JP7420366B2 - Method for producing Duttan buckwheat bran in which rutin decomposition is suppressed, and its use - Google Patents
Method for producing Duttan buckwheat bran in which rutin decomposition is suppressed, and its use Download PDFInfo
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- JP7420366B2 JP7420366B2 JP2019155479A JP2019155479A JP7420366B2 JP 7420366 B2 JP7420366 B2 JP 7420366B2 JP 2019155479 A JP2019155479 A JP 2019155479A JP 2019155479 A JP2019155479 A JP 2019155479A JP 7420366 B2 JP7420366 B2 JP 7420366B2
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- Prior art keywords
- rutin
- bran
- buckwheat
- roasted
- duttan
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Description
本発明は、ルチンの分解が抑制されたダッタンソバふすまの製造方法、及びその利用に関する。 The present invention relates to a method for producing Duttan buckwheat bran in which the decomposition of rutin is suppressed, and its use.
ダッタンソバはタデ科の一年草である。ダッタンソバの子実には機能性成分のルチンが普通種ソバと比べ、品種により20~1,000倍も多い。ルチンは、子実に含まれるルチン分解酵素が作用することにより苦みの原因となるケルセチンを生じる。そのため、ソバ粉の製造工程においては、ルチン分解酵素を失活させるために加熱処理することが検討されてきた(特許文献1~4、非特許文献1)。また、ルチン分解酵素活性値が一定以下であるダッタンソバ粉を用いたルチン高含有の食品・飲料が開発されている(特許文献5、6)。 Buckwheat is an annual plant belonging to the Polygonaceae family. The grains of Datta buckwheat contain 20 to 1,000 times more rutin, a functional component, than regular buckwheat, depending on the variety. Rutin produces quercetin, which causes bitterness, through the action of the rutin-degrading enzyme contained in the fruit. Therefore, in the production process of buckwheat flour, heat treatment has been considered to inactivate the rutin-degrading enzyme (Patent Documents 1 to 4, Non-Patent Document 1). In addition, foods and beverages containing high rutin using Duttan buckwheat flour whose rutin-degrading enzyme activity value is below a certain level have been developed (Patent Documents 5 and 6).
一方、ダッタンソバは一般的にはソバ粉の状態で流通している。ソバ粉は、玄ソバ(子実)のままロール製粉し、粉砕物をふるいで分別することにより製造される。その際、ふるいに残った残渣のうち大きな物はソバ殻などであり、通常は廃棄され、粒径の小さい残渣画分はふすまである。通常、玄ソバの約1割がふすまとなる。ルチン含量の高いダッタンソバふすまを、所定の条件で焙煎等の加熱加工することで、嗜好性の高い飲料や食品用の食品素材とすることが提案されている(特許文献7)。 On the other hand, Duttan soba is generally distributed in the form of buckwheat flour. Buckwheat flour is produced by roll-milling brown buckwheat (seeds) and separating the crushed product with a sieve. At this time, the large residues remaining on the sieve are buckwheat hulls, etc., and are usually discarded, and the residue fraction with small particle sizes is bran. Usually, about 10% of brown soba is bran. It has been proposed to heat-process Duttan buckwheat bran, which has a high rutin content, such as roasting under predetermined conditions to make it into a food material for highly palatable beverages and foods (Patent Document 7).
ダッタンソバふすまには、ソバ粉の5~10倍のルチンが含まれる。またダッタンソバふすまは、ソバ粉に比較して、タンパク質、脂質、食物繊維が多く含まれ、鉄、亜鉛、マンガン等のミネラルも豊富である。そのため、ダッタンソバふすまを、より有効に利用することができれば望ましい。 Buckwheat bran contains 5 to 10 times more rutin than buckwheat flour. Furthermore, compared to buckwheat flour, Duttan buckwheat bran contains more protein, fat, and dietary fiber, and is also rich in minerals such as iron, zinc, and manganese. Therefore, it would be desirable to be able to use Duttan buckwheat bran more effectively.
しかしながら、ダッタンソバふすまにはルチン分解酵素が含まれており、ルチン分解酵素を失活させるために加熱処理することで、ルチン自体が熱分解してしまうという問題があることが分かった。ダッタンソバふすまに関しては、分解されずに残存するルチンが70%以上であれば、味には影響しないと考えられるため、ルチン残存率70%以上を達成できる技術があれば望ましい。 However, it has been found that buckwheat bran contains a rutin-degrading enzyme, and when heat-treated to inactivate the rutin-degrading enzyme, the rutin itself is thermally decomposed. Regarding Duttan buckwheat bran, if rutin remains undecomposed and remains at 70% or more, it is considered that the taste will not be affected, so it would be desirable to have a technology that can achieve a rutin residual rate of 70% or more.
また、従来のソバ粉におけるルチン分解酵素を失活させるための処理条件は、製麺を想定した加水条件でのルチン残存率や、加水後の比較的短い時間経過した時点でのルチン残存率を指標としている。そのため、その処理条件が、麺以外の食品の製造や、加水後保蔵される場合においても有効かは不明であった。 In addition, the conventional treatment conditions for inactivating the rutin-degrading enzyme in buckwheat flour are based on the rutin residual rate under water-added conditions assuming noodle production, and the rutin residual rate after a relatively short period of time after water is added. It is used as an indicator. Therefore, it was unclear whether these processing conditions would be effective in the production of foods other than noodles, or in cases where foods are stored after adding water.
本発明者らは、ダッタンソバふすまにおいてルチン分解を抑制するための技術について鋭意検討した。その結果、ダッタンソバふすまに適したルチン分解酵素失活条件を見出し、本発明を完成した。本願は、以下の発明を提供する。 The present inventors have intensively studied techniques for suppressing rutin decomposition in Duttan buckwheat bran. As a result, they found conditions for inactivating rutin-degrading enzymes suitable for Duttan buckwheat bran, and completed the present invention. This application provides the following inventions.
[1] ダッタンソバのふすまを、140~195℃ 、5~50分の焙煎条件で焙煎し、これによりふすまに含まれるルチンの熱分解を抑制しつつ、ふすまに含まれるルチン分解酵素を失活させる工程を含む、焙煎ダッタンソバふすまの製造方法。
[2] 焙煎条件が、140~165℃、15分以下である、1に記載の製造方法。
[3] 焙煎条件が、155~195℃、20分以上である、1に記載の製造方法。
[4] ルチンの含量が40mg/g以上であり、ルチン分解酵素が失活化されている、焙煎ダッタンソバふすま。
[5] 4に記載の焙煎ダッタンソバふすまを含む、食品組成物。
[6] ルチン残存率が70%以上である、焙煎ダッタンソバふすま含有食品組成物。
[7] 麺、又はガレットである、6に記載の食品組成物。
[8] 一日摂取量あたり、又は一回摂取量あたり、300~500mgのルチン又は5~10gの焙煎ダッタンソバふすまを含む、5~7のいずれか1項に記載の食品組成物。
[9] ダッタンソバの品種が、満点きらりである、1~3のいずれか1項に記載の製造方法、4に記載の焙煎ダッタンソバふすま、又は5~8のいずれか1項に記載の食品組成物。
[1] The bran of Duttan buckwheat is roasted at 140-195℃ for 5-50 minutes, thereby suppressing the thermal decomposition of rutin contained in the bran and losing the rutin-degrading enzyme contained in the bran. A method for producing roasted Dattan buckwheat bran, including a step of activating it.
[2] The manufacturing method according to 1, wherein the roasting conditions are 140 to 165°C for 15 minutes or less.
[3] The manufacturing method according to 1, wherein the roasting conditions are 155 to 195°C for 20 minutes or more.
[4] Roasted buckwheat bran with a rutin content of 40 mg/g or more and rutin-degrading enzymes inactivated.
[5] A food composition comprising the roasted buckwheat bran according to 4.
[6] A food composition containing roasted Dattan buckwheat bran, which has a rutin residual rate of 70% or more.
[7] The food composition according to 6, which is noodles or galettes.
[8] The food composition according to any one of items 5 to 7, comprising 300 to 500 mg of rutin or 5 to 10 g of roasted buckwheat bran per daily intake or per single intake.
[9] The production method according to any one of 1 to 3, wherein the variety of Datta buckwheat is Full Kirari, the roasted Datta buckwheat bran according to 4, or the food composition according to any one of 5 to 8. thing.
ダッタンソバふすまに適した条件で、ルチン分解酵素を失活できる。 Rutin-degrading enzymes can be inactivated under conditions suitable for buckwheat bran.
ルチン分解酵素が十分に失活処理されているため、様々な食品に利用できる、焙煎ダッタンソバふすまを提供できる。またルチンを多く含むため、少量用いることでルチンを多く含む食品が製造できる、焙煎ダッタンソバふすまを提供できる。 Since the rutin-degrading enzyme has been sufficiently inactivated, it is possible to provide roasted buckwheat bran that can be used in a variety of foods. In addition, since it contains a large amount of rutin, it is possible to provide roasted buckwheat bran that can be used to produce a food containing a large amount of rutin by using a small amount.
様々な食品に利用できるため、ダッタンソバふすまの食品素材としての利用が拡大できる。 Since it can be used in a variety of foods, the use of Duttan buckwheat bran as a food ingredient can be expanded.
<ダッタンソバのふすまの製造方法>
本願は、ダッタンソバのふすまを、140~195℃、5~50分の焙煎条件で焙煎し、これによりふすまに含まれるルチンの熱分解を抑制しつつ、ふすまに含まれるルチン分解酵素を失活させる工程を含む、焙煎ダッタンソバふすまの製造方法を提供する。
<Method for producing Duttan buckwheat bran>
In this application, the bran of Duttan buckwheat is roasted at 140 to 195°C for 5 to 50 minutes, thereby suppressing the thermal decomposition of rutin contained in the bran and depleting the rutin-degrading enzyme contained in the bran. To provide a method for producing roasted Duttan buckwheat bran, including a step of activating it.
(ダッタンソバ)
本発明にはダッタンソバ(韃靼蕎麦、学名:Fagopyrum tataricum)が用いられる。ダッタンソバの品種には、信永イエロー、北海T8号、北海T9号、北海T10号、北陸4号、気の力、気の宝、気の豊、大禅、信濃くろつぶ、ダルマだったん、イオンの黄彩、満天きらり、西のはるか等がある。本発明に用いるダッタンソバの品種には特に制限はないが、苦みが少なくルチン含量が多い点で、満天きらりを用いることが好ましい。
(Duttan Soba)
In the present invention, Tartary buckwheat (scientific name: Fagopyrum tataricum) is used. Varieties of Datta buckwheat include Shin'aga Yellow, Hokkai T8, Hokkai T9, Hokkai T10, Hokuriku 4, Ki Power, Ki no Takara, Ki No Toyo, Daizen, Shinano Kurotsubu, Daruma Dan, and Aeon's. There are yellow colors, Manten Kirari, Nishi no Haruka, etc. Although there are no particular restrictions on the variety of Datta buckwheat used in the present invention, it is preferable to use Manten Kirari because it has low bitterness and high rutin content.
(ダッタンソバふすま)
本発明にはダッタンソバのふすまが用いられる。ふすまは、ソバ殻とソバ粉を得る胚乳の間の層に由来し、ソバ粉を製造する際に副生される。一般的には、玄ソバ(子実)をロール製粉し、粉砕物をふるいで分別することによりソバ粉を製造する際に、ふるいに残った残渣のうち大きな物はソバ殻などであり、粒径の小さい残渣画分をふすまとして得ることができる。ダッタンソバふすまには、ソバ粉の5~10倍のルチンが含まれる。
(Duttan buckwheat bran)
In the present invention, bran of Datta buckwheat is used. Bran originates from the layer between the buckwheat husk and the endosperm from which buckwheat flour is obtained, and is a by-product during the production of buckwheat flour. Generally, when buckwheat flour is produced by roll-milling brown buckwheat (seeds) and separating the crushed material through a sieve, the large residues remaining on the sieve are buckwheat husks and grains. A residue fraction with a small diameter can be obtained as bran. Buckwheat bran contains 5 to 10 times more rutin than buckwheat flour.
ルチンは、ケルセチンの3位に二糖のβ-ルチノース(6-O-α-L-ラムノシル-β-D-グルコース)がグリコシド結合したフラボノイド配糖体である。ルトシドあるいは、ケルセチン3-O-ルチノシドと称されることもある。ダッタンソバのソバ粉については、麺等に加工した際に、内在するルチン分解酵素によってルチンが分解され、ルチン含量が低下することが知られている。ルチンの分解により生じたケルセチンは苦みを呈する。 Rutin is a flavonoid glycoside in which the disaccharide β-rutinose (6-O-α-L-rhamnosyl-β-D-glucose) is glycosidic bonded to the 3rd position of quercetin. It is also called rutoside or quercetin 3-O-rutinoside. It is known that when buckwheat flour from Duttan buckwheat is processed into noodles, etc., rutin is degraded by the endogenous rutin-degrading enzyme, resulting in a decrease in rutin content. Quercetin produced by the decomposition of rutin has a bitter taste.
なお、本明細書でダッタンソバふすまというとき、焙煎前の生のものを指す場合と、焙煎後のものを指す場合があるが、どちらを指しているかは文脈から判断できる。 In this specification, when we refer to buckwheat bran, we may refer to the raw one before roasting or to the bran after roasting, but which one is referred to can be determined from the context.
(焙煎条件)
本発明では、ダッタンソバふすまを、ふすまに含まれるルチンの熱分解を抑制しつつ、ふすまに含まれるルチン分解酵素を失活させる条件で、焙煎する。
(Roasting conditions)
In the present invention, buckwheat bran is roasted under conditions that suppress the thermal decomposition of rutin contained in the bran and deactivate the rutin-degrading enzyme contained in the bran.
焙煎は、乾煎り、ローストと称されることもあるが、熱媒体として油や水を使わずに食材を加熱乾燥させる処理をいう。本発明でダッタンソバふすまを焙煎する際、焙煎のための装置には特に制限はなく、従来技術の焙煎装置を用いることができる。焙煎は、むらなく確実に加熱されるよう、食材を撹拌しながら行ってもよい。 Roasting, sometimes referred to as dry roasting or roasting, is a process of heating and drying food without using oil or water as a heat medium. When roasting buckwheat bran in the present invention, there are no particular restrictions on the roasting device, and any conventional roasting device can be used. Roasting may be done while stirring the food to ensure even heating.
ルチンの熱分解を抑制しつつ、ルチン分解酵素を失活させる焙煎条件は、具体的には、温度は140~195℃であり、時間は5~50分である。 Specifically, the roasting conditions for deactivating the rutin-degrading enzyme while suppressing the thermal decomposition of rutin include a temperature of 140 to 195°C and a time of 5 to 50 minutes.
本発明者らの検討によると、ダッタンソバふすまに含まれるルチンは、140℃では90分焙煎しても分解せず、また160℃では40分焙煎しても分解しない。しかし、180℃では15分の焙煎で一部のルチンが分解し、200℃では7分の焙煎でかなりの部分のルチンが分解する。なお本発明に関し、ルチンの分解の程度を評価するときは、特に記載した場合を除き、ルチンの含量とルチンの分解産物であるケルセチンの含量を測定し、それらの値に基づいて計算されたルチン残存率に拠る。ルチン残存率の計算方法は、本明細書の実施例の項に詳細に記載されている。 According to studies by the present inventors, rutin contained in Duttan buckwheat bran does not decompose even after roasting for 90 minutes at 140°C, and does not decompose even after roasting for 40 minutes at 160°C. However, at 180℃, some rutin decomposes after 15 minutes of roasting, and at 200℃, a significant portion of rutin decomposes after 7 minutes of roasting. Regarding the present invention, when evaluating the degree of decomposition of rutin, unless otherwise specified, the content of rutin and the content of quercetin, which is a decomposition product of rutin, are measured, and the rutin content calculated based on these values is Depends on survival rate. The method for calculating the residual rate of rutin is described in detail in the Examples section of this specification.
また本発明者らの検討によると、ダッタンソバふすまに含まれるルチン分解酵素は、140℃では90分焙煎しても完全には失活せずにルチンを分解する活性が残るが、160~180℃では30分、200℃では7分焙煎することにより、ほぼ完全に活性がみられなくなる。なお本発明に関し、ルチン分解酵素の活性を評価するときは、特に記載した場合を除き、ルチン減少率に拠る。ルチン減少率の計算方法は、本明細書の実施例の項に詳細に記載されている。 Furthermore, according to the studies conducted by the present inventors, the rutin-degrading enzyme contained in Duttan buckwheat bran is not completely deactivated even after roasting for 90 minutes at 140°C, and the activity to decompose rutin remains. Roasting for 30 minutes at ℃ and 7 minutes at 200℃ will almost completely eliminate the activity. Regarding the present invention, when evaluating the activity of rutin-degrading enzyme, it is based on the rutin reduction rate, unless otherwise specified. The method for calculating the rutin reduction rate is described in detail in the Examples section of this specification.
好ましい態様の一つでは、焙煎条件は、140~165℃、15分以下(5~15分)であり、155~165℃、12分以下(5~12分)であることがより好ましい。この焙煎条件であれば、ルチンの熱分解はほとんどなく、また得られた焙煎ダッタンソバふすまを製麺条件で加水した場合であっても、ルチン分解酵素による影響が少ない。
なお、加水率(%)は、粉類に対して使用する水又は塩水の質量%をいい、例えばダッタンソバふすま1kgに対して水500gを使用することを、50%加水という。
In one preferred embodiment, the roasting conditions are 140 to 165°C for 15 minutes or less (5 to 15 minutes), and more preferably 155 to 165°C for 12 minutes or less (5 to 12 minutes). Under these roasting conditions, there is almost no thermal decomposition of rutin, and even when the obtained roasted buckwheat bran is hydrated under noodle-making conditions, there is little influence by rutin-degrading enzymes.
Note that the hydration rate (%) refers to the mass % of water or salt water used for flour, and for example, using 500 g of water for 1 kg of Duttan buckwheat bran is called 50% hydration.
別の好ましい態様では、焙煎条件は、155~195℃、20分以上である(20~50分)であろ、160~180℃、30~40分であることがより好ましい。この焙煎条件であれば、ルチンの熱分解はほとんどなく、また得られた焙煎ダッタンソバふすまを配合したガレットを製造する場合のような高い加水率で用いた場合であっても、ルチン分解酵素による影響が少ない。 In another preferred embodiment, the roasting conditions are 155-195°C for 20 minutes or more (20-50 minutes), more preferably 160-180°C for 30-40 minutes. Under these roasting conditions, there is almost no thermal decomposition of rutin, and even when used at a high hydration rate, such as when producing a galette containing the roasted Dattan buckwheat bran, rutin degrading enzyme There is little influence from
<焙煎ダッタンソバふすま、焙煎ダッタンソバふすま含有食品>
本願はまた、上述の焙煎条件による焙煎工程を含む製造方法により製造された、ダッタンソバふすま、及びその焙煎ダッタンソバふすまを含有する食品組成物を提供する。
<Roasted Dattan buckwheat bran, foods containing roasted Dattan buckwheat bran>
The present application also provides Datta buckwheat bran produced by a production method including a roasting step under the above-mentioned roasting conditions, and a food composition containing the roasted Datta buckwheat bran.
(ルチン含量、ルチン分解酵素の失活化、ルチン残存率)
本発明により提供される焙煎ダッタンソバふすまのルチンの含量は、40mg/g以上であり、好ましくは45mg/g以上であり、より好ましくは50mg/mg以上である。なお、焙煎ダッタンソバふすまや後述する食品組成物等に関し、ルチン含量をいうときは、特に記載した場合を除き、焙煎ダッタンソバふすまや食品の全量に対するルチンの質量として表した値である。焙煎ダッタンソバふすまの場合、全量質量は乾燥質量とほぼ一致する。
(Rutin content, rutin-degrading enzyme inactivation, rutin residual rate)
The rutin content of the roasted buckwheat bran provided by the present invention is 40 mg/g or more, preferably 45 mg/g or more, and more preferably 50 mg/mg or more. In addition, when referring to the rutin content in relation to the roasted Dattan buckwheat bran and the food compositions described below, unless otherwise specified, it is the value expressed as the mass of rutin relative to the total amount of the roasted Dattan buckwheat bran or the food. In the case of roasted Duttan buckwheat bran, the total mass almost matches the dry mass.
本発明により提供される焙煎ダッタンソバふすまにおいては、ルチン分解酵素が失活化されている。ルチン分解酵素が失活化されているとは、対象となる焙煎ダッタンソバふすまを45%又は400%加水し、室温又は4℃で24時間保蔵した場合に、ルチン残存率が70%以上であること、好ましくは75%以上であること、より好ましくは80%以上であることをいう。 In the roasted buckwheat bran provided by the present invention, the rutin degrading enzyme is inactivated. The rutin-degrading enzyme is inactivated when the rutin residual rate is 70% or more when the target roasted Dattan buckwheat bran is 45% or 400% hydrated and stored at room temperature or 4℃ for 24 hours. That is, preferably 75% or more, more preferably 80% or more.
またこのような焙煎ダッタンソバふすまは、食品素材として食品組成物に配合できる。本発明により提供される、焙煎ダッタンソバふすまを含む食品組成物は、ルチン残存率が70%以上であり、好ましくは75%以上であり、より好ましくは80%以上である。 Further, such roasted buckwheat bran can be incorporated into a food composition as a food material. The food composition containing roasted Duttan buckwheat bran provided by the present invention has a rutin residual rate of 70% or more, preferably 75% or more, and more preferably 80% or more.
ここでいうルチンの残存率は、対象となる焙煎ダッタンソバふすまについてルチンの含量とルチンの分解産物であるケルセチンの含量を測定し、それらの値に基づいて計算されたルチン残存率である。ルチン残存率の計算方法は、本明細書の実施例の項に詳細に記載されている。 The residual rate of rutin referred to herein is the residual rate of rutin calculated based on the measured values of the content of rutin and the content of quercetin, which is a decomposition product of rutin, in the target roasted buckwheat bran. The method for calculating the residual rate of rutin is described in detail in the Examples section of this specification.
(焙煎ダッタンソバふすまの配合量)
本発明により提供される焙煎ダッタンソバふすまは、ルチン分解酵素が失活化されているために製造工程等においても苦みが出にくく、食品をおいしく感じられなくなるという不都合がほとんどないと考えられる。そのため、食品組成物におけるその配合量は、付与したいルチンの量等に応じ、適宜とすることができる。
(Amount of roasted Dattan buckwheat bran)
In the roasted buckwheat bran provided by the present invention, since the rutin-degrading enzyme is inactivated, bitterness does not easily appear during the manufacturing process, and it is thought that there is almost no inconvenience that the food becomes unpalatable. Therefore, the amount of rutin added in the food composition can be determined as appropriate depending on the amount of rutin to be added.
具体的には、食品組成物の一日摂取量あたり、又は一回摂取量あたりの焙煎ダッタンソバふすまの配合量は、1~30gとすることができ、好ましくは3~20gであり、より好ましくは5~10gである。ルチンの含量としては、食品組成物の一日摂取量あたり、又は一回摂取量あたり100~700mgとすることができ、好ましくは200~600mgであり、さらに好ましくは300~500mgである。 Specifically, the amount of roasted buckwheat bran added per daily intake or per intake of the food composition can be 1 to 30 g, preferably 3 to 20 g, and more preferably is 5-10g. The content of rutin can be 100 to 700 mg per daily intake or per single intake of the food composition, preferably 200 to 600 mg, and more preferably 300 to 500 mg.
このような食品組成物は、繰り返し、又は長期間にわたって摂取してもよく、例えば毎日、又は一日おき等の間隔で、1週間以上、好ましくは4週間以上にわたって摂取することができる。 Such food compositions may be taken repeatedly or over extended periods of time, eg, daily or at intervals such as every other day, over a period of one week or more, preferably four weeks or more.
(形態)
本発明の焙煎ダッタンソバふすまを含む食品組成物の形態は、特に限定されず、固体、液体、混合物、懸濁液、粉末、顆粒、ペースト、ゼリー、ゲル、カプセル等とすることができる。
(form)
The form of the food composition containing roasted buckwheat bran of the present invention is not particularly limited, and may be solid, liquid, mixture, suspension, powder, granule, paste, jelly, gel, capsule, etc.
具体的には、菓子類(例えば、クッキー、ビスケット、クラッカー、ボーロ、スナック、スポンジケーキ、アイスクリーム、飴、チョコレート、ようかん、ういろ、まんじゅう、及び団子等)、パン類(例えば、食パン、菓子パン、ベーグル、蒸しパン、及びバターロール等)、麺類(例えば、そば、うどん、冷麺、パスタ、及びそうめん等)、ミックス粉(例えば、から揚げ粉、天ぷら粉、パン用ミックス粉、ホットケーキミックス粉、お好み焼きミックス粉、及びたこ焼きミックス粉等)、飲料(例えば、茶飲料、スープ類、青汁、スムージー)等が挙げられる、また、また飲料や食品に混合して摂取するための、顆粒、粉末、ペースト、濃厚液等の形態とすることができる。 Specifically, confectionery (e.g., cookies, biscuits, crackers, bolo, snacks, sponge cake, ice cream, candy, chocolate, yokan, fish cake, manju, dumplings, etc.), breads (e.g., white bread, sweet bread, bagels, steamed bread, butter rolls, etc.), noodles (e.g., soba, udon, cold noodles, pasta, somen, etc.), mixed flours (e.g., fried chicken flour, tempura flour, bread mix flour, pancake mix flour) , okonomiyaki mixed powder, takoyaki mixed powder, etc.), beverages (e.g., tea drinks, soups, green juice, smoothies), etc., and also granules and powders for mixing with beverages and foods. It can be in the form of , paste, concentrated liquid, etc.
なお、本発明に関し、食品というときは、固体状のものに限定されず、飲料、スープ等の液体状のものも含む。また、食品は、ヒト用のものに限定されず、コンパニオンアニマルや家畜等の非ヒト動物用のものも含む。 In the present invention, the term food is not limited to solid foods, but also includes liquid foods such as drinks and soups. Furthermore, foods are not limited to those for humans, but also include those for non-human animals such as companion animals and livestock.
(他の成分、添加剤)
焙煎ダッタンソバふすまを含む食品組成物は、ルチン以外に、食品として許容可能な他の栄養成分を含んでいてもよい。そのような成分の例は、食物繊維、タンパク質、脂質、糖質(グルコース、ショ糖、果糖、麦芽糖、トレハロース、エリスリトール、マルチトール、パラチノース、キシリトール、デキストリン)、電解質(例えば、ナトリウム、カリウム、カルシウム、マグネシウム)、アミノ酸類(例えば、リジン、アルギニン、グリシン、アラニン、グルタミン酸、ロイシン、イソロイシン、バリン)、ビタミン(例えば、ビタミンA、ビタミンB1、ビタミンB2、ビタミンB6、ビタミンB12、ビタミンC、ビタミンD、ビタミンE、ビタミンK、ビオチン、葉酸、パントテン酸及びニコチン酸類)、ミネラル(例えば、銅、亜鉛、鉄、コバルト、マンガン)、抗生物質、等である。
(Other ingredients, additives)
In addition to rutin, the food composition containing roasted buckwheat bran may contain other nutritional components that are acceptable as food. Examples of such ingredients are dietary fiber, protein, fat, carbohydrates (glucose, sucrose, fructose, maltose, trehalose, erythritol, maltitol, palatinose, xylitol, dextrin), electrolytes (e.g. sodium, potassium, calcium). , magnesium), amino acids (e.g. lysine, arginine, glycine, alanine, glutamic acid, leucine, isoleucine, valine), vitamins (e.g. vitamin A, vitamin B1, vitamin B2, vitamin B6, vitamin B12, vitamin C, vitamin D , vitamin E, vitamin K, biotin, folic acid, pantothenic acid and nicotinic acids), minerals (e.g. copper, zinc, iron, cobalt, manganese), antibiotics, etc.
(その他)
食品組成物の製造における焙煎ダッタンソバふすまの配合の段階は、適宜選択することができる。有効成分の特性を著しく損なわない限り配合の段階は特に制限されない。例えば、製造の初期の段階に、他の原材料(例えば、小麦粉等の穀類粉)に混合して配合することができる。
(others)
The stage of blending the roasted Duttan buckwheat bran in the production of the food composition can be selected as appropriate. There are no particular restrictions on the step of compounding as long as the properties of the active ingredients are not significantly impaired. For example, it can be blended with other raw materials (for example, cereal flour such as wheat flour) at an early stage of production.
焙煎ダッタンソバふすまを含む食品組成物には、ダッタンソバふすまを原材料として用いている旨、ルチン含量、ルチンの分解による苦みが少ないこと等を表示することができ、またルチンが含まれることにより期待できる特定の保健の目的(機能性)を表示することができる。表示は、直接的に又は間接的にすることができる。直接的な表示の例は、製品自体、パッケージ、容器、ラベル、タグ等の有体物への記載であり、間接的な表示は、ウェブサイト、店頭、パンフレット、チラシ、ポスター、書籍、新聞、雑誌、テレビ、ラジオ、展示会、郵送物、電子メール等の手段による、広告・宣伝活動を含む。 Food compositions containing roasted Dattan buckwheat bran can be labeled to the effect that Dattang buckwheat bran is used as a raw material, the rutin content, and the fact that there is little bitterness due to the decomposition of rutin. A specific health purpose (functionality) can be indicated. Indication can be direct or indirect. Examples of direct labeling are written on tangible objects such as the product itself, packages, containers, labels, tags, etc.; indirect labeling is on websites, storefronts, pamphlets, flyers, posters, books, newspapers, magazines, etc. Includes advertising and promotional activities by means such as television, radio, exhibitions, mail, and e-mail.
以下、実施例を用いて、本発明をさらに具体的に説明する。但し、本発明の技術的範囲は、これら実施例に限定されるものではない。 Hereinafter, the present invention will be explained in more detail using Examples. However, the technical scope of the present invention is not limited to these Examples.
[ルチン分解を抑制する処理方法の検討]
ダッタンソバふすまを様様な条件で焙煎してルチンの熱分解の有無を確認し、ルチンを熱分解させない焙煎条件を明らかにした。またダッタンソバふすまに含まれるルチン分解酵素を失活させる焙煎条件を明らかにした。さらに、焙煎したふすまを加水して保蔵し、ルチン残存率を評価した。
〔材料、方法〕
以下の実験は、特に記載した場合を除き、下記の材料、方法で行った。
[Study of treatment methods to suppress rutin decomposition]
We roasted Duttan buckwheat bran under various conditions to confirm the presence or absence of rutin thermal decomposition, and clarified the roasting conditions that do not cause rutin to thermally decompose. We also clarified the roasting conditions that deactivate the rutin-degrading enzyme contained in Duttan buckwheat bran. Furthermore, the roasted bran was stored with water and the residual rate of rutin was evaluated.
[Materials, methods]
The following experiments were conducted using the materials and methods described below, unless otherwise specified.
(ダッタンソバふすま)
ダッタンソバ品種・満点きらりから得たふすま(小林食品、北海道興部町興部865-3)を用いた。
(Duttan buckwheat bran)
Bran obtained from the Duttan buckwheat variety Manten Kirari (Kobayashi Foods, 865-3 Okobbe, Okopube-cho, Hokkaido) was used.
(焙煎)
オーブンを用いて焙煎する。オーブンは予め設定温度+10~20℃まで余熱する。(サンプル(ふすま)を入れるときに温度が下がってしまうため。)148×102×61mmの硬質アルミ製のトレーに10gのサンプルを入れ、所定の温度及び時間で、焙煎する。
(roasting)
Roast using an oven. Preheat the oven to the set temperature +10 to 20°C. (This is because the temperature drops when adding the sample (bran).) Place 10g of the sample in a 148 x 102 x 61 mm hard aluminum tray and roast at the specified temperature and time.
(ルチンの抽出:80%エタノールを用いる方法)
・標準液(標品):Rutin、Quercetinそれぞれを、100mlのメスフラスコに慎重に10mg量りとり、抽出液(80%エタノール)を注ぐ。完全に解けたら、密閉できるガラス瓶に入れて-30℃冷凍庫で保存する。
・測定装置:島津
送液ユニット;LC-20AD
脱気ユニット;DGU-20A 3R
オートサンプラー;SIL-20AC
ダイオードアレイディテクター;SPD-M20A
カラムオーブン;CTO-20AC
・カラム:Cadenza CD-C18, Imtakt, 3μm, 150×2mm
・バイアル:島津 ディスポバイアル 型番:228-31600-91
・ソルベント:
A:7.5%アセトニトリル 92.5%D.W 0.1%TFA
B:50%アセトニトリル 50%D.W 0.1%TFA
・HPLC測定条件
グラジエントなし
T. Flow;0.3 ml/min
B. Conc;35.0%
カラムオーブン温度;40℃
測定時間;20分
(Rutin extraction: method using 80% ethanol)
・Standard solution: Carefully weigh 10mg of each of Rutin and Quercetin into a 100ml volumetric flask, and pour in the extract (80% ethanol). Once completely thawed, put it in an airtight glass bottle and store it in the -30°C freezer.
・Measuring device: Shimadzu Liquid feeding unit: LC-20AD
Deaeration unit; DGU-20A 3R
Auto sampler; SIL-20AC
Diode array detector; SPD-M20A
Column oven; CTO-20AC
・Column: Cadenza CD-C18, Imtakt, 3μm, 150×2mm
・Vial: Shimadzu disposable vial model number: 228-31600-91
・Solvent:
A: 7.5% Acetonitrile 92.5%DW 0.1%TFA
B: 50% acetonitrile 50%DW 0.1%TFA
・HPLC measurement conditions: No gradient
T. Flow; 0.3 ml/min
B.Conc;35.0%
Column oven temperature: 40℃
Measurement time: 20 minutes
・手順:
1.チューブにサンプル(30mg)を量り取り、抽出液(80%エタノール)を1ml注ぐ。
2.ボルテックスにかけ、底まで混ざったのを確認して5分間、チューブミキサーで撹拌する。
3.37℃で3時間抽出する。途中1時間おきに、5分間、チューブミキサーで撹拌する。(抽出中に分析用のバイアル瓶を用意しておく)
4.3時間後、5分間、チューブミキサーで撹拌する。
5.4℃で5分間、遠心機にかける。(16000rpm)
6.上清をバイアル瓶に入れて、標準液と同時に分析する。
·procedure:
1.Weigh the sample (30mg) into a tube and pour 1ml of the extract (80% ethanol).
2. Vortex to make sure it is mixed all the way to the bottom, then stir with a tube mixer for 5 minutes.
Extract for 3 hours at 3.37°C. Stir with a tube mixer for 5 minutes every hour during the process. (Prepare a vial for analysis during extraction)
4. After 3 hours, mix with a tube mixer for 5 minutes.
Centrifuge at 5.4°C for 5 minutes. (16000rpm)
6.Pour the supernatant into a vial and analyze at the same time as the standard solution.
(ルチンの抽出:ルチン抽出液を用いる方法)
・手順
1.サンプル30 mgに、ルチン抽出液(リン酸200μl、メタノール180ml、蒸留水(HPLC用)20mlを混合して調製)を1ml加え、50℃で15分間抽出する。5分ごとに撹拌する。
2.抽出後14,000rpmで10分間遠心する。
3.上清について、「ルチンの抽出:80%エタノールを用いる方法」に記載したのと同様に、HPLCによりルチン含量を計測する。
(Rutin extraction: method using rutin extract)
·procedure
1. Add 1 ml of rutin extract (prepared by mixing 200 μl of phosphoric acid, 180 ml of methanol, and 20 ml of distilled water (for HPLC)) to 30 mg of sample, and extract at 50°C for 15 minutes. Stir every 5 minutes.
2. After extraction, centrifuge at 14,000 rpm for 10 minutes.
3. Measure the rutin content of the supernatant by HPLC in the same manner as described in "Extraction of rutin: Method using 80% ethanol."
(ルチン分解酵素活性の簡易測定)
・サンプルの準備
サンプルを、スクリューキャップに50mg測り取る。1サンプルについて、6本のチューブに測り取る。
(Simple measurement of rutin degrading enzyme activity)
・Sample preparation Measure 50mg of sample into a screw cap. Measure each sample into 6 tubes.
・手順:
1.0分サンプル:メタノール1mlをシリンジで入れる。続いて、250μLの50mM酢酸リチウムバッファーpH5.5を入れる。これを3本のチューブについて行う。
2.15分サンプル:250μLの50mM酢酸リチウムバッファーpH5.5を入れ、ボルテックスで均一になるまで撹拌する。正確に15分後にメタノール1mlをシリンジで入れボルテックスで均一になるまで撹拌する。これを3本のチューブについて行う。なお、室温で行う。
3.上記液を一晩(12時間)以上3日以内、室温で放置する。
4.ボルテックスで均一になるまで撹拌し、フィルター濾過して、「ルチンの抽出:80%エタノールを用いる方法」に記載したのと同様に、HPLCによりルチン含量を測定する。
5.0分サンプルのルチン含量と15分サンプルのルチン含量に基づき、ルチン減少率を算出する。ルチン減少率は以下の式で求める。
·procedure:
1.0 minute sample: Add 1 ml of methanol with a syringe. Subsequently, add 250 μL of 50 mM lithium acetate buffer pH 5.5. Do this for three tubes.
2.15 min sample: Add 250 μL of 50 mM lithium acetate buffer pH 5.5 and vortex until uniform. After exactly 15 minutes, add 1 ml of methanol with a syringe and stir by vortexing until uniform. Do this for three tubes. Note that this is done at room temperature.
3. Leave the above solution at room temperature for at least overnight (12 hours) and within 3 days.
4. Vortex until homogeneous, filter, and measure the rutin content by HPLC as described in "Extraction of Rutin: Method using 80% ethanol."
Calculate the rutin reduction rate based on the rutin content of the 5.0 minute sample and the rutin content of the 15 minute sample. The rutin reduction rate is calculated using the following formula.
ルチン減少率=(0分サンプルのルチン割合-15分サンプルのルチン割合)/
0分サンプルのルチン割合)×100
0分サンプルのルチン割合=(0分サンプルのルチン質量)/(0分サンプルのケルセチン質量+0分サンプルのケルセチン質量)×100
15分サンプルのルチン割合=(15分サンプルのルチン質量)/(15分サンプルのルチン質量+15分サンプルのケルセチン質量)×100
Rutin reduction rate = (rutin percentage of 0 minute sample - rutin percentage of 15 minute sample)/
Rutin percentage of 0 minute sample) x 100
Rutin ratio of 0 minute sample = (rutin mass of 0 minute sample) / (quercetin mass of 0 minute sample + quercetin mass of 0 minute sample) × 100
Rutin percentage of 15-minute sample = (rutin mass of 15-minute sample) / (rutin mass of 15-minute sample + quercetin mass of 15-minute sample) × 100
ルチン減少率の値が大きいほど15分間の反応でルチンが減少している、すなわち酵素活性が高い(=酵素が失活していない)ことを示している。そして、ルチン減少率が0%であれば酵素が失活していると判断できる。 The larger the value of the rutin reduction rate, the more rutin is reduced in a 15-minute reaction, which indicates that the enzyme activity is high (=the enzyme is not inactivated). If the rutin reduction rate is 0%, it can be determined that the enzyme is inactivated.
〔結果〕
(ルチンの熱分解)
焙煎を高温で長時間行えば、ルチン分解酵素が失活するのは当然である。しかし、酵素が失活した際にルチンが熱分解していては意味がない。そのため、熱分解の有無を確認する必要がある。従来の報告では、ルチンの熱分解を考慮していないものも見られる。
〔result〕
(Thermal decomposition of rutin)
It is natural that rutin-degrading enzymes become inactive if roasting is carried out at high temperatures for a long time. However, it is meaningless if rutin is thermally decomposed when the enzyme is deactivated. Therefore, it is necessary to confirm the presence or absence of thermal decomposition. Some previous reports do not take into account the thermal decomposition of rutin.
140℃、160℃、180℃、及び200℃で所定の時間焙煎を行ったときのルチンの分解を、ルチン含量及びケルセチン含量の測定値に基づくルチン残存率により、評価した。ルチンの抽出は、80%のエタノールを用いる方法で行った。なお、本発明者らの検討によると、ルチンの分解をルチン含量のみから評価するより、ルチンの分解産物であるケルセチン含量も考慮して評価したほうが、適切に判断できることが分かっている。ルチン残存率の計算式を、以下に示す。 The decomposition of rutin when roasting was performed at 140°C, 160°C, 180°C, and 200°C for predetermined times was evaluated by the rutin residual rate based on the measured values of rutin content and quercetin content. Rutin was extracted using 80% ethanol. According to studies conducted by the present inventors, it has been found that it is more appropriate to evaluate the decomposition of rutin by also considering the content of quercetin, which is a decomposition product of rutin, than to evaluate it only from the rutin content. The formula for calculating the rutin residual rate is shown below.
ルチン残存率=焙煎後のルチン含量/(焙煎後のルチン含量+焙煎後のケルセチン含量に相当するルチン含量)×100
ケルセチン含量に相当するルチン含量=ケルセチン含量×(ルチンのモル質量610.517 g/mol/ケルセチンのモル質量302.236 g/mol)
Rutin residual rate = Rutin content after roasting / (Rutin content after roasting + Rutin content equivalent to quercetin content after roasting) x 100
Rutin content equivalent to quercetin content = Quercetin content × (molar mass of rutin 610.517 g/mol/molar mass of quercetin 302.236 g/mol)
結果を図1Aに示した。140℃90分、160℃40分では熱分解しないが、180℃では15分以上、 200℃では6分以上加熱すると、熱分解することが明らかとなった。 The results are shown in Figure 1A. It has become clear that thermal decomposition does not occur when heated at 140°C for 90 minutes or 160°C for 40 minutes, but thermal decomposition occurs when heated at 180°C for more than 15 minutes and at 200°C for more than 6 minutes.
なお、ソバ粉(満点きらり)についても焙煎してルチン含量を測定し、ふすまの場合とともに図1Bに示した。焙煎したふすまには、焙煎したソバ粉(満点きらり)より多くのルチンが含まれていることが示された。 The rutin content of buckwheat flour (Fuzen Kirari) was also roasted and measured, and the results are shown in Figure 1B along with the case of bran. Roasted bran was shown to contain more rutin than roasted buckwheat flour (Manke Kirari).
(酵素の失活)
次に、ダッタンソバふすまのルチン分解酵素を失活させる焙煎条件を明らかにした。焙煎したダッタンソバふすま及びソバ粉に対し、ルチン分解酵素活性の簡易測定法によりルチン減少率を求め、酵素の失活を評価した。
(Deactivation of enzyme)
Next, we clarified the roasting conditions that inactivate the rutin-degrading enzyme in Duttan buckwheat bran. The rutin reduction rate was determined using a simple method for measuring rutin-degrading enzyme activity for roasted Duttan buckwheat bran and buckwheat flour, and the inactivation of the enzyme was evaluated.
結果を図2に示した。ダッタンソバふすまのルチン分解酵素は140℃では90分焙煎しても失活せず、160~180℃では30分、200℃では7分焙煎することにより、失活することが明らかになった。またソバ粉(満点きらり)とふすまでは、ふすまのほうが酵素分解による影響が大きいことが明らかになった。 The results are shown in Figure 2. It was revealed that the rutin-degrading enzyme in Duttan buckwheat bran was not inactivated even after roasting for 90 minutes at 140℃, but was deactivated by roasting for 30 minutes at 160-180℃ and 7 minutes at 200℃. . It was also revealed that between buckwheat flour (Mansaku Kirari) and wheat bran, the effect of enzymatic decomposition was greater on wheat bran.
(加水後保蔵)
各条件で焙煎したダッタンソバふすまに対して、製麺を想定した45%加水を行った場合と、ガレットを想定した400%加水を行った場合について、室温又は冷蔵(4℃)での保蔵後のルチン残存率を、上記と同様に求めた。なお、ルチンの抽出は、ルチン抽出液を用いる方法で行った。
(Stored after adding water)
After storage at room temperature or refrigerated (4℃), Duttan buckwheat bran roasted under various conditions was added with 45% water for noodle making and 400% water was added for galette. The residual rate of rutin was determined in the same manner as above. Note that rutin was extracted by a method using a rutin extract.
結果を図3A及び図3Bに示した。また、焙煎条件、熱分解の有無とともに、下表にまとめた。 The results are shown in Figures 3A and 3B. The roasting conditions and presence or absence of thermal decomposition are also summarized in the table below.
加水後にもルチン残存率70%以上を維持するためには、45%加水の場合は軽めの焙煎(例えば、160℃、10分)で良いが、400%加水の場合は強めの焙煎(例えば、160℃、40分、又は180℃、30分)がよいことが明らかになった。なお、ルチン残存率が70%以上であれば、味にも影響しないと考えられる。 In order to maintain rutin residual rate of 70% or more even after adding water, light roasting (for example, 160℃, 10 minutes) is sufficient when adding 45% water, but strong roasting is required when adding 400% water. (For example, 160°C for 40 minutes or 180°C for 30 minutes) was found to be better. Furthermore, if the rutin residual rate is 70% or more, it is considered that the taste will not be affected.
従来の報告では、加水条件が1点であったため、焙煎不足、過焙煎が懸念されるが、本発明では45%加水と400%加水との双方を行うことにより、用途に適した焙煎条件を示すことができる。 In previous reports, the water addition condition was at one point, which raised concerns about insufficient roasting and over-roasting.However, in the present invention, by adding both 45% and 400% water, roasting suitable for the purpose can be achieved. Can indicate roasting conditions.
また、冷蔵・冷凍保蔵でのルチン残存率からは、冷蔵すればルチン分解酵素が働かず、冷蔵で酵素活性が抑えられることが明らかとなった。 Furthermore, the residual rate of rutin during refrigerated and frozen storage revealed that rutin-degrading enzymes do not work if refrigerated, and that enzyme activity is suppressed by refrigeration.
[製造例]
(ソバ麺)
ダッタンソバふすまと小麦粉を、ふすま:小麦粉=1:9の重量比で配合し、常法により製麺する。
[Manufacturing example]
(Soba noodles)
Dattan buckwheat bran and wheat flour are mixed in a weight ratio of bran:flour = 1:9, and noodles are made by a conventional method.
(白パン)
下記の配合で、ダッタンソバふすまを用いた白パンを製造できる。
小麦粉 98 g
ダッタンソバふすま 2.0g
砂糖 5.0g
ショートニング 5.0g
塩 5.0g
イースト 2.0g
アスコルビン酸 100ppm
水 適量
(White bread)
White bread using Duttan buckwheat bran can be manufactured using the following formulation.
Flour 98 g
Duttan buckwheat bran 2.0g
Sugar 5.0g
Shortening 5.0g
salt 5.0g
Yeast 2.0g
Ascorbic acid 100ppm
Appropriate amount of water
(バターロール)
下記の配合で、ダッタンソバふすまを用いたバターロールを製造できる。
小麦粉 98 g
ダッタンソバふすま 2.0g
砂糖 12 g
バター 15 g
脱脂粉乳 3.0g
塩 1.8g
イースト 3.0g
全卵 10 g
アスコルビン酸 100ppm
水 適量
(butter roll)
Butter rolls using Duttan buckwheat bran can be manufactured using the following formulation.
Flour 98 g
Duttan buckwheat bran 2.0g
12 g sugar
15 g butter
Skimmed milk powder 3.0g
1.8g salt
Yeast 3.0g
10 g whole eggs
Ascorbic acid 100ppm
Appropriate amount of water
(パウンドケーキ)
下記の配合で、ダッタンソバふすまを用いたパウンドケーキを製造できる。
小麦粉 95 g
ダッタンソバふすま 5.0g
ベーキングパウダー 5.0g
バター 100 g
全卵 100 g
※170℃40分で焼く
(Pound Cake)
A pound cake using Duttan buckwheat bran can be manufactured using the following formulation.
95 g flour
Duttan buckwheat bran 5.0g
Baking powder 5.0g
100 g butter
100 g whole eggs
*Bake at 170℃ for 40 minutes.
(ガレット)
下記の配合で、ダッタンソバふすまを用いたガレットを製造できる。
小麦粉 90 g
ダッタンソバふすま 10 g
塩 1.0g
水 400mL
(Galette)
A galette using Duttan buckwheat bran can be produced with the following formulation.
90 g flour
Duttan buckwheat bran 10 g
salt 1.0g
400mL water
(クッキー)
下記の配合で、ダッタンソバふすまを用いたクッキーを製造できる。
小麦粉 30.4 g
ダッタンソバふすま 7.6 g
砂糖 13 g
全卵 19.5 g
バター 4.65g
塩 0.25g
(cookie)
Cookies using Duttan buckwheat bran can be manufactured using the following formulation.
Flour 30.4 g
Duttan buckwheat bran 7.6 g
13 g sugar
Whole egg 19.5 g
Butter 4.65g
salt 0.25g
(食パン)
下記の配合で、ダッタンソバふすまを用いた食パンを製造できる。
小麦粉 252 g
ダッタンソバふすま 28 g
砂糖 20 g
塩 4 g
バター 20 g
スキムミルク 6 g
ドライイースト 2.4g
水 190mL
(Plain bread)
Bread using Duttan buckwheat bran can be manufactured using the following formulation.
252 g flour
Duttan buckwheat bran 28 g
20 g sugar
4 g salt
20 g butter
6 g skim milk
2.4g dry yeast
190mL water
この配合で製造した食パンを8名で食味したところ、苦味を感じる人と気にならない人はほぼ半々だった。 When 8 people tasted the bread made with this mixture, almost 50-50 found that those who found the taste bitter and those who did not.
Claims (8)
製造されたふすまを用いて食品組成物を製造する、焙煎ダッタンソバふすまを含む、食品組成物の製造方法。 Roasted Dattan buckwheat bran is produced by the production method according to any one of claims 1 to 3,
A method for producing a food composition comprising roasted Dattan buckwheat bran, which comprises producing a food composition using the produced bran.
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JP2012244927A (en) | 2011-05-26 | 2012-12-13 | Toyo Suisan Kaisha Ltd | Food group including instant noodle made from tartary buckwheat flour containing rutin and having superior quality and method for producing the same |
JP2014087273A (en) | 2012-10-29 | 2014-05-15 | Habataki Kk | Method for manufacturing roasted wholegrain buckwheat flour |
JP2017153433A (en) | 2016-03-03 | 2017-09-07 | 国立研究開発法人農業・食品産業技術総合研究機構 | Method for producing high rutin-containing tartary buckwheat bran and buckwheat flour, and method for producing high rutin-containing food raw material |
JP2018191552A (en) | 2017-05-16 | 2018-12-06 | 昭和産業株式会社 | Noodle containing bran, and production method thereof |
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JP2012244927A (en) | 2011-05-26 | 2012-12-13 | Toyo Suisan Kaisha Ltd | Food group including instant noodle made from tartary buckwheat flour containing rutin and having superior quality and method for producing the same |
JP2014087273A (en) | 2012-10-29 | 2014-05-15 | Habataki Kk | Method for manufacturing roasted wholegrain buckwheat flour |
JP2017153433A (en) | 2016-03-03 | 2017-09-07 | 国立研究開発法人農業・食品産業技術総合研究機構 | Method for producing high rutin-containing tartary buckwheat bran and buckwheat flour, and method for producing high rutin-containing food raw material |
JP2018191552A (en) | 2017-05-16 | 2018-12-06 | 昭和産業株式会社 | Noodle containing bran, and production method thereof |
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