WO2021106833A1 - Spice paste seasoning composition - Google Patents

Spice paste seasoning composition Download PDF

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Publication number
WO2021106833A1
WO2021106833A1 PCT/JP2020/043574 JP2020043574W WO2021106833A1 WO 2021106833 A1 WO2021106833 A1 WO 2021106833A1 JP 2020043574 W JP2020043574 W JP 2020043574W WO 2021106833 A1 WO2021106833 A1 WO 2021106833A1
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WO
WIPO (PCT)
Prior art keywords
mass
less
oil
oils
spice
Prior art date
Application number
PCT/JP2020/043574
Other languages
French (fr)
Japanese (ja)
Inventor
誠人 中西
勇輝 中島
ますみ 佐藤
弘子 大熊
将樹 湯山
賢治 伊藤
茂樹 里見
Original Assignee
ハウス食品株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2019216793A external-priority patent/JP7540624B2/en
Priority claimed from JP2019216825A external-priority patent/JP2021083426A/en
Application filed by ハウス食品株式会社 filed Critical ハウス食品株式会社
Priority to CN202080082522.4A priority Critical patent/CN115151143A/en
Publication of WO2021106833A1 publication Critical patent/WO2021106833A1/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/10Natural spices, flavouring agents or condiments; Extracts thereof

Definitions

  • the present invention relates to a spice paste seasoning composition having separation stability and good melting and richness, and a method for producing the same.
  • a paste-like seasoning (hereinafter, may be referred to as "spices paste seasoning composition") in which a spice is mixed with an edible oil or fat together with a seasoning or the like is known.
  • the spice paste seasoning composition is used for seasoning and flavoring in cooking various dishes such as fried dishes, stewed dishes, hot pot dishes, and soups.
  • Patent Document 1 describes a method for producing a paste-like seasoning containing a liquid fat, an extremely hardened oil, a fat and oil raw material containing a plastic fat and oil, a powder raw material such as a spice, and an emulsifier.
  • Spices and emulsifiers are heated with stirring until the product temperature reaches 72 ° C., then cooled to 35 ° C., and then 20.0 parts by mass of shortening, which is a plastic fat, is mixed and prepared.
  • the composition is disclosed.
  • Patent Document 2 describes an oil and fat composition composed of ingredients such as oil and fat and green dried vegetables, and discloses a composition containing rapeseed extremely hydrogenated oil in an amount of 10% by mass as the oil and fat.
  • Patent Document 3 describes an oil / fat food in which a flexible container is filled with an oil / fat composition composed of ingredients such as oil / fat and dried spices, and the oil / fat food contains rapeseed extremely hydrogenated oil in an amount of 10% by mass as the oil / fat. Is disclosed.
  • Patent Document 4 describes a paste spice produced by grinding a spice together with an edible oil and fat and then heat sterilizing it.
  • Patent Document 5 describes edible oils and fats having a solid fat content (hereinafter referred to as "SFC") at 10 ° C., powder seasonings such as spices, and emulsifiers having an HLB of 4 or less at 5 ° C.
  • SFC solid fat content
  • a method for producing a semi-kneaded seasoning in a tube, which comprises mixing at ⁇ 35 ° C., is described, and a semi-kneaded seasoning containing shortening in the fat and oil in an amount of 88% by mass is disclosed as an edible fat and oil.
  • Patent Document 6 describes an invention relating to a thickening or solidifying agent for a fat or oil having excellent transparency, which is characterized by containing a polyglycerin fatty acid ester, and spices as the fat or oil are immersed in the fat or oil or in a solid state. It is stated that dispersed flavor oils can be used.
  • JP-A-2019-122268 Japanese Patent No. 3106465 Japanese Patent No. 3252389 Japanese Unexamined Patent Publication No. 2004-283056 Japanese Patent No. 6046411 Japanese Unexamined Patent Publication No. 2018-42550
  • the present invention can not only be used by heating, but also when eaten as it is without heating, the good flavor of the spice can be felt, and it has sufficient smoothness and is put into the mouth. It is an object of the present invention to provide a spice paste seasoning composition having a good texture that melts in the mouth and is rich and has high separation stability. Further, when the container is filled in a flexible container, the container can be easily squeezed out by pressing the container with a finger, and it is an object of the present invention to provide a spice paste seasoning composition.
  • the present inventors have made spices of 1% by mass or more and 70% by mass or less, and fats and oils of 30% by mass or more and 99% by mass or less, and the solid fats and oils contained in the fats and oils are 0% by mass. It contains fats and oils of more than% and less than 50% by mass, water of 0% by mass or more and less than 10% by mass, and water-soluble powder raw materials of 0.1% by mass or more and 69% by mass or less, and the SFC of crude fat content is 25 ° C.
  • a spice paste seasoning composition having a mass of more than 0.5% and a viscosity at 25 ° C.
  • a shear rate of 1 (1 / s) of 2000 mPa ⁇ s to 1000 Pa ⁇ s is not only used by heating, but also heated. It was found that even when eaten as it is without doing so, the good flavor of the spice can be felt, the mouthfeel is good and the texture is rich, and the separation stability is high. ..
  • a spice paste seasoning composition having a viscosity at 1 (1 / s) of 2000 mPa ⁇ s to 1000 Pa ⁇ s.
  • the composition of [1] wherein the amount of the extremely hardened fat and oil contained in the fat and oil is 0% by mass or more and 19% by mass or less.
  • the composition of [1] or [2] further containing an oil-based thickener.
  • [5] 1 or 2 selected from the group consisting of salt, water-soluble dextrin, monosodium glutamate, glucose, granulated sugar, white sugar, citric acid, granulated salt, rock salt, inosinic acid, and guanylic acid as the raw material for the water-soluble powder.
  • the spice is one or more spices selected from the group consisting of pepper, sesame, pepper, garlic, onion, Japanese pepper, Chinese pepper, and ginger.
  • the spice is one or more spices selected from the group consisting of pepper, sesame, pepper, garlic, onion, Japanese pepper, Chinese pepper, and ginger.
  • the present inventors have thickened oils and fats using an oil-based thickener, which contains spices, and contains 0% by mass or more and 10% by mass of water.
  • a spice paste seasoning composition containing less than%, the amount of solid fat contained in the fat and oil in an amount of more than 0% by mass and less than 50% by mass and having an SFC value of a predetermined crude fat content is simply used by heating. Even when eaten as it is without heating, you can feel the good flavor of spices, it has sufficient smoothness, it melts in the mouth and has a good texture, and it is separated and stable. It has been found that when the container is highly flexible and is filled in a flexible container, the container can be easily squeezed out by pushing it with a finger.
  • the present invention is based on these findings and includes the following inventions.
  • [1] Contains spices, fats and oils, and oil-based thickeners, contains water in an amount of 0% by mass or more and less than 10% by mass, and the solid fats and oils contained in the fats and oils are in an amount of more than 0% by mass and less than 50% by mass.
  • a spice paste seasoning composition in which the crude fat content SFC exceeds 0.5% at 25 ° C. and is filled in a container.
  • the composition according to [1] wherein the amount of the extremely hardened fat and oil contained in the fat and oil is 0% by mass or more and 19% by mass or less.
  • [3] The composition of [1] or [2] having a viscosity of 2000 mPa ⁇ s to 1000 Pa ⁇ s at 25 ° C. and a shear rate of 1 (1 / s).
  • [4] The composition according to any one of [1] to [3], wherein the oil-based thickener is a polyglycerin fatty acid ester.
  • [5] The composition according to any one of [1] to [4], wherein the spice is one or more spices selected from the group consisting of pepper, pepper, garlic, Japanese pepper, Chinese pepper, and ginger.
  • spices of 1% by mass or more and 70% by mass or less and fats and oils of 30% by mass or more and 99% by mass or less are solid fats and oils contained in the fats and oils.
  • Oils and fats of more than 0% by mass and less than 50% by mass, and water of 0% by mass or more and less than 10% by mass are heated and mixed at a temperature of 60 ° C. or higher, and the crude fat of the spice paste seasoning composition produced.
  • the spice paste seasoning composition produced by a method including adjusting the SFC of the minute to be more than 0.5% at 25 ° C. is not only used by heating, but also eaten as it is without heating. Even in the case of spices, it is possible to feel the good flavor and richness of spices, to have sufficient smoothness, to have a good texture that melts in the mouth, and to have high separation stability. I found it.
  • Spices of 1% by mass or more and 70% by mass or less, fats and oils of 30% by mass or more and 99% by mass or less, and solid fats and oils contained in the fats and oils are more than 0% by mass and less than 50% by mass, and 0% by mass.
  • % Or more and less than 10% by mass of water is heated and mixed at a temperature of 60 ° C. or higher, and the SFC of the crude fat content of the spice paste seasoning composition is more than 0.5% at 25 ° C.
  • a method for producing a spice paste seasoning composition including.
  • [2] The production method according to [1], wherein the amount of extremely hardened fat and oil contained in the fat and oil is 0% by mass or more and 19% by mass or less.
  • the spice is one or more spices selected from the group consisting of pepper, sesame, pepper, garlic, onion, Japanese pepper, Chinese pepper, and ginger.
  • a spice paste seasoning composition produced by any of the production methods of [1] to [6].
  • This specification is described in the specification and / or drawings of Japanese patent application 2019-216868, Japanese patent application 2019-216825, and Japanese patent application 2019-216793, which are the basis of the priority of the present application. Including the content. All publications, patents and patent applications cited herein are incorporated herein by reference in their entirety.
  • the present invention not only when it is used by heating, but also when it is eaten as it is without heating, it is possible to feel the good flavor and richness of the spice, and it has sufficient smoothness and mouth. It is possible to provide a spice paste seasoning composition having a good texture that is thick and rich, and further has high separation stability. Further, when the container is filled in a flexible container, it is possible to provide a spice paste seasoning composition that can be easily squeezed by pressing the container with a finger.
  • spices of 1% by mass or more and 70% by mass or less, fats and oils of 30% by mass or more and 99% by mass or less, and solid fats and oils contained in the fats and oils are more than 0% by mass and less than 50% by mass, 0% by mass. It contains water of% or more and less than 10% by mass, and a water-soluble powder raw material of 0.1% by mass or more and 69% by mass or less, and the SFC of crude fat content exceeds 0.5% at 25 ° C., and shears at 25 ° C. It relates to a spice paste seasoning composition having a viscosity at a speed of 1 (1 / s) of 2000 mPa ⁇ s to 1000 Pa ⁇ s.
  • the present invention contains spices, fats and oils, and oil-based thickeners, contains water in an amount of 0% by mass or more and less than 10% by mass, and the solid fats and oils contained in the fats and oils are more than 0% by mass and less than 50% by mass. It relates to a spice paste seasoning composition in which the crude fat content SFC exceeds 0.5% at 25 ° C. and is filled in a container.
  • spices of 1% by mass or more and 70% by mass or less, fats and oils of 30% by mass or more and 99% by mass or less, and solid fats and oils contained in the fats and oils are more than 0% by mass and less than 50% by mass.
  • water of 0% by mass or more and less than 10% by mass is heated and mixed at a temperature of 60 ° C. or higher, and the crude fat content SFC of the produced spice paste seasoning composition is 0.5% at 25 ° C. It relates to a method for producing a spice paste seasoning composition, which comprises adjusting the composition so as to be super.
  • spices is a general term for substances that are collected from plants and impart aroma, pungency, color, or eliminate odors during cooking, and are blended with herbs, spice plants, and a plurality of spices. Things can be mentioned.
  • the spices that can be used in the present invention include Ajowan, Anis, Eshalot, All Spice, Onion, Oregano, Kafalime, Kahokuzansho (Japanese pepper), Cardamon, Curry leaf, Caraway, Cumin, Green pepper, Clove, Sesame , Pepper, Coriander (Pakuchi), Saffron, Sansho, Perilla, Cinnamon, Ginger, Star Anis, Sage, Thyme, Turmeric, Tade, Taragon, Chinpi, Dill, Pepper, Natsumegu, Nira, Niniku, Negi, Basil, Parsley, Vanilla , Paprika, Jalapeno, Fenuglique, Fennell, Horse Radish, Marjorum, Mustard, Mikan
  • the spice can be used in the form of a powder, and can be used in the form of a dry pulverized product or a dry powder of an extract.
  • the spice paste seasoning composition of the present invention can contain an arbitrary amount of spices, and the amount can be appropriately set according to the spices used.
  • the spice paste seasoning composition of the present invention contains spices in an amount of 1% by mass or more, 2% by mass or more, 3% by mass or more, 4% by mass or more, or 5% by mass or more, and the upper limit thereof is particularly high. Although not limited to, it can be, for example, 70% by mass or less, 60% by mass or less, 50% by mass or less, 40% by mass or less, or 30% by mass or less.
  • the spice is added, for example, 1% by mass or more and 70% by mass or less, preferably 2% by mass or more and 60% by mass or less, more preferably 3% by mass or more and 50% by mass or less, still more preferably. It can be contained in an amount appropriately selected from the range of 4% by mass or more and 40% by mass or less, most preferably 5% by mass or more and 30% by mass or less. If the amount of spice is less than 1% by mass, a good flavor of the spice may not be obtained, and if it is more than 70% by mass, the smoothness of the spice paste seasoning composition may not be obtained.
  • fat and oil means animal and vegetable fats and oils (sometimes also called edible oils) used for food, and liquid fats and oils, solid fats and oils (for example, extremely hardened fats and oils, plastic fats and oils (shortening, lard, ester)). Replacement fats and oils)), etc., and one or more of these fats and oils are used.
  • fats and oils examples include shortening, margarine, palm oil, palm kernel oil, cottonseed oil, rapeseed white squeezed oil, soybean oil, corn oil, saflower oil, sunflower oil, olive oil, rice bran oil, and mustard oil.
  • vegetable oils and fats such as oils, animal fats and oils such as butter, lard, beef and pork fats, extremely hardened fats and oils thereof, and ester-exchanged fats and oils (not limited to these).
  • the fats and oils may be used alone or in combination of different fats and oils.
  • the spice paste seasoning composition of the present invention may contain any amount of fats and oils, the amount of which is the solid fat content (SFC) of the crude fat contained in the spice paste seasoning composition of the present invention. It can be appropriately adjusted within a range of a desired value described later.
  • SFC solid fat content
  • the spice paste seasoning composition of the present invention contains fats and oils in an amount of 30% by mass or more, 35% by mass or more, or 40% by mass or more, and the upper limit thereof is not particularly limited. It can be 99% by mass or less, 98% by mass or less, or 95% by mass or less.
  • the spice paste seasoning composition of the present invention contains fats and oils, for example, from a range of 30% by mass or more and 99% by mass or less, preferably 35% by mass or more and 98% by mass or less, and more preferably 40% by mass or more and 95% by mass or less. It can be included in an appropriately selected amount.
  • the spice paste seasoning composition of the present invention may have a decrease in texture such as smoothness and melting in the mouth, or a decrease in flavor. May occur.
  • solid fats and oils contain more than 0% by mass, more than 0.5% by mass, more than 1% by mass, more than 2% by mass, more than 3% by mass, more than 4% by mass, and more than 5% by mass.
  • it is contained in an amount of more than 6% by mass, and the upper limit thereof is not particularly limited, but for example, less than 50% by mass, less than 40% by mass, less than 30% by mass, less than 20% by mass, less than 15% by mass, Or it can be less than 10% by mass.
  • solid fats and oils are more than 0% by mass and less than 50% by mass, that is, more than 0% by mass and less than 40% by mass, more than 0% by mass and less than 30% by mass, and more than 0% by mass and less than 20% by mass, 5 It may be contained in an amount of more than mass% and less than 15% by mass, or more than 5% by mass and less than 10% by mass.
  • Solid fats and oils means fats and oils having a rising melting point of 30 ° C. or higher.
  • solid fats and oils include shortening, lard, transesterified fats and oils, coconut butter, beef tallow, palm kernel oil, rapeseed extremely hardened oil, soybean extremely hardened oil, palm extremely hardened oil and the like, but are limited thereto. Not done.
  • the fats and oils used in the present invention contain liquid fats and oils in an amount of 50% by mass or more, 60% by mass or more, 70% by mass or more, 80% by mass or more, 85% by mass or more, or 90% by mass or more.
  • the upper limit thereof is not particularly limited, but may be, for example, less than 100% by mass, 95% by mass or less, or less than 95% by mass.
  • Liquid fats and oils used in the present invention include, for example, 50% by mass or more and less than 100% by mass, that is, 60% by mass or more and less than 100% by mass, 70% by mass or more and less than 100% by mass, 80% by mass or more and 100% by mass.
  • liquid fat and oil Even when the spice paste seasoning composition is eaten as it is without heating, it has sufficient smoothness and can be melted in the mouth and given a good texture.
  • Liquid fat means a fat having a rising melting point of less than 30 ° C.
  • liquid fats and oils include vegetable fats and oils such as palm oil, palm kernel oil, cottonseed oil, rapeseed white squeezed oil, soybean oil, corn oil, saflower oil, sunflower oil, olive oil, rice bran oil, and mustard oil. However, it is not limited to these.
  • the fat and oil used in the present invention contains shortening in an amount of 0% by mass or more, 0.5% by mass or more, or 1% by mass or more, and the upper limit thereof is not particularly limited, but for example, 50. It can be less than mass%, 45% by mass or less, 40% by mass or less, 30% by mass or less, 20% by mass or less, 10% by mass or less, or 5% by mass or less.
  • shortening is, for example, 0% by mass or more and less than 50% by mass, that is, 0% by mass or more and 45% by mass or less, 0% by mass or more and 40% by mass or less, 0% by mass or more and 30.
  • the smoothness of the spice paste seasoning composition produced can be adjusted, and oil floating during storage can be suppressed.
  • shortening is contained in an amount of 50% by mass or more, the spice paste seasoning composition produced is not smooth enough to be eaten as it is without heating, and it melts in the mouth. It may be bad and the texture may be bad.
  • the fats and oils used in the present invention contain extremely hardened fats and oils in an amount of 0% by mass or more, and are not particularly limited, but for example, 0.5% by mass or more, 1% by mass or more, or 1. It is contained in an amount of 5% by mass or more, and the upper limit thereof is not particularly limited, but for example, 19% by mass or less, 18% by mass or less, 17% by mass or less, 16% by mass or less, 15% by mass or less, 14 Mass% or less, 13% by mass or less, 12% by mass or less, 11% by mass or less, 10% by mass or less, 9% by mass or less, 8% by mass or less, 7% by mass or less, 6% by mass or less, 5% by mass or less, 4 It can be included in an amount of mass% or less, 3 mass% or less, or 2 mass% or less.
  • the extremely hardened fats and oils are 0% by mass or more and 19% by mass or less, 0% by mass or more and 15% by mass or less, 0% by mass or more and 10% by mass or less, 0% by mass or more and 7% by mass or less.
  • 0% by mass or more and less than 5% by mass more preferably 0% by mass or more and less than 4% by mass, that is, 0% by mass or more and 4.5% by mass or less, 0% by mass or more and 4% by mass or less, 0% by mass or more 3 It may be contained in an amount of mass% or less, 0.5% by mass or more and 2% by mass or less, or 1% by mass or more and 1.5% by mass or less.
  • the smoothness of the spice paste seasoning composition produced can be adjusted, and oil floating during storage can be suppressed.
  • the extremely hardened fat and oil is contained in an amount larger than the above range, it may not be possible to obtain the desired viscosity of the produced spice paste seasoning composition, and the texture such as smoothness and melting in the mouth is deteriorated. In addition, it may not be possible to obtain a good texture of the blended spices and the ingredients described in detail below.
  • Extremely hardened fats and oils are fats and oils that have been hydrogenated until there are almost no unsaturated fatty acids, that is, until the iodine value is substantially 0 (usually 2 to 3 or less), and the hardness is high. It means a solid fat and oil having a high melting point of 50 to 70 ° C.
  • Examples of such extremely hardened fats and oils include rapeseed oil, soybean oil, corn oil, safflower oil, sunflower oil, olive oil, rice bran oil, cottonseed oil, palm oil, palm fractionated oil, mustard oil, lard, and beef fat (these are).
  • Examples include extremely hardened fats and oils prepared from fats and oils selected from).
  • the "water-soluble powder raw material” is a substance that dissolves in the water when it encounters water, so that when the spice paste seasoning composition of the present invention contains the water-soluble powder raw material, it is in the mouth. When added, the water-soluble powder raw material dissolves in saliva, and the viscosity of the spice paste seasoning composition of the present invention decreases, so that a good melting in the mouth can be obtained.
  • the "water-soluble powder raw material” in the present invention include salt, water-soluble dextrin, monosodium glutamate, glucose, granulated sugar, white sugar, citric acid, granulated salt, rock salt, inosinic acid, guanylic acid and the like. However, it is not limited to these.
  • additives such as excipients, lubricants, binders and disintegrants, which are usually used in the production of foods and drinks, and those used as seasonings can be used.
  • water-soluble powder raw materials having tastes such as saltiness (salt, etc.), umami (soda glutamate), acidity, bitterness, and sweetness (water-soluble dextrin, glucose) promote saliva secretion when put in the mouth. Since saliva reduces the viscosity of the spicy paste seasoning composition of the present invention, a better melting in the mouth can be obtained.
  • the spice paste seasoning composition of the present invention may contain a water-soluble powder raw material in an arbitrary amount of 0% by mass or more, and the content thereof can be appropriately set according to the powder raw material used.
  • the amount thereof is, for example, 0.1% by mass or more, 0.5% by mass or more, 1% by mass or more, 5% by mass or more, 10 It is mass% or more, 20 mass% or more, or 30 mass% or more, and the upper limit thereof is not particularly limited, but for example, 69 mass% or less, 60 mass% or less, 50 mass% or less, 40 mass% or less.
  • the spice paste seasoning composition of the present invention can contain a water-soluble powder raw material in an amount of 0.1% by mass or more and 69% by mass or less, preferably 0.1% by mass or more and 50% by mass or less.
  • a good melting in the mouth can be achieved when the spice paste seasoning composition of the present invention is put in the mouth.
  • the powder raw material is salt, it can be contained in an amount of 0.1% by mass or more and 20% by mass or less, more preferably 1% by mass or more and 10% by mass or less, and when it is a water-soluble dextrin, 1% by mass.
  • It can be contained in an amount appropriately selected from the range of% or more and 50% by mass or less, more preferably 5% by mass or more and 30% by mass or less, and in the case of sodium glutamate, 0.1% by mass or more and 10% by mass or less. More preferably, it can be contained in an amount of 1% by mass or more and 5% by mass or less.
  • the "oil-based thickener” means a substance capable of thickening, solidifying, and / or sol-gelling the fat and oil by adding and dissolving the fat and oil.
  • a polyglycerin fatty acid ester containing a fatty acid and polyglycerin as constituent components can be preferably used.
  • the fatty acids constituting the polyglycerin fatty acid ester have a high viscosity when a linear fatty acid having 16 to 18 carbon atoms is contained as a molecular number of 45% or more among all the constituent fatty acids. Can be obtained. This ratio indicates the ratio of the number of moles of linear fatty acid having 16 to 18 carbon atoms to the number of moles of all constituent fatty acids.
  • the constituent fatty acid preferably contains any one of a linear fatty acid having 8 to 14 carbon atoms, a branched fatty acid having 18 to 22 carbon atoms, and an unsaturated fatty acid having 18 to 22 carbon atoms.
  • constituent fatty acids (a) at least one type of linear saturated fatty acid having 16 to 22 carbon atoms, (b) linear saturated fatty acid having 8 to 14 carbon atoms, branched fatty acid having 18 to 22 carbon atoms, and 18 to 18 carbon atoms. At least one selected from the group consisting of 22 unsaturated fatty acids can be mentioned.
  • the ratio of the fatty acid (a) and the fatty acid (b) in the constituent fatty acids is 0.91: 0.09 to 0.99: 0.01 in terms of molar ratio, the viscosity is high with a low addition amount and the viscosity is high for a long period of time. Separation of fats and oils can be suppressed.
  • Examples of the fatty acid (a) include, but are not limited to, palmitic acid, stearic acid, arachidic acid, behenic acid and the like.
  • Examples of the fatty acid (b) include, but are not limited to, caprylic acid, capric acid, lauric acid, myristic acid, oleic acid, erucic acid, isostearic acid and the like.
  • the polyglycerin constituting the polyglycerin fatty acid ester it is preferable to use one having an average degree of polymerization of 10 or more based on the hydroxyl value.
  • polyglycerin having an average degree of polymerization of less than 10 is used, sufficient viscosity cannot be obtained, and separation of fats and oils may not be suppressed for a long period of time.
  • the average degree of polymerization of polyglycerin is 20 or more, more preferably 30 or more, still more preferably 40 or more, and the higher the average degree of polymerization, the higher the viscosity and the solidification is achieved with a low addition amount. can do.
  • the average degree of polymerization of polyglycerin based on the hydroxyl value is determined by the terminal group analysis method according to a conventionally known method (Japanese Patent Laid-Open No. 2018-42550), and the hydroxyl value is the standard established by the Japan Oil Chemists'Association, edited by the Japan Oil Chemists' Society. It can be calculated according to the "Fat and oil analysis test method (I) 1996 version".
  • the esterification rate of the polyglycerin fatty acid ester is preferably 70% or more. If the esterification rate is less than 70%, sufficient viscosity may not be obtained and separation of fats and oils may not be suppressed for a long period of time. More preferably, the esterification rate of the polyglycerin fatty acid ester is 80% or more, further preferably 90% or more, and the higher the esterification rate, the higher the viscosity, and solidification can be achieved with a low addition amount. it can.
  • the esterification rate can be calculated according to a conventionally known method (Japanese Unexamined Patent Publication No. 2018-42550).
  • a polyglycerin fatty acid ester produced according to a conventional method can be used. More specifically, each of the above components is charged with a composition satisfying the above conditions, and a catalyst such as sodium hydroxide is used. In addition, those produced by subjecting to an esterification reaction under normal pressure or reduced pressure can be used. Further, in the present invention, a commercially available product may be used as the polyglycerin fatty acid ester, for example, TAISET AD (Taiyo Kagaku Co., Ltd.), TAISET50 (Taiyo Kagaku Co., Ltd.), Ryoto Polyglyceride B-100D (Mitsubishi Chemical Foods Co., Ltd.). Co., Ltd.) and the like can be preferably used.
  • the spice paste seasoning composition of the present invention may contain an oil-based thickener in an arbitrary amount of 0% by mass or more, and the amount thereof is desired so that the viscosity of the produced spice paste seasoning composition is as follows. It can be adjusted as appropriate within the range of values.
  • the amount thereof is, for example, 0.1% by mass or more, preferably 0.5% by mass or more, more preferably 1% by mass or more, and further. It is preferably 2% by mass or more, and the upper limit is not particularly limited, but may be, for example, 10% by mass or less, 7% by mass or less, 5% by mass or less, or 3% by mass or less.
  • the spice paste seasoning composition of the present invention contains an oil-based thickener in an amount of 0.1% by mass to 10% by mass, more preferably 0.5% by mass to 5% by mass, and more preferably 1 to 3% by mass. It can be included in an amount appropriately selected from the range of%.
  • the viscosity of the fat and oil may not be sufficient, while if it is more than 10% by mass, the viscosity of the fat and oil may be too high, and as a result, the viscosity of the fat and oil may be too high.
  • the separation stability of the spice paste seasoning composition of the present invention is lowered to cause oil floating or the like, when the texture such as smoothness or melting in the mouth is deteriorated, or when the container is filled in a flexible container, the container is used. It may be difficult to squeeze out.
  • the solid fat content (SFC) of the crude fat content in the spice paste seasoning composition of the present invention at 25 ° C. is more than 0.5%, preferably 0.6% or more, more preferably 0.8%. As described above, the upper limit thereof is not particularly limited, but may be, for example, 20% or less, 15% or less, or 10% or less.
  • the crude fat content of the SFC contained in the spice paste seasoning composition of the present invention is, for example, 0.6% to 20%, preferably 0.8% to 20%, and more preferably 1% to 10%.
  • the spice paste seasoning composition of the present invention has a deteriorated texture such as smoothness and melting in the mouth, or when it is filled in a flexible container, the container is concerned. It may be difficult to squeeze out from.
  • the "crude fat content” is not limited to those derived from fats and oils used in the present invention, but also spice paste seasonings such as those derived from spices and ingredients, those derived from additives, and those derived from other ingredients. It indicates the crude fat content contained in the entire composition.
  • the solid fat content (SFC) of the crude fat content contained in the spice paste seasoning composition at 25 ° C. is obtained by extracting the crude fat content contained in the spice paste seasoning composition by a socksley extraction method and using Japanese oil. It can be measured according to the NMR method (provisional 3-1983 provisional solid fat content) described in the standard fat analysis test method (II) established by the Chemical Society.
  • the NMR method (provisional 3-1983 provisional solid fat content) described in the standard fat analysis test method (II) established by the Japan Oil Chemists' Society is specifically that the sample is heated in a constant temperature bath at 90 ° C. to be uniform. Then, fill a test tube (2 mL) with a rubber stopper. After holding the sample packed in the sample tube and the control sample (Japanese olive oil) at 60 ⁇ 0.2 ° C. for 30 minutes, the NMR signal of each sample is read. These samples are then held at 0 ⁇ 2 ° C. for 30 minutes and then at the measurement temperature (T ⁇ 0.2 ° C.) for 30 minutes to read each signal. SFC at T ° C. is calculated by the following formula.
  • SFC (%) 100-A / B x C / D x 100
  • A is the reading of the NMR signal of the control sample at 60 ° C.
  • B is the reading of the NMR signal of the measurement sample at 60 ° C.
  • C is the reading of the NMR signal of the measurement sample at T ° C.
  • D is the reading of the NMR signal of the measurement sample at T ° C. It is a reading of the NMR signal of the control sample at T ° C.
  • the viscosity of the spice paste seasoning composition of the present invention has a value of 2000 mPa ⁇ s or more, preferably 4000 mPa ⁇ s or more, more preferably 6000 mPa ⁇ s or more, still more preferably 6000 mPa ⁇ s or more at 25 ° C. and a shear rate of 1 (1 / s). It is 8000 mPa ⁇ s or more, and the upper limit thereof is not particularly limited, but can be, for example, 1000 Pa ⁇ s or less, 980 Pa ⁇ s or less, 970 Pa ⁇ s or less, or 960 Pa ⁇ s or less.
  • the viscosity of the spice paste seasoning composition of the present invention under the above conditions is, for example, preferably 2000 mPa ⁇ s to 1000 Pa ⁇ s, more preferably 1 Pa ⁇ s to 500 Pa ⁇ s, and 10 Pa ⁇ s to 100 Pa ⁇ s. -S is more preferable.
  • By imparting a certain viscosity to the fat and oil it is possible to enhance the aftertaste of the scent of the blended spices and the ingredients described in detail below, maintain a good texture, and the blended spices and ingredients. It is possible to provide a spice paste seasoning composition in which the material is less likely to cause precipitation or non-uniform dispersion during production, transportation, or storage, has good dispersibility, and has high separation stability.
  • the viscosity is less than 2000 mPa ⁇ s, the separation stability of the spice paste seasoning composition is poor, and oil floating or the like may occur.
  • a sample from which particles of 1 mm or more were removed was subjected to a rotary viscoelasticity measuring device (for example, RheoStress 6000 manufactured by HAAKE), a parallel plate having a diameter of 35 mm, a shear rate of 0.1 s- 1 to 31 s at 25 ° C. It can be measured by measuring from the low shear rate side up to -1.
  • a rotary viscoelasticity measuring device for example, RheoStress 6000 manufactured by HAAKE
  • the viscosity of the spice paste seasoning composition of the present invention may be adjusted by blending one or more (two or more) selected from fats and oils, particularly solid fats and oils, shortenings, extremely hardened fats and oils, and oil-based thickeners. ..
  • water can be added in an amount of 0% by mass or more and less than 10% by mass as long as the desired properties of the spice paste seasoning composition of the present invention are not impaired. ..
  • water can be contained in an amount of 0% by mass or more and less than 10% by mass.
  • the desired viscosity of the produced spice paste seasoning composition may not be obtained, resulting in a decrease in texture such as smoothness and melting in the mouth and flavor. It may cause a decrease, the separation of fats and oils may not be suppressed, the separation stability of the composition may decrease, and the storage stability may further decrease.
  • water is used in an amount of 0% by mass or more and less than 10% by mass, that is, 0% by mass or more and 8% by mass or less, 0% by mass or more and 5% by mass or less, 0% by mass or more and 3% by mass or less, 0% by mass or more. It may be added in an amount of 2% by mass or less, 0% by mass or more and 1% by mass or less, or 0% by mass or more and 0.5% by mass or less.
  • These waters include not only the water directly added in the production of the spice paste seasoning composition, but also the water mixed in the raw materials in the process of preparing one or more raw materials for producing the spice paste seasoning composition. Causes are included.
  • the spice paste seasoning composition of the present invention can further include an ingredient capable of imparting a texture to the composition when the composition is eaten as it is without heating.
  • the "ingredient” is blended with the spice paste seasoning composition of the present invention, and when the composition is eaten as it is without heating, it is “crispy”, “crispy”, “crispy”, “crispy”, “crispy”, “ It means ingredients and spices that can give a texture such as “crunchy”, “crunchy”, “polypoly”, or “jarigari” (not limited to these), and in particular, it has a chewy texture reminiscent of brittle fracture. / Ingredients and spices with a texture are preferable.
  • a load having a deformation rate of 50% or less when the load differential value in the breaking strength analysis before being blended in the composition of the present invention is determined by the following measuring method.
  • the minimum value of the differentiated value is less than -2N /%, preferably less than -5N /%, more preferably less than -10N /%, and the maximum value obtained by differentiating the load within 2% from the deformation rate is Ingredients having a value of 0 N /% or more can be mentioned.
  • a measurement method first, a plunger having a diameter of 3 mm is used in a creep meter, and a rupture strength analysis is performed at a storage pitch of 0.01 seconds and a measurement speed of 0.1 mm / sec.
  • the deformation rate of an arbitrary measurement point is x%
  • the stress is yN
  • the deformation rate of the next measurement point is X%
  • the stress is YN
  • (Y-y) / (X-x) (difference in load between consecutive measurement points) (N) divided by the difference in deformation rate (%)) is calculated as the differentiated value (N /%).
  • any creep meter can be used as long as the above measurement method can be carried out, and for example, RE2-3305B manufactured by Sanyo Electric Railway Co., Ltd., which is also used in the following examples, can be preferably used ( Not limited to this).
  • the load derivative value in the breaking strength analysis of the ingredient to be used is not included in the above range, a good texture of the ingredient may not be obtained when the spice paste seasoning composition of the present invention is eaten. .. Furthermore, if a good texture of the ingredients cannot be obtained, the texture of the spice paste seasoning composition and the complexity of the flavor of the ingredients cannot be obtained, and the stickiness of the fats and oils is strongly felt. It is not possible to obtain an appropriate flavor that can be eaten by heating.
  • Ingredients that can be used in the present invention include, for example, poppy seeds, sesame seeds, onion chips, garlic chips, puffs, granola, okaki, fried balls, sardines, bread flour, croutons, cumin, grain mustard, pepper, and shellfish (shrimp). , Crabs, etc.), edible insects, dried vegetables, dried meat, dried seafood, dried fruits, corn glitz and other foodstuffs and spices, but are not limited to these.
  • the ingredient can be used in any size as long as it has the load derivative value in the above-mentioned breaking strength analysis, and can be used as it is or in the form of a pulverized product depending on the size of the ingredient used.
  • the ingredients may have a particle size in the range of about 0.5 to 20 mm, preferably about 1 to 10 mm. If the size of the ingredient is smaller than 0.5 mm, a good texture of the ingredient may not be obtained, and if it is larger than 20 mm, the smoothness of the composition of the present invention may not be obtained. ..
  • the spice paste seasoning composition of the present invention may contain an arbitrary amount of ingredients, and the amount can be appropriately set according to the ingredients to be used.
  • the spice paste seasoning composition of the present invention contains the ingredients in an amount of 1% by mass or more, 2% by mass or more, or 3% by mass or more, and the upper limit thereof is not particularly limited.
  • it can be 70% by mass or less, 60% by mass or less, 50% by mass or less, 40% by mass or less, or 35% by mass or less.
  • the spice paste seasoning composition of the present invention contains ingredients, for example, 1% by mass or more and 70% by mass or less, preferably 2% by mass or more and 60% by mass or less, and more preferably 3% by mass or more and 50% by mass or less (for example).
  • the spice paste seasoning composition of the present invention further contains excipients, lubricants, binders, disintegrants, etc., which are usually used in the production of foods and drinks. Additives can be included.
  • Excipients include, for example, lactose, sucrose, D-mannitol, D-sorbitol, starch, pregelatinized starch, dextrin, glucose, corn starch, crystalline cellulose, low-substituted hydroxypropyl cellulose, sodium carboxymethyl cellulose, gum arabic, pullulan. , Light anhydrous silicate, synthetic aluminum silicate, magnesium aluminometasilicate and the like.
  • lubricant examples include sugar esters such as sucrose fatty acid esters, waxes such as calcium stearate, magnesium stearate, stearic acid, stearyl alcohol, and beeswax, talc, silicic acid, and silicon.
  • binder examples include pregelatinized starch, sucrose, gelatin, gum arabic, methyl cellulose, carboxymethyl cellulose, sodium carboxymethyl cellulose, crystalline cellulose, sucrose, D-mannitol, trehalose, dextrin, pullulan, hydroxypropyl cellulose, and hydroxypropyl methyl cellulose. , Polyvinylpyrrolidone and the like.
  • disintegrant examples include lactose, sucrose, starch, carboxymethyl cellulose, carboxymethyl cellulose calcium, croscarmellose sodium, carboxymethyl starch sodium, light anhydrous silicic acid, and low-degree-of-substitution hydroxypropyl cellulose.
  • amino acids for example, glutamine, cysteine, lecithin, arginine, etc.
  • polyhydric alcohols for example, ethylene
  • Glycol polyethylene glycol, propylene glycol, glycerin, sugar alcohol, etc.
  • natural polymers eg, lecithin, starch, dextrin, etc.
  • vitamins eg, vitamin C, vitamin B group, etc.
  • minerals eg, calcium, magnesium, zinc, etc.
  • Iron etc.
  • dietary fiber eg, mannan, pectin, hemicellulose, etc.
  • surfactant eg, sorbitan fatty acid ester, etc.
  • diluent, stabilizer, isotonic agent pH adjuster, buffer, wetting agent, dissolution
  • suspending agents coloring agents, flavoring agents, flavoring agents, fragrances, antioxidants, sweeteners, taste components, acidulants and the like can be appropriately included.
  • the present invention is a spice of 1% by mass or more and 70% by mass or less, and a fat or oil of 30% by mass or more and 99% by mass or less, and the solid fat or oil contained in the fat or oil is more than 0% by mass and less than 50% by mass.
  • Oil and fat and water of 0% by mass or more and less than 10% by mass are heated and mixed at a temperature of 60 ° C. or higher, and the SFC of the crude fat content of the spice paste seasoning composition produced is 0.
  • a method for producing a spice paste seasoning composition which comprises adjusting the amount to more than 5%.
  • a spice of 1% by mass or more and 70% by mass or less, and a fat or oil of 30% by mass or more and 99% by mass or less, and the solid fat or oil contained in the fat or oil is more than 0% by mass and less than 50% by mass.
  • heat and mixing 0% by mass or more and less than 10% by mass of water at a temperature of 60 ° C. or higher and “the SFC of the crude fat content of the spicy paste seasoning composition produced is 25 ° C.
  • Adjusting to more than 0.5% may be described in this order, but this does not mean that these steps are performed in this order.
  • the spice paste seasoning composition of the present invention is 1% by mass or more and 70% by mass or less of spices, and 30% by mass or more and 99% by mass or less of fats and oils, and the solid fats and oils contained in the fats and oils are 0% by mass.
  • 1% by mass or more and 70% by mass or less of spices, 30% by mass or more and 99% by mass or less of fats and oils, and the solid fats and oils contained in the fats and oils are more than 0% by mass and less than 50% by mass.
  • Mixing certain fats and oils, water of 0% by mass or more and less than 10% by mass, and water-soluble powder raw material of 0.1% by mass or more and 69% by mass or less may be described in this order, but this does not mean that these steps are performed in this order.
  • the SFC of the crude fat content exceeds 0.5% at 25 ° C., and the viscosity at 25 ° C. and a shear rate of 1 (1 / s) is 2000 mPa ⁇ s to 1000 Pa ⁇ s"
  • This adjustment is made.
  • the amount of oils and fats that make the solid fat content (SFC) of the crude fat content of the produced spicy paste seasoning composition a predetermined value, and the viscosity of the produced spicy paste seasoning composition to a predetermined value.
  • the spices have a determined composition capable of achieving the SFC and viscosity.
  • Oils and fats, and water-soluble powder raw materials, and if necessary, water and other components described above may be mixed.
  • the spice paste seasoning composition of the present invention contains spices, oils and fats, and, if necessary, a water-soluble powder raw material, an oil-based thickener, water, and the above other components in the above amounts, respectively. It can be produced by mixing under heating conditions and then cooling at room temperature or in a refrigerator. All the components may be added together and mixed, or the components may be added separately or sequentially in any combination (in any order) and mixed. The components can be mixed at one or more before, during, and after heating.
  • the heating temperature is 60 ° C. or higher, for example, 60 ° C. or higher, 65 ° C. or higher, 70 ° C. or higher, 75 ° C. or higher, 80 ° C. or higher, 85 ° C. or higher, 90 ° C.
  • Temporal means the temperature of the composition itself.
  • the upper limit of the heating temperature is not particularly limited, but can be 160 ° C. or lower, preferably 140 ° C. or lower.
  • a good flavor of the spice can be imparted to the produced spice paste seasoning composition, more preferably to a temperature of 90 ° C. or higher, still more preferably 100 ° C. or higher.
  • caramelization Maillard reaction, etc.
  • the cooking feeling is increased, the flavor can be increased, and a better flavor of spices can be imparted.
  • the spice flavor may not be sufficiently felt, or the heating may cause charring and a bitter taste or the like.
  • the shortening is heated, the composition is cooled to room temperature (5 ° C. to 35 ° C.), and then added and mixed.
  • the crystals of fats and oils may dissolve, and when it is cooled again, coarse crystals different from those before heating may be produced. May reduce the texture of the paste to something that is not smooth.
  • heating can be maintained at that temperature for 0 to 15 minutes, preferably 0 to 10 minutes, and more preferably 0 to 5 minutes. After the heating is complete, the composition is cooled at room temperature or in a refrigerator.
  • the spice paste seasoning composition of the present invention can be provided in a container-filled form.
  • the form of the container is not particularly limited, but may be a pouch, a can, a bottle, a tube, a bottle, or the like.
  • the size of the container is not particularly limited, but for example, 10 to 500 mL (typically 10 mL, 15 mL, 20 mL, 30 mL, 40 mL, 50 mL, 95 mL, 100 mL, 150 mL, 200 mL, 250 mL, 300 mL, 350 mL, 400 mL, 450 mL or It can be as large as 500 mL).
  • the container is preferably a flexible container.
  • the "flexible container” means a container that can be deformed by applying a force and can return to its original shape when the force is released, and is specifically deformable and has a shape-retaining property. Examples include flexible containers such as tubes and plastic bottles.
  • the spice paste seasoning composition can be squeezed out by pressing the container with a finger, which is convenient.
  • the filling of the container may be performed before the step of cooling the composition at room temperature or in a refrigerator, or may be performed after the step.
  • each component was mixed, heated and mixed to a temperature of 80 ° C., and then cooled and mixed with ice water to 5 ° C. to produce each spice paste seasoning composition. ..
  • a polyglycerin fatty acid ester product name: TAISET AD (Taiyo Kagaku Co., Ltd.)
  • TAISET AD Tiniyo Kagaku Co., Ltd.
  • the amount of each component in the table is shown by mass ratio.
  • Each of the obtained spice paste seasoning compositions was evaluated for melting in the mouth in the same manner as described above. The results of each experiment are also shown in the table below.
  • spices of 1% by mass or more and 70% by mass or less, fats and oils of 30% by mass or more and 99% by mass or less, and solid fats and oils contained in the fats and oils are more than 0% by mass and less than 50% by mass, 0 Spice paste seasoning containing water of 0.1% by mass or more and less than 10% by mass and water-soluble powder raw material of 0.1% by mass or more and 69% by mass or less, and SFC of crude fat content exceeds 0.5% at 25 ° C. It was clarified that the material composition had high separation stability and had a good melting in the mouth and a spicy feeling.
  • each component other than the special salt and monosodium glutamate is mixed, heated to 80 ° C, and then heated to 55 ° C with ice water. Cooled and mixed. Next, a special salt and monosodium glutamate were added and mixed, and then cooled and mixed with ice water to 5 ° C. to produce each spice paste seasoning composition.
  • components other than shortening, special salt, and monosodium glutamate were mixed, heated and mixed to a temperature of 80 ° C., cooled to room temperature, shortened and mixed, and then mixed with the special salt.
  • Monosodium glutamate was mixed in the same manner as above.
  • polyglycerin fatty acid ester product name: TAISET AD (Taiyo Kagaku Co., Ltd.)
  • Viscosity indicates a value measured at a shear rate of 1 (1 / s) at 25 ° C.
  • the obtained composition was used in the following experiments.
  • a creep meter RE2-3305B manufactured by Yamaden Co., Ltd.
  • the deformation rate of an arbitrary measurement point is x%
  • the stress is yN
  • the deformation rate of the next measurement point is X%
  • the stress is YN
  • (Y-y) / (X-x) (difference in load between consecutive measurement points) (N) divided by the difference in deformation rate (%)) was calculated as a differentiated value (N /%).
  • the minimum value obtained by differentiating the load at a deformation rate of 50% or less and the maximum value obtained by differentiating the load within 2% from the deformation rate were as follows: pepper (-106.6 N /). % And 1.3N /%), sesame (-5.16N /% and 0N /%).
  • a spice paste seasoning composition containing 19% by mass or less of extremely hardened fat and oil, containing no water, having an SFC of more than 0.5%, and having a viscosity of 2000 mPa ⁇ s or more.
  • the minimum value obtained by differentiating the load at a deformation rate of 50% or less using a creep meter under the above-mentioned predetermined conditions is less than -2N /%, and within 2% of the deformation rate.
  • 1% by mass or more of the ingredients having the maximum value obtained by differentiating the load is 0 N /% or more; 30% by mass or more of the fat and oil, and the solid fat and oil contained in the fat and oil is 0% by mass or more, and /
  • the extremely hardened fat and oil contained in the fat and oil contains 0% by mass or more and 19% by mass or less of fat and oil; and 0% by mass or more and less than 10% by mass of water, and the crude fat content SFC is 0.5 at 25 ° C.
  • the spicy paste seasoning composition having a viscosity of more than% and a viscosity of 2000 mPa ⁇ s or more at 25 ° C. and a shear rate of 1 (1 / s) is good as a blended ingredient when eaten as it is without heating. You can feel the texture (for example, crunchy feeling), and the blended ingredients are less likely to cause precipitation or non-uniform dispersion during production, transportation, or storage, and have good dispersibility. It was revealed that it has high separation stability.
  • the spice paste seasoning composition having a crude fat content of SFC exceeding 0.5% at 25 ° C. had high separation stability and had a good melting and spicy feeling. .. It was also confirmed that the composition is easy to squeeze out with a finger when filled in a flexible container, and is easy to use and handle.
  • Each of the four specialized panelists ate the spice paste seasoning composition, and for each composition, the flavor of each spice was ⁇ (strong spice), ⁇ (spicy), ⁇ (spicy). Is not enough), ⁇ (weak spice feeling).
  • the spice when the spice is pepper, heating at a temperature of 60 ° C. reduces the dustiness of the pepper and gives a clear scent. By heating at a temperature of 100 ° C., the pepper is heated. The dustiness disappeared and the cooking aroma could be added. On the other hand, a burning odor was felt in the composition obtained by heating at a temperature of 160 ° C.
  • heating at a temperature of 60 ° C. slightly weakens the green scent, and the sweet scent of red pepper can be imparted. By heating to a temperature exceeding 100 ° C., the spice is heavy and sweet. The roasted aroma could be added.
  • the raw aroma when the spice is onion, the raw aroma can be weakened by heating at a temperature of 60 ° C, and a scent with a cooking feeling can be imparted by heating at a temperature of 80 ° C. It was possible to impart a fragrant roasted aroma by heating at a temperature of 100 ° C.

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Abstract

The present invention relates to: a spice paste seasoning composition that is capable of realizing a feeling of a good spice flavor, that has a sufficient smoothness, that also has a good melt-in-the-mouth feeling and a good texture when put in the mouth, and that has high separation stability; and a manufacturing method for said composition.

Description

香辛料ペースト調味料組成物Spice paste seasoning composition
 本発明は、分離安定性を有し、かつ良好な口どけとコクを有する香辛料ペースト調味料組成物、ならびにその製造方法に関する。 The present invention relates to a spice paste seasoning composition having separation stability and good melting and richness, and a method for producing the same.
 香辛料を調味料等と共に食用油脂と混合してなるペースト状調味料(以下、「香辛料ペースト調味料組成物」と記載する場合がある)が知られている。香辛料ペースト調味料組成物は、炒め料理、煮込み料理、鍋料理、及びスープ等の種々の料理の調理において、味付け及び香り付けに利用されている。 A paste-like seasoning (hereinafter, may be referred to as "spices paste seasoning composition") in which a spice is mixed with an edible oil or fat together with a seasoning or the like is known. The spice paste seasoning composition is used for seasoning and flavoring in cooking various dishes such as fried dishes, stewed dishes, hot pot dishes, and soups.
 従来、様々な香辛料ペースト調味料組成物が開発され、報告されている。 Conventionally, various spice paste seasoning compositions have been developed and reported.
 特許文献1には、液状油脂、極度硬化油及び可塑性油脂を含む油脂原料と、香辛料等の粉体原料と、乳化剤とを含むペースト状調味料の製造方法が記載され、液状油脂、極度硬化油、香辛料及び乳化剤を品温が72℃に達するまで攪拌しながら加熱し、その後、品温が35℃になるまで冷却してから、可塑性油脂であるショートニングを20.0質量部混合して調製された組成物が開示されている。 Patent Document 1 describes a method for producing a paste-like seasoning containing a liquid fat, an extremely hardened oil, a fat and oil raw material containing a plastic fat and oil, a powder raw material such as a spice, and an emulsifier. , Spices and emulsifiers are heated with stirring until the product temperature reaches 72 ° C., then cooled to 35 ° C., and then 20.0 parts by mass of shortening, which is a plastic fat, is mixed and prepared. The composition is disclosed.
 特許文献2には、油脂及び緑色乾燥野菜等の具材からなる油脂組成物が記載され、油脂として菜種極度硬化油を10質量%の量で含む組成物が開示されている。 Patent Document 2 describes an oil and fat composition composed of ingredients such as oil and fat and green dried vegetables, and discloses a composition containing rapeseed extremely hydrogenated oil in an amount of 10% by mass as the oil and fat.
 特許文献3には、油脂及び乾燥香辛料等の具材からなる油脂組成物が可撓性容器に充填された油脂食品が記載され、油脂として菜種極度硬化油を10質量%の量で含む油脂食品が開示されている。 Patent Document 3 describes an oil / fat food in which a flexible container is filled with an oil / fat composition composed of ingredients such as oil / fat and dried spices, and the oil / fat food contains rapeseed extremely hydrogenated oil in an amount of 10% by mass as the oil / fat. Is disclosed.
 特許文献4には、香辛料を食用油脂とともに磨砕した後、加熱殺菌して製造されるペースト香辛料が記載されている。 Patent Document 4 describes a paste spice produced by grinding a spice together with an edible oil and fat and then heat sterilizing it.
 特許文献5には、10℃における固体脂含有量(以下、「SFC」と記載する)が25%以下である食用油脂、香辛料等の粉体調味料、及びHLBが4以下の乳化剤を5℃~35℃で混合することを含む、チューブ入り半練り状調味料の製造方法が記載され、食用油脂としてショートニングを油脂中に88質量%の量で含む半練り状調味料が開示されている。 Patent Document 5 describes edible oils and fats having a solid fat content (hereinafter referred to as "SFC") at 10 ° C., powder seasonings such as spices, and emulsifiers having an HLB of 4 or less at 5 ° C. A method for producing a semi-kneaded seasoning in a tube, which comprises mixing at ~ 35 ° C., is described, and a semi-kneaded seasoning containing shortening in the fat and oil in an amount of 88% by mass is disclosed as an edible fat and oil.
 特許文献6は、ポリグリセリン脂肪酸エステルを含有することを特徴とする透明性に優れた油脂の増粘又は固化剤にかかる発明について記載されており、油脂として香辛料類を油脂に浸漬又は固体状態で分散させた香味油を使用できることが記載されている。 Patent Document 6 describes an invention relating to a thickening or solidifying agent for a fat or oil having excellent transparency, which is characterized by containing a polyglycerin fatty acid ester, and spices as the fat or oil are immersed in the fat or oil or in a solid state. It is stated that dispersed flavor oils can be used.
特開2019-122268号公報JP-A-2019-122268 特許第3106465号公報Japanese Patent No. 3106465 特許第3252389号公報Japanese Patent No. 3252389 特開2004-283056号公報Japanese Unexamined Patent Publication No. 2004-283056 特許第6046411号公報Japanese Patent No. 6046411 特開2018-42550号公報Japanese Unexamined Patent Publication No. 2018-42550
 従来の香辛料ペースト調味料組成物の多くは炒め料理、煮込み料理、鍋料理、及びスープ等の種々の料理の調理において用いられ、すなわち、加熱して使用されることを前提としており、加熱することなくそのまま食される(例えば、タレやディップソースとして利用する)ことは意図されていなかった。そのため従来の香辛料ペースト調味料組成物を、加熱することなくそのまま食した場合には香辛料の風味が十分に感じられない場合や、滑らかさが十分でなく、また口に入れた際の口どけが悪く良好な食感が得られない場合があった。さらに、従来の香辛料ペースト調味料組成物には分離安定性が高くないものがあり、保存中に油浮きを生じる場合があった。また、従来の香辛料ペースト調味料組成物には、可撓性容器に充填されている場合に、容器を指で押しても容易に絞り出すことができない場合があった。 Many of the conventional spicy paste seasoning compositions are used in cooking various dishes such as fried dishes, stewed dishes, hot pot dishes, and soups, that is, they are supposed to be used by heating and are to be heated. It was not intended to be eaten as is (for example, used as a sauce or dip sauce). Therefore, when the conventional spice paste seasoning composition is eaten as it is without heating, the flavor of the spice is not sufficiently felt, the smoothness is not sufficient, and the mouth melts when put in the mouth. In some cases, a bad and good texture could not be obtained. Further, some conventional spice paste seasoning compositions do not have high separation stability, and oil floating may occur during storage. Further, in the conventional spice paste seasoning composition, when it is filled in a flexible container, it may not be possible to easily squeeze it even if the container is pushed with a finger.
 そこで本発明は、加熱して用いられるだけでなく、加熱することなくそのまま食した場合においても、香辛料の良好な風味を感じることができ、また、十分な滑らかさを有し、口に入れた際の口どけもよくコクがある良好な食感を有し、さらに、高い分離安定性を有する香辛料ペースト調味料組成物を提供することを目的とする。また、可撓性容器に充填されている場合には、容器を指で押して容易に絞り出すことが可能であり、香辛料ペースト調味料組成物を提供することを目的とする。 Therefore, the present invention can not only be used by heating, but also when eaten as it is without heating, the good flavor of the spice can be felt, and it has sufficient smoothness and is put into the mouth. It is an object of the present invention to provide a spice paste seasoning composition having a good texture that melts in the mouth and is rich and has high separation stability. Further, when the container is filled in a flexible container, the container can be easily squeezed out by pressing the container with a finger, and it is an object of the present invention to provide a spice paste seasoning composition.
 本発明者らは上記課題を解決すべく鋭意検討した結果、1質量%以上70質量%以下の香辛料、30質量%以上99質量%以下の油脂であって該油脂に含まれる固形油脂は0質量%超50質量%未満である油脂、0質量%以上かつ10質量%未満の水、及び0.1質量%以上69質量%以下の水溶性粉体原料を含み、粗脂肪分のSFCが25℃で0.5%を超え、25℃及びせん断速度1(1/s)における粘度が2000mPa・s~1000Pa・sである、香辛料ペースト調味料組成物が、加熱して用いられるだけでなく、加熱することなくそのまま食した場合においても、香辛料の良好な風味を感じることができ、また、口どけもよくコクがある良好な食感を有し、さらに、高い分離安定性を有することを見出した。 As a result of diligent studies to solve the above problems, the present inventors have made spices of 1% by mass or more and 70% by mass or less, and fats and oils of 30% by mass or more and 99% by mass or less, and the solid fats and oils contained in the fats and oils are 0% by mass. It contains fats and oils of more than% and less than 50% by mass, water of 0% by mass or more and less than 10% by mass, and water-soluble powder raw materials of 0.1% by mass or more and 69% by mass or less, and the SFC of crude fat content is 25 ° C. A spice paste seasoning composition having a mass of more than 0.5% and a viscosity at 25 ° C. and a shear rate of 1 (1 / s) of 2000 mPa · s to 1000 Pa · s is not only used by heating, but also heated. It was found that even when eaten as it is without doing so, the good flavor of the spice can be felt, the mouthfeel is good and the texture is rich, and the separation stability is high. ..
 本発明はこれらの知見に基づくものであり、以下の発明を包含する。
[1] 1質量%以上70質量%以下の香辛料、30質量%以上99質量%以下の油脂であって該油脂に含まれる固形油脂は0質量%超50質量%未満である油脂、0質量%以上かつ10質量%未満の水、及び0.1質量%以上69質量%以下の水溶性粉体原料を含み、粗脂肪分のSFCが25℃で0.5%を超え、25℃及びせん断速度1(1/s)における粘度が2000mPa・s~1000Pa・sである、香辛料ペースト調味料組成物。
[2] 前記油脂中に含まれる極度硬化油脂は0質量%以上19質量%以下の量である、[1]の組成物。
[3] さらに油系増粘剤を含む、[1]又は[2]の組成物。
[4] 油系増粘剤がポリグリセリン脂肪酸エステルである、[3]に記載の組成物。
[5] 水溶性粉体原料が食塩、水溶性デキストリン、グルタミン酸ソーダ、ブドウ糖、グラニュー糖、上白糖、クエン酸、造粒塩、岩塩、イノシン酸、グアニル酸からなる群から選択される1又は2以上の粉体原料である、[1]~[4]のいずれかの組成物。
[6] 香辛料がコショウ、ゴマ、トウガラシ、ニンニク、オニオン、山椒、花椒、生姜からなる群から選択される1又は2以上の香辛料である、[1]~[5]のいずれかの組成物。
[7] 1質量%以上70質量%以下の香辛料、30質量%以上99質量%以下の油脂であって該油脂に含まれる固形油脂は0質量%超50質量%未満である油脂、0質量%以上かつ10質量%未満の水、及び0.1質量%以上69質量%以下の水溶性粉体原料を混合すること、香辛料ペースト調味料組成物の粗脂肪分のSFCが25℃で0.5%を超とし、さらに25℃及びせん断速度1(1/s)における粘度が2000mPa・s~1000Pa・sとすること、を含む、香辛料ペースト調味料組成物の製造方法。
[8] 前記油脂中に含まれる極度硬化油脂は0質量%以上19質量%以下の量である、[7]の製造方法。
[9] さらに油系増粘剤を混合すること、を含む、[7]又は[8]の製造方法。
[10] 油系増粘剤がポリグリセリン脂肪酸エステルである、[7]~[9]のいずれかの製造方法。
[11] 水溶性粉体原料が食塩、水溶性デキストリン、グルタミン酸ソーダ、ブドウ糖、グラニュー糖、上白糖、クエン酸、造粒塩、岩塩、イノシン酸、グアニル酸からなる群から選択される1又は2以上の粉体原料である、[7]~[10]のいずれかの製造方法。
[12] 香辛料がコショウ、ゴマ、トウガラシ、ニンニク、オニオン、山椒、花椒、生姜からなる群から選択される1又は2以上の香辛料である、[7]~[11]のいずれかの製造方法。
The present invention is based on these findings and includes the following inventions.
[1] Spices of 1% by mass or more and 70% by mass or less, fats and oils of 30% by mass or more and 99% by mass or less, and the solid fats and oils contained in the fats and oils are more than 0% by mass and less than 50% by mass, 0% by mass. It contains water of more than 10% by mass and less than 10% by mass, and a water-soluble powder raw material of 0.1% by mass or more and 69% by mass or less, and the SFC of crude fat content exceeds 0.5% at 25 ° C., 25 ° C. and shear rate. A spice paste seasoning composition having a viscosity at 1 (1 / s) of 2000 mPa · s to 1000 Pa · s.
[2] The composition of [1], wherein the amount of the extremely hardened fat and oil contained in the fat and oil is 0% by mass or more and 19% by mass or less.
[3] The composition of [1] or [2] further containing an oil-based thickener.
[4] The composition according to [3], wherein the oil-based thickener is a polyglycerin fatty acid ester.
[5] 1 or 2 selected from the group consisting of salt, water-soluble dextrin, monosodium glutamate, glucose, granulated sugar, white sugar, citric acid, granulated salt, rock salt, inosinic acid, and guanylic acid as the raw material for the water-soluble powder. The composition according to any one of [1] to [4], which is the above powder raw material.
[6] The composition according to any one of [1] to [5], wherein the spice is one or more spices selected from the group consisting of pepper, sesame, pepper, garlic, onion, Japanese pepper, Chinese pepper, and ginger.
[7] Spices of 1% by mass or more and 70% by mass or less, fats and oils of 30% by mass or more and 99% by mass or less, and the solid fats and oils contained in the fats and oils are more than 0% by mass and less than 50% by mass, 0% by mass. Mixing more than 10% by mass of water and 0.1% by mass or more and 69% by mass or less of water-soluble powder raw material, SFC of crude fat content of spice paste seasoning composition is 0.5 at 25 ° C. % Is more than%, and the viscosity at 25 ° C. and a shear rate of 1 (1 / s) is 2000 mPa · s to 1000 Pa · s.
[8] The production method according to [7], wherein the amount of extremely hardened fat and oil contained in the fat and oil is 0% by mass or more and 19% by mass or less.
[9] The production method of [7] or [8], which further comprises mixing an oil-based thickener.
[10] The production method according to any one of [7] to [9], wherein the oil-based thickener is a polyglycerin fatty acid ester.
[11] 1 or 2 selected from the group consisting of salt, water-soluble dextrin, monosodium glutamate, glucose, granulated sugar, white sugar, citric acid, granulated salt, rock salt, inosinic acid, and guanylic acid as the raw material for the water-soluble powder. The production method according to any one of [7] to [10], which is the above powder raw material.
[12] The production method according to any one of [7] to [11], wherein the spice is one or more spices selected from the group consisting of pepper, sesame, pepper, garlic, onion, Japanese pepper, Chinese pepper, and ginger.
 また、本発明者らは上記課題を解決すべく鋭意検討した結果、油系増粘剤を用いて油脂を増粘させ、その中に香辛料を含んでなり、水を0質量%以上かつ10質量%未満の量、油脂に含まれる固形油脂は0質量%超50質量%未満の量で含み、所定の粗脂肪分のSFC値を有する香辛料ペースト調味料組成物が、加熱して用いられるだけでなく、加熱することなくそのまま食した場合においても、香辛料の良好な風味を感じることができ、また、十分な滑らかさを有し、口どけもよく良好な食感を有し、さらに、分離安定性が高く、可撓性容器に充填されている場合には、容器を指で押して容易に絞り出すことが可能であることを見出した。 In addition, as a result of diligent studies to solve the above problems, the present inventors have thickened oils and fats using an oil-based thickener, which contains spices, and contains 0% by mass or more and 10% by mass of water. A spice paste seasoning composition containing less than%, the amount of solid fat contained in the fat and oil in an amount of more than 0% by mass and less than 50% by mass and having an SFC value of a predetermined crude fat content is simply used by heating. Even when eaten as it is without heating, you can feel the good flavor of spices, it has sufficient smoothness, it melts in the mouth and has a good texture, and it is separated and stable. It has been found that when the container is highly flexible and is filled in a flexible container, the container can be easily squeezed out by pushing it with a finger.
 本発明はこれらの知見に基づくものであり、以下の発明を包含する。
[1] 香辛料、油脂、油系増粘剤を含み、水を0質量%以上10質量%未満の量で含み、前記油脂に含まれる固形油脂は0質量%超50質量%未満の量であり、粗脂肪分のSFCが25℃で0.5%を超え、かつ容器に充填されている、香辛料ペースト調味料組成物。
[2] さらに前記油脂中に含まれる極度硬化油脂は0質量%以上19質量%以下の量である、[1]の組成物。
[3] 25℃及びせん断速度1(1/s)における粘度が2000mPa・s~1000Pa・sである、[1]又は[2]の組成物。
[4] 油系増粘剤がポリグリセリン脂肪酸エステルである、[1]~[3]のいずれかの組成物。
[5] 香辛料がコショウ、トウガラシ、ニンニク、山椒、花椒、生姜からなる群から選択される1又は2以上の香辛料である、[1]~[4]のいずれかの組成物。
[6] 香辛料含量が1質量%以上70質量%以下であり、油脂含量が30質量%以上99質量%以下である、[1]~[5]のいずれかの組成物。
[7] 香辛料、油系増粘剤、固形油脂が0質量%超50質量%未満の量である油脂、0質量%以上10質量%未満の量の水、を混合し、粗脂肪分のSFCが25℃で0.5%を超えるように調整する工程、
 得られた組成物を容器に充填する工程、
を含む、香辛料ペースト調味料組成物の製造方法。
[8] さらに極度硬化油脂を0質量%以上19質量%以下の量で混合する、[7]の製造方法。
[9] 油系増粘剤がポリグリセリン脂肪酸エステルである、[7]又は[8]の製造方法。
[10] 香辛料がコショウ、トウガラシ、ニンニク、山椒、花椒、生姜からなる群から選択される1又は2以上の香辛料である、[7]~[9]のいずれかの製造方法。
[11] 香辛料を1質量%以上70質量%以下、油脂を30質量%以上99質量%以下の量にてそれぞれ混合する、[7]~[10]のいずれかの製造方法。
[12] 組成物の25℃及びせん断速度1(1/s)における粘度が2000mPa・s~1000Pa・sとなる、[7]~[11]のいずれかの製造方法。
The present invention is based on these findings and includes the following inventions.
[1] Contains spices, fats and oils, and oil-based thickeners, contains water in an amount of 0% by mass or more and less than 10% by mass, and the solid fats and oils contained in the fats and oils are in an amount of more than 0% by mass and less than 50% by mass. , A spice paste seasoning composition in which the crude fat content SFC exceeds 0.5% at 25 ° C. and is filled in a container.
[2] The composition according to [1], wherein the amount of the extremely hardened fat and oil contained in the fat and oil is 0% by mass or more and 19% by mass or less.
[3] The composition of [1] or [2] having a viscosity of 2000 mPa · s to 1000 Pa · s at 25 ° C. and a shear rate of 1 (1 / s).
[4] The composition according to any one of [1] to [3], wherein the oil-based thickener is a polyglycerin fatty acid ester.
[5] The composition according to any one of [1] to [4], wherein the spice is one or more spices selected from the group consisting of pepper, pepper, garlic, Japanese pepper, Chinese pepper, and ginger.
[6] The composition according to any one of [1] to [5], wherein the spice content is 1% by mass or more and 70% by mass or less, and the fat and oil content is 30% by mass or more and 99% by mass or less.
[7] Spices, oil-based thickeners, fats and oils having a solid fat content of more than 0% by mass and less than 50% by mass, and water having an amount of 0% by mass or more and less than 10% by mass are mixed, and SFC having a crude fat content is mixed. The process of adjusting the temperature to exceed 0.5% at 25 ° C.
The process of filling the container with the obtained composition,
A method for producing a spice paste seasoning composition, which comprises.
[8] The production method according to [7], wherein the extremely cured fats and oils are further mixed in an amount of 0% by mass or more and 19% by mass or less.
[9] The method for producing [7] or [8], wherein the oil-based thickener is a polyglycerin fatty acid ester.
[10] The production method according to any one of [7] to [9], wherein the spice is one or more spices selected from the group consisting of pepper, pepper, garlic, Japanese pepper, Chinese pepper, and ginger.
[11] The production method according to any one of [7] to [10], wherein spices are mixed in an amount of 1% by mass or more and 70% by mass or less, and fats and oils are mixed in an amount of 30% by mass or more and 99% by mass or less.
[12] The production method according to any one of [7] to [11], wherein the viscosity of the composition at 25 ° C. and a shear rate of 1 (1 / s) is 2000 mPa · s to 1000 Pa · s.
 また、本発明者らは上記課題を解決すべく鋭意検討した結果、1質量%以上70質量%以下の香辛料、30質量%以上99質量%以下の油脂であって該油脂に含まれる固形油脂は0質量%超50質量%未満である油脂、及び0質量%以上かつ10質量%未満の水を60℃達温以上で加熱、混合すること、ならびに製造される香辛料ペースト調味料組成物の粗脂肪分のSFCが25℃で0.5%超となるように調整すること、を含む方法により製造された香辛料ペースト調味料組成物が、加熱して用いられるだけでなく、加熱することなくそのまま食した場合においても、香辛料の良好な風味とコクを感じることができ、また、十分な滑らかさを有し、口どけもよく良好な食感を有し、さらに、高い分離安定性を有することを見出した。 Further, as a result of diligent studies to solve the above problems, the present inventors have found that spices of 1% by mass or more and 70% by mass or less and fats and oils of 30% by mass or more and 99% by mass or less are solid fats and oils contained in the fats and oils. Oils and fats of more than 0% by mass and less than 50% by mass, and water of 0% by mass or more and less than 10% by mass are heated and mixed at a temperature of 60 ° C. or higher, and the crude fat of the spice paste seasoning composition produced. The spice paste seasoning composition produced by a method including adjusting the SFC of the minute to be more than 0.5% at 25 ° C. is not only used by heating, but also eaten as it is without heating. Even in the case of spices, it is possible to feel the good flavor and richness of spices, to have sufficient smoothness, to have a good texture that melts in the mouth, and to have high separation stability. I found it.
 本発明はこれらの知見に基づくものであり、以下の発明を包含する。
[1] 1質量%以上70質量%以下の香辛料、30質量%以上99質量%以下の油脂であって該油脂に含まれる固形油脂は0質量%超50質量%未満である油脂、及び0質量%以上かつ10質量%未満の水を60℃達温以上で加熱、混合すること、ならびに、香辛料ペースト調味料組成物の粗脂肪分のSFCが25℃で0.5%超とすること、を含む、香辛料ペースト調味料組成物の製造方法。
[2] 前記油脂中に含まれる極度硬化油脂は0質量%以上19質量%以下の量である、[1]の製造方法。
[3] さらに油系増粘剤を混合すること、を含む、[1]又は[2]の製造方法。
[4] 油系増粘剤がポリグリセリン脂肪酸エステルである、[3]の製造方法。
[5] 香辛料がコショウ、ゴマ、トウガラシ、ニンニク、オニオン、山椒、花椒、生姜からなる群から選択される1又は2以上の香辛料である、[1]~[4]のいずれかの製造方法。
[6] 組成物の25℃及びせん断速度1(1/s)における粘度が2000mPa・s~1000Pa・sとなる、[1]~[5]のいずれかの製造方法。
[7] [1]~[6]のいずれかの製造方法により製造された香辛料ペースト調味料組成物。
 本明細書は本願の優先権の基礎である日本国特許出願2019-216868号、日本国特許出願2019-216825号、及び日本国特許出願2019-216793号の明細書および/または図面に記載される内容を包含する。
 本明細書で引用した全ての刊行物、特許および特許出願をそのまま参考として本明細書にとり入れるものとする。
The present invention is based on these findings and includes the following inventions.
[1] Spices of 1% by mass or more and 70% by mass or less, fats and oils of 30% by mass or more and 99% by mass or less, and solid fats and oils contained in the fats and oils are more than 0% by mass and less than 50% by mass, and 0% by mass. % Or more and less than 10% by mass of water is heated and mixed at a temperature of 60 ° C. or higher, and the SFC of the crude fat content of the spice paste seasoning composition is more than 0.5% at 25 ° C. A method for producing a spice paste seasoning composition, including.
[2] The production method according to [1], wherein the amount of extremely hardened fat and oil contained in the fat and oil is 0% by mass or more and 19% by mass or less.
[3] The production method of [1] or [2], which further comprises mixing an oil-based thickener.
[4] The method for producing [3], wherein the oil-based thickener is a polyglycerin fatty acid ester.
[5] The production method according to any one of [1] to [4], wherein the spice is one or more spices selected from the group consisting of pepper, sesame, pepper, garlic, onion, Japanese pepper, Chinese pepper, and ginger.
[6] The production method according to any one of [1] to [5], wherein the viscosity of the composition at 25 ° C. and a shear rate of 1 (1 / s) is 2000 mPa · s to 1000 Pa · s.
[7] A spice paste seasoning composition produced by any of the production methods of [1] to [6].
This specification is described in the specification and / or drawings of Japanese patent application 2019-216868, Japanese patent application 2019-216825, and Japanese patent application 2019-216793, which are the basis of the priority of the present application. Including the content.
All publications, patents and patent applications cited herein are incorporated herein by reference in their entirety.
 本発明によれば、加熱して用いられるだけでなく、加熱することなくそのまま食した場合においても、香辛料の良好な風味とコクを感じることができ、また、十分な滑らかさを有し、口どけもよくコクがある良好な食感を有し、さらに、高い分離安定性を有する香辛料ペースト調味料組成物を提供することができる。また、可撓性容器に充填されている場合には、容器を指で押して容易に絞り出すことが可能な香辛料ペースト調味料組成物を提供することができる。 According to the present invention, not only when it is used by heating, but also when it is eaten as it is without heating, it is possible to feel the good flavor and richness of the spice, and it has sufficient smoothness and mouth. It is possible to provide a spice paste seasoning composition having a good texture that is thick and rich, and further has high separation stability. Further, when the container is filled in a flexible container, it is possible to provide a spice paste seasoning composition that can be easily squeezed by pressing the container with a finger.
 本発明は、1質量%以上70質量%以下の香辛料、30質量%以上99質量%以下の油脂であって該油脂に含まれる固形油脂は0質量%超50質量%未満である油脂、0質量%以上かつ10質量%未満の水、及び0.1質量%以上69質量%以下の水溶性粉体原料を含み、粗脂肪分のSFCが25℃で0.5%を超え、25℃及びせん断速度1(1/s)における粘度が2000mPa・s~1000Pa・sである、香辛料ペースト調味料組成物に関するものである。 In the present invention, spices of 1% by mass or more and 70% by mass or less, fats and oils of 30% by mass or more and 99% by mass or less, and solid fats and oils contained in the fats and oils are more than 0% by mass and less than 50% by mass, 0% by mass. It contains water of% or more and less than 10% by mass, and a water-soluble powder raw material of 0.1% by mass or more and 69% by mass or less, and the SFC of crude fat content exceeds 0.5% at 25 ° C., and shears at 25 ° C. It relates to a spice paste seasoning composition having a viscosity at a speed of 1 (1 / s) of 2000 mPa · s to 1000 Pa · s.
 また、本発明は、香辛料、油脂、油系増粘剤を含み、水を0質量%以上10質量%未満の量で含み、前記油脂に含まれる固形油脂は0質量%超50質量%未満の量であり、粗脂肪分のSFCが25℃で0.5%を超え、かつ容器に充填されている、香辛料ペースト調味料組成物に関するものである。 Further, the present invention contains spices, fats and oils, and oil-based thickeners, contains water in an amount of 0% by mass or more and less than 10% by mass, and the solid fats and oils contained in the fats and oils are more than 0% by mass and less than 50% by mass. It relates to a spice paste seasoning composition in which the crude fat content SFC exceeds 0.5% at 25 ° C. and is filled in a container.
 また、本発明は、1質量%以上70質量%以下の香辛料、30質量%以上99質量%以下の油脂であって該油脂に含まれる固形油脂は0質量%超50質量%未満である油脂、及び、0質量%以上かつ10質量%未満の水を60℃達温以上で加熱、混合すること、ならびに製造される香辛料ペースト調味料組成物の粗脂肪分のSFCが25℃で0.5%超となるように調整することを含む、香辛料ペースト調味料組成物の製造方法に関するものである。 Further, in the present invention, spices of 1% by mass or more and 70% by mass or less, fats and oils of 30% by mass or more and 99% by mass or less, and solid fats and oils contained in the fats and oils are more than 0% by mass and less than 50% by mass. In addition, water of 0% by mass or more and less than 10% by mass is heated and mixed at a temperature of 60 ° C. or higher, and the crude fat content SFC of the produced spice paste seasoning composition is 0.5% at 25 ° C. It relates to a method for producing a spice paste seasoning composition, which comprises adjusting the composition so as to be super.
 本発明において「香辛料」とは、植物から採取され、調理の際に香りや辛味、色を付与したり、臭みを消したりするものの総称であり、ハーブ類や香辛植物、複数の香辛料をブレンドしたものが挙げられる。例えば、本発明において利用可能な香辛料としては、アジョワン、アニス、エシャロット、オールスパイス、オニオン、オレガノ、カファライム、カホクザンショウ(花椒)、カルダモン、カレーリーフ、キャラウェイ、クミン、グリーンペッパー、クローブ、ゴマ、コショウ、コリアンダー(パクチー)、サフラン、山椒、シソ、シナモン、生姜、スターアニス、セージ、タイム、ターメリック、タデ、タラゴン、チンピ、ディル、トウガラシ、ナツメグ、ニラ、ニンイク、ネギ、バジル、パセリ、バニラ、パプリカ、ハラペーニョ、フェヌグリーク、フェンネル、ホースラディッシュ、マージョラム、マスタード、ミカン、ミント、ラディッシュ、レモン、レモングラス、ローズマリー、ローリエ、ワサビ、五香粉、ガラムマサラ、カレー粉、七味唐辛子、柚子胡椒(柚子唐辛子)、ケシの実等が挙げられるが、これらに限定はされない。好ましくは、本発明の香辛料ペースト調味料組成物には、香辛料として、コショウ、ゴマ、トウガラシ、ニンニク、オニオン、山椒、花椒、生姜からなる群から選択される1又は2以上の刺激性香辛料が含まれる。 In the present invention, "spices" is a general term for substances that are collected from plants and impart aroma, pungency, color, or eliminate odors during cooking, and are blended with herbs, spice plants, and a plurality of spices. Things can be mentioned. For example, the spices that can be used in the present invention include Ajowan, Anis, Eshalot, All Spice, Onion, Oregano, Kafalime, Kahokuzansho (Japanese pepper), Cardamon, Curry leaf, Caraway, Cumin, Green pepper, Clove, Sesame , Pepper, Coriander (Pakuchi), Saffron, Sansho, Perilla, Cinnamon, Ginger, Star Anis, Sage, Thyme, Turmeric, Tade, Taragon, Chinpi, Dill, Pepper, Natsumegu, Nira, Niniku, Negi, Basil, Parsley, Vanilla , Paprika, Jalapeno, Fenuglique, Fennell, Horse Radish, Marjorum, Mustard, Mikan, Mint, Radish, Lemon, Lemongrass, Rosemary, Laurier, Wasabi, Five Spices, Garam Masala, Curry Powder, Shichimi Pepper, Yuzu Pepper ), Pepper fruit, etc., but are not limited to these. Preferably, the spice paste seasoning composition of the present invention comprises one or more stimulating spices selected from the group consisting of pepper, sesame, pepper, garlic, onion, Japanese pepper, Chinese pepper and ginger as spices. Is done.
 本発明において、香辛料は粉末の形態で用いることが可能であり、乾燥粉砕物や抽出物の乾燥粉末の形態で用いることができる。 In the present invention, the spice can be used in the form of a powder, and can be used in the form of a dry pulverized product or a dry powder of an extract.
 本発明の香辛料ペースト調味料組成物には、香辛料を任意の量で含めることができ、その量は用いる香辛料に応じて適宜設定することができる。例えば、本発明の香辛料ペースト調味料組成物には、香辛料を1質量%以上、2質量%以上、3質量%以上、4質量%以上、又は5質量%以上の量で含み、その上限は特に限定されるものではないが、例えば、70質量%以下、60質量%以下、50質量%以下、40質量%以下、又は30質量%以下とすることができる。本発明の香辛料ペースト調味料組成物には、香辛料を例えば1質量%以上70質量%以下、好ましくは2質量%以上60質量%以下、より好ましくは3質量%以上50質量%以下、さらに好ましくは4質量%以上40質量%以下、最も好ましくは5質量%以上30質量%以下の範囲より適宜選択される量で含めることができる。香辛料が1質量%よりも少ないと香辛料の良好な風味が得られない場合があり、70質量%よりも多いと、香辛料ペースト調味料組成物の滑らかさが得られない場合がある。 The spice paste seasoning composition of the present invention can contain an arbitrary amount of spices, and the amount can be appropriately set according to the spices used. For example, the spice paste seasoning composition of the present invention contains spices in an amount of 1% by mass or more, 2% by mass or more, 3% by mass or more, 4% by mass or more, or 5% by mass or more, and the upper limit thereof is particularly high. Although not limited to, it can be, for example, 70% by mass or less, 60% by mass or less, 50% by mass or less, 40% by mass or less, or 30% by mass or less. In the spice paste seasoning composition of the present invention, the spice is added, for example, 1% by mass or more and 70% by mass or less, preferably 2% by mass or more and 60% by mass or less, more preferably 3% by mass or more and 50% by mass or less, still more preferably. It can be contained in an amount appropriately selected from the range of 4% by mass or more and 40% by mass or less, most preferably 5% by mass or more and 30% by mass or less. If the amount of spice is less than 1% by mass, a good flavor of the spice may not be obtained, and if it is more than 70% by mass, the smoothness of the spice paste seasoning composition may not be obtained.
 本発明において「油脂」とは、食用に供される動植物性油脂(食用油とも呼ばれる場合がある)を意味し、液体油脂、固形油脂(例えば、極度硬化油脂、可塑性油脂(ショートニング、ラード、エステル交換油脂))等であり、これらの油脂の1種又は2種以上が利用される。 In the present invention, "fat and oil" means animal and vegetable fats and oils (sometimes also called edible oils) used for food, and liquid fats and oils, solid fats and oils (for example, extremely hardened fats and oils, plastic fats and oils (shortening, lard, ester)). Replacement fats and oils)), etc., and one or more of these fats and oils are used.
 本発明において利用可能な油脂としては、例えば、ショートニング、マーガリン、パーム油、パーム核油、綿実油、菜種白絞油、大豆油、コーン油、サフラワー油、ヒマワリ油、オリーブ油、米ぬか油、からし油等の植物油脂、バター、ラード、牛脂及び豚脂等の動物油脂、及びこれらの極度硬化油脂、エステル交換油脂等を挙げることができる(これらに限定はされない)。油脂はいずれか単独で用いてもよいし、異なる油脂を組み合わせて用いてもよい。 Examples of fats and oils that can be used in the present invention include shortening, margarine, palm oil, palm kernel oil, cottonseed oil, rapeseed white squeezed oil, soybean oil, corn oil, saflower oil, sunflower oil, olive oil, rice bran oil, and mustard oil. Examples thereof include vegetable oils and fats such as oils, animal fats and oils such as butter, lard, beef and pork fats, extremely hardened fats and oils thereof, and ester-exchanged fats and oils (not limited to these). The fats and oils may be used alone or in combination of different fats and oils.
 本発明の香辛料ペースト調味料組成物には、油脂を任意の量で含めることができ、その量は本発明の香辛料ペースト調味料組成物に含まれる粗脂肪分の固体脂含有量(SFC)が後述する所望の値となる範囲で適宜調整することができる。 The spice paste seasoning composition of the present invention may contain any amount of fats and oils, the amount of which is the solid fat content (SFC) of the crude fat contained in the spice paste seasoning composition of the present invention. It can be appropriately adjusted within a range of a desired value described later.
 例えば、本発明の香辛料ペースト調味料組成物には油脂が30質量%以上、35質量%以上、又は40質量%以上の量で含まれ、その上限は特に限定されるものではないが、例えば、99質量%以下、98質量%以下、又は95質量%以下とすることができる。本発明の香辛料ペースト調味料組成物には油脂を、例えば、30質量%以上99質量%以下、好ましくは35質量%以上98質量%以下、より好ましくは40質量%以上95質量%以下の範囲より適宜選択される量で含めることができる。油脂が30質量%よりも少ない場合や、99質量%よりも多い場合には、本発明の香辛料ペースト調味料組成物の滑らかさや口どけ等の食感の低下を生じる場合や、風味の低下を生じる場合がある。 For example, the spice paste seasoning composition of the present invention contains fats and oils in an amount of 30% by mass or more, 35% by mass or more, or 40% by mass or more, and the upper limit thereof is not particularly limited. It can be 99% by mass or less, 98% by mass or less, or 95% by mass or less. The spice paste seasoning composition of the present invention contains fats and oils, for example, from a range of 30% by mass or more and 99% by mass or less, preferably 35% by mass or more and 98% by mass or less, and more preferably 40% by mass or more and 95% by mass or less. It can be included in an appropriately selected amount. When the amount of fats and oils is less than 30% by mass or more than 99% by mass, the spice paste seasoning composition of the present invention may have a decrease in texture such as smoothness and melting in the mouth, or a decrease in flavor. May occur.
 本発明に利用する油脂中には、固形油脂が0質量%超、0.5質量%超、1質量%超、2質量%超、3質量%超、4質量%超、5質量%超、又は6質量%超の量で含まれ、その上限は特に限定されるものではないが、例えば、50質量%未満、40質量%未満、30質量%未満、20質量%未満、15質量%未満、又は10質量%未満、とすることができる。本発明に利用する油脂中、固形油脂が0質量%超50質量%未満、すなわち、0質量%超40質量%未満、0質量%超30質量%未満、0質量%超20質量%未満、5質量%超15質量%未満、又は5質量%超10質量%未満の量で含まれていてもよい。油脂中に固形油脂が含まれることによって、香辛料ペースト調味料組成物の滑らかさを調節することができ、また香辛料や下記に詳述する具材の香りや辛みを程よく持続させ、コクを付与し、風味を強く感じさせることができ、さらに保存中の油浮きを抑えることができる。 Among the fats and oils used in the present invention, solid fats and oils contain more than 0% by mass, more than 0.5% by mass, more than 1% by mass, more than 2% by mass, more than 3% by mass, more than 4% by mass, and more than 5% by mass. Alternatively, it is contained in an amount of more than 6% by mass, and the upper limit thereof is not particularly limited, but for example, less than 50% by mass, less than 40% by mass, less than 30% by mass, less than 20% by mass, less than 15% by mass, Or it can be less than 10% by mass. Among the fats and oils used in the present invention, solid fats and oils are more than 0% by mass and less than 50% by mass, that is, more than 0% by mass and less than 40% by mass, more than 0% by mass and less than 30% by mass, and more than 0% by mass and less than 20% by mass, 5 It may be contained in an amount of more than mass% and less than 15% by mass, or more than 5% by mass and less than 10% by mass. By including solid fats and oils in the fats and oils, the smoothness of the spice paste seasoning composition can be adjusted, and the aroma and spiciness of the spices and the ingredients described in detail below are moderately maintained and rich. , The flavor can be strongly felt, and the oil floating during storage can be suppressed.
 「固形油脂」とは、上昇融点が30℃以上の油脂を意味する。このような固形油脂としては、例えば、ショートニング、ラード、エステル交換油脂、カカオバター、牛脂、パーム核油、菜種極度硬化油、大豆極度硬化油、パーム極度硬化油等が挙げられるが、これらに限定はされない。 "Solid fats and oils" means fats and oils having a rising melting point of 30 ° C. or higher. Examples of such solid fats and oils include shortening, lard, transesterified fats and oils, coconut butter, beef tallow, palm kernel oil, rapeseed extremely hardened oil, soybean extremely hardened oil, palm extremely hardened oil and the like, but are limited thereto. Not done.
 また、本発明に利用する油脂中には、液状油脂が50質量%以上、60質量%以上、70質量%以上、80質量%以上、85質量%以上、又は90質量%以上の量で含まれ、その上限は特に限定されるものではないが、例えば、100質量%未満、95質量%以下、又は95質量%未満とすることができる。本発明に利用する油脂中には液状油脂を、例えば、50質量%以上100質量%未満、すなわち、60質量%以上100質量%未満、70質量%以上100質量%未満、80質量%以上100質量%未満、85質量%以上95質量%以下もしくは95質量%未満、又は90質量%以上95質量%以下もしくは95質量%未満の量で含めることができる。液状油脂を含めることによって、香辛料ペースト調味料組成物を加熱することなくそのまま食した場合においても、十分な滑らかさを有し、口どけもよく良好な食感を付与することができる。 Further, the fats and oils used in the present invention contain liquid fats and oils in an amount of 50% by mass or more, 60% by mass or more, 70% by mass or more, 80% by mass or more, 85% by mass or more, or 90% by mass or more. The upper limit thereof is not particularly limited, but may be, for example, less than 100% by mass, 95% by mass or less, or less than 95% by mass. Liquid fats and oils used in the present invention include, for example, 50% by mass or more and less than 100% by mass, that is, 60% by mass or more and less than 100% by mass, 70% by mass or more and less than 100% by mass, 80% by mass or more and 100% by mass. It can be included in an amount of less than%, 85% by mass or more and 95% by mass or less or less than 95% by mass, or 90% by mass or more and 95% by mass or less or less than 95% by mass. By including the liquid fat and oil, even when the spice paste seasoning composition is eaten as it is without heating, it has sufficient smoothness and can be melted in the mouth and given a good texture.
 「液状油脂」とは、上昇融点が30℃未満の油脂を意味する。このような液状油脂としては、例えば、パーム油、パーム核油、綿実油、菜種白絞油、大豆油、コーン油、サフラワー油、ヒマワリ油、オリーブ油、米ぬか油、からし油等の植物油脂等が挙げられるが、これらに限定はされない。 "Liquid fat" means a fat having a rising melting point of less than 30 ° C. Examples of such liquid fats and oils include vegetable fats and oils such as palm oil, palm kernel oil, cottonseed oil, rapeseed white squeezed oil, soybean oil, corn oil, saflower oil, sunflower oil, olive oil, rice bran oil, and mustard oil. However, it is not limited to these.
 本発明に利用する油脂中には、ショートニングが0質量%以上、0.5質量%以上、又は1質量%以上の量で含まれ、その上限は特に限定されるものではないが、例えば、50質量%未満、45質量%以下、40質量%以下、30質量%以下、20質量%以下、10質量%以下、又は5質量%以下とすることができる。本発明に利用する油脂中にはショートニングが、例えば、ショートニングが0質量%以上50質量%未満、すなわち、0質量%以上45質量%以下、0質量%以上40質量%以下、0質量%以上30質量%以下、0質量%以上20質量%以下、0質量%以上10質量%以下、又は0質量%以上5質量%以下の量で含まれていてもよい。ショートニングを含めることによって、製造される香辛料ペースト調味料組成物の滑らかさを調節することができ、また保存中の油浮きを抑えることができる。ショートニングを50質量%以上の量で含む場合には、製造される香辛料ペースト調味料組成物について、加熱することなくそのまま食するには滑らかさが十分でなく、また口に入れた際の口どけが悪く食感が不良であったりする場合がある。 The fat and oil used in the present invention contains shortening in an amount of 0% by mass or more, 0.5% by mass or more, or 1% by mass or more, and the upper limit thereof is not particularly limited, but for example, 50. It can be less than mass%, 45% by mass or less, 40% by mass or less, 30% by mass or less, 20% by mass or less, 10% by mass or less, or 5% by mass or less. In the fats and oils used in the present invention, shortening is, for example, 0% by mass or more and less than 50% by mass, that is, 0% by mass or more and 45% by mass or less, 0% by mass or more and 40% by mass or less, 0% by mass or more and 30. It may be contained in an amount of 0% by mass or less, 0% by mass or more and 20% by mass or less, 0% by mass or more and 10% by mass or less, or 0% by mass or more and 5% by mass or less. By including shortening, the smoothness of the spice paste seasoning composition produced can be adjusted, and oil floating during storage can be suppressed. When shortening is contained in an amount of 50% by mass or more, the spice paste seasoning composition produced is not smooth enough to be eaten as it is without heating, and it melts in the mouth. It may be bad and the texture may be bad.
 さらに、本発明に利用する油脂中、極度硬化油脂が0質量%以上の量で含まれ、特に限定されるものではないが、例えば、0.5質量%以上、1質量%以上、又は1.5質量%以上の量で含まれ、その上限は特に限定されるものではないが、例えば、19質量%以下、18質量%以下、17質量%以下、16質量%以下、15質量%以下、14質量%以下、13質量%以下、12質量%以下、11質量%以下、10質量%以下、9質量%以下、8質量%以下、7質量%以下、6質量%以下、5質量%以下、4質量%以下、3質量%以下、又は2質量%以下の量で含めることができる。例えば、本発明に利用する油脂中、極度硬化油脂が0質量%以上19質量%以下、0質量%以上15質量%以下、0質量%以上10質量%以下、0質量%以上7質量%以下、好ましくは0質量%以上5質量%未満、より好ましくは0質量%以上4質量%未満、すなわち、0質量%以上4.5質量%以下、0質量%以上4質量%以下、0質量%以上3質量%以下、0.5質量%以上2質量%以下、又は1質量%以上1.5質量%以下の量で含まれていてもよい。極度硬化油脂を含めることによって、製造される香辛料ペースト調味料組成物の滑らかさを調節することができ、また保存中の油浮きを抑えることができる。極度硬化油脂を上記範囲よりも多くの量で含む場合には、製造される香辛料ペースト調味料組成物について、所望の粘度を得ることができない場合があり、滑らかさや口どけ等の食感の低下を生じる場合があり、また、配合した香辛料や下記に詳述する具材の良好な食感が得られない場合がある。 Further, the fats and oils used in the present invention contain extremely hardened fats and oils in an amount of 0% by mass or more, and are not particularly limited, but for example, 0.5% by mass or more, 1% by mass or more, or 1. It is contained in an amount of 5% by mass or more, and the upper limit thereof is not particularly limited, but for example, 19% by mass or less, 18% by mass or less, 17% by mass or less, 16% by mass or less, 15% by mass or less, 14 Mass% or less, 13% by mass or less, 12% by mass or less, 11% by mass or less, 10% by mass or less, 9% by mass or less, 8% by mass or less, 7% by mass or less, 6% by mass or less, 5% by mass or less, 4 It can be included in an amount of mass% or less, 3 mass% or less, or 2 mass% or less. For example, among the fats and oils used in the present invention, the extremely hardened fats and oils are 0% by mass or more and 19% by mass or less, 0% by mass or more and 15% by mass or less, 0% by mass or more and 10% by mass or less, 0% by mass or more and 7% by mass or less. Preferably 0% by mass or more and less than 5% by mass, more preferably 0% by mass or more and less than 4% by mass, that is, 0% by mass or more and 4.5% by mass or less, 0% by mass or more and 4% by mass or less, 0% by mass or more 3 It may be contained in an amount of mass% or less, 0.5% by mass or more and 2% by mass or less, or 1% by mass or more and 1.5% by mass or less. By including the extremely hardened oil and fat, the smoothness of the spice paste seasoning composition produced can be adjusted, and oil floating during storage can be suppressed. When the extremely hardened fat and oil is contained in an amount larger than the above range, it may not be possible to obtain the desired viscosity of the produced spice paste seasoning composition, and the texture such as smoothness and melting in the mouth is deteriorated. In addition, it may not be possible to obtain a good texture of the blended spices and the ingredients described in detail below.
 「極度硬化油脂」とは、不飽和脂肪酸がほとんど存在しなくなるまで、すなわちヨウ素価が実質的に0(通常は2~3以下)になるまで水素添加を施した油脂であって、硬度が高く、融点も50~70℃と高い固形油脂を意味する。このような極度硬化油脂としては、例えば、菜種油、大豆油、コーン油、サフラワー油、ヒマワリ油、オリーブ油、米ぬか油、綿実油、パーム油、パーム分別油、からし油、ラード、牛脂等(これらに限定はされない)から選択される油脂から調製された極度硬化油脂が挙げられる。 "Extremely hardened fats and oils" are fats and oils that have been hydrogenated until there are almost no unsaturated fatty acids, that is, until the iodine value is substantially 0 (usually 2 to 3 or less), and the hardness is high. It means a solid fat and oil having a high melting point of 50 to 70 ° C. Examples of such extremely hardened fats and oils include rapeseed oil, soybean oil, corn oil, safflower oil, sunflower oil, olive oil, rice bran oil, cottonseed oil, palm oil, palm fractionated oil, mustard oil, lard, and beef fat (these are). Examples include extremely hardened fats and oils prepared from fats and oils selected from).
 本発明において「水溶性粉体原料」とは水分と出会うと、当該水分中に溶解する物質であり、これにより本発明の香辛料ペースト調味料組成物が水溶性粉体原料を含む場合、口に入れた際に水溶性粉体原料が唾液に溶解し、本発明の香辛料ペースト調味料組成物の粘度が低下することで良好な口どけを得ることができる。本発明において「水溶性粉体原料」としては、例えば、食塩、水溶性デキストリン、グルタミン酸ソーダ、ブドウ糖、グラニュー糖、上白糖、クエン酸、造粒塩、岩塩、イノシン酸、グアニル酸等が挙げられるが、これらに限定はされない。水溶性粉体原料は飲食品の製造において通常用いられている、賦形剤、滑沢剤、結合剤、崩壊剤等の添加剤や、調味料として用いられるものを利用することができる。 In the present invention, the "water-soluble powder raw material" is a substance that dissolves in the water when it encounters water, so that when the spice paste seasoning composition of the present invention contains the water-soluble powder raw material, it is in the mouth. When added, the water-soluble powder raw material dissolves in saliva, and the viscosity of the spice paste seasoning composition of the present invention decreases, so that a good melting in the mouth can be obtained. Examples of the "water-soluble powder raw material" in the present invention include salt, water-soluble dextrin, monosodium glutamate, glucose, granulated sugar, white sugar, citric acid, granulated salt, rock salt, inosinic acid, guanylic acid and the like. However, it is not limited to these. As the water-soluble powder raw material, additives such as excipients, lubricants, binders and disintegrants, which are usually used in the production of foods and drinks, and those used as seasonings can be used.
 特に塩味(食塩等)、旨味(グルタミン酸ソーダ)、酸味、苦味、甘味(水溶性デキストリン、ブドウ糖)等の味がある水溶性粉体原料は口に入れた際に唾液の分泌が促進され、その唾液により本発明の香辛料ペースト調味料組成物の粘度の低下が起こることで、さらに良好な口どけを得ることができる。 In particular, water-soluble powder raw materials having tastes such as saltiness (salt, etc.), umami (soda glutamate), acidity, bitterness, and sweetness (water-soluble dextrin, glucose) promote saliva secretion when put in the mouth. Since saliva reduces the viscosity of the spicy paste seasoning composition of the present invention, a better melting in the mouth can be obtained.
 本発明の香辛料ペースト調味料組成物には、水溶性粉体原料を0質量%以上の任意の量で含めることができ、その含量は用いる粉体原料に応じて適宜設定することができる。本発明の香辛料ペースト調味料組成物が水溶性粉体原料を含む場合にはその量は例えば、0.1質量%以上、0.5質量%以上、1質量%以上、5質量%以上、10質量%以上、20質量%以上、又は30質量%以上であり、その上限は特に限定されるものではないが、例えば、69質量%以下、60質量%以下、50質量%以下、40質量%以下、30質量%以下、20質量%以下、10質量%以下、又は5質量%以下の量で含めることができる。例えば、本発明香辛料ペースト調味料組成物には、水溶性粉体原料を0.1質量%以上69質量%以下、好ましくは0.1質量%以上50質量%以下の量で含めることができる。水溶性の粉体原料を前記範囲で含めることによって、本発明の香辛料ペースト調味料組成物を口に入れた際に良好な口どけを奏することができる。例えば、粉体原料が食塩である場合には0.1質量%以上20質量%以下、より好ましくは1質量%以上10質量%以下で含めることができ、水溶性デキストリンである場合には1質量%以上50質量%以下、より好ましくは5質量%以上30質量%以下の範囲より適宜選択される量で含めることができ、グルタミン酸ソーダである場合には0.1質量%以上10質量%以下、より好ましくは1質量%以上5質量%以下で含めることができる。 The spice paste seasoning composition of the present invention may contain a water-soluble powder raw material in an arbitrary amount of 0% by mass or more, and the content thereof can be appropriately set according to the powder raw material used. When the spice paste seasoning composition of the present invention contains a water-soluble powder raw material, the amount thereof is, for example, 0.1% by mass or more, 0.5% by mass or more, 1% by mass or more, 5% by mass or more, 10 It is mass% or more, 20 mass% or more, or 30 mass% or more, and the upper limit thereof is not particularly limited, but for example, 69 mass% or less, 60 mass% or less, 50 mass% or less, 40 mass% or less. , 30% by mass or less, 20% by mass or less, 10% by mass or less, or 5% by mass or less. For example, the spice paste seasoning composition of the present invention can contain a water-soluble powder raw material in an amount of 0.1% by mass or more and 69% by mass or less, preferably 0.1% by mass or more and 50% by mass or less. By including the water-soluble powder raw material in the above range, a good melting in the mouth can be achieved when the spice paste seasoning composition of the present invention is put in the mouth. For example, when the powder raw material is salt, it can be contained in an amount of 0.1% by mass or more and 20% by mass or less, more preferably 1% by mass or more and 10% by mass or less, and when it is a water-soluble dextrin, 1% by mass. It can be contained in an amount appropriately selected from the range of% or more and 50% by mass or less, more preferably 5% by mass or more and 30% by mass or less, and in the case of sodium glutamate, 0.1% by mass or more and 10% by mass or less. More preferably, it can be contained in an amount of 1% by mass or more and 5% by mass or less.
 本発明において「油系増粘剤」とは、液状の油脂に添加して溶解することにより、当該油脂を増粘、固化、及び/又はゾル・ゲル化することが可能な物質を意味する。このような油系増粘剤としては、脂肪酸とポリグリセリンとを構成成分として含む、ポリグリセリン脂肪酸エステルを好適に用いることができる。 In the present invention, the "oil-based thickener" means a substance capable of thickening, solidifying, and / or sol-gelling the fat and oil by adding and dissolving the fat and oil. As such an oil-based thickener, a polyglycerin fatty acid ester containing a fatty acid and polyglycerin as constituent components can be preferably used.
 ポリグリセリン脂肪酸エステルを構成する脂肪酸(以下、「構成脂肪酸」と記載する)については、全構成脂肪酸の内、炭素数16~18の直鎖脂肪酸が分子数として45%以上含まれる場合に高い粘度を得ることができる。この割合は、全構成脂肪酸のモル数に対する炭素数16~18の直鎖脂肪酸のモル数の割合を示す。 The fatty acids constituting the polyglycerin fatty acid ester (hereinafter referred to as "constituting fatty acids") have a high viscosity when a linear fatty acid having 16 to 18 carbon atoms is contained as a molecular number of 45% or more among all the constituent fatty acids. Can be obtained. This ratio indicates the ratio of the number of moles of linear fatty acid having 16 to 18 carbon atoms to the number of moles of all constituent fatty acids.
 構成脂肪酸には、炭素数8~14の直鎖脂肪酸、炭素数18~22の分岐脂肪酸及び炭素数18~22の不飽和脂肪酸のいずれかを含む事が好ましい。 The constituent fatty acid preferably contains any one of a linear fatty acid having 8 to 14 carbon atoms, a branched fatty acid having 18 to 22 carbon atoms, and an unsaturated fatty acid having 18 to 22 carbon atoms.
 構成脂肪酸として、(a)炭素数16~22の直鎖飽和脂肪酸を少なくとも1種以上、(b)炭素数8~14の直鎖飽和脂肪酸、炭素数18~22の分岐脂肪酸及び炭素数18~22の不飽和脂肪酸からなる群より選択される少なくとも1種以上が挙げられる。構成脂肪酸における脂肪酸(a)と脂肪酸(b)の比率をモル比にして、0.91:0.09~0.99:0.01とするとき、低添加量にて粘度が高く、長期間油脂の分離を抑えることができる。 As constituent fatty acids, (a) at least one type of linear saturated fatty acid having 16 to 22 carbon atoms, (b) linear saturated fatty acid having 8 to 14 carbon atoms, branched fatty acid having 18 to 22 carbon atoms, and 18 to 18 carbon atoms. At least one selected from the group consisting of 22 unsaturated fatty acids can be mentioned. When the ratio of the fatty acid (a) and the fatty acid (b) in the constituent fatty acids is 0.91: 0.09 to 0.99: 0.01 in terms of molar ratio, the viscosity is high with a low addition amount and the viscosity is high for a long period of time. Separation of fats and oils can be suppressed.
 脂肪酸(a)としては、パルミチン酸、ステアリン酸、アラキジン酸、ベヘン酸等が挙げられるが、これらに限定されるものではない。脂肪酸(b)としては、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、オレイン酸、エルカ酸、イソステアリン酸等が挙げられるが、これらに限定されるものではない。 Examples of the fatty acid (a) include, but are not limited to, palmitic acid, stearic acid, arachidic acid, behenic acid and the like. Examples of the fatty acid (b) include, but are not limited to, caprylic acid, capric acid, lauric acid, myristic acid, oleic acid, erucic acid, isostearic acid and the like.
 ポリグリセリン脂肪酸エステルを構成するポリグリセリンについては、水酸基価に基づく平均重合度が10以上のものを用いるのが好ましい。平均重合度が10未満であるポリグリセリンを用いた場合、十分な粘度は得られず、長期間油脂の分離を抑えることができない場合がある。より好ましくは、ポリグリセリンの平均重合度は20以上であり、さらに好ましくは30以上、よりさらに好ましくは40以上であり、平均重合度が高い程、粘度が高くなり、低添加量で固化を達成することができる。 As for the polyglycerin constituting the polyglycerin fatty acid ester, it is preferable to use one having an average degree of polymerization of 10 or more based on the hydroxyl value. When polyglycerin having an average degree of polymerization of less than 10 is used, sufficient viscosity cannot be obtained, and separation of fats and oils may not be suppressed for a long period of time. More preferably, the average degree of polymerization of polyglycerin is 20 or more, more preferably 30 or more, still more preferably 40 or more, and the higher the average degree of polymerization, the higher the viscosity and the solidification is achieved with a low addition amount. can do.
 ポリグリセリンの水酸基価に基づく平均重合度は、従来公知の手法(特開2018-42550号公報)にしたがって、末端基分析法、水酸基価は社団法人日本油化学会編「日本油化学会制定 基準油脂分析試験法(I)1996年度版」に準じて算出することができる。 The average degree of polymerization of polyglycerin based on the hydroxyl value is determined by the terminal group analysis method according to a conventionally known method (Japanese Patent Laid-Open No. 2018-42550), and the hydroxyl value is the standard established by the Japan Oil Chemists'Association, edited by the Japan Oil Chemists' Society. It can be calculated according to the "Fat and oil analysis test method (I) 1996 version".
 ポリグリセリン脂肪酸エステルのエステル化率は、70%以上であることが好ましい。エステル化率が70%未満である場合、十分な粘度は得られず、長期間油脂の分離を抑えることができない場合がある。より好ましくは、ポリグリセリン脂肪酸エステルのエステル化率は80%以上であり、さらに好ましくは90%以上であり、エステル化率が高い程、粘度が高くなり、低添加量で固化を達成することができる。 The esterification rate of the polyglycerin fatty acid ester is preferably 70% or more. If the esterification rate is less than 70%, sufficient viscosity may not be obtained and separation of fats and oils may not be suppressed for a long period of time. More preferably, the esterification rate of the polyglycerin fatty acid ester is 80% or more, further preferably 90% or more, and the higher the esterification rate, the higher the viscosity, and solidification can be achieved with a low addition amount. it can.
 エステル化率は、従来公知の手法(特開2018-42550号公報)にしたがって算出することができる。 The esterification rate can be calculated according to a conventionally known method (Japanese Unexamined Patent Publication No. 2018-42550).
 本発明においてポリグリセリン脂肪酸エステルは常法にしたがって製造されたものを用いることができ、より詳細には、上記の各成分を、上記条件を満たすような組成で仕込み、水酸化ナトリウム等の触媒を加えて、常圧又は減圧下におけるエステル化反応に付すことにより製造されたものを用いることができる。また、本発明においてポリグリセリン脂肪酸エステルは市販品を利用してもよく、例えば、TAISET AD(太陽化学株式会社)、TAISET50(太陽化学(株))、リョートーポリグリエステルB-100D(三菱化学フーズ(株))等を好適に用いることができる。 In the present invention, a polyglycerin fatty acid ester produced according to a conventional method can be used. More specifically, each of the above components is charged with a composition satisfying the above conditions, and a catalyst such as sodium hydroxide is used. In addition, those produced by subjecting to an esterification reaction under normal pressure or reduced pressure can be used. Further, in the present invention, a commercially available product may be used as the polyglycerin fatty acid ester, for example, TAISET AD (Taiyo Kagaku Co., Ltd.), TAISET50 (Taiyo Kagaku Co., Ltd.), Ryoto Polyglyceride B-100D (Mitsubishi Chemical Foods Co., Ltd.). Co., Ltd.) and the like can be preferably used.
 本発明の香辛料ペースト調味料組成物には、油系増粘剤を0質量%以上の任意の量で含めることができ、その量は製造された香辛料ペースト調味料組成物の粘度が下記所望の値となる範囲で適宜調整することができる。 The spice paste seasoning composition of the present invention may contain an oil-based thickener in an arbitrary amount of 0% by mass or more, and the amount thereof is desired so that the viscosity of the produced spice paste seasoning composition is as follows. It can be adjusted as appropriate within the range of values.
 本発明の香辛料ペースト調味料組成物が油系増粘剤を含む場合にはその量は例えば、0.1質量%以上、好ましくは0.5質量%以上、より好ましくは1質量%以上、さらに好ましくは2質量%以上であり、上限は特に限定されるものではないが、例えば、10質量%以下、7質量%以下、5質量%以下、又は3質量%以下とすることができる。例えば、本発明の香辛料ペースト調味料組成物には油系増粘剤を、0.1質量%~10質量%、より好ましくは0.5質量%~5質量%、より好ましくは1~3質量%の範囲より適宜選択される量で含めることができる。油系増粘剤が0.1量%よりも少ないと、油脂の粘度が十分でない場合があり、一方、10質量%よりも多いと、油脂の粘度が高くなり過ぎる場合があり、その結果、本発明の香辛料ペースト調味料組成物の分離安定性が低下し油浮き等を生じる場合、滑らかさや口どけ等の食感の低下を生じる場合、可撓性容器に充填された場合に当該容器からの絞り出しが困難となる場合がある。 When the spice paste seasoning composition of the present invention contains an oil-based thickener, the amount thereof is, for example, 0.1% by mass or more, preferably 0.5% by mass or more, more preferably 1% by mass or more, and further. It is preferably 2% by mass or more, and the upper limit is not particularly limited, but may be, for example, 10% by mass or less, 7% by mass or less, 5% by mass or less, or 3% by mass or less. For example, the spice paste seasoning composition of the present invention contains an oil-based thickener in an amount of 0.1% by mass to 10% by mass, more preferably 0.5% by mass to 5% by mass, and more preferably 1 to 3% by mass. It can be included in an amount appropriately selected from the range of%. If the amount of the oil-based thickener is less than 0.1% by weight, the viscosity of the fat and oil may not be sufficient, while if it is more than 10% by mass, the viscosity of the fat and oil may be too high, and as a result, the viscosity of the fat and oil may be too high. When the separation stability of the spice paste seasoning composition of the present invention is lowered to cause oil floating or the like, when the texture such as smoothness or melting in the mouth is deteriorated, or when the container is filled in a flexible container, the container is used. It may be difficult to squeeze out.
 本発明の香辛料ペースト調味料組成物に含まれる粗脂肪分の25℃における固体脂含有量(SFC)は0.5%超え、好ましくは0.6%以上であり、より好ましくは0.8%以上であり、その上限は特に限定されるものではないが、例えば、20%以下、15%以下、又は10%以下とすることができる。本発明の香辛料ペースト調味料組成物に含まれる粗脂肪分の前記SFCは例えば、0.6%~20%、好ましくは0.8%~20%、より好ましくは1%~10%である。前記SFCが0.5%以下である場合には、本発明の香辛料ペースト調味料組成物の安定性を低下させ油浮き等を生じる場合や、製造、輸送、又は、保存中に、配合した香辛料や下記に詳述する具材の沈殿や不均一な分散を生じる場合がある。一方、前記SFCが20%を超える場合には、本発明の香辛料ペースト調味料組成物の滑らかさや口どけ等の食感の低下を生じる場合や、可撓性容器に充填された場合に当該容器からの絞り出しが困難となる場合がある。なお、「粗脂肪分」とは、本発明に利用される油脂由来のもののみならず、香辛料や具材由来のもの、添加材由来のもの、その他の成分由来のもの等、香辛料ペースト調味料組成物全体に含まれる粗脂肪分を示すものである。 The solid fat content (SFC) of the crude fat content in the spice paste seasoning composition of the present invention at 25 ° C. is more than 0.5%, preferably 0.6% or more, more preferably 0.8%. As described above, the upper limit thereof is not particularly limited, but may be, for example, 20% or less, 15% or less, or 10% or less. The crude fat content of the SFC contained in the spice paste seasoning composition of the present invention is, for example, 0.6% to 20%, preferably 0.8% to 20%, and more preferably 1% to 10%. When the SFC is 0.5% or less, the spices blended when the stability of the spice paste seasoning composition of the present invention is lowered and oil floating or the like occurs, or during production, transportation, or storage. And may cause precipitation or non-uniform dispersion of the ingredients described in detail below. On the other hand, when the SFC exceeds 20%, the spice paste seasoning composition of the present invention has a deteriorated texture such as smoothness and melting in the mouth, or when it is filled in a flexible container, the container is concerned. It may be difficult to squeeze out from. The "crude fat content" is not limited to those derived from fats and oils used in the present invention, but also spice paste seasonings such as those derived from spices and ingredients, those derived from additives, and those derived from other ingredients. It indicates the crude fat content contained in the entire composition.
 ここで、香辛料ペースト調味料組成物に含まれる粗脂肪分の25℃における固体脂含有量(SFC)は、香辛料ペースト調味料組成物に含まれる粗脂肪分をソックスレー抽出法により抽出し、日本油化学会制定の基準油脂分析試験法(II)に記載されるNMR法(暫3-1983  暫定固体脂含量)に準じて測定することができる。 Here, the solid fat content (SFC) of the crude fat content contained in the spice paste seasoning composition at 25 ° C. is obtained by extracting the crude fat content contained in the spice paste seasoning composition by a socksley extraction method and using Japanese oil. It can be measured according to the NMR method (provisional 3-1983 provisional solid fat content) described in the standard fat analysis test method (II) established by the Chemical Society.
 日本油化学会制定の基準油脂分析試験法(II)に記載されるNMR法(暫3-1983  暫定固体脂含量)とは、具体的には、試料を90℃の恒温槽で加熱して均一にし、試験管(2mL)に詰めゴム栓をする。試料管に詰めた試料及び対照試料(局方オリーブ油)を60±0.2℃に30分間保持した後、それぞれの試料のNMRシグナルを読む。次いでこれらの試料を0±2℃に30分間保持した後、測定温度(T±0.2℃)に30分間保持して、それぞれのシグナルを読む。T℃におけるSFCは次の式により計算される。
 SFC(%)=100-A/B×C/D×100
 式中、Aは60℃における対照試料のNMRシグナルの読みであり、Bは60℃における測定試料のNMRシグナルの読みであり、CはT℃における測定試料のNMRシグナルの読みであり、DはT℃における対照試料のNMRシグナルの読みである。
The NMR method (provisional 3-1983 provisional solid fat content) described in the standard fat analysis test method (II) established by the Japan Oil Chemists' Society is specifically that the sample is heated in a constant temperature bath at 90 ° C. to be uniform. Then, fill a test tube (2 mL) with a rubber stopper. After holding the sample packed in the sample tube and the control sample (Japanese olive oil) at 60 ± 0.2 ° C. for 30 minutes, the NMR signal of each sample is read. These samples are then held at 0 ± 2 ° C. for 30 minutes and then at the measurement temperature (T ± 0.2 ° C.) for 30 minutes to read each signal. SFC at T ° C. is calculated by the following formula.
SFC (%) = 100-A / B x C / D x 100
In the formula, A is the reading of the NMR signal of the control sample at 60 ° C., B is the reading of the NMR signal of the measurement sample at 60 ° C., C is the reading of the NMR signal of the measurement sample at T ° C., and D is the reading of the NMR signal of the measurement sample at T ° C. It is a reading of the NMR signal of the control sample at T ° C.
 本発明の香辛料ペースト調味料組成物の粘度は、25℃及びせん断速度1(1/s)における値が2000mPa・s以上、好ましくは4000mPa・s以上、より好ましくは6000mPa・s以上、さらに好ましくは8000mPa・s以上であり、その上限は特に限定されるものではないが、例えば、1000Pa・s以下、980Pa・s以下、970Pa・s以下、又は960Pa・s以下とすることができる。前記条件における本発明の香辛料ペースト調味料組成物の粘度は、例えば、2000mPa・s~1000Pa・sであることが好ましく、1Pa・s~500Pa・sであることがより好ましく、10Pa・s~100Pa・sであることがさらに好ましい。油脂に一定の粘度を付与する事で、配合した香辛料や下記に詳述する具材の香りの後引きを増強すること、良好な食感を保持することができ、また、配合した香辛料や具材が製造、輸送、又は、保存中に沈殿や不均一な分散を生じにくく良好な分散性を有し、さらに、高い分離安定性を有する香辛料ペースト調味料組成物を提供することができる。一方、前記粘度が2000mPa・s未満である場合には、香辛料ペースト調味料組成物の分離安定性が乏しく、油浮き等を生じる場合がある。 The viscosity of the spice paste seasoning composition of the present invention has a value of 2000 mPa · s or more, preferably 4000 mPa · s or more, more preferably 6000 mPa · s or more, still more preferably 6000 mPa · s or more at 25 ° C. and a shear rate of 1 (1 / s). It is 8000 mPa · s or more, and the upper limit thereof is not particularly limited, but can be, for example, 1000 Pa · s or less, 980 Pa · s or less, 970 Pa · s or less, or 960 Pa · s or less. The viscosity of the spice paste seasoning composition of the present invention under the above conditions is, for example, preferably 2000 mPa · s to 1000 Pa · s, more preferably 1 Pa · s to 500 Pa · s, and 10 Pa · s to 100 Pa · s. -S is more preferable. By imparting a certain viscosity to the fat and oil, it is possible to enhance the aftertaste of the scent of the blended spices and the ingredients described in detail below, maintain a good texture, and the blended spices and ingredients. It is possible to provide a spice paste seasoning composition in which the material is less likely to cause precipitation or non-uniform dispersion during production, transportation, or storage, has good dispersibility, and has high separation stability. On the other hand, when the viscosity is less than 2000 mPa · s, the separation stability of the spice paste seasoning composition is poor, and oil floating or the like may occur.
 前記粘度は、1mm以上の粒子を取り除いたサンプルを回転式粘弾性測定装置(例えば、HAAKE社製RheoStress 6000)を用い、直径35mmパラレルプレート、25℃にて、ずり速度0.1s-1から31s-1までの間を低ずり速度側から測定することにより測定することができる。 For the viscosity, a sample from which particles of 1 mm or more were removed was subjected to a rotary viscoelasticity measuring device (for example, RheoStress 6000 manufactured by HAAKE), a parallel plate having a diameter of 35 mm, a shear rate of 0.1 s- 1 to 31 s at 25 ° C. It can be measured by measuring from the low shear rate side up to -1.
 本発明の香辛料ペースト調味料組成物の粘度は、油脂、特に固形油脂、ショートニング、極度硬化油脂、及び油系増粘剤より選択される一又は複数(二以上)の配合によって調整してもよい。 The viscosity of the spice paste seasoning composition of the present invention may be adjusted by blending one or more (two or more) selected from fats and oils, particularly solid fats and oils, shortenings, extremely hardened fats and oils, and oil-based thickeners. ..
 本発明の香辛料ペースト調味料組成物には、本発明の香辛料ペースト調味料組成物の所望の特性が妨げられない範囲で、水を0質量%以上かつ10質量%未満の量で加えることができる。 To the spice paste seasoning composition of the present invention, water can be added in an amount of 0% by mass or more and less than 10% by mass as long as the desired properties of the spice paste seasoning composition of the present invention are not impaired. ..
 例えば、本発明において、水を0質量%以上かつ10質量%未満の量で含むことができる。水を10質量%以上の量で含む場合には、製造された香辛料ペースト調味料組成物について、所望の粘度を得ることができない場合があり、滑らかさや口どけ等の食感の低下や風味の低下を生じる場合があり、また油脂の分離を抑えることができず組成物の分離安定性が低下する場合があり、さらに保存性が低下する場合がある。例えば、本発明において水を、0質量%以上10質量%未満、すなわち、0質量%以上8質量%以下、0質量%以上5質量%以下、0質量%以上3質量%以下、0質量%以上2質量%以下、0質量%以上1質量%以下、又は0質量%以上0.5質量%以下の量で加えてもよい。これらの水には、香辛料ペースト調味料組成物の製造において直接加えられる水だけでなく、香辛料ペースト調味料組成物を製造するための一又は複数の原材料の調製過程において当該原材料に混入した水に起因するものが含まれる。 For example, in the present invention, water can be contained in an amount of 0% by mass or more and less than 10% by mass. When water is contained in an amount of 10% by mass or more, the desired viscosity of the produced spice paste seasoning composition may not be obtained, resulting in a decrease in texture such as smoothness and melting in the mouth and flavor. It may cause a decrease, the separation of fats and oils may not be suppressed, the separation stability of the composition may decrease, and the storage stability may further decrease. For example, in the present invention, water is used in an amount of 0% by mass or more and less than 10% by mass, that is, 0% by mass or more and 8% by mass or less, 0% by mass or more and 5% by mass or less, 0% by mass or more and 3% by mass or less, 0% by mass or more. It may be added in an amount of 2% by mass or less, 0% by mass or more and 1% by mass or less, or 0% by mass or more and 0.5% by mass or less. These waters include not only the water directly added in the production of the spice paste seasoning composition, but also the water mixed in the raw materials in the process of preparing one or more raw materials for producing the spice paste seasoning composition. Causes are included.
 本発明の香辛料ペースト調味料組成物にはさらに、当該組成物を加熱することなくそのまま食した際に、当該組成物に食感を付与することが可能な具材を含めることができる。 The spice paste seasoning composition of the present invention can further include an ingredient capable of imparting a texture to the composition when the composition is eaten as it is without heating.
 本発明において「具材」とは、本発明の香辛料ペースト調味料組成物に配合され、当該組成物を加熱することなくそのまま食した際に、「カリカリ」、「サクサク」、「パリパリ」、「バリバリ」、「ボリボリ」、「ポリポリ」、又は「ジャリジャリ」等(これらに限定されない)とした食感を付与することが可能な食材や香辛料を意味し、特に、脆性破壊を想起させるような歯ごたえ/歯ざわりを有する食材や香辛料が好ましい。本発明において利用可能な具材としては、本発明の組成物中に配合される前の破断強度解析における荷重微分値が、下記測定方法で求めた場合に、変形率50%以下での荷重を微分した値の最小値が-2N/%未満、好ましくは-5N/%未満、より好ましくは-10N/%未満であり、その変形率から2%以内での荷重を微分した値の最大値が0N/%以上となる具材が挙げられる。ここで、測定方法としては、まず、クリープメータにおいて直径3mmのプランジャーを用い、格納ピッチ0.01秒、測定速度0.1mm/秒での破断強度解析を実施する。任意の測定点の変形率がx%、応力がyN、次の測定点の変形率X%、応力YNのとき、(Y―y)/(X―x)(連続した測定点の荷重の差(N)を変形率の差(%)で除した値)を微分した値(N/%)として算出する。クリープメータは上記測定方法を実施することができる限り、任意のクリープメータを用いることができるが、例えば下記実施例においても利用される株式会社山電製RE2-3305Bを好適に用いることができる(これに限定はされない)。用いる具材の破断強度解析における荷重微分値が、前記範囲に含まれない場合、本発明の香辛料ペースト調味料組成物を食した際に、具材の良好な食感が得られない場合がある。さらに、具材の良好な食感を得られない場合、香辛料ペースト調味料組成物の食感や具材等の風味の複雑さを得ることが出来ず、油脂のべたつきを強く感じてしまい、非加熱で喫食し得る適切な風味を得られない。本発明において利用可能な具材としては、例えば、ケシの実、胡麻、オニオンチップ、ガーリックチップ、パフ、グラノーラ、おかき、揚げ玉、おこげ、パン粉、クルトン、クミン、粒マスタード、胡椒、甲殻類(エビ、カニ等)、食用昆虫類、乾燥野菜、乾燥肉、乾燥海産物、乾燥果物、コーングリッツ等の食材や香辛料が挙げられるが、これらに限定はされない。具材は上記の破断強度解析における荷重微分値を有する限り、任意の大きさで用いることが可能であり、用いる具材の大きさに応じて、そのまま又は粉砕物の形態で用いることができる。例えば、本発明において、具材は粒径がおよそ0.5~20mm、好ましくはおよそ1~10mmの範囲内の大きさとすることができる。具材の大きさがが、0.5mmよりも小さいと具材の良好な食感が得られない場合があり、20mmよりも大きいと本発明の組成物の滑らかさが得られない場合がある。 In the present invention, the "ingredient" is blended with the spice paste seasoning composition of the present invention, and when the composition is eaten as it is without heating, it is "crispy", "crispy", "crispy", "crispy", " It means ingredients and spices that can give a texture such as "crunchy", "crunchy", "polypoly", or "jarigari" (not limited to these), and in particular, it has a chewy texture reminiscent of brittle fracture. / Ingredients and spices with a texture are preferable. As an ingredient that can be used in the present invention, a load having a deformation rate of 50% or less when the load differential value in the breaking strength analysis before being blended in the composition of the present invention is determined by the following measuring method. The minimum value of the differentiated value is less than -2N /%, preferably less than -5N /%, more preferably less than -10N /%, and the maximum value obtained by differentiating the load within 2% from the deformation rate is Ingredients having a value of 0 N /% or more can be mentioned. Here, as a measurement method, first, a plunger having a diameter of 3 mm is used in a creep meter, and a rupture strength analysis is performed at a storage pitch of 0.01 seconds and a measurement speed of 0.1 mm / sec. When the deformation rate of an arbitrary measurement point is x%, the stress is yN, the deformation rate of the next measurement point is X%, and the stress is YN, (Y-y) / (X-x) (difference in load between consecutive measurement points) (N) divided by the difference in deformation rate (%)) is calculated as the differentiated value (N /%). As the creep meter, any creep meter can be used as long as the above measurement method can be carried out, and for example, RE2-3305B manufactured by Sanyo Electric Railway Co., Ltd., which is also used in the following examples, can be preferably used ( Not limited to this). If the load derivative value in the breaking strength analysis of the ingredient to be used is not included in the above range, a good texture of the ingredient may not be obtained when the spice paste seasoning composition of the present invention is eaten. .. Furthermore, if a good texture of the ingredients cannot be obtained, the texture of the spice paste seasoning composition and the complexity of the flavor of the ingredients cannot be obtained, and the stickiness of the fats and oils is strongly felt. It is not possible to obtain an appropriate flavor that can be eaten by heating. Ingredients that can be used in the present invention include, for example, poppy seeds, sesame seeds, onion chips, garlic chips, puffs, granola, okaki, fried balls, sardines, bread flour, croutons, cumin, grain mustard, pepper, and shellfish (shrimp). , Crabs, etc.), edible insects, dried vegetables, dried meat, dried seafood, dried fruits, corn glitz and other foodstuffs and spices, but are not limited to these. The ingredient can be used in any size as long as it has the load derivative value in the above-mentioned breaking strength analysis, and can be used as it is or in the form of a pulverized product depending on the size of the ingredient used. For example, in the present invention, the ingredients may have a particle size in the range of about 0.5 to 20 mm, preferably about 1 to 10 mm. If the size of the ingredient is smaller than 0.5 mm, a good texture of the ingredient may not be obtained, and if it is larger than 20 mm, the smoothness of the composition of the present invention may not be obtained. ..
 本発明の香辛料ペースト調味料組成物には、具材を任意の量で含めることができ、その量は用いる具材に応じて適宜設定することができる。例えば、本発明の香辛料ペースト調味料組成物には、具材が1質量%以上、2質量%以上、又は3質量%以上の量で含まれ、その上限は特に限定されるものではないが、例えば、70質量%以下、60質量%以下、50質量%以下、40質量%以下、又は35質量%以下とすることができる。本発明の香辛料ペースト調味料組成物には具材を、例えば1質量%以上70質量%以下、好ましくは2質量%以上60質量%以下、より好ましくは3質量%以上50質量%以下(例えば、3質量%以上40質量%以下、3質量%以上35質量%以下等)の範囲より適宜選択される量で含めることができる。具材の含有量が、1質量%よりも少ないと具材の良好な食感が得られない場合があり、70質量%よりも多いと本発明の組成物の滑らかさが得られない場合がある。 The spice paste seasoning composition of the present invention may contain an arbitrary amount of ingredients, and the amount can be appropriately set according to the ingredients to be used. For example, the spice paste seasoning composition of the present invention contains the ingredients in an amount of 1% by mass or more, 2% by mass or more, or 3% by mass or more, and the upper limit thereof is not particularly limited. For example, it can be 70% by mass or less, 60% by mass or less, 50% by mass or less, 40% by mass or less, or 35% by mass or less. The spice paste seasoning composition of the present invention contains ingredients, for example, 1% by mass or more and 70% by mass or less, preferably 2% by mass or more and 60% by mass or less, and more preferably 3% by mass or more and 50% by mass or less (for example). It can be included in an amount appropriately selected from the range of 3% by mass or more and 40% by mass or less, 3% by mass or more and 35% by mass or less, etc.). If the content of the ingredient is less than 1% by mass, a good texture of the ingredient may not be obtained, and if it is more than 70% by mass, the smoothness of the composition of the present invention may not be obtained. is there.
 本発明の香辛料ペースト調味料組成物には、必要に応じて、上記成分に加えてさらに、飲食品の製造において通常用いられている、賦形剤、滑沢剤、結合剤、崩壊剤等の添加剤を含めることができる。 In addition to the above-mentioned components, the spice paste seasoning composition of the present invention further contains excipients, lubricants, binders, disintegrants, etc., which are usually used in the production of foods and drinks. Additives can be included.
 賦形剤としては、例えば、乳糖、白糖、D-マンニトール、D-ソルビトール、デンプン、α化デンプン、デキストリン、ブドウ糖、コーンスターチ、結晶セルロース、低置換度ヒドロキシプロピルセルロース、カルボキシメチルセルロースナトリウム、アラビアゴム、プルラン、軽質無水ケイ酸、合成ケイ酸アルミニウム、メタケイ酸アルミン酸マグネシウム等が挙げられる。 Excipients include, for example, lactose, sucrose, D-mannitol, D-sorbitol, starch, pregelatinized starch, dextrin, glucose, corn starch, crystalline cellulose, low-substituted hydroxypropyl cellulose, sodium carboxymethyl cellulose, gum arabic, pullulan. , Light anhydrous silicate, synthetic aluminum silicate, magnesium aluminometasilicate and the like.
 滑沢剤としては、例えば、ショ糖脂肪酸エステル等のシュガーエステル類、ステアリン酸カルシウム、ステアリン酸マグネシウム、ステアリン酸、ステアリルアルコール、サラシミツロウ等のロウ類、タルク、ケイ酸、ケイ素等が挙げられる。 Examples of the lubricant include sugar esters such as sucrose fatty acid esters, waxes such as calcium stearate, magnesium stearate, stearic acid, stearyl alcohol, and beeswax, talc, silicic acid, and silicon.
 結合剤としては、例えば、α化デンプン、ショ糖、ゼラチン、アラビアゴム、メチルセルロース、カルボキシメチルセルロース、カルボキシメチルセルロースナトリウム、結晶セルロース、白糖、D-マンニトール、トレハロース、デキストリン、プルラン、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、ポリビニルピロリドン等が挙げられる。 Examples of the binder include pregelatinized starch, sucrose, gelatin, gum arabic, methyl cellulose, carboxymethyl cellulose, sodium carboxymethyl cellulose, crystalline cellulose, sucrose, D-mannitol, trehalose, dextrin, pullulan, hydroxypropyl cellulose, and hydroxypropyl methyl cellulose. , Polyvinylpyrrolidone and the like.
 崩壊剤としては、例えば、乳糖、白糖、デンプン、カルボキシメチルセルロース、カルボキシメチルセルロースカルシウム、クロスカルメロースナトリウム、カルボキシメチルスターチナトリウム、軽質無水ケイ酸、低置換度ヒドロキシプロピルセルロース等が挙げられる。 Examples of the disintegrant include lactose, sucrose, starch, carboxymethyl cellulose, carboxymethyl cellulose calcium, croscarmellose sodium, carboxymethyl starch sodium, light anhydrous silicic acid, and low-degree-of-substitution hydroxypropyl cellulose.
 また、本発明の香辛料ペースト調味料組成物には、必要に応じてさらに、飲食品の製造において通常用いられている、アミノ酸(例えばグルタミン、システイン、ロイシン、アルギニン等)、多価アルコール(例えばエチレングリコール、ポリエチレングリコール、プロピレングリコール、グリセリン、糖アルコール等)、天然高分子(例えば、レシチン、澱粉、デキストリン等)、ビタミン(例えばビタミンC、ビタミンB群等)、ミネラル(例えばカルシウム、マグネシウム、亜鉛、鉄等)、食物繊維(例えばマンナン、ペクチン、ヘミセルロース等)、界面活性剤(例えばソルビタン脂肪酸エステル等)、希釈剤、安定化剤、等張化剤、pH調製剤、緩衝剤、湿潤剤、溶解補助剤、懸濁化剤、着色剤、矯味剤、矯臭剤、香料、酸化防止剤、甘味料、呈味成分、酸味料等を適宜含めることができる。 Further, in the spicy starch seasoning composition of the present invention, if necessary, amino acids (for example, glutamine, cysteine, lecithin, arginine, etc.) and polyhydric alcohols (for example, ethylene), which are usually used in the production of foods and drinks, are further added. Glycol, polyethylene glycol, propylene glycol, glycerin, sugar alcohol, etc.), natural polymers (eg, lecithin, starch, dextrin, etc.), vitamins (eg, vitamin C, vitamin B group, etc.), minerals (eg, calcium, magnesium, zinc, etc.) Iron, etc.), dietary fiber (eg, mannan, pectin, hemicellulose, etc.), surfactant (eg, sorbitan fatty acid ester, etc.), diluent, stabilizer, isotonic agent, pH adjuster, buffer, wetting agent, dissolution Auxiliary agents, suspending agents, coloring agents, flavoring agents, flavoring agents, fragrances, antioxidants, sweeteners, taste components, acidulants and the like can be appropriately included.
 一態様において、本発明は、1質量%以上70質量%以下の香辛料、30質量%以上99質量%以下の油脂であって該油脂に含まれる固形油脂は0質量%超50質量%未満である油脂、及び、0質量%以上かつ10質量%未満の水を60℃達温以上で加熱、混合すること、ならびに製造される香辛料ペースト調味料組成物の粗脂肪分のSFCが25℃で0.5%超となるように調整することを含む、香辛料ペースト調味料組成物の製造方法を提供する。なお、本発明において、「1質量%以上70質量%以下の香辛料、30質量%以上99質量%以下の油脂であって該油脂に含まれる固形油脂は0質量%超50質量%未満である油脂、及び、0質量%以上かつ10質量%未満の水を60℃達温以上で加熱、混合すること」、ならびに、「製造される香辛料ペースト調味料組成物の粗脂肪分のSFCが25℃で0.5%超となるように調整すること」とはこの順序で記載されることがあるが、これはこれらの工程がこの順序で行われることを意味するものではない。また、「製造される香辛料ペースト調味料組成物の粗脂肪分のSFCが25℃で0.5%超となるように調整すること」について、この調整は、製造される香辛料ペースト調味料組成物の粗脂肪分の固体脂含有量(SFC)を所定の値にする油脂等の量が一度決定されれば、本発明の製造方法を実施する際に毎回行われる必要はなく、当該SFCを達成可能な決定された配合で、香辛料、及び、油脂、ならびに必要に応じて水やその他の成分を混合すればよい。 In one aspect, the present invention is a spice of 1% by mass or more and 70% by mass or less, and a fat or oil of 30% by mass or more and 99% by mass or less, and the solid fat or oil contained in the fat or oil is more than 0% by mass and less than 50% by mass. Oil and fat and water of 0% by mass or more and less than 10% by mass are heated and mixed at a temperature of 60 ° C. or higher, and the SFC of the crude fat content of the spice paste seasoning composition produced is 0. Provided is a method for producing a spice paste seasoning composition, which comprises adjusting the amount to more than 5%. In the present invention, "a spice of 1% by mass or more and 70% by mass or less, and a fat or oil of 30% by mass or more and 99% by mass or less, and the solid fat or oil contained in the fat or oil is more than 0% by mass and less than 50% by mass". And, "heating and mixing 0% by mass or more and less than 10% by mass of water at a temperature of 60 ° C. or higher" and "the SFC of the crude fat content of the spicy paste seasoning composition produced is 25 ° C. "Adjusting to more than 0.5%" may be described in this order, but this does not mean that these steps are performed in this order. In addition, regarding "adjusting the SFC of the crude fat content of the produced spice paste seasoning composition to exceed 0.5% at 25 ° C.", this adjustment is made for the produced spice paste seasoning composition. Once the amount of fats and oils, etc. that set the solid fat content (SFC) of the crude fat content to a predetermined value is determined, it is not necessary to carry out each time when the production method of the present invention is carried out, and the SFC is achieved. Spices and fats and oils, and optionally water and other ingredients, may be mixed in the determined formulation possible.
 また、一態様において本発明の香辛料ペースト調味料組成物は、1質量%以上70質量%以下の香辛料、30質量%以上99質量%以下の油脂であって該油脂に含まれる固形油脂は0質量%超50質量%未満である油脂、0質量%以上かつ10質量%未満の水、及び0.1質量%以上69質量%以下の水溶性粉体原料を混合すること、粗脂肪分のSFCが25℃で0.5%を超え、25℃及びせん断速度1(1/s)における粘度が2000mPa・s~1000Pa・sとすること、を含む方法により製造することができる。なお、本明細書中において、「1質量%以上70質量%以下の香辛料、30質量%以上99質量%以下の油脂であって該油脂に含まれる固形油脂は0質量%超50質量%未満である油脂、0質量%以上かつ10質量%未満の水、及び0.1質量%以上69質量%以下の水溶性粉体原料を混合すること」、及び「香辛料ペースト調味料組成物の粗脂肪分のSFCが25℃で0.5%を超とすること」とはこの順序で記載されることがあるが、これはこれらの工程がこの順序で行われることを意味するものではない。また、「粗脂肪分のSFCが25℃で0.5%を超え、25℃及びせん断速度1(1/s)における粘度が2000mPa・s~1000Pa・sとすること」について、この調整は、製造される香辛料ペースト調味料組成物の粗脂肪分の固体脂含有量(SFC)を所定の値にする油脂等の量、また、製造される香辛料ペースト調味料組成物の粘度を所定の値にする油脂や油系増粘剤等の量が一度決定されれば、本発明の製造方法を実施する際に毎回行われる必要はなく、当該SFC及び粘度を達成可能な決定された配合で、香辛料、油脂、及び、水溶性粉体原料、ならびに必要に応じて水や上記のその他の成分を混合すればよい。 Further, in one embodiment, the spice paste seasoning composition of the present invention is 1% by mass or more and 70% by mass or less of spices, and 30% by mass or more and 99% by mass or less of fats and oils, and the solid fats and oils contained in the fats and oils are 0% by mass. Mixing fats and oils of more than% by mass and less than 50% by mass, water of 0% by mass or more and less than 10% by mass, and water-soluble powder raw materials of 0.1% by mass or more and 69% by mass or less, SFC of crude fat content It can be produced by a method including exceeding 0.5% at 25 ° C. and having a viscosity at 25 ° C. and a shear rate of 1 (1 / s) of 2000 mPa · s to 1000 Pa · s. In the present specification, "1% by mass or more and 70% by mass or less of spices, 30% by mass or more and 99% by mass or less of fats and oils, and the solid fats and oils contained in the fats and oils are more than 0% by mass and less than 50% by mass. Mixing certain fats and oils, water of 0% by mass or more and less than 10% by mass, and water-soluble powder raw material of 0.1% by mass or more and 69% by mass or less ", and" crude fat content of spice paste seasoning composition "SFC greater than 0.5% at 25 ° C." may be described in this order, but this does not mean that these steps are performed in this order. Further, regarding "the SFC of the crude fat content exceeds 0.5% at 25 ° C., and the viscosity at 25 ° C. and a shear rate of 1 (1 / s) is 2000 mPa · s to 1000 Pa · s", this adjustment is made. The amount of oils and fats that make the solid fat content (SFC) of the crude fat content of the produced spicy paste seasoning composition a predetermined value, and the viscosity of the produced spicy paste seasoning composition to a predetermined value. Once the amount of fats and oils, oil-based thickener, etc. to be used is determined, it is not necessary to carry out each time when the production method of the present invention is carried out, and the spices have a determined composition capable of achieving the SFC and viscosity. , Oils and fats, and water-soluble powder raw materials, and if necessary, water and other components described above may be mixed.
 本発明の香辛料ペースト調味料組成物は、香辛料、及び油脂、ならびに必要に応じて、水溶性粉体原料、油系増粘剤、水、及び上記のその他の成分を、それぞれ上記の量で、加熱条件下にて混合した後、室温又は冷蔵下で冷却することによって製造することができる。各成分は全て一緒に加えて混合してもよいし、各成分を別々にもしくは任意の組み合わせで順次加えて(順序は問わない)混合してもよい。成分の混合は、加熱の前、加熱の最中、及び加熱した後の一つ以上にて行うことができる。加熱の温度は、60℃達温以上、例えば、60℃を超える、65℃以上、70℃以上、75℃以上、80℃以上、85℃以上、90℃以上、95℃以上、100℃以上、105℃以上、110℃以上、115℃以上又は120℃以上の達温まで加熱する。「達温」とは、組成物自体の温度を意味する。加熱の温度の上限は特に限定されないが、160℃達温以下、好ましくは140℃達温以下とすることができる。60℃達温以上まで加熱することによって、製造される香辛料ペースト調味料組成物に香辛料の良好な風味を付与することができ、より好ましくは90℃以上の達温まで、さらに好ましくは100℃以上の達温まで加熱することによって、カラメル化やメイラード反応等が起こり調理感が増して風味を増すことができ、香辛料のより良好な風味を付与することができる。60℃達温未満又は160℃達温を超える加熱によっては、香辛料の風味が十分に感じられない場合や、加熱によって焦げを生じ苦み等の異味が感じられる場合がある。ただし、例えばショートニングを用いる場合には、ショートニングは加熱後、組成物を常温(5℃~35℃)まで冷却した後に加えて混合する。ショートニングを、常温を超える温度に加熱した場合、油脂の結晶が溶解してしまい、再度冷却した場合に加熱前とは異なる粗大な結晶を生じる場合があり、これが製造される香辛料ペースト調味料組成物の食感をぼそぼそと滑らかでないものに低下させる場合がある。 The spice paste seasoning composition of the present invention contains spices, oils and fats, and, if necessary, a water-soluble powder raw material, an oil-based thickener, water, and the above other components in the above amounts, respectively. It can be produced by mixing under heating conditions and then cooling at room temperature or in a refrigerator. All the components may be added together and mixed, or the components may be added separately or sequentially in any combination (in any order) and mixed. The components can be mixed at one or more before, during, and after heating. The heating temperature is 60 ° C. or higher, for example, 60 ° C. or higher, 65 ° C. or higher, 70 ° C. or higher, 75 ° C. or higher, 80 ° C. or higher, 85 ° C. or higher, 90 ° C. or higher, 95 ° C. or higher, 100 ° C. or higher. Heat to a temperature of 105 ° C. or higher, 110 ° C. or higher, 115 ° C. or higher, or 120 ° C. or higher. "Temperature" means the temperature of the composition itself. The upper limit of the heating temperature is not particularly limited, but can be 160 ° C. or lower, preferably 140 ° C. or lower. By heating to a temperature of 60 ° C. or higher, a good flavor of the spice can be imparted to the produced spice paste seasoning composition, more preferably to a temperature of 90 ° C. or higher, still more preferably 100 ° C. or higher. By heating to the temperature reached, caramelization, Maillard reaction, etc. occur, the cooking feeling is increased, the flavor can be increased, and a better flavor of spices can be imparted. Depending on the heating below 60 ° C. or above 160 ° C., the spice flavor may not be sufficiently felt, or the heating may cause charring and a bitter taste or the like. However, when shortening is used, for example, the shortening is heated, the composition is cooled to room temperature (5 ° C. to 35 ° C.), and then added and mixed. When shortening is heated to a temperature exceeding room temperature, the crystals of fats and oils may dissolve, and when it is cooled again, coarse crystals different from those before heating may be produced. May reduce the texture of the paste to something that is not smooth.
 加熱は所定の達温まで達した後、その温度で0~15分、好ましくは0~10分、さらに好ましくは0~5分保持することができる。加熱の終了後、組成物を室温又は冷蔵下で冷却する。 After reaching a predetermined temperature, heating can be maintained at that temperature for 0 to 15 minutes, preferably 0 to 10 minutes, and more preferably 0 to 5 minutes. After the heating is complete, the composition is cooled at room temperature or in a refrigerator.
 本発明の香辛料ペースト調味料組成物は容器に充填された形態で提供することができる。容器の形態は特に限定されないが、パウチ、缶、瓶、チューブ、ボトル等の形状とすることができる。容器の大きさは特に限定されないが、例えば、10~500mL(典型的には10mL、15mL、20mL、30mL、40mL、50mL、95mL、100mL、150mL、200mL、250mL、300mL、350mL、400mL、450mL又は500mL)の大きさとすることができる。容器は可撓性容器であることが好ましい。「可撓性容器」とは、力を加えて変形させることができ、かつその力を抜くと元の形状に戻ることが可能な変形容易かつ保形性のある容器を意味し、具体的にはチューブ及びプラスチックボトル等の柔軟性のある容器が挙げられる。可撓性容器に香辛料ペースト調味料組成物を充填することによって、当該容器を指で押すことによって香辛料ペースト調味料組成物を絞り出すことができ使い勝手良い。容器への充填は、組成物を室温又は冷蔵下で冷却する工程の前に行っても良いし、あるいは当該工程の後に行ってもよい。 The spice paste seasoning composition of the present invention can be provided in a container-filled form. The form of the container is not particularly limited, but may be a pouch, a can, a bottle, a tube, a bottle, or the like. The size of the container is not particularly limited, but for example, 10 to 500 mL (typically 10 mL, 15 mL, 20 mL, 30 mL, 40 mL, 50 mL, 95 mL, 100 mL, 150 mL, 200 mL, 250 mL, 300 mL, 350 mL, 400 mL, 450 mL or It can be as large as 500 mL). The container is preferably a flexible container. The "flexible container" means a container that can be deformed by applying a force and can return to its original shape when the force is released, and is specifically deformable and has a shape-retaining property. Examples include flexible containers such as tubes and plastic bottles. By filling the flexible container with the spice paste seasoning composition, the spice paste seasoning composition can be squeezed out by pressing the container with a finger, which is convenient. The filling of the container may be performed before the step of cooling the composition at room temperature or in a refrigerator, or may be performed after the step.
 以下、本発明を実施例により、更に詳しく説明する。 Hereinafter, the present invention will be described in more detail by way of examples.
[実験1]
1-1.香辛料ペースト調味料組成物の調製
 下記表1の組成にしたがって、各成分を混合し80℃達温まで加熱混合し、次いで5℃まで冷却混合して各香辛料ペースト調味料組成物を製造した。油系増粘剤はポリグリセリン脂肪酸エステル(製品名:TAISET AD(太陽化学株式会社))を使用した。粘度は25℃でのせん断速度1(1/s)にて測定した値を示す。得られた組成物を以下の実験に用いた。なお、表中の各成分の量は質量比にて示し、各実験の結果も併記する。
[Experiment 1]
1-1. Preparation of Spice Paste Seasoning Composition According to the composition shown in Table 1 below, each component was mixed, heated and mixed to a temperature of 80 ° C., and then cooled and mixed to 5 ° C. to produce each spice paste seasoning composition. As the oil-based thickener, polyglycerin fatty acid ester (product name: TAISET AD (Taiyo Kagaku Co., Ltd.)) was used. Viscosity indicates a value measured at a shear rate of 1 (1 / s) at 25 ° C. The obtained composition was used in the following experiments. The amount of each component in the table is shown by mass ratio, and the results of each experiment are also shown.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
1-2.分離安定性の評価
 実施例及び比較例の香辛料ペースト調味料組成物をそれぞれ、50mLのファルコンチューブに40g充填し、表面を平らにし、40℃で2週間保管した。その後、各組成物について、表層の分離した液体油脂の量を観察し、その幅が25mm未満の場合に「〇」、25mm以上の場合に「×」と評価した。
1-2. Evaluation of Separation Stability 40 g of each of the spice paste seasoning compositions of Examples and Comparative Examples was filled in a 50 mL falcon tube, the surface was flattened, and the mixture was stored at 40 ° C. for 2 weeks. Then, for each composition, the amount of the separated liquid fats and oils on the surface layer was observed, and when the width was less than 25 mm, it was evaluated as "◯", and when the width was 25 mm or more, it was evaluated as "x".
1-3.口どけの評価
 専門パネラー4人が実施例及び比較例の香辛料ペースト調味料組成物をそれぞれ食し、各組成物について口どけを◎(とても口どけが良い)、○(口どけが良い)、△(口どけが良いとは言えない)×(口どけが良くなく、製品には不適)で評価した。
1-3. Evaluation of melting in the mouth Four specialized panelists ate the spice paste seasoning compositions of the examples and comparative examples, and each composition was melted in the mouth ◎ (very good in the mouth), ○ (good in the mouth), △ (It cannot be said that the mouthfeel is good) × (The mouthfeel is not good and it is not suitable for the product).
1-4.スパイス感の評価
 専門パネラー4人が実施例及び比較例の香辛料ペースト調味料組成物をそれぞれ食し、各組成物について香辛料の風味を◎(スパイス感が強い)、○(スパイス感がある)、△(スパイス感はあるが十分ではない)、×(スパイス感が弱い)で評価した。
1-4. Evaluation of spice feeling Four specialized panelists ate the spice paste seasoning compositions of the examples and comparative examples, and each composition had a spice flavor of ◎ (strong spice feeling), ○ (has a spice feeling), △ (Spicy but not enough), × (weak spice).
1-5.結果
 固形油脂を含まず、香辛料ペースト調味料組成物の25℃における粗脂肪分のSFCが0.5%である場合には(比較例1)、保管後、表層に液状油脂の分離が認められ、分離安定性が乏しいことが確認された。
 一方、固形油脂を含み、当該SFCが0.5%超である香辛料ペースト調味料組成物においては(実施例1~11)、保管後に液体油脂の分離は認められず、高い分離安定性を有することが確認された。この結果は、香辛料ペースト調味料組成物の分離安定性に、粗脂肪分のSFCが影響を与えることを示す。
1-5. Results When the spice paste seasoning composition does not contain solid fats and oils and the SFC of the crude fat content at 25 ° C. is 0.5% (Comparative Example 1), separation of liquid fats and oils is observed on the surface layer after storage. , It was confirmed that the separation stability was poor.
On the other hand, in the spice paste seasoning composition containing solid fats and oils and having an SFC of more than 0.5% (Examples 1 to 11), separation of liquid fats and oils is not observed after storage, and the spice paste seasoning composition has high separation stability. It was confirmed that. This result indicates that the crude fat content SFC affects the separation stability of the spice paste seasoning composition.
1-6.水溶性粉体原料による効果の評価
 下記表の組成にしたがって、各成分を混合し80℃達温まで加熱混合し、次いで5℃まで氷水で冷却混合して各香辛料ペースト調味料組成物を製造した。表2において、油系増粘剤はポリグリセリン脂肪酸エステル(製品名:TAISET AD(太陽化学株式会社))を使用した。なお、表中の各成分の量は質量比にて示す。
 得られた各香辛料ペースト調味料組成物について、上記と同様に、口どけについて評価した。各実験の結果も下記表に併記する。
1-6. Evaluation of the effect of the water-soluble powder raw material According to the composition in the table below, each component was mixed, heated and mixed to a temperature of 80 ° C., and then cooled and mixed with ice water to 5 ° C. to produce each spice paste seasoning composition. .. In Table 2, a polyglycerin fatty acid ester (product name: TAISET AD (Taiyo Kagaku Co., Ltd.)) was used as the oil-based thickener. The amount of each component in the table is shown by mass ratio.
Each of the obtained spice paste seasoning compositions was evaluated for melting in the mouth in the same manner as described above. The results of each experiment are also shown in the table below.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
1-7.結果
 香辛料ペースト調味料組成物に水溶性粉体原料を加えることによって、油っぽさを感じさせない、良好な口どけが得られることが確認された。
 また、口どけの効果に関し、食塩、グルタミン酸ソーダ、及びブドウ糖で有意な差は認められなかったが、食塩を加えた場合には特に良好なスパイス感が得られた。
 これらの効果は、油系増粘剤の使用の有無に関わらず確認された。
1-7. Results It was confirmed that by adding the water-soluble powder raw material to the spice paste seasoning composition, a good melting in the mouth without feeling oily was obtained.
In addition, regarding the effect of melting in the mouth, no significant difference was observed between salt, monosodium glutamate, and glucose, but a particularly good spice feeling was obtained when salt was added.
These effects were confirmed with or without the use of oil-based thickeners.
 以上の結果より、1質量%以上70質量%以下の香辛料、30質量%以上99質量%以下の油脂であって該油脂に含まれる固形油脂は0質量%超50質量%未満である油脂、0質量%以上かつ10質量%未満の水、及び0.1質量%以上69質量%以下の水溶性粉体原料を含み、粗脂肪分のSFCが25℃で0.5%を超える、香辛料ペースト調味料組成物は、分離安定性が高く、かつ良好な口どけ及びスパイス感を有することが明らかとなった。 From the above results, spices of 1% by mass or more and 70% by mass or less, fats and oils of 30% by mass or more and 99% by mass or less, and solid fats and oils contained in the fats and oils are more than 0% by mass and less than 50% by mass, 0 Spice paste seasoning containing water of 0.1% by mass or more and less than 10% by mass and water-soluble powder raw material of 0.1% by mass or more and 69% by mass or less, and SFC of crude fat content exceeds 0.5% at 25 ° C. It was clarified that the material composition had high separation stability and had a good melting in the mouth and a spicy feeling.
[実験2]
2-1.香辛料ペースト調味料組成物の調製
 下記表4-1、表4-2の組成にしたがって、特例塩とグルタミン酸ナトリウム以外の各成分を混合し80℃達温まで加熱混合した後、氷水で55℃まで冷却混合した。次いで、特例塩とグルタミン酸ナトリウムを加えて混合した後、氷水で5℃まで冷却混合して各香辛料ペースト調味料組成物を製造した。実施例52については、ショートニング、特例塩、グルタミン酸ナトリウム以外の各成分を混合し80℃達温まで加熱混合した後、組成物を常温まで冷却した後にショートニングを加えて混合し、その後、特例塩とグルタミン酸ナトリウムを上記と同様に混合した。油系増粘剤はポリグリセリン脂肪酸エステル(製品名:TAISET AD(太陽化学株式会社))を使用した。粘度は25℃でのせん断速度1(1/s)にて測定した値を示す。得られた組成物を以下の実験に用いた。なお、胡椒、胡麻は、クリープメータ(株式会社山電製RE2-3305B)において直径3mmのプランジャーを用い、格納ピッチ0.01秒、測定速度0.1mm/秒での破断強度解析を実施した。任意の測定点の変形率がx%、応力がyN、次の測定点の変形率X%、応力YNのとき、(Y―y)/(X―x)(連続した測定点の荷重の差(N)を変形率の差(%)で除した値)を微分した値(N/%)として算出した。変形率50%以下での荷重を微分した値の最小値、及びその変形率から2%以内での荷重を微分した値の最大値はそれぞれ以下のとおりであった:胡椒(-106.6N/%及び1.3N/%)、胡麻(-5.16N/%及び0N/%)。また、各嵩比重を測定したところ、胡椒は56g/100mL、けしの実は60g/100mL、胡麻は51g/100mL、特例塩は10.6g/100mLであった。表中の各成分の量は質量比にて示す。
[Experiment 2]
2-1. Preparation of spice paste seasoning composition According to the composition of Table 4-1 and Table 4-2 below, each component other than the special salt and monosodium glutamate is mixed, heated to 80 ° C, and then heated to 55 ° C with ice water. Cooled and mixed. Next, a special salt and monosodium glutamate were added and mixed, and then cooled and mixed with ice water to 5 ° C. to produce each spice paste seasoning composition. In Example 52, components other than shortening, special salt, and monosodium glutamate were mixed, heated and mixed to a temperature of 80 ° C., cooled to room temperature, shortened and mixed, and then mixed with the special salt. Monosodium glutamate was mixed in the same manner as above. As the oil-based thickener, polyglycerin fatty acid ester (product name: TAISET AD (Taiyo Kagaku Co., Ltd.)) was used. Viscosity indicates a value measured at a shear rate of 1 (1 / s) at 25 ° C. The obtained composition was used in the following experiments. For pepper and sesame, a creep meter (RE2-3305B manufactured by Yamaden Co., Ltd.) was used to analyze the breaking strength at a storage pitch of 0.01 seconds and a measurement speed of 0.1 mm / sec using a plunger with a diameter of 3 mm. .. When the deformation rate of an arbitrary measurement point is x%, the stress is yN, the deformation rate of the next measurement point is X%, and the stress is YN, (Y-y) / (X-x) (difference in load between consecutive measurement points) (N) divided by the difference in deformation rate (%)) was calculated as a differentiated value (N /%). The minimum value obtained by differentiating the load at a deformation rate of 50% or less and the maximum value obtained by differentiating the load within 2% from the deformation rate were as follows: pepper (-106.6 N /). % And 1.3N /%), sesame (-5.16N /% and 0N /%). Moreover, when each bulk specific gravity was measured, pepper was 56 g / 100 mL, poppy seed was 60 g / 100 mL, sesame was 51 g / 100 mL, and special salt was 10.6 g / 100 mL. The amount of each component in the table is shown by mass ratio.
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000005
2-2.分離安定性の評価
 実施例及び比較例の香辛料ペースト調味料組成物をそれぞれ、50mLのファルコンチューブに40g充填し、表面を平らにし、40℃で2週間保管した。その後、各組成物について、表層の分離した液体油脂の量を観察し、その幅が25mm未満の場合に「〇」、25mm以上の場合に「×」と評価した。
2-2. Evaluation of Separation Stability 40 g of each of the spice paste seasoning compositions of Examples and Comparative Examples was filled in a 50 mL falcon tube, the surface was flattened, and the mixture was stored at 40 ° C. for 2 weeks. Then, for each composition, the amount of the separated liquid fats and oils on the surface layer was observed, and when the width was less than 25 mm, it was evaluated as "◯", and when the width was 25 mm or more, it was evaluated as "x".
2-3.製造適正の評価
 実施例及び比較例の香辛料ペースト調味料組成物をそれぞれ、50mLのファルコンチューブに40g充填し、25℃で12時間保管した。その後、各組成物について具材の分散の程度を観察し、表層の分離した液体油脂の量を観察し、その幅が40mm未満の場合に「〇」、その幅が40mm以上の場合に「×」と評価した。
2-3. Evaluation of Production Suitability 40 g of each of the spice paste seasoning compositions of Examples and Comparative Examples was filled in a 50 mL falcon tube and stored at 25 ° C. for 12 hours. After that, observe the degree of dispersion of the ingredients for each composition, observe the amount of liquid fats and oils separated on the surface layer, "○" when the width is less than 40 mm, and "×" when the width is 40 mm or more. I evaluated it.
2-4.スパイス感の評価
 専門パネラー4人が実施例及び比較例の香辛料ペースト調味料組成物をそれぞれ食し、各組成物について具材の風味を○(スパイス感が強い)×(スパイス感が弱い)で評価した。
2-4. Evaluation of spice feeling Four specialized panelists ate the spice paste seasoning compositions of Examples and Comparative Examples, and evaluated the flavor of the ingredients for each composition as ○ (strong spice feeling) × (weak spice feeling). did.
2-5.具材の食感の評価(カリカリ感の官能評価)
 専門パネラー4人が実施例及び比較例の香辛料ペースト調味料組成物をそれぞれ食し、各組成物について具材の食感を○(カリカリ感が強い)、×(カリカリ感が弱い)で評価した。
2-5. Evaluation of texture of ingredients (sensory evaluation of crispness)
Four specialized panelists ate the spice paste seasoning compositions of Examples and Comparative Examples, respectively, and the texture of the ingredients was evaluated as ○ (strong crunchy) and × (weak crunchy) for each composition.
2-6.口どけの評価
 専門パネラー4人が実施例及び比較例の香辛料ペースト調味料組成物をそれぞれし、各組成物について口どけを◎(とても口どけが良い)、○(口どけが良い)、△(口どけが良いとは言えない)×(口どけが良くなく、製品には不適)で評価した。
2-6. Evaluation of mouthfeel Four specialized panelists made spice paste seasoning compositions of Examples and Comparative Examples, and each composition was given a mouthfeel ◎ (very good mouthfeel), ○ (good mouthfeel), △ (It cannot be said that the mouthfeel is good) × (The mouthfeel is not good and it is not suitable for the product).
2-7.コクの評価
 専門パネラー4人が実施例及び比較例の香辛料ペースト調味料組成物をそれぞれし、各組成物についてコクを○(コクがある)、△(コクがないとは言えない)×(コクがなく、製品には不適)で評価した。
2-7. Evaluation of richness Four specialized panelists made the spice paste seasoning compositions of the examples and comparative examples, and each composition was marked with ○ (richness), △ (it cannot be said that there is no richness) × (richness). It is not suitable for the product).
2-8.結果
 実施例及び比較例の香辛料ペースト調味料組成物の各評価結果を下記表5-1、表5-2に示す。
2-8. Results Each evaluation result of the spice paste seasoning composition of Examples and Comparative Examples is shown in Tables 5-1 and 5-2 below.
 香辛料ペースト調味料組成物の25℃における粗脂肪分のSFCが0.5%であり、25℃及びせん断速度1(1/s)における粘度が1776mPa・sである場合には(比較例4)、保管後、表層に液状油脂の分離が認められ、分離安定性が乏しいことが確認された。 When the SFC of the crude fat content of the spice paste seasoning composition at 25 ° C. is 0.5% and the viscosity at 25 ° C. and a shear rate of 1 (1 / s) is 1776 mPa · s (Comparative Example 4). After storage, separation of liquid fats and oils was observed on the surface layer, and it was confirmed that the separation stability was poor.
 香辛料ペースト調味料組成物の25℃における粗脂肪分のSFCが0%であり、25℃及びせん断速度1(1/s)における粘度が配合成分の沈殿により測定不能である場合には(比較例5)、表層に液状油脂の分離が認められ分離安定性が乏しいこと、及び、製造直後より具材の沈殿、不均一な分散等が認められ製造適正が乏しいことが確認された。また、香りや味の持続性がなく、コクが感じられなかった。 When the SFC of the crude fat content at 25 ° C. of the spice paste seasoning composition is 0% and the viscosity at 25 ° C. and a shear rate of 1 (1 / s) cannot be measured due to the precipitation of the compounding components (Comparative Example). 5) It was confirmed that the separation of liquid fats and oils was observed on the surface layer and the separation stability was poor, and that the ingredients were precipitated and unevenly dispersed immediately after production, and the production suitability was poor. In addition, the aroma and taste did not last long, and the richness was not felt.
 水を10質量%含む場合には(比較例6及び7)、具材の食感が乏しいことが確認された。 When 10% by mass of water was contained (Comparative Examples 6 and 7), it was confirmed that the texture of the ingredients was poor.
 極度硬化油脂を比較的多く含む場合(油脂中に20.59質量%、20.83質量%)には(比較例8,9)、口どけが乏しいことが確認された。 When a relatively large amount of extremely hardened fat and oil was contained (20.59% by mass and 20.83% by mass in the fat and oil) (Comparative Examples 8 and 9), it was confirmed that the mouthfeel was poor.
 一方、油脂中に19質量%以下の量の極度硬化油脂を含み、水を含まず、上記SFCが0.5%超であり、上記粘度が2000mPa・s以上である香辛料ペースト調味料組成物において(実施例36~47)、各種保管後に液体油脂の分離は認められず、高い分離安定性と、具材の沈殿や不均一な分散が認められず、良好な製造適正を有することが確認された。また、いずれの組成物についても、具材の良好な食感、香りや味の持続性があり、コクが感じられた。 On the other hand, in a spice paste seasoning composition containing 19% by mass or less of extremely hardened fat and oil, containing no water, having an SFC of more than 0.5%, and having a viscosity of 2000 mPa · s or more. (Examples 36 to 47), separation of liquid fats and oils was not observed after various storages, high separation stability, precipitation of ingredients and non-uniform dispersion were not observed, and it was confirmed that the product had good manufacturing suitability. It was. In addition, all the compositions had a good texture, aroma and taste persistence of the ingredients, and a richness was felt.
Figure JPOXMLDOC01-appb-T000006
Figure JPOXMLDOC01-appb-T000006
Figure JPOXMLDOC01-appb-T000007
Figure JPOXMLDOC01-appb-T000007
 以上の結果より、上記所定の条件下にてクリープメータを用いて、変形率50%以下での荷重を微分した値の最小値が-2N/%未満であり、その変形率から2%以内に荷重を微分した値の最大値が0N/%以上となる具材を1質量%以上;30質量%以上の油脂であって、該油脂に含まれる固形油脂は0質量%以上である、及び/又は該油脂に含まれる極度硬化油脂は0質量%以上19質量%以下である油脂;ならびに、0質量%以上10質量%未満の水、を含み、粗脂肪分のSFCが25℃で0.5%を超え、かつ25℃及びせん断速度1(1/s)における粘度が2000mPa・s以上である香辛料ペースト調味料組成物は、加熱することなくそのまま食した場合に、配合した具材の良好な食感(例えば、カリカリ感等)を感じることができ、また、配合した具材が製造、輸送、又は、保存中に沈殿や不均一な分散を生じにくく良好な分散性を有し、さらに、高い分離安定性を有することが明らかとなった。 From the above results, the minimum value obtained by differentiating the load at a deformation rate of 50% or less using a creep meter under the above-mentioned predetermined conditions is less than -2N /%, and within 2% of the deformation rate. 1% by mass or more of the ingredients having the maximum value obtained by differentiating the load is 0 N /% or more; 30% by mass or more of the fat and oil, and the solid fat and oil contained in the fat and oil is 0% by mass or more, and / Alternatively, the extremely hardened fat and oil contained in the fat and oil contains 0% by mass or more and 19% by mass or less of fat and oil; and 0% by mass or more and less than 10% by mass of water, and the crude fat content SFC is 0.5 at 25 ° C. The spicy paste seasoning composition having a viscosity of more than% and a viscosity of 2000 mPa · s or more at 25 ° C. and a shear rate of 1 (1 / s) is good as a blended ingredient when eaten as it is without heating. You can feel the texture (for example, crunchy feeling), and the blended ingredients are less likely to cause precipitation or non-uniform dispersion during production, transportation, or storage, and have good dispersibility. It was revealed that it has high separation stability.
[実験3]
3-1.香辛料ペースト調味料組成物の調製
 下記表6の組成にしたがって、各成分を混合し80℃達温まで加熱混合し、次いで5℃まで冷却混合して各香辛料ペースト調味料組成物を製造した。油系増粘剤はポリグリセリン脂肪酸エステル(製品名:TAISET AD(太陽化学株式会社))を使用した。粘度は25℃でのせん断速度1(1/s)にて測定した値を示す。得られた組成物を以下の実験に用いた。なお、表中の各成分の量は質量比にて示し、各実験の結果も併記する。
[Experiment 3]
3-1. Preparation of Spice Paste Seasoning Composition According to the composition shown in Table 6 below, each component was mixed, heated and mixed to a temperature of 80 ° C., and then cooled and mixed to 5 ° C. to produce each spice paste seasoning composition. As the oil-based thickener, polyglycerin fatty acid ester (product name: TAISET AD (Taiyo Kagaku Co., Ltd.)) was used. Viscosity indicates a value measured at a shear rate of 1 (1 / s) at 25 ° C. The obtained composition was used in the following experiments. The amount of each component in the table is shown by mass ratio, and the results of each experiment are also shown.
Figure JPOXMLDOC01-appb-T000008
Figure JPOXMLDOC01-appb-T000008
3-2.分離安定性の評価
 実施例及び比較例の香辛料ペースト調味料組成物をそれぞれ、50mLのファルコンチューブに40g充填し、表面を平らにし、40℃で2週間保管した。その後、各組成物について、表層に分離した液状油脂の量を観察し、その幅が25mm未満の場合に「〇」、25mm以上の場合に「×」と評価した。
3-2. Evaluation of Separation Stability 40 g of each of the spice paste seasoning compositions of Examples and Comparative Examples was filled in a 50 mL falcon tube, the surface was flattened, and the mixture was stored at 40 ° C. for 2 weeks. Then, for each composition, the amount of liquid fats and oils separated on the surface layer was observed, and when the width was less than 25 mm, it was evaluated as "◯", and when the width was 25 mm or more, it was evaluated as "x".
3-3.絞り出し性の評価
 実施例及び比較例の香辛料ペースト調味料組成物をそれぞれ、可撓性のチューブ容器(95mL、口径8mm)に充填し、4℃で一週間保管した。その後、専門パネラーが指でチューブから各組成物を絞り出し、その出しやすさを、◎(とても絞り出しやすい)、○(絞り出しやすい)、△(絞れるが力が必要、又は少し液漏れしてしまう)、×(絞り出しにくい、又は液漏れしてしまう)で評価した。
3-3. Evaluation of Squeezeability The spice paste seasoning compositions of Examples and Comparative Examples were each filled in a flexible tube container (95 mL, diameter 8 mm) and stored at 4 ° C. for one week. After that, a specialized panelist squeezes each composition from the tube with a finger, and the ease of squeezing out is ◎ (very easy to squeeze out), ○ (easy to squeeze out), △ (squeeze but force is required, or a little liquid leaks) , X (difficult to squeeze out or leak).
3-4.口どけの評価
 専門パネラー4人が実施例及び比較例の香辛料ペースト調味料組成物をそれぞれ食し、各組成物について口どけを◎(とても口どけが良い)、○(口どけが良い)、△(口どけが良いとは言えない)×(口どけが良くなく、製品には不適)で評価した。
3-4. Evaluation of melting in the mouth Four specialized panelists ate the spice paste seasoning compositions of the examples and comparative examples, and each composition was melted in the mouth ◎ (very good in the mouth), ○ (good in the mouth), △ (It cannot be said that the mouthfeel is good) × (The mouthfeel is not good and it is not suitable for the product).
3-5.スパイス感の評価
 専門パネラー4人が実施例及び比較例の香辛料ペースト調味料組成物をそれぞれ食し、各組成物について香辛料の風味を◎(スパイス感が強い)、○(スパイス感がある)、△(スパイス感はあるが十分ではない)、×(スパイス感が弱い)で評価した。
3-5. Evaluation of spice feeling Four specialized panelists ate the spice paste seasoning compositions of the examples and comparative examples, and each composition had a spice flavor of ◎ (strong spice feeling), ○ (has a spice feeling), △ (Spicy but not enough), × (weak spice).
3-6.結果
 固形油脂を含まず、粗脂肪分のSFC(25℃)が0.5%である比較例10の香辛料ペースト調味料組成物においては、保管後、表層に液状油脂の分離が認められ、分離安定性が乏しいことが確認された。また、当該比較例10の組成物については、充填された可撓性チューブ容器からの絞り出し(取り出し)が容易ではなく、滑らかさが不十分であると共に、上記液状油脂の分離により液漏れが認められた。
 一方、固形油脂を含み、粗脂肪分のSFC(25℃)が0.5%を超える実施例53~63の香辛料ペースト調味料組成物においては、保管後、表層に液状油脂の分離が認められず、高い分離安定性を有することが確認された。また、当該実施例53~63の組成物については、充填された可撓性チューブ容器からの絞り出しを可能とする十分な滑らかさが認められた。
3-6. Results In the spice paste seasoning composition of Comparative Example 10 which does not contain solid fats and oils and has a crude fat content of SFC (25 ° C.) of 0.5%, separation of liquid fats and oils was observed on the surface layer after storage, and separation was observed. It was confirmed that the stability was poor. Further, with respect to the composition of Comparative Example 10, it is not easy to squeeze (take out) from the filled flexible tube container, the smoothness is insufficient, and liquid leakage is observed due to the separation of the liquid fats and oils. Was done.
On the other hand, in the spice paste seasoning compositions of Examples 53 to 63 containing solid fats and oils and having a crude fat content of SFC (25 ° C.) exceeding 0.5%, separation of liquid fats and oils was observed on the surface layer after storage. However, it was confirmed that it had high separation stability. In addition, the compositions of Examples 53 to 63 were found to be sufficiently smooth to allow squeezing from the filled flexible tube container.
 以上の結果より、香辛料、油脂、油系増粘剤を含み、水を0質量%以上かつ10質量%未満の量で含み、前記油脂に含まれる固形油脂は0質量%超50質量%未満の量であり、粗脂肪分のSFCが25℃で0.5%を超える、香辛料ペースト調味料組成物は、分離安定性が高く、かつ良好な口どけ及びスパイス感を有することが明らかとなった。また、当該組成物は可撓性容器に充填した場合に指で絞り出すことが容易であり、使い勝手がよく扱いやすいことが確認された。 From the above results, it contains spices, fats and oils, and oil-based thickeners, contains water in an amount of 0% by mass or more and less than 10% by mass, and the solid fats and oils contained in the fats and oils are more than 0% by mass and less than 50% by mass. It was revealed that the spice paste seasoning composition having a crude fat content of SFC exceeding 0.5% at 25 ° C. had high separation stability and had a good melting and spicy feeling. .. It was also confirmed that the composition is easy to squeeze out with a finger when filled in a flexible container, and is easy to use and handle.
[実験4]
4-1.香辛料ペースト調味料組成物の調製
 下記表7-1,7-2の組成にしたがって、各成分を混合し80℃達温まで加熱混合し、次いで5℃まで冷却混合して各香辛料ペースト調味料組成物を製造した。油系増粘剤はポリグリセリン脂肪酸エステル(製品名:TAISET AD(太陽化学株式会社))を使用した。粘度は25℃でのせん断速度1(1/s)にて測定した値を示す。得られた組成物を以下の実験に用いた。なお、表中の各成分の量は質量比にて示し、各実験の結果も併記する。
[Experiment 4]
4-1. Preparation of spice paste seasoning composition According to the composition of Tables 7-1 and 7-2 below, each component is mixed, heated and mixed to a temperature of 80 ° C., and then cooled and mixed to 5 ° C. to prepare each spice paste seasoning composition. Manufactured a thing. As the oil-based thickener, polyglycerin fatty acid ester (product name: TAISET AD (Taiyo Kagaku Co., Ltd.)) was used. Viscosity indicates a value measured at a shear rate of 1 (1 / s) at 25 ° C. The obtained composition was used in the following experiments. The amount of each component in the table is shown by mass ratio, and the results of each experiment are also shown.
Figure JPOXMLDOC01-appb-T000009
Figure JPOXMLDOC01-appb-T000009
Figure JPOXMLDOC01-appb-T000010
Figure JPOXMLDOC01-appb-T000010
4-2.分離安定性の評価
 実施例及び比較例の香辛料ペースト調味料組成物をそれぞれ、50mLのファルコンチューブに40g充填し、表面を平らにし、40℃で2週間保管した。その後、各組成物について、表層の分離した液状油脂の量を観察し、その幅が25mm未満の場合に「〇」、25mm以上の場合に「×」と評価した。
4-2. Evaluation of Separation Stability 40 g of each of the spice paste seasoning compositions of Examples and Comparative Examples was filled in a 50 mL falcon tube, the surface was flattened, and the mixture was stored at 40 ° C. for 2 weeks. Then, for each composition, the amount of the separated liquid fats and oils on the surface layer was observed, and when the width was less than 25 mm, it was evaluated as "◯", and when the width was 25 mm or more, it was evaluated as "x".
4-3.口どけの評価
 専門パネラー4人が実施例及び比較例の香辛料ペースト調味料組成物をそれぞれ食し、各組成物について口どけを◎(とても口どけが良い)、○(口どけが良い)、△(口どけが良いとは言えない)×(口どけが良くなく、製品には不適)で評価した。
4-3. Evaluation of melting in the mouth Four specialized panelists ate the spice paste seasoning compositions of the examples and comparative examples, and each composition was melted in the mouth ◎ (very good in the mouth), ○ (good in the mouth), △ (It cannot be said that the mouthfeel is good) × (The mouthfeel is not good and it is not suitable for the product).
4-4.スパイス感の評価
 専門パネラー4人が実施例及び比較例の香辛料ペースト調味料組成物をそれぞれ食し、各組成物について香辛料の風味を◎(スパイス感が強い)、○(スパイス感がある)、△(スパイス感はあるが十分ではない)、×(スパイス感が弱い)で評価した。
4-4. Evaluation of spice feeling Four specialized panelists ate the spice paste seasoning compositions of the examples and comparative examples, and each composition had a spice flavor of ◎ (strong spice feeling), ○ (has a spice feeling), △ (Spicy but not enough), × (weak spice).
4-5.結果
 固形油脂を含まず、香辛料ペースト調味料組成物の25℃における粗脂肪分のSFCが0.5%である場合には(比較例11)、保管後、表層に液状油脂の分離が認められ、分離安定性が乏しいことが確認された。
 一方、固形油脂を含み、当該SFCが0.5%超である香辛料ペースト調味料組成物においては(実施例64~77)、保管後に液状油脂の分離は認められず、高い分離安定性を有することが確認された。この結果は、香辛料ペースト調味料組成物の分離安定性に、粗脂肪分のSFCが影響を与えることを示す。
4-5. Results When the SFC of the crude fat content at 25 ° C. of the spice paste seasoning composition does not contain solid fats and oils is 0.5% (Comparative Example 11), separation of liquid fats and oils is observed on the surface layer after storage. , It was confirmed that the separation stability was poor.
On the other hand, in the spice paste seasoning composition containing solid fats and oils and having an SFC of more than 0.5% (Examples 64 to 77), separation of liquid fats and oils is not observed after storage, and the spice paste seasoning composition has high separation stability. It was confirmed that. This result indicates that the crude fat content SFC affects the separation stability of the spice paste seasoning composition.
4-6.加熱温度によるスパイス感への影響
 下記表8の組成にしたがって各成分を混合し、加熱なし、あるいは60℃、80℃、100℃、120℃、140℃、又は160℃達温まで加熱混合し、次いで5℃まで冷却混合して各香辛料ペースト調味料組成物を製造した。油系増粘剤はポリグリセリン脂肪酸エステル(製品名:TAISET AD(太陽化学株式会社))を使用した。なお、表中の各成分の量は質量比にて示す。
4-6. Effect of heating temperature on spice feeling Mix each component according to the composition shown in Table 8 below, and heat and mix without heating or until the temperature reaches 60 ° C, 80 ° C, 100 ° C, 120 ° C, 140 ° C, or 160 ° C. Then, each spice paste seasoning composition was produced by cooling and mixing to 5 ° C. As the oil-based thickener, polyglycerin fatty acid ester (product name: TAISET AD (Taiyo Kagaku Co., Ltd.)) was used. The amount of each component in the table is shown by mass ratio.
Figure JPOXMLDOC01-appb-T000011
Figure JPOXMLDOC01-appb-T000011
 専門パネラー4人が製造された香辛料ペースト調味料組成物をそれぞれ食し、各組成物について各香辛料の風味について、◎(スパイス感が強い)、○(スパイス感がある)、△(スパイス感はあるが十分ではない)、×(スパイス感が弱い)で評価した。 Each of the four specialized panelists ate the spice paste seasoning composition, and for each composition, the flavor of each spice was ◎ (strong spice), ○ (spicy), △ (spicy). Is not enough), × (weak spice feeling).
 結果を下記表9に示す。香辛料ペースト調味料組成物の製造において、加熱せず得られた組成物についてはいずれの香辛料についても、良好な香辛料の風味が感じられなかった。一方、60℃~80℃達温で加熱して得られた組成物については、加熱せず得られた組成物と異なり良好な香りが感じられた。さらに、100℃~140℃達温で加熱して得られた組成物については、調理感がつき風味が増して特に良好な香りが感じられた。 The results are shown in Table 9 below. In the production of the spice paste seasoning composition, no good spice flavor was felt for any of the spices obtained without heating. On the other hand, the composition obtained by heating at a temperature of 60 ° C. to 80 ° C. had a good scent unlike the composition obtained without heating. Further, the composition obtained by heating at a temperature of 100 ° C. to 140 ° C. was cooked, the flavor was increased, and a particularly good aroma was felt.
 特に、香辛料がコショウである場合、60℃達温で加熱することによって、コショウの埃っぽさが少なくなりクリアな香りを付与することができ、100℃達温で加熱することによって、コショウの埃っぽさがなくなり、調理香を付与することができた。一方、160℃達温で加熱して得られた組成物については、焦げ臭が感じられた。また、香辛料がトウガラシである場合、60℃達温で加熱することによって、青臭い香りが少し弱まり、トウガラシの甘い香りを付与することができ、100℃を超える達温まで加熱することによって、重甘い焙煎香を付与することができた。さらに、香辛料がオニオンである場合、60℃達温で加熱することによって、生っぽい香りは弱くすることができ、80℃達温で加熱することによって、調理感のある香りを付与することができ、100℃達温で加熱することによって、香ばしい焙煎香を付与することができた。 In particular, when the spice is pepper, heating at a temperature of 60 ° C. reduces the dustiness of the pepper and gives a clear scent. By heating at a temperature of 100 ° C., the pepper is heated. The dustiness disappeared and the cooking aroma could be added. On the other hand, a burning odor was felt in the composition obtained by heating at a temperature of 160 ° C. When the spice is red pepper, heating at a temperature of 60 ° C. slightly weakens the green scent, and the sweet scent of red pepper can be imparted. By heating to a temperature exceeding 100 ° C., the spice is heavy and sweet. The roasted aroma could be added. Furthermore, when the spice is onion, the raw aroma can be weakened by heating at a temperature of 60 ° C, and a scent with a cooking feeling can be imparted by heating at a temperature of 80 ° C. It was possible to impart a fragrant roasted aroma by heating at a temperature of 100 ° C.
Figure JPOXMLDOC01-appb-T000012
Figure JPOXMLDOC01-appb-T000012
 以上の結果より、香辛料、及び油脂を含み、その25℃における粗脂肪分のSFCが0.5%とする香辛料ペースト調味料組成物の製造において、60℃達温以上で加熱、混合することによって、分離安定性が高く、口どけもよく、かつ香辛料の良好な風味とコクを有する香辛料ペースト調味料組成物が得られることが確認された。

 
From the above results, in the production of a spice paste seasoning composition containing spices and fats and oils and having a crude fat content of 0.5% at 25 ° C., by heating and mixing at a temperature of 60 ° C. or higher. It was confirmed that a spice paste seasoning composition having high separation stability, good melting in the mouth, and good flavor and richness of spices can be obtained.

Claims (12)

  1.  1質量%以上70質量%以下の香辛料、30質量%以上99質量%以下の油脂であって該油脂に含まれる固形油脂は0質量%超50質量%未満である油脂、0質量%以上かつ10質量%未満の水、及び0.1質量%以上69質量%以下の水溶性粉体原料を含み、粗脂肪分のSFCが25℃で0.5%を超え、25℃及びせん断速度1(1/s)における粘度が2000mPa・s~1000Pa・sである、香辛料ペースト調味料組成物。 1% by mass or more and 70% by mass or less of spices, 30% by mass or more and 99% by mass or less of fats and oils, and the solid fats and oils contained in the fats and oils are 0% by mass or more and less than 50% by mass, 0% by mass or more and 10 It contains less than mass% water and a water-soluble powder raw material of 0.1% by mass or more and 69% by mass or less, and the SFC of the crude fat content exceeds 0.5% at 25 ° C., 25 ° C. and a shear rate of 1 (1). A spice paste seasoning composition having a viscosity at / s) of 2000 mPa · s to 1000 Pa · s.
  2.  前記油脂中に含まれる極度硬化油脂は0質量%以上19質量%以下の量である、請求項1に記載の組成物。 The composition according to claim 1, wherein the amount of the extremely hardened fat and oil contained in the fat and oil is 0% by mass or more and 19% by mass or less.
  3.  さらに油系増粘剤を含む、請求項1又は2に記載の組成物。 The composition according to claim 1 or 2, further comprising an oil-based thickener.
  4.  油系増粘剤がポリグリセリン脂肪酸エステルである、請求項3に記載の組成物。 The composition according to claim 3, wherein the oil-based thickener is a polyglycerin fatty acid ester.
  5.  水溶性粉体原料が食塩、水溶性デキストリン、グルタミン酸ソーダ、ブドウ糖、グラニュー糖、上白糖、クエン酸、造粒塩、岩塩、イノシン酸、グアニル酸からなる群から選択される1又は2以上の粉体原料である、請求項1~4のいずれか一項に記載の組成物。 Water-soluble powder One or more powders selected from the group consisting of salt, water-soluble dextrin, monosodium glutamate, glucose, granulated sugar, white sugar, citric acid, granulated salt, rock salt, inosinic acid, and guanylic acid. The composition according to any one of claims 1 to 4, which is a body raw material.
  6.  香辛料がコショウ、ゴマ、トウガラシ、ニンニク、オニオン、山椒、花椒、生姜からなる群から選択される1又は2以上の香辛料である、請求項1~5のいずれか一項に記載の組成物。 The composition according to any one of claims 1 to 5, wherein the spice is one or more spices selected from the group consisting of pepper, sesame, pepper, garlic, onion, Japanese pepper, Chinese pepper, and ginger.
  7.  1質量%以上70質量%以下の香辛料、30質量%以上99質量%以下の油脂であって該油脂に含まれる固形油脂は0質量%超50質量%未満である油脂、0質量%以上かつ10質量%未満の水、及び0.1質量%以上69質量%以下の水溶性粉体原料を混合すること、香辛料ペースト調味料組成物の粗脂肪分のSFCが25℃で0.5%を超とし、さらに25℃及びせん断速度1(1/s)における粘度が2000mPa・s~1000Pa・sとすること、
    を含む、香辛料ペースト調味料組成物の製造方法。
    1% by mass or more and 70% by mass or less of spices, 30% by mass or more and 99% by mass or less of fats and oils, and the solid fats and oils contained in the fats and oils are 0% by mass or more and less than 50% by mass, 0% by mass or more and 10 Mixing less than mass% of water and water-soluble powder raw material of 0.1% by mass or more and 69% by mass or less, SFC of crude fat content of spice paste seasoning composition exceeds 0.5% at 25 ° C. Further, the viscosity at 25 ° C. and a shear rate of 1 (1 / s) shall be 2000 mPa · s to 1000 Pa · s.
    A method for producing a spice paste seasoning composition, which comprises.
  8.  前記油脂中に含まれる極度硬化油脂は0質量%以上19質量%以下の量である、請求項7に記載の製造方法。 The production method according to claim 7, wherein the amount of the extremely hardened fat and oil contained in the fat and oil is 0% by mass or more and 19% by mass or less.
  9.  さらに油系増粘剤を混合すること、を含む、請求項7又は8に記載の製造方法。 The production method according to claim 7 or 8, further comprising mixing an oil-based thickener.
  10.  油系増粘剤がポリグリセリン脂肪酸エステルである、請求項7~9のいずれか一項に記載の製造方法。 The production method according to any one of claims 7 to 9, wherein the oil-based thickener is a polyglycerin fatty acid ester.
  11.  水溶性粉体原料が食塩、水溶性デキストリン、グルタミン酸ソーダ、ブドウ糖、グラニュー糖、上白糖、クエン酸、造粒塩、岩塩、イノシン酸、グアニル酸からなる群から選択される1又は2以上の粉体原料である、請求項7~10のいずれか一項に記載の製造方法。 Water-soluble powder One or more powders selected from the group consisting of salt, water-soluble dextrin, monosodium glutamate, glucose, granulated sugar, white sugar, citric acid, granulated salt, rock salt, inosinic acid, and guanylic acid. The production method according to any one of claims 7 to 10, which is a body raw material.
  12.  香辛料がコショウ、ゴマ、トウガラシ、ニンニク、オニオン、山椒、花椒、生姜からなる群から選択される1又は2以上の香辛料である、請求項7~11のいずれか一項に記載の製造方法。

     
    The production method according to any one of claims 7 to 11, wherein the spice is one or more spices selected from the group consisting of pepper, sesame, pepper, garlic, onion, Japanese pepper, Chinese pepper, and ginger.

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JPH11290016A (en) * 1998-04-13 1999-10-26 Ajinomoto Co Inc Semi-pasty seasoning composition
JP2000069931A (en) * 1998-08-28 2000-03-07 Ajinomoto Co Inc Novel half kenaded seasoning
JP2014030381A (en) * 2012-08-03 2014-02-20 S & B Foods Inc Semi-kneaded tubed seasoning
JP2016123319A (en) * 2014-12-26 2016-07-11 ヱスビー食品株式会社 Viscous food seasoning composition, and method for producing viscous food using the same
JP2019110927A (en) * 2019-04-22 2019-07-11 日清食品ホールディングス株式会社 Deposition prevention method of pasty seasoning
JP2019122268A (en) * 2018-01-12 2019-07-25 ハウス食品株式会社 Pasty seasoning and method of producing the same

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11290016A (en) * 1998-04-13 1999-10-26 Ajinomoto Co Inc Semi-pasty seasoning composition
JP2000069931A (en) * 1998-08-28 2000-03-07 Ajinomoto Co Inc Novel half kenaded seasoning
JP2014030381A (en) * 2012-08-03 2014-02-20 S & B Foods Inc Semi-kneaded tubed seasoning
JP2016123319A (en) * 2014-12-26 2016-07-11 ヱスビー食品株式会社 Viscous food seasoning composition, and method for producing viscous food using the same
JP2019122268A (en) * 2018-01-12 2019-07-25 ハウス食品株式会社 Pasty seasoning and method of producing the same
JP2019110927A (en) * 2019-04-22 2019-07-11 日清食品ホールディングス株式会社 Deposition prevention method of pasty seasoning

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