JP7397381B2 - Steel plates for hot stamping and hot stamping molded bodies - Google Patents

Description

The present invention relates to a hot stamping steel plate and a hot stamping molded article.
This application claims priority based on Japanese Patent Application No. 2020-156562 filed in Japan on September 17, 2020, the contents of which are incorporated herein.

In recent years, high-strength steel plates have been applied to automobile body parts due to demands for reducing vehicle body weight and improving collision safety. Since car body parts are formed by press forming, there is a need to improve press formability, especially shape fixability. Therefore, the hot stamping method is attracting attention as a method for manufacturing high-strength car body parts with excellent shape accuracy.

Furthermore, in recent years, a technique of applying tailored blanks to the hot stamping method has been studied. A tailored blank is a steel plate made by welding multiple steel plates with different plate thicknesses, chemical compositions, metal structures, etc. In a tailored blank, the properties of a single joined steel plate can be partially changed. For example, by giving high strength to a certain part, deformation in that part can be suppressed, and by giving low strength to another part, that part can be deformed and shock can be absorbed. Parts with low strength are required to have excellent ductility so as to suppress breakage during deformation.

As a technique for applying a tailored blank to the hot stamping method, there is a technique that uses a tailored blank in which a steel plate having low strength after hot stamping and a steel plate having high strength after hot stamping are joined by welding. As a steel plate having high strength after hot stamping, for example, a steel plate as disclosed in Patent Document 1 can be used. In order to obtain a steel plate having low strength after hot stamping, the chemical composition of the steel may be adjusted so that it has low strength after mold cooling in hot stamping.

One of the steel types used for tailored blanks is low carbon steel. Low carbon steel has a low carbon content, so it is difficult to increase its strength even if it is rapidly cooled after heating. Patent Document 2 discloses that ultra-low carbon steel is used as a low-strength material in a hot stamping method. Patent Document 2 discloses a technique for improving local deformability by hot stamping a steel plate after heating it to a temperature of Ac ₃ or higher to create a metal structure containing bainite and bainitic ferrite as the main phases. ing. Patent Document 2 discloses that this technology makes it difficult for car body parts to break when they are deformed in bending mode during a collision, and has excellent impact absorption ability due to plastic deformation.

In recent years, hot-stamped molded products having a tensile strength of less than 1500 MPa have attracted attention as high-strength materials with high crash performance. Such a hot-stamped molded product is required to have a desired strength and also to have higher ductility after hot-stamping so that fracture during deformation can be sufficiently suppressed.

Japanese Patent Application Publication No. 2004-197213 International Publication No. 2012/157581

The present invention has been made in view of the above circumstances, and aims to provide a hot-stamped molded body having high strength and excellent ductility, and a hot-stamped steel plate from which this hot-stamped molded body can be manufactured.

The present inventors investigated a method for improving the ductility of a hot-stamped molded product. As a result, they found that the ductility of a hot-stamped compact can be improved by increasing the area ratio of the hard phase with high dislocation density present on martensite in the metallographic structure of the hot-stamped compact.

In addition, the present inventors have found that the above-mentioned hot-stamped molded product can be obtained by preferably controlling the chemical composition of the hot-stamping steel sheet and increasing the number ratio of ferrite containing a hard phase in the ferrite grains. I found out.

The present invention was obtained based on the above findings, and the gist of the present invention is as follows.
(1) The hot stamping steel sheet according to one aspect of the present invention has a chemical composition in mass %,
C: 0.060-0.200%,
Si: 0.010 to 1.000%,
Mn: 1.20-3.00%,
Al: 0.010-0.500%,
P: 0.100% or less,
S: 0.0100% or less,
N: 0.0100% or less,
Nb: 0% or more, less than 0.020%,
Ti: 0 to 0.100%,
Cr: 0 to 0.50%,
B: 0 to 0.0100%,
Mo: 0-1.00%,
Co: 0-2.00%,
Ni: 0 to 0.50%,
V: 0 to 0.10%,
Ca: 0-0.0100%,
Contains Mg: 0 to 0.0100%, and REM: 0 to 0.0100%,
The remainder consists of Fe and impurities,
In the metal structure at a position of 1/4 plate thickness from the surface ,
The polar density in the {112}<110> direction at the center of the plate thickness is over 3.0,
The area ratio is 5 to 95% ferrite,
The number ratio of the ferrite containing a hard phase in the ferrite grains is 30% or more of all ferrite.
(2) The hot stamping steel sheet according to (1) above has the chemical composition in mass%,
Nb: 0.001% or more, less than 0.020%,
Ti: 0.010 to 0.100%,
Cr: 0.05-0.50%,
B: 0.0001 to 0.0100%,
Mo: 0.01-1.00%,
Co: 0.01-2.00%,
Ni: 0.01-0.50%,
V: 0.01 to 0.10%,
Ca: 0.0005-0.0100%,
Mg: 0.0005-0.0100%, and REM: 0.0005-0.0100%
It may contain one or more types from the group consisting of.
(3) The hot-stamped molded article according to another aspect of the present invention has a chemical composition in mass %,
C: 0.060-0.200%,
Si: 0.010-1.00%,
Mn: 1.20-3.00%,
Al: 0.010-0.500%,
P: 0.100% or less,
S: 0.0100% or less,
N: 0.0100% or less,
Nb: 0% or more, less than 0.020%,
Ti: 0 to 0.100%,
Cr: 0 to 0.50%,
B: 0 to 0.0100%,
Mo: 0-1.00%,
Co: 0-2.00%,
Ni: 0 to 0.50%,
V: 0 to 0.10%,
Ca: 0-0.0100%,
Contains Mg: 0 to 0.0100%, and REM: 0 to 0.0100%,
The remainder consists of Fe and impurities,
In the metal structure at a position of 1/4 plate thickness from the surface ,
In terms of area ratio, martensite is 80% or more,
The area ratio of a hard phase with a GAIQ value of 26,000 or less existing on the martensite is 1.0% or more (however, the term "existing on the martensite" refers to the lath boundaries, between the laths, and inside the laths of the martensite. , present at block boundaries, packet boundaries, and prior austenite grain boundaries) .
(4) The hot-stamped molded article according to (3) above has the chemical composition in mass %,
Nb: 0.001% or more, less than 0.020%,
Ti: 0.010 to 0.100%,
Cr: 0.05-0.50%,
B: 0.0001 to 0.0100%,
Mo: 0.01-1.00%,
Co: 0.01-2.00%,
Ni: 0.01 to 0.50%,
V: 0.01 to 0.10%,
Ca: 0.0005-0.0100%,
Mg: 0.0005-0.0100%, and REM: 0.0005-0.0100%
It may contain one or more types from the group consisting of.

According to the above aspects of the present invention, it is possible to provide a hot-stamped molded body having high strength and excellent ductility, and a hot-stamped steel plate from which this hot-stamped molded body can be manufactured.

Hereinafter, a hot stamping steel plate and a hot stamping molded article according to the present embodiment will be described in detail. First, the reason for limiting the chemical composition of the hot stamping steel sheet according to this embodiment will be explained. Note that the numerically limited range written between "~" includes the lower limit value and the upper limit value. Numerical values indicated as "less than" or "greater than" do not include the value within the numerical range. Moreover, all percentages regarding chemical compositions mean percentages by mass.

The hot-stamped molded article according to the present embodiment has a chemical composition in mass% of C: 0.060 to 0.200%, Si: 0.010 to 1.000%, and Mn: 1.20 to 3.00. %, Al: 0.010 to 0.500%, P: 0.100% or less, S: 0.0100% or less, N: 0.0100% or less, and the remainder: Fe and impurities. Each element will be explained below.

C: 0.060-0.200%
C is an element that greatly affects the strength and ductility of the hot stamped compact. If the C content is too low, martensitic transformation will not be promoted and the strength of the hot-stamped molded product will be low, making it easy to break due to insufficient strength. Therefore, the C content is set to 0.060% or more. Preferably, it is 0.080% or more, 0.100% or more, or 0.120% or more.
On the other hand, if the C content is too high, the hardness of the martensite matrix becomes too high, resulting in a decrease in the ductility of the hot-stamped molded product. Therefore, the C content is set to 0.200% or less. Preferably, it is 0.170% or less or 0.150% or less.

Si: 0.010-1.000%
Si is an element that has solid solution strengthening ability and is an element necessary to obtain strength of the hot stamp molded product. If the Si content is too low, desired strength cannot be obtained in the hot-stamped molded product. Therefore, the Si content is set to 0.010% or more. Preferably, it is 0.100% or more, 0.300% or more, or 0.500% or more.
On the other hand, if the Si content is too high, ferrite transformation will proceed excessively, making it impossible to obtain a desired amount of martensite in the hot-stamped molded product. Therefore, the Si content is set to 1.000% or less. Preferably, it is 0.900% or less or 0.800% or less.

Mn: 1.20-3.00%
Mn is an element having solid solution strengthening ability, and is included in order to obtain strength of the hot-stamped molded product. If the Mn content is too low, ferrite transformation progresses too much and martensite is difficult to generate, making it impossible to obtain the desired strength in the hot-stamped molded product. Therefore, the Mn content is set to 1.20% or more. Preferably, it is 1.40% or more or 1.60% or more.
On the other hand, if the Mn content is too high, the hardenability of the steel will increase, and the formation of ferrite during air cooling after heating during hot stamping will be suppressed, thereby reducing the ductility of the hot stamped compact. Therefore, the Mn content is set to 3.00% or less. Preferably, it is 2.80% or less or 2.60% or less.

Al: 0.010-0.500%
Al is an important element for promoting ferrite transformation. If the Al content is too low, ferrite transformation will be difficult to proceed, making it impossible to obtain a desired amount of ferrite in the hot-stamped molded product. Therefore, the Al content is set to 0.010% or more. Preferably, it is 0.020% or more or 0.030% or more.
On the other hand, if the Al content is too high, the transformation to ferrite will proceed excessively, making it impossible to obtain a desired amount of martensite in the hot-stamped molded product. Therefore, the Al content is set to 0.500% or less. Preferably, it is 0.450% or less or 0.400% or less.

P: 0.100% or less P has solid solution strengthening ability and is an effective element for obtaining desired strength in a hot stamp molded product. However, if the P content is too high, the ductility of the hot-stamped compact will deteriorate. Therefore, the P content is set to 0.100% or less. Preferably, it is 0.080% or less, 0.060% or less, or 0.050% or less.
Although the lower limit of the P content is not particularly specified, from the viewpoint of ensuring strength due to P, the P content may be set to 0.001% or more or 0.005% or more.

S: 0.0100% or less S is an element that is contained as an impurity in steel and makes the steel brittle. Therefore, the smaller the S content, the better. The S content shall be 0.0100% or less. Preferably, it is 0.0080% or less, 0.0060% or less, or 0.0040% or less.
Although the lower limit of the S content is not particularly defined, if the S content is reduced excessively, the cost in the desulfurization process will increase, so the S content may be set to 0.0005% or more or 0.0010% or more.

N: 0.0100% or less N is an impurity element that forms nitrides in steel and deteriorates the ductility of the hot stamped compact. If the N content is too high, nitrides in the steel will become coarse and the ductility of the hot stamped body will deteriorate. Therefore, the N content is set to 0.0100% or less. Preferably, it is 0.0080% or less or 0.0060% or less.
Although the lower limit of the N content is not particularly defined, the N content may be set to 0.0010% or more, since reducing the N content excessively increases the cost in the steel manufacturing process.

The hot stamping steel plate according to the present embodiment may contain the above elements, with the remainder consisting of Fe and impurities. Examples of impurities include those that are unavoidably mixed in from steel raw materials or scraps and/or during the steel manufacturing process, or elements that are allowed within a range that does not impede the properties of the hot stamp molded product according to the present embodiment.

In order to improve various properties, the hot stamping steel sheet according to the present embodiment may contain any of the following arbitrary elements in place of a part of Fe. In order to reduce the alloy cost, it is not necessary to intentionally include these arbitrary elements in the steel, so the lower limit of the content of these arbitrary elements is 0%.

Nb: 0.001% or more, less than 0.020% Nb is an element that suppresses austenite grain growth, refines austenite grains, and promotes transformation into ferrite. In order to reliably obtain this effect, the Nb content is preferably 0.001% or more.
On the other hand, if the Nb content is too high, the above effects will be saturated and the cost will increase. Therefore, the Nb content is made less than 0.020%.

Ti: 0.010-0.100%
Ti is an element that suppresses grain growth of austenite, refines the austenite grains, and promotes transformation into ferrite. In order to reliably obtain this effect, the Ti content is preferably 0.010% or more.
On the other hand, if the Ti content is too high, coarse Ti sulfides, Ti nitrides, and Ti oxides are formed, which deteriorates the formability of the steel sheet. Therefore, the Ti content is set to 0.100% or less.

Cr: 0.05-0.50%
Cr is also an effective element for improving the hardenability of steel, promoting the formation of martensite, and increasing the strength of hot-stamped compacts. In order to reliably obtain this effect, the Cr content is preferably 0.05% or more.
On the other hand, if the Cr content is too high, a large amount of coarse Cr carbide is formed which can become a starting point for fracture. Therefore, the Cr content is set to 0.50% or less.

B: 0.0001-0.0100%
B is an element that segregates in prior austenite grain boundaries, has the effect of suppressing ferrite transformation, and contributes to improving the strength of the hot-stamped compact. In order to reliably obtain this effect, the B content is preferably 0.0001% or more.
On the other hand, if the B content is too high, the ductility of the hot stamped body will be reduced. Therefore, the B content is set to 0.0100% or less.

Mo: 0.01~1.00%
Mo forms carbides in the steel and improves the strength of the hot stamped body through precipitation strengthening. In order to reliably obtain this effect, the Mo content is preferably 0.01% or more.
On the other hand, if the Mo content is too high, the ductility of the hot-stamped molded product will decrease. Therefore, the Mo content is set to 1.00% or less.

Co:0.01~2.00%
Co improves the strength of the hot stamp molded product through solid solution strengthening. In order to reliably obtain this effect, the Co content is preferably 0.01% or more.
On the other hand, if the Co content is too high, the effect of the above action will be saturated and the cost will increase. Therefore, the Co content is set to 2.00% or less.

Ni: 0.01~0.50%
Ni improves the strength of the hot stamp molded product. In order to reliably obtain this effect, the Ni content is preferably 0.01% or more.
On the other hand, if the Ni content is too high, castability may deteriorate. Therefore, the Ni content is set to 0.50% or less.

V:0.01~0.10%
V improves the strength of the hot-stamped body by strengthening the hot-stamped body by strengthening the precipitates, suppressing the grain growth of austenite, and making the austenite grains finer. In order to reliably obtain this effect, the V content is preferably 0.01% or more.
On the other hand, if the V content is too high, a large amount of carbonitrides will precipitate, reducing the formability of the steel sheet. Therefore, the V content is set to 0.10% or less.

Ca: 0.0005-0.0100%
Ca is an element that has the effect of deoxidizing molten steel and making the steel sound (suppressing the occurrence of defects such as blowholes in the steel). In order to reliably obtain this effect, the Ca content is preferably 0.0005% or more.
On the other hand, since the above effect is saturated even if the Ca content is too high, the Ca content is preferably 0.0100% or less.

Mg: 0.0005-0.0100%
Mg is an element that has the effect of deoxidizing molten steel and making the steel sound. In order to reliably obtain this effect, the Mg content is preferably 0.0005% or more.
On the other hand, if the Mg content is too high, the above effects will be saturated and the cost will increase. Therefore, the Mg content is preferably 0.0100% or less.

REM: 0.0005-0.0100%
REM is an element that has the effect of deoxidizing molten steel and making the steel sound. In order to reliably obtain this effect, it is preferable that the REM content is 0.0005% or more.
On the other hand, since the above effect is saturated even if the REM content is too high, the REM content is preferably 0.0100% or less.
Note that in this embodiment, REM refers to a total of 17 elements consisting of Sc, Y, and lanthanoids. In this embodiment, the content of REM refers to the total content of these elements.

The above-mentioned chemical composition may be measured by a general analytical method. For example, it may be measured using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometry). Note that C and S may be measured using a combustion-infrared absorption method, and N may be measured using an inert gas melting-thermal conductivity method. When the steel plate for hot stamping or the hot stamping molded article has a plating layer on the surface, the chemical composition may be analyzed after removing the plating layer on the surface by mechanical grinding.

Next, the metallographic structure of the hot stamping steel plate according to this embodiment will be explained.
In the steel sheet for hot stamping according to the present embodiment, in the metallographic structure, the polar density in the {112}<110> direction at the center of the sheet thickness is more than 3.0, and the area ratio of ferrite is 5 to 95%. , the number ratio of the ferrite containing a hard phase in the ferrite grains is 30% or more of all ferrite. Each regulation will be explained in detail below.
In addition, in this embodiment, the area ratio of the ferrite at a position of 1/4 of the plate thickness from the surface (region from 1/8 depth of the plate thickness from the surface to 3/8 depth of the plate thickness from the surface) and the area ratio of the ferrite are Specify the number ratio.

Polar density in the {112}<110> direction at the center of the plate thickness: more than 3.0 If the polar density in the {112}<110> direction at the center of the plate thickness is 3.0 or less, the desired hot stamp molded product can be obtained. metallographic structure cannot be obtained. Therefore, the pole density in the {112}<110> direction at the center of the plate thickness is set to be over 3.0. Preferably, it is 3.5 or more or 4.0 or more. The upper limit is not particularly limited, but may be 10.0 or less.
In this embodiment, the central part of the plate thickness refers to a region from 1/4 depth of the plate thickness from the surface to 3/4 depth of the plate thickness from the surface.

The polar density in the {112}<110> direction at the center of the plate thickness is obtained by the following method.
For the measurement, a device combining a scanning electron microscope and an EBSD analyzer and OIM Analysis (registered trademark) manufactured by TSL are used. From the crystal orientation distribution function (ODF) that displays the three-dimensional texture, which is calculated using the orientation data measured by the EBSD (Electron Back Scattering Diffraction) method and the spherical harmonic function, {11 2} Find the polar density in the <110> direction. The measurement range is from 1/4 depth of the plate thickness from the surface to 3/4 depth of the plate thickness from the surface. The measurement pitch is 5 μm/step.

Note that {hkl} represents a crystal plane parallel to the rolling surface, and <uvw> represents a crystal direction parallel to the rolling direction. That is, {hkl}<uvw> indicates a crystal in which {hkl} is oriented in the normal direction of the plate surface and <uvw> is oriented in the rolling direction.

Ferrite area ratio: 5-95%
If the area ratio of ferrite is less than 5%, the desired metal structure cannot be obtained in the hot-stamped molded product, and as a result, the desired ductility cannot be obtained. Therefore, the area ratio of ferrite is set to 5% or more. Preferably it is 30% or more, 40% or more, 50% or more, or 60% or more.
If the area ratio of ferrite is more than 95%, it is impossible to obtain a desired metal structure in the hot stamped product. Therefore, the area ratio of ferrite is set to 95% or less. Preferably, it is 70% or less, 60% or less, 50% or less, or 40% or less.

Residual Structure The remaining structure other than ferrite is a hard phase consisting of one or more of martensite, bainite, and pearlite. The total area ratio of the hard phase is preferably 5% or more. Preferably it is 10% or more. The upper limit of the area ratio of the hard phase is not particularly limited, but the total may be 95% or less, 90% or less, 80% or less, or 70% or less.

Method for Measuring Area Ratio of Metal Structure A sample is taken from a position 10 mm or more away from the end face of a steel plate for hot stamping so that the plate thickness cross section perpendicular to the surface serves as the observation surface. After polishing the observation surface, it was corroded with nital, and was measured using an optical microscope and a scanning electron microscope (SEM) at a position of 1/4 of the plate thickness from the surface (1/8 depth of the plate thickness from the surface to a depth of 1/8 of the plate thickness from the surface). Observe at least three 30 μm x 30 μm regions (3/8 depth region). By performing image analysis on the microstructure photographs obtained through this microstructure observation, the area ratios of ferrite, pearlite, and bainite are obtained. After that, after performing repeller corrosion on the same observation position, the structure was observed using an optical microscope and a scanning electron microscope, and the area ratio of martensite was determined by performing image analysis on the obtained structure photographs. Calculate.

In the tissue observation described above, each tissue is identified by the following method.
Martensite has a high dislocation density and has a substructure of blocks and packets within the grains, so it is difficult to distinguish it from other metal structures based on electron channeling contrast images using a scanning electron microscope. It is possible.
It is a collection of lath-shaped crystal grains, and among the structures that do not contain Fe-based carbide with a major axis of 20 nm or more inside the structure, it is a non-martensite structure, and the structure that contains Fe-based carbide with a major axis of 20 nm or more inside the structure and its Fe A structure in which the carbides have a single variant, that is, Fe-based carbides extending in the same direction, is considered to be bainite. Here, the Fe-based carbide extending in the same direction refers to one in which the difference in the elongation direction of the Fe-based carbide is within 5°.

A structure that is a massive crystal grain and does not contain a substructure such as a lath inside the structure is considered to be ferrite.
A structure in which plate-shaped ferrite and Fe-based carbide are layered is considered to be pearlite.

Number ratio of ferrite containing a hard phase within ferrite grains: 30% or more If the number ratio of ferrite containing a hard phase within ferrite grains is less than 30% of all ferrite, in the metallographic structure of the hot-stamped compact, The number ratio of ferrite grains containing a hard phase becomes low, and as a result, excellent ductility cannot be obtained. Therefore, the number ratio of ferrite containing a hard phase in the ferrite grains is set to 30% or more. Preferably it is 40% or more, 50% or more, or 60% or more.
Although the upper limit of the number ratio of ferrite containing a hard phase in ferrite grains is not particularly limited, it may be 100% or less or 95% or less.
Note that the hard phase here refers to the above-mentioned residual structure, and refers to one or more of martensite, bainite, and pearlite.

Method for measuring the number ratio of ferrite containing a hard phase within the ferrite grains Using the microstructure photograph used to measure the area ratio of the metal structure described above, it is possible to determine the total number of ferrite as well as the hard phase (martensite) within the ferrite grains. , bainite and pearlite). By calculating the number of ferrite particles containing a hard phase inside the ferrite grains relative to the total number of ferrite particles, /total number of ferrites)×100) is obtained.

The hot stamping steel plate according to this embodiment may have a plating layer on one or both sides. It is preferable to have a plating layer on the surface because it improves the corrosion resistance of the hot stamped molded product after hot stamping.
Examples of the plating that can be applied include aluminum plating, aluminum-zinc plating, aluminum-silicon plating, hot-dip galvanizing, electrolytic galvanizing, and alloyed hot-dip galvanizing.

The thickness of the steel plate for hot stamping is not particularly limited, but from the viewpoint of reducing the weight of the vehicle body, it is preferably 0.5 to 3.5 mm.

Next, a hot-stamped molded article according to the present embodiment obtained by hot-stamping the above-described hot-stamping steel plate will be described. The chemical composition of the hot-stamped molded body according to the present embodiment can be considered to be the same as the chemical composition of the hot-stamped steel plate described above, and therefore, a description of the chemical composition will be omitted.

In the hot-stamped molded article according to the present embodiment, martensite accounts for 80% or more in terms of area ratio in the metallographic structure, and the area ratio of a hard phase with a GAIQ value of 26,000 or less existing on the martensite is 1. It is 0% or more. Each regulation will be explained below.
In addition, in this embodiment, the area ratio of the martensite and the hard Specify the area ratio of the phase.

Area ratio of martensite: 80% or more When the area ratio of martensite is less than 80%, desired strength cannot be obtained in the hot stamp molded product. Therefore, the area ratio of martensite is set to 80% or more. Preferably, it is 85% or more or 90% or more. The upper limit of the martensite area ratio is not particularly limited, but may be 100% or less or 95% or less.

Residual structure The remaining structure other than martensite is one or two of ferrite, bainite, and pearlite. If the area ratio of ferrite is less than 1%, excellent ductility may not be obtained. Therefore, the area ratio of ferrite may be set to 1% or more. More preferably, it is 2% or more.
The total area ratio of bainite and pearlite may be 15% or less or 10% or less.

The area ratio of the hard phase with a GAIQ value of 26000 or less existing on martensite is 1.0% or more.The higher the GAIQ value, the lower the dislocation density.The lower the GAIQ value, the higher the dislocation density. show. Therefore, the GAIQ value is a parameter that can reflect the dislocation density of crystal grains. By increasing the area ratio of the hard phase having a GAIQ value of 26,000 or less, that is, the hard phase having a high dislocation density, which is present on martensite, the ductility of the hot-stamped compact can be improved.

If the area percentage of the hard phase with a GAIQ value of 26,000 or less existing on martensite is less than 1.0%, excellent ductility cannot be obtained. Therefore, the area ratio of the hard phase having a GAIQ value of 26,000 or less that exists on martensite is set to 1.0% or more. Preferably it is 1.2% or more, 1.5% or more, 2.0% or more, 2.5% or more, or 3.0% or more.
The upper limit of the area ratio of the hard phase having a GAIQ value of 26,000 or less that exists on martensite is not particularly limited, but may be 10.0% or less or 7.0% or less.

Note that the hard phase having a GAIQ value of 26,000 or less includes martensite and bainite. In this embodiment, the hard phase having a GAIQ value of 26,000 or less may include either martensite or bainite, or both, and being present on martensite means ferrite grains, bainite grains, It means that it exists outside of the inside of pearlite grains; in other words, it means that it exists at martensite lath boundaries, between laths, inside laths, block boundaries and packet boundaries, and at prior austenite grain boundaries.

Method for measuring the area ratio of the metal structure and the area ratio of the hard phase with a GAIQ value of 26,000 or less existing on martensite From a position 10 mm or more away from the end surface of the hot stamped molded object (or a position avoiding the end), Collect the sample so that the plate thickness cross section perpendicular to the surface is the observation surface. After polishing the observation surface, it was corroded with nital, and was measured using an optical microscope and a scanning electron microscope (SEM) at a position of 1/4 of the plate thickness from the surface (1/8 depth of the plate thickness from the surface to a depth of 1/8 of the plate thickness from the surface). Observe at least three 30 μm x 30 μm regions (3/8 depth region). By performing image analysis on the microstructure photographs obtained through this microstructure observation, the area ratios of pearlite and bainite are obtained. After that, after performing repeller corrosion on the same observation position, the structure was observed using an optical microscope and a scanning electron microscope, and the area ratio of martensite was determined by performing image analysis on the obtained structure photographs. Calculate.
In the structure observation, each structure is identified by the same method as in the case of hot stamping steel sheets.

Next, a sample is cut out so that the plate thickness cross section can be observed from a position 10 mm or more away from the end surface of the hot stamp molded body (or a position avoiding the end). After polishing the thickness cross section of this sample using #600 to #1500 silicon carbide paper, we polished it to a mirror surface using a dilute solution such as alcohol or a liquid in which diamond powder with a particle size of 1 to 6 μm was dispersed in pure water. Finish it. Next, the sample is polished for 8 minutes using colloidal silica without an alkaline solution at room temperature to remove the strain introduced into the surface layer of the sample.

At any position in the longitudinal direction of the sample's plate thickness cross-section, a length of 50 μm and an area from 1/8 depth of the plate thickness from the surface to 3/8 depth of the plate thickness from the surface are measured at measurement intervals of 0.1 μm. Obtain crystal orientation information by electron backscatter diffraction method. For the measurement, an EBSD device consisting of a thermal field emission scanning electron microscope (JSM-7001F manufactured by JEOL) and an EBSD detector (DVC5 type detector manufactured by TSL) is used. At this time, the degree of vacuum in the EBSD device is 9.6×10 ⁻⁵ Pa or less, the acceleration voltage is 15 kV, the irradiation current level is 13, and the electron beam irradiation level is 62.

The obtained crystal orientation information is analyzed using the Grain Average Image Qu ality map ( GAIQ map). In the obtained GAIQ map, regions surrounded by grain boundaries with a crystal orientation difference of 5° or more are defined as crystal grains. A region having an average GAIQ value of 42,000 or more within a unit crystal grain is regarded as ferrite, and the area ratio of the region is calculated to obtain the area ratio of ferrite.

Furthermore, in the obtained GAIQ map, the area ratio of the hard phase present on martensite and having a GAIQ value of 26,000 or less is measured. Thereby, the area ratio of the hard phase present on martensite and having a GAIQ value of 26,000 or less is obtained. Note that martensite is assumed to be identified by the method described above.

The hot stamp molded article according to this embodiment may have a plating layer on one side or both sides. Having a plating layer on the surface improves the corrosion resistance of the hot-stamped molded product, which is preferable.
Examples of the plating that can be applied include aluminum plating, aluminum-zinc plating, aluminum-silicon plating, hot-dip galvanizing, electrolytic galvanizing, and alloyed hot-dip galvanizing.

The thickness of the hot stamp molded product is not particularly limited, but from the viewpoint of reducing the weight of the vehicle body, it is preferably 0.5 to 3.5 mm.

The tensile (maximum) strength of the hot stamp molded article according to this embodiment may be 980 to 1400 MPa. Moreover, the total elongation of the hot-stamped molded article according to this embodiment may be 7.0% or more. Furthermore, the product of tensile strength and total elongation (TS×El) of the hot-stamped molded article according to the present embodiment may be 12,000 MPa·% or more.
The tensile strength and total elongation are obtained by taking a JIS No. 5 test piece from the hot-stamped molded product and conducting a tensile test in accordance with JIS Z 2241:2011.

Next, a preferred method for manufacturing the hot stamping steel plate according to the present embodiment will be described. A preferred method for manufacturing a hot stamping steel plate according to the present embodiment includes the following steps.
A slab is obtained by setting the casting speed to 0.80 m/min or more.
A hot-rolled steel plate is obtained by performing hot rolling at a coiling temperature in a temperature range of 500 to 700°C.
After obtaining a cold-rolled steel plate by cold rolling, this cold-rolled steel plate is heated and held in a temperature range of 750 to Ac ₃ points (first holding), and then the average cooling rate in the temperature range of 600 to 700°C is Cool down to 15° C./s or less. Next, it is rapidly cooled to a temperature range of 300 to 500°C and held in this temperature range (second holding). Thereafter, it is rapidly cooled to a temperature range of 100° C. or lower.
Note that the rapid cooling herein refers to cooling in which the average cooling rate is more than 15° C./s.
Each step will be explained below.

Casting speed: 0.80 m/min or more By manufacturing a slab at a casting speed of 0.80 m/min or more, Mn segregation in the steel can be promoted. The casting speed may be 3.00 m/min or less from the viewpoint of suppressing slab cracking.

Winding temperature: 500-700℃
By performing hot rolling at a coiling temperature in the range of 500 to 700°C, Mn can be concentrated in the carbide. Other conditions for hot rolling are not particularly limited and may be general conditions. Further, the cold rolling conditions may be general, and the cumulative rolling reduction may be 30 to 70%.

After the first holding, cool so that the average cooling rate is 15°C/s or less After cold rolling, the cold rolled steel sheet is heated and held in the two-phase region, that is, the temperature range of 750 to Ac ₃ points (first holding ), and then cooled so that the average cooling rate in the temperature range of 600 to 700°C is 15°C/s or less, so that a hard phase enriched with Mn can remain inside the ferrite grains. By holding in the above temperature range, untransformed austenite without Mn enrichment transforms into ferrite, but untransformed austenite with Mn enrichment has a lower transformation point, so it does not transform into ferrite and remains as untransformed austenite. remain.

Note that the holding time in the first holding may be 10 to 300 seconds. In the present embodiment, the average cooling rate is a value obtained by dividing the temperature difference between the surface temperature at the start of cooling and the surface temperature at the time of stopping cooling by the time difference from the time of starting cooling to the time of stopping cooling.
Further, the Ac ₃ points can be determined by the following formula.

Ac ₃ (℃)=910-203×C ^0.5 +66×Si-25×Mn+700×P-11×Cr+109×Al+400×Ti-15.2×Ni+104×V+31.5×Mo
The element symbol in the above formula indicates the content in mass % of each element, and when the element is not contained, 0 is substituted.

After quenching, hold for a second time and further quench. After cooling so that the average cooling rate in the temperature range of 600 to 700 °C is 15 °C/s or less, rapidly cool to a temperature range of 300 to 500 °C. Hold (second hold) and then further rapidly cool. Thereby, the carbide remaining in the ferrite grains can be transformed into a hard phase. As a result, the number ratio of ferrite containing a hard phase within the ferrite grains can be increased.
Note that the holding time in the second holding may be 10 to 600 seconds.

By the manufacturing method described above, the hot stamping steel plate according to this embodiment can be stably manufactured. In addition to the above-described manufacturing method, the method may include a step of forming a plating layer on one or both sides of the hot stamping steel plate.

Next, a preferred method for manufacturing the hot stamp molded article according to this embodiment will be described. The method for manufacturing a hot stamp molded body according to the present embodiment includes the following steps.
A steel plate for hot stamping is heated to a temperature range of Ac ₃ or higher and held.
Cooling is performed to a temperature range of 100° C. or lower at an average cooling rate of 30° C./s or higher.
Each step will be explained below.

Heating temperature and holding temperature: Ac ₃ points or more By heating and holding the above-mentioned hot stamping steel plate to a temperature range of Ac ₃ points or more, it can be sufficiently austenitized. The holding time in the temperature range of Ac ₃ points or higher is not particularly limited, but may be, for example, 10 to 300 seconds. After holding in a temperature range of ₃ or more Ac points, hot stamping is performed.

Average cooling rate to a temperature range of 100°C or less: 30°C/s or more Obtain the desired amount of hard phase by cooling so that the average cooling rate to a temperature range of 100°C or less is 30°C/s or more. be able to. As a result, the area ratio of the hard phase having a GAIQ value of 26,000 or less existing on martensite can be increased. Cooling to a temperature range of 100° C. or lower may be performed by contacting with a mold.

The hot-stamped molded article according to this embodiment can be obtained by the method described above. The steel plate for hot stamping according to this embodiment has relatively low strength, so after hot stamping, it is joined with a steel plate having high strength to form a tailored blank, which is then hot stamped and formed into a vehicle body part. This vehicle body part was manufactured by hot-stamping a tailored blank made of low-strength materials and high-strength materials, so it has low-strength portions and high-strength portions.

Various welding methods can be used to manufacture the tailored blank, including laser welding, seam welding, arc welding, and plasma welding, but there are no particular limitations. Further, the high strength material (steel plate having high strength after hot stamping) used together with the low strength material (the hot stamping steel plate according to the present embodiment) is not particularly limited. These may be selected appropriately for each vehicle body part to be manufactured.

There is no problem even if the steel plate for hot stamping according to this embodiment is not applied to a tailored blank, but only the steel plate is used to manufacture vehicle body parts. There is no problem in creating a patchwork blank by joining steel plates together by spot welding and then hot stamping the blank.

Next, examples of the present invention will be described. The conditions in the examples are examples of conditions adopted to confirm the feasibility and effects of the present invention, and the present invention is based on this example of conditions. It is not limited. The present invention can adopt various conditions as long as the purpose of the present invention is achieved without departing from the gist of the present invention.

Using slabs having the chemical compositions shown in Tables 1A and 1B, hot stamping steel plates shown in Tables 2A to 2C were manufactured under the conditions shown in Tables 2A to 2C. Next, hot stamp molded bodies shown in Tables 3A to 3C were obtained under the conditions shown in Tables 3A to 3C.

Note that the slabs were manufactured at the casting speeds listed in Tables 2A to 2C. In the cold rolling after winding, the cumulative rolling reduction was 30 to 70%. The holding time in the first holding was 10 to 300 seconds, and the holding time in the second holding was 10 to 600 seconds. In addition, after cooling so that the average cooling rate in the temperature range of 600 to 700°C became the average cooling rate listed in Tables 2A to 2C, it was rapidly cooled to the second holding temperature. After the second holding, it was rapidly cooled to a temperature range of 100°C or lower.
Furthermore, during heating during hot stamping, the holding time was set to 10 to 300 seconds.

The metallographic structure of the hot-stamped steel sheet, the metallographic structure and mechanical properties (tensile strength and total elongation) of the hot-stamped molded product were measured by the above-mentioned method.
Examples with a tensile strength of 980 to 1400 MPa were judged to have high strength and were passed. On the other hand, examples in which the tensile strength was less than 980 MPa or more than 1400 MPa were determined to be rejected.
In addition, examples in which the total elongation was 7.0% or more and the product of tensile strength and total elongation (TS x El) were 12000 MPa·% or more were judged to be excellent in ductility and passed. On the other hand, examples in which the total elongation was less than 7.0% and examples in which the product of tensile strength and total elongation (TS×El) were less than 12000 MPa·% were judged to be poor in ductility and were judged to be rejected.

According to Tables 1A to 3C, it can be seen that the hot-stamped molded articles according to the examples of the present invention have high strength and excellent ductility.
On the other hand, it can be seen that the hot-stamped molded article according to the comparative example does not have high strength and/or excellent ductility.

According to the above aspects of the present invention, it is possible to provide a hot-stamped molded body having high strength and excellent ductility, and a hot-stamped steel plate from which this hot-stamped molded body can be manufactured.

Claims (4)

The chemical composition is in mass%,
C: 0.060-0.200%,
Si: 0.010 to 1.000%,
Mn: 1.20-3.00%,
Al: 0.010-0.500%,
P: 0.100% or less,
S: 0.0100% or less,
N: 0.0100% or less,
Nb: 0% or more, less than 0.020%,
Ti: 0 to 0.100%,
Cr: 0 to 0.50%,
B: 0 to 0.0100%,
Mo: 0-1.00%,
Co: 0-2.00%,
Ni: 0 to 0.50%,
V: 0 to 0.10%,
Ca: 0-0.0100%,
Contains Mg: 0 to 0.0100%, and REM: 0 to 0.0100%,
The remainder consists of Fe and impurities,
In the metal structure at a position of 1/4 plate thickness from the surface ,
The polar density in the {112}<110> direction at the center of the plate thickness is over 3.0,
The area ratio is 5 to 95% ferrite,
A steel sheet for hot stamping, characterized in that the number ratio of the ferrite containing a hard phase in the ferrite grains is 30% or more of all ferrite. The chemical composition is in mass%,
Nb: 0.001% or more, less than 0.020%,
Ti: 0.010 to 0.100%,
Cr: 0.05-0.50%,
B: 0.0001 to 0.0100%,
Mo: 0.01-1.00%,
Co: 0.01-2.00%,
Ni: 0.01-0.50%,
V: 0.01 to 0.10%,
Ca: 0.0005-0.0100%,
Mg: 0.0005-0.0100%, and REM: 0.0005-0.0100%
The steel plate for hot stamping according to claim 1, characterized in that it contains one or more of the following. The chemical composition is in mass%,
C: 0.060-0.200%,
Si: 0.010 to 1.000%,
Mn: 1.20-3.00%,
Al: 0.010-0.500%,
P: 0.100% or less,
S: 0.0100% or less,
N: 0.0100% or less,
Nb: 0% or more, less than 0.020%,
Ti: 0 to 0.100%,
Cr: 0 to 0.50%,
B: 0 to 0.0100%,
Mo: 0-1.00%,
Co: 0-2.00%,
Ni: 0 to 0.50%,
V: 0 to 0.10%,
Ca: 0-0.0100%,
Contains Mg: 0 to 0.0100%, and REM: 0 to 0.0100%,
The remainder consists of Fe and impurities,
In the metal structure at a position of 1/4 plate thickness from the surface ,
In terms of area ratio, martensite is 80% or more,
A hot-stamped molded article characterized in that the area ratio of a hard phase with a GAIQ value of 26000 or less existing on the martensite is 1.0% or more (However, existing on the martensite means martensite (existence at lath boundaries, between laths, inside laths, block boundaries and packet boundaries, and prior austenite grain boundaries) . The chemical composition is in mass%,
Nb: 0.001% or more, less than 0.020%,
Ti: 0.010 to 0.100%,
Cr: 0.05-0.50%,
B: 0.0001 to 0.0100%,
Mo: 0.01-1.00%,
Co: 0.01-2.00%,
Ni: 0.01-0.50%,
V: 0.01 to 0.10%,
Ca: 0.0005-0.0100%,
Mg: 0.0005-0.0100%, and REM: 0.0005-0.0100%
The hot-stamped molded article according to claim 3, characterized in that it contains one or more of the group consisting of: