JP7465573B2 - Hair dye composition containing hydroxytyrosol - Google Patents
Hair dye composition containing hydroxytyrosol Download PDFInfo
- Publication number
- JP7465573B2 JP7465573B2 JP2022182174A JP2022182174A JP7465573B2 JP 7465573 B2 JP7465573 B2 JP 7465573B2 JP 2022182174 A JP2022182174 A JP 2022182174A JP 2022182174 A JP2022182174 A JP 2022182174A JP 7465573 B2 JP7465573 B2 JP 7465573B2
- Authority
- JP
- Japan
- Prior art keywords
- extract
- hair
- weight
- hair dye
- dye composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- JUUBCHWRXWPFFH-UHFFFAOYSA-N Hydroxytyrosol Chemical compound OCCC1=CC=C(O)C(O)=C1 JUUBCHWRXWPFFH-UHFFFAOYSA-N 0.000 title claims description 90
- 239000000118 hair dye Substances 0.000 title claims description 58
- 239000000203 mixture Substances 0.000 title claims description 55
- 229940095066 hydroxytyrosol Drugs 0.000 title claims description 26
- 235000003248 hydroxytyrosol Nutrition 0.000 title claims description 26
- 244000299461 Theobroma cacao Species 0.000 claims description 56
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 51
- 241000405414 Rehmannia Species 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
- 235000005764 Theobroma cacao ssp. cacao Nutrition 0.000 claims description 27
- 235000005767 Theobroma cacao ssp. sphaerocarpum Nutrition 0.000 claims description 27
- 235000001046 cacaotero Nutrition 0.000 claims description 27
- 239000008213 purified water Substances 0.000 claims description 26
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 25
- 239000001509 sodium citrate Substances 0.000 claims description 25
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 25
- 229940094952 green tea extract Drugs 0.000 claims description 22
- 235000020688 green tea extract Nutrition 0.000 claims description 22
- 239000006000 Garlic extract Substances 0.000 claims description 19
- 235000020706 garlic extract Nutrition 0.000 claims description 19
- 241001107116 Castanospermum australe Species 0.000 claims description 17
- 235000021279 black bean Nutrition 0.000 claims description 17
- 229940069765 bean extract Drugs 0.000 claims description 15
- 244000017020 Ipomoea batatas Species 0.000 claims 1
- 235000002678 Ipomoea batatas Nutrition 0.000 claims 1
- 235000013399 edible fruits Nutrition 0.000 claims 1
- 210000004209 hair Anatomy 0.000 description 48
- 238000004043 dyeing Methods 0.000 description 39
- 239000000843 powder Substances 0.000 description 36
- 235000009470 Theobroma cacao Nutrition 0.000 description 29
- 230000000052 comparative effect Effects 0.000 description 28
- 244000269722 Thea sinensis Species 0.000 description 24
- 235000006468 Thea sinensis Nutrition 0.000 description 21
- 244000068988 Glycine max Species 0.000 description 20
- 235000010469 Glycine max Nutrition 0.000 description 20
- 240000002234 Allium sativum Species 0.000 description 19
- 238000002474 experimental method Methods 0.000 description 19
- 235000004611 garlic Nutrition 0.000 description 19
- GGNQRNBDZQJCCN-UHFFFAOYSA-N benzene-1,2,4-triol Chemical compound OC1=CC=C(O)C(O)=C1 GGNQRNBDZQJCCN-UHFFFAOYSA-N 0.000 description 14
- 238000000034 method Methods 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 230000006378 damage Effects 0.000 description 8
- 210000004761 scalp Anatomy 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000002244 precipitate Substances 0.000 description 7
- 238000001556 precipitation Methods 0.000 description 7
- 229940079990 rubus coreanus fruit extract Drugs 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- 231100000640 hair analysis Toxicity 0.000 description 6
- 238000007654 immersion Methods 0.000 description 6
- 239000008399 tap water Substances 0.000 description 6
- 235000020679 tap water Nutrition 0.000 description 6
- 238000001914 filtration Methods 0.000 description 5
- 239000001508 potassium citrate Substances 0.000 description 5
- 229960002635 potassium citrate Drugs 0.000 description 5
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 5
- 235000011082 potassium citrates Nutrition 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 4
- LUMVCLJFHCTMCV-UHFFFAOYSA-M potassium;hydroxide;hydrate Chemical compound O.[OH-].[K+] LUMVCLJFHCTMCV-UHFFFAOYSA-M 0.000 description 4
- 239000002453 shampoo Substances 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 235000009569 green tea Nutrition 0.000 description 3
- NAJVRARAUNYNDX-UHFFFAOYSA-N picamilon Chemical compound OC(=O)CCCNC(=O)C1=CC=CN=C1 NAJVRARAUNYNDX-UHFFFAOYSA-N 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 241001618264 Rubus coreanus Species 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 210000001519 tissue Anatomy 0.000 description 2
- FZIPCQLKPTZZIM-UHFFFAOYSA-N 2-oxidanylpropane-1,2,3-tricarboxylic acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O.OC(=O)CC(O)(C(O)=O)CC(O)=O FZIPCQLKPTZZIM-UHFFFAOYSA-N 0.000 description 1
- 241001116389 Aloe Species 0.000 description 1
- 241000512259 Ascophyllum nodosum Species 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 244000111489 Gardenia augusta Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 235000002789 Panax ginseng Nutrition 0.000 description 1
- 244000046146 Pueraria lobata Species 0.000 description 1
- 235000010575 Pueraria lobata Nutrition 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000011399 aloe vera Nutrition 0.000 description 1
- -1 black red ginseng Natural products 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 229940099112 cornstarch Drugs 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000003724 hair brightness Effects 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 230000003700 hair damage Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 230000005722 itchiness Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 210000003625 skull Anatomy 0.000 description 1
- 235000020712 soy bean extract Nutrition 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Cosmetics (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Mycology (AREA)
- Microbiology (AREA)
- Botany (AREA)
- Biotechnology (AREA)
- Emergency Medicine (AREA)
Description
本発明は、ヒドロキシチロソールを含有する染毛用組成物に係り、より詳細には、人体に無害であり、染毛力に優れ、様々な環境にさらされても長期間にわたって染毛状態に変化がほとんどなく、頻繁な使用でも頭皮や毛髪を傷つけない染毛用組成物に関する。 The present invention relates to a hair dye composition containing hydroxytyrosol, and more specifically, to a hair dye composition that is harmless to the human body, has excellent hair dyeing power, shows little change in the dyed hair condition over a long period of time even when exposed to various environments, and does not damage the scalp or hair even with frequent use.
毛髪は、太陽光、雨、風、寒さまたは外部衝撃などから人間の頭蓋骨と頭皮部分を保護すると同時に、様々な色や形で髪の形態に変化を加えることで個人の個性を表現する手段にもなる非常に重要な身体器官であり、皮膚組織の一種である。 Hair is a very important bodily organ and a type of skin tissue that protects the human skull and scalp from sunlight, rain, wind, cold, and external shocks, while also allowing individuals to express their individuality by changing the shape of their hair in various colors and shapes.
このような毛髪は、皮膚の表皮組織などのように一生伸び続けるという特性があり、年齢を重ねるにつれて毛髪が細くなったり、総本数が徐々に減少したりすることもあり、ある年齢になると、それぞれの個性的な髪の色が徐々に白や灰色に変化する。 These hairs have the characteristic of continuing to grow throughout life, like the epidermal tissue of the skin. As we age, the hairs may thin and the total number of hairs may gradually decrease, and at a certain age, the unique hair color of each individual will gradually change to white or gray.
そのため、加齢により白や灰色に変色した毛髪を特定の色に染めたり、このように老化に伴う毛髪の変色がなくても、各自の個性を表現する手段として、様々な色で毛髪を染めたりする。 For this reason, some people dye their hair a specific color when it turns white or gray with age, and even if their hair does not change color as a result of aging, they dye it a variety of colors as a way to express their individuality.
しかし、従来から使用されている染毛剤の必須成分である１，２，４－トリヒドロキシベンゼン（ＴＨＢ）は、医療界、学界、産業界で現在でも様々な有害性の議論がなされている、有害性の疑いがある物質である。１，２，４－トリヒドロキシベンゼン（ＴＨＢ）は、このように様々な有害性の議論が絶えない状況でも、短時間で効率的に染色することができるという理由だけで、現在でもほとんどの染毛用化粧品や染毛剤に含まれて流通しているのが実情である。 However, 1,2,4-trihydroxybenzene (THB), an essential ingredient in hair dyes that have been used for a long time, is a substance that is still being debated in various medical, academic and industrial circles and is suspected to be harmful. Even in a situation where the harmfulness of 1,2,4-trihydroxybenzene (THB) is still being debated, the reality is that it is still included in most hair dye cosmetics and hair dyes that are on the market today, simply because it allows for efficient dyeing in a short amount of time.
一方、このような問題を解決するために、下記特許文献１は、天然成分である黒紅参、大豆粉、コーンスターチ（トウモロコシ澱粉）、クズ（葛）、クルミの皮、オークの棘、アロエ、クチナシ、緑茶葉、昆布、五倍子粉を含む天然物で組成された染毛剤を開示しているが、これらの天然成分の組み合わせだけでは染毛力及び染色持続力が比較的低いという限界があった。 Meanwhile, to solve these problems, the following Patent Document 1 discloses a hair dye composed of natural products including black red ginseng, soybean flour, cornstarch, kudzu, walnut bark, oak thorns, aloe, gardenia, green tea leaves, kelp, and oak gallnut powder. However, the combination of these natural ingredients alone has limitations in that the dyeing power and dye retention are relatively low.
したがって、１，２，４－トリヒドロキシベンゼン（ＴＨＢ）を使用しないため人体に無害であり、１，２，４－トリヒドロキシベンゼン（ＴＨＢ）がなくても優れた染毛力を発揮することができ、様々な環境にさらされても長期間にわたって染毛状態に変化がほとんどなく、頻繁な使用でも頭皮や毛髪を傷つけない染毛用組成物に関する開発が切実に求められているのが現状である。 Therefore, there is currently an urgent need to develop a hair dye composition that is harmless to the human body because it does not use 1,2,4-trihydroxybenzene (THB), that can exhibit excellent hair dyeing power even without 1,2,4-trihydroxybenzene (THB), that shows little change in the dyed hair over a long period of time even when exposed to various environments, and that does not damage the scalp or hair even with frequent use.
そこで、本発明では、上記問題を解決するために、１，２，４－トリヒドロキシベンゼン（ＴＨＢ）を全く使用せず、ヒドロキシチロソールを用いるため人体に無害であり、優れた染毛力を発揮することができ、様々な環境にさらされても長期間にわたって染毛状態に変化がほとんどなく、頻繁な使用でも頭皮や毛髪を傷つけない染毛用組成物を開発することになった。 Therefore, in order to solve the above problems, the present invention has developed a hair dye composition that does not use any 1,2,4-trihydroxybenzene (THB) at all, but uses hydroxytyrosol, which is harmless to the human body, has excellent hair dyeing power, shows little change in the dyed hair condition over a long period of time even when exposed to various environments, and does not damage the scalp or hair even with frequent use.
したがって、本発明の一態様は、ヒドロキシチロソールを含有することにより、人体に無害であり、優れた染毛力を発揮することができ、様々な環境にさらされても長期間にわたって染毛状態に変化がほとんどなく、頻繁な使用でも頭皮や毛髪を傷つけない染毛用組成物を提供するところにある。 Therefore, one aspect of the present invention is to provide a hair dye composition that contains hydroxytyrosol, is harmless to the human body, exhibits excellent hair dyeing power, shows little change in the dyed hair condition over a long period of time even when exposed to various environments, and does not damage the scalp or hair even with frequent use.
本発明の一実施形態に係る染毛用組成物は、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）を含有することを特徴とする。 The hair dye composition according to one embodiment of the present invention is characterized by containing hydroxytyrosol (3,4-dihydroxyphenylethanol).
本発明の一実施形態に係る前記染毛用組成物は、カカオ抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ（Ｃｏｃｏａ）Ｅｘｔｒａｃｔ）及びカカオ種子抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ（Ｃｏｃｏａ）Ｓｅｅｄ Ｅｘｔｒａｃｔ）のうちの少なくとも１つをさらに含有することを特徴とする。 The hair dye composition according to one embodiment of the present invention is characterized by further containing at least one of a cacao extract (Theobroma Cacao (Cocoa) Extract) and a cacao seed extract (Theobroma Cacao (Cocoa) Seed Extract).
本発明の一実施形態に係る前記染毛用組成物は、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）をさらに含有することを特徴とする。 The hair dye composition according to one embodiment of the present invention is characterized by further containing green tea extract (Camellia Sinensis Leaf Extract).
本発明の一実施形態に係る前記染毛用組成物は、トックリイチゴ果実抽出物（Ｒｕｂｕｓ Ｃｏｒｅａｎｕｓ Ｆｒｕｉｔ Ｅｘｔｒａｃｔ）をさらに含有することを特徴とする。 The hair dye composition according to one embodiment of the present invention is characterized by further containing Rubus Coreanus Fruit Extract.
本発明の一実施形態に係る前記染毛用組成物は、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）をさらに含有することを特徴とする。 The hair dye composition according to one embodiment of the present invention is characterized by further containing Glycine Soja Seed Extract.
本発明の一実施形態に係る前記染毛用組成物は、ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）をさらに含有することを特徴とする。 The hair dye composition according to one embodiment of the present invention is characterized by further containing garlic extract (Allium Sativum Bulb Extract).
本発明の一実施形態に係る前記染毛用組成物は、ジオウ根抽出物（Ｒｅｈｍａｎｎｉａ Ｃｈｉｎｅｎｓｉｓ Ｒｏｏｔ Ｅｘｔｒａｃｔ）をさらに含有することを特徴とする。 The hair dye composition according to one embodiment of the present invention is characterized by further containing Rehmannia chinensis root extract.
本発明に係る染毛用組成物は、１，２，４－トリヒドロキシベンゼン（ＴＨＢ）を全く使用しないため人体に無害であり、１，２，４－トリヒドロキシベンゼン（ＴＨＢ）がなくても優れた染毛力を発揮することができ、様々な環境にさらされても長期間にわたって染毛状態に変化がほとんどなく、頻繁な使用でも頭皮や毛髪を傷つけないという利点を有する。 The hair dye composition of the present invention is harmless to the human body because it does not contain any 1,2,4-trihydroxybenzene (THB), and has the advantages of being able to exhibit excellent hair dyeing power even without 1,2,4-trihydroxybenzene (THB), showing little change in the dyed hair over a long period of time even when exposed to various environments, and not damaging the scalp or hair even with frequent use.
本発明をより具体的に説明するに先たって、本明細書及び特許請求の範囲で使われた用語や単語は通常的や辞書的な意味に限定して解釈されてはならず、発明を最善の方法で説明するために、用語の概念を適切に定義できるという原則に則って、本発明の技術的な思想に合致する意味及び概念で解釈されるべきである。したがって、本明細書に記載の実施形態の構成は、本発明の好適な一例に過ぎず、本発明の技術的な思想のすべてを代弁するものではないため、本発明の時点においてこれらに代替できる多様な均等物及び変形例があり得ることを理解しなければならない。 Before describing the present invention in more detail, the terms and words used in this specification and claims should not be interpreted as being limited to their ordinary or dictionary meanings, but should be interpreted in a way that is consistent with the technical ideas of the present invention, in accordance with the principle that the concepts of terms can be properly defined in order to best describe the invention. Therefore, it should be understood that the configurations of the embodiments described in this specification are merely preferred examples of the present invention, and do not represent the entire technical ideas of the present invention, and therefore that there may be various equivalents and modifications that can be substituted for them at the time of the present invention.
以下、本発明が属する技術分野において通常の知識を有する者が本発明を容易に実施できるように、本発明の好適な実施形態を詳細に説明する。なお、本発明を説明するに当たって、本発明の要旨をかえって不明にすると判断される関連公知技術に関する詳細な説明は省略する。 Below, a preferred embodiment of the present invention will be described in detail so that a person having ordinary knowledge in the technical field to which the present invention pertains can easily implement the present invention. In explaining the present invention, detailed explanations of related publicly known technologies that are deemed to obscure the gist of the present invention will be omitted.
本発明の一実施形態に係る染毛用組成物は、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）を含有する。 The hair dye composition according to one embodiment of the present invention contains hydroxytyrosol (3,4-dihydroxyphenylethanol).
本発明の一実施形態に係る前記染毛用組成物は、カカオ抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ（Ｃｏｃｏａ）Ｅｘｔｒａｃｔ）及びカカオ種子抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ（Ｃｏｃｏａ）Ｓｅｅｄ Ｅｘｔｒａｃｔ）のうちの少なくとも１つをさらに含有していてもよい。 The hair dye composition according to one embodiment of the present invention may further contain at least one of a cacao extract (Theobroma Cacao (Cocoa) Extract) and a cacao seed extract (Theobroma Cacao (Cocoa) Seed Extract).
本発明の一実施形態に係る前記染毛用組成物は、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）をさらに含有していてもよい。 The hair dye composition according to one embodiment of the present invention may further contain green tea extract (Camellia Sinensis Leaf Extract).
本発明の一実施形態に係る前記染毛用組成物は、トックリイチゴ果実抽出物（Ｒｕｂｕｓ Ｃｏｒｅａｎｕｓ Ｆｒｕｉｔ Ｅｘｔｒａｃｔ）をさらに含有していてもよい。 The hair dye composition according to one embodiment of the present invention may further contain Rubus Coreanus Fruit Extract.
本発明の一実施形態に係る前記染毛用組成物は、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）をさらに含有していてもよい。 The hair dye composition according to one embodiment of the present invention may further contain glycine soja seed extract.
本発明の一実施形態に係る前記染毛用組成物は、ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）をさらに含有していてもよい。 The hair dye composition according to one embodiment of the present invention may further contain garlic extract (Allium Sativum Bulb Extract).
本発明の一実施形態に係る前記染毛用組成物は、ジオウ根抽出物（Ｒｅｈｍａｎｎｉａ Ｃｈｉｎｅｎｓｉｓ Ｒｏｏｔ Ｅｘｔｒａｃｔ）をさらに含有していてもよい。 The hair dye composition according to one embodiment of the present invention may further contain Rehmannia chinensis root extract.
一方、本発明の他の実施形態に係る染毛用組成物は、前記ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）、カカオ抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ（Ｃｏｃｏａ）Ｅｘｔｒａｃｔ）、カカオ種子抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ（Ｃｏｃｏａ）Ｓｅｅｄ Ｅｘｔｒａｃｔ）、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）、トックリイチゴ果実抽出物（Ｒｕｂｕｓ Ｃｏｒｅａｎｕｓ Ｆｒｕｉｔ Ｅｘｔｒａｃｔ）、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）、ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）、ジオウ根抽出物（Ｒｅｈｍａｎｎｉａ Ｃｈｉｎｅｎｓｉｓ Ｒｏｏｔ Ｅｘｔｒａｃｔ）に加えて、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）、または下記化学式（１）のＮ－ニコチノイル－ＧＡＢＡを、さらに含有していてもよい。 Meanwhile, the hair dye composition according to another embodiment of the present invention is a composition containing the above-mentioned hydroxytyrosol (3,4-dihydroxyphenylethanol), cacao extract (Theobroma Cacao (Cocoa) Extract), cacao seed extract (Theobroma Cacao (Cocoa) Seed Extract), green tea extract (Camellia Sinensis Leaf Extract), Rubus Coreanus Fruit Extract, Glycine Soja Seed Extract, garlic extract (Allium Sativum Bulb Extract), Rehmannia chinensis Root Extract, and the like. In addition to the extract, it may further contain citric acid, sodium citrate, potassium hydroxide, or N-nicotinoyl-GABA of the following chemical formula (1).
本発明において、精製水１，０００重量当たり、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）１～１５０重量、カカオ抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ（Ｃｏｃｏａ）Ｅｘｔｒａｃｔ）１～１５０重量、カカオ種子抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ（Ｃｏｃｏａ）Ｓｅｅｄ Ｅｘｔｒａｃｔ）１～１５０重量、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）１～１５０重量、トックリイチゴ果実抽出物（Ｒｕｂｕｓ Ｃｏｒｅａｎｕｓ Ｆｒｕｉｔ Ｅｘｔｒａｃｔ）１～１５０重量、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）１～１５０重量、ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）１～１５０重量、ジオウ根抽出物（Ｒｅｈｍａｎｎｉａ Ｃｈｉｎｅｎｓｉｓ Ｒｏｏｔ Ｅｘｔｒａｃｔ）１～１５０重量、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）１～１００重量、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）１～１００重量、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）１～１００重量、Ｎ－ニコチノイル－ＧＡＢＡ１～１５０重量の割合で混合することが可能である。 In the present invention, per 1,000 weight of purified water, 1 to 150 weight of hydroxytyrosol (3,4-dihydroxyphenylethanol), 1 to 150 weight of cacao extract (Theobroma Cacao (Cocoa) Extract), 1 to 150 weight of cacao seed extract (Theobroma Cacao (Cocoa) Seed Extract), 1 to 150 weight of green tea extract (Camellia Sinensis Leaf Extract), 1 to 150 weight of Rubus Coreanus Fruit Extract, 1 to 150 weight of black bean extract (Glycine Soja Seed Extract), 1 to 150 weight of garlic extract (Allium sativum extract), 1 to 150 weight of glycine soja seed extract, ... It is possible to mix the following in a ratio of 1-150 parts by weight of Sativum Bulb Extract, 1-150 parts by weight of Rehmannia Chinansis Root Extract, 1-100 parts by weight of Citric Acid, 1-100 parts by weight of Sodium Citrate, 1-100 parts by weight of Potassium Hydroxide, and 1-150 parts by weight of N-nicotinoyl-GABA.
本発明において、前記カカオ種子抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ Ｓｅｅｄ Ｅｘｔｒａｃｔ）は、カカオ種子を採取し、乾燥過程なしで洗浄し、細かく粉砕した後、粉砕されたカカオ種子１００重量当たり約１，０００重量の精製水を加えて約３０分間加熱し、室温（２５℃）に冷却した後、２００メッシュのフィルターを通して固形成分を除去し、約４℃の温度で約２４時間沈殿過程を行った後、沈殿物を除去し、残りの上層部の液状抽出物を得る方法により得られた。 In the present invention, the cacao seed extract (Theobroma Cacao Seed Extract) was obtained by collecting cacao seeds, washing them without drying, and finely grinding them, adding about 1,000 weight of purified water per 100 weight of the ground cacao seeds, heating for about 30 minutes, cooling to room temperature (25°C), filtering through a 200 mesh filter to remove solid components, carrying out a precipitation process at a temperature of about 4°C for about 24 hours, removing the precipitate, and obtaining a liquid extract of the remaining upper layer.
本発明において、前記カカオ抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ Ｅｘｔｒａｃｔ）は、カカオ果肉を準備し、乾燥過程なしで洗浄し、細かく粉砕した後、粉砕されたカカオ果肉１００重量当たり約１，０００重量の精製水を加えて約３０分間加熱し、室温（２５℃）に冷却した後、２００メッシュのフィルターを通して固形成分を除去し、約４℃の温度で約２４時間沈殿過程を行った後、沈殿物を除去し、残りの上層部の液状抽出物を得る方法により得られた。 In the present invention, the cacao extract (Theobroma Cacao Extract) is obtained by preparing cacao pulp, washing it without drying, and finely grinding it, adding about 1,000 weight of purified water per 100 weight of the ground cacao pulp, heating it for about 30 minutes, cooling it to room temperature (25°C), removing solid components through a 200 mesh filter, carrying out a precipitation process at a temperature of about 4°C for about 24 hours, removing the precipitate, and obtaining the liquid extract of the remaining upper layer.
本発明において、前記緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）は、緑茶葉を採取し、乾燥過程なしで洗浄し、細かく粉砕した後、粉砕された緑茶葉１００重量当たり約１，０００重量の精製水を加えて約３０分間加熱し、室温（２５℃）に冷却した後、２００メッシュのフィルターを通して固形成分を除去し、約４℃の温度で約２４時間沈殿過程を行った後、沈殿物を除去し、残りの上層部の液状抽出物を得る方法により得られた。 In the present invention, the green tea extract (Camellia Sinensis Leaf Extract) is obtained by collecting green tea leaves, washing them without drying, and finely crushing them, adding about 1,000 weights of purified water per 100 weights of crushed green tea leaves, heating for about 30 minutes, cooling to room temperature (25°C), filtering through a 200 mesh filter to remove solid components, carrying out a precipitation process at a temperature of about 4°C for about 24 hours, removing the precipitate, and obtaining the remaining liquid extract from the upper layer.
本発明において、前記トックリイチゴ果実抽出物（Ｒｕｂｕｓ Ｃｏｒｅａｎｕｓ Ｆｒｕｉｔ Ｅｘｔｒａｃｔ）は、トックリイチゴ果肉を採取し、乾燥過程なしで洗浄し、細かく粉砕した後、粉砕されたトックリイチゴ果肉１００重量当たり約１，０００重量の精製水を加えて約３０分間加熱し、室温（２５℃）に冷却した後、２００メッシュのフィルターを通して固形成分を除去し、約４℃の温度で約２４時間沈殿過程を行った後、沈殿物を除去し、残りの上層部の液状抽出物を得る方法により得られた。 In the present invention, the Rubus Coreanus Fruit Extract was obtained by collecting Rubus Coreanus pulp, washing it without drying, and finely crushing it, adding about 1,000 weight of purified water per 100 weight of the crushed Rubus Coreanus pulp, heating it for about 30 minutes, cooling it to room temperature (25°C), removing solid components through a 200 mesh filter, carrying out a precipitation process at a temperature of about 4°C for about 24 hours, removing the precipitate, and obtaining a liquid extract from the remaining upper layer.
本発明において、前記黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）は、黒豆を採取し、乾燥過程なしで洗浄し、細かく粉砕した後、粉砕された黒豆１００重量当たり約１，０００重量の精製水を加えて約３０分間加熱し、室温（２５℃）に冷却した後、２００メッシュのフィルターを通して固形成分を除去し、約４℃の温度で約２４時間沈殿過程を行った後、沈殿物を除去し、残りの上層部の液状抽出物を得る方法により得られた。 In the present invention, the Glycine Soja Seed Extract is obtained by collecting black beans, washing them without drying, and crushing them finely, adding about 1,000 weights of purified water per 100 weights of crushed black beans, heating for about 30 minutes, cooling to room temperature (25°C), filtering through a 200 mesh filter to remove solid components, carrying out a precipitation process at a temperature of about 4°C for about 24 hours, removing the precipitate, and obtaining the liquid extract of the remaining upper layer.
本発明において、前記ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）は、ニンニクを採取し、乾燥過程なしで洗浄し、細かく粉砕した後、粉砕されたニンニク１００重量当たり約１，０００重量の精製水を加えて約３０分間加熱し、室温（２５℃）に冷却した後、２００メッシュのフィルターを通して固形成分を除去し、約４℃の温度で約２４時間沈殿過程を行った後、沈殿物を除去し、残りの上層部の液状抽出物を得る方法により得られた。 In the present invention, the garlic extract (Allium Sativum Bulb Extract) is obtained by collecting garlic, washing it without drying, and crushing it finely, adding about 1,000 weights of purified water per 100 weights of crushed garlic, heating it for about 30 minutes, cooling it to room temperature (25°C), filtering it through a 200 mesh filter to remove solid components, carrying out a precipitation process at a temperature of about 4°C for about 24 hours, removing the precipitate, and obtaining a liquid extract from the remaining upper layer.
本発明において、前記ジオウ根抽出物（Ｒｅｈｍａｎｎｉａ Ｃｈｉｎｅｎｓｉｓ Ｒｏｏｔ Ｅｘｔｒａｃｔ）は、ジオウ根を採取し、乾燥過程なしで洗浄し、細かく粉砕した後、粉砕されたジオウ根１００重量当たり約１，０００重量の精製水を加えて約３０分間加熱し、室温（２５℃）に冷却した後、２００メッシュのフィルターを通して固形成分を除去し、約４℃の温度で約２４時間沈殿過程を行った後、沈殿物を除去し、残りの上層部の液状抽出物を得る方法により得られた。 In the present invention, the Rehmannia root extract (Rehmannia chinensis Root Extract) was obtained by collecting Rehmannia root, washing it without drying, and finely crushing it, adding about 1,000 weight of purified water per 100 weight of the crushed Rehmannia root, heating it for about 30 minutes, cooling it to room temperature (25°C), filtering it through a 200 mesh filter to remove solid components, carrying out a precipitation process at a temperature of about 4°C for about 24 hours, removing the precipitate, and obtaining a liquid extract from the remaining upper layer.
以下、各種実施例及び比較例を用いて、本発明の効果を確認するための実験及びその結果について説明する。 Below, we will explain the experiments to confirm the effects of the present invention and their results using various examples and comparative examples.
［実施例１］
精製水１，０００ｇ、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）５０ｇ、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）５０ｇ、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）粉末２０ｇ、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）粉末２０ｇ、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）粉末２０ｇを均一に混合して染毛用組成物を調製した。
[Example 1]
A hair dye composition was prepared by uniformly mixing 1,000 g of purified water, 50 g of hydroxytyrosol (3,4-dihydroxyphenylethanol), 50 g of green tea extract (Camellia Sinensis Leaf Extract), 20 g of citric acid powder, 20 g of sodium citrate powder, and 20 g of potassium hydroxide powder.
［実施例２］
精製水１，０００ｇ、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）５０ｇ、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）５０ｇ、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）粉末２０ｇ、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）粉末２０ｇ、水酸化カリウム（Ｐｏｔａｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）粉末２０ｇを均一に混合して染毛用組成物を調製した。
[Example 2]
A hair dye composition was prepared by uniformly mixing 1,000 g of purified water, 50 g of hydroxytyrosol (3,4-dihydroxyphenylethanol), 50 g of green tea extract (Camellia Sinensis Leaf Extract), 50 g of black soybean extract (Glycine Soja Seed Extract), 20 g of citric acid powder, 20 g of sodium citrate powder, and 20 g of potassium hydroxide powder.
［実施例３］
精製水１，０００ｇ、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）５０ｇ、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）５０ｇ、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）５０ｇ、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）粉末２０ｇ、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）粉末２０ｇ、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）粉末２０ｇを均一に混合して染毛用組成物を調製した。
[Example 3]
A hair dye composition was prepared by uniformly mixing 1,000 g of purified water, 50 g of hydroxytyrosol (3,4-dihydroxyphenylethanol), 50 g of green tea extract (Camellia Sinensis Leaf Extract), 50 g of black bean extract (Glycine Soja Seed Extract), 50 g of garlic extract (Allium Sativum Bulb Extract), 20 g of citric acid powder, 20 g of sodium citrate powder, and 20 g of potassium hydroxide powder.
［実施例４］
精製水１，０００ｇ、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）５０ｇ、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）５０ｇ、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）５０ｇ、ジオウ根抽出物（Ｒｅｈｍａｎｎｉａ Ｃｈｉｎｅｎｓｉｓ Ｒｏｏｔ Ｅｘｔｒａｃｔ）５０ｇ、カカオ種子抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）粉末２０ｇ、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）粉末２０ｇ、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）粉末２０ｇを均一に混合して染毛用組成物を調製した。
[Example 4]
Purified water 1,000g, Hydroxytyrosol (3,4-dihydroxyphenylethanol) 50g, Green tea extract (Camellia Sinensis Leaf Extract) 50g, Black bean extract (Glycine Soja Seed Extract) 50g, Garlic extract (Allium Sativum Bulb Extract) 50g, Rehmannia Chinensis Root Extract (Rehmannia Chinensis Root Extract) 50g, Cacao seed extract (Theobroma Cacao Seed Extract) 50g, Citric acid powder 20g, Sodium citrate (Sodium citrate) 20g A hair dye composition was prepared by uniformly mixing 20 g of potassium citrate powder and 20 g of potassium hydroxide powder.
［実施例５］
精製水１，０００ｇ、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）５０ｇ、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）５０ｇ、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）５０ｇ、ジオウ根抽出物（Ｒｅｈｍａｎｎｉａ Ｃｈｉｎｅｎｓｉｓ Ｒｏｏｔ Ｅｘｔｒａｃｔ）５０ｇ、カカオ種子抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）粉末２０ｇ、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）粉末２０ｇ、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）粉末２０ｇ、トックリイチゴ果実抽出物（Ｒｕｂｕｓ Ｃｏｒｅａｎｕｓ Ｆｒｕｉｔ Ｅｘｔｒａｃｔ）５０ｇを均一に混合して染毛用組成物を調製した。
[Example 5]
Purified water 1,000g, Hydroxytyrosol (3,4-dihydroxyphenylethanol) 50g, Green tea extract (Camellia Sinensis Leaf Extract) 50g, Black bean extract (Glycine Soja Seed Extract) 50g, Garlic extract (Allium Sativum Bulb Extract) 50g, Rehmannia Chinensis Root Extract (Rehmannia Chinensis Root Extract) 50g, Cacao seed extract (Theobroma Cacao Seed Extract) 50g, Citric acid powder 20g, Sodium citrate (Sodium citrate) 20g A hair dye composition was prepared by uniformly mixing 20 g of potassium citrate powder, 20 g of potassium hydroxide powder, and 50 g of Rubus Coreanus Fruit Extract.
［実施例６］
精製水１，０００ｇ、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）５０ｇ、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）５０ｇ、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）５０ｇ、ジオウ根抽出物（Ｒｅｈｍａｎｎｉａ Ｃｈｉｎｅｎｓｉｓ Ｒｏｏｔ Ｅｘｔｒａｃｔ）５０ｇ、カカオ種子抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）粉末２０ｇ、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）粉末２０ｇ、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）粉末２０ｇ、トックリイチゴ果実抽出物（Ｒｕｂｕｓ Ｃｏｒｅａｎｕｓ Ｆｒｕｉｔ Ｅｘｔｒａｃｔ）５０ｇ、Ｎ－ニコチノイル－ＧＡＢＡ５０ｇを均一に混合して染毛用組成物を調製した。
[Example 6]
Purified water 1,000g, Hydroxytyrosol (3,4-dihydroxyphenylethanol) 50g, Green tea extract (Camellia Sinensis Leaf Extract) 50g, Black bean extract (Glycine Soja Seed Extract) 50g, Garlic extract (Allium Sativum Bulb Extract) 50g, Rehmannia Chinensis Root Extract (Rehmannia Chinensis Root Extract) 50g, Cacao seed extract (Theobroma Cacao Seed Extract) 50g, Citric acid powder 20g, Sodium citrate (Sodium citrate) 20g A hair dye composition was prepared by uniformly mixing 20 g of potassium citrate powder, 20 g of potassium hydroxide powder, 50 g of Rubus Coreanus Fruit Extract, and 50 g of N-nicotinoyl-GABA.
［比較例１］－実施例４からヒドロキシチロソールを除く
精製水１，０００ｇ、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）５０ｇ、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）５０ｇ、ジオウ根抽出物（Ｒｅｈｍａｎｎｉａ Ｃｈｉｎｅｎｓｉｓ Ｒｏｏｔ Ｅｘｔｒａｃｔ）５０ｇ、カカオ種子抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）粉末２０ｇ、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）粉末２０ｇ、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）粉末２０ｇを均一に混合して染毛用組成物を調製した。
Comparative Example 1 - Example 4 except for excluding hydroxytyrosol 1,000 g purified water, 50 g green tea extract (Camellia Sinensis Leaf Extract), 50 g black bean extract (Glycine Soja Seed Extract), 50 g garlic extract (Allium Sativum Bulb Extract), 50 g Rehmannia Chinensis Root Extract, 50 g cacao seed extract (Theobroma Cacao Seed Extract), 20 g citric acid powder, and 20 g sodium citrate. A hair dye composition was prepared by uniformly mixing 20 g of potassium citrate powder and 20 g of potassium hydroxide powder.
［比較例２］－実施例４から緑茶抽出物を除く
精製水１，０００ｇ、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）５０ｇ、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）５０ｇ、ジオウ根抽出物（Ｒｅｈｍａｎｎｉａ Ｃｈｉｎｅｎｓｉｓ Ｒｏｏｔ Ｅｘｔｒａｃｔ）５０ｇ、カカオ種子抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）粉末２０ｇ、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）粉末２０ｇ、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）粉末２０ｇを均一に混合して染毛用組成物を調製した。
Comparative Example 2 - Example 4 except for the absence of green tea extract Purified water 1,000 g, hydroxytyrosol (3,4-dihydroxyphenylethanol) 50 g, black bean extract (Glycine Soja Seed Extract) 50 g, garlic extract (Allium Sativum Bulb Extract) 50 g, Rehmannia Chinensis Root Extract (Rehmannia Chinensis Root Extract) 50 g, cacao seed extract (Theobroma Cacao Seed Extract) 50 g, citric acid powder 20 g, sodium citrate powder 20 g, potassium hydroxide Hydroxide powder (20 g) was uniformly mixed to prepare a hair dye composition.
［比較例３］－実施例４から黒豆抽出物を除く
精製水１，０００ｇ、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）５０ｇ、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）５０ｇ、ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）５０ｇ、ジオウ根抽出物（Ｒｅｈｍａｎｎｉａ Ｃｈｉｎｅｎｓｉｓ Ｒｏｏｔ Ｅｘｔｒａｃｔ）５０ｇ、カカオ種子抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）粉末２０ｇ、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）粉末２０ｇ、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）粉末２０ｇを均一に混合して染毛用組成物を調製した。
Comparative Example 3: Example 4 except for black bean extract. Purified water 1,000 g, hydroxytyrosol (3,4-dihydroxyphenylethanol) 50 g, green tea extract (Camellia Sinensis Leaf Extract) 50 g, garlic extract (Allium Sativum Bulb Extract) 50 g, Rehmannia Chinensis Root Extract (Rehmannia Chinensis Root Extract) 50 g, cacao seed extract (Theobroma Cacao Seed Extract) 50 g, citric acid powder 20 g, sodium citrate powder 20 g, potassium hydroxide (Potassium Hydroxide) ... Hydroxide powder (20 g) was uniformly mixed to prepare a hair dye composition.
［比較例４］－実施例４からニンニク抽出物を除く
精製水１，０００ｇ、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）５０ｇ、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）５０ｇ、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、ジオウ根抽出物（Ｒｅｈｍａｎｎｉａ Ｃｈｉｎｅｎｓｉｓ Ｒｏｏｔ Ｅｘｔｒａｃｔ）５０ｇ、カカオ種子抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）粉末２０ｇ、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）粉末２０ｇ、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）粉末２０ｇを均一に混合して染毛用組成物を調製した。
Comparative Example 4 - Example 4 except for garlic extract 1,000g purified water, 50g hydroxytyrosol (3,4-dihydroxyphenylethanol), 50g green tea extract (Camellia Sinensis Leaf Extract), 50g black bean extract (Glycine Soja Seed Extract), 50g Rehmannia Chinensis Root Extract, 50g cacao seed extract (Theobroma Cacao Seed Extract), 20g citric acid powder, 20g sodium citrate powder, 20g potassium hydroxide Hydroxide powder (20 g) was uniformly mixed to prepare a hair dye composition.
［比較例５］－実施例４からジオウ根抽出物を除く
精製水１，０００ｇ、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）５０ｇ、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）５０ｇ、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）５０ｇ、カカオ種子抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）粉末２０ｇ、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）粉末２０ｇ、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）粉末２０ｇを均一に混合して染毛用組成物を調製した。
Comparative Example 5 - Example 4 except for Rehmannia Root Extract 1,000 g purified water, 50 g hydroxytyrosol (3,4-dihydroxyphenylethanol), 50 g green tea extract (Camellia Sinensis Leaf Extract), 50 g black bean extract (Glycine Soja Seed Extract), 50 g garlic extract (Allium Sativum Bulb Extract), 50 g cacao seed extract (Theobroma Cacao Seed Extract), 20 g citric acid powder, 20 g sodium citrate powder, 20 g potassium hydroxide Hydroxide powder (20 g) was uniformly mixed to prepare a hair dye composition.
［比較例６］－実施例４からカカオ種子抽出物を除く
精製水１，０００ｇ、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）５０ｇ、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）５０ｇ、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）５０ｇ、ジオウ根抽出物（Ｒｅｈｍａｎｎｉａ Ｃｈｉｎｅｎｓｉｓ Ｒｏｏｔ Ｅｘｔｒａｃｔ）５０ｇ、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）粉末２０ｇ、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）粉末２０ｇ、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）粉末２０ｇを均一に混合して染毛用組成物を調製した。
Comparative Example 6 - Example 4 except for cacao seed extract 1,000 g purified water, 50 g hydroxytyrosol (3,4-dihydroxyphenylethanol), 50 g green tea extract (Camellia Sinensis Leaf Extract), 50 g black bean extract (Glycine Soja Seed Extract), 50 g garlic extract (Allium Sativum Bulb Extract), 50 g Rehmannia Chinensis Root Extract, 20 g citric acid powder, 20 g sodium citrate powder, 20 g potassium hydroxide Hydroxide powder (20 g) was uniformly mixed to prepare a hair dye composition.
［比較例７］－実施例４からクエン酸粉末を除く
精製水１，０００ｇ、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）５０ｇ、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）５０ｇ、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）５０ｇ、ジオウ根抽出物（Ｒｅｈｍａｎｎｉａ Ｃｈｉｎｅｎｓｉｓ Ｒｏｏｔ Ｅｘｔｒａｃｔ）５０ｇ、カカオ種子抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）粉末２０ｇ、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）粉末２０ｇを均一に混合して染毛用組成物を調製した。
Comparative Example 7 - Example 4 except for citric acid powder Purified water 1,000 g, hydroxytyrosol (3,4-dihydroxyphenylethanol) 50 g, green tea extract (Camellia Sinensis Leaf Extract) 50 g, black bean extract (Glycine Soja Seed Extract) 50 g, garlic extract (Allium Sativum Bulb Extract) 50 g, Rehmannia Chinensis Root Extract (Rehmannia Chinensis Root Extract) 50 g, cacao seed extract (Theobroma Cacao Seed Extract) 50 g, sodium citrate (Sodium Citrate) 50 g, 1,0 ... A hair dye composition was prepared by uniformly mixing 20 g of potassium citrate powder and 20 g of potassium hydroxide powder.
［比較例８］－実施例４からクエン酸ナトリウム粉末を除く
精製水１，０００ｇ、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）５０ｇ、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）５０ｇ、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）５０ｇ、ジオウ根抽出物（Ｒｅｈｍａｎｎｉａ Ｃｈｉｎｅｎｓｉｓ Ｒｏｏｔ Ｅｘｔｒａｃｔ）５０ｇ、カカオ種子抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）粉末２０ｇ、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）粉末２０ｇを均一に混合して染毛用組成物を調製した。
Comparative Example 8: Example 4 except for sodium citrate powder. 1,000 g purified water, 50 g hydroxytyrosol (3,4-dihydroxyphenylethanol), 50 g green tea extract (Camellia Sinensis Leaf Extract), 50 g black bean extract (Glycine Soja Seed Extract), 50 g garlic extract (Allium Sativum Bulb Extract), 50 g Rehmannia Chinensis Root Extract, 50 g cacao seed extract (Theobroma Cacao Seed Extract), 50 g citric acid (Citric Acid) A hair dye composition was prepared by uniformly mixing 20 g of potassium hydroxide powder and 20 g of dimethyl ether powder.
［比較例９］－実施例４から水酸化カリウム粉末を除く
精製水１，０００ｇ、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）５０ｇ、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）５０ｇ、黒豆抽出物（Ｇｌｙｃｉｎｅ Ｓｏｊａ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、ニンニク抽出物（Ａｌｌｉｕｍ Ｓａｔｉｖｕｍ Ｂｕｌｂ Ｅｘｔｒａｃｔ）５０ｇ、ジオウ根抽出物（Ｒｅｈｍａｎｎｉａ Ｃｈｉｎｅｎｓｉｓ Ｒｏｏｔ Ｅｘｔｒａｃｔ）５０ｇ、カカオ種子抽出物（Ｔｈｅｏｂｒｏｍａ Ｃａｃａｏ Ｓｅｅｄ Ｅｘｔｒａｃｔ）５０ｇ、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）粉末２０ｇ、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）粉末２０ｇを均一に混合して染毛用組成物を調製した。
Comparative Example 9 - Example 4 except for potassium hydroxide powder. Purified water 1,000 g, hydroxytyrosol (3,4-dihydroxyphenylethanol) 50 g, green tea extract (Camellia Sinensis Leaf Extract) 50 g, black bean extract (Glycine Soja Seed Extract) 50 g, garlic extract (Allium Sativum Bulb Extract) 50 g, Rehmannia Chinensis Root Extract (Rehmannia Chinensis Root Extract) 50 g, cacao seed extract (Theobroma Cacao Seed Extract) 50 g, citric acid powder 20 g, sodium citrate (Sodium Citrate) 20 g, glycerin (Glucose ... Citrate powder (20 g) was uniformly mixed to prepare a hair dye composition.
［比較例１０］－実施例１からヒドロキシチロソールを除く
精製水１，０００ｇ、緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）５０ｇ、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）粉末２０ｇ、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）粉末２０ｇ、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）粉末２０ｇを均一に混合して染毛用組成物を調製した。
Comparative Example 10 - Example 1 except that hydroxytyrosol was omitted 1,000 g of purified water, 50 g of Camellia Sinensis Leaf Extract, 20 g of citric acid powder, 20 g of sodium citrate powder, and 20 g of potassium hydroxide powder were uniformly mixed to prepare a hair dye composition.
［比較例１１］－実施例１から緑茶抽出物（Ｃａｍｅｌｌｉａ Ｓｉｎｅｎｓｉｓ Ｌｅａｆ Ｅｘｔｒａｃｔ）を除く
精製水１，０００ｇ、ヒドロキシチロソール（３，４－ジヒドロキシフェニルエタノール）５０ｇ、クエン酸（Ｃｉｔｒｉｃ Ａｃｉｄ）粉末２０ｇ、クエン酸ナトリウム（Ｓｏｄｉｕｍ Ｃｉｔｒａｔｅ）粉末２０ｇ、水酸化カリウム（Ｐｏｔａｓｓｉｕｍ Ｈｙｄｒｏｘｉｄｅ）粉末２０ｇを均一に混合して染毛用組成物を調製した。
Comparative Example 11 - Example 1 except that the green tea extract (Camellia Sinensis Leaf Extract) was removed. 1,000 g of purified water, 50 g of hydroxytyrosol (3,4-dihydroxyphenylethanol), 20 g of citric acid powder, 20 g of sodium citrate powder, and 20 g of potassium hydroxide powder were uniformly mixed to prepare a hair dye composition.
［実験１］
上記実施例１～６及び比較例１～１１で調製した染毛用組成物を用いて染毛力をテストする実験を行った。
[Experiment 1]
Using the hair dye compositions prepared in Examples 1 to 6 and Comparative Examples 1 to 11, an experiment was carried out to test the hair dyeing ability.
染毛力テストでは、実施例１～６及び比較例１～１１で調製した染毛用組成物に、白色の自然毛サンプル（各１０ｇ）を１５分間完全に浸漬し、１５分間の浸漬を終了した後、水道の流水で３回洗浄し、自然風で１時間乾燥させた後、毛髪の染色度合いを測定し、染色度合いは、毛髪の明度値（１００：最も明るい、０：最も暗い、すなわち、明度値が低いほど優れた染色力を示す）を測定することにより調べ、その結果を下記表１に示した。 In the hair dyeing power test, white natural hair samples (10 g each) were completely immersed in the hair dye compositions prepared in Examples 1 to 6 and Comparative Examples 1 to 11 for 15 minutes, and after the 15-minute immersion was completed, the hair was washed three times with running tap water and dried in natural wind for 1 hour, after which the degree of dyeing of the hair was measured. The degree of dyeing was examined by measuring the brightness value of the hair (100: brightest, 0: darkest, i.e., the lower the brightness value, the better the dyeing power), and the results are shown in Table 1 below.
上記表１の結果を見ると、比較例１０及び１１に比べて、実施例１～６が優れた染色力を発揮することが確認できる。 The results in Table 1 above confirm that Examples 1 to 6 exhibit superior dyeing power compared to Comparative Examples 10 and 11.
また、比較例１～９に比べて、実施例４が優れた染色力を発揮することを確認することができる。 It can also be seen that Example 4 exhibits superior dyeing power compared to Comparative Examples 1 to 9.
また、実施例１～３に比べて、実施例４がさらに優れた染色力を発揮することが確認できる。 It can also be seen that Example 4 exhibits even better dyeing power than Examples 1 to 3.
また、実施例６が最も優れた染色力を発揮することが確認できる。 It can also be seen that Example 6 exhibits the best dyeing power.
［実験２］
上記実施例１～６及び比較例１～１１で調製した染毛用組成物を用いて、高温環境下で染毛力がどの程度維持されるかを確認する実験を行った。
[Experiment 2]
Using the hair dye compositions prepared in Examples 1 to 6 and Comparative Examples 1 to 11 above, experiments were carried out to confirm the extent to which the hair dyeing power was maintained in a high temperature environment.
高温環境下での染色力維持実験では、実施例１～６及び比較例１～１１で調製した染毛用組成物に、白色の自然毛サンプル（それぞれ１０ｇ）を１５分間完全に浸漬し、１５分間の浸漬を終了した後、水道の流水で３回洗浄し、自然風で１時間乾燥させた後、４５℃を保つチャンバーに２０日間保管後、取り出して毛髪の染色状態を測定し、染毛度合いは、毛髪の明度値（１００：最も明るい、０：最も暗い、すなわち、明度値が低いほど優れた染色力を示す）を測定することにより調べ、その結果を下記表２に示した。 In the dyeing power retention experiment in a high temperature environment, a white natural hair sample (10 g each) was completely immersed in the hair dye compositions prepared in Examples 1 to 6 and Comparative Examples 1 to 11 for 15 minutes, and after the 15-minute immersion was completed, it was washed three times with running tap water, dried in natural wind for one hour, and then stored in a chamber maintained at 45°C for 20 days. The hair was then removed and the dyed state of the hair was measured, and the degree of dyeing was examined by measuring the hair's brightness value (100: brightest, 0: darkest, i.e., the lower the brightness value, the better the dyeing power). The results are shown in Table 2 below.
上記表２の結果を表１の結果と比較して調べると、実施例４～６では毛髪の染色度合いが全く変化していないことが確認できる。 When comparing the results in Table 2 above with those in Table 1, it can be seen that there is absolutely no change in the degree of hair dyeing in Examples 4 to 6.
［実験３］
上記実施例１～６及び比較例１～１１で調製した染毛用組成物を用いて、高塩分大気環境下で染毛力がどの程度維持されるかを確認する実験を行った。
[Experiment 3]
Using the hair dye compositions prepared in Examples 1 to 6 and Comparative Examples 1 to 11, experiments were carried out to confirm the extent to which the hair dyeing power was maintained in a high salinity atmospheric environment.
高塩分大気環境下での染色力維持実験では、実施例１～６及び比較例１～１１で調製した染毛用組成物に、白色の自然毛サンプル（各１０ｇ）を１５分間完全に浸漬し、１５分間の浸漬を終了した後、水道の流水で３回洗浄し、自然風で１時間乾燥させた後、空気中の塩分（ＮａＣｌ）濃度が３ｇ／ｍ３に保たれる塩分大気状態を作り維持するチャンバーに２０日間保管後、取り出して毛髪の染色状態を測定し、染毛度合いは、毛髪の明度値（１００：最も明るい、０：最も暗い、すなわち、明度値が低いほど優れた染色力を示す）を測定することにより調べ、その結果を下記表３に示した。 In the dyeing power maintenance experiment under high salinity air environment, white natural hair samples (10 g each) were completely immersed in the hair dye compositions prepared in Examples 1 to 6 and Comparative Examples 1 to 11 for 15 minutes, and after the 15-minute immersion was completed, the samples were washed three times with running tap water and dried in natural wind for 1 hour. The samples were then stored for 20 days in a chamber that created and maintained a saline atmosphere in which the salt (NaCl) concentration in the air was kept at 3 g/ m3 , and then taken out to measure the dyeing state of the hair. The degree of dyeing was examined by measuring the lightness value of the hair (100: lightest, 0: darkest, i.e., the lower the lightness value, the better the dyeing power). The results are shown in Table 3 below.
上記表３の結果を表１の結果と比較して調べると、実施例４～６では毛髪の染色度合いが全く変化していないことが確認できる。 When comparing the results in Table 3 above with those in Table 1, it can be seen that there is absolutely no change in the degree of hair dyeing in Examples 4 to 6.
［実験４］
上記実施例１～６及び比較例１～１１で調製した染毛用組成物を用いて、高湿度大気環境下で染毛力がどの程度維持されるかを確認する実験を行った。
[Experiment 4]
Using the hair dye compositions prepared in Examples 1 to 6 and Comparative Examples 1 to 11, experiments were carried out to confirm the extent to which the hair dyeing power was maintained under a high humidity atmospheric environment.
高湿度大気環境下での染色力維持実験では、実施例１～６及び比較例１～１１で調製した染毛用組成物に、白色の自然毛サンプル（各１０ｇ）を１５分間完全に浸漬し、１５分間の浸漬を終了した後、水道の流水に３回洗浄し、自然風で１時間乾燥させた後、空気中の湿度が７０％に保たれる高湿度大気状態を作り維持するチャンバーに２０日間保管後、取り出して毛髪の染色状態を測定し、染毛度合いは、毛髪の明度値（１００：最も明るい、０：最も暗い、すなわち、明度値が低いほど優れた染色力を示す）を測定することにより調べ、その結果を下記表４に示した。 In the dyeing power retention experiment in a high humidity atmospheric environment, white natural hair samples (10 g each) were completely immersed in the hair dye compositions prepared in Examples 1 to 6 and Comparative Examples 1 to 11 for 15 minutes, and after the 15 minutes of immersion, they were washed three times with running tap water and dried in natural wind for 1 hour. They were then stored for 20 days in a chamber that created and maintained a high humidity atmospheric condition in which the humidity in the air was kept at 70%, after which they were removed and the dyeing state of the hair was measured. The degree of dyeing was examined by measuring the brightness value of the hair (100: brightest, 0: darkest, i.e., the lower the brightness value, the better the dyeing power), and the results are shown in Table 4 below.
上記表４の結果を表１の結果と比較して調べると、実施例４～６では毛髪の染色度合いが全く変化していないことが確認できる。 When comparing the results in Table 4 above with those in Table 1, it can be seen that there is absolutely no change in the degree of hair dyeing in Examples 4 to 6.
［実験５］
上記実施例１～６及び比較例１～１１で調製した染毛用組成物を用いて、頻繁なシャンプー使用後に染毛力がどの程度維持されるかを確認する実験を行った。
[Experiment 5]
Using the hair dye compositions prepared in Examples 1 to 6 and Comparative Examples 1 to 11, an experiment was carried out to confirm the extent to which the hair dyeing power was maintained after frequent shampooing.
頻繁なシャンプー使用後の染色力維持実験では、実施例１～６及び比較例１～１１で調製した染毛用組成物に、白色の自然毛サンプル（各１０ｇ）を１５分間完全に浸漬し、１５分間の浸漬を終了した後、水道の流水で３回洗浄し、自然風で１時間乾燥させた後、毎回同量のシャンプーを使用し、水及びシャンプーを用いて１分間泡立てて洗浄した後、自然乾燥させる過程を２４時間間隔で２０回繰り返し、その後、毛髪の染色状態を測定し、染毛度合いは、毛髪の明度値（１００：最も明るい、０：最も暗い、すなわち、明度値が低いほど優れた染色力を示す）を測定することにより調べ、その結果を下記表５に示した。 In the experiment to test the dyeing power retention after frequent shampooing, white natural hair samples (10 g each) were completely immersed in the hair dye compositions prepared in Examples 1 to 6 and Comparative Examples 1 to 11 for 15 minutes. After the 15-minute immersion, the samples were washed three times with running tap water and dried in natural wind for 1 hour. The same amount of shampoo was used each time, and the samples were washed by lathering with water and shampoo for 1 minute and then naturally dried. This process was repeated 20 times at 24-hour intervals. The dyeing state of the hair was then measured, and the degree of dyeing was examined by measuring the lightness value of the hair (100: lightest, 0: darkest, i.e., the lower the lightness value, the better the dyeing power). The results are shown in Table 5 below.
上記表５の結果を表１の結果と比較して調べると、実施例４～６では毛髪の染色度合いが全く変化していないことが確認できる。 When comparing the results in Table 5 above with those in Table 1, it can be seen that there is absolutely no change in the degree of hair dyeing in Examples 4 to 6.
［実験６］
上記実施例１～６及び比較例１～１１で調製した染毛用組成物を用いて、頻繁なシャンプー使用後の毛髪の損傷の有無を確認する実験を行った。
[Experiment 6]
Using the hair dye compositions prepared in the above Examples 1 to 6 and Comparative Examples 1 to 11, an experiment was carried out to confirm whether or not hair was damaged after frequent shampooing.
毛髪の損傷の有無確認実験では、実施例１～６及び比較例１～１１で調製した染毛用組成物に、白色の自然毛サンプル（各１０ｇ）を１５分間完全に浸漬し、１５分間の浸漬を終了した後、水道の流水で３回洗浄し、自然風で１時間乾燥させた後、毎回同量のシャンプーを使用し、水及びシャンプーを用いて１分間泡立てて洗浄した後、自然乾燥させる過程を２４時間間隔で２０回繰り返し、その後、毛髪表面を顕微鏡で観察して損傷状態を確認し、その結果を下記表６に示した。 In an experiment to confirm the presence or absence of hair damage, white natural hair samples (10 g each) were completely immersed in the hair dye compositions prepared in Examples 1 to 6 and Comparative Examples 1 to 11 for 15 minutes, and after the 15-minute immersion was completed, they were washed three times with running tap water and dried in natural wind for 1 hour. The same amount of shampoo was used each time, and the hair was washed by lathering with water and shampoo for 1 minute and then naturally dried. This process was repeated 20 times at 24-hour intervals, and the surface of the hair was then observed under a microscope to confirm the state of damage, and the results are shown in Table 6 below.
オリジナルのサンプルの表面写真と比較して、追加損傷が無ければＸ、追加損傷が有ればＯを付けた。 By comparing with the surface photograph of the original sample, if there was no additional damage, an X was marked, and if there was additional damage, an O was marked.
上記の表６の結果を見ると、いずれの場合も毛髪の損傷が全く発生していないことが確認できる。 Looking at the results in Table 6 above, it can be seen that no damage to the hair occurred in any case.
［実験７］
一方、実験参加者１６０名（男性８０名、女性８０名、１グループ１６名、１グループ毎に各参加者は、それぞれ上記実施例１～６及び比較例１～１１で調製した染毛用組成物を使用、１０グループ反復実験）は、上記実施例１～６及び比較例１～１１で調製した染毛用組成物を用いて、３０日間毎日毛髪を染色し、３０日間経過するまでに実験参加者の頭皮の状態を調べたところ、１６０名の被験者のいずれも、頭皮に皮膚の発赤、かゆみ、炎症などの副作用が全く発生しなかった。
[Experiment 7]
Meanwhile, 160 participants (80 men, 80 women, 16 people per group, each participant in each group used the hair dye compositions prepared in the above Examples 1 to 6 and Comparative Examples 1 to 11, respectively, 10 groups were repeated) dyed their hair every day for 30 days using the hair dye compositions prepared in the above Examples 1 to 6 and Comparative Examples 1 to 11, and when the condition of the participants' scalps was examined after 30 days had passed, none of the 160 subjects experienced any side effects such as redness, itchiness, or inflammation on the scalp.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020220096186A KR102551315B1 (en) | 2022-08-02 | 2022-08-02 | Composition for har coloring containing hydroxytyrosol |
| KR10-2022-0096186 | 2022-08-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2024021027A JP2024021027A (en) | 2024-02-15 |
| JP7465573B2 true JP7465573B2 (en) | 2024-04-11 |
Family
ID=87156684
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022182174A Active JP7465573B2 (en) | 2022-08-02 | 2022-11-14 | Hair dye composition containing hydroxytyrosol |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP7465573B2 (en) |
| KR (1) | KR102551315B1 (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002138024A (en) | 2000-10-27 | 2002-05-14 | Riaru Kagaku Kk | Hair dyeing agent, hair dyeing set and hair dyeing method using the same |
| JP2006347910A (en) | 2005-06-14 | 2006-12-28 | Ogawa & Co Ltd | Moisture retention plant extract, and external preparation, cosmetic product, bathing agent and detergent containing the extract |
| JP2007217321A (en) | 2006-02-15 | 2007-08-30 | Hoyu Co Ltd | Hair dye composition |
| JP2011026216A (en) | 2009-07-22 | 2011-02-10 | Shodoshima Healty Land Kk | Cosmetic |
| WO2014103475A1 (en) | 2012-12-27 | 2014-07-03 | 株式会社林原 | Skin-exterior anti-ageing composition and production method therefor |
| WO2018126041A1 (en) | 2016-12-30 | 2018-07-05 | Northwestern University | Vehicles for applying bacteria to skin, scalp, and hair |
| CN112641693A (en) | 2020-12-31 | 2021-04-13 | 广州植境生物科技有限公司 | Hair care composition, preparation method and application thereof |
| US20220087925A1 (en) | 2020-09-23 | 2022-03-24 | Barnet Products, LLC | Synergistic antioxidant cosmetic composition containing at least one hydroxytyrosol and at least one sulforaphane |
| KR102405047B1 (en) | 2021-05-24 | 2022-06-02 | 박준기 | Composition for hair permanent wave and hair-straight perming comprising specific compounds |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI991896A1 (en) * | 1999-09-09 | 2001-03-09 | Carlo Ghisalberti | MELANINES AND VEGETABLE PIGMENTS |
| KR20110108717A (en) * | 2010-03-29 | 2011-10-06 | 노은미 | Fermentation soap including natural dyes, fermentation extracts |
| KR20120055861A (en) * | 2010-11-24 | 2012-06-01 | 이용선 | Scalp Cleansing & Hair Loss Composition Shampoo Soap Containing Pear Herbal Extract |
| KR101922996B1 (en) | 2018-09-05 | 2018-11-28 | 김창진 | Hair dye with natural substance |
| FR3090379B1 (en) * | 2018-12-20 | 2021-01-29 | Lvmh Rech | Aqueous gels for coloring or making up the eyebrows |
-
2022
- 2022-08-02 KR KR1020220096186A patent/KR102551315B1/en active IP Right Grant
- 2022-11-14 JP JP2022182174A patent/JP7465573B2/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002138024A (en) | 2000-10-27 | 2002-05-14 | Riaru Kagaku Kk | Hair dyeing agent, hair dyeing set and hair dyeing method using the same |
| JP2006347910A (en) | 2005-06-14 | 2006-12-28 | Ogawa & Co Ltd | Moisture retention plant extract, and external preparation, cosmetic product, bathing agent and detergent containing the extract |
| JP2007217321A (en) | 2006-02-15 | 2007-08-30 | Hoyu Co Ltd | Hair dye composition |
| JP2011026216A (en) | 2009-07-22 | 2011-02-10 | Shodoshima Healty Land Kk | Cosmetic |
| WO2014103475A1 (en) | 2012-12-27 | 2014-07-03 | 株式会社林原 | Skin-exterior anti-ageing composition and production method therefor |
| WO2018126041A1 (en) | 2016-12-30 | 2018-07-05 | Northwestern University | Vehicles for applying bacteria to skin, scalp, and hair |
| US20220087925A1 (en) | 2020-09-23 | 2022-03-24 | Barnet Products, LLC | Synergistic antioxidant cosmetic composition containing at least one hydroxytyrosol and at least one sulforaphane |
| CN112641693A (en) | 2020-12-31 | 2021-04-13 | 广州植境生物科技有限公司 | Hair care composition, preparation method and application thereof |
| KR102405047B1 (en) | 2021-05-24 | 2022-06-02 | 박준기 | Composition for hair permanent wave and hair-straight perming comprising specific compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| KR102551315B1 (en) | 2023-07-04 |
| JP2024021027A (en) | 2024-02-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2864084T3 (en) | Composition containing extract of Dendrobium candidum and method of preparation and use of the same | |
| BR112013012332A2 (en) | use of a combination of tea polyphenol or tea pigment, product for dyeing human or animal hair and combined product for dyeing human or animal hair | |
| JP2016145233A (en) | Composition for cosmetic for skin-whitening containing extracts from trees including paper mulberry and cosmetic | |
| CA2326625C (en) | Topical liquid composition for promoting hair growth and process of manufacturing thereof | |
| CN112057411A (en) | Deep-repairing camellia hydrolat mask and preparation method thereof | |
| KR101997177B1 (en) | Shampoo composition for improving state of scalp and hair | |
| CN112716855B (en) | Composition with barrier repairing and anti-aging effects and preparation method and application thereof | |
| JP7465573B2 (en) | Hair dye composition containing hydroxytyrosol | |
| CN106344442A (en) | Anti-alopecia composition and preparation method thereof | |
| JP2007319124A (en) | Health food | |
| JP4546540B2 (en) | Vegetable black pigment used for hair beautification and its application | |
| CN111329805A (en) | Preparation method of novel natural madder graphene hair dye | |
| KR101017129B1 (en) | Hair cosmetic composition comprising an extract of herb medicine for preventing depilatory | |
| JP7288689B2 (en) | Hair coloring agent composition | |
| KR20170107943A (en) | Skin Whitening Cosmetic Composition Containing Extracts of Wikstroemia trichotoma | |
| WO2007007936A1 (en) | Composition for hairdye comprising mulberry, mulberry leaves or mori radicis cortex | |
| KR102439454B1 (en) | Methods for manufacturing natural good salons, including black bean seed skin extract and chamomile | |
| KR20150109784A (en) | Cosmetic composition for hair care product that contains natural conjugated materials, and manufacturing method thereof, and hair care composition with it | |
| KR101261321B1 (en) | Shampo Compositions comprising Chondrus ocellatus and manufacturing thereof | |
| CN109793689A (en) | A kind of disposable hair film of moisture-keeping nutrient and preparation method thereof | |
| CN108567726A (en) | A kind of anti-chap lipstick and preparation method containing lycium ruthenicum pigment and acer truncatum seed oil | |
| CN107510630A (en) | A kind of hair tonic emulsion and preparation method thereof | |
| CN111529437B (en) | Pure traditional Chinese medicine natural hair blackening cream and application method thereof | |
| CN108524343A (en) | A kind of composition and its preparation method and application nourishing scalp and hair conditioning | |
| BRPI1104203A2 (en) | SUBSTANCE FORMULATION FOR HAIR COLORING AND TREATMENT |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20221115 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20221115 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20221117 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20231219 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20240208 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20240227 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20240325 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 7465573 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |