器に充填され密封される。容器としては内容物を取り出し可能なものであれば限定されないが、例えばパウチ状容器、口栓付きパウチ、プラスチック製のカップ容器などを利用することができる。 The resulting mixture (i.e., food composition) is filled into a container and sealed. There are no limitations on the container as long as the contents can be removed, but examples of containers that can be used include pouch-shaped containers, pouches with stoppers, and plastic cup containers.

容器に充填された前記食品組成物は、-50℃~-5℃、好ましくは-50℃~-15℃にて冷凍処理を施すことにより、容器入り冷凍食品組成物を得ることができる。得られた容器入り冷凍食品組成物は、冷凍(-30℃~-15℃、好ましくは-30℃~-5℃、更に好ましくは-30℃~-10℃)保管することができる。冷凍保管することによって、本発明の容器入り冷凍食品組成物の変質や変性を防ぐことができ、また、微生物の発育や増殖を阻止することができる。 The food composition filled in a container can be subjected to a freezing treatment at -50°C to -5°C, preferably -50°C to -15°C, to obtain a packaged frozen food composition. The packaged frozen food composition obtained can be stored frozen (-30°C to -15°C, preferably -30°C to -5°C, more preferably -30°C to -10°C). By storing it in a frozen state, it is possible to prevent the deterioration or denaturation of the packaged frozen food composition of the present invention, and also to inhibit the growth and proliferation of microorganisms.

本発明の容器入り冷凍食品組成物は、手等で簡単にほぐすことが可能であり、必要に応じて、容器より必要な分を取り分け、取り出すことが可能である。
また、本発明の容器入り冷凍食品組成物は、手等で簡単にほぐすことが可能であり、それによって加熱ムラを解消し、均一な食感を有する食品を作ることができる。
また、本発明の容器入り冷凍食品組成物は、電子レンジ等で加熱処理することにより、食材は同時に、併存する前記液部により風味付けや味付けがなされ、時間をかけて調理したような味、加熱感、柔らかな食感を有することができ、従来の冷凍食品で見受けられた加熱処理に伴うドリップの発生や冷凍された食品特有のいやな臭いの発生が低減された食品を作ることができる。
The containerized frozen food composition of the present invention can be easily loosened by hand or the like, and the required amount can be separated and removed from the container as needed.
Furthermore, the containerized frozen food composition of the present invention can be easily loosened by hand or the like, thereby eliminating uneven heating and enabling the production of food with a uniform texture.
In addition, by heating the containerized frozen food composition of the present invention in a microwave oven or the like, the ingredients are simultaneously flavored and seasoned by the coexisting liquid portion, giving the food ingredients a taste, cooked feel, and soft texture as if they had been cooked over a long period of time, and it is possible to produce a food product with reduced dripping associated with the heat treatment seen in conventional frozen foods and reduced unpleasant odors peculiar to frozen foods.

2.冷凍食材用調味料組成物
また、別の態様において、本発明は、冷凍食材用調味料組成物に関するものである。本発明の冷凍食材用調味料組成物は、冷凍された食材と共に加熱処理に付されることにより、当該食材に風味付けや味付けを行うことを可能とするものであり、このようにして処理して得られた食材は、時間をかけて調理したような味、加熱感、柔らかな食感を有することができ、従来の冷凍食品で見受けられた加熱処理に伴うドリップの発生や冷凍された食品特有のいやな臭いの発生を低減することができる。
2. Seasoning composition for frozen food materials In another aspect, the present invention relates to a seasoning composition for frozen food materials. The seasoning composition for frozen food materials of the present invention is capable of flavoring or seasoning the frozen food materials by being subjected to a heat treatment together with the frozen food materials, and the food materials obtained by such treatment can have a taste, cooked feel, and soft texture as if they had been cooked over a long period of time, and can reduce the occurrence of drips associated with heat treatments observed in conventional frozen foods and the occurrence of unpleasant odors peculiar to frozen foods.

本発明の冷凍食材用調味料組成物は、油脂、調味料、必要に応じて水を含んでなり、25℃及びせん断速度1(1/s)における粘度が120mPa・s超であることを特徴とするものである。本発明の冷凍食材用調味料組成物は、上記粘度を有する限り、常温のときに液体の形態、あるいは、ゾル及びゲル等の半固体/半液体の形態であってもよい。本発明の冷凍食材用調味料組成物が、上記粘度及び形態を有することによって、冷凍された食材又は冷凍される前の食材と混合させることにより、当該食材に満遍なく行き渡り、付着させることができる。 The seasoning composition for frozen ingredients of the present invention comprises fats and oils, seasonings, and water as necessary, and is characterized by having a viscosity of more than 120 mPa·s at 25°C and a shear rate of 1 (1/s). As long as the seasoning composition for frozen ingredients of the present invention has the above viscosity, it may be in a liquid form at room temperature, or in a semi-solid/semi-liquid form such as a sol or gel. By having the above viscosity and form, the seasoning composition for frozen ingredients of the present invention can be evenly distributed and adhered to frozen ingredients or ingredients before freezing when mixed with the ingredients.

本発明の冷凍食材用調味料組成物について、「油脂」、「調味料」、「水」、及び「粘度」は、上記「液部」において定義したとおりであり、本発明の冷凍食材用調味料組成物においても、上記定義及び配合量に従うものである。 In the seasoning composition for frozen food materials of the present invention, "oil and fat," "seasoning," "water," and "viscosity" are as defined in the "liquid portion" above, and the above definitions and amounts of ingredients are also applicable to the seasoning composition for frozen food materials of the present invention.

本発明の冷凍食材用調味料組成物には必要に応じてさらに、飲食品の製造において通常用いられている、上述の添加剤やその他の成分を含めることができる。これらは、本発明の冷凍食材用調味料組成物の上記所定の粘度や形態、所望される効果を妨げない範囲の量で適宜配合することができる。 The seasoning composition for frozen food materials of the present invention may further contain the above-mentioned additives and other ingredients that are commonly used in the manufacture of food and beverages, as necessary. These may be appropriately blended in amounts that do not interfere with the above-mentioned specified viscosity, form, or desired effect of the seasoning composition for frozen food materials of the present invention.

本発明の冷凍食材用調味料組成物は、前記組成物100質量%に対して15質量%超の油脂と15質量%未満~0質量%以上の水、及び調味料とを混合すること、ならびに、
前記組成物の25℃及びせん断速度1(1/s)における粘度が120mPa・s超とすること、を含む、製造方法により製造することができる。
なお、本方法において、「前記組成物100質量%に対して15質量%超の油脂と15質量%未満~0質量%以上の水、及び調味料とを混合すること」、ならびに、「前記組成物の25℃及びせん断速度1(1/s)における粘度が120mPa・s超とすること」とはこの順序で記載されることがあるが、これの記載は、これらの工程がこの順序で行われることを意味するものではない。
また、「前記組成物の25℃及びせん断速度1(1/s)における粘度が120mPa・s超とすること」について、この調整は、製造される冷凍食材用調味料組成物の粘度を所定の値にする油脂、調味料、水等の量が一度決定されれば、本製造方法を実施する際に毎回行われる必要はなく、当該粘度を達成可能な決定された配合で、油脂、調味料、水等を混合すればよい。
The seasoning composition for frozen food materials of the present invention is a mixture of more than 15% by mass of fats and oils, less than 15% by mass to 0% by mass or more of water, and a seasoning, based on 100% by mass of the composition; and
The composition can be produced by a production method including making the viscosity of the composition greater than 120 mPa·s at 25° C. and a shear rate of 1 (1/s).
In this method, "mixing more than 15% by mass of fat or oil, less than 15% by mass to 0% by mass or more of water, and a seasoning, relative to 100% by mass of the composition" and "having a viscosity of the composition at 25° C. and a shear rate of 1 (1/s) exceed 120 mPa·s" are sometimes described in this order, but this description does not mean that these steps are performed in this order.
Regarding "the viscosity of the composition at 25°C and a shear rate of 1 (1/s) exceeds 120 mPa·s," once the amounts of fats and oils, seasonings, water, etc. that will give the seasoning composition for frozen food materials to have a predetermined viscosity have been determined, this adjustment does not have to be made every time the present production method is carried out; it is sufficient to mix the fats and oils, seasonings, water, etc. in the determined ratio that will achieve the desired viscosity.

本発明の冷凍食材用調味料組成物は、油脂、調味料、及び必要に応じて水、ならびに必要に応じて飲食品の製造において通常用いられている、上述の添加剤やその他の成分を、それぞれ上記の量にて混合することによって製造することができる。各成分は全て一緒に加えて混合してもよいし、各成分を別々にもしくは任意の組み合わせで順次加えて(順序は問わない)混合してもよい。混合は常温で行ってもよいし、0~10℃の冷蔵条件下、-1℃以下の冷凍条件下で行ってもよい。 The seasoning composition for frozen food materials of the present invention can be produced by mixing the fats and oils, seasonings, and water as required, as well as the additives and other ingredients commonly used in the production of food and beverages as required, each in the amounts described above. All of the ingredients may be added together and mixed, or the ingredients may be added separately or in any combination and added sequentially (in any order) and mixed. Mixing may be performed at room temperature, under refrigerated conditions of 0 to 10°C, or under frozen conditions of -1°C or below.

得られた混合物(すなわち、冷凍食材用調味料組成物)は容器に充填され密封されてもよい。容器としては内容物を取り出し可能なものであれば限定されないが、例えばパウチ状容器、口栓付きパウチ、プラスチック製のカップ容器、金属缶などを利用することができる。 The resulting mixture (i.e., seasoning composition for frozen food materials) may be filled into a container and sealed. There are no limitations on the container as long as the contents can be removed, but examples of the container that can be used include pouch-shaped containers, pouches with stoppers, plastic cup containers, and metal cans.

本発明の冷凍食材用調味料組成物は、冷凍された食材と共に加熱処理に付されることにより、当該食材に風味付けや味付けを行うこと等を可能とするものである。 The seasoning composition for frozen food materials of the present invention is subjected to a heat treatment together with frozen food materials, thereby making it possible to impart flavor or seasoning to the food materials.

「食材」としては、上記のものが挙げられ、冷凍された食材、又は冷凍される前の食材と混合することができる。 "Food ingredients" include those listed above, and can be mixed with frozen food ingredients or food ingredients before freezing.

食材と本発明の冷凍食材用調味料組成物との混合において、両者の混合比は特に限定されず、食材に当該調味料組成物が満遍なく行き渡らせることを可能とする量であればよく、食材の種類や形態等の要因に応じて適宜選択することができる。例えば、食材100gに対して、当該調味料組成物を2~100g、好ましくは5~80g、より好ましくは8~60g、さらに好ましくは10~50gとなる混合比(重量比)にて、両者を混合することができる(これらに限定はされない)。冷凍された食材との混合は常温で行ってもよいし、0~10℃の冷蔵条件下、-1℃以下の冷凍条件下で行ってもよい。 When mixing food materials with the seasoning composition for frozen food materials of the present invention, the mixing ratio of the two is not particularly limited, and any amount that allows the seasoning composition to be evenly distributed over the food materials may be used, and can be appropriately selected depending on factors such as the type and form of the food materials. For example, the two can be mixed at a mixing ratio (weight ratio) of 2 to 100 g, preferably 5 to 80 g, more preferably 8 to 60 g, and even more preferably 10 to 50 g of the seasoning composition per 100 g of food materials (this is not limited to these). Mixing with frozen food materials may be performed at room temperature, under refrigerated conditions of 0 to 10°C, or under frozen conditions of -1°C or below.

冷凍された食材と本発明の冷凍食材用調味料組成物との混合物を、電子レンジ等で加熱処理することにより、食材は同時に、併存する冷凍食材用調味料組成物により風味付けや味付けがなされ、時間をかけて調理したような味、加熱感、柔らかな食感を有することができ、従来の冷凍食品で見受けられた加熱処理に伴うドリップの発生や冷凍された食品特有のいやな臭いの発生が低減された食品を作ることができる。 By subjecting a mixture of frozen food ingredients and the seasoning composition for frozen food ingredients of the present invention to a heat treatment in a microwave oven or the like, the food ingredients are simultaneously flavored and seasoned with the coexisting seasoning composition for frozen food ingredients, giving the food ingredients a taste, cooked feel, and soft texture as if they had been cooked over a long period of time, and reducing the occurrence of drips associated with heat treatments seen in conventional frozen foods and the unpleasant odors peculiar to frozen foods.

なお、冷凍される前の食材と本発明の冷凍食材用調味料組成物とを混合した場合には、当該食材と一緒に冷凍されて冷凍食品組成物を形成することができる(冷凍された食材と混合した場合においても、一緒に冷凍されて冷凍食品組成物を形成することができる)。当該冷凍食品組成物は、電子レンジ等で加熱処理することにより、食材は同時に、併存する冷凍食材用調味料組成物により風味付けや味付けがなされ、時間をかけて調理したような味、加熱感、柔らかな食感を有することができ、従来の冷凍食品で見受けられた加熱処理に伴うドリップの発生や冷凍された食品特有のいやな臭いの発生が低減された食品を作ることができる。 When food ingredients before freezing are mixed with the seasoning composition for frozen food ingredients of the present invention, they can be frozen together to form a frozen food composition (even when mixed with frozen food ingredients, they can be frozen together to form a frozen food composition). By heating the frozen food composition in a microwave oven or the like, the food ingredients are simultaneously flavored and seasoned with the seasoning composition for frozen food ingredients present therein, resulting in a taste, cooked texture, and soft texture as if the food had been cooked over a long period of time, and a food can be produced in which the generation of drips associated with the heating process and the generation of unpleasant odors specific to frozen foods, which were seen in conventional frozen foods, are reduced.

以下、実施例により本発明を説明するが、本発明はこれらの実施例に限定されるものではない。 The present invention will be described below with reference to examples, but the present invention is not limited to these examples.

実験1:冷凍食材用調味料組成物の調味料含量と粘度の影響
1.冷凍食材用調味料組成物の調製
下記表1の組成にしたがって、各成分を混合して、極度硬化油脂の配合の有無に起因して、粘性付与なし及び粘性付与ありの各冷凍食材用調味料組成物を調製した。粘度は25℃でのせん断速度1(1/s)にて測定した値を示す。得られた調味料組成物を以下の実験に用いた。
Experiment 1: Effect of seasoning content and viscosity of seasoning composition for frozen food ingredients 1. Preparation of seasoning composition for frozen food ingredients According to the composition in Table 1 below, each component was mixed to prepare seasoning compositions for frozen food ingredients with and without viscosity imparting depending on the presence or absence of blending of extremely hardened oils and fats. The viscosity is shown as a value measured at 25°C and a shear rate of 1 (1/s). The obtained seasoning compositions were used in the following experiments.

なお、表中の各成分の量は、得られた調味料組成物の量を100質量%とする、「質量%」の量にて示される。 The amount of each component in the table is shown in "% by mass" with the amount of the resulting seasoning composition being 100% by mass.

2.実験方法
各冷凍食材用調味料組成物(5g)と冷凍野菜(50g)とを、金属製のボウルに計量して入れ、ビニール手袋をした手で混合して、冷凍野菜全体に各調味料組成物を混ぜ合わせた。その後、ビニール袋に入れて冷凍し、得られた冷凍食品について以下の評価を行った。冷凍食品の風味や味の評価を行う場合には、冷凍食品を冷凍状態のまま皿にのせ、ラップをかけて600Wの電子レンジで2分間加熱した後に、食した。
2. Experimental method Each seasoning composition for frozen food ingredients (5 g) and frozen vegetables (50 g) were weighed and placed in a metal bowl, and mixed with hands wearing vinyl gloves to mix each seasoning composition into the entire frozen vegetables. Then, they were placed in a plastic bag and frozen, and the following evaluations were performed on the resulting frozen foods. When evaluating the flavor and taste of the frozen foods, the frozen foods were placed on a plate in the frozen state, covered with plastic wrap, and heated in a 600 W microwave oven for 2 minutes, and then eaten.

3.評価・結果
(1)分離
冷凍野菜に各調味料組成物を混ぜ合わせた直後の、冷凍野菜からの調味料組成物の分離の様子を下記の基準にしたがって目視により、訓練された3名のパネラーが評価した。
3. Evaluation and Results (1) Separation Immediately after mixing each seasoning composition with the frozen vegetables, separation of the seasoning composition from the frozen vegetables was visually evaluated by three trained panelists according to the following criteria.

<分離の程度の評価基準>
〇:混ぜ合わせた後に、冷凍野菜からの調味料組成物の分離は認められない
×:混ぜ合わせた後に、冷凍野菜からの調味料組成物の分離が確認される。
<分離の程度の評価結果>
<Criteria for evaluating the degree of separation>
◯: After mixing, separation of the seasoning composition from the frozen vegetables is not observed. ×: After mixing, separation of the seasoning composition from the frozen vegetables is observed.
<Evaluation results of the degree of separation>

粘性付与なしの冷凍食材用調味料組成物は、冷凍野菜と混ぜ合わせる以前に、既に食塩の沈降が確認され、均一に食塩を含んで計量することが難しかった。冷凍野菜と混ぜ合わせた後においては、調味料組成物(特に油)が冷凍野菜から流れ落ちて、ビニール袋の底に溜まっているのが確認された。 When the seasoning composition for frozen foodstuffs without viscosity additive was mixed with the frozen vegetables, salt settling was already observed, making it difficult to measure the salt evenly. After mixing with the frozen vegetables, it was observed that the seasoning composition (especially the oil) ran off the frozen vegetables and accumulated at the bottom of the plastic bag.

一方、粘性付与ありの冷凍食材用調味料組成物においては、食塩の沈降は認められず、均一に計量することができた。また、冷凍野菜と混ぜ合わせた後においては、調味料組成物は冷凍野菜の表面に付着したまま垂れ落ちず、混ぜ合わされた際の均一性を保持していることが確認された。 On the other hand, in the seasoning composition for frozen food materials with added viscosity, no settling of salt was observed and it was possible to measure it uniformly. Furthermore, after mixing with the frozen vegetables, it was confirmed that the seasoning composition remained attached to the surface of the frozen vegetables without dripping off, and maintained the uniformity it had when mixed.

(2)風味のばらつき
冷凍食品における各冷凍食材用調味料組成物による風味のばらつきを下記の基準にしたがって、冷凍食品を実際に加熱し、訓練された3名のパネラーが食して評価した。
(2) Variation in Flavor Variation in flavor of each seasoning composition for frozen food ingredients in frozen foods was evaluated by actually heating the frozen foods and having three trained panelists eat them according to the following criteria.

<風味のばらつきの評価基準>
〇:電子レンジで加熱した冷凍食品を食した場合に、野菜の部位によって風味にばらつきがあるとは認められない(風味にばらつきが無い)
×:電子レンジで加熱した冷凍食品を食した場合に、野菜の部位によって風味にばらつきがあることが確認される(風味にばらつきがある)。
<風味のばらつきの評価結果>
<Evaluation criteria for flavor variation>
〇: When eating frozen foods heated in a microwave oven, there is no noticeable difference in flavor depending on the part of the vegetable (there is no variation in flavor)
×: When eating frozen food heated in a microwave oven, it is confirmed that the flavor varies depending on the part of the vegetable (flavor varies).
<Evaluation results of flavor variation>

粘性付与なしの冷凍食材用調味料組成物を用いた場合には、加熱した冷凍食品(野菜)に調味料組成物(食塩)が局所的に付着しているところや、全く付着していないところが混在し、風味のばらつきが大きいことが確認された。粘性付与なしの冷凍食材用調味料組成物を用いた場合には、製造される冷凍食品の品質を、均一に安定して保つことは容易ではないことが示唆された。 When a seasoning composition for frozen food ingredients without viscosity imparting was used, it was confirmed that the heated frozen food (vegetables) had a mixture of areas where the seasoning composition (salt) was locally attached and areas where it was not attached at all, resulting in a large variation in flavor. This suggests that when a seasoning composition for frozen food ingredients without viscosity imparting is used, it is not easy to maintain a uniform and stable quality of the frozen food produced.

一方、粘性付与ありの冷凍食材用調味料組成物を用いた場合においては、加熱した冷凍食品(野菜)に調味料組成物(食塩)が全体的に、ほぼ均一に付着しており、風味のばらつきが少ないことが確認された。 On the other hand, when a seasoning composition for frozen foodstuffs with added viscosity was used, the seasoning composition (salt) adhered almost uniformly to the entire surface of the heated frozen food (vegetables), and it was confirmed that there was little variation in flavor.

(3)味の付き具合の評価
冷凍野菜に各冷凍食材用調味料組成物を混ぜ合わせたときの、調味料組成物(塩)による味の付き具合を下記の基準にしたがって、冷凍食品を訓練された3名のパネラーが実際に食して評価した。
(3) Evaluation of flavor When each seasoning composition for frozen food ingredients was mixed with frozen vegetables, the flavor of the seasoning composition (salt) was evaluated by three panelists who were trained in frozen foods, who actually tasted the mixture and evaluated it according to the following criteria.

<味の付き具合の評価基準>
〇:電子レンジで加熱した冷凍食品を食した場合に、野菜の全体が調味されていることが確認される
△:電子レンジで加熱した冷凍食品を食した場合に、野菜に薄い塩味が感じられる、及び/又は、味にムラがあることが感じられる
×:電子レンジで加熱した冷凍食品を食した場合に、野菜にごく僅かな塩味のみが感じられる。
<味の付き具合の評価結果>
<Evaluation criteria for flavor>
◯: When eating a frozen food heated in a microwave oven, it is confirmed that the vegetables are seasoned throughout. △: When eating a frozen food heated in a microwave oven, the vegetables have a slight salty taste and/or there is an uneven taste. ×: When eating a frozen food heated in a microwave oven, the vegetables have only a very slight salty taste.
<Flavor evaluation results>

食塩の配合量が4質量%場合には、粘性付与の有無にかかわらず、加熱した冷凍食品(野菜)における塩味の付き具合が薄く、物足りない味が僅かに感じられるのみであった。ただし、粘性付与なしの冷凍食材用調味料組成物を用いた場合には、調味料組成物(食塩)が局所的に付着している部分があり、その部分については塩味が強く感じられたが、塩が局在しているだけであり、料理としての一体感は感じられなかった。 When the salt content was 4% by mass, the heated frozen food (vegetables) had a weak salty taste, with or without viscosity imparted, and only a slightly unsatisfying taste was felt. However, when a seasoning composition for frozen food ingredients without viscosity imparting was used, there were areas where the seasoning composition (salt) adhered locally, and those areas had a strong salty taste, but the salt was merely localized, and there was no sense of unity as a dish.

粘性付与なしの冷凍食材用調味料組成物は、食塩の配合量を5質量%及び6質量%とした場合においても、加熱した冷凍食品(野菜)において味にムラが感じられ、塩味が感じられるところとそうではないところの差が大きかった。 When the seasoning composition for frozen food ingredients without viscosity additive was used and the salt content was set at 5% by mass and 6% by mass, the flavor of the heated frozen food (vegetables) was uneven, with a large difference between the areas that tasted salty and those that did not.

一方、粘性付与ありの冷凍食材用調味料組成物を用いた場合には、加熱した冷凍食品(野菜)において、食塩の配合量が5質量%である場合には薄い塩味が感じられるのみであったが、食塩の配合量が6質量%である場合には、塩味が全体的に感じられ、はっきりと調味されていることが確認された。調味の面からみても、粘性付与なしの冷凍食材用調味料組成物を用いた場合には、製造される冷凍食品の品質を、均一に安定して保つことは容易ではないことが示唆された。 On the other hand, when a thickening seasoning composition for frozen food ingredients was used, only a slight salty taste was felt in the heated frozen food (vegetables) when the salt content was 5% by mass, but when the salt content was 6% by mass, the salty taste was felt throughout, and it was confirmed that the food was clearly seasoned. From the perspective of seasoning, it was suggested that it is not easy to maintain a uniform and stable quality of the frozen food produced when a thickening seasoning composition for frozen food ingredients without thickening is used.

実験2:冷凍食材用調味料組成物の粘度の違いによる影響
1.冷凍食材用調味料組成物の調製
下記表5の組成にしたがって、各成分を混合して、極度硬化油脂の配合量の異なる、粘性付与ありの各冷凍食材用調味料組成物を調製した。粘度は25℃でのせん断速度1(1/s)にて測定した値を示す。得られた調味料組成物を以下の実験に用いた。
Experiment 2: Effect of difference in viscosity of seasoning composition for frozen food ingredients 1. Preparation of seasoning composition for frozen food ingredients Each component was mixed according to the composition in Table 5 below to prepare seasoning compositions for frozen food ingredients with different amounts of extremely hardened oil and fat and with viscosity imparted. The viscosity is shown as a value measured at 25°C and a shear rate of 1 (1/s). The obtained seasoning compositions were used in the following experiments.

なお、表中の各成分の量は、得られた調味料組成物の量を100質量%とする、「質量%」の量にて示される。 The amount of each component in the table is shown in "% by mass" with the amount of the resulting seasoning composition being 100% by mass.

2.実験方法
各調味料組成物(5g)と冷凍野菜(50g)とを、上記実験1の「2.実験方法」に記載のとおり混合、冷凍し、得られた冷凍食品について以下の評価を行った。加熱は、冷凍食品を冷凍状態のまま皿にのせ、ラップをかけて600Wの電子レンジで2分間加熱することにより行った。
2. Experimental Method Each seasoning composition (5 g) and frozen vegetables (50 g) were mixed and frozen as described in "2. Experimental Method" of Experiment 1 above, and the resulting frozen foods were evaluated as follows. Heating was performed by placing the frozen foods on a plate while still frozen, covering them with plastic wrap, and heating them in a 600 W microwave oven for 2 minutes.

3.評価・結果
(1)冷凍後のほぐしやすさ、加熱後のドリップ発生の程度
冷凍後の冷凍食品のほぐしやすさ、ならびに、加熱後のドリップの発生の程度について、下記の基準にしたがって、訓練された3名のパネラーがそれぞれ評価した。
3. Evaluation and Results (1) Ease of loosening after freezing and degree of dripping after heating Three trained panelists each evaluated the ease of loosening the frozen foods after freezing and the degree of dripping after heating according to the following criteria.

<ほぐしやすさの評価基準>
〇:冷凍食品を冷凍したまま、手で難なく、ほぐすことができる
△:冷凍食品を冷凍したまま、手で難なく、ほぐすことができるが、一部に硬化して手ではほぐせない部分がある
×:冷凍食品が硬化しており、手ではほぐすことができない
<Easy to loosen evaluation criteria>
◯: The frozen food can be easily loosened by hand while still frozen. △: The frozen food can be easily loosened by hand while still frozen, but some parts have hardened and cannot be loosened by hand. ×: The frozen food has hardened and cannot be loosened by hand.

<加熱後のドリップ発生の評価基準>
〇:冷凍食品の加熱後に発生したドリップの量が少ない(ドリップの量が12g以下)
△:冷凍食品の加熱後に発生したドリップの量がやや多い(ドリップの量が14g未満)
×:冷凍食品の加熱後に発生したドリップの量が多い(ドリップの量が14g以上)
(評価結果)
<Evaluation criteria for dripping after heating>
Good: The amount of dripping generated after heating the frozen food is small (the amount of dripping is 12g or less)
△: A little more dripping occurred after heating the frozen food (amount of dripping was less than 14 g)
×: A large amount of dripping occurred after heating the frozen food (amount of dripping was 14 g or more)
(Evaluation results)

冷凍食品のほぐしやすさについて、極度硬化油脂の配合量の違いに起因して、大きな差は認められなかった。 No significant differences were observed in the ease of breaking up frozen foods due to differences in the amount of hardened oils and fats used.

極度硬化油脂の配合量が2質量%の調味料組成物を用いた場合には、冷凍野菜と混合した際にビニール袋の底に、油脂が溜まっているのが確認されたが、凍結後の冷凍食品のほぐしやすさへ大きく影響をもたらすものではなかった。これは、冷凍野菜と金属製のボウルで混合した際に、必要最低限の油脂が、冷凍野菜の表面に付着したものと考えられる。実際、極度硬化油脂の配合量が2質量%の調味料組成物では、凍結後の冷凍食品において、油脂をまとっていない部分が所々で見受けられ、その部分同士が固まって凍結していることが確認されたが、そのような箇所は部分的であったため、冷凍食品を手でほぐすことに問題はなかった。 When a seasoning composition containing 2% by mass of extremely hardened oils and fats was used, it was confirmed that oils and fats accumulated at the bottom of the plastic bag when mixed with frozen vegetables, but this did not have a significant effect on the ease of loosening the frozen food after freezing. This is thought to be because the minimum amount of oil and fats was attached to the surface of the frozen vegetables when they were mixed in a metal bowl. In fact, when a seasoning composition containing 2% by mass of extremely hardened oils and fats was used, parts of the frozen food after freezing that were not covered with oil and fats were found in places, and it was confirmed that these parts were frozen together, but since such parts were partial, there was no problem in loosening the frozen food by hand.

一方、極度硬化油脂の配合量が3質量%、4質量%、及び6質量%の調味料組成物を用いた場合には、冷凍後の冷凍野菜は、難なくほぐすことができた。また、冷凍野菜と混合した際にビニール袋の底への油脂溜まりも認められなかった。 On the other hand, when seasoning compositions containing 3% by mass, 4% by mass, and 6% by mass of extremely hardened oils and fats were used, the frozen vegetables could be easily loosened after freezing. In addition, no accumulation of oil and fat was observed at the bottom of the plastic bag when mixed with the frozen vegetables.

冷凍食品の加熱後のドリップ発生の程度については、極度硬化油脂の配合量の違いに起因して、大きな差が認められた。 A large difference was observed in the degree of dripping of frozen foods after heating, due to differences in the amount of hardened oils and fats used.

極度硬化油脂の配合量が2質量%の調味料組成物を用いた場合には、凍結後の冷凍食品をレンジ加熱すると、大量のドリップが発生した。一方、極度硬化油脂の配合量が3質量%、4質量%、及び6質量%の調味料組成物を用いた場合には、当該レンジ加熱後に発生するドリップの量を大きく低減することができた。 When a seasoning composition containing 2% by mass of extremely hardened oils and fats was used, a large amount of dripping occurred when the frozen food was heated in a microwave after freezing. On the other hand, when seasoning compositions containing 3%, 4%, and 6% by mass of extremely hardened oils and fats were used, the amount of dripping that occurred after heating in the microwave was significantly reduced.

実験3:冷凍食材用調味料組成物が油系か水系かの違いによる影響
1.冷凍食材用調味料組成物の調製
下記表7の組成にしたがって、各成分を混合して、油脂及び水の配合量が異なる、粘性付与ありの各冷凍食材用調味料組成物を調製した。
Experiment 3: Influence of whether the seasoning composition for frozen food ingredients is oil-based or water-based 1. Preparation of seasoning composition for frozen food ingredients According to the composition in Table 7 below, each component was mixed to prepare each seasoning composition for frozen food ingredients with viscosity imparted, which had different amounts of oil and water.

なお、表中の各成分の量は、得られた調味料組成物の量を100質量%とする、「質量%」の量にて示される。 The amount of each component in the table is shown in "% by mass" with the amount of the resulting seasoning composition being 100% by mass.

2.評価・結果
(1)均一性、滑らかさ
調製直後の各種冷凍食材用調味料組成物について、その均一性及び滑らかさの様子を、常温において下記の基準にしたがって目視により、訓練された3名のパネラーが評価した。
2. Evaluation and Results (1) Uniformity and Smoothness Immediately after preparation, the uniformity and smoothness of each of the seasoning compositions for frozen food materials were visually evaluated at room temperature by three trained panelists according to the following criteria.

<均一性の評価基準>
〇:水又は油脂の分離が認められない
×:水又は油脂の分離が確認される
<滑らかさの評価基準>
〇:滑らかなペースト状である
×:滑らかでなくペースト状でない
<均一性、滑らかさの評価結果>
<Uniformity evaluation criteria>
◯: No separation of water or oil is observed. ×: Separation of water or oil is observed. <Smoothness evaluation criteria>
◯: Smooth and paste-like ×: Not smooth and not paste-like <Evaluation results of uniformity and smoothness>

水の配合量が15質量%以上となると、水と油脂が分離してしまい均一性が保てず、安定したペースト状態を保てないことが分かった。 It was found that if the amount of water added was 15% by mass or more, the water and oil would separate, making it impossible to maintain uniformity and maintain a stable paste state.

一方、油脂の量を減らしていくと15質量%以下となったところで滑らかさが失われ、ぼそぼそとした物性になることが確認された。このぼそぼそした状態でムラなく野菜などの食材に付着させることは難しく、上記所望の特性を有する、すなわち、ほぐれやすく、風味及び味の付き具合が良好な冷凍食品を得ることは容易ではないことが示唆される。 On the other hand, it was confirmed that when the amount of oil and fat was reduced to 15% by mass or less, the smoothness was lost and the physical properties became gritty. In this gritty state, it is difficult to adhere the oil and fat evenly to ingredients such as vegetables, suggesting that it is not easy to obtain a frozen food that has the desired characteristics described above, i.e., is easy to break apart and has a good flavor and taste.

実験4:冷凍食材用調味料組成物の粘性付与手段の違いによる影響
1.冷凍食材用調味料組成物の調製
下記表10の組成にしたがって、各成分を混合して、粘性付与手段が異なる、粘性付与ありの各冷凍食材用調味料組成物を調製した。油系増粘剤として、ポリグリセリン脂肪酸エステル(TAISET AD(太陽化学株式会社))を用いた。
Experiment 4: Influence of difference in viscosity imparting means on seasoning composition for frozen food materials 1. Preparation of seasoning composition for frozen food materials Each component was mixed according to the composition in Table 10 below to prepare seasoning compositions for frozen food materials with different viscosity imparting means and with viscosity imparting. Polyglycerol fatty acid ester (TAISET AD (Taiyo Kagaku Co., Ltd.)) was used as the oil-based thickener.

なお、表中の各成分の量は、得られた調味料組成物の量を100質量%とする、「質量%」の量にて示される。 The amount of each component in the table is shown in "% by mass" with the amount of the resulting seasoning composition being 100% by mass.

2.実験方法
各調味料組成物(5g)と冷凍野菜(50g)とを、上記実験1の「2.実験方法」に記載のとおり混合、冷凍し、得られた冷凍食品について、訓練された3名のパネラーが以下の評価を行った。加熱は、冷凍食品を冷凍状態のまま皿にのせ、ラップをかけて600Wの電子レンジで2分間加熱することにより行った。
2. Experimental Method Each seasoning composition (5 g) and frozen vegetables (50 g) were mixed and frozen as described in "2. Experimental Method" of Experiment 1 above, and three trained panelists evaluated the resulting frozen foods as follows. Heating was performed by placing the frozen foods on a plate while still frozen, covering them with plastic wrap, and heating them in a 600 W microwave oven for 2 minutes.

3.評価・結果
(1)風味のばらつき
冷凍食品を実際に加熱し、食して、冷凍食品における各冷凍食材用調味料組成物による風味のばらつきを上記実験1の「3.評価・結果」に記載のとおり評価した。
3. Evaluation and Results (1) Variation in Flavor The frozen foods were actually heated and eaten, and the variation in flavor of each seasoning composition for frozen food ingredients in the frozen foods was evaluated as described in "3. Evaluation and Results" of Experiment 1 above.

<風味のばらつきの評価結果> <Evaluation results of flavor variation>

粘性付与手段として、ラードを用いた場合、油系増粘剤を用いた場合、ラード及び油系増粘剤を用いた場合、いずれの粘性付与手段でも所定の粘性を付与することができるため、調味料組成物(食塩)が沈降せずバラつきの無い風味になり、製造される冷凍食品の品質を、均一に安定して保つことができることが示唆された。 When lard is used as the viscosity imparting means, when an oil-based thickener is used, or when lard and an oil-based thickener are used, any of the viscosity imparting means can impart a predetermined viscosity, so it was suggested that the seasoning composition (salt) does not settle, resulting in a consistent flavor and that the quality of the manufactured frozen food can be maintained uniformly and stably.

(2)冷凍後のほぐしやすさ、加熱後のドリップ発生の程度
冷凍後の冷凍食品のほぐしやすさ、ならびに、加熱後のドリップの発生の程度について、上記実験2の「3.評価・結果」に記載のとおりそれぞれ評価した。
<ほぐしさすさ、ドリップ発生の評価結果>
(2) Ease of loosening after freezing and degree of dripping after heating The ease of loosening the frozen foods after freezing and the degree of dripping after heating were each evaluated as described in "3. Evaluation and Results" of Experiment 2 above.
<Easy to loosen and dripping evaluation results>

冷凍食品のほぐしやすさについて、粘性付与手段の違いに起因して、大きな差は認められなかった。 No significant differences were observed in the ease of loosening frozen foods due to differences in viscosity imparting methods.

冷凍食品の加熱後のドリップ発生の程度についても、粘性付与手段の違いに起因して、大きな差は認められなかった。このことから、いずれの粘性付与手段でもむらなく野菜表面に冷凍食材用調味料組成物が付着し、付着後も均一に野菜表面にコーティングされている状態を維持できていたためであることが示唆された。 Regarding the degree of dripping after heating of frozen foods, no significant difference was observed due to the difference in viscosity imparting means. This suggests that the seasoning composition for frozen food materials adhered evenly to the vegetable surface with any viscosity imparting means, and was able to maintain a uniform coating on the vegetable surface even after adhesion.

以上の結果より、冷凍食材用調味料組成物であって、前記組成物100質量%に対して15質量%超の油脂と15質量%未満~0質量%以上の水、及び調味料とを含み、25℃及びせん断速度1(1/s)における粘度が120mPa・s超である、冷凍食材用調味料組成物を用いることによって、冷凍により完全に硬化することなく、手で容易にほぐすことができ、また、電子レンジ等で加熱処理した場合に、冷凍された食品特有のいやな臭いや、ドリップの発生を低減し、味や品質の低下等を抑制することが可能な冷凍食品が得られることが確認された。 The above results confirmed that by using a seasoning composition for frozen food ingredients, which contains more than 15% by mass of fats and oils, less than 15% to 0% by mass of water, and seasonings relative to 100% by mass of the composition, and has a viscosity of more than 120 mPa·s at 25°C and a shear rate of 1 (1/s), it is possible to obtain frozen foods that can be easily loosened by hand without completely hardening due to freezing, and that can reduce the unpleasant odor and dripping characteristic of frozen foods when heated in a microwave oven or the like, and that can suppress deterioration in taste and quality, etc.

Claims (13)

冷凍食品組成物が容器に収納されている、容器入り冷凍食品組成物であって、
前記冷凍食品組成物は、冷凍食材とそれと混合、付着させた、常温のときに液体である液部を含み、
前記液部が、前記液部100質量%に対して15質量%超の油脂と15質量%未満~0質量%以上の水、及び調味料とを含み(ただし、ゼラチン、コラーゲン、寒天、カラギーナンは含まない)、25℃及びせん断速度1(1/s)における粘度が120mPa・s超であり、
前記液部が、食材100gに対して、2~100gとなる混合比にて含まれ、
前記食材が複数個からなり、野菜類、肉類、魚類、豆類、穀類、卵類(魚卵は除く)の一又は複数を含み、
前記冷凍食品組成物は、加熱処理に付して用いられる、容器入り冷凍食品組成物。
A container-packed frozen food composition, the frozen food composition being packed in a container,
The frozen food composition comprises a frozen food material and a liquid portion that is mixed with or adhered to the frozen food material and is liquid at room temperature;
the liquid portion contains more than 15% by mass of fats and oils, less than 15% by mass to 0% by mass or more of water, and a seasoning, relative to 100% by mass of the liquid portion (but does not contain gelatin, collagen, agar, or carrageenan) ; and has a viscosity of more than 120 mPa·s at 25° C. and a shear rate of 1 (1/s);
The liquid portion is contained in a mixing ratio of 2 to 100 g per 100 g of food material,
The food ingredients are composed of a plurality of ingredients , and include one or more of vegetables, meat, fish, beans, grains, and eggs (excluding fish eggs);
The frozen food composition is a containerized frozen food composition that is subjected to a heat treatment before use .
前記油脂が、極度硬化油脂を含み、前記極度硬化油脂を前記液部100質量%に対して2質量%超の量で含む、請求項1に記載の容器入り冷凍食品組成物。 The containerized frozen food composition according to claim 1, wherein the oil contains extremely hardened oil and fat, and the amount of the extremely hardened oil and fat is more than 2% by mass relative to 100% by mass of the liquid portion. 前記液部100質量%に対して、前記調味料が4質量%超の量で含まれる、請求項1に記載の容器入り冷凍食品組成物。 The containerized frozen food composition according to claim 1, wherein the seasoning is contained in an amount of more than 4% by mass relative to 100% by mass of the liquid portion. 冷凍食材用調味料組成物であって、前記組成物100質量%に対して15質量%超の油脂と15質量%未満~0質量%以上の水、及び調味料とを含み(ただし、ゼラチン、コラーゲン、寒天、カラギーナンは含まない)
25℃及びせん断速度1(1/s)における粘度が120mPa・s超であり、
前記食材が複数個からなり、野菜類、肉類、魚類、豆類、穀類、卵類(魚卵は除く)の一又は複数を含み、前記冷凍食材は、加熱処理に付して用いられ、
冷凍された食材又は冷凍される前の食材100gに対して、2~100gとなる混合比にて混合、付着させて用いられる、冷凍食材用調味料組成物。
A seasoning composition for frozen food materials, comprising, relative to 100% by mass of the composition, more than 15% by mass of fat or oil, less than 15% by mass to 0% by mass or more of water, and a seasoning (but excluding gelatin, collagen, agar, and carrageenan) ;
The viscosity at 25° C. and a shear rate of 1 (1/s) is greater than 120 mPa·s;
The food material is composed of a plurality of ingredients, and includes one or more of vegetables, meat, fish, beans, grains, and eggs (excluding fish eggs) , and the frozen food material is used after being subjected to a heat treatment;
The seasoning composition for frozen food materials is used by mixing and applying it at a mixing ratio of 2 to 100 g per 100 g of frozen food materials or food materials before freezing.
前記油脂が、極度硬化油脂を含み、前記極度硬化油脂を前記組成物100質量%に対して2質量%超の量で含む、請求項に記載の冷凍食材用調味料組成物。 The seasoning composition for frozen food materials according to claim 4 , wherein the oil and fat comprises extremely hardened oil and fat, and the amount of the extremely hardened oil and fat is greater than 2% by mass relative to 100% by mass of the composition. 前記組成物100質量%に対して、前記調味料が4質量%超の量で含まれる、請求項に記載の冷凍食材用調味料組成物。 5. The seasoning composition for frozen food materials according to claim 4 , wherein the seasoning is contained in an amount of more than 4% by mass relative to 100% by mass of the composition. 冷凍食材用調味料組成物の製造方法であって、前記組成物100質量%に対して15質量%超の油脂と15質量%未満~0質量%以上の水、及び調味料とを混合すること、ならびに、
前記組成物の25℃及びせん断速度1(1/s)における粘度が120mPa・s超とすること、
を含み、
前記食材が複数個からなり、野菜類、肉類、魚類、豆類、穀類、卵類(魚卵は除く)の一又は複数を含み、前記冷凍食材は、加熱処理に付して用いられ、
前記組成物が冷凍された食材又は冷凍される前の食材100gに対して、2~100gとなる混合比にて混合、付着させて用いられる(ただし、ゼラチン、コラーゲン、寒天、カラギーナンは含まない)
製造方法。
A method for producing a seasoning composition for frozen food materials, comprising mixing more than 15% by mass of fats and oils, less than 15% by mass to 0% by mass or more of water, and a seasoning, relative to 100% by mass of the composition;
The viscosity of the composition at 25° C. and a shear rate of 1 (1/s) is greater than 120 mPa·s;
Including,
The food material is composed of a plurality of ingredients, and includes one or more of vegetables, meat, fish, beans, grains, and eggs (excluding fish eggs) , and the frozen food material is used after being subjected to a heat treatment;
The composition is mixed and applied at a mixing ratio of 2 to 100 g per 100 g of frozen or unfrozen food material (however, gelatin, collagen, agar, and carrageenan are not included) .
Production method.
前記油脂が、極度硬化油脂を含み、前記極度硬化油脂を前記組成物100質量%に対して2質量%超の量で含む、請求項に記載の製造方法。 The method according to claim 7 , wherein the oil or fat comprises extremely hardened oil or fat, and the amount of the extremely hardened oil or fat is greater than 2% by mass relative to 100% by mass of the composition. 前記組成物100質量%に対して、前記調味料を4質量%超の量で混合する、請求項に記載の製造方法。 The method according to claim 7 , wherein the seasoning is mixed in an amount of more than 4% by mass relative to 100% by mass of the composition. 容器入り冷凍食品組成物の製造方法であって、食材と冷凍食材用調味料組成物を混合し、付着させ、得られた混合物を冷凍する工程を含み、
前記冷凍食材用調味料組成物が食材100gに対して、2~100gとなる混合比にて混合、付着させて用いられ、
前記冷凍食材用調味料組成物が、前記冷凍食材用調味料組成物100質量%に対して15質量%超の油脂と15質量%未満~0質量%以上の水、及び調味料とを含み(ただし、ゼラチン、コラーゲン、寒天、カラギーナンは含まない)、25℃及びせん断速度1(1/s)における粘度が120mPa・s超であり、
前記食材が複数個からなり、野菜類、肉類、魚類、豆類、穀類、卵類(魚卵は除く)の一又は複数を含み、
前記冷凍食品組成物は、加熱処理に付して用いられる、製造方法。
A method for producing a packaged frozen food composition, comprising the steps of mixing and adhering a seasoning composition for frozen food materials to a food material, and freezing the resulting mixture,
The seasoning composition for frozen food materials is mixed and applied to the food material in a mixing ratio of 2 to 100 g per 100 g of food material,
The seasoning composition for frozen food ingredients contains more than 15% by mass of fats and oils, less than 15% by mass to 0% by mass or more of water, and a seasoning, relative to 100% by mass of the seasoning composition for frozen food ingredients (however, does not contain gelatin, collagen, agar, or carrageenan) , and has a viscosity of more than 120 mPa·s at 25° C. and a shear rate of 1 (1/s);
The food ingredients are composed of a plurality of ingredients , and include one or more of vegetables, meat, fish, beans, grains, and eggs (excluding fish eggs);
The frozen food composition is subjected to a heat treatment before use .
前記油脂が、極度硬化油脂を含み、前記極度硬化油脂を前記組成物100質量%に対して2質量%超の量で含む、請求項10に記載の製造方法。 The method according to claim 10 , wherein the oil or fat comprises extremely hardened oil or fat, and the amount of the extremely hardened oil or fat is greater than 2% by mass relative to 100% by mass of the composition. 前記冷凍食材用調味料組成物100質量%に対して、前記調味料が4質量%超の量で含まれる、請求項10に記載の製造方法。 The method according to claim 10 , wherein the seasoning is contained in an amount of more than 4% by mass relative to 100% by mass of the seasoning composition for frozen food materials. 前記得られた混合物を、容器に収納した後に冷凍する、請求項10に記載の製造方法。 The method according to claim 10 , wherein the mixture is frozen after being placed in a container.
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