JP7441615B2 - 疑似移動床における工程および三分画塔を介した分画化の工程を用いたパラキシレンの製造方法 - Google Patents

疑似移動床における工程および三分画塔を介した分画化の工程を用いたパラキシレンの製造方法 Download PDF

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JP7441615B2
JP7441615B2 JP2019116113A JP2019116113A JP7441615B2 JP 7441615 B2 JP7441615 B2 JP 7441615B2 JP 2019116113 A JP2019116113 A JP 2019116113A JP 2019116113 A JP2019116113 A JP 2019116113A JP 7441615 B2 JP7441615 B2 JP 7441615B2
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fraction
desorbent
raffinate
xylene
zeolite
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JP2020023475A5 (enExample
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プレヴォー イザベル
ピグリエ ジェローム
マルタン ピエール-イヴ
コット アルノー
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767Changing the number of side-chains
    • C07C5/277Catalytic processes
    • C07C5/2791Catalytic processes with metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02Monocyclic hydrocarbons
    • C07C15/067C8H10 hydrocarbons
    • C07C15/08Xylenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/005Processes comprising at least two steps in series
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D15/00Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08Selective adsorption, e.g. chromatography
    • B01D15/10Selective adsorption, e.g. chromatography characterised by constructional or operational features
    • B01D15/18Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to flow patterns
    • B01D15/1814Recycling of the fraction to be distributed
    • B01D15/1821Simulated moving beds
    • B01D15/185Simulated moving beds characterised by the components to be separated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14Fractional distillation or use of a fractionation or rectification column
    • B01D3/141Fractional distillation or use of a fractionation or rectification column where at least one distillation column contains at least one dividing wall
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14Fractional distillation or use of a fractionation or rectification column
    • B01D3/143Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14Fractional distillation or use of a fractionation or rectification column
    • B01D3/143Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
    • B01D3/145One step being separation by permeation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729Changing the branching point of an open chain or the point of substitution on a ring
    • C07C5/2732Catalytic processes
    • C07C5/2737Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729Changing the branching point of an open chain or the point of substitution on a ring
    • C07C5/2732Catalytic processes
    • C07C5/2754Catalytic processes with metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767Changing the number of side-chains
    • C07C5/277Catalytic processes
    • C07C5/2775Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/04Purification; Separation; Use of additives by distillation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/12Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14Fractional distillation or use of a fractionation or rectification column
    • B01D3/32Other features of fractionating columns ; Constructional details of fractionating columns not provided for in groups B01D3/16 - B01D3/30
    • B01D3/322Reboiler specifications
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/74Noble metals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2019116113A 2018-06-29 2019-06-24 疑似移動床における工程および三分画塔を介した分画化の工程を用いたパラキシレンの製造方法 Active JP7441615B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1856050A FR3083230B1 (fr) 2018-06-29 2018-06-29 Procede de production de paraxylene utilisant une etape en lit mobile simule, et une etape de fractionnement via une colonne de 3 coupes
FR1856050 2018-06-29

Publications (3)

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JP2020023475A JP2020023475A (ja) 2020-02-13
JP2020023475A5 JP2020023475A5 (enExample) 2022-06-29
JP7441615B2 true JP7441615B2 (ja) 2024-03-01

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JP2019116113A Active JP7441615B2 (ja) 2018-06-29 2019-06-24 疑似移動床における工程および三分画塔を介した分画化の工程を用いたパラキシレンの製造方法

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US (1) US10954176B2 (enExample)
EP (1) EP3587384B1 (enExample)
JP (1) JP7441615B2 (enExample)
KR (1) KR102666617B1 (enExample)
CN (1) CN110655439B (enExample)
ES (1) ES3002662T3 (enExample)
FR (1) FR3083230B1 (enExample)
PL (1) PL3587384T3 (enExample)
PT (1) PT3587384T (enExample)
TW (1) TWI805790B (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3083231B1 (fr) * 2018-06-29 2020-07-17 Axens Procede de production de paraxylene utilisant une etape en lit mobile simule, et une etape de fractionnement de deux fractions
WO2021173238A1 (en) * 2020-02-27 2021-09-02 Exxonmobil Chemical Patents Inc. Xylene separation processes using a membrane separator
FR3116443B1 (fr) * 2020-11-24 2023-07-28 Ifp Energies Now Procédé et dispositif de production de paraxylene en lit mobile simulé réactif avec lignes de court-circuit reactives

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007512293A (ja) 2003-11-26 2007-05-17 アンスティテュ フランセ デュ ペトロール 1回の吸着工程と、2回の異性化工程とを包含するパラキシレンを製造する方法
JP2009520592A (ja) 2005-12-22 2009-05-28 アンスティテュ フランセ デュ ペトロール Euoゼオライトと、10mrゼオライトと、12mrゼオライトとを含む触媒および芳香族c8化合物の異性化におけるその使用
US20130158330A1 (en) 2011-12-15 2013-06-20 Uop Llc Process and Apparatus for para-Xylene Production Using Multiple Adsorptive Separation Units and a Split Fractionating Column
JP2013528576A (ja) 2010-04-21 2013-07-11 エクソンモービル ケミカル パテンツ インコーポレイテッド キシレンの異性化プロセスおよびそのための触媒
JP2014501704A (ja) 2010-10-29 2014-01-23 エクソンモービル ケミカル パテンツ インコーポレイテッド パラキシレンの製造方法
JP2014108962A (ja) 2012-12-03 2014-06-12 IFP Energies Nouvelles パラキシレンの高生産性製造のための、擬似向流クロマト分離のための方法および装置
US20140179975A1 (en) 2012-12-26 2014-06-26 Uop Llc Split-shell raffinate columns and methods for use in continuous adsorptive separation processes
US20170210682A1 (en) 2014-07-18 2017-07-27 IFP Energies Nouvelles Process for the production of high-purity paraxylene from a xylenes cut, using two simulated moving bed separation units operating in series and two isomerization units.
US20170247301A1 (en) 2016-02-26 2017-08-31 Exxonmobil Chemical Patents Inc. Paraxylene Separation Process
JP2018514546A (ja) 2015-04-30 2018-06-07 エクソンモービル・ケミカル・パテンツ・インク パラキシレンを製造するプロセスおよび装置

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7553998B2 (en) * 2006-06-21 2009-06-30 Uop Llc Energy-efficient process for para-xylene production
FR3005059A1 (fr) * 2013-04-26 2014-10-31 Axens Procede d'hydrogenation d'une charge d'hydrocarbures comprenant des composes aromatiques
FR3010911B1 (fr) * 2013-09-20 2017-06-09 Ifp Energies Now Procede de separation des xylenes par contre courant simule traitant une charge contenant des impuretes oxygenees aromatiques de type phenols
FR3023842B1 (fr) * 2014-07-18 2017-11-24 Ifp Energies Now Procede de production de paraxylene a haute purete a partir d'une coupe xylene, procede utilisant une unite de separation en lit mobile simule et deux unites d'isomerisation, l'une en phase gaz l'autre en phase liquide.
FR3023841B1 (fr) 2014-07-18 2016-07-15 Ifp Energies Now Procede de production de paraxylene comprenant deux unites de separation en lit mobile simule et deux unites d'isomerisation dont l'une en phase gaz
US9517980B2 (en) * 2015-04-30 2016-12-13 Exxonmobil Chemical Patents Inc. Process and apparatus for the production of para-xylene

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007512293A (ja) 2003-11-26 2007-05-17 アンスティテュ フランセ デュ ペトロール 1回の吸着工程と、2回の異性化工程とを包含するパラキシレンを製造する方法
JP2009520592A (ja) 2005-12-22 2009-05-28 アンスティテュ フランセ デュ ペトロール Euoゼオライトと、10mrゼオライトと、12mrゼオライトとを含む触媒および芳香族c8化合物の異性化におけるその使用
JP2013528576A (ja) 2010-04-21 2013-07-11 エクソンモービル ケミカル パテンツ インコーポレイテッド キシレンの異性化プロセスおよびそのための触媒
JP2014501704A (ja) 2010-10-29 2014-01-23 エクソンモービル ケミカル パテンツ インコーポレイテッド パラキシレンの製造方法
US20130158330A1 (en) 2011-12-15 2013-06-20 Uop Llc Process and Apparatus for para-Xylene Production Using Multiple Adsorptive Separation Units and a Split Fractionating Column
JP2014108962A (ja) 2012-12-03 2014-06-12 IFP Energies Nouvelles パラキシレンの高生産性製造のための、擬似向流クロマト分離のための方法および装置
US20140179975A1 (en) 2012-12-26 2014-06-26 Uop Llc Split-shell raffinate columns and methods for use in continuous adsorptive separation processes
US20170210682A1 (en) 2014-07-18 2017-07-27 IFP Energies Nouvelles Process for the production of high-purity paraxylene from a xylenes cut, using two simulated moving bed separation units operating in series and two isomerization units.
JP2018514546A (ja) 2015-04-30 2018-06-07 エクソンモービル・ケミカル・パテンツ・インク パラキシレンを製造するプロセスおよび装置
US20170247301A1 (en) 2016-02-26 2017-08-31 Exxonmobil Chemical Patents Inc. Paraxylene Separation Process

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Publication number Publication date
CN110655439A (zh) 2020-01-07
ES3002662T3 (en) 2025-03-07
US20200002252A1 (en) 2020-01-02
PL3587384T3 (pl) 2025-04-22
EP3587384A1 (fr) 2020-01-01
TWI805790B (zh) 2023-06-21
EP3587384B1 (fr) 2024-09-18
KR20200002662A (ko) 2020-01-08
KR102666617B1 (ko) 2024-05-16
FR3083230A1 (fr) 2020-01-03
FR3083230B1 (fr) 2021-04-23
US10954176B2 (en) 2021-03-23
CN110655439B (zh) 2024-06-18
JP2020023475A (ja) 2020-02-13
TW202005937A (zh) 2020-02-01
PT3587384T (pt) 2024-12-23

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