CN110655439B - 使用模拟移动床中的步骤和经由三馏分塔分馏的步骤来生产对二甲苯的方法 - Google Patents

使用模拟移动床中的步骤和经由三馏分塔分馏的步骤来生产对二甲苯的方法 Download PDF

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CN110655439B
CN110655439B CN201910575139.1A CN201910575139A CN110655439B CN 110655439 B CN110655439 B CN 110655439B CN 201910575139 A CN201910575139 A CN 201910575139A CN 110655439 B CN110655439 B CN 110655439B
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fraction
desorbent
xylene
raffinate
column
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CN110655439A (zh
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I.普雷沃
J.皮古里耶
P-Y.马丁
A.科特
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Axens SA
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    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/005Processes comprising at least two steps in series
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767Changing the number of side-chains
    • C07C5/277Catalytic processes
    • C07C5/2791Catalytic processes with metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D15/00Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08Selective adsorption, e.g. chromatography
    • B01D15/10Selective adsorption, e.g. chromatography characterised by constructional or operational features
    • B01D15/18Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to flow patterns
    • B01D15/1814Recycling of the fraction to be distributed
    • B01D15/1821Simulated moving beds
    • B01D15/185Simulated moving beds characterised by the components to be separated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14Fractional distillation or use of a fractionation or rectification column
    • B01D3/141Fractional distillation or use of a fractionation or rectification column where at least one distillation column contains at least one dividing wall
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14Fractional distillation or use of a fractionation or rectification column
    • B01D3/143Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14Fractional distillation or use of a fractionation or rectification column
    • B01D3/143Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
    • B01D3/145One step being separation by permeation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02Monocyclic hydrocarbons
    • C07C15/067C8H10 hydrocarbons
    • C07C15/08Xylenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729Changing the branching point of an open chain or the point of substitution on a ring
    • C07C5/2732Catalytic processes
    • C07C5/2737Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729Changing the branching point of an open chain or the point of substitution on a ring
    • C07C5/2732Catalytic processes
    • C07C5/2754Catalytic processes with metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767Changing the number of side-chains
    • C07C5/277Catalytic processes
    • C07C5/2775Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
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    • CCHEMISTRY; METALLURGY
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
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    • C07C7/13Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14Fractional distillation or use of a fractionation or rectification column
    • B01D3/32Other features of fractionating columns ; Constructional details of fractionating columns not provided for in groups B01D3/16 - B01D3/30
    • B01D3/322Reboiler specifications
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/74Noble metals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201910575139.1A 2018-06-29 2019-06-28 使用模拟移动床中的步骤和经由三馏分塔分馏的步骤来生产对二甲苯的方法 Active CN110655439B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1856050A FR3083230B1 (fr) 2018-06-29 2018-06-29 Procede de production de paraxylene utilisant une etape en lit mobile simule, et une etape de fractionnement via une colonne de 3 coupes
FR1856050 2018-06-29

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CN110655439A CN110655439A (zh) 2020-01-07
CN110655439B true CN110655439B (zh) 2024-06-18

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US (1) US10954176B2 (enExample)
EP (1) EP3587384B1 (enExample)
JP (1) JP7441615B2 (enExample)
KR (1) KR102666617B1 (enExample)
CN (1) CN110655439B (enExample)
ES (1) ES3002662T3 (enExample)
FR (1) FR3083230B1 (enExample)
PL (1) PL3587384T3 (enExample)
PT (1) PT3587384T (enExample)
TW (1) TWI805790B (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3083231B1 (fr) * 2018-06-29 2020-07-17 Axens Procede de production de paraxylene utilisant une etape en lit mobile simule, et une etape de fractionnement de deux fractions
WO2021173238A1 (en) * 2020-02-27 2021-09-02 Exxonmobil Chemical Patents Inc. Xylene separation processes using a membrane separator
FR3116443B1 (fr) * 2020-11-24 2023-07-28 Ifp Energies Now Procédé et dispositif de production de paraxylene en lit mobile simulé réactif avec lignes de court-circuit reactives

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1886357A (zh) * 2003-11-26 2006-12-27 法国石油公司 包括一个吸附步骤和两个异构化步骤的制备对二甲苯的方法
CN107531590A (zh) * 2015-04-30 2018-01-02 埃克森美孚化学专利公司 用于生产对二甲苯的方法和装置

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2895283B1 (fr) 2005-12-22 2008-02-01 Inst Francais Du Petrole Catalyseur comprenant une zeolithe euo, une zeolithe 10mr et une zeolithe 12mr et son utilisation en isomerisation des composes c8 aromatiques
US7553998B2 (en) * 2006-06-21 2009-06-30 Uop Llc Energy-efficient process for para-xylene production
CA2796341C (en) 2010-04-21 2014-12-30 Exxonmobil Chemical Patents Inc. Xylene isomerization process and catalyst therefor
CN103201240B (zh) 2010-10-29 2015-11-25 埃克森美孚化学专利公司 对二甲苯的制备方法
US8802914B2 (en) * 2011-12-15 2014-08-12 Uop Llc Process and apparatus for para-xylene production using multiple adsorptive separation units and a split fractionating column
FR2998807B1 (fr) 2012-12-03 2015-10-16 IFP Energies Nouvelles Procede et dispositif de separation chromatographique a contre-courant simule pour la production de paraxylene a haute productivite
US20140179975A1 (en) * 2012-12-26 2014-06-26 Uop Llc Split-shell raffinate columns and methods for use in continuous adsorptive separation processes
FR3005059A1 (fr) * 2013-04-26 2014-10-31 Axens Procede d'hydrogenation d'une charge d'hydrocarbures comprenant des composes aromatiques
FR3010911B1 (fr) * 2013-09-20 2017-06-09 Ifp Energies Now Procede de separation des xylenes par contre courant simule traitant une charge contenant des impuretes oxygenees aromatiques de type phenols
FR3023840B1 (fr) 2014-07-18 2016-07-15 Ifp Energies Now Procede de production de paraxylene a haute purete a partir d'une coupe xylenes, utilisant deux unites de separation en lit mobile simule fonctionnant en serie et deux unites d'isomerisation.
FR3023842B1 (fr) * 2014-07-18 2017-11-24 Ifp Energies Now Procede de production de paraxylene a haute purete a partir d'une coupe xylene, procede utilisant une unite de separation en lit mobile simule et deux unites d'isomerisation, l'une en phase gaz l'autre en phase liquide.
FR3023841B1 (fr) 2014-07-18 2016-07-15 Ifp Energies Now Procede de production de paraxylene comprenant deux unites de separation en lit mobile simule et deux unites d'isomerisation dont l'une en phase gaz
US9517980B2 (en) * 2015-04-30 2016-12-13 Exxonmobil Chemical Patents Inc. Process and apparatus for the production of para-xylene
US9850186B2 (en) 2016-02-26 2017-12-26 Exxonmobil Chemical Patents Inc. Paraxylene separation process

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1886357A (zh) * 2003-11-26 2006-12-27 法国石油公司 包括一个吸附步骤和两个异构化步骤的制备对二甲苯的方法
CN107531590A (zh) * 2015-04-30 2018-01-02 埃克森美孚化学专利公司 用于生产对二甲苯的方法和装置

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CN110655439A (zh) 2020-01-07
ES3002662T3 (en) 2025-03-07
US20200002252A1 (en) 2020-01-02
PL3587384T3 (pl) 2025-04-22
EP3587384A1 (fr) 2020-01-01
TWI805790B (zh) 2023-06-21
EP3587384B1 (fr) 2024-09-18
KR20200002662A (ko) 2020-01-08
KR102666617B1 (ko) 2024-05-16
JP7441615B2 (ja) 2024-03-01
FR3083230A1 (fr) 2020-01-03
FR3083230B1 (fr) 2021-04-23
US10954176B2 (en) 2021-03-23
JP2020023475A (ja) 2020-02-13
TW202005937A (zh) 2020-02-01
PT3587384T (pt) 2024-12-23

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