JP2006197817A - Oil and fat composition for batter - Google Patents

Oil and fat composition for batter Download PDF

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JP2006197817A
JP2006197817A JP2005010802A JP2005010802A JP2006197817A JP 2006197817 A JP2006197817 A JP 2006197817A JP 2005010802 A JP2005010802 A JP 2005010802A JP 2005010802 A JP2005010802 A JP 2005010802A JP 2006197817 A JP2006197817 A JP 2006197817A
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oil
batter
fat
mass
fat composition
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JP4493508B2 (en
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Yoshio Wakamatsu
義夫 若松
Masayoshi Takegahara
正義 竹ヶ原
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Adeka Corp
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Adeka Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an oil and fat composition for batter excellent in dispersing properties in batter liquid, with which crispy palate feeling is imparted to fry food obtained from the composition, the palate feeling retains for a long time, and the fry food has favorable crispy feeling even after cooked with a microwave when reheating the fry food frozen or refrigerated; and to provide batter liquid containing the oil and fat composition for batter. <P>SOLUTION: The oil and fat composition for batter comprises 2-30 mass% of phospholipid in an oil phase (oil-phase bases) and 1-10 mass% of extremely hardened oil and fat (oil-phase bases): wherein SFC (solid fat content) of the oil phase is 2-25% at all the temperature of 10-40°C. The batter liquid comprises 3-30 mass% of the oil and fat composition for batter. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、バッター液に添加する際の分散性が良好で、サクサクした食感のフライ食品を得ることができるバッター用油脂組成物、及び該バッター用油脂組成物を含有してなるバッター液に関する。   The present invention relates to a batter oil and fat composition that has good dispersibility when added to a batter liquid and that can provide a crispy fried food, and a batter liquid containing the batter oil and fat composition. .

コロッケ、メンチかつなどのフライ食品は、タネ(食品素材)を、澱粉類と水を主体とし、その他必要に応じ卵液や調味料などを添加したバッター液に浸漬後、パン粉を付着させ、フライ油でフライして得られるものであり、バッター液に含まれる澱粉や蛋白質、あるいは付着させたパン粉が高温のフライ用油脂でフライされることによりサクサクした食感が得られ、これが特徴となっている。
また、てんぷらは、タネ(食品素材)を、ダシ汁や水に、澱粉類を薄く溶いたバッター液に浸漬後、フライ油でフライして得られるものであり、バッター液に含まれる澱粉や蛋白質が高温のフライ用油脂でフライされることによりサクサクした食感が得られ、これが特徴となっている。
Frozen foods such as croquettes, menthi bonito, etc. are soaked in seed batter that contains seeds (food ingredients), mainly starch and water, and egg liquid or seasoning as necessary. It is obtained by frying with oil, and starch and protein contained in batter liquid, or attached bread crumbs are fried with high-temperature frying fat, resulting in a crispy texture. Yes.
Tempura is obtained by immersing seed (food material) in dashi juice or water in a batter solution in which starch is thinly dissolved and then fried in frying oil. Starch and protein contained in batter solution The crunchy texture is obtained by frying with hot oil for frying.

しかし、これらのフライ食品のサクサク感は、フライ後、時間が経過するにつれ、タネ(食品素材)に含まれる水分の移行や、空気中の水分の吸湿により徐々に失われ、べたついた食感になってしまう。
また、フライ食品を冷凍保管あるいは冷蔵保管した際の再加熱時に、電子レンジを使用するとさらにべとつきの激しい食感になってしまい、当初のサクサク感は微塵もみられなくなってしまう。
そこで、これらの場合においても良好なサクサクした食感を保持するフライ食品とするため、従来より、フライ用油脂の改良や、パン粉の改良、タネ(食品素材)の改良、バッター液の改良など、様々な改良がなされてきた。
However, the crispness of these fried foods is gradually lost as time passes after frying, due to the transfer of moisture contained in the seeds (food ingredients) and the absorption of moisture in the air, resulting in a sticky texture. turn into.
In addition, when a microwave oven is used during reheating when fried foods are stored frozen or refrigerated, the texture becomes even more sticky and the initial crispy texture does not show fine dust.
Therefore, in order to make a fried food that retains a good crispy texture even in these cases, conventionally, improvement of frying fats and oils, improvement of bread crumbs, improvement of seeds (food material), improvement of batter liquid, Various improvements have been made.

このうち、バッター液の改良に関するものは上記のなかでも最も普遍性が高いことから各種の発明がなされており、例えば、卵類や澱粉類などの加熱セット性を有する原料を含有し約20〜50%の液状油脂と水相からなる水中油型乳化型のバッター液(例えば特許文献1参照)、10℃における固体脂含有量が15〜35%且つ15℃における固体脂含有量が0〜10%である油脂組成物を使用する方法(例えば特許文献2参照)や、温度5〜20℃での固体脂含有率が2〜10%となる流動状食用油脂と、融点が45℃以上の食用油脂とを所定割合で混合した油脂組成物を使用する方法(例えば特許文献3参照)、25℃における固体脂含量が1〜5%であり、且つ、構成脂肪酸中、炭素数20〜22の飽和脂肪酸を0.3〜4質量%含有することを特徴とするバッター用油脂組成物(例えば特許文献4参照)等が知られている。   Among these, various inventions relating to the improvement of batter liquids have been made since they are the most universal among the above, and include, for example, raw materials having heat setting properties such as eggs and starches, and about 20 to Oil-in-water emulsified batter liquid consisting of 50% liquid fat and water phase (see, for example, Patent Document 1) The solid fat content at 10 ° C is 15 to 35% and the solid fat content at 15 ° C is 0 to 10 % Using a fat and oil composition (see, for example, Patent Document 2), fluid edible fat and oil with a solid fat content of 2 to 10% at a temperature of 5 to 20 ° C, and an edible with a melting point of 45 ° C or higher A method of using an oil and fat composition in which fats and oils are mixed at a predetermined ratio (see, for example, Patent Document 3), a solid fat content at 25 ° C. of 1 to 5%, and a saturated fatty acid having 20 to 22 carbon atoms in the constituent fatty acid Contains 0.3-4% by weight of fatty acids Batter fat composition for (for example, see Patent Document 4), and the like, characterized by.

しかし、特許文献1のバッター液では、フライ食品がソフトな食感となってしまい、サクサクした食感が得られない問題があり、特許文献2で使用する油脂組成物は、使用油脂の融点が高く、冬季など固化してしまうため扱いにくく、その場合バッター液への分散性が極端に悪いという問題があった。また、特許文献3の方法では、別途粉末状の高融点油脂を用意する必要があるため作業が煩雑であり、また上記2種の油脂を混合した油脂組成物は高融点油脂が沈降してしまう問題があることに加え、バッター液中に高融点油脂が均一に分散しにくいという問題があり、特許文献4のバッター用油脂組成物では、バッター液への分散性が十分ではないため、均質なバッター液を得るためには強力な攪拌装置を必要とするという問題があった。
特開平1−144939号公報 特開平9−94074号公報 特開平10−248487号公報 特開2001−128617号公報
However, in the batter liquid of Patent Document 1, the fried food has a soft texture, and there is a problem that a crunchy texture cannot be obtained. The oil and fat composition used in Patent Document 2 has a melting point of the used oil and fat. It is expensive and difficult to handle because it solidifies in winter and in that case there is a problem that the dispersibility in the batter liquid is extremely bad. Moreover, in the method of patent document 3, since it is necessary to prepare a powdery high melting point oil and fat separately, an operation | work is complicated, and the high melting point fat and oil will precipitate in the oil and fat composition which mixed the said 2 types of fats and oils. In addition to the problem, there is a problem that the high melting point oil and fat is difficult to uniformly disperse in the batter liquid. The batter oil and fat composition of Patent Document 4 is not sufficiently dispersible in the batter liquid, so that it is homogeneous. In order to obtain a batter liquid, there was a problem that a powerful stirring device was required.
JP-A-1-144939 JP-A-9-94074 JP-A-10-248487 JP 2001-128617 A

従って、本発明の目的は、バッター液への分散性に優れ、得られたフライ食品がサクサクした食感であって、この食感が長時間保たれ、さらにフライ食品を冷凍保管あるいは冷蔵保管した際の再加熱時に電子レンジを使用しても良好なサクサク感が得られる、バッター用油脂組成物、及び該バッター用油脂組成物を含有するバッター液を提供することにある。   Therefore, the object of the present invention is excellent dispersibility in batter liquid, and the obtained fried food has a crispy texture, the texture is maintained for a long time, and the fried food is stored frozen or refrigerated. An object of the present invention is to provide a batter oil-and-fat composition and a batter liquid containing the batter oil-and-fat composition, which can provide a good crispy feeling even when a microwave oven is used during reheating.

本発明者等は、上記目的を達成すべく種々検討した結果、従来使用されていたよりも極めて多量のリン脂質と、極度硬化油脂を併用した油脂組成物により、上記目的を達成可能なことを知見した。
本発明は、上記知見に基づいてなされたもので、油相中にリン脂質を2〜30質量%(油相基準)及び極度硬化油脂を1〜10質量%(油相基準)含有し、且つ、該油相のSFCが、10℃〜40℃の全ての温度において2〜25%であることを特徴とするバッター用油脂組成物、及び、該バッター用油脂組成物を3〜30質量%含有してなるバッター液を提供するものである。
As a result of various studies to achieve the above-mentioned object, the present inventors have found that the above object can be achieved by using an oil / fat composition in which an extremely large amount of phospholipid and an extremely hardened oil / fat are used in combination. did.
The present invention has been made based on the above knowledge, and contains 2 to 30% by mass (based on oil phase) of phospholipid and 1 to 10% by mass (based on oil phase) of extremely hardened oil and fat in the oil phase, and The oil phase SFC is 2 to 25% at all temperatures of 10 ° C. to 40 ° C., and the batter oil and fat composition contains 3 to 30% by mass. Thus, a batter solution is provided.

本発明のバッター用油脂組成物は、広い温度域でほぼ同一の物性を示し、バッター液への分散性に優れる。また、該バッター用油脂組成物を含有する本発明のバッター液を使用した、てんぷら、コロッケ、メンチかつなどのフライ食品は、サクサクした食感が得られ、この食感が長時間保たれ、さらに、冷凍保管品の解凍時や、冷蔵保管や長期保管により、べたついた食感となってしまったフライ食品を再加熱する際に、電子レンジを使用しても良好なサクサク感が得られる。   The batter oil and fat composition of the present invention exhibits substantially the same physical properties in a wide temperature range, and is excellent in dispersibility in a batter liquid. In addition, fried foods such as tempura, croquettes, menthi bonito, etc. using the batter liquid of the present invention containing the batter oil and fat composition provide a crispy texture, and this texture is maintained for a long time. A good crispy feeling can be obtained even when a microwave oven is used when re-heating fried foods that have become sticky textures by thawing frozen storage products, refrigerated storage, or long-term storage.

まず、本発明のバッター用油脂組成物について詳述する。
本発明のバッター用油脂組成物は、油相中に、リン脂質を2〜30質量%、好ましくは8〜30質量%、更に好ましくは10〜30質量%(油相基準)含有する。
リン脂質含量が2質量%未満であると、バッター用油脂組成物は広い温度域での一定の粘性が出ず、バッター液への分散性が悪くなってしまう。また、30質量%を超えると、粘度が高くなりすぎ、バッター用油脂組成物のバッター液への分散性が極端に悪化してしまうことに加え、得られるフライ食品の口溶けが極めて悪くなってしまう。
First, the batter oil and fat composition of the present invention will be described in detail.
The fat and oil composition for batter of the present invention contains 2 to 30% by mass, preferably 8 to 30% by mass, and more preferably 10 to 30% by mass (based on the oil phase) of phospholipid in the oil phase.
If the phospholipid content is less than 2% by mass, the batter oil-and-fat composition does not exhibit a certain viscosity in a wide temperature range, and the dispersibility in the batter liquid becomes poor. On the other hand, if it exceeds 30% by mass, the viscosity becomes too high and the dispersibility of the batter oil / fat composition in the batter liquid is extremely deteriorated, and the meltability of the resulting fried food becomes extremely poor. .

本発明で使用するリン脂質とは、ホスファチジルコリン、ホスファチジルエタノールアミン、ホスファチジルセリン、ホスファチジルイノシトール、ホスファチジルグリセロール、ホスファチジン酸等のジアシルグリセロリン脂質、及び、これらをリゾ化、水素化、分別等の処理を施したもの、さらには、これらの2種以上の混合物を含むものである。
本発明で使用するリン脂質の起源としては特に限定されず、ナタネ、卵黄、大豆、牛乳等が挙げられる。
また、本発明では、精製されたリン脂質を使用してもよいが、リン脂質を含有する大豆レシチン、ナタネレシチン、卵黄レシチン、卵黄油、あるいは牛乳レシチン、脱脂濃縮乳等の食品素材や食品添加物を用いることも勿論可能である。
上記リン脂質を含有する食品素材や食品添加物を使用する場合は、固形分中のリン脂質の含有量が10質量%以上、好ましくは30質量%以上、さらに好ましくは50質量%以上である食品素材や食品添加物を使用することが好ましい。
また、上記のリン脂質を含有する食品素材や食品添加物は、液体状でも、粉末状でも、濃縮物でも構わない。
The phospholipid used in the present invention is phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylinositol, phosphatidylglycerol, phosphatidic acid, and other diacylglycerophospholipids, and these are subjected to treatments such as lysolysis, hydrogenation, and fractionation. Or a mixture of two or more of these.
The origin of the phospholipid used in the present invention is not particularly limited, and examples thereof include rapeseed, egg yolk, soybean, and milk.
In the present invention, purified phospholipids may be used, but food materials and food additives such as soybean lecithin, rapeseed lecithin, egg yolk lecithin, egg yolk oil, milk lecithin, and defatted concentrated milk containing phospholipids may be used. Of course, it is also possible to use a thing.
When the food material or food additive containing the phospholipid is used, the food having a solid content of phospholipid of 10% by mass or more, preferably 30% by mass or more, more preferably 50% by mass or more. It is preferable to use raw materials and food additives.
The food material and food additive containing the phospholipid may be liquid, powder, or concentrate.

また、本発明のバッター用油脂組成物では、リン脂質の一部又は全部がリゾ化されたものであることが好ましい。該リゾ化されたリン脂質(リゾリン脂質)を含有することにより、バッター液への分散性をより向上させることができる。また該リゾ化されたリン脂質を使用したフライ食品は、フライ時の風味劣化や、増粘、食感の劣化が少なくなる。   Moreover, in the batter oil-fat composition of the present invention, it is preferable that part or all of the phospholipid is lysed. By containing the lysed phospholipid (lysophospholipid), the dispersibility in the batter liquid can be further improved. In addition, fried foods using the lysed phospholipids are less susceptible to flavor deterioration, thickening, and texture deterioration during frying.

本発明のバッター用油脂組成物で用いるリゾリン脂質としては、リゾ化率50%以上のものが好ましく、より好ましくは80%以上である。
リン脂質をリゾ化するにはホスホリパーゼAで処理すればよい。ホスホリパーゼAは、リン脂質分子のグリセロール部分と脂肪酸残基とを結びつけている結合を切断し、この脂肪酸残基を水酸基で置き換える作用を有する酵素である。ホスホリパーゼAは、作用する部位の違いによってA1、A2に分かれるが、A2が好ましい。ホスホリパーゼA2の場合、リン脂質分子のグリセロール部分の2位の脂肪酸残基が選択的に切り離される。
The lysophospholipid used in the batter oil / fat composition of the present invention is preferably 50% or more, and more preferably 80% or more.
In order to lyze the phospholipid, it may be treated with phospholipase A. Phospholipase A is an enzyme having an action of cleaving a bond connecting a glycerol part of a phospholipid molecule and a fatty acid residue and replacing the fatty acid residue with a hydroxyl group. Phospholipase A is divided into A1 and A2 depending on the site of action, but A2 is preferred. In the case of phospholipase A2, the fatty acid residue at position 2 of the glycerol part of the phospholipid molecule is selectively cleaved.

また、本発明のバッター用油脂組成物は、油相中に、上記リン脂質に加え、極度硬化油脂を1〜10質量%、好ましくは1〜8質量%、更に好ましくは3〜8質量%(油相基準)含有する。
極度硬化油脂含量が1質量%未満であると、バッター用油脂組成物は広い温度域での一定の粘性が出ず、バッター液への分散性が悪くなってしまう。また、10質量%を超えると、粘度が高くなりすぎ、バッター用油脂組成物のバッター液への分散性が極端に悪化してしまうことに加え、得られるフライ食品の口溶けが極めて悪くなってしまう。
上記極度硬化油脂は、原料油脂に対し、ヨウ素価が好ましくは10以下、さらに好ましくは5以下、最も好ましくは1未満となるまで水素添加し、実質的に構成成分である不飽和脂肪酸をほぼ完全に飽和することによって得られる油脂であって、その融点は、好ましくは50℃以上、より好ましくは55℃以上である。
なお、融点の上限については特に制限はないが、好ましくは80℃である。
Moreover, the fats and oils composition for batters of this invention is 1-10 mass% in an oil phase in addition to the said phospholipid, Preferably it is 1-8 mass%, Preferably it is 1-8 mass%, More preferably, it is 3-8 mass% ( Oil phase standard) contained.
If the extremely hardened oil / fat content is less than 1% by mass, the oil / fat composition for batter does not exhibit a certain viscosity in a wide temperature range, and the dispersibility in the batter liquid becomes poor. On the other hand, when the content exceeds 10% by mass, the viscosity becomes too high, and the dispersibility of the batter oil composition in the batter liquid is extremely deteriorated, and in addition, the meltability of the resulting fried food becomes extremely poor. .
The above extremely hardened fat / oil is hydrogenated with respect to the raw oil / fat until the iodine value is preferably 10 or less, more preferably 5 or less, and most preferably less than 1. It is an oil obtained by saturating the oil, and its melting point is preferably 50 ° C. or higher, more preferably 55 ° C. or higher.
In addition, although there is no restriction | limiting in particular about the upper limit of melting | fusing point, Preferably it is 80 degreeC.

また、上記極度硬化油脂は、上記極度硬化油脂を更に分別した硬部油、あるいは1種又は2種以上の極度硬化油脂をエステル交換したものであってもよく、また、極度硬化油脂と、飽和脂肪酸や、飽和脂肪酸を主体とする部分グリセリド等とをエステル交換したものであってもよい。本発明では、これら全てを極度硬化油脂として扱う。   Further, the extremely hardened oil or fat may be a hard part oil obtained by further separating the extremely hardened oil or fat, or one obtained by transesterifying one or more kinds of extremely hardened oil or fat. A transesterified fatty acid or a partial glyceride mainly composed of a saturated fatty acid may be used. In the present invention, all of these are treated as extremely hardened fats and oils.

本発明のバッター用油脂組成物においては、上記極度硬化油脂の中でも、微細結晶が得られ、バッター液への分散性が特に優れている点において、結晶形がβプライム型である極度硬化油脂を使用することが好ましい。
結晶形がβプライム型である極度硬化油脂の好ましい例としては、下記(1) 〜(5) の油脂が挙げられる。
(1) 「牛脂、豚脂、乳脂等の奇数酸を多く含む動物油脂や、ハイエルシン菜種油、魚油等の長鎖脂肪酸を多く含有する油脂」を原料油脂とした極度硬化油脂。
(2) 「構成脂肪酸の平均鎖長が異なる2種又は3種以上の油脂からなる油脂配合物を、化学的あるいは酵素的にエステル交換して、構成脂肪酸の鎖長をばらつかせた油脂配合物」を原料油脂とした極度硬化油脂。
(3) 「1種又は2種以上の油脂に、該油脂と構成脂肪酸の平均鎖長が異なる飽和脂肪酸又は該飽和脂肪酸を主体とする部分グリセリドを添加してなる油脂配合物を、化学的あるいは酵素的にエステル交換して、構成脂肪酸の鎖長をばらつかせた油脂」を原料油脂とした極度硬化油脂。
(4) 構成脂肪酸の平均鎖長が異なる2種以上の極度硬化油脂をエステル交換した油脂。
(5) 「1種又は2種以上の極度硬化油脂に、該極度硬化油脂と構成脂肪酸の平均鎖長が異なる飽和脂肪酸又は該飽和脂肪酸を主体とする部分グリセリドを添加してなる油脂配合物」を、化学的あるいは酵素的にエステル交換して、構成脂肪酸の鎖長をばらつかせた油脂。
In the oil composition for batter of the present invention, among the above extremely hardened fats and oils, fine crystals are obtained, and the dispersibility in batter liquid is particularly excellent. It is preferable to use it.
Preferable examples of extremely hardened fats and oils whose crystal form is β prime type include the following fats and oils (1) to (5).
(1) Extremely hardened fats and oils made from “fats and fats rich in odd acids such as beef tallow, pork tallow and milk fats, and fats and fats high in long-chain fatty acids such as hay erucin rapeseed oil and fish oil”.
(2) “Fat blended with a mixture of two or more fats and oils with different average chain lengths of the constituent fatty acids, chemically or enzymatically transesterified to vary the chain length of the constituent fatty acids Extremely hardened fats and oils made from raw materials.
(3) “An oil or fat composition obtained by adding a saturated fatty acid having a different average chain length between the fat and oil or a constituent fatty acid or a partial glyceride mainly composed of the saturated fatty acid to one or more oils or fats, Extremely hardened fats and oils made from “oils and fats that have undergone transesterification enzymatically to vary the chain length of the constituent fatty acids”.
(4) Fats and oils obtained by transesterifying two or more kinds of extremely hardened fats and oils having different average chain lengths of constituent fatty acids.
(5) "Oil mixture obtained by adding saturated fatty acid having a different average chain length between the extremely hardened oil and the constituent fatty acid or partial glyceride mainly composed of the saturated fatty acid to one or more kinds of extremely hardened oil and fat" Oils and fats that have been transesterified chemically or enzymatically to vary the chain length of the constituent fatty acids.

本発明では、これらの極度硬化油脂の中でも、ハイエルシン菜種油の極度硬化油脂、魚油の極度硬化油脂等、長鎖脂肪酸を多く含む油脂を原料油脂とした極度硬化油脂が、広い温度域で固液分離が特に少ないバッター用油脂組成物を得られる点で好ましく使用される。
なお、上記極度硬化油脂の結晶形がβプライム型であることを確認するには、極度硬化油脂を80℃で完全溶解した後、0℃で30分間保持し、次いで5℃で30分間保持して析出させた油脂結晶について、2θ:17〜26度の範囲でX線回折測定を実施し、4.1〜4.3オングストロームの面間隔に対応する強い回折線が得られることを確認すればよい。
In the present invention, among these extremely hardened oils and fats, extremely hardened fats and oils made from raw fats and oils containing a lot of long-chain fatty acids such as extremely hardened fats and oils of Hyelsin rapeseed oil, extremely hardened fats and oils of fish oil, etc. are solid-liquid separated in a wide temperature range Is particularly preferred in that it can provide a batter oil or fat composition with a small amount.
In addition, in order to confirm that the crystal form of the above extremely hardened oil and fat is β prime type, after completely dissolving the extremely hardened oil and fat at 80 ° C, hold it at 0 ° C for 30 minutes, and then hold at 5 ° C for 30 minutes. When the X-ray diffraction measurement is performed in the range of 2θ: 17 to 26 degrees and it is confirmed that strong diffraction lines corresponding to the surface spacing of 4.1 to 4.3 angstroms are obtained. Good.

本発明のバッター用油脂組成物は、上記リン脂質及び上記極度硬化油脂に加え、その他の油脂を、油相のSFCが10〜40℃の全ての温度において2〜25%、好ましくは6〜25%となるように、油脂のヨウ素価、平均脂肪酸鎖長を勘案し、油相に配合する。
ここで、油相のSFCが10〜40℃のいずれかの温度において2%未満であると、流動性が高すぎて、バッター液への分散性が悪化し、均一なバッター液が得られない上に、得られるフライ食品がサクサク感に乏しいものとなってしまう。また、油相のSFCが10〜40℃のいずれかの温度において25%を超えると、保存中、あるいは温度変動等によって固化してしまい、その場合、バッター液への分散性が悪化し、均一なバッター液が得られない上に、得られるフライ食品の食感が硬すぎ、口溶けの悪いものになってしまう。
尚、上記SFCは、次のようにして測定する。即ち、先ず、油相を60℃に30分間保持して完全に融解した後、0℃に30分間保持して固化させる。次いで、25℃に30分間保持し、テンパリングを行い、その後、0℃に30分間保持する。これを各測定温度に順次30分間保持後、SFCを測定する。
In addition to the phospholipid and the extremely hardened oil and fat, the oil and fat composition for batter of the present invention contains other oil and fat at 2 to 25%, preferably 6 to 25 at all temperatures of SFC of the oil phase of 10 to 40 ° C. %, The iodine value of the fat and oil and the average fatty acid chain length are taken into account and blended into the oil phase.
Here, when the SFC of the oil phase is less than 2% at any temperature of 10 to 40 ° C., the fluidity is too high, the dispersibility in the batter liquid deteriorates, and a uniform batter liquid cannot be obtained. On top of that, the resulting fried food will be less crispy. Also, if the SFC of the oil phase exceeds 25% at any temperature of 10 to 40 ° C., it will solidify during storage or due to temperature fluctuations, etc. In that case, the dispersibility in the batter liquid will deteriorate and become uniform In addition, a batter solution cannot be obtained, and the texture of the resulting fried food is too hard, resulting in poor melting of the mouth.
The SFC is measured as follows. That is, first, the oil phase is kept at 60 ° C. for 30 minutes to completely melt and then kept at 0 ° C. for 30 minutes to solidify. Subsequently, it hold | maintains at 25 degreeC for 30 minutes, tempering is performed, and it hold | maintains at 0 degreeC after that for 30 minutes. After maintaining this at each measurement temperature for 30 minutes, SFC is measured.

上記SFCに調整するために使用するその他の油脂としては、食用に適する油脂であればよく、その代表例としては、大豆油、菜種油、コーン油、綿実油、オリーブ油、落花生油、米油、べに花油、ひまわり油等の常温で液体の油脂が挙げられるが、その他に、パーム油、パーム核油、ヤシ油、サル脂、マンゴ脂、乳脂、牛脂、乳脂、豚脂、カカオ脂、魚油、鯨油等の常温で固体の油脂も挙げられ、更に、これらの食用油脂の水素添加油脂、分別油、エステル交換油等の物理的又は化学的処理の1種又は2種以上の処理を施した油脂を使用することもできる。本発明においては、これらの油脂を単独で用いることもでき、又は2種以上を組み合わせて用いることもできる。   Other fats and oils used for adjusting to the above SFC may be fats and oils suitable for edible use, and representative examples thereof are soybean oil, rapeseed oil, corn oil, cottonseed oil, olive oil, peanut oil, rice oil, beni flower oil. , Oils that are liquid at room temperature, such as sunflower oil, but other oils such as palm oil, palm kernel oil, coconut oil, monkey fat, mango fat, milk fat, beef fat, milk fat, pork fat, cacao fat, fish oil, whale oil, etc. Also included are oils and fats that are solid at room temperature, and oils and fats that have been subjected to one or more physical or chemical treatments such as hydrogenated oils, fractionated oils, and transesterified oils of these edible oils. You can also In the present invention, these fats and oils can be used alone or in combination of two or more.

本発明のバッター用油脂組成物では、上記その他の油脂の中でも、10℃において液状である油脂を使用することが、バッター液への分散性が良好な油脂組成物が得られる点で好ましく、具体的には、大豆油、菜種油、コーン油、綿実油、オリーブ油、落花生油、米油、べに花油、ひまわり油、パーム分別軟部油、パーム分別軟部油のエステル交換油の分別軟部油の中から選択される1種又は2種以上の混合油脂が好ましく使用される。
本発明のバッター用油脂組成物における上記その他の油脂の配合量は、油相中に、好ましくは60〜96質量%、より好ましくは65〜90質量%(油相基準)である。
本発明のバッター用油脂組成物における油相には、後述のその他の成分のうち、油溶性成分を含有してもよい。該成分としては、β−カロチン等の着色料、トコフェロール、茶抽出物等の酸化防止剤、着香料、リン脂質以外の乳化剤等の食品素材や食品添加物が挙げられる。
In the oil composition for batters of the present invention, among the other oils and fats described above, it is preferable to use oils and fats that are liquid at 10 ° C. in terms of obtaining oil compositions that have good dispersibility in the batter liquid. Specifically, it is selected from soybean oil, rapeseed oil, corn oil, cottonseed oil, olive oil, peanut oil, rice oil, ben flower oil, sunflower oil, palm fraction soft part oil, and fractionated soft part oil of palm fraction soft part oil. One or two or more mixed oils and fats are preferably used.
The blending amount of the other fats and oils in the batter fat and oil composition of the present invention is preferably 60 to 96% by mass, more preferably 65 to 90% by mass (based on the oil phase) in the oil phase.
The oil phase in the batter oil-fat composition of the present invention may contain an oil-soluble component among other components described below. Examples of the components include food materials and food additives such as coloring agents such as β-carotene, antioxidants such as tocopherol and tea extract, flavoring agents, and emulsifiers other than phospholipids.

本発明のバッター用油脂組成物の油相含量は、好ましくは80〜100質量%、より好ましくは90〜100質量%、さらに好ましくは99〜100質量%である。
すなわち本発明のバッター用油脂組成物における水相含量は、好ましくは20質量%未満、より好ましくは10%未満、さらに好ましくは1%未満である。
油相含量が80質量%未満、すなわち水相成分が20質量%を超えると、保存中にリン脂質の吸水により、バッター用油脂組成物が濁ったり、バッター用油脂組成物中にダマが発生してしまうなどの問題を生じるおそれがある。また、バッター液が水中油中水型の二重乳化の形態になってしまうこともあり、その場合、フライ食品に水分が残りやすく、結果としてサクサクした食感のフライ食品が得られない。
The oil phase content of the fat and oil composition for batter of the present invention is preferably 80 to 100% by mass, more preferably 90 to 100% by mass, and further preferably 99 to 100% by mass.
That is, the water phase content in the batter oil / fat composition of the present invention is preferably less than 20% by mass, more preferably less than 10%, and even more preferably less than 1%.
When the oil phase content is less than 80% by mass, that is, when the water phase component exceeds 20% by mass, the oil composition for batter becomes cloudy due to absorption of phospholipids during storage, or lumps are generated in the batter oil composition. May cause problems such as In addition, the batter liquid may be in the form of a water-in-oil-in-water double emulsion, in which case moisture tends to remain in the fried food, and as a result, a crispy fried food cannot be obtained.

本発明のバッター用油脂組成物は、10〜40℃の全ての温度において、粘度が、100mPa・s以上、特に500mPa・s以上であることが好ましく、20,000mPa・s以下、特に18,000mPa・s以下であることが好ましい。
10〜40℃のいずれかの温度において粘度が100mPa・s未満であると、保存中に固液分離を起こすおそれがあり、また、バッター液中に分散させる際の混合時間が延びたり、乳化せずにダマになる等、分散性が低下しやすい。
一方、10〜20℃のいずれかの温度において粘度が20,000mPa・sを超えると、硬すぎてバッター液への分散性が悪化し、均一なバッター液が得られない上に、得られるフライ食品の食感が口溶けの悪いものになってしまう。
The batter oil and fat composition of the present invention has a viscosity of 100 mPa · s or more, particularly 500 mPa · s or more, preferably 20,000 mPa · s or less, particularly 18,000 mPa at all temperatures of 10 to 40 ° C. -It is preferable that it is below s.
If the viscosity is less than 100 mPa · s at any temperature of 10 to 40 ° C., solid-liquid separation may occur during storage, and the mixing time for dispersing in batter liquid may be prolonged or emulsified. Dispersibility tends to decrease, such as becoming lumps.
On the other hand, if the viscosity exceeds 20,000 mPa · s at any temperature of 10 to 20 ° C., it is too hard to deteriorate the dispersibility in the batter liquid, and a uniform batter liquid cannot be obtained. The texture of food becomes poorly melted.

本発明のバッター用油脂組成物は、上記以外のその他の成分を含有することができる。該その他の成分としては、例えば、グリセリン脂肪酸エステル、蔗糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、グリセリン有機酸脂肪酸エステル、ポリグリセリン脂肪酸エステル、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウム、ポリオキシエチレンソルビタン脂肪酸エステル等の乳化剤、ローカストビーンガム、カラギーナン、アルギン酸類、ペクチン、キサンタンガム、結晶セルロース、カルボキシメチルセルロース、メチルセルロース、寒天、グルコマンナン、ゼラチン、澱粉、化工澱粉等の増粘安定剤、食塩、塩化カリウム等の塩味剤、酢酸、乳酸、グルコン酸等の酸味料、糖類や糖アルコール類、ステビア、アスパルテーム等の甘味料、β−カロチン、カラメル、紅麹色素等の着色料、トコフェロール、茶抽出物等の酸化防止剤、小麦蛋白や大豆蛋白といった植物蛋白、卵及び各種卵加工品、着香料、乳製品、調味料、pH調整剤、食品保存料、日持ち向上剤、果実、果汁、コーヒー、ナッツペースト、香辛料、ココアマス、ココアパウダー、穀類、豆類、野菜類、肉類、魚介類等の食品素材や食品添加物が挙げられる。
本発明のバッター用油脂組成物における上記その他の成分の含有量は、好ましくは20質量%以下、より好ましくは5質量%以下である。
The batter oil and fat composition of the present invention may contain other components other than those described above. Examples of the other components include glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, glycerin organic acid fatty acid ester, polyglycerin fatty acid ester, stearoyl calcium lactate, stearoyl sodium lactate, polyoxyethylene sorbitan fatty acid. Emulsifiers such as esters, locust bean gum, carrageenan, alginic acids, pectin, xanthan gum, crystalline cellulose, carboxymethylcellulose, methylcellulose, agar, glucomannan, gelatin, starch, modified starch and other thickening stabilizers, salt, potassium chloride, etc. Salting agents, acidulants such as acetic acid, lactic acid and gluconic acid, sugars and sugar alcohols, sweeteners such as stevia and aspartame, β-carotene, caramel, red yeast rice pigment Colorants, antioxidants such as tocopherols, tea extracts, plant proteins such as wheat and soy protein, eggs and various processed eggs, flavorings, dairy products, seasonings, pH adjusters, food preservatives, improved shelf life Examples include food materials and food additives such as agents, fruits, fruit juices, coffee, nut paste, spices, cocoa mass, cocoa powder, cereals, beans, vegetables, meats, and seafood.
Content of the said other component in the fats and oils composition for batters of this invention becomes like this. Preferably it is 20 mass% or less, More preferably, it is 5 mass% or less.

次に本発明のバッター用油脂組成物の製造方法を説明する。
本発明のバッター用油脂組成物は、その製造方法が特に制限されるものではなく、リン脂質、極度硬化油脂、その他の油脂を含有する油相を溶解、混合後、冷却、結晶化させることにより製造することができる。
詳しくは、先ず、リン脂質を2〜30質量%(油相基準)及び極度硬化油脂を1〜10質量%(油相基準)含有し、SFCが10〜40℃の全ての温度において2〜25%である油相を溶解し、必要により該油相に水相を混合乳化する。そして、次に殺菌処理するのが望ましい。殺菌方法は、タンクでのバッチ式でも、プレート型熱交換機や掻き取り式熱交換機を用いた連続式でも構わない。
Next, the manufacturing method of the fats and oils composition for batters of this invention is demonstrated.
The batter oil / fat composition of the present invention is not particularly limited in its production method. By dissolving, mixing, cooling, and crystallizing an oil phase containing phospholipid, extremely hardened oil / fat, and other oils / fats. Can be manufactured.
Specifically, first, it contains 2 to 30% by mass (based on the oil phase) of phospholipid and 1 to 10% by mass (based on the oil phase) of extremely hardened fat and oil, and 2 to 25 at all temperatures of 10 to 40 ° C. % Oil phase is dissolved, and if necessary, the water phase is mixed and emulsified in the oil phase. Then, it is desirable to sterilize next. The sterilization method may be a batch type in a tank, or a continuous type using a plate type heat exchanger or a scraping type heat exchanger.

次に、溶解した油相(又は油相と水相との混合乳化物)を冷却し、結晶化させる。好ましくは冷却可塑化する。冷却条件は、好ましくは−0.5℃/分以上、さらに好ましくは−5℃/分以上とする。この際、徐冷却より、急速冷却の方が好ましい。冷却する機器としては、密閉型連続式チューブ冷却機、例えば、ボテーター、コンピネーター、パーフェクター等のマーガリン製造機やプレート型熱交換機等が挙げられ、また、開放型のダイアクーラーとコンプレクターとの組み合わせも挙げられる。
また、本発明のバッター用油脂組成物を製造する際のいずれかの製造工程で、窒素、空気等を含気させてもよいが、気相を含有することにより粘度が高くなり、特に低温度域での流動性が失われるおそれがあることから、気相を含有しないものであることが好ましい。
Next, the dissolved oil phase (or a mixed emulsion of an oil phase and an aqueous phase) is cooled and crystallized. Preferably, cooling plasticization is performed. The cooling condition is preferably −0.5 ° C./min or more, more preferably −5 ° C./min or more. At this time, rapid cooling is preferable to slow cooling. Examples of the equipment to be cooled include a closed continuous tube cooler, for example, a margarine manufacturing machine such as a botator, a compinator, and a perfector, a plate heat exchanger, and the like, and an open type diacooler and a compressor. Combinations are also mentioned.
In addition, in any of the production steps when producing the batter fat composition of the present invention, nitrogen, air, etc. may be included, but the viscosity increases due to the inclusion of the gas phase, particularly at low temperatures. Since the fluidity in the region may be lost, it is preferable that the gas phase is not contained.

以上のようにして得られた本発明のバッター用油脂組成物は、マーガリンやショートニング等の可塑性油脂と異なり、一定の粘性と流動性を有することに加え、さらにリン脂質を多量に含有するため、従来のバッター用油脂組成物に比べて極めて容易に水や卵液に分散し、均質なバッター液を得ることができる。
そのため、特別な混合機を必要とせずとも、手混ぜであっても簡単に均質なバッター液とすることが可能であるという特徴を有する。
The batter oil composition of the present invention obtained as described above, unlike plastic oils such as margarine and shortening, in addition to having a certain viscosity and fluidity, further contains a large amount of phospholipid, Compared to conventional batter oils and fat compositions, it can be dispersed very easily in water or egg liquid to obtain a homogeneous batter liquid.
Therefore, even if it is hand-mixed, a homogeneous batter liquid can be easily obtained without requiring a special mixer.

次に本発明のバッター液について述べる。
本発明のバッター液は、上記の本発明のバッター用油脂組成物を3〜30質量%、好ましくは5〜20質量%含有してなるものであり、タネ(食品素材)への付着性が適度であり、該バッター液を使用して得られたフライ食品はサクサクした食感であって、この食感が長時間保たれ、さらにフライ食品を冷凍保管あるいは冷蔵保管した際の再加熱時に電子レンジを使用しても良好なサクサク感が得られるという特徴を有する。
Next, the batter liquid of the present invention will be described.
The batter liquid of the present invention contains 3 to 30% by mass, preferably 5 to 20% by mass of the above-mentioned batter oil and fat composition of the present invention, and has an appropriate adhesion to seeds (food material). The fried food obtained using the batter liquid has a crispy texture, the texture is maintained for a long time, and the microwave oven is used for reheating when the fried food is stored frozen or refrigerated. Even if it uses, it has the characteristics that a favorable crispy feeling is obtained.

本発明のバッター液は、従来のバッター液を製造する際に使用する食品素材や食品添加物に加え、本発明のバッター用油脂組成物を上記の含有量となるように添加して製造すればよい。
つまり、水、クリーム、牛乳、濃縮乳、醗酵乳、卵、ダシ汁等の水性原料や、穀粉及び/又は澱粉等の粉体原料に加え、本発明のバッター用油脂組成物を使用し、これに必要に応じて、糖類、脱脂粉乳や全粉乳等の乳製品、食塩等の塩味剤、β−カロチン等の着色料、小麦蛋白や大豆蛋白といった植物蛋白、ホエー蛋白質、カゼイン蛋白質等の動物蛋白質、卵及び各種卵加工品、酢酸やクエン酸等の酸味料、アルギン酸ナトリウム、カラギーナン、ゼラチン、ペクチン、キサンタンガム等の増粘安定剤、乳化剤、酸化防止剤、膨張剤、保存料、苦味料、グルタミン酸ナトリウム等の調味料、ステビア抽出物等の甘味料、香辛料、香辛料抽出物、香料、食塩等の無機塩類、着色料、調味料、豆類、野菜類等の食品素材や食品添加物を加え、常法に従って加工することにより、本発明のバッター液を得ることができる。
If the batter liquid of the present invention is produced by adding the batter oil / fat composition of the present invention to the above content in addition to the food materials and food additives used in producing the conventional batter liquid, Good.
In other words, in addition to aqueous raw materials such as water, cream, milk, concentrated milk, fermented milk, eggs and dashi juice, and powder raw materials such as flour and / or starch, the fat composition for batter of the present invention is used. As needed, saccharides, dairy products such as skim milk powder and whole milk powder, salty agents such as salt, colorants such as β-carotene, plant proteins such as wheat protein and soy protein, animal proteins such as whey protein and casein protein , Eggs and various processed eggs, acidulants such as acetic acid and citric acid, thickeners such as sodium alginate, carrageenan, gelatin, pectin, xanthan gum, emulsifiers, antioxidants, swelling agents, preservatives, bitters, glutamic acid Contain seasonings such as sodium, sweeteners such as stevia extract, spices, spice extracts, fragrances, inorganic salts such as salt, colorants, seasonings, beans, vegetables, and other food ingredients and food additives. Law Thus by processing, it is possible to obtain a batter of the present invention.

本発明のバッター用油脂組成物をバッター液に含有させる方法としては、予め、穀粉及び/又は澱粉等の粉体原料を水性原料に分散させたバッター液に、本発明のバッター用油脂組成物を添加し、十分に混合する方法、穀粉及び/又は澱粉等の粉体原料に、本発明のバッター用油脂組成物を分散させた後、水性原料を添加し、十分に混合する方法、本発明のバッター用油脂組成物を水性原料に分散させた後、穀粉及び/又は澱粉等の粉体原料を添加し、十分に混合する方法等があり、これらのうちの何れの方法でも良い。
なお、本発明のバッター用油脂組成物は、分散性が極めて良好であるため、手混ぜであっても簡単に均質なバッター液とすることが可能であるが、コロイドミル等の乳化機、ホモゲナイザー等の均質化機を使用することにより、より均質で良好な物性のバッター液を得ることができる。
The batter oil / fat composition of the present invention is contained in the batter liquid in advance by mixing the batter liquid / fat composition of the present invention in a batter liquid in which powder raw materials such as flour and / or starch are dispersed in an aqueous raw material. A method of adding and mixing sufficiently, a method of adding an aqueous raw material to a powder raw material such as flour and / or starch, and then mixing an aqueous raw material and mixing sufficiently, There is a method of dispersing a batter oil-and-fat composition in an aqueous raw material and then adding a powder raw material such as flour and / or starch and mixing them well, and any of these methods may be used.
The batter oil-fat composition of the present invention has extremely good dispersibility, and can be easily made into a homogeneous batter liquid even by hand mixing. However, an emulsifier such as a colloid mill or a homogenizer By using a homogenizer such as a homogenizer, a batter solution having more uniform and good physical properties can be obtained.

本発明のバッター液は、てんぷら、コロッケ、クリームコロッケ、メンチカツ、魚介類や畜肉類のフライ等の、各種フライ食品に使用することができる。
本発明のバッター液の使用方法は、従来のバッター液の使用方法と同様であり、例えばタネ(食品素材)に、必要に応じ小麦粉等の打ち粉をまぶし、次いでバッター液を付着させ、更にパン粉を付け、又はそのまま成型するというものである。これを直ちに、又は冷蔵や冷凍等の方法にて保管後、フライ油で揚げることによってフライ食品が得られる。
なかでも本発明のバッター液は、フライ食品が、バッター液を付着後成型冷凍保管したもの、あるいは、フライ油で揚げたものを冷凍保管したものなどの、冷凍過程を経たものに使用した場合、特にサクサク感の改良効果が顕著であり、適している。
The batter liquid of the present invention can be used for various fried foods such as tempura, croquettes, cream croquettes, rice cutlets, seafood and livestock meat fries.
The method of using the batter liquid of the present invention is the same as the conventional method of using the batter liquid. For example, the seed (food material) is dusted with flour such as wheat flour if necessary, then the batter liquid is adhered, and the bread crumb is further applied. Or is molded as it is. The fried food is obtained by frying it with frying oil immediately after storing it by a method such as refrigeration or freezing.
Among them, the batter liquid of the present invention is used when the fried food is used after undergoing a freezing process, such as a frozen food stored after the batter liquid is attached, or a fried food fried in a frying oil. In particular, the effect of improving the crispness is remarkable and suitable.

〔実施例1〕
菜種油87質量%及びハイエルシン菜種油の極度硬化油脂(融点60℃・ヨウ素価1未満)3質量%の混合油脂を70℃に加熱して溶融した後、大豆レシチン(リン脂質を60質量%含有)10質量%を均一に溶解し、パーフェクターを使用して5秒間で15℃に急速冷却して、リン脂質を6質量%及び極度硬化油脂を3質量%含有し、油相のSFCが10℃で9%、20℃で9%、30℃で9%、40℃で8%である本発明のバッター用油脂組成物を得た。このバッター用油脂組成物は、ビスコステスター(リオン(株)製)で粘度を測定したところ、10〜40℃の全ての温度において、500〜2,000mPa・sであった。
[Example 1]
A mixed fat of 87% by mass of rapeseed oil and 3% by mass of extremely hardened oil and fat of hay rapeseed oil (melting point 60 ° C., iodine value less than 1) is heated to 70 ° C. and melted, and then soybean lecithin (containing 60% by mass of phospholipid) 10 Dissolve mass% uniformly, rapidly cool to 15 ° C. in 5 seconds using a perfector, contain 6 mass% phospholipid and 3 mass% extremely hardened oil and fat, and SFC of oil phase is 10 ° C. The batter oil-fat composition of the present invention was 9%, 9% at 20 ° C, 9% at 30 ° C, and 8% at 40 ° C. This batter oil-fat composition was 500 to 2,000 mPa · s at all temperatures of 10 to 40 ° C. when the viscosity was measured with a viscoester (manufactured by Lion Co., Ltd.).

〔実施例2〕
菜種油70質量%及びハイエルシン菜種油の極度硬化油脂(融点60℃・ヨウ素価1未満)3質量%の混合油脂を70℃に加熱して溶融した後、大豆レシチン(リン脂質を60質量%含有)27質量%を均一に溶解し、パーフェクターを使用して5秒間で15℃に急速冷却して、リン脂質を16質量%及び極度硬化油脂を3質量%含有し、油相のSFCが10℃で16%、20℃で16%、30℃で16%、40℃で15%である本発明のバッター用油脂組成物を得た。このバッター用油脂組成物は、ビスコステスター(リオン(株)製)で粘度を測定したところ、10〜40℃の全ての温度において、500〜2,000mPa・sであった。
[Example 2]
70% by mass of rapeseed oil and 3% by mass of highly hardened oil / fat of Hyelsin rapeseed oil (melting point 60 ° C., iodine value less than 1) are heated to 70 ° C. and melted, and then soybean lecithin (containing 60% by mass of phospholipid) 27 Dissolve the mass% uniformly, rapidly cool to 15 ° C. in 5 seconds using a perfector, contain 16 mass% phospholipid and 3 mass% extremely hardened oil and fat, and the SFC of the oil phase is 10 ° C. The batter fat and oil composition of the present invention was 16%, 16% at 20 ° C, 16% at 30 ° C, and 15% at 40 ° C. This batter oil-fat composition was 500 to 2,000 mPa · s at all temperatures of 10 to 40 ° C. when the viscosity was measured with a viscoester (manufactured by Lion Co., Ltd.).

〔実施例3〕
パームスーパーオレイン35質量%、菜種油35質量%及びハイエルシン菜種油の極度硬化油脂(融点60℃・ヨウ素価1未満)3質量%の混合油脂を70℃に加熱して溶融した後、大豆レシチン(リン脂質を60質量%含有)27質量%を均一に溶解し、パーフェクターを使用して5秒間で15℃に急速冷却して、リン脂質を16質量%及び極度硬化油脂を3質量%含有し、油相のSFCが10℃で24%、20℃で16%、30℃で16%、40℃で16%である本発明のバッター用油脂組成物を得た。このバッター用油脂組成物は、ビスコステスター(リオン(株)製)で粘度を測定したところ、20℃〜40℃の範囲では500〜20,000mPa・sであったが、10℃における粘度が25,000Pa・sを超えていた。
Example 3
After heating and melting a mixed fat of 35% by mass of palm super olein, 35% by mass of rapeseed oil and 3% by mass of Hyelsin rapeseed oil (melting point 60 ° C., iodine value less than 1) to 70 ° C., soybean lecithin (phospholipid) 27 mass%) was dissolved uniformly and rapidly cooled to 15 ° C. in 5 seconds using a perfector, containing 16 mass% phospholipid and 3 mass% extremely hardened oil and fat. The batter oil-fat composition of the present invention having a phase SFC of 24% at 10 ° C, 16% at 20 ° C, 16% at 30 ° C, and 16% at 40 ° C was obtained. When the viscosity of this batter oil and fat composition was measured with a viscoester (manufactured by Rion Co., Ltd.), it was 500 to 20,000 mPa · s in the range of 20 ° C. to 40 ° C., but the viscosity at 10 ° C. It was over 25,000 Pa · s.

〔実施例4〕
菜種油70質量%及びハイエルシン菜種油の極度硬化油脂(融点60℃・ヨウ素価1未満)8質量%の混合油脂を70℃に加熱して溶融した後、大豆レシチン(リン脂質を60質量%含有)22質量%を均一に溶解し、パーフェクターを使用して5秒間で15℃に急速冷却して、リン脂質を13質量%及び極度硬化油脂を8質量%含有し、油相のSFCが10℃で18%、20℃で18%、20℃で17%、40℃で17%である本発明のバッター用油脂組成物を得た。このバッター用油脂組成物は、ビスコステスター(リオン(株)製)で粘度を測定したところ、10〜40℃の全ての温度において、500〜15,000mPa・sであった。
Example 4
70% by mass of rapeseed oil and 8% by mass of extremely hardened oil / fat of Hyelsin rapeseed oil (melting point: 60 ° C., iodine value of less than 1) are heated to 70 ° C. and melted, and then soybean lecithin (containing 60% by mass of phospholipid) 22 Dissolve the mass% uniformly, rapidly cool to 15 ° C. in 5 seconds using a perfector, contain 13 mass% phospholipid and 8 mass% extremely hardened oil, and the SFC of the oil phase is 10 ° C. The batter oil-fat composition of the present invention was 18%, 18% at 20 ° C, 17% at 20 ° C, and 17% at 40 ° C. When the viscosity of this batter oil / fat composition was measured with a viscoester (manufactured by Rion Co., Ltd.), it was 500 to 15,000 mPa · s at all temperatures of 10 to 40 ° C.

〔実施例5〕
菜種油87質量%及びハイエルシン菜種油の極度硬化油脂(融点60℃・ヨウ素価1未満)3質量%の混合油脂を70℃に加熱して溶融した後、豚の膵液由来のホスホリパーゼAを使用して酵素処理した大豆リゾレシチン(リン脂質を60質量%含有、リゾ化率80%)10質量%を均一に溶解し、パーフェクターを使用して5秒間で15℃に急速冷却して、リン脂質を6質量%(うちリゾ化リン脂質は5質量%)及び極度硬化油脂を3質量%含有し、油相のSFCが10℃で8%、20℃で8%、30℃で7%、40℃で6%である本発明のバッター用油脂組成物を得た。このバッター用油脂組成物は、ビスコステスター(リオン(株)製)で粘度を測定したところ、10〜40℃の全ての温度において、500〜2,000mPa・sであった。
Example 5
After heating and melting a mixed fat of 87% by mass of rapeseed oil and 3% by mass of extremely hardened fat (high melting point of 60 ° C. and iodine value of less than 1) of Hyelsin rapeseed oil to 70 ° C., an enzyme using phospholipase A derived from porcine pancreatic juice is used. 10% by mass of the treated soybean lysolecithin (containing 60% by mass of phospholipid, 80% lysozyme) is uniformly dissolved, and rapidly cooled to 15 ° C. in 5 seconds using a perfector, and 6% by mass of phospholipid. % (Of which lysylated phospholipid is 5% by mass) and 3% by mass of extremely hardened oil and fat, the SFC of the oil phase is 8% at 10 ° C, 8% at 20 ° C, 7% at 30 ° C, 6% at 40 ° C % Batter oil and fat composition of the present invention was obtained. This batter oil-fat composition was 500 to 2,000 mPa · s at all temperatures of 10 to 40 ° C. when the viscosity was measured with a viscoester (manufactured by Lion Co., Ltd.).

〔実施例6〕
菜種油82質量%及びハイエルシン菜種油の極度硬化油脂(融点60℃・ヨウ素価1未満)8質量%の混合油脂を70℃に加熱して溶融した後、豚の膵液由来のホスホリパーゼAを使用して酵素処理した大豆リゾレシチン(リン脂質を60質量%含有、リゾ化率90%)10質量%を均一に溶解し、パーフェクターを使用して5秒間で15℃に急速冷却して、リン脂質を6質量%(うちリゾ化リン脂質は5質量%)及び極度硬化油脂を8質量%含有し、油相のSFCが10℃で13%、20℃で13%、30℃で12%、40℃で12%である本発明のバッター用油脂組成物を得た。このバッター用油脂組成物は、ビスコステスター(リオン(株)製)で粘度を測定したところ、10〜40℃の全ての温度において、500〜15,000mPa・sであった。
Example 6
After mixing 82% by mass of rapeseed oil and 8% by mass of extremely hardened fats and oils (high melting point 60 ° C., iodine value less than 1) of hay rapeseed oil to 70 ° C., the enzyme is used using phospholipase A derived from porcine pancreatic juice. 10% by mass of the treated soybean lysolecithin (containing 60% by mass of phospholipid, 90% lysozyme) is uniformly dissolved, rapidly cooled to 15 ° C. in 5 seconds using a perfector, and 6% by mass of phospholipid. % (Of which lysylated phospholipid is 5% by mass) and 8% by mass of extremely hardened oil and fat, SFC of the oil phase is 13% at 10 ° C, 13% at 20 ° C, 12% at 30 ° C, 12 at 40 ° C % Batter oil and fat composition of the present invention was obtained. When the viscosity of this batter oil / fat composition was measured with a viscoester (manufactured by Rion Co., Ltd.), it was 500 to 15,000 mPa · s at all temperatures of 10 to 40 ° C.

〔比較例1〕
菜種油(SFCが10℃で0%、20℃で0%、30℃で0%、40℃で0%)をそのまま比較例1のバッター用油脂組成物とした。この菜種油は、ビスコステスター(リオン(株)製)で粘度を測定したところ、10〜40℃の全ての温度において、100mPa・s未満であった。
[Comparative Example 1]
Rapeseed oil (SFC 0% at 10 ° C., 0% at 20 ° C., 0% at 30 ° C., 0% at 40 ° C.) was used as the batter oil and fat composition of Comparative Example 1 as it was. The viscosity of this rapeseed oil was less than 100 mPa · s at all temperatures of 10 to 40 ° C. when the viscosity was measured with a viscoester (manufactured by Lion Co., Ltd.).

〔比較例2〕
菜種油97質量%及びハイエルシン菜種油の極度硬化油脂(融点60℃・ヨウ素価1未満)3質量%の混合油脂を70℃に加熱して均一に溶解した後、パーフェクターを使用して5秒間で15℃に急速冷却して、リン脂質を含有せず、極度硬化油脂を3質量%含有し、油相のSFCが10℃で4%、20℃で4%、30℃で4%、40℃で3%である、比較例2のバッター用油脂組成物を得た。このバッター用油脂組成物は、ビスコステスター(リオン(株)製)で粘度を測定したところ、10〜40℃の全ての温度において、500〜2,000mPa・sであった。
[Comparative Example 2]
A mixed fat / oil of 97% by mass of rapeseed oil and 3% by mass of extremely hardened oil / fat of Hyelsin rapeseed oil (melting point: 60 ° C., iodine value of less than 1) is heated to 70 ° C. and uniformly dissolved, then 15% in 5 seconds using a perfector. It is rapidly cooled to 0 ° C, does not contain phospholipids, contains 3% by mass of extremely hardened fats and oils, and the SFC of the oil phase is 4% at 10 ° C, 4% at 20 ° C, 4% at 30 ° C, at 40 ° C The batter oil and fat composition of Comparative Example 2 was 3%. This batter oil-fat composition was 500 to 2,000 mPa · s at all temperatures of 10 to 40 ° C. when the viscosity was measured with a viscoester (manufactured by Lion Co., Ltd.).

〔比較例3〕
菜種油70質量%を70℃に加熱して溶融した後、大豆レシチン(リン脂質を60質量%含有)30質量%を均一に溶解し、パーフェクターを使用して5秒間で15℃に急速冷却して、リン脂質を18質量%含有し、極度硬化油脂を含有せず、油相のSFCが10℃で12%、20℃で12%、30℃で12%、40℃で12%である比較例3のバッター用油脂組成物を得た。このバッター用油脂組成物は、ビスコステスター(リオン(株)製)で粘度を測定したところ、10〜40℃の全ての温度において、100〜300mPa・sであった。
[Comparative Example 3]
After rapeseed oil 70% by mass is heated to 70 ° C. and melted, 30% by mass of soybean lecithin (containing 60% by mass of phospholipid) is uniformly dissolved and rapidly cooled to 15 ° C. in 5 seconds using a perfector. Comparison in which 18% by mass of phospholipid is contained, no extremely hardened oil and fat is contained, and the SFC of the oil phase is 12% at 10 ° C, 12% at 20 ° C, 12% at 30 ° C, and 12% at 40 ° C The batter oil-fat composition of Example 3 was obtained. This batter oil and fat composition was 100 to 300 mPa · s at all temperatures of 10 to 40 ° C. when the viscosity was measured with a viscoester (Rion Co., Ltd.).

〔比較例4〕
菜種硬化油(融点23℃)97質量%及びハイエルシン菜種油の極度硬化油脂(融点60℃・ヨウ素価1未満)3質量%を70℃に加熱して均一に溶解した後、パーフェクターを使用して5秒間で15℃に急速冷却して、リン脂質を含有せず、極度硬化油脂を3質量%含有し、油相のSFCが10℃で20%、20℃で8%、20℃で4%、40℃で4%である比較例4のバッター用油脂組成物を得た。このバッター用油脂組成物は、ビスコステスター(リオン(株)製)で粘度を測定したところ、20℃〜40℃の範囲では500〜20,000mPa・sであったが、10℃における粘度が25,000Pa・sを超えていた。
[Comparative Example 4]
97% by mass of rapeseed oil (melting point: 23 ° C) and 3% by mass of Hyelsin rapeseed oil (melting point: 60 ° C, iodine value of less than 1) 3% by heating to 70 ° C, and then using a perfector Rapid cooling to 15 ° C in 5 seconds, no phospholipids, 3% by weight of extremely hardened fat, oil phase SFC 20% at 10 ° C, 8% at 20 ° C, 4% at 20 ° C The batter oil-fat composition of Comparative Example 4 was 4% at 40 ° C. When the viscosity of this batter oil and fat composition was measured with a viscoester (manufactured by Rion Co., Ltd.), it was 500 to 20,000 mPa · s in the range of 20 ° C. to 40 ° C., but the viscosity at 10 ° C. It was over 25,000 Pa · s.

〔比較例5〕
菜種硬化油(融点23℃)100質量%を70℃に加熱して均一に溶解した後、パーフェクターを使用して5秒間で15℃に急速冷却して、リン脂質及び極度硬化油脂を含有せず、油相のSFCが10℃で17%、20℃で4%、20℃で0%、40℃で0%である比較例5のバッター用油脂組成物を得た。このバッター用油脂組成物は、ビスコステスター(リオン(株)製)で粘度を測定したところ、10℃において20,000Pa・sを超え、且つ、40℃において100Pa・s未満であった。
[Comparative Example 5]
100% by weight of rapeseed oil (melting point: 23 ° C) is heated to 70 ° C and dissolved uniformly, then rapidly cooled to 15 ° C for 5 seconds using a perfector to contain phospholipids and extremely hardened oils and fats. Thus, an oily composition for batter of Comparative Example 5 in which the SFC of the oil phase was 17% at 10 ° C, 4% at 20 ° C, 0% at 20 ° C, and 0% at 40 ° C was obtained. The viscosity of this batter oil and fat composition was 20,000 Pa · s at 10 ° C. and less than 100 Pa · s at 40 ° C. when the viscosity was measured with a viscoester (Rion Co., Ltd.).

<分散性試験>
上記の実施例1〜6及び比較例1〜5で得られたバッター用油脂組成物について、下記の方法で分散性試験を行なった。
1,000ml容のステンレスビーカーに水600gを入れ、撹拌羽根を使用して泡立たないように400rpmで撹拌しながら、ここへバッター用油脂組成物100gを一度に添加し、さらに400rpmで2分混合・分散させた。その際のバッター用油脂組成物の分散性について、下記評価基準に従って4段階で評価した。その結果を表1に記載した。
(分散性の評価基準)
◎:極めて良好(撹拌を止めて2分以上たっても乳化層が残る)
○:良好(撹拌を止めると徐々に分離して2分後にははっきりと2層に分かれる)
△:やや悪い(撹拌を止めるとすぐに2層に分かれる)
×:悪い(撹拌しても乳化しない)
<Dispersibility test>
About the batter oil-fat composition obtained in said Examples 1-6 and Comparative Examples 1-5, the dispersibility test was done with the following method.
Add 600 g of water to a 1,000 ml stainless beaker and add 100 g of batter oil and fat composition at a time while stirring at 400 rpm to avoid foaming using a stirring blade. Dispersed. The dispersibility of the batter oil composition at that time was evaluated in four stages according to the following evaluation criteria. The results are shown in Table 1.
(Evaluation criteria for dispersibility)
A: Very good (Emulsion layer remains even after 2 minutes or more after stirring is stopped)
○: Good (when the stirring is stopped, it gradually separates and after 2 minutes it is clearly separated into two layers)
Δ: Slightly bad (separate into two layers as soon as stirring is stopped)
X: Bad (not emulsified even when stirred)

Figure 2006197817
Figure 2006197817

<バッター液の調製及びフライ試験>
上記の実施例1〜6及び比較例1〜5で得られたバッター用油脂組成物を使用して、下記の方法でバッター液をそれぞれ調製し、調製した各バッター液について、下記の方法でフライ試験を行なった。
1,000ml容のステンレスビーカーに水600gを入れ、撹拌羽根を使用して泡立たないように400rpmで撹拌しながら、ここへバッター用油脂組成物100gを一度に添加し、さらに400rpmで2分混合・分散させた。次いで小麦粉300gを投入してさらに2分混合・分散させ、バッター液を調製した。
このバッター液に白身魚(タラ)の切り身10gを浸漬し、パン粉を付着させたものを急速冷凍し、−20℃で1週間冷凍保管した。冷凍のまま180℃のフライ油(菜種油使用)で4分間フライしてフライ食品を得た。
このフライ食品のフライ直後及びフライ5時間後の食感(サクサク感)について、下記評価基準に従って4段階で評価した。その結果を表2に記載した。
また、得られたフライ食品の一部については、ただちに急速冷凍し、−20℃の冷凍庫にて1週間保管後、電子レンジで再加熱した際の食感(サクサク感)について、同様に評価した。その結果を表2に併せて記載した。
(食感の評価基準)
23名のパネラーにより下記の4段階評価を行なった。そして、その評価点数の平均点を算出した。
6点:サクサク感がきわめて良好
4点:サクサク感が良好
2点:サクサク感がやや悪い
0点:サクサク感が全く認められない
<Preparation of batter liquid and fly test>
Using the fat and oil compositions for batters obtained in Examples 1 to 6 and Comparative Examples 1 to 5, batter liquids were prepared by the following methods, and the prepared batter liquids were fried by the following method. A test was conducted.
Add 600 g of water to a 1,000 ml stainless beaker and add 100 g of batter oil and fat composition at a time while stirring at 400 rpm to avoid foaming using a stirring blade. Dispersed. Next, 300 g of flour was added and mixed and dispersed for another 2 minutes to prepare a batter solution.
A 10 g white fish (cod) fillet was dipped in this batter liquid, and the bread crumbs were quickly frozen and stored frozen at -20 ° C. for 1 week. The food was fried for 4 minutes with 180 ° C. frying oil (uses rapeseed oil) while frozen.
The texture (crispy feeling) immediately after frying of this fried food and after 5 hours of frying was evaluated in four stages according to the following evaluation criteria. The results are shown in Table 2.
In addition, some of the obtained fried foods were immediately frozen, immediately stored in a freezer at −20 ° C. for 1 week, and then similarly evaluated for the texture (crispy feeling) when reheated in a microwave oven. . The results are also shown in Table 2.
(Evaluation criteria for texture)
The following 4 grades were evaluated by 23 panelists. And the average score of the evaluation score was calculated.
6 points: Very good crispness 4 points: Good crispness 2 points: Slightly crispiness 0 points: No crispness

Figure 2006197817
Figure 2006197817

表1及び表2から判るように、実施例1〜6のバッター用油脂組成物は、分散性が良好で、得られたバッター液を使用したフライ食品の食感もサクサク感があり、フライ5時間後あるいは冷凍保管品を電子レンジで再加熱した場合もその食感が保持されていた。
それに対し、極度硬化油脂もリン脂質も含有しない比較例1及び比較例5のバッター用油脂組成物、並びに、極度硬化油脂は含有するが、リン脂質を含有しない比較例2及び比較例4のバッター用油脂組成物は、いずれも、分散性が極めて悪い上に、得られたバッター液を使用したフライ食品はサクサク感が劣り、またフライ5時間後あるいは冷凍保管品を電子レンジで再加熱した場合のサクサク感の消失も大きいものであった。
また、リン脂質は含有するが、極度硬化油脂を含有しない比較例3のバッター用油脂組成物は、分散性がやや悪く、得られたバッター液を使用したフライ食品のサクサク感は良好であるものの、フライ5時間後あるいは冷凍保管品を電子レンジで再加熱した場合のサクサク感の消失が大きいものであった。
As can be seen from Table 1 and Table 2, the batter oil and fat compositions of Examples 1 to 6 have good dispersibility, and the texture of the fried food using the batter liquid obtained is also crispy, and the fry 5 The texture was maintained after time or when the frozen storage product was reheated in a microwave oven.
In contrast, the batter oil compositions of Comparative Examples 1 and 5 that do not contain extremely hardened oils and phospholipids, and the batters of Comparative Examples 2 and 4 that contain extremely hardened oils but do not contain phospholipids All of the oil and fat compositions have extremely poor dispersibility, and the fried food using the obtained batter liquid is inferior in crispness, and after 5 hours of frying or when the frozen storage product is reheated in a microwave oven The disappearance of the crispness was also significant.
Moreover, although the fat and oil composition for batters of Comparative Example 3 containing phospholipid but not containing extremely hardened fats and oils is slightly poor in dispersibility, the crunchiness of the fried food using the obtained batter liquid is good. The disappearance of the crispness was great after 5 hours of frying or when the frozen stored product was reheated in a microwave oven.

Claims (5)

油相中にリン脂質を2〜30質量%(油相基準)及び極度硬化油脂を1〜10質量%(油相基準)含有し、且つ、該油相のSFCが、10〜40℃の全ての温度において2〜25%であることを特徴とするバッター用油脂組成物。   The oil phase contains 2 to 30% by mass of phospholipid (based on the oil phase) and 1 to 10% by mass of extremely hardened fat (based on the oil phase), and the SFC of the oil phase is 10 to 40 ° C. An oil / fat composition for batters, characterized in that it is 2 to 25% at the temperature. 上記リン脂質の一部又は全部がリゾ化されたものである請求項1記載のバッター用油脂組成物。   The fats and oils composition for batters according to claim 1, wherein a part or all of the phospholipid is lysed. 10〜40℃の全ての温度において、粘度が100〜20,000mPa・sである請求項1又は2記載のバッター用油脂組成物。   The fats and oils composition for batters of Claim 1 or 2 whose viscosity is 100-20,000 mPa * s in all the temperature of 10-40 degreeC. 上記極度硬化油脂がハイエルシン菜種油の極度硬化油脂である請求項1〜3のいずれかに記載のバッター用油脂組成物。   The batter oil / fat composition according to any one of claims 1 to 3, wherein the extremely hardened oil / fat is an extremely hardened oil / fat of Hyelsin rapeseed oil. 請求項1〜4のいずれかに記載のバッター用油脂組成物を3〜30質量%含有してなるバッター液。
The batter liquid formed by containing 3-30 mass% of the fats-and-oils composition for batters in any one of Claims 1-4.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019135972A (en) * 2018-02-09 2019-08-22 日本製粉株式会社 Cocoa powder-containing tempura batter and method for producing tempura using same, and cocoa powder-containing tempura batter mix
JP2019162069A (en) * 2018-03-20 2019-09-26 日油株式会社 Oil and fat composition for modifying fried food
WO2024048705A1 (en) * 2022-09-02 2024-03-07 ハウス食品株式会社 Packaged frozen food composition

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* Cited by examiner, † Cited by third party
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JPH07274881A (en) * 1994-04-07 1995-10-24 Kanegafuchi Chem Ind Co Ltd Method for improving quality of battery solution for fried food
JPH10248487A (en) * 1997-03-11 1998-09-22 Nof Corp Fat composition for batter liquid and batter liquid for fried food
JP2001128617A (en) * 1999-11-05 2001-05-15 Honen Corp Fatty oil composition for batter liquid and batter liquid using the same
JP2001136906A (en) * 1999-11-18 2001-05-22 Honen Corp Oil and fat composition for batter liquid and batter liquid using the same
JP2002291434A (en) * 2001-04-03 2002-10-08 Fuji Oil Co Ltd Oil and fat composition for batter and batter liquid for fried food

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07274881A (en) * 1994-04-07 1995-10-24 Kanegafuchi Chem Ind Co Ltd Method for improving quality of battery solution for fried food
JPH10248487A (en) * 1997-03-11 1998-09-22 Nof Corp Fat composition for batter liquid and batter liquid for fried food
JP2001128617A (en) * 1999-11-05 2001-05-15 Honen Corp Fatty oil composition for batter liquid and batter liquid using the same
JP2001136906A (en) * 1999-11-18 2001-05-22 Honen Corp Oil and fat composition for batter liquid and batter liquid using the same
JP2002291434A (en) * 2001-04-03 2002-10-08 Fuji Oil Co Ltd Oil and fat composition for batter and batter liquid for fried food

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019135972A (en) * 2018-02-09 2019-08-22 日本製粉株式会社 Cocoa powder-containing tempura batter and method for producing tempura using same, and cocoa powder-containing tempura batter mix
JP2019162069A (en) * 2018-03-20 2019-09-26 日油株式会社 Oil and fat composition for modifying fried food
WO2024048705A1 (en) * 2022-09-02 2024-03-07 ハウス食品株式会社 Packaged frozen food composition

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