JP7521255B2 - Polyester false twist yarn and knitted fabric - Google Patents

Polyester false twist yarn and knitted fabric Download PDF

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JP7521255B2
JP7521255B2 JP2020088832A JP2020088832A JP7521255B2 JP 7521255 B2 JP7521255 B2 JP 7521255B2 JP 2020088832 A JP2020088832 A JP 2020088832A JP 2020088832 A JP2020088832 A JP 2020088832A JP 7521255 B2 JP7521255 B2 JP 7521255B2
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浩史 須山
昌弘 小澤
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Toray Industries Inc
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本発明は、梳毛調ポリエステル仮撚糸の課題であった、耐スナッグ性を改良し、かつナチュラルな杢感、ふくらみ感、落ち着いた光沢を有するポリエステル仮撚糸及びそれからなる織編物に関する。 The present invention relates to polyester false-twist yarn that has improved snag resistance, a problem that has been a problem with worsted polyester false-twist yarn, and has a natural heathered feel, fullness, and a subdued luster, and to woven and knitted fabrics made from the same.

従来から、ポリエステル糸は、他の合成繊維に比べてハリ腰感が高く、かつシワになりにくいので、スーツ、ジャケット、スラックス等において天然ウール素材の置き換えとして使用されており、外観や風合い、光沢をウールライクにした梳毛調ポリエステル加工糸が種々開発されてきている。ポリエステル糸に梳毛調外観や風合を付与する従来技術としては、ポリエステル糸を構成する各々のフィラメントに、長さ方向に未延伸部(太部)と延伸部(細部)を設け、太部と細部をフィラメント糸中で分散させて存在させた糸がよく知られている(特許文献1参照)。しかしながら、上記糸は、そのような加工を施していないポリエステル仮撚糸に比べて杢調外観などの点で優れているものの、ウールのようなナチュラルな杢感、ふくらみ感は有しておらず、また仮撚で断面が扁平化することのよる合繊特有のギラギラした光沢が課題であった。 Conventionally, polyester yarn has been used as a replacement for natural wool materials in suits, jackets, slacks, etc., because it has a higher firmness and wrinkle resistance than other synthetic fibers, and various worsted polyester processed yarns with a wool-like appearance, texture, and luster have been developed. A well-known conventional technique for imparting a worsted appearance and texture to polyester yarn is a yarn in which each filament constituting the polyester yarn is provided with an unstretched portion (thick portion) and a stretched portion (detailed portion) in the length direction, and the thick portion and the detailed portion are dispersed within the filament yarn (see Patent Document 1). However, although the above-mentioned yarn is superior in terms of a heathered appearance and the like compared to polyester false-twisted yarn that has not been subjected to such processing, it does not have the natural heathered feel and fullness of wool, and the glittering luster peculiar to synthetic fibers due to the cross section being flattened by false twisting has been an issue.

また、上記の太細延伸技術と異型断面フィラメント糸を組み合わせた技術として、凹部を有する異形断面フィラメントを不均一に延伸したポリエステルマルチフィラメント糸(特許文献2参照)や、2種類以上の異なる多葉型断面形状の単フィラメントが分散して混繊されたポリエステルマルチフィラメント糸が提案されている(特許文献3参照)。これらの糸は吸水性や清涼感に優れているが、ナチュラルな杢感、ふくらみ感は有していなかった。 As a technology that combines the above-mentioned thick-thin drawing technology with irregular cross-section filament yarn, polyester multifilament yarn in which irregular cross-section filaments with recesses are unevenly drawn (see Patent Document 2) and polyester multifilament yarn in which two or more different types of monofilaments with multi-lobed cross-section shapes are dispersed and mixed (see Patent Document 3) have been proposed. These yarns have excellent water absorbency and a refreshing feel, but do not have a natural heathered feel or a fluffy feel.

一方、繊度の異なる2種類のポリエステルフィラメント糸からなる芯鞘型の混繊加工糸において、鞘部の糸に太細部を設け、自然な杢調を発現せしめたポリエステル混繊加工糸(特許文献4参照)や、イオン性染色糸のシックアンドシン仮撚糸と非イオン性染色糸のシックアンドシン仮撚糸が交絡した、多色カスリムラ効果と凹凸手触り感を有する、自然感のあるスパンライクな風合いを有する複合仮撚糸が提案されている(特許文献5参照)。これらの手法ではナチュラルな杢感、ふくらみ感を得ることができるものの、繰り返し洗濯時に2種類のフィラメントが分離して、耐スナッグ性が悪化するという課題があり、アウター用衣服には適用しにくいものであった。 On the other hand, in a core-sheath type mixed fiber processed yarn made of two kinds of polyester filament yarns with different fineness, a polyester mixed fiber processed yarn in which a thick section is provided in the sheath yarn to give it a natural heathered look (see Patent Document 4) and a composite false-twisted yarn in which a thick and thin false-twisted yarn made of ionic dyed yarn is intertwined with a thick and thin false-twisted yarn made of non-ionic dyed yarn, have been proposed, which have a multicolored cassamla effect, an uneven texture, and a natural, spun-like feel (see Patent Document 5). Although these techniques can give a natural heathered look and fullness, there is a problem in that the two types of filaments separate during repeated washing, deteriorating snag resistance, making them difficult to apply to outerwear.

このように従来の技術では、梳毛調のナチュラルな杢感、ふくらみ感、落ち着いた光沢と、品質課題である耐スナッグ性の洗濯耐久性を満足させる加工糸は得られていなかった。 As such, conventional technology has been unable to produce processed yarn that satisfies the natural heathered feel, fluffiness, and subtle luster of combed yarn, as well as the quality issue of snag resistance and washing durability.

特開昭60-181316号公報Japanese Unexamined Patent Publication No. 181316/1983 特開平4-91219号公報Japanese Patent Application Publication No. 4-91219 特開平8-218241号公報Japanese Patent Application Publication No. 8-218241 特開2003-119640号公報JP 2003-119640 A 特開2001-20144号公報JP 2001-20144 A

本発明の目的は、梳毛調ポリエステル仮撚糸の課題であった、繰り返し洗濯後の耐スナッグ性を改善し、かつナチュラルな杢感、ふくらみ感、落ち着いた光沢を有する仮撚糸及びそれからなる織編物を提供することにある。 The object of the present invention is to provide a false-twisted yarn that improves the snag resistance after repeated washing, which has been an issue with worsted polyester false-twisted yarn, and that has a natural heathered feel, fullness, and a subdued luster, and a woven or knitted fabric made from the same.

かかる課題を解決するため本発明のポリエステル仮撚糸は、以下のいずかの構成を有する。
(1) 長さ方向に太細ムラを有するポリエステル仮撚糸であって、捲縮率が26~45%、局所的単糸糸長差が5~20%であることを特徴とするポリエステル仮撚糸。
(2) 単糸間で太細ムラに位相差があることを特徴とする、前記(1)に記載にポリエステル仮撚糸。
(3) ホモポリマーからなることを特徴とする、前記(1)または(2)に記載のポリエステル仮撚糸。
(4) 単糸断面が6~10ヶの凹部を有することを特徴とする、前記(1)~(3)のいずれかに記載のポリエステル仮撚糸。
(5) 交絡度が50~150ヶ/mであることを特徴とする、前記(1)~(4)のいずれかに記載のポリエステル仮撚糸。
(6) 前記(1)~(5)のいずれかに記載の仮撚糸を用いたことを特徴とする織編物。
(7) 洗濯20回後のJIS L 1058法:2011 7.2によるスナッグ試験の結果が3級以上であることを特徴とする、前記(6)に記載の織編物。
In order to solve such problems, the polyester false twist yarn of the present invention has any one of the following configurations.
(1) A polyester false-twisted yarn having thickness variations in the length direction, characterized in that the crimp rate is 26 to 45% and the local single yarn length difference is 5 to 20%.
(2) A polyester false twist yarn as described in (1) above, characterized in that there is a phase difference in the thick/thin unevenness between single yarns.
(3) The polyester false twist yarn according to (1) or (2) above, characterized in that it is made of a homopolymer.
(4) A polyester false twist yarn according to any one of (1) to (3) above, characterized in that the cross section of a single yarn has 6 to 10 recesses.
(5) The polyester false twist yarn according to any one of (1) to (4) above, characterized in that the degree of entanglement is 50 to 150 pcs/m.
(6) A woven or knitted fabric, characterized in that the false twist yarn according to any one of (1) to (5) above is used.
(7) The woven or knitted fabric according to (6) above, characterized in that the result of a snag test according to JIS L 1058: 2011 7.2 after 20 washes is grade 3 or higher.

本発明によれば、繰り返し洗濯後の耐スナッグ性が改良された、ナチュラルな杢感、ふくらみ感、落ち着いた光沢を有するポリエステル仮撚糸及びそれからなる織編物を得ることができる。 According to the present invention, it is possible to obtain polyester false-twist yarn that has improved snag resistance after repeated washing, a natural heathered feel, a fluffy feel, and a subdued luster, and a woven or knitted fabric made from the same.

ポリエステル仮撚糸を構成する単糸の横断面模式図である。FIG. 2 is a schematic cross-sectional view of a single yarn constituting a polyester false twist yarn.

本発明のポリエステル仮撚糸を構成するポリマーとしては、ポリエチレンテレフタレート、ポリプロピレンテレフタレート、ポリブチレンテレフタレートなどの芳香族系ポリエステル、ポリ乳酸、ポリグリコール酸などの脂肪族系ポリエステルなどが挙げられるが、なかでも、ポリエチレンテレフタレート、ポリプロピレンテレフタレート、およびポリブチレンテレフタレートは、繊維の機械的特性や耐久性に優れ、捲縮が堅牢であるため好ましい。より好ましくは、未延伸部分の糸強度が高くなるポリエチレンテレフタレートである。 The polymers constituting the polyester false twist yarn of the present invention include aromatic polyesters such as polyethylene terephthalate, polypropylene terephthalate, and polybutylene terephthalate, and aliphatic polyesters such as polylactic acid and polyglycolic acid. Among these, polyethylene terephthalate, polypropylene terephthalate, and polybutylene terephthalate are preferred because they have excellent mechanical properties and durability of the fiber and have robust crimp. More preferred is polyethylene terephthalate, which increases the yarn strength of the unstretched portion.

ポリエチレンテレフタレートとしては、テレフタル酸を主たる酸成分とし、エチレングリコールを主たるグリコール成分とする、90モル%以上がエチレンテレフタレートの繰り返し単位からなるポリエステルを用いることができる。また、本発明の効果を阻害しない範囲内において、他のエステル結合を形成可能な共重合成分を含んでも良い。共重合可能な化合物としては、例えばイソフタル酸、シクロヘキサンジカルボン酸、アジピン酸、ダイマ酸、セバシン酸、スルホン酸などのジカルボンサン類を例示できる。 As the polyethylene terephthalate, a polyester consisting of 90 mol % or more of repeating units of ethylene terephthalate, with terephthalic acid as the main acid component and ethylene glycol as the main glycol component, can be used. In addition, other copolymerizable components capable of forming ester bonds may be included within a range that does not impair the effects of the present invention. Examples of copolymerizable compounds include dicarboxylic acids such as isophthalic acid, cyclohexanedicarboxylic acid, adipic acid, dimer acid, sebacic acid, and sulfonic acid.

本発明のポリエステル仮撚糸は、長さ方向に未延伸部(太部)と延伸部(細部)との太細ムラを有する。このような構成により、織編物にした際、太部が濃染、細部が淡染に染色され、杢調外観及びふくらみ感を得ることができる。ここで、長さ方向に太細ムラがない仮撚糸はプレーンな表面外観でふくらみ感を得ることができない。 The polyester false-twisted yarn of the present invention has thickness unevenness in the length direction between the unstretched parts (thick parts) and the stretched parts (details). With this configuration, when it is made into a woven or knitted fabric, the thick parts are dyed dark and the details are dyed light, resulting in a mottled appearance and a fluffy feel. Here, a false-twisted yarn that does not have thickness unevenness in the length direction has a plain surface appearance and does not have a fluffy feel.

そして、本発明においては、単糸間で太細ムラに位相差を設ける、すなわち単糸間で太部や細部の位置を長さ方向に分散させることが好ましい。こうすることで、入射光を拡散反射することができ、ギラツキをよりおさえることができる。単糸間で太細ムラに位相差がない仮撚糸は、合繊特有のギラツキ光沢を生じやすい。 In the present invention, it is preferable to provide a phase difference in the thick and thin unevenness between single yarns, i.e. to distribute the positions of the thick and thin parts between single yarns in the length direction. This allows the incident light to be diffusely reflected, further reducing glare. False-twist yarns that have no phase difference in the thick and thin unevenness between single yarns are prone to producing the glare that is characteristic of synthetic fibers.

本発明のポリエステル仮撚糸は、捲縮率が26~45(%)であることが重要である。本発明のポリエステル仮撚糸は未延伸部(太部)を有するので、低配向の未延伸部に付与される捲縮は、延伸部(細部)対比、弱くなる傾向にあるが、仮撚糸として捲縮率を26%以上有することができれば、織編物に高いストレッチ性及びふくらみ感を付与することができる。ここで、捲縮率が26%未満であれば、ふくらみ感が不足し、梳毛調の風合いを得ることができない。また捲縮率が45%を超えると、太部の単糸捲縮が織物表面に飛び出すようになり、耐スナッグ性が低下する。 It is important that the polyester false-twisted yarn of the present invention has a crimp rate of 26 to 45%. Because the polyester false-twisted yarn of the present invention has unstretched portions (thick portions), the crimp imparted to the low-oriented unstretched portions tends to be weaker than the stretched portions (details). However, if the false-twisted yarn can have a crimp rate of 26% or more, it can impart high stretchability and a fluffy feel to woven and knitted fabrics. Here, if the crimp rate is less than 26%, the fluffy feel is insufficient and it is not possible to obtain a worsted texture. Furthermore, if the crimp rate exceeds 45%, the single yarn crimp in the thick portions will protrude to the surface of the woven fabric, reducing snag resistance.

また本発明のポリエステル仮撚糸として、例えばポリエチレンテレフタレートとポリトリメチレンテレフタレートのバイメタル構造の糸を採用することも可能であるが、捲縮が強くなりすぎ、耐スナッグ性が低下しやすいので、ホモポリマーからなるポリエステル仮撚糸が好ましい。 It is also possible to use a bimetallic yarn made of, for example, polyethylene terephthalate and polytrimethylene terephthalate as the polyester false twist yarn of the present invention, but as this tends to cause excessive crimping and reduce snag resistance, a polyester false twist yarn made of a homopolymer is preferred.

本発明のポリエステル仮撚糸は、局所的単糸糸長差が5~20%であることが重要である。ここでいう局所的単糸糸長差とは、仮撚糸を短い長さでみた場合の、それを構成する単糸の糸長差であって、具体的には、任意の5cm間という局所的な単糸の糸長差のことである。従来、織編物にナチュラルな杢感、ふくらみ感を付与するには、2種類以上の糸からなる芯鞘型複合糸とし、その芯部を構成する糸と鞘部を構成する糸とに糸長差を付与する方法が考えられていたが、その手法では繰り返し洗濯後に交絡が外れ、鞘部を構成するフィラメントが織編物表面に飛び出し、耐スナッグ性が低下しやすい。また、2種類の糸の複合では、混繊バラツキが発生しやすく、織編物に染着差によるスジ欠点が発生しやすい。これに対して、本発明においては、ポリエステル仮撚糸を構成する単糸が上述の範囲の局所的単糸糸長差を有するようにすることで、ナチュラルな杢感、ふくらみ感を発現するだけでなく、優れた耐スナッグ性を発現し、さらに、混繊バラツキや染着差によるスジ欠点の発生を防ぐことができる。 It is important that the polyester false-twist yarn of the present invention has a local single-yarn length difference of 5 to 20%. The local single-yarn length difference here means the difference in the length of the single yarns that compose the false-twist yarn when viewed at a short length, specifically, the local single-yarn length difference of any 5 cm. In the past, in order to give a natural heathered feel and fullness to woven and knitted fabrics, a method was considered in which a core-sheath type composite yarn made of two or more types of yarn was used and a difference in the length of the yarns that compose the core and the sheath was given. However, with this method, the intertwining is easily removed after repeated washing, and the filaments that compose the sheath are easily exposed to the surface of the woven and knitted fabric, which reduces the snag resistance. In addition, when two types of yarn are combined, the mixed fibers are easily uneven, and streaks due to dyeing differences are easily caused in the woven and knitted fabric. In contrast, in the present invention, by making the single yarns that make up the polyester false twist yarn have a local single yarn length difference within the above-mentioned range, not only does it produce a natural heathered feel and a fluffy feel, it also produces excellent snag resistance, and furthermore, it is possible to prevent the occurrence of streak defects due to unevenness in the mixed fibers and differences in dyeing.

本発明においては、局所的単糸糸長差が5%以上あることで、織編物にナチュラルな杢調外観、ふくらみ感を付与できる。かつ局所的にみた場合に単糸糸長差が存在するような織編物では、繰り返し洗濯後もフィラメントが織編物表面に飛び出し難く、耐スナッグ性が良好である。単糸糸長差が5%未満であると、単調な杢調外観になりで、ふくらみ感も乏しくなる。一方、単糸糸長差が20%を超えると、太部の単糸捲縮が織物表面に飛び出すようになり、スナッグが低下する。 In the present invention, a local single yarn length difference of 5% or more can impart a natural heathered appearance and a fluffy feel to the woven or knitted fabric. Furthermore, in a woven or knitted fabric in which there is a localized single yarn length difference, filaments are less likely to protrude onto the surface of the woven or knitted fabric even after repeated washing, and the fabric has good snag resistance. If the single yarn length difference is less than 5%, the fabric will have a monotonous heathered appearance and a poor fluffy feel. On the other hand, if the single yarn length difference is more than 20%, the single yarn crimp in the thick part will protrude onto the surface of the fabric, and snag resistance will decrease.

そして、かかる単糸糸長差を発現させるために、例えば上述したように、単糸の太細ムラの位相を単糸間で長さ方向に分散する場合には、入射光を拡散反射することができ、ギラツキをおさえることができる。 In order to realize such differences in the length of single yarns, for example, by dispersing the phase of the thickness unevenness of the single yarns in the length direction between the single yarns as described above, the incident light can be diffusely reflected, and glare can be reduced.

また、本発明のポリエステル仮撚糸において、局所的単糸糸長差は2種類の糸の複合による糸長差ではなく、1種類の糸による局所的な単糸糸長差であることが好ましい。 In addition, in the polyester false twist yarn of the present invention, it is preferable that the local single yarn length difference is not a yarn length difference caused by combining two types of yarn, but a local single yarn length difference caused by one type of yarn.

本発明のポリエステル仮撚糸は、それを構成する単糸の断面が、6~10ヶの凹部を有する非円形断面であることが好ましい。単糸の断面が6~10ヶの凹部を有することで、入射光を拡散反射することができ、ギラツキをおさえることができる。また凹部を有することで、ホットピン延伸時に単糸がばらけやすくなり、その結果、単糸間で太細部の位相がずれることで、局所的単糸糸長差が発生しやすくなる。ここで、凹部が6ヶ未満であると、ギラツキが発生しやすくなり、単調な杢調外観になりやすく、ふくらみ感も低下し易く好ましくない。一方凹部が10ヶを超えると、凹部の深さが浅くなり、ギラツキ低減効果が小さくなり好ましくない。より好ましい凹部の個数は7~9個である。なお、凹部とは、図1に示すように、繊維横断面図において、断面輪郭に複数の接点S1、S2で接する直線T1を引いた時、その接点間に存在する凹部(U)を意味する。 In the polyester false twist yarn of the present invention, the cross section of the single yarn constituting it is preferably a non-circular cross section having 6 to 10 recesses. By having 6 to 10 recesses in the cross section of the single yarn, incident light can be diffusely reflected and glare can be suppressed. In addition, by having recesses, the single yarn is more likely to break apart during hot pin drawing, and as a result, the phase of the thick part between the single yarns is shifted, and local single yarn length differences are more likely to occur. Here, if there are less than 6 recesses, glare is more likely to occur, and the appearance is more likely to be monotonous and mottled, and the sense of fullness is also likely to decrease, which is not preferable. On the other hand, if there are more than 10 recesses, the depth of the recesses becomes shallow and the effect of reducing glare is smaller, which is not preferable. A more preferable number of recesses is 7 to 9. Note that the recesses refer to the recesses (U) that exist between the contact points S1 and S2 when a straight line T1 is drawn that touches the cross-sectional contour at multiple contact points S1 and S2 in the fiber cross-sectional view as shown in FIG. 1.

また、本発明のポリエステル仮撚糸は無機微粒子を含有していてもよく、その無機微粒子含有率は、ポリエステル仮撚糸の0.3~3.0質量%であることが、ギラツキをおさえることができ好ましい。ここで、無機微粒子含有率が0.3質量%未満であると、ギラツキが強くなりやすく、かつフィラメント間の摩擦が高くなり、繰り返し洗濯においてフィラメントが飛び出しやすくなり、耐スナッグ性が低下しやすいので、好ましくない。また、無機微粒子含有率が3.0質量%を超えると、染色時に濃色が出にくくなり、好ましくない。より好ましい無機微粒子含有率は0.5~2.5質量%である。なお、無機微粒子としては、二酸化チタン、シリカ、カオリナイト、アルミナ等任意の無機粒子を用いて問題ないが、好ましくは屈折率が高く、光散乱効果の高い酸化チタンである。 The polyester false twist yarn of the present invention may contain inorganic fine particles, and the inorganic fine particle content is preferably 0.3 to 3.0% by mass of the polyester false twist yarn, since glare can be suppressed. Here, if the inorganic fine particle content is less than 0.3% by mass, glare tends to be strong, friction between filaments increases, filaments tend to fly out during repeated washing, and snag resistance tends to decrease, which is undesirable. If the inorganic fine particle content exceeds 3.0% by mass, it becomes difficult to produce dark colors during dyeing, which is undesirable. A more preferable inorganic fine particle content is 0.5 to 2.5% by mass. Note that any inorganic particles such as titanium dioxide, silica, kaolinite, and alumina can be used as the inorganic fine particles, but titanium oxide, which has a high refractive index and a high light scattering effect, is preferable.

本発明のポリエステル仮撚糸は、沸騰水収縮率が4~9%であることが好ましい。沸騰水収縮率が9%を超えると、繰り返し洗濯において単糸の太部が飛び出しやすくなり、耐スナッグ性が低下するので好ましくない。また沸騰水収縮率が4%未満であると、ふくらみ感が低下するので好ましくない。 The polyester false twist yarn of the present invention preferably has a boiling water shrinkage rate of 4 to 9%. If the boiling water shrinkage rate exceeds 9%, the thick part of the single yarn is likely to pop out during repeated washing, and snag resistance decreases, which is not preferable. Also, if the boiling water shrinkage rate is less than 4%, the sense of fullness decreases, which is not preferable.

本発明のポリエステル仮撚糸の総繊度は、50~450dtexであることが、ハリ腰を織編物に付与する点で好ましい。該総繊度が上記好ましい範囲から外れると、衣服としたときハリ腰が不十分で、ギラツキが目立ち易くなるおそれがある。 The total fineness of the polyester false twist yarn of the present invention is preferably 50 to 450 dtex in order to impart firmness to the woven or knitted fabric. If the total fineness is outside the above preferred range, the fabric may not have sufficient firmness when made into clothing, and glare may be noticeable.

一方、ポリエステル仮撚糸を構成する単糸の繊度は、0.5~10dtexであることが、ハリ腰を織編物に付与する点で好ましい。該単糸繊度がそれぞれ上記好ましい範囲から外れると、繰り返し洗濯を受けた際においても、太部の単糸捲縮が織物表面に飛び出し易く、スナッグが発生しやすくなるおそれがある。 On the other hand, the fineness of the single yarns constituting the polyester false twist yarn is preferably 0.5 to 10 dtex in order to impart firmness to the woven or knitted fabric. If the single yarn fineness is outside the above-mentioned preferred ranges, the single yarn crimp in the thick part is likely to protrude to the surface of the woven fabric even after repeated washing, and snags may easily occur.

また本発明のポリエステル仮撚糸の交絡度は50~150ヶ/mであることが好ましい。交絡度が50ヶ/m未満であると、繰り返し洗濯後に太部の単糸捲縮が織物表面に飛び出し易くなり、好ましくない。また交絡度が150ヶ/mを超えると、上述の局所的単糸糸長差を発現しにくくなるので、好ましくない。 The degree of entanglement of the polyester false twist yarn of the present invention is preferably 50 to 150 pcs/m. If the degree of entanglement is less than 50 pcs/m, the single yarn crimp in the thick part is likely to pop out onto the surface of the woven fabric after repeated washing, which is undesirable. If the degree of entanglement is more than 150 pcs/m, it is undesirable because it becomes difficult to realize the above-mentioned local single yarn length difference.

また、本発明のポリエステル仮撚糸には、後工程で撚糸を付与しても何ら問題無い。耐スナッグ性とふくらみ感の両立から、好ましい撚糸数は100~1000T/mであり、さらに好ましくは200~700T/mである。 The polyester false twist yarn of the present invention can be twisted in a later process without any problems. In order to achieve both snag resistance and a fluffy feel, the preferred number of twists is 100 to 1000 T/m, and more preferably 200 to 700 T/m.

次に、本発明のポリエステル仮撚糸及び織編物の製造方法について説明する。 Next, we will explain the manufacturing method of the polyester false twist yarn and woven/knitted fabric of the present invention.

まず、本発明のポリエステル仮撚糸の元糸となる原糸を紡糸するにあたっては、高配向未延伸糸を紡糸することが好ましい。ここで、ホットピン延伸時に単糸間の太細差を強調し局所的に単糸糸長差を発生させやすくするためには、低紡速が好ましく、好ましい紡糸速度は2500~3100m/minである。 First, when spinning the raw yarn that will become the base yarn of the polyester false twist yarn of the present invention, it is preferable to spin a highly oriented undrawn yarn. Here, in order to emphasize the difference in thickness between single yarns during hot pin drawing and to easily generate localized differences in single yarn length, a low spinning speed is preferable, and the preferred spinning speed is 2500 to 3100 m/min.

高配向未延伸糸を本発明の仮撚糸とするためには、仮撚する前にホットピンで低倍率熱処理延伸を行い、太細ムラを単糸に付与し、局所的に単糸糸長差を発生させる。好ましいホットピン延伸条件は1.2~1.6倍である。また、局所的に単糸糸長差を発生させるためには、ホットピン温度は低い方が好ましく、好ましい条件は65~85℃の範囲である。 To turn a highly oriented undrawn yarn into the false-twisted yarn of the present invention, a low-magnification heat treatment and drawing is performed with a hot pin before false-twisting, to impart thick and thin unevenness to the single yarn and to generate localized differences in the single yarn length. The preferred hot pin drawing conditions are 1.2 to 1.6 times. In addition, to generate localized differences in the single yarn length, a lower hot pin temperature is preferred, with the preferred conditions being in the range of 65 to 85°C.

続いて仮撚加工を行うが、仮撚条件としては任意の条件を選定できる。ツイスターにはスピンドル式、フリクションディスク式、ベルトニップ式いずれを用いても構わないが、高速で仮撚可能で単糸捲縮飛び出しが比較的少ないフリクションディスク式が好ましい。 Next, false twist processing is performed, and any conditions can be selected for the false twisting. Any type of twister can be used, including spindle, friction disk, and belt nip types, but a friction disk type is preferred, as it allows false twisting at high speed and causes relatively little popping out of single yarn crimp.

仮撚温度は、接触式ヒータの場合、170~215℃であれば、洗濯の繰り返しで劣化しない強固な捲縮付与ができる点で好ましい。 When using a contact heater, a false twist temperature of 170 to 215°C is preferable because it creates a strong crimp that does not deteriorate with repeated washing.

仮撚数においては、仮撚係数(仮撚数(T/M)×繊度(dtex)0.5)が27,000~33,000の範囲内となるように設定することが、洗濯繰り返しで劣化しない強固な捲縮を付与する点で好ましい。 Regarding the number of false twists, it is preferable to set the false twist coefficient (number of false twists (T/M)×fineness (dtex) 0.5 ) within the range of 27,000 to 33,000 in order to impart strong crimp that does not deteriorate with repeated washing.

また、仮撚の前後に任意でインターレースノズルにより交絡を付与することができる。コスト面も考慮して、交絡圧は0.1~0.6(MPa)であることが好ましい。 Interlacing can also be done before or after false twisting using an interlace nozzle. Taking cost into consideration, it is preferable that the interlacing pressure is 0.1 to 0.6 (MPa).

糸加工速度については早ければ生産性が高くなり好ましいが、安定加工性を考慮すると、100~800(m/min)が好ましい。 The faster the yarn processing speed, the higher the productivity, which is preferable, but when stable processing is taken into consideration, a speed of 100 to 800 (m/min) is preferable.

このようにして製造した本発明の仮撚糸を、公知の製織方法、編成方法を用いて、織物や編物とする。織組織や編組織としては公知の如何なる組織をも適用できる。なお本発明においては、織物と編物を総称して「織編物」という。本発明の織編物は組織あるいは密度になんら制約されることはない。 The false twist yarn of the present invention thus produced is made into a woven or knitted fabric using known weaving and knitting methods. Any known weaving or knitting structure can be used. In the present invention, woven and knitted fabrics are collectively referred to as "woven or knitted fabrics." There are no restrictions on the structure or density of the woven or knitted fabrics of the present invention.

製織に用いられる織機は、一般に使用される普通織機、レピア、ウオータージェットルーム、エアージェットルーム等の機種を例示でき、特に限定されることなく採用できる。 Examples of looms used for weaving include commonly used normal looms, rapiers, water jet looms, air jet looms, etc., and there are no particular limitations on which looms can be used.

また、製編の際は、丸編み機、トリコット機およびラッシェル機等、市販の編機を使用することができる。 When knitting, commercially available knitting machines such as circular knitting machines, tricot machines, and raschel machines can be used.

本発明の仮撚糸を、編糸の少なくとも一部に使用する際は、各々の張力を適正化して製編を行う必要がある。編組織としては、天竺、スムース、ポンチ、リブおよびハーフ組織等、任意の設計が可能となる。 When the false twist yarn of the present invention is used as at least a part of the knitting yarn, it is necessary to optimize the tension of each yarn during knitting. Any knitting structure can be designed, including plain, smooth, punch, rib, and half structures.

次に、本発明の仮撚糸を用いた織編物に施される染色加工について説明する。染色加工工程は、一般のポリエステル仮撚糸を用いた織編物の染色工程及び条件に準じて行うことができる。その中で、仮撚捲縮を充分に発現させるため、リラックス熱処理は120℃以上の高温高圧液流リラックス加工とし、織編物にモミ効果を付与することが好ましい。 Next, we will explain the dyeing process applied to woven and knitted fabrics using the false-twisted yarn of the present invention. The dyeing process can be carried out in accordance with the dyeing process and conditions for woven and knitted fabrics using general polyester false-twisted yarn. In order to fully express the false-twisted crimp, it is preferable that the relaxation heat treatment be a high-temperature, high-pressure liquid flow relaxation process at 120°C or higher, and that the woven and knitted fabrics are given a kneading effect.

また、洗濯収縮を抑制するため、中間セット温度を170℃以上210℃以下にすることが好ましい。中間セット温度を上記好ましい範囲内とすることで、フィラメントが融着することを防ぐことができる。 In addition, to suppress shrinkage during washing, it is preferable to set the intermediate set temperature to 170°C or higher and 210°C or lower. By setting the intermediate set temperature within the above preferred range, filaments can be prevented from fusing.

本発明においては、ソフト風合いを得る面で、織編物にアルカリ減量を施しても構わないが、好ましい減量率は15%以下である。減量率が上記好ましい範囲内であると、繰り返し洗濯や繰り返しても毛羽立ちなどが発生しにくい。 In the present invention, in order to obtain a soft feel, the woven or knitted fabric may be subjected to alkali weight loss, but the preferred weight loss rate is 15% or less. If the weight loss rate is within the above preferred range, pilling is unlikely to occur even after repeated washing.

本発明の織編物においては洗濯20回後のJIS L 1058法:2011 7.2によるスナッグ試験の結果が3級以上であることが好ましい。これにより、洗濯が繰り返し行われても、スナッグが発生し難い、耐久性に優れたアウター素材に好適な織編物といえる。 The woven or knitted fabric of the present invention preferably has a result of grade 3 or higher in the snag test according to JIS L 1058:2011 7.2 after 20 washes. This makes the woven or knitted fabric less susceptible to snagging even after repeated washing, and is highly durable and suitable for use as an outerwear material.

以下、実施例により本発明をさらに具体的に説明する。 The present invention will be explained in more detail below with reference to the following examples.

(1)繊度
枠周1.0mの検尺機を用いて100回分のカセを作製し、下記式に従って繊度を測定した。
繊度(dtex)=100回分のカセ重量(g)×100
(1) Fineness Using a measuring machine with a frame circumference of 1.0 m, 100 skeins were prepared, and the fineness was measured according to the following formula.
Fineness (dtex) = weight of skein for 100 times (g) x 100

(2)伸度
試料を引張試験機(オリエンテック製“テンシロン”(TENSILON)UCT-100)でJIS L 1013(2010) 8.5.1 標準時試験に示される定速伸長条件で測定した。この時の掴み間隔は20cm、引張り速度は20cm/分、試験回数は10回とした。なお、破断伸度はSS曲線における最大強力を示した点の伸びから求めた。
(2) Elongation The sample was measured using a tensile tester (Orientec "TENSILON" UCT-100) under the constant-speed elongation conditions specified in JIS L 1013 (2010) 8.5.1 Standard Time Test. The gripping distance was 20 cm, the tensile speed was 20 cm/min, and the number of tests was 10. The breaking elongation was determined from the elongation at the point showing the maximum strength in the SS curve.

(3)交絡度
交絡度は、0.1cN/dtexの張力下における1m当たりの交絡部の数であり、糸に0.02cN/dtexの張力下で非交絡部にピンを刺し、糸1mにわたり0.1cN/dtexの張力でピンを糸の長手方向の上下に移動せしめ、抵抗なく移動した部分を非交絡部として移動した距離を記録し、ピンが止まる部分を交絡部とした。この作業を30回繰り返し、その非交絡部の距離の平均値から1m当たりの交絡度を計算した。
(3) Degree of entanglement The degree of entanglement is the number of entangled parts per meter under a tension of 0.1 cN/dtex. A pin was inserted into the non-entangled part of the yarn under a tension of 0.02 cN/dtex, and the pin was moved up and down in the longitudinal direction of the yarn over 1 m under a tension of 0.1 cN/dtex. The part that moved without resistance was taken as a non-entangled part, and the distance traveled was recorded. The part where the pin stopped was taken as an entangled part. This operation was repeated 30 times, and the degree of entanglement per meter was calculated from the average distance of the non-entangled parts.

(4)捲縮率
周長0.8mの検尺機に、90mg/dtexの張力下で糸を10回巻回してカセ取りした後、2cm以下の棒につり下げ、約24時間放置した。このカセをガーゼにくるみ、無緊張状態下で90℃×20分間熱水処理した後、2cm以下の棒につり下げ約12時間放置した。放置後のカセの一端をフックにかけ他端に初荷重と測定荷重をかけ水中に垂下し2分間放置した。このときの初荷重(g)=2mg/dtex、測定荷重(g)=90mg/dtex、水温=20±2℃とした。放置したカセの内側の長さを測り、Lとした。さらに、測定荷重を除き初荷重だけにした状態で2分間放置し、放置したカセの内側の長さを測り、L1とした。次式により、捲縮を求め、この作業を5回繰り返し、平均値により求めた。
捲縮率(%)={(L-L1)/L}×100
(4) Shrinkage The yarn was wound 10 times around a measuring machine with a circumference of 0.8 m under a tension of 90 mg/dtex to take a skein, and then hung on a rod of 2 cm or less and left for about 24 hours. The skein was wrapped in gauze, treated with hot water at 90°C for 20 minutes under no tension, and then hung on a rod of 2 cm or less and left for about 12 hours. One end of the skein after leaving was hung on a hook, and the other end was subjected to an initial load and a measurement load, and the skein was left for 2 minutes. The initial load (g) at this time was 2 mg/dtex, the measurement load (g) was 90 mg/dtex, and the water temperature was 20 ± 2°C. The inner length of the left skein was measured and designated as L. Furthermore, the measurement load was removed and the skein was left for 2 minutes with only the initial load, and the inner length of the left skein was measured and designated as L1. The shrinkage was calculated using the following formula, and this operation was repeated 5 times to determine the average value.
Crimp rate (%) = {(L-L1)/L} x 100

(5)沸騰水収縮率
JIS L 1013(2010) 8.18.1 かせ寸法変化率(A法)に基づき求めた。
(5) Boiling water shrinkage was determined based on JIS L 1013 (2010) 8.18.1 Hank dimensional change rate (Method A).

(6)凹部個数
加工糸を繊維横断面方向に厚さ5μmでカットした後、光学顕微鏡で断面写真を撮影し、繊維横断面図において、断面輪郭に複数の接点S1、S2で接する直線T1を引いた時、その接点間の凹部個数を数えた。なお、測定は50個のフィラメントの平均で行った。小数第1位を四捨五入して算出した。
(6) Number of recesses The textured yarn was cut in the fiber cross-sectional direction at a thickness of 5 μm, and then a cross-sectional photograph was taken with an optical microscope. In the fiber cross-sectional view, a straight line T1 was drawn that touches the cross-sectional contour at multiple contact points S1 and S2, and the number of recesses between the contact points was counted. The measurement was performed on the average of 50 filaments. The calculation was rounded off to the first decimal place.

(7)局所的単糸糸長差
(5)の沸騰水収縮を行ったかせを用いて、任意の箇所から5cmカットして取り出した後、各単糸に分解して、各単糸の長さを測定し、次式により、単糸糸長差を求めた。この作業を5回繰り返し、平均値により求めた。
単糸糸長差(%)=(最大長-最小長)/最小長×100
(7) Local Single Yarn Length Difference Using the skein that had been shrunk in boiling water as described in (5), a 5 cm length was cut from an arbitrary location, taken out, and then disassembled into individual single yarns. The length of each single yarn was measured, and the single yarn length difference was calculated according to the following formula. This procedure was repeated five times and the average value was used.
Single yarn length difference (%) = (maximum length - minimum length) / minimum length x 100

(8)耐スナッグ性(洗濯20回後)
2槽式洗濯機で液温度40℃、洗濯時間5分、すすぎ30℃×2分×2回、脱水30秒のサイクルを洗濯1回とした。洗剤には花王の“アタック”(登録商標)を1g/Lを用い、液量40L、試験布と導布である綿布の重量を合算して830gで実施した。この洗濯作業を20回繰り返した後、JIS L 1058:2011 7.2(針布ローラ法)に従いスナッグ評価を行い、級判定を行った。3級以上が合格である。
(8) Snag resistance (after 20 washes)
A two-tub washing machine was used, with a liquid temperature of 40°C, a washing time of 5 minutes, rinsing at 30°C x 2 minutes x 2 times, and a spin cycle of 30 seconds. Kao's "Attack" (registered trademark) was used as the detergent at 1 g/L, with a liquid volume of 40 L and a combined weight of 830 g for the test cloth and the cotton cloth used as the guide cloth. After repeating this washing operation 20 times, a snag evaluation was performed according to JIS L 1058:2011 7.2 (clothed roller method) and a grade was determined. Grade 3 or higher is considered to be acceptable.

(9)杢感
実施例で作成した織編物の杢感において、無作為に選んだ30人の評価で最も意見の多かった評価を結果とした。判定が同数の場合は下位の結果を採用した。◎と○は合格と判定できるレベルにある。
◎:杢の長さが規則的でなく、濃染部ベースに淡染部の杢が多く確認でき、天然ウール同様のナチュラルな杢感を有する。
○:杢の長さが規則的でなく、淡染部ベースに濃染部の杢が多く確認でき、ナチュラルな杢感を有する。
△:杢の長さがやや規則的で、人工的な杢感を有する。
×:杢感を有しておらず、フラットな表面感である。
(9) Heathered Feel The heathered feel of the woven and knitted fabrics created in the examples was evaluated by 30 randomly selected people, and the result was determined based on the most common opinion. In the case of a tie, the lower result was used. ◎ and ○ are at a level that can be judged as acceptable.
◎: The length of the grain is not regular, and many grains can be seen in the light-dyed areas on a base of darkly dyed areas, giving it a natural grain look similar to that of natural wool.
○: The length of the grain is not regular, and many grains can be seen in the dark dyed areas on top of the light dyed areas, giving it a natural grain look.
△: The grain length is somewhat regular, giving it an artificial grain feel.
×: No grainy texture, flat surface.

(10)ふくらみ感
実施例で作成した織編物のふくらみ感において、無作為に選んだ30人の評価で最も意見の多かった評価を結果とした。判定が同数の場合は下位の結果を採用した。◎と○は合格と判定できるレベルにある。
◎:織編物を握ったときに非常に大きいふくらみを感じる。
○:織編物を握ったときに大きいふくらみを感じる。
△:織編物を握ったときにふくらみ感が不足している。
×:織編物を握ったときにふくらみをほとんど感じない。
(10) Fluffiness The results were based on the most common opinion given by 30 randomly selected people regarding the fluffy feel of the woven and knitted fabrics produced in the examples. In the case of a tie, the lower result was used. ◎ and ○ are at a level that can be judged as acceptable.
⊚: When the woven or knitted fabric is gripped, a very large bulge is felt.
◯: A large bulge is felt when the woven or knitted fabric is gripped.
Δ: When the woven or knitted fabric is gripped, there is a lack of volume.
×: Almost no swelling is felt when the woven or knitted fabric is gripped.

(11)ギラツキ感
実施例で作成した織編物のギラツキ感においては、ライトボックス内のD65光源下で判定を行い、無作為に選んだ30人の評価で最も意見の多かった評価を結果とした。判定が同数の場合は下位の結果を採用した。◎と○は合格と判定できるレベルにある。
◎:合繊特有のギラツキはなく、大変落ち着いた光沢外観を有する。
○:合繊特有のギラツキはほとんどなく、落ち着いた光沢外観を有する。
△:局所的に合繊特有のギラツキ光沢を有する。
×:全体的に合繊特有のギラツキ光沢を有する。
(11) Glare The glare of the woven and knitted fabrics produced in the examples was judged under a D65 light source in a light box, and the result was determined based on the most common opinion given by 30 randomly selected judges. In the case of a tie, the lower result was used. ◎ and ○ are at a level that can be judged as acceptable.
: No glare typical of synthetic fibers, and has a very calm glossy appearance.
◯: Almost no glare characteristic of synthetic fibers, and has a subdued glossy appearance.
Δ: The glossy sheen characteristic of synthetic fibers is locally observed.
×: Overall, the material has a shiny luster characteristic of synthetic fibers.

<実施例1>
酸化チタン含有率0.7質量%、八葉断面のポリエチレンテレフタレートを紡速2,8000(m/min)で紡糸し、繊度275dtex、48フィラメント、伸度160%の高配向未延伸糸を得た。そして、上記高配向未延伸糸を、フリクション仮撚機(ATF12:TMTマシナリー製)を用いてフィードローラから給糸し、加工速度:400m/minでまずホットピン75℃で1.5倍の低倍率延伸を行い、その後、延伸倍率:1.1倍、ヒータ温度:200℃、仮撚係数:31,000で仮撚を行い、その後、交絡圧:0.2MPaでインターレース加工を行い、繊度:167dtex、捲縮率:32%、沸騰水収縮率:4.8%、局所的単糸糸長差:9%、交絡数:95ケ/m、凹部個数:8ヶの加工糸を得た。
Example 1
Polyethylene terephthalate having an eight-lobe cross section and a titanium oxide content of 0.7% by mass was spun at a spinning speed of 2,8000 (m/min) to obtain a highly oriented undrawn yarn having a fineness of 275 dtex, 48 filaments, and an elongation of 160%. The highly oriented undrawn yarn was fed from a feed roller using a friction false twisting machine (ATF12, manufactured by TMT Machinery) and first subjected to low-ratio drawing of 1.5 times at 75°C with a hot pin at a processing speed of 400 m/min. Thereafter, false twisting was performed at a draw ratio of 1.1 times, a heater temperature of 200°C, and a false twist coefficient of 31,000. Thereafter, interlacing processing was performed at an entanglement pressure of 0.2 MPa to obtain a textured yarn having a fineness of 167 dtex, a crimp rate of 32%, a boiling water shrinkage rate of 4.8%, a local single yarn length difference of 9%, an entanglement number of 95/m, and a number of recesses of 8.

その後、上記糸を経糸・緯糸に用いて、エアージェット織機で平織物に製織を行い、次に、得られた製織生地に対して、98℃拡布連続精練、120℃液流リラックス、180℃の中間セット、分散染料を用いた130℃での紺色染色を行い、さらに160℃仕上げセットを施し、加工密度(経糸:110本/2.54cm、緯糸:90本/2.54cm)の製品とした。 The yarns were then used as the warp and weft to weave a plain weave fabric on an air jet loom. The resulting woven fabric was then subjected to continuous open-weave scouring at 98°C, flow relaxation at 120°C, intermediate setting at 180°C, and dyed navy blue at 130°C using a disperse dye, and then finishing setting at 160°C to produce a product with a processed density (warp: 110 threads/2.54 cm, weft: 90 threads/2.54 cm).

得られた織物は天然ウール同様のナチュラルな杢感を有し、ふくらみ感が非常に大きく、大変落ち着いた光沢外観を有しているものであった。また、繰り返し洗濯後の耐スナッグ性も大変優れており、梳毛調アウター衣料として好適であった。 The resulting fabric had a natural heathered look similar to that of natural wool, was very fluffy, and had a very calm, glossy appearance. It also had excellent snag resistance even after repeated washing, making it suitable for use as a worsted outer garment.

<実施例2>
酸化チタン含有率0.7質量%、六葉断面のポリエチレンテレフタレートを紡速2,8000(m/min)で紡糸し、繊度275dtex、48フィラメント、伸度162%の高配向未延伸糸を得た。そして、上記高配向未延伸糸をフリクション仮撚機(ATF12:TMTマシナリー製)を用いてフィードローラから給糸し、加工速度:400m/minでまずホットピン80℃で1.5倍の低倍率延伸を行い、その後、延伸倍率:1.1倍、ヒータ温度:190℃、仮撚係数:30,000で仮撚を行い、その後、交絡圧:0.3MPaでインターレース加工を行い、繊度:167dtex、捲縮率:27%、沸騰水収縮率:6.5%、単糸糸長差:7%、交絡数:132ケ/m、凹部個数:6ヶの加工糸を得た。
Example 2
Polyethylene terephthalate having a hexapave cross section and a titanium oxide content of 0.7% by mass was spun at a spinning speed of 2,8000 (m/min) to obtain a highly oriented undrawn yarn having a fineness of 275 dtex, 48 filaments, and an elongation of 162%. The highly oriented undrawn yarn was then fed from a feed roller using a friction false twisting machine (ATF12, manufactured by TMT Machinery) and first subjected to low-ratio drawing of 1.5 times at a hot pin temperature of 80°C at a processing speed of 400 m/min, followed by false twisting at a draw ratio of 1.1 times, a heater temperature of 190°C, and a false twist coefficient of 30,000, and then interlacing at an entanglement pressure of 0.3 MPa to obtain a textured yarn having a fineness of 167 dtex, a crimp rate of 27%, a boiling water shrinkage rate of 6.5%, a single yarn length difference of 7%, an entanglement number of 132/m, and a number of recesses of 6.

その後、上記糸に撚糸300T/Mを施してから、経糸・緯糸に用いて、エアージェット織機で平織物に製織を行い、次に、得られた製織生地に対して、98℃拡布連続精練、120℃液流リラックス、180℃の中間セット、分散染料を用いた130℃での紺色染色を行い、さらに160℃仕上げセットを施し、加工密度(経糸:110本/2.54cm、緯糸:90本/2.54cm)の製品とした。 The yarn was then twisted at 300T/M and used as the warp and weft to create a plain weave fabric on an air jet loom. The resulting woven fabric was then subjected to continuous open-weave scouring at 98°C, flow relaxation at 120°C, intermediate setting at 180°C, and dyed navy blue at 130°C using a disperse dye, and then finishing setting at 160°C to create a product with a processed density (warp: 110 threads/2.54 cm, weft: 90 threads/2.54 cm).

得られた織物はナチュラルな杢感を有し、ふくらみ感が大きく、落ち着いた光沢外観を有しているものであった。また、繰り返し洗濯後の耐スナッグ性も大変優れており、梳毛調アウター衣料として好適であった。 The resulting fabric had a natural heathered look, a large sense of volume, and a subdued, lustrous appearance. It also had excellent snag resistance even after repeated washing, making it suitable for use as a worsted outer garment.

<実施例3>
酸化チタン含有率2.3質量%、八葉断面のポリエチレンテレフタレートを紡速2,8000(m/min)で紡糸し、繊度275dtex、72フィラメント、伸度158%の高配向未延伸糸を得た。そして、上記高配向未延伸糸をピン仮撚機(TH312:愛機製作所製)を用いてフィードローラから給糸し、加工速度:100m/minでまずホットピン80℃で1.5倍の低倍率延伸を行い、その後、延伸倍率:1.1倍、ヒータ温度:190℃、仮撚係数:33,000で仮撚を行い、その後、交絡圧:0.15MPaでインターレース加工を行い、繊度:167dtex、捲縮率:41%、沸騰水収縮率:4.5%、単糸糸長差:12%、交絡数:58ケ/m、凹部個数:8ヶの加工糸を得た。
Example 3
Polyethylene terephthalate having an eight-lobe cross section and a titanium oxide content of 2.3% by mass was spun at a spinning speed of 2,8000 (m/min) to obtain a highly oriented undrawn yarn having a fineness of 275 dtex, 72 filaments, and an elongation of 158%. The highly oriented undrawn yarn was fed from a feed roller using a pin false twisting machine (TH312, manufactured by Aiki Seisakusho) and first subjected to low-ratio drawing of 1.5 times at a hot pin temperature of 80°C at a processing speed of 100 m/min, then false twisted at a draw ratio of 1.1 times, a heater temperature of 190°C, and a false twist coefficient of 33,000, and then interlaced at an entanglement pressure of 0.15 MPa to obtain a textured yarn having a fineness of 167 dtex, a crimp rate of 41%, a boiling water shrinkage rate of 4.5%, a single yarn length difference of 12%, an entanglement number of 58/m, and a number of recesses of 8.

その後、上記糸を経糸・緯糸に用いて、エアージェット織機で平織物に製織を行い、次に、得られた製織生地に対して、98℃拡布連続精練、120℃液流リラックス、180℃の中間セット、分散染料を用いた130℃での紺色染色を行い、さらに160℃仕上げセットを施し、加工密度(経糸:110本/2.54cm、緯糸:90本/2.54cm)の製品とした。 The yarns were then used as the warp and weft to weave a plain weave fabric on an air jet loom. The resulting woven fabric was then subjected to continuous open-weave scouring at 98°C, flow relaxation at 120°C, intermediate setting at 180°C, and dyed navy blue at 130°C using a disperse dye, and then finishing setting at 160°C to produce a product with a processed density (warp: 110 threads/2.54 cm, weft: 90 threads/2.54 cm).

得られた織物は天然ウール同様のナチュラルな杢感を有し、ふくらみ感が非常に大きく、大変落ち着いた光沢外観を有しているものであった。また、繰り返し洗濯後の耐スナッグ性も優れており、梳毛調アウター衣料として好適であった。 The resulting fabric had a natural heathered look similar to that of natural wool, was very fluffy, and had a very calm, glossy appearance. It also had excellent snag resistance even after repeated washing, making it suitable for use as a worsted outer garment.

<比較例1>
酸化チタン含有率0.7質量%、丸断面のポリエチレンテレフタレートを紡速3,2000(m/min)で紡糸し、繊度265dtex、48フィラメント、伸度142%の高配向未延伸糸を得た。そして、上記高配向未延伸糸をフリクション仮撚機(ATF12:TMTマシナリー製)を用いてフィードローラから給糸し、加工速度:400m/minでまずホットピン75℃で1.45倍の低倍率延伸を行い、その後、延伸倍率:1.1倍、ヒータ温度:200℃、仮撚係数:31,000で仮撚を行い、その後、交絡圧:0.2MPaでインターレース加工を行い、繊度:167dtex、捲縮率:33%、沸騰水収縮率:7.5%、単糸糸長差:3%、交絡数:90ケ/m、凹部個数:1ヶの加工糸を得た。
<Comparative Example 1>
Polyethylene terephthalate having a round cross section and a titanium oxide content of 0.7% by mass was spun at a spinning speed of 3,2000 (m/min) to obtain a highly oriented undrawn yarn having a fineness of 265 dtex, 48 filaments, and an elongation of 142%. The highly oriented undrawn yarn was then fed from a feed roller using a friction false twisting machine (ATF12, manufactured by TMT Machinery) and first subjected to low-ratio drawing of 1.45 times at a hot pin temperature of 75°C at a processing speed of 400 m/min, followed by false twisting at a draw ratio of 1.1 times, a heater temperature of 200°C, and a false twist coefficient of 31,000, and then subjected to interlacing processing at an entanglement pressure of 0.2 MPa to obtain a processed yarn having a fineness of 167 dtex, a crimp rate of 33%, a boiling water shrinkage rate of 7.5%, a single yarn length difference of 3%, an entanglement number of 90/m, and a number of recesses of 1.

その後、上記糸に撚糸300T/Mを施してから、経糸・緯糸に用いて、エアージェット織機で平織物に製織を行い、次に、得られた製織生地に対して、98℃拡布連続精練、120℃液流リラックス、180℃の中間セット、分散染料を用いた130℃での紺色染色を行い、さらに160℃仕上げセットを施し、加工密度(経糸:110本/2.54cm、緯糸:90本/2.54cm)の製品とした。 The yarn was then twisted at 300T/M and used as the warp and weft to create a plain weave fabric on an air jet loom. The resulting woven fabric was then subjected to continuous open-weave scouring at 98°C, flow relaxation at 120°C, intermediate setting at 180°C, and dyed navy blue at 130°C using a disperse dye, and then finishing setting at 160°C to create a product with a processed density (warp: 110 threads/2.54 cm, weft: 90 threads/2.54 cm).

得られた織物は人工的な杢感を有し、ふくらみ感も不足しており、全体的に合繊特有のギラツキ光沢を有するものであった。 The resulting fabric had an artificial heathered look, lacked volume, and had an overall shiny sheen characteristic of synthetic fibers.

<比較例2>
酸化チタン含有率0.7質量%、八葉断面のポリエチレンテレフタレートを紡速3,2000(m/min)で紡糸し、繊度265dtex、48フィラメント、伸度143%の高配向未延伸糸を得た。そして、上記高配向未延伸糸をフリクション仮撚機(ATF12:TMTマシナリー製)を用いてフィードローラから給糸し、加工速度:400m/minで延伸倍率:1.6倍、ヒータ温度:200℃、仮撚係数:31,000で仮撚を行い、その後、交絡圧:0.15MPaでインターレース加工を行い、繊度:167dtex、捲縮率:43%、沸騰水収縮率:6.1%、単糸糸長差:2%、交絡数:65ケ/m、凹部個数:8ヶの加工糸を得た。
<Comparative Example 2>
Polyethylene terephthalate with a titanium oxide content of 0.7% by mass and an eight-lobe cross section was spun at a spinning speed of 3,2000 (m/min) to obtain a highly oriented undrawn yarn with a fineness of 265 dtex, 48 filaments, and an elongation of 143%. The highly oriented undrawn yarn was fed from a feed roller using a friction false twisting machine (ATF12: manufactured by TMT Machinery) and false twisted at a processing speed of 400 m/min, a draw ratio of 1.6 times, a heater temperature of 200° C., and a false twist coefficient of 31,000. Thereafter, interlacing was performed at an interlacing pressure of 0.15 MPa to obtain a processed yarn with a fineness of 167 dtex, a crimp rate of 43%, a boiling water shrinkage rate of 6.1%, a single yarn length difference of 2%, an interlacing number of 65/m, and a number of recesses of 8.

その後、上記糸に撚糸300T/Mを施してから、経糸・緯糸に用いて、エアージェット織機で平織物に製織を行い、次に、得られた製織生地に対して、98℃拡布連続精練、120℃液流リラックス、180℃の中間セット、分散染料を用いた130℃での紺色染色を行い、さらに160℃仕上げセットを施し、加工密度(経糸:110本/2.54cm、緯糸:90本/2.54cm)の製品とした。 The yarn was then twisted at 300T/M and used as the warp and weft to create a plain weave fabric on an air jet loom. The resulting woven fabric was then subjected to continuous open-weave scouring at 98°C, flow relaxation at 120°C, intermediate setting at 180°C, and dyed navy blue at 130°C using a disperse dye, and then finishing setting at 160°C to create a product with a processed density (warp: 110 threads/2.54 cm, weft: 90 threads/2.54 cm).

得られた織物は、落ち着いた光沢を有してはいるが、ふくらみ感が不足しており、杢感も有しておらず、フラットな表面感であった。 The resulting fabric had a subdued luster, but lacked volume and a flat surface with no grain.

<比較例3>
酸化チタン含有率0.7質量%のポリエチレンテレフタレートを、四葉型24孔と八葉型24孔を配列した口金を用い、紡速3,2000(m/min)で紡糸し、トータル繊度264dtex、48フィラメント、伸度141%の高配向未延伸糸を得た。そして、上記高配向未延伸糸をフリクション仮撚機(ATF12:TMTマシナリー製)を用いてフィードローラから給糸し、加工速度:400m/minでまずホットピン74℃で1.38倍の低倍率延伸を行い、その後、延伸倍率:1.15倍、ヒータ温度:130℃、仮撚係数:31,000で仮撚を行い、その後、交絡圧:0.35MPaでインターレース加工を行い、繊度:167dtex、捲縮率:23%、沸騰水収縮率:7.7%、単糸糸長差:16%、交絡数:155ケ/m、凹部個数:4ヶ及び8ヶの複合加工糸を得た。
<Comparative Example 3>
Polyethylene terephthalate having a titanium oxide content of 0.7% by mass was spun at a spinning speed of 3,2000 (m/min) using a spinneret having 24 four-lobe holes and 24 eight-lobe holes arranged, to obtain a highly oriented undrawn yarn having a total fineness of 264 dtex, 48 filaments, and an elongation of 141%. The highly oriented undrawn yarn was then fed from a feed roller using a friction false twisting machine (ATF12, manufactured by TMT Machinery) and first subjected to a low-ratio drawing of 1.38 times at a hot pin temperature of 74°C at a processing speed of 400 m/min, followed by false twisting at a draw ratio of 1.15 times, a heater temperature of 130°C, and a false twist coefficient of 31,000, and then interlacing at an entanglement pressure of 0.35 MPa to obtain a composite textured yarn having a fineness of 167 dtex, a crimp rate of 23%, a boiling water shrinkage rate of 7.7%, a single yarn length difference of 16%, an entanglement number of 155/m, and a number of recesses of 4 and 8.

その後、上記糸を経糸・緯糸に用いて、エアージェット織機で平織物に製織を行い、次に、得られた製織生地に対して、98℃拡布連続精練、120℃液流リラックス、180℃の中間セット、分散染料を用いた130℃での紺色染色を行い、さらに160℃仕上げセットを施し、加工密度(経糸:110本/2.54cm、緯糸:90本/2.54cm)の製品とした。 The yarns were then used as the warp and weft to weave a plain weave fabric on an air jet loom. The resulting woven fabric was then subjected to continuous open-weave scouring at 98°C, flow relaxation at 120°C, intermediate setting at 180°C, and dyed navy blue at 130°C using a disperse dye, and then finishing setting at 160°C to produce a product with a processed density (warp: 110 threads/2.54 cm, weft: 90 threads/2.54 cm).

得られた織物は天然ウール同様のナチュラルな杢感、落ち着いた光沢外観を有しているが、ふくらみ感は不足しており、かつ繰り返し洗濯後は単糸の飛び出しが一部あり、耐スナッグ性は2級であった。 The resulting fabric had the same natural heathered look as natural wool and a subdued glossy appearance, but it lacked volume and fluffiness, and after repeated washing some of the single threads came loose, giving it a grade 2 snag resistance.

<比較例4>
酸化チタン含有率0.7質量%、八葉断面のポリエチレンテレフタレートを紡速3,2000(m/min)で紡糸し、繊度140dtex、36フィラメント、伸度140%の高配向未延伸糸を得た。そして、上記高配向未延伸糸を2本準備し、それぞれを別フィードローラで給糸を行い、フリクション仮撚機(ATF12:TMTマシナリー製)を用いて、加工速度:400m/minで、一方の糸をホットピン75℃で1.5倍の低倍率延伸を行い、もう一方の糸をホットピン110℃で1.7倍の延伸を行い、その後、2本の糸を合流させ、交絡圧:0.25MPaでインターレース加工を行い、その後、延伸倍率:1.05倍、ヒータ温度:2100℃、仮撚係数:31,000で仮撚を行い、繊度:170dtex、捲縮率:8%、沸騰水収縮率:5.3%、単糸糸長差:23%、交絡数:97ケ/m、凹部個数:8ヶの複合加工糸を得た。
<Comparative Example 4>
Polyethylene terephthalate having an eight-lobe cross section and a titanium oxide content of 0.7% by mass was spun at a spinning speed of 3,2000 (m/min) to obtain a highly oriented undrawn yarn having a fineness of 140 dtex, 36 filaments and an elongation of 140%. Then, two of the highly oriented undrawn yarns were prepared, and each was fed by a separate feed roller. Using a friction false twisting machine (ATF12: manufactured by TMT Machinery), one of the yarns was drawn at a low magnification of 1.5 times at a hot pin of 75°C and the other yarn was drawn at a hot pin of 1.7 times at a processing speed of 400 m/min. Thereafter, the two yarns were joined together and interlaced at an entanglement pressure of 0.25 MPa. Thereafter, false twisting was performed at a draw ratio of 1.05 times, a heater temperature of 2100°C, and a false twist coefficient of 31,000 to obtain a composite textured yarn having a fineness of 170 dtex, a crimp rate of 8%, a boiling water shrinkage rate of 5.3%, a single yarn length difference of 23%, an entanglement number of 97 pieces/m, and a number of recesses of 8.

その後、上記糸に撚糸1000T/Mを施し、経糸・緯糸に用いて、エアージェット織機で平織物に製織を行い、次に、得られた製織生地に対して、98℃拡布連続精練、120℃液流リラックス、180℃の中間セット、分散染料を用いた130℃での紺色染色を行い、さらに160℃仕上げセットを施し、加工密度(経糸:110本/2.54cm、緯糸:90本/2.54cm)の製品とした。 The yarn was then twisted at 1000T/M and used as the warp and weft to create a plain weave fabric on an air jet loom. The resulting woven fabric was then subjected to continuous open-weave scouring at 98°C, flow relaxation at 120°C, intermediate setting at 180°C, and dyed navy blue at 130°C using a disperse dye, and then finishing setting at 160°C to create a product with a processed density (warp: 110 threads/2.54 cm, weft: 90 threads/2.54 cm).

得られた織物はナチュラルな杢感、落ち着いた光沢外観、大きなふくらみ感を有しているが、繰り返し洗濯後は単糸の飛び出しが目立ち、耐スナッグ性が1級であった。 The resulting fabric had a natural heathered look, a subdued glossy appearance, and a large sense of volume, but after repeated washing, the single threads were noticeably sticking out, and the snag resistance was grade 1.

<比較例5>
酸化チタン含有率0.7質量%のポリエチレンテレフタレート及び酸化チタン含有率0.1質量%のポリトリメチレンテレフタレートを50:50の質量割合でサイドバイドサイド型にバイメタル複合し、紡速3,1000(m/min)で紡糸し、繊度268dtex、48フィラメント、伸度165%の高配向未延伸糸を得た。そして、上記高配向未延伸糸をフリクション仮撚機(ATF12:TMTマシナリー製)を用いてフィードローラから給糸し、加工速度:400m/minでまずホットピン75℃で1.5倍の低倍率延伸を行い、その後、延伸倍率:1.1倍、ヒータ温度:200℃、仮撚係数:32,000で仮撚を行い、その後、交絡圧:0.2MPaでインターレース加工を行い、繊度:167dtex、捲縮率:48%、沸騰水収縮率:7.5%、単糸糸長差:3%、交絡数:87ケ/m、凹部個数:2ヶの加工糸を得た。
<Comparative Example 5>
Polyethylene terephthalate having a titanium oxide content of 0.7% by mass and polytrimethylene terephthalate having a titanium oxide content of 0.1% by mass were bimetallicly combined in a side-by-side type in a mass ratio of 50:50 and spun at a spinning speed of 3,1000 (m/min) to obtain a highly oriented undrawn yarn having a fineness of 268 dtex, 48 filaments and an elongation of 165%. The highly oriented undrawn yarn was then fed from a feed roller using a friction false twisting machine (ATF12, manufactured by TMT Machinery) and first subjected to a low-ratio drawing of 1.5 times at a hot pin temperature of 75°C at a processing speed of 400 m/min, followed by false twisting at a draw ratio of 1.1 times, a heater temperature of 200°C, and a false twist coefficient of 32,000, and then interlacing at an entanglement pressure of 0.2 MPa to obtain a textured yarn having a fineness of 167 dtex, a crimp rate of 48%, a boiling water shrinkage rate of 7.5%, a single yarn length difference of 3%, an entanglement number of 87/m, and a number of recesses of 2.

その後、上記糸に撚糸300T/Mを施し、経糸・緯糸に用いて、エアージェット織機で平織物に製織を行い、次に、得られた製織生地に対して、98℃拡布連続精練、120℃液流リラックス、180℃の中間セット、分散染料を用いた130℃での紺色染色を行い、160℃仕上げセットを施し、加工密度(経糸:110本/2.54cm、緯糸:90本/2.54cm)の製品とした。 The yarn was then twisted at 300T/M and used as the warp and weft to create a plain weave fabric on an air jet loom. The resulting woven fabric was then subjected to continuous open-weave scouring at 98°C, flow relaxation at 120°C, intermediate setting at 180°C, and dyed navy blue at 130°C using a disperse dye, and finished setting at 160°C to create a product with a processed density (warp: 110 threads/2.54 cm, weft: 90 threads/2.54 cm).

得られた織物はナチュラルな杢感、非常に大きなふくらみ感を有していたが、局所的に合繊特有のギラツキ光沢を有するものであった。また、かつ繰り返し洗濯後は単糸の飛び出しがあり、耐スナッグ性は2級であった。 The resulting fabric had a natural heathered look and a very fluffy feel, but also had a shiny luster characteristic of synthetic fibers in some places. Furthermore, after repeated washing, single threads came loose, and the snag resistance was grade 2.

Figure 0007521255000001
Figure 0007521255000001

本発明により得られる仮撚糸及び織編物は、アウター衣料としてカジュアルからフォーマル、スポーツ衣料まで幅広く使用される。特に婦人洋装のスーツ、ブレザー、コート、スカート、パンツ、さらには紳士用アウター、ボトム、ジャケットなどの用途に好適に用いられる。 The false-twisted yarn and woven/knitted fabrics obtained by the present invention are widely used as outerwear for casual, formal and sportswear. They are particularly suitable for use in women's Western-style suits, blazers, coats, skirts and pants, as well as men's outerwear, bottoms and jackets.

S1 直線T1と繊維横断面輪郭との接点
S2 直線T1と繊維横断面輪郭との接点
T1 繊維横断面輪郭にS1およびS2で接する直線
U 接点S1および接点S2の間の凹部
S1: Point of contact S2 between the line T1 and the fiber cross-sectional profile; Point of contact T1 between the line T1 and the fiber cross-sectional profile; Line U tangent to the fiber cross-sectional profile at S1 and S2; Recess between the points of contact S1 and S2

Claims (6)

長さ方向に太細ムラを有するポリエステル仮撚糸であって、ホモポリマーからなり、無機微粒子含有率が0.3~3.0質量%であり、沸騰水収縮率が4~9%であり、捲縮率が26~45%であり、単糸断面が6~10ヶの凹部を有し1種類の糸による局所的単糸糸長差が5~20%であることを特徴とするポリエステル仮撚糸。 The polyester false-twisted yarn has thickness unevenness in the length direction, is made of a homopolymer, has an inorganic fine particle content of 0.3 to 3.0 mass%, a boiling water shrinkage rate of 4 to 9%, a crimp rate of 26 to 45% , has 6 to 10 recesses in a single yarn cross section , and has a local single yarn length difference of 5 to 20% for one type of yarn . 前記ホモポリマーがポリエチレンテレフタレートである、請求項1に記載にポリエステル仮撚糸。2. The polyester false twist yarn of claim 1, wherein said homopolymer is polyethylene terephthalate. 単糸間で太細ムラに位相差があることを特徴とする、請求項1または2に記載にポリエステル仮撚糸。 3. The polyester false twist yarn according to claim 1 , wherein there is a phase difference in the thick/thin unevenness between single yarns. 交絡度が50~150ヶ/mであることを特徴とする、請求項1~のいずれかに記載のポリエステル仮撚糸。 4. The polyester false twist yarn according to claim 1 , wherein the degree of entanglement is 50 to 150 pcs/m. 請求項1~のいずれかに記載の仮撚糸を用いたことを特徴とする織編物。 A woven or knitted fabric using the false twist yarn according to any one of claims 1 to 4 . 洗濯20回後のJIS L 1058法:2011 7.2によるスナッグ試験の結果が3級以上であることを特徴とする、請求項に記載の織編物。 The woven or knitted fabric according to claim 5 , characterized in that the result of a snag test according to JIS L 1058: 2011 7.2 after 20 washes is grade 3 or higher.
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