JP7483416B2 - 着色感光性樹脂組成物、カラーフィルタ、及び表示装置用部材又は表示装置 - Google Patents
着色感光性樹脂組成物、カラーフィルタ、及び表示装置用部材又は表示装置 Download PDFInfo
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- JP7483416B2 JP7483416B2 JP2020039964A JP2020039964A JP7483416B2 JP 7483416 B2 JP7483416 B2 JP 7483416B2 JP 2020039964 A JP2020039964 A JP 2020039964A JP 2020039964 A JP2020039964 A JP 2020039964A JP 7483416 B2 JP7483416 B2 JP 7483416B2
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- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 6
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 6
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- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 6
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
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- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
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- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- SHBDDIJUSNNBLQ-UHFFFAOYSA-M sodium;3-[[4-[(2-chlorophenyl)-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)Cl)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SHBDDIJUSNNBLQ-UHFFFAOYSA-M 0.000 description 1
- RWVGQQGBQSJDQV-UHFFFAOYSA-M sodium;3-[[4-[(e)-[4-(4-ethoxyanilino)phenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]-2-methylcyclohexa-2,5-dien-1-ylidene]methyl]-n-ethyl-3-methylanilino]methyl]benzenesulfonate Chemical compound [Na+].C1=CC(OCC)=CC=C1NC1=CC=C(C(=C2C(=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=2C(=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=C1 RWVGQQGBQSJDQV-UHFFFAOYSA-M 0.000 description 1
- UWGCNDBLFSEBDW-UHFFFAOYSA-M sodium;4-[[4-(diethylamino)phenyl]-(4-diethylazaniumylidenecyclohexa-2,5-dien-1-ylidene)methyl]naphthalene-2,7-disulfonate Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C2=CC=C(C=C2C=C(C=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 UWGCNDBLFSEBDW-UHFFFAOYSA-M 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000005092 sublimation method Methods 0.000 description 1
- 150000003458 sulfonic acid derivatives Chemical class 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000004992 toluidines Chemical class 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 235000019235 yellow 2G Nutrition 0.000 description 1
- 239000001043 yellow dye Substances 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
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- Materials For Photolithography (AREA)
- Liquid Crystal (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Optical Filters (AREA)
Description
また、本開示に係る発明の他の目的は、上記の特性を有する着色感光性樹脂組成物から形成されるカラーフィルタ、及び該カラーフィルタを備えた表示装置用部材又は表示装置を提供することにある。
該アルカリ可溶性樹脂が、不飽和カルボン酸又はその無水物に由来する構成単位(A)と、下記式(1)
で表される化合物に由来する構成単位(B)とを含む共重合体であって、示差走査熱量計を用いて、5℃/分の速度で昇温した際に現れる発熱ピークトップ温度が180~220℃である共重合体である着色感光性樹脂組成物を提供する。
(c1)アルキル基で置換されていてもよいスチレン
(c2)N-置換マレイミド
(c3)N-ビニル化合物
(c4)下記式(2)
で表される不飽和カルボン酸誘導体
本開示においては、アルカリ可溶性樹脂として、不飽和カルボン酸又はその無水物に由来する構成単位(A)と、前記式(1)で表される化合物に由来する構成単位(B)とを含む共重合体であって、示差走査熱量計を用いて、5℃/分の速度で昇温した際に現れる発熱ピークトップ温度が180~220℃である共重合体を用いる。前記共重合体は、さらに、前記(c1)~(c4)からなる群より選択された少なくとも1つの化合物に由来する構成単位(C)を含んでいてもよい。また、さらに構成単位(A)~(C)以外の構成単位として後述の構成単位(D)を含んでいてもよい。
構成単位(A)は不飽和カルボン酸又はその酸無水物(a)を共重合に付すことにより共重合体に導入することができる。
構成単位(C)は、アルキル基で置換されていてもよいスチレン(c1)、N-置換マレイミド(c2)、N-ビニル化合物(c3)、及び前記式(2)で表される不飽和カルボン酸誘導体(c4)からなる群より選択された少なくとも1つの化合物に由来する構成単位である。構成単位(C)は硬化物(硬化皮膜)に硬度を付与する機能や、共重合反応を円滑化する機能、溶媒への溶解性を高める機能、基材への密着性を高める機能などを有する。
アルキル基で置換されていてもよいスチレン(c1)におけるアルキル基は特に限定されないが、例えば、メチル基、エチル基、プロピル基、イソプロピル基、ブチル基、イソブチル基、t-ブチル基、ヘキシル基等の炭素数1~7のアルキル基が挙げられる。これらの中でも、メチル基又はエチル基等の炭素数1~4のアルキル基が好ましく、メチル基がより好ましい。前記アルキル基はスチレンのビニル基及びベンゼン環のいずれに結合していてもよい。
N-ビニル化合物(c3)としては特に限定されないが、例えば、N-ビニルホルムアミド、N-ビニルアセトアミド、N-ビニルイソプロピルアミド、N-ビニル-N-メチルアセトアミド、N-ビニルピロリドン、N-ビニルカルバゾール、N-ビニルピペリドン、N-ビニルカプロラクタム等が挙げられる。N-ビニル化合物(c3)は、単独で又は2種以上を組み合わせて使用できる。
本開示における前記共重合体は、前記構成単位(A)~(C)以外の構成単位(D)を含んでいてもよい。構成単位(D)として、例えば、(メタ)アクリルアミド、(メタ)アクリルニトリルに由来する構成単位が挙げられる。
本開示における前記共重合体は、不飽和カルボン酸又はその無水物(a)と、環上にエポキシ基を有する多環式脂肪族基と不飽和結合を有する基とを有する化合物(b)と、必要に応じて、前記(c1)~(c4)からなる群より選択された少なくとも1つの化合物と、前記構成単位(D)に対応する化合物とを共重合に付すことにより製造することができる。以下、不飽和カルボン酸又はその無水物(a)等の共重合体に導入し得る化合物を「単量体」と総称することがある。
本開示において、色材(着色剤)としては着色性を有するものであればよく、カラーフィルタ等の用途に応じて色彩や材質を適宜選択することができる。具体的には、色材として、顔料、染料及び天然色素の何れをも使用することができるが、カラーフィルタ用途には高い色純度、輝度、コントラスト等が求められることから、顔料及び/又は染料が 好ましい。
本開示において、光重合性化合物としては、特に限定されないが、例えば、多官能ビニル化合物、多官能チオール化合物、多官能エポキシ化合物が挙げられる。
本開示において、光重合開始剤としては、特に限定されないが、光ラジカル重合開始剤、光カチオン重合開始剤が挙げられる。
溶剤としては、例えば、エーテル(ジエチルエーテル;エチレングリコールモノ又はジアルキルエーテル、ジエチレングリコールモノ又はジアルキルエーテル、プロピレングリコールモノ又はジアルキルエーテル、プロピレングリコールモノ又はジアリールエーテル、ジプロピレングリコールモノ又はジアルキルエーテル、トリプロピレングリコールモノ又はジアルキルエーテル、1,3-プロパンジオールモノ又はジアルキルエーテル、1,3-ブタンジオールモノ又はジアルキルエーテル、1,4-ブタンジオールモノ又はジアルキルエーテル、グリセリンモノ,ジ又はトリアルキルエーテル等のグリコールエーテル類等の鎖状エーテル;テトラヒドロフラン、ジオキサン等の環状エーテル等)、エステル(酢酸メチル、酢酸エチル、酢酸ブチル、酢酸イソアミル、乳酸エチル、3-メトキシプロピオン酸メチル、3-エトキシプロピオン酸エチル、C5-6シクロアルカンジオールモノ又はジアセテート、C5-6シクロアルカンジメタノールモノ又はジアセテート等のカルボン酸エステル類;エチレングリコールモノアルキルエーテルアセテート、エチレングリコールモノ又はジアセテート、ジエチレングリコールモノアルキルエーテルアセテート、ジエチレングリコールモノ又はジアセテート、プロピレングリコールモノアルキルエーテルアセテート、プロピレングリコールモノ又はジアセテート、ジプロピレングリコールモノアルキルエーテルアセテート、ジプロピレングリコールモノ又はジアセテート、1,3-プロパンジオールモノアルキルエーテルアセテート、1,3-プロパンジオールモノ又はジアセテート、1,3-ブタンジオールモノアルキルエーテルアセテート、1,3-ブタンジオールモノ又はジアセテート、1,4-ブタンジオールモノアルキルエーテルアセテート、1,4-ブタンジオールモノ又はジアセテート、グリセリンモノ,ジ又はトリアセテート、グリセリンモノ又はジC1-4アルキルエーテルジ又はモノアセテート、トリプロピレングリコールモノアルキルエーテルアセテート、トリプロピレングリコールモノ又はジアセテート等のグリコールアセテート類又はグリコールエーテルアセテート類等)、ケトン(アセトン、メチルエチルケトン、メチルイソブチルケトン、シクロヘキサノン、3,5,5-トリメチル-2-シクロヘキセン-1-オン等)などが挙げられる。これらの溶剤は、単独で用いてもよく、2種以上を混合して用いてもよい。
本開示に係るカラーフィルタは、前記着色感光性樹脂組成物から形成された着色パターンを備えるものである。カラーフィルタは、例えば、基板上に前記着色感光性樹脂組成物を用いて着色パターンを形成する工程、及び前記着色パターンをポストベークする工程を経て製造することができる。
本開示の表示装置用部材又は表示装置は、前記のカラーフィルタを備えている。前記表示装置用部材として、例えば、カラー液晶表示素子が挙げられる。また、前記表示装置としては、例えば、カラー液晶表示装置が挙げられる。カラー液晶表示素子やカラー液晶表示の構造としては、特に限定されず、適宜の構造をとることができる。
装置:検出器:RID-20A(島津製作所)
ポンプ:LC-20AD(島津製作所)
システムコントローラー:CBM-20Alite(島津製作所)
デガッサー:DGU-20A3(島津製作所)
オートインジェクター:SIL-20A HT(島津製作所)
カラム:Shodex KF-806L(昭和電工)
溶離液:THF(テトラヒドロフラン)0.8ml/min
温度:オーブン:40℃、RI:40℃
検出器:RI
33.7gの5-ノルボルネン-2-メタノール、41.3gのトリエチルアミン、及び6.5mgのメトキノンを57.2gのTHF(テトラヒドロフラン)に加えた混合溶液に対し、42.4gのメタクリル酸クロリドを、内温を20℃以下に維持しながら40分かけて滴下した後、20℃で4時間撹拌した。ガスクロマトグラフィーで原料である5-ノルボルネン-2-メタノールの消失を確認した後に、100gの酢酸エチルと84.0gの水を加えた。分液後、94.8gの10%水酸化ナトリウム水溶液で洗浄し、68.0gの水で3回洗浄した。得られた有機相を40℃、15Torrの条件で濃縮することにより、48.3gの5-ノルボルネン-2-メチルアクリレート粗生成物を得た。前記粗生成物の純度は93%、収率は86%であった。
還流冷却器、滴下ロート、及び撹拌機を備えた1Lのフラスコ内に窒素を適量流して窒素雰囲気とし、前記フラスコ内に150重量部のプロピレングリコールモノメチルエーテルアセテートを入れ、撹拌しながら80℃まで加熱した。その後、7重量部の2,2’-アゾビスイソブチロニトリル(AIBN)を、30重量部のプロピレングリコールモノメチルエーテルアセテートを用いて洗い流しながら加えた。次いで、該フラスコ内に、単量体としての11重量部のアクリル酸(AA)及び89重量部のモノマーB1と、20重量部のプロピレングリコールモノメチルエーテルアセテートとの混合溶液を、滴下ポンプを用いて約4時間かけて滴下した。単量体の滴下が終了した後、4時間、同温度に保持し、その後室温まで冷却して、固形分34.6重量%の共重合体含有溶液を得た。生成した共重合体の重量平均分子量Mwは19,000、分散度は3.47であった。
単量体として11重量部のアクリル酸(AA)、79重量部のモノマーB1、及び10重量部のスチレン(ST)を用いたこと以外は製造例1と同様の操作を行うことで、固形分33.8重量%の共重合体含有溶液を得た。生成した共重合体の重量平均分子量Mwは17,000、分散度は3.33であった。
単量体として11重量部のアクリル酸(AA)、79重量部のモノマーB1、及び10重量部のメタクリル酸メチル(MMA)を用いたこと以外は製造例1と同様の操作を行うことで、固形分34.2重量%の共重合体含有溶液を得た。生成した共重合体の重量平均分子量Mwは18,500、分散度は3.41であった。
単量体として11重量部のアクリル酸(AA)、79重量部のモノマーB1、及び10重量部のシクロヘキシルマレイミド(CHMI)を用いたこと以外は製造例1と同様の操作を行うことで、固形分34.4重量%の共重合体含有溶液を得た。生成した共重合体の重量平均分子量Mwは18,000、分散度は3.40であった。
単量体として11重量部のアクリル酸(AA)、79重量部のモノマーB1、及び10重量部のN-ビニルピロリドン(VP)を用いたこと以外は製造例1と同様の操作を行うことで、固形分34.4重量%の共重合体含有溶液を得た。生成した共重合体の重量平均分子量Mwは17,500、分散度は3.38であった。
還流冷却器、滴下ロート及び撹拌機を備えた1Lのフラスコ内に窒素を適量流して窒素雰囲気とし、150重量部のプロピレングリコールモノメチルエーテルアセテートを入れ、撹拌しながら65℃まで加熱した。その後、14重量部の2,2’-アゾビス(2,4-ジメチルバレロニトリル)を30重量部のプロピレングリコールモノメチルエーテルアセテートで洗い流しながら加えた。次いで、該フラスコ内に、単量体として11重量部のアクリル酸(AA)、79重量部のグリシジルメタクリレート(GMA)、10重量部のメタクリル酸メチル(MMA)を20重量部のプロピレングリコールモノメチルエーテルアセテートに溶解した溶液を、滴下ポンプを用いて約4時間かけて滴下した。単量体の滴下が終了した後、約4時間同温度に保持し、その後室温まで冷却して、固形分33.8重量%の共重合体含有溶液を得た。生成した共重合体の重量平均分子量Mwは16,000、分散度は3.32であった。
単量体として11重量部のアクリル酸(AA)、79重量部の3,4-エポキシシクロヘキシルメチルメタクリレート(サイクロマーM100)、10重量部のメタクリル酸メチル(MMA)を用いたこと以外は製造例6と同様の操作を行い、固形分33.4重量%の共重合体含有溶液を得た。生成した共重合体の重量平均分子量Mwは16,000、分散度は3.30であった。
単量体として11重量部のアクリル酸(AA)、89重量部の3,4-エポキシトリシクロ[5.2.1.02,6]デカン-9-イルアクリレートと3,4-エポキシトリシクロ[5.2.1.02,6]デカン-8-イルアクリレートの混合物(モノマーB2)を用いたこと以外は製造例1と同様の操作を行い、固形分34.1重量%の共重合体含有溶液を得た。生成した共重合体の重量平均分子量Mwは18,000、分散度は3.43であった。
色材として顔料のC.I.ピグメントレッド254を7.7g、分散剤としてDISPERBYK-2000を3.1g、溶剤としてMMPGACを36.0gそれぞれ容器にはかり取り、さらに径1.0mmのジルコニアビーズ45gを加え、フタをした。これをペイントシェーカーで3時間振とうし、3時間後、顔料分散液とジルコニアビーズを分別し、0.5mmのジルコニアビーズ45gを加え、ペイントシェーカーでさらに3時間振とうした。その後、顔料分散液とジルコニアビーズを分別し、0.3mmのジルコニアビーズ45gを加え、ペイントシェーカーでさらに3時間振とうした後、ジルコニアビーズを分別し顔料分散液を得た。
得られた顔料分散液4.68gに対し、アルカリ可溶性樹脂として、上記製造例1で得られた共重合体を、共重合体含有溶液として8.09g、光重合性化合物としてDPHAを2.25g、光重合開始剤として1-ヒドロキシシクロヘキシルフェニルケトンを0.20g、溶剤としてMMPGACを15.2gをそれぞれ容器にはかり取り30分間撹拌することで、着色感光性樹脂組成物1を調製した。
アルカリ可溶性樹脂として、上記製造例2で得られた共重合体を、共重合体含有溶液として8.09g用いた以外は、実施例1と同様の操作を行い、着色感光性樹脂組成物2を調製した。
アルカリ可溶性樹脂として、上記製造例3で得られた共重合体を、共重合体含有溶液として8.09g用いた以外は、実施例1と同様の操作を行い、着色感光性樹脂組成物3を調製した。
アルカリ可溶性樹脂として、上記製造例4で得られた共重合体を、共重合体含有溶液として8.09g用いた以外は、実施例1と同様の操作を行い、着色感光性樹脂組成物4を調製した。
アルカリ可溶性樹脂として、上記製造例5で得られた共重合体を、共重合体含有溶液として8.09g用いた以外は、実施例1と同様の操作を行い、着色感光性樹脂組成物5を調製した。
アルカリ可溶性樹脂として、上記製造例6で得られた共重合体を、共重合体含有溶液として8.09g用いた以外は、実施例1と同様の操作を行い、着色感光性樹脂組成物6を調製した。
アルカリ可溶性樹脂として、上記製造例7で得られた共重合体を、共重合体含有溶液として8.09g用いた以外は、実施例1と同様の操作を行い、着色感光性樹脂組成物7を調製した。
アルカリ可溶性樹脂として、上記製造例8で得られた共重合体を、共重合体含有溶液として8.09g用いた以外は、実施例1と同様の操作を行い、着色感光性樹脂組成物8を調製した。
実施例及び比較例で得られた各着色感光性樹脂組成物を用いて以下の評価試験を行った。結果を表3に示す。
実施例及び比較例で得られた着色感光性樹脂組成物を40℃のオーブンで1週間保管した。重合直後の粘度と40℃で1週間保管後の粘度を測定した。粘度増加率を以下の計算式で算出した。なお、粘度(単位:mPa・s)は、粘度計(商品名「LVDV2T」、ブルックフィールド社製)を用いて、回転数60、温度:23℃の条件で測定される。
P:重合直後の粘度、Q:40℃で1週間保管した後の粘度
粘度増加率={(Q/P)×100}-100
ガラス板に実施例及び比較例で得られた着色感光性樹脂組成物をスピンコーターで塗布した後、200℃で30分間加熱硬化させることで試験片を作製した。硬化後の塗膜の厚みは2μmであった。
試験片の調製において、硬化温度を230℃としたこと以外は耐溶剤性試験-1と同様にして、硬化物の耐溶剤性試験を行った。
モノマーB1:3-オキサトリシクロ[3.2.1.02,4]オクタンー6-イルメチルメタクリレート(参考例1を参照)
GMA:グリシジルメタクリレート(日油(株)製)
サイクロマーM100:3,4-エポキシシクロヘキシルメチルメタクリレート((株)ダイセル製)
モノマーB2:3,4-エポキシトリシクロ[5.2.1.02,6]デカン-9-イルアクリレートと3,4-エポキシトリシクロ[5.2.1.02,6]デカン-8-イルアクリレートの混合物(商品名「E-DCPA」、(株)ダイセル製)
ST:スチレン(富士フイルム和光純薬(株)製)
MMA:メタクリル酸メチル(富士フイルム和光純薬(株)製)
CHMI:シクロヘキシルマレイミド(日本触媒(株)製)
VP:N-ビニルピロリドン(東京化成工業(株)製)
MMPGAC:プロピレングリコールモノメチルエーテルアセテート((株)ダイセル製)
PR 254:C.I.ピグメントレッド254(東京化成工業(株)製)
DISPERBYK-2000:アミン価4mgKOH/g、不揮発分40%(ビックケミー・ジャパン製)
DHPA:ジペンタエリスリトールヘキサアクリレート(商品名「KAYARAD DPHA」;日本化薬(株)製)
1-ヒドロキシシクロヘキシルフェニルケトン(富士フイルム和光純薬(株)製)
Claims (5)
- アルカリ可溶性樹脂と、色材、光重合性化合物、光重合開始剤および溶剤を含み、
該アルカリ可溶性樹脂が、不飽和カルボン酸又はその無水物に由来する構成単位(A)と、下記式(1)
で表される化合物に由来する構成単位(B)とを含む共重合体であって、前記共重合体の全構成単位に対する前記構成単位(A)の含有量が3~40重量%、前記構成単位(B)の含有量が60~95重量%であり、示差走査熱量計を用いて、5℃/分の速度で昇温した際に現れる発熱ピークトップ温度が180~220℃である共重合体である着色感光性樹脂組成物。 - 前記色材は、顔料及び/又は染料である請求項1又は2に記載の着色感光性樹脂組成物。
- 請求項1~3のいずれか1項に記載の着色感光性樹脂組成物から形成されるカラーフィルタ。
- 請求項4記載のカラーフィルタを備える表示装置用部材又は表示装置。
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JP2011133610A (ja) | 2009-12-24 | 2011-07-07 | Seiko Epson Corp | カラーフィルター用インク、カラーフィルター用インクセット、カラーフィルター、画像表示装置および電子機器 |
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