JP7352246B2 - Bristle materials for makeup brushes, makeup brushes using the bristle materials - Google Patents

Bristle materials for makeup brushes, makeup brushes using the bristle materials Download PDF

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JP7352246B2
JP7352246B2 JP2022122503A JP2022122503A JP7352246B2 JP 7352246 B2 JP7352246 B2 JP 7352246B2 JP 2022122503 A JP2022122503 A JP 2022122503A JP 2022122503 A JP2022122503 A JP 2022122503A JP 7352246 B2 JP7352246 B2 JP 7352246B2
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makeup
bristle material
brush
brushes
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JP2022140604A (en
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亘 榎本
彰子 櫟
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Taiki Corp Ltd
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    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B9/00Arrangements of the bristles in the brush body
    • A46B9/02Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups
    • A46B9/021Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups arranged like in cosmetics brushes, e.g. mascara, nail polish, eye shadow
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/02Bristles details
    • A46D1/0238Bristles with non-round cross-section
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/02Bristles details
    • A46D1/0276Bristles having pointed ends
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/02Bristles details
    • A46D1/0207Bristles characterised by the choice of material, e.g. metal
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/02Bristles details
    • A46D1/0269Monofilament bristles
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/02Bristles details
    • A46D1/0292Bristles having split ends
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/253Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/26Yarns or threads characterised by constructional features, e.g. blending, filament/fibre with characteristics dependent on the amount or direction of twist
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B2200/00Brushes characterized by their functions, uses or applications
    • A46B2200/10For human or animal care
    • A46B2200/1046Brush used for applying cosmetics
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2509/00Medical; Hygiene

Description

本発明は、化粧ブラシ用毛材、化粧ブラシ用毛材集合体および化粧ブラシに関する。 The present invention relates to a bristle material for a makeup brush, a bristle material assembly for a makeup brush, and a makeup brush.

従来、化粧ブラシ用毛材には、リス毛、馬毛、山羊毛等の天然獣毛が使用されてきた。天然獣毛は、液状または粉末状化粧料に対する含み性や放出性が良く、毛腰が柔軟で肌あたりなどの使用感が良好であるといわれ愛用者も多い。特に、リス毛の化粧ブラシや山羊毛の化粧ブラシは、獣毛の化粧ブラシの最高級品として消費者から高い評価を得ている。しかしながら、天然獣毛は多くの利点を有しているものの天然資源であるため供給量に限界があるほか、動物愛護や地球生態保護などの観点から、次第にその入手が困難になりつつある。そこで、近年では天然獣毛の代替品として、合成繊維から作られた化粧ブラシ用毛材が提案されている。 Conventionally, natural animal hair such as squirrel hair, horse hair, goat hair, etc. has been used as the bristle material for makeup brushes. Natural animal hair is said to have good absorbency and release properties for liquid or powder cosmetics, has a soft texture, and is said to feel good on the skin, and is loved by many users. In particular, squirrel hair makeup brushes and goat hair makeup brushes are highly regarded by consumers as the highest quality animal hair makeup brushes. However, although natural animal hair has many advantages, since it is a natural resource, there is a limit to its supply, and it is becoming increasingly difficult to obtain it from the viewpoints of animal welfare and global ecology. Therefore, in recent years, bristle materials for cosmetic brushes made from synthetic fibers have been proposed as a substitute for natural animal hair.

例えば、特許文献1には、ポリプロピレンテレフタレートを主成分とし、特定の屈曲回復率を示す化粧ブラシ等のブラシ用毛材が提案されている。ポリプロピレンテレフタレートのみからなるブラシ用毛材は、先端が先細形状としたものであっても、ポリブチレンテレフタレートのみからなるブラシ用毛材よりも、耐久性が優れること、さらには、従来のブラシ用毛材よりも、柔軟性のあるソフト感を有する素材であることが具体的に開示されている(特許文献1参照)。
特許文献2には、芯鞘構造複合モノフィラメントからなり、その一端にテーパー部を形成した、化粧ブラシ用毛材が提案されている。テーパー部の断面形状を円形断面とし、テーパー部以外の本体部の断面形状を八葉形とすることにより、液体化粧料に対する優れた塗布性能と、天然獣毛に匹敵する使用感とを兼ね備えた、化粧ブラシ用途に適した毛材であることが具体的に開示されている(特許文献2参照)。
For example, Patent Document 1 proposes a bristle material for brushes such as makeup brushes that contains polypropylene terephthalate as a main component and exhibits a specific bending recovery rate. Brush bristles made only of polypropylene terephthalate, even if they have tapered tips, are more durable than brush bristles made only of polybutylene terephthalate. It is specifically disclosed that it is a material that has a softer and more flexible feel than wood (see Patent Document 1).
Patent Document 2 proposes a bristle material for a makeup brush that is made of a core-sheath composite monofilament and has a tapered portion formed at one end thereof. The cross-sectional shape of the tapered part is circular, and the cross-sectional shape of the main body other than the tapered part is eight-lobed, providing excellent application performance for liquid cosmetics and a feeling of use comparable to that of natural animal hair. specifically discloses that it is a bristle material suitable for use in makeup brushes (see Patent Document 2).

特開2003-245133号公報Japanese Patent Application Publication No. 2003-245133 特開2009-201794号公報JP2009-201794A

天然獣毛は、微妙に捲縮しているため、毛を束ねた状態では塗布部先端が広がった状態となるため、特に、頬紅やアイシャドウ等の粉末状化粧料をぼかした状態で塗布することに適している。一方、合成繊維からなるブラシ用毛材は、合成繊維自体が直線状であるため、毛を束ねた状態では塗布部先端は広がらずストレートな状態であるため、アイライナーや口紅等の固形状、練り状または液状の化粧料を塗布することに適しているが、粉末状化粧料の塗布には適さないことが知られている。
そこで、本発明は、粉末状化粧料および液状化粧料それぞれの塗布に適した、より詳しくは、粉末状または液状化粧料に対するキャッチ&リリース性が良好な、合成樹脂からなる化粧ブラシ用毛材、化粧ブラシ用毛材集合体およびそれらを用いた化粧ブラシを提供することを課題としている。
Natural animal hair is delicately crimped, so if the hair is tied up, the tip of the application area will be spread out, so especially powdered cosmetics such as blusher and eye shadow should be applied in a blurred state. It is suitable for this purpose. On the other hand, with synthetic fiber brush bristles, the synthetic fibers themselves are linear, so when the bristles are bundled, the tip of the applied part does not spread out and remains straight. Although it is suitable for applying paste-like or liquid cosmetics, it is known that it is not suitable for applying powder-like cosmetics.
Therefore, the present invention provides a bristle material for a cosmetic brush made of synthetic resin, which is suitable for applying powdered cosmetics and liquid cosmetics, and more specifically, has good catch and release properties for powdered or liquid cosmetics. An object of the present invention is to provide a bristle assembly for a makeup brush and a makeup brush using the same.

本発明者は上記課題を解決するために鋭意研究を重ねた結果、特定の断面形状を有するS撚りまたはZ撚りの合成樹脂製ブラシ用毛材が、粉末状または液状化粧料に対するキャッチ&リリース性に極めて優れていることを見出し、上記課題を解決するに至ったものである。 As a result of extensive research in order to solve the above problems, the inventors of the present invention have found that S-twisted or Z-twisted synthetic resin brush bristle material having a specific cross-sectional shape has catch-and-release properties for powdered or liquid cosmetics. We have found that the above-mentioned problem is solved by discovering that it is extremely superior.

本発明は、具体的には次の事項を要旨とする。
1.S撚りまたはZ撚りの合成樹脂製モノフィラメントからなり、
前記モノフィラメントの繊維軸と垂直方向の断面が、まゆ型形状であることを特徴とする化粧ブラシ用毛材。
2.前記モノフィラメントが、テーパー状に形成された先細部を備えていることを特徴とする1.記載の化粧ブラシ用毛材。
3.前記テーパー状に形成された先細部が分岐していることを特徴とする2.記載の化粧ブラシ用毛材。
4.前記合成樹脂がポリエステル系樹脂であることを特徴とする1.~3.の何れか1項に記載の化粧ブラシ用毛材。
5.前記ポリエステル系樹脂が、ポリトリメチレンテレフタレート、ポリエチレンテレフタレート及びポリブチレンテレフタレートから選択された1種または2種以上であることを特徴とする4.記載の化粧ブラシ用毛材。
6.S撚り及びZ撚りの合成樹脂製モノフィラメントの混合集合体からなり、
前記モノフィラメントの繊維軸と垂直方向の断面が、まゆ型形状であることを特徴とする化粧ブラシ用毛材集合体。
7.1.~5.の何れか1項に記載の化粧ブラシ用毛材または6.に記載の化粧ブラシ用毛材集合体を、少なくとも一部に使用したことを特徴とする化粧ブラシ。
Specifically, the present invention has the following points.
1. Consists of S-twisted or Z-twisted synthetic resin monofilament,
A bristle material for a makeup brush, characterized in that a cross section of the monofilament in a direction perpendicular to the fiber axis has an eyebrow shape.
2. 1. The monofilament is characterized in that it has a tapered portion. Bristle material for makeup brushes as described.
3. 2. The tapered part is branched. Bristle material for makeup brushes as described.
4. 1. The synthetic resin is a polyester resin. ~3. The bristle material for a makeup brush according to any one of the above.
5. 4. The polyester resin is one or more selected from polytrimethylene terephthalate, polyethylene terephthalate, and polybutylene terephthalate. Bristle material for makeup brushes as described.
6. Consists of a mixed aggregate of S-twisted and Z-twisted synthetic resin monofilaments,
A bristle assembly for a makeup brush, characterized in that a cross section of the monofilament in a direction perpendicular to the fiber axis has an eyebrow shape.
7.1. ~5. The bristle material for makeup brushes according to any one of Item 1 or 6. A makeup brush, characterized in that the bristle material aggregate for makeup brushes described in 1 is used in at least a portion thereof.

本発明の化粧ブラシ用毛材は、撚りと特定の断面形状という2つの特異的な立体形状を有することで、それぞれの立体形状の組み合わせにより相乗効果を発揮し、粉末状または液状化粧料に対するキャッチ&リリース性において、天然獣毛より優れた性能を実現する。さらに、テーパー状に形成された先細部を備えることにより、天然獣毛に匹敵する肌あたりと柔軟性を兼ね備えた化粧ブラシ用毛材とすることができる。 The bristle material for cosmetic brushes of the present invention has two specific three-dimensional shapes, namely twisted and a specific cross-sectional shape, and the combination of these three-dimensional shapes produces a synergistic effect, making it an attractive material for powdered or liquid cosmetics. &Releases better performance than natural animal hair. Furthermore, by providing the tapered end, the bristle material for a makeup brush can have both skin feel and flexibility comparable to natural animal hair.

本発明の化粧ブラシ用毛材における、まゆ型形状の断面概略図である。FIG. 1 is a schematic cross-sectional view of an eyebrow-shaped bristle material for a cosmetic brush according to the present invention. 本発明のまゆ型形状の1例を示す断面概略図である。FIG. 2 is a schematic cross-sectional view showing an example of the eyebrow-shaped shape of the present invention. (A)~(C)は、本発明に含まれない断面形状概略図である。(A) to (C) are schematic diagrams of cross-sectional shapes that are not included in the present invention. 本発明の化粧ブラシ用毛材の光学顕微鏡写真(150倍)である。It is an optical micrograph (150 times) of the bristle material for makeup brushes of this invention. 先細部が分岐している本発明の化粧ブラシ用毛材の光学顕微鏡写真(100倍)である。It is an optical micrograph (100 times) of the bristle material for makeup brushes of this invention in which the taper part is branched. 実施例の「化粧ブラシの使用性能の評価1:パウダーキャッチ性の評価」の評価試験結果を示すグラフである。It is a graph showing the evaluation test results of "Evaluation 1 of Usage Performance of Cosmetic Brush: Evaluation of Powder Catching Performance" in Example. 実施例の「化粧ブラシの使用性能の評価2:パウダーリリース性の評価」の評価試験結果を示すグラフである。It is a graph showing the evaluation test results of "Evaluation of usability of makeup brushes 2: Evaluation of powder release properties" in Examples.

本発明は、S撚りまたはZ撚りの合成樹脂製モノフィラメントからなり、前記モノフィラメントの繊維軸と垂直方向の断面が、まゆ型形状である化粧ブラシ用毛材、化粧ブラシ用毛材集合体および化粧ブラシに関する。
以下、本発明について詳細に説明する。
The present invention relates to a bristle material for a makeup brush, a bristle material assembly for a makeup brush, and a makeup brush, which are made of S-twisted or Z-twisted synthetic resin monofilaments, and the monofilament has an eyebrow-shaped cross section in a direction perpendicular to the fiber axis. Regarding.
The present invention will be explained in detail below.

本発明の化粧ブラシ用毛材は、S撚りまたはZ撚りの撚り構造を有する合成樹脂製モノフィラメントからなる。すなわち、「S撚り毛材(右撚り)」または「Z撚り毛材(左撚り)」の何れかの螺旋構造を有しており、ストレートな繊維や波形状の繊維と異なり、螺旋軸に直交する方向に3次元的な広がりを有する。
このような撚りによる螺旋構造を有する1本の毛材が占める体積は、従来公知のギヤクリンプ方式によって形成される平面的なジグザグ構造の毛材の場合に比べても大きく、本発明の化粧ブラシ用毛材からなる化粧ブラシ用毛材集合体や化粧ブラシは、静置状態でも毛材同士の重なりや密着が抑制されて内部に空隙部を多く含む、ふんわりとした量感の高いものとなる。さらに、S撚りとZ撚りを組み合わせると、内部の空隙部がより多くなり立体感を高めることができ好ましい。
The bristle material for a cosmetic brush of the present invention is made of synthetic resin monofilament having an S-twist or Z-twist structure. In other words, it has a helical structure of either "S-twist material (right-handed twist)" or "Z-twist material (left-handed twist)," and unlike straight fibers or wave-shaped fibers, the fibers are perpendicular to the helical axis. It has a three-dimensional spread in the direction of
The volume occupied by one bristle material having a spiral structure due to such twisting is larger than that of a bristle material having a flat zigzag structure formed by a conventionally known gear crimp method, and the volume occupied by one bristle material having a spiral structure due to such twisting is larger than that of a bristle material having a flat zigzag structure formed by a conventionally known gear crimp method. Bristle aggregates for makeup brushes made of bristle materials and makeup brushes are fluffy and have a high volume, with the bristle materials suppressing overlapping and adhesion to each other even in a stationary state, and containing many voids inside. Furthermore, it is preferable to combine S twist and Z twist because the number of internal voids increases and the three-dimensional effect can be enhanced.

本発明の化粧ブラシ用毛材の撚り数は、化粧ブラシ用毛材集合体や化粧ブラシとした際に、粉末状または液状化粧料を保持するための空隙部を隣接する毛材間に形成するために、S撚り、Z撚りいずれの場合も30T/m(ターン/m)以上100T/m(ターン/m)以下の範囲内になるように設定することが好ましく、40T/m(ターン/m)以上90T/m(ターン/m)以下の範囲内がより好ましい。撚数が、上記範囲内であれば、繊維の長さ方向に10mmを超え35mm以下の波長幅で螺旋構造を与えることができる。
通常、モノフィラメントに立体感を出すためには、より波長幅を短くするために強撚りとするべきところ、本発明の化粧ブラシ用毛材では、撚数を小さく(甘撚り)とすることで波長幅を長くしている。このように撚数を小さくすることで、より立体感のあるブラシ用毛材を得ることができると共に、モノフィラメントを何本か合わせて撚りを掛けた後、梳くことで容易に開繊させることができ、製造効率を向上させ得るという効果も奏する。また、強撚りでは、毛材のコシが硬くなり肌あたりも悪くなりやすい。
一方、波長幅が35mmを越えると、撚りが甘くなって毛材が直線状に近くなるために毛材の3次元的な広がりが少なくなり、毛材間の空隙が減るので粉末状または液状化粧料の捕集量や保持量が低下しやすくなる。また、波長幅が10mm未満では、毛材同士が絡まりやすくなり、製造効率が低下する。本発明の化粧ブラシ用毛材の波長幅は、好ましくは11mm以上25mm以下、さらに好ましくは12mm以上20mm以下の範囲である。
The number of twists of the bristle material for makeup brushes of the present invention is such that when it is made into a bristle material aggregate for a makeup brush or a makeup brush, a void is formed between adjacent bristle materials for holding powdered or liquid cosmetics. Therefore, it is preferable to set it within the range of 30 T/m (turns/m) or more and 100 T/m (turns/m) or less for both S twist and Z twist, and 40 T/m (turns/m). ) or more and 90 T/m (turns/m) or less is more preferable. If the number of twists is within the above range, it is possible to provide a helical structure with a wavelength width of more than 10 mm and less than 35 mm in the length direction of the fiber.
Normally, in order to give monofilament a three-dimensional effect, strong twisting is required to shorten the wavelength width, but in the cosmetic brush bristle material of the present invention, the number of twists is small (soft twisting). The width is increased. By reducing the number of twists in this way, it is possible to obtain a brush bristle material with a more three-dimensional appearance, and after twisting several monofilaments together, the fibers can be easily opened by combing. This also has the effect of improving manufacturing efficiency. In addition, with heavy twisting, the hair becomes stiff and feels uncomfortable against the skin.
On the other hand, when the wavelength width exceeds 35 mm, the twist becomes loose and the hair material becomes nearly linear, so the three-dimensional spread of the hair material decreases, and the voids between the hair materials are reduced, so powdery or liquid makeup is used. The amount of collected and retained materials tends to decrease. Furthermore, if the wavelength width is less than 10 mm, the hair materials tend to become entangled with each other, resulting in a decrease in manufacturing efficiency. The wavelength width of the bristle material for cosmetic brushes of the present invention is preferably in the range of 11 mm or more and 25 mm or less, more preferably 12 mm or more and 20 mm or less.

本発明の化粧ブラシ用毛材は、S撚りまたはZ撚りの合成樹脂製モノフィラメントの繊維軸と垂直方向の断面が、まゆ型形状のものである。
本発明の化粧ブラシ用毛材の断面形状について、図1~3に従って説明する。図1、2ともに、本発明の化粧ブラシ用毛材の断面形状概略図である。図3(A)~(C)は、本発明に含まれない断面形状概略図である。
本発明におけるまゆ型形状は、図1に示すように、カイコが作る繭のように長形で中央部分(胴部分)になだらかなくびれがある俵型形状を意味し、図3(A)のような、中央部分(胴部分)にくびれのない断面形状は含まない。また、本発明のまゆ型形状は、図2に示すような中央部分(胴部分)に大きなくびれを有するものも含まれるが、図3(B)、(C)のような鋭角な溝のようなくびれを有するものは含まない。
本発明におけるまゆ型形状は、図1、2に示すように、くびれ中央部を基点とし、なだらかなくびれに沿った2つの接線(点線)がなす「角度」が90度より大きく180度より小さいことを特徴とする。本発明におけるまゆ型形状は、この「角度」が100度以上であることが好ましく、120度以上がより好ましく、130度以上がさらに好ましい。本発明に含まれない態様は、図3(B)に示すように、くびれ中央部を基点とし、くびれに沿った2つの接線(点線)がなす「角度」が90度より小さく、鋭角な縦溝が構成されている。
化粧ブラシ用毛材は、繊維の長さ方向に縦溝が存在すると、粉末状または液状化粧料に対するキャッチ性(含み性)が向上することを本発明者は確認していた。しかしながら、この縦溝が鋭角(90度以内)の角度を有するものであると、化粧ブラシ用毛材が含んだ粉末状または液状化粧料が、この縦溝に保持されてしまい、リリース性(放出性)が低下することを本発明者は今回初めて見出した。すなわち、本発明の化粧ブラシ用毛材は、その断面を、なだらかな流線形、すなわち、上記「角度」が90度より大きく180度より小さな角度からなるくびれを有するまゆ型形状とすることにより、粉末状または液状化粧料に対するキャッチ&リリース性、特に、リリース性(放出性)に優れる性能を発揮することを見出し、本発明を完成するに至ったものである。
The bristle material for a cosmetic brush of the present invention is made of S-twisted or Z-twisted synthetic resin monofilament whose cross section in the direction perpendicular to the fiber axis is eyebrow-shaped.
The cross-sectional shape of the bristle material for cosmetic brushes of the present invention will be explained according to FIGS. 1 to 3. Both FIGS. 1 and 2 are schematic cross-sectional views of the bristle material for a makeup brush of the present invention. FIGS. 3A to 3C are schematic diagrams of cross-sectional shapes that are not included in the present invention.
The cocoon-shaped shape in the present invention means a straw-shaped shape that is long and has a gentle constriction in the center (body part) like a cocoon made by a silkworm, as shown in Figure 1, and as shown in Figure 3 (A). It does not include cross-sectional shapes that have no constriction in the center portion (body portion). In addition, the cocoon-shaped shape of the present invention includes a shape having a large constriction in the center portion (body portion) as shown in FIG. Does not include those with constrictions.
As shown in FIGS. 1 and 2, the eyebrow-shaped shape according to the present invention has an "angle" formed by two tangent lines (dotted lines) along the gentle constriction starting from the center of the constriction and being greater than 90 degrees and less than 180 degrees. It is characterized by In the eyebrow shape according to the present invention, the "angle" is preferably 100 degrees or more, more preferably 120 degrees or more, and even more preferably 130 degrees or more. An aspect that is not included in the present invention is that, as shown in FIG. 3(B), the "angle" between two tangent lines (dotted lines) along the waist is smaller than 90 degrees, and the vertical angle is acute. A groove is formed.
The present inventor has confirmed that the presence of longitudinal grooves in the length direction of the fibers of the bristle material for cosmetic brushes improves the ability to catch powdered or liquid cosmetics. However, if the vertical grooves have an acute angle (within 90 degrees), the powdered or liquid cosmetics contained in the makeup brush bristle material will be retained in the vertical grooves, resulting in poor release (release). The present inventors have discovered for the first time that this decreases the That is, the bristle material for a makeup brush of the present invention has a cross section that is gently streamlined, that is, an eyebrow-shaped shape having a constriction in which the above-mentioned "angle" is greater than 90 degrees and smaller than 180 degrees. The present invention was completed based on the discovery that it exhibits excellent catch and release properties, particularly release properties, for powdered or liquid cosmetics.

本発明の化粧ブラシ用毛材の断面形状について、図1に従いさらに詳しく説明する。
図1におけるaは、本発明の化粧ブラシ用毛材の長径(以下、長径aという。)、bはくぼみ幅(以下、くぼみ幅bという。)、cは短径(以下、短径cという。)、dはくぼみ径(以下、くぼみ径dという。)を意味する。
本発明の化粧ブラシ用毛材においては、長径aは100μm以上200μm以下の範囲にあり、中でも、110μm以上170μm以下の範囲が好ましく、120μm以上160μm以下の範囲がより好ましい。くぼみ幅bは長径aの50%以上75%以下の範囲にあり、短径cは10μm以上100μm以下の範囲にあり、くぼみ径dは短径cの40%以上90%以下である。長径aとくぼみ径dとのアスペクト比(a/d)は、1.1以上8.0以下の範囲にあり、中でも2.0以上7.8以下の範囲であると好ましい。また、短径cとくぼみ径dとのアスペクト比(c/d)は、1.1以上3.0以下の範囲にあり、1.1以上2.5以下の範囲にあると好ましい。
長径a、くぼみ幅b、短径c、くぼみ径dが、上記の範囲にあると、粉末状または液状化粧料に対するキャッチ&リリース性において、優れた性能を発揮する。
The cross-sectional shape of the bristle material for a makeup brush of the present invention will be explained in more detail with reference to FIG.
In FIG. 1, a represents the major axis of the bristle material for makeup brushes of the present invention (hereinafter referred to as major axis a), b represents the recess width (hereinafter referred to as recess width b), and c represents the short axis (hereinafter referred to as short axis c). ), d means the diameter of the depression (hereinafter referred to as the diameter of the depression d).
In the bristle material for cosmetic brushes of the present invention, the major axis a is in the range of 100 μm or more and 200 μm or less, particularly preferably 110 μm or more and 170 μm or less, and more preferably 120 μm or more and 160 μm or less. The recess width b is in the range of 50% or more and 75% or less of the major axis a, the short axis c is in the range of 10 μm or more and 100 μm or less, and the recess diameter d is 40% or more and 90% or less of the short axis c. The aspect ratio (a/d) between the major axis a and the depression diameter d is in the range of 1.1 or more and 8.0 or less, and preferably in the range of 2.0 or more and 7.8 or less. Further, the aspect ratio (c/d) between the minor axis c and the depression diameter d is in the range of 1.1 or more and 3.0 or less, preferably in the range of 1.1 or more and 2.5 or less.
When the major axis a, the recess width b, the short axis c, and the recess diameter d are within the above ranges, excellent performance is exhibited in terms of catch and release properties for powdered or liquid cosmetics.

本発明の化粧ブラシ用毛材は、S撚りまたはZ撚りの撚り構造を有し、かつ、その断面がまゆ型形状であるという、2つの特異的な立体形状の組み合わせにより相乗効果を発揮し、粉末状または液状化粧料に対するキャッチ&リリース性において、特に、粉末状または液状化粧料に対するリリース性(放出性)において、初期リリース性に極めて優れるという性能を発揮する。後述する実施例において詳しく説明するが、本発明の化粧ブラシ用毛材は、獣毛の化粧ブラシの最高級品として消費者から高い評価を得ている山羊毛の化粧ブラシに比べて、粉末状化粧料に対するキャッチ性(含み性)が1.3~1.8倍程度高く、優れた性能を有する。また、粉末状または液状化粧料に対するリリース性(放出性)については、山羊毛の化粧ブラシと比べて、初期リリース性(放出性)が1.2倍程度高く、優れた性能を有する。これら本発明の化粧ブラシ用毛材が発揮する、粉末状または液状化粧料に対するキャッチ&リリース性の効果、すなわち、含み性と放出性の両性能に優れていることは、本発明者が初めて確認した格別顕著な効果である。 The bristle material for cosmetic brushes of the present invention exhibits a synergistic effect due to the combination of two specific three-dimensional shapes, which have an S-twist or Z-twist twist structure and a cocoon-shaped cross section. It exhibits extremely excellent initial release properties in terms of catch and release properties for powdered or liquid cosmetics, particularly in terms of release properties (release properties) for powdered or liquid cosmetics. As will be explained in detail in the examples below, the bristle material for makeup brushes of the present invention has a powder-like bristle material compared to goat hair makeup brushes, which have received high praise from consumers as the highest quality animal hair makeup brushes. It has excellent performance, with a 1.3 to 1.8 times higher ability to catch cosmetics. In addition, regarding the release properties (release properties) for powdered or liquid cosmetics, the initial release properties (release properties) are about 1.2 times higher than that of goat hair makeup brushes, and the brush has excellent performance. The present inventor has confirmed for the first time that the bristle material for cosmetic brushes of the present invention exhibits a catch-and-release effect on powdered or liquid cosmetics, that is, is excellent in both retention and release performance. This is a particularly remarkable effect.

本発明の化粧ブラシ用毛材は、合成樹脂製モノフィラメントからなる。この合成樹脂としては、ポリアミド系樹脂、ポリオレフィン系樹脂、ポリアクリロニトリル系樹脂、ポリエステル系樹脂などの合成樹脂の1種または2種以上を選択または組み合わせて使用することができるが、これらの中で、ポリエステル系樹脂が化粧ブラシ用毛材として、適度の剛性と耐久性を有すると共に、押出加工、撚り加工、先細加工等に優れているため好適である。中でも、ポリトリメチレンテレフタレート、ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリ乳酸等のポリエステル系樹脂から選ばれた1種または2種以上であることが好ましい。さらに、適度な柔軟性と弾性とを具備する点において、ポリトリメチレンテレフタレート(PTT)、ポリエチレンテレフタレート(PET)、ポリブチレンテレフタレート(PBT)から選ばれた1種または2種以上であることがより好ましい。本発明の合成樹脂製モノフィラメントは、本発明の目的を阻害しない範囲であれば、耐熱剤、耐候剤、可塑剤、着色剤等の慣用添加剤を含むことができる。 The bristle material for a cosmetic brush of the present invention is made of synthetic resin monofilament. As this synthetic resin, one type or two or more types of synthetic resins such as polyamide resin, polyolefin resin, polyacrylonitrile resin, and polyester resin can be selected or used in combination, but among these, Polyester resin is suitable as a bristle material for makeup brushes because it has appropriate rigidity and durability and is excellent in extrusion processing, twisting processing, tapering processing, etc. Among these, one or more types selected from polyester resins such as polytrimethylene terephthalate, polyethylene terephthalate, polybutylene terephthalate, and polylactic acid are preferable. Furthermore, in terms of having appropriate flexibility and elasticity, it is preferable to use one or more selected from polytrimethylene terephthalate (PTT), polyethylene terephthalate (PET), and polybutylene terephthalate (PBT). preferable. The synthetic resin monofilament of the present invention may contain conventional additives such as heat resistant agents, weather resistant agents, plasticizers, colorants, etc., as long as they do not impede the object of the present invention.

本発明の化粧ブラシは、本発明の化粧ブラシ用毛材または本発明の化粧ブラシ用毛材集合体を、少なくとも一部に使用したことを特徴とするものである。より詳しくは、本発明の化粧ブラシは、本発明の化粧ブラシ用毛材または本発明の化粧ブラシ用毛材集合体を、化粧ブラシ用毛材全体の10重量%以上含有することが好ましく、20重量%以上含有することがより好ましく、25重量%以上含有することがさらに好ましく、30重量%以上含有することが特に好ましい。
本発明の化粧ブラシは、本発明の化粧ブラシ用毛材または本発明の化粧ブラシ用毛材集合体を、化粧ブラシ用毛材全体の10重量%以上100重量%以下の範囲において含有することにより、粉末状または液状化粧料に対するキャッチ&リリース性において、天然獣毛を用いた化粧ブラシより優れた性能を発揮することができるほか、肌あたりと柔軟性においても、天然獣毛を用いた化粧ブラシに近似したものとすることができる。特に、本発明の化粧ブラシ用毛材または本発明の化粧ブラシ用毛材集合体を、化粧ブラシ用毛材全体の30重量%以上含有する本発明の化粧ブラシは、本発明の効果を十分に発揮することができる。
本発明の化粧ブラシは、本発明の化粧ブラシ用毛材または本発明の化粧ブラシ用毛材集合体以外は、ナイロン繊維やポリエステル繊維などの合成繊維からなる化粧ブラシ用毛材を使用することができる。
また、本発明の化粧ブラシにおいては、合成樹脂製モノフィラメントの先端が、テーパー状に形成された先細部を備えるように加工されていることが好ましい。さらに、このテーパー状に形成された先細部が分岐するように加工されているとより好ましい。このように先端部を加工することにより、化粧料の塗布時において肌あたりがよくなり、天然獣毛により近い優れた触感が得られる。
The cosmetic brush of the present invention is characterized in that the cosmetic brush bristle material of the present invention or the cosmetic brush bristle material assembly of the present invention is used at least in part. More specifically, the cosmetic brush of the present invention preferably contains the cosmetic brush bristle material of the present invention or the cosmetic brush bristle aggregate of the present invention in an amount of 10% or more by weight of the entire makeup brush bristle material, and preferably contains 20% by weight or more of the cosmetic brush bristle material of the present invention. The content is more preferably 25% by weight or more, even more preferably 30% by weight or more, and particularly preferably 30% by weight or more.
The cosmetic brush of the present invention contains the bristle material for a cosmetic brush of the present invention or the bristle material aggregate for a cosmetic brush of the present invention in an amount of 10% to 100% by weight of the entire bristle material for a cosmetic brush. Cosmetic brushes made from natural animal hair not only exhibit superior performance in catching and releasing powdered or liquid cosmetics than cosmetic brushes made from natural animal hair, but also in terms of skin feel and flexibility. It can be approximated by In particular, the cosmetic brush of the present invention, which contains the bristle material for a cosmetic brush of the present invention or the bristle material aggregate for a cosmetic brush of the present invention in an amount of 30% by weight or more based on the entire bristle material for a cosmetic brush, can fully exhibit the effects of the present invention. able to demonstrate.
In the makeup brush of the present invention, other than the makeup brush bristle material of the present invention or the makeup brush bristle aggregate of the present invention, makeup brush bristle materials made of synthetic fibers such as nylon fibers and polyester fibers may be used. can.
Further, in the cosmetic brush of the present invention, it is preferable that the tip of the synthetic resin monofilament is processed to have a tapered part. Furthermore, it is more preferable that the tapered portion is processed to branch. By processing the tip in this way, it feels better on the skin when applying cosmetics, and provides an excellent tactile sensation that is closer to natural animal hair.

<化粧ブラシ用毛材の製造方法>
次に、本発明の化粧ブラシ用毛材の製造方法の1例について説明する。
化粧ブラシ用毛材の合成樹脂製モノフィラメントは、ポリエステル系樹脂等の合成樹脂ペレットまたは粉末と、必要に応じて添加剤とを均一に分散するように混合撹拌した後、押出型紡糸機のホッパーに供給し、加熱溶融された合成樹脂混合物を本発明の毛材断面形状に対応するまゆ型形状のノズルから押出して、紡糸口より紡糸して3段の加熱延伸により4~5倍の延伸を行い、断面がまゆ型形状の合成樹脂製モノフィラメントを製造する。
合成樹脂製モノフィラメントを上述の撚数で撚った後、撚り合わせた合成樹脂製モノフィラメントを、合成樹脂の融点以下の温度で加熱して、熱セットする。熱セットの時間は温度にもよるが、例えば、185℃で5分間程度である。これによって、撚りが掛かった構造が固定化され使用環境の影響を受けず形状が安定となる。そして熱セットした合成樹脂製モノフィラメントを所定の長さ、例えば、長さ25mm以上、好ましくは50mm以上100mm以下の範囲に切断する。
<Method for manufacturing bristle material for makeup brushes>
Next, one example of the method for manufacturing the bristle material for cosmetic brushes of the present invention will be described.
Synthetic resin monofilaments used as bristle materials for makeup brushes are made by mixing and stirring synthetic resin pellets or powder such as polyester resin and additives as necessary to uniformly disperse them, and then placing them in the hopper of an extrusion-type spinning machine. The synthetic resin mixture supplied and heated and melted is extruded from a cocoon-shaped nozzle corresponding to the cross-sectional shape of the hair material of the present invention, spun from a spinneret, and stretched 4 to 5 times by three stages of heating and stretching. , a synthetic resin monofilament with a cocoon-shaped cross section is manufactured.
After twisting the synthetic resin monofilaments to the above-described number of twists, the twisted synthetic resin monofilaments are heated at a temperature below the melting point of the synthetic resin to heat set. The heat setting time depends on the temperature, but is, for example, about 5 minutes at 185°C. As a result, the twisted structure is fixed and the shape becomes stable without being affected by the usage environment. Then, the heat-set synthetic resin monofilament is cut into a predetermined length, for example, 25 mm or more, preferably 50 mm or more and 100 mm or less.

切断した合成樹脂製モノフィラメントは、必要に応じて、先端にテーパー状の先細部を形成してもよい。そのためには、強アルカリ溶液(例えば、水酸化ナトリウム水溶液)に加水分解促進用の触媒を添加し一定温度条件に保った中に、切断した合成樹脂製モノフィラメントの先端から中央部付近までを浸漬する。所定時間浸漬した後、引き上げることで、合成樹脂製モノフィラメントの先端がテーパー状に細くなり、尖った先細部が形成される。この方法で得られた合成樹脂製モノフィラメントは、ほぼ綺麗なテーパー状の先細部を備えたものとなる。また、浸漬時間を適宜設定することにより、合成樹脂製モノフィラメント断面のまゆ型形状のくびれ部分が溶解し、先細部の先端が2つに枝分かれしかつ先鋭化された化粧ブラシ用毛材を得ることができる。この方法は、先細部が分岐した化粧ブラシ用毛材を容易に形成できるため好適である。この先細部の長さは、使用目的や用途に応じて1~30mmの範囲に、分岐した部分の長さは0.1~20mmの範囲にすればよい。 The cut synthetic resin monofilament may have a tapered tip at its tip, if necessary. To do this, the cut synthetic resin monofilament is immersed from the tip to the center in a strong alkaline solution (e.g., aqueous sodium hydroxide solution) with a catalyst added to promote hydrolysis and maintained at a constant temperature. . After being immersed for a predetermined period of time, the tip of the synthetic resin monofilament is tapered and a sharp tapered part is formed by pulling it up. The synthetic resin monofilament obtained by this method has an almost perfectly tapered end. In addition, by appropriately setting the soaking time, the eyebrow-shaped constriction of the cross section of the synthetic resin monofilament is dissolved, and the tip of the tapered part is branched into two and sharpened bristle material for a makeup brush can be obtained. I can do it. This method is suitable because it can easily form a bristle material for a makeup brush with branched taper parts. The length of this tapered part may be in the range of 1 to 30 mm, and the length of the branched part may be in the range of 0.1 to 20 mm, depending on the purpose and application.

次いで、この合成樹脂製モノフィラメントの束を水洗し、乾燥する。そして、合成樹脂製モノフィラメントの束を梳いて撚り合わせたものを1本の化粧ブラシ用毛材とする。
このようにして、得られた化粧ブラシ用毛材は、モノフィラメントの繊維軸と垂直方向の断面が、まゆ型形状であり、かつ、熱セットされた撚りの跡が残り、図4に示すように、特定の断面形状と螺旋構造を有した状態となる。また、アルカリ処理を行うことにより、図5に示すような先細部が分岐した化粧ブラシ用毛材が得られる。
さらに必要に応じて染色処理を行ってもよい。染料は分散染料を使用できるが、耐候堅牢度が5級以上のものが、化粧ブラシの使用時に変色や退色が少ないことから好ましい。また、染料は公知の染色キャリヤー剤を併用してもよいが、染色キャリヤー剤を必要としない高圧染色であることが好ましい。また、モノフィラメントの製造原料に、カーボンブラックや各種顔料などを添加してもよい。この場合には染色時の染料が節約できるばかりか、用途によっては染色を行う必要がないなどの点で好ましい。
Next, this bundle of synthetic resin monofilaments is washed with water and dried. Then, a bundle of synthetic resin monofilaments is combed and twisted together to form a single bristle material for a makeup brush.
The thus obtained cosmetic brush bristle material has an eyebrow-shaped cross section in the direction perpendicular to the fiber axis of the monofilament, and leaves traces of heat-set twisting, as shown in Figure 4. , it has a specific cross-sectional shape and helical structure. Further, by performing an alkali treatment, a bristle material for a makeup brush having a branched taper as shown in FIG. 5 can be obtained.
Furthermore, dyeing treatment may be performed as necessary. Disperse dyes can be used as dyes, but dyes with a weather fastness of grade 5 or higher are preferred because they are less prone to discoloration or fading when used with makeup brushes. Further, although the dye may be used in combination with a known dye carrier agent, it is preferable to use high-pressure dyeing that does not require a dye carrier agent. Furthermore, carbon black, various pigments, and the like may be added to the raw materials for producing monofilaments. This case is preferable because not only can the amount of dye used during dyeing be saved, but also dyeing may not be necessary depending on the application.

<化粧ブラシ用毛材集合体>
本発明の化粧ブラシ用毛材集合体は、S撚り及びZ撚りの化粧ブラシ用毛材の混合集合体である。S撚りとZ撚りの化粧ブラシ用毛材が混在する化粧ブラシ用毛材集合体を使用して化粧ブラシとすると、その塗布部先端の毛材の流れがランダムとなり、粉末状または液状化粧料の捕集量や保持量が均一となり好ましい。化粧ブラシは使用者の使い方や使用癖により、一定方向に捩れて塗布部にクセが付く可能性もあるが、S撚りとZ撚りのものが混在することにより、このクセが付きにくく化粧ブラシの耐久性が一層向上し好適である。
本発明の化粧ブラシ用毛材集合体において、S撚りの化粧ブラシ用毛材とZ撚りの化粧ブラシ用毛材とが、4:6~6:4で混合されていることが好ましい。4:6~6:4で混合された化粧ブラシ用毛材集合体を、化粧ブラシの塗布部に使用することで、内部の空隙部がより多くなり立体感のある塗布部が形成され、天然の獣毛を用いた塗布具に一層近似したものとなり、粉末状または液状化粧料を均一に塗布できるものとなる。さらに、S撚りの化粧ブラシ用毛材とZ撚りの化粧ブラシ用毛材とがほぼ均一に混合されていることが好ましい。この「ほぼ均一に混合される」とは、S撚りの化粧ブラシ用毛材とZ撚りの化粧ブラシ用毛材それぞれが固まって局在化するのではなく、分散された状態を意味する。例えば、S撚りの化粧ブラシ用毛材の隣はZ撚りの化粧ブラシ用毛材が配置され、逆にZ撚りの化粧ブラシ用毛材の隣はS撚りの化粧ブラシ用毛材が存在するように、化粧ブラシの塗布部のほぼ全体に亘ってS撚りの化粧ブラシ用毛材とZ撚りの化粧ブラシ用毛材がほぼ交互に配置される状態をいう。S撚りの化粧ブラシ用毛材とZ撚りの化粧ブラシ用毛材とがほぼ均一に混合されることで、隣接し合う化粧ブラシ用毛材同士が密着し合って密集することが阻害されるために、化粧ブラシ用毛材間に空隙部が形成されやすくなり、ふんわりとした量感の高い化粧ブラシを形成できる。
また、S撚りの化粧ブラシ用毛材とZ撚りの化粧ブラシ用毛材とがほぼ均一に混合されてなる化粧ブラシの塗布部は、0.3g/cm~0.5g/cmの毛密度であることが好ましい。化粧ブラシの塗布部の毛密度が、上述の範囲であれば、塗布部に立体感があり、塗布部の先端部分が広がりボリュウム感が出ることで、天然の獣毛を用いた塗布具に近似したものとなり、粉末状または液状化粧料の塗布に適したものとなる。
<Bristles aggregate for makeup brushes>
The bristle material assembly for cosmetic brushes of the present invention is a mixed assembly of S-twisted and Z-twisted bristle materials for cosmetic brushes. When a makeup brush is made from a makeup brush bristle assembly containing a mixture of S-twist and Z-twist makeup brush bristle materials, the flow of the bristle material at the tip of the application part becomes random, and powdery or liquid cosmetics are mixed. This is preferable because the amount of collection and the amount of retention are uniform. Depending on the user's usage and usage habits, makeup brushes can twist in a certain direction and cause curls in the application area, but the combination of S-twist and Z-twist makes makeup brushes less likely to get curly. The durability is further improved, which is preferable.
In the makeup brush bristle material assembly of the present invention, it is preferable that the S-twist makeup brush bristle material and the Z-twist makeup brush bristle material are mixed in a ratio of 4:6 to 6:4. By using a bristle aggregate for makeup brushes mixed at a ratio of 4:6 to 6:4 in the application area of the makeup brush, the internal voids become larger and an application area with a three-dimensional effect is formed. This applicator is more similar to the applicator using animal hair, and can evenly apply powdered or liquid cosmetics. Further, it is preferable that the S-twist bristle material for a makeup brush and the Z-twist bristle material for a makeup brush are almost uniformly mixed. This "substantially uniformly mixed" means that the S-twist makeup brush bristle material and the Z-twist makeup brush bristle material are not solidified and localized, but are dispersed. For example, a Z-twist makeup brush bristle material is placed next to an S-twist makeup brush bristle material, and conversely, an S-twist makeup brush bristle material is placed next to a Z-twist makeup brush bristle material. This refers to a state in which S-twist makeup brush bristle material and Z-twist makeup brush bristle material are arranged almost alternately over almost the entire application area of the makeup brush. Because the S-twist makeup brush bristle material and the Z-twist makeup brush bristle material are almost uniformly mixed, adjacent makeup brush bristle materials are prevented from coming into close contact with each other and crowding together. In addition, voids are easily formed between the bristle materials for the makeup brush, and a fluffy makeup brush with a high volume can be formed.
In addition, the application area of a makeup brush made of an almost uniform mixture of S-twisted makeup brush bristle material and Z-twisted makeup brush bristle material has bristle of 0.3 g/cm 3 to 0.5 g/cm 3 . Density is preferred. If the hair density of the application part of the makeup brush is within the range mentioned above, the application part will have a three-dimensional effect, and the tip of the application part will expand and give a sense of volume, resembling an applicator using natural animal hair. This makes it suitable for applying powdered or liquid cosmetics.

<化粧ブラシの製造方法>
上述の製造方法等により得られた、本発明の化粧ブラシ用毛材または化粧ブラシ用毛材集合体を使用した化粧ブラシの製造方法の1例について説明する。
本発明の化粧ブラシ用毛材または化粧ブラシ用毛材集合体を、化粧ブラシ用毛材全体の少なくとも一部に、好ましくは10重量%以上、より好ましくは20重量%以上、さらに好ましくは25重量%以上、特に好ましは30重量%以上含有させたものをブラシ穂先形成用の壺に投入し、振動を与えながら壺の内部形状に従い、中央部が盛り上がった穂先部を成形し、次いで、成形された穂先部を化粧ブラシハンドル部の先に設けた円筒状口金内に挿入し化粧ブラシとする。
<Method for manufacturing makeup brushes>
An example of a method for manufacturing a makeup brush using the bristle material for makeup brushes or the bristle material aggregate for makeup brushes of the present invention obtained by the above-mentioned manufacturing method etc. will be described.
The bristle material for makeup brushes or the bristle material aggregate for makeup brushes of the present invention is applied to at least a portion of the entire bristle material for makeup brushes, preferably at least 10% by weight, more preferably at least 20% by weight, and even more preferably at least 25% by weight. % or more, preferably 30% or more by weight, is put into a jar for forming a brush tip, and while applying vibration, a brush tip with a raised center part is formed according to the internal shape of the jar, and then molded. The brushed tip portion is inserted into a cylindrical mouthpiece provided at the tip of the makeup brush handle portion to form a makeup brush.

本発明の化粧ブラシは、粉末状または液状化粧料を均一に塗布するために好適で、各種化粧ブラシ、例えばリキッドブラシ、リップブラシ、ネイルケアブラシ、ファンデーションブラシ、パウダーブラシ、シャドウ用ブラシ、頬紅用ブラシ、ハイライト用ブラシまたはコンシーラーブラシ等として利用できる。中でも、粉末状化粧料を皮膚面上で薄く伸ばしながら塗布する使用法、いわゆるボカシ塗りに特に適しており、このような塗布法を多用する、フェイス用ブラシ、頬紅用ブラシ、ハイライト用ブラシ又はアイシャドウ等のシャドウ用ブラシとして使用する際に優れた性能を発揮する。 The makeup brush of the present invention is suitable for uniformly applying powdered or liquid cosmetics, and can be used with various makeup brushes, such as liquid brushes, lip brushes, nail care brushes, foundation brushes, powder brushes, shadow brushes, and blusher brushes. , can be used as a highlight brush, concealer brush, etc. Among these, it is particularly suitable for applying powdered cosmetics while spreading it thinly on the skin surface, so-called blurring, and is suitable for use with face brushes, blusher brushes, highlight brushes, or brushes that often use this application method. Demonstrates excellent performance when used as a brush for shadows such as eye shadow.

以下、実施例を挙げて本発明を説明するが、本発明の技術範囲はこれらにより限定されるものではない。 The present invention will be explained below with reference to Examples, but the technical scope of the present invention is not limited by these.

<本発明の化粧ブラシ用毛材および化粧ブラシの製造例>
(化粧ブラシA)
まゆ型形状の断面形状を有するポリトリメチレンテレフタレートモノフィラメント(長径a=156μm、くぼみ幅b=100μm、短径c=56μm、くぼみ径d=25μmに相当。)×60本を、合撚機で80T/m(ターン/m)の撚り数をS字方向に入れたもの(S撚り)と、Z字方向に入れたもの(Z撚り)をそれぞれ、120℃で40分間の蒸気処理により撚り止めを行い、波長幅が11mmのS撚り及びZ撚りの化粧ブラシ用毛材集合体を得た。次いで、化粧ブラシ用毛材集合体のS撚りとZ撚りとを1:1の割合で混ぜながら引き揃え、直径4cmの繊維束を作成し、紙を巻き保護した。この繊維束を8cmの長さにカットし直径4cm、長さ8cmのコロとした。さらに、水酸化ナトリウム100g/L、第4級アミン(一方社油脂工業株式会社製、商品名「DYK-1125」)6g/Lの水溶液を作成し、該溶液に繊維束の一端を浸漬し、130℃で130分間処理を行い、先細加工した繊維束を染色した後、撚りを櫛で梳いて凹型の壺に毛先を下にして振動を与え、毛型を整えた化粧ブラシAを作成した。
<Manufacturing example of the bristle material for makeup brushes and makeup brushes of the present invention>
(Makeup brush A)
60 pieces of polytrimethylene terephthalate monofilament having a cocoon-shaped cross-sectional shape (equivalent to major axis a = 156 μm, concave width b = 100 μm, minor axis c = 56 μm, concave diameter d = 25 μm) were twisted using a twisting machine at 80T. /m (turns/m) of twists in the S-shaped direction (S twist) and those in the Z-shaped direction (Z twist) were treated with steam at 120°C for 40 minutes to stop twisting. As a result, S-twist and Z-twist bristle aggregates for cosmetic brushes with a wavelength width of 11 mm were obtained. Next, the S-twist and Z-twist of the bristle material aggregate for a makeup brush were mixed at a ratio of 1:1 and pulled together to form a fiber bundle with a diameter of 4 cm, which was protected by wrapping with paper. This fiber bundle was cut into a length of 8 cm to form a roll having a diameter of 4 cm and a length of 8 cm. Furthermore, an aqueous solution containing 100 g/L of sodium hydroxide and 6 g/L of quaternary amine (manufactured by Ippo Sha Yushi Kogyo Co., Ltd., trade name "DYK-1125") was prepared, and one end of the fiber bundle was immersed in the solution. After processing at 130°C for 130 minutes to dye the tapered fiber bundles, the strands were combed and placed in a concave pot with the bristles facing down and vibrated to create a makeup brush A with the hair shape adjusted. .

(化粧ブラシB)
上記「化粧ブラシA」の製造例において、まゆ型形状の断面形状を有するポリトリメチレンテレフタレートモノフィラメント(長径a=126μm、くぼみ幅b=76μm、短径c=54μm、くぼみ径d=46μmに相当。)×60本を、合撚機で80T/m(ターン/m)の撚り数をS字方向に入れたもの(S撚り)と、Z字方向に入れたもの(Z撚り)を使用した以外は同様にして、化粧ブラシBを作成した。
(Makeup brush B)
In the production example of the above-mentioned "cosmetic brush A", a polytrimethylene terephthalate monofilament having an eyebrow-shaped cross-sectional shape (corresponding to the major axis a = 126 μm, the concave width b = 76 μm, the minor axis c = 54 μm, and the concave diameter d = 46 μm). ) x 60 strands were twisted at 80 T/m (turns/m) using a twisting machine in the S-shaped direction (S twist) and in the Z-shaped direction (Z twist). Cosmetic brush B was created in the same manner.

(比較例ブラシ)
上記「化粧ブラシA」の製造例において、円形状の断面形状を有するポリトリメチレンテレフタレートモノフィラメント75μm(0.075mm:「繊維直径」に相当。)×60本を、合撚機で80T/m(ターン/m)の撚り数をS字方向に入れたもの(S撚り)と、Z字方向に入れたもの(Z撚り)を使用した以外は同様にして、比較例ブラシを作成した。
(Comparative example brush)
In the manufacturing example of the above "cosmetic brush A", 60 pieces of polytrimethylene terephthalate monofilament having a circular cross-sectional shape of 75 μm (0.075 mm: equivalent to "fiber diameter") are twisted by a twisting machine at 80 T/m ( Comparative example brushes were created in the same manner except that the number of twists (turns/m) in the S-shaped direction (S twist) and in the Z-shaped direction (Z twist) were used.

<化粧ブラシの使用性能の評価1:パウダーキャッチ性の評価>
本発明の化粧ブラシにおける、パウダーキャッチ性(含み性)について評価する試験を行った。本発明における、パウダーキャッチ性(含み性)とは、化粧ブラシに対する粉末状化粧料の粉付きを示すものである。
(試験検体)
上記製造例により製造した、化粧ブラシA、B、比較例ブラシのほか、獣毛の化粧ブラシの最高級品として消費者から高い評価を得ている市販の山羊毛(粗光峰)の化粧ブラシを使用して、粉末状化粧料(株式会社資生堂製:インテグレートミネラルグロープレストパウダー)のパウダーキャッチ性(含み性)を、表面性試験機(株式会社トリニティーラボ製、商品名:トリラボ ハンディーラブテスターType:TL701)を用いて評価した。
(試験方法)
粉末状化粧料が充填された円形容器(直径:5.5cm)を、上記表面性試験機の接触子に略垂直に両面テープで貼り付けた。粉末状化粧料の表面に、試験検体である化粧ブラシの穂先部が略直角に接するように、各試験検体を回転台に取り付け、試験台に対して水平となるように固定した。
化粧ブラシの穂先部を粉末状化粧料の表面に対して、10回スイープさせて(速度:6rpm、回転半径:100mm、回転角度:90度)、化粧ブラシの穂先部に粉末状化粧料をピックアップさせた。
各試験検体のパウダーキャッチ性は、試験終了前後の化粧ブラシの重量を計測し、その重量差を10回パウダーキャッチ量(含み量)として評価した。
なお、未使用の化粧ブラシについては、上記試験方法により、粉末状化粧料の表面を10回スイープさせて粉末状化粧料を捕集させた後、当該化粧ブラシをティッシュにスイープさせて、ティッシュに粉末状化粧料が付着しなくなるまで放出させたものを試験検体として使用した。
試験は2回行い、各試験検体の平均値を図6に示した。
<Evaluation of usability of makeup brushes 1: Evaluation of powder catchability>
A test was conducted to evaluate the powder catchability (retainability) of the makeup brush of the present invention. In the present invention, powder catchability (retainability) refers to the ability of powdered cosmetics to stick to a makeup brush.
(Test sample)
In addition to the cosmetic brushes A, B, and comparative example brushes manufactured according to the above production example, commercially available goat hair (Sokoho) cosmetic brushes are highly rated by consumers as the highest quality animal hair makeup brushes. Using a surface property tester (manufactured by Trinity Lab Co., Ltd., product name: Tori Labo Handy Love Tester Type), the powder catching property (inclusion property) of a powdered cosmetic (manufactured by Shiseido Co., Ltd.: Integrate Mineral Glow Presto Powder) was measured using :TL701).
(Test method)
A circular container (diameter: 5.5 cm) filled with a powdered cosmetic was attached approximately perpendicularly to the contact of the surface property tester using double-sided tape. Each test sample was attached to a rotary stand so that the tip of the makeup brush, which was a test sample, was in contact with the surface of the powdered cosmetic at a substantially right angle, and was fixed horizontally to the test stand.
Sweep the tip of the makeup brush against the surface of the powdered cosmetic 10 times (speed: 6 rpm, rotation radius: 100 mm, rotation angle: 90 degrees) to pick up the powdered cosmetic on the tip of the makeup brush. I let it happen.
The powder catching ability of each test sample was evaluated by measuring the weight of the makeup brush before and after the test, and evaluating the weight difference 10 times as the powder catching amount (containing amount).
For unused makeup brushes, use the above test method to sweep the surface of powdered cosmetics 10 times to collect the powdered cosmetics, and then sweep the makeup brush against a tissue. The powdered cosmetic was released until it no longer adhered and was used as a test sample.
The test was conducted twice, and the average value of each test specimen is shown in FIG.

図6の結果より、本発明の化粧ブラシ用毛材からなる化粧ブラシA、Bは、断面形状が円形状である比較例ブラシに比べて、パウダーキャッチ量が約2.6~3.4倍多いことが確認された。また、市販されている山羊毛の化粧ブラシと比べると、パウダーキャッチ量が約1.3~1.8倍多くなることも確認された。
本発明の化粧ブラシ用毛材は、撚りと特定の断面形状という2つの特異的な立体形状の組み合わせにより相乗効果を発揮し、パウダーキャッチ性(含み性)に優れた化粧ブラシとし得ることが、この評価結果より明らかとなった。
From the results shown in FIG. 6, the amount of powder caught by the makeup brushes A and B made of the bristle material for makeup brushes of the present invention is approximately 2.6 to 3.4 times that of the comparative brush having a circular cross-sectional shape. It was confirmed that there are many It was also confirmed that the amount of powder caught was approximately 1.3 to 1.8 times greater than that of commercially available goat hair makeup brushes.
The bristle material for makeup brushes of the present invention exhibits a synergistic effect through the combination of two specific three-dimensional shapes, namely, twisting and a specific cross-sectional shape, and can be made into a makeup brush with excellent powder catching properties. This became clear from the evaluation results.

<化粧ブラシの使用性能の評価2:パウダーリリース性の評価>
本発明の化粧ブラシにおける、パウダーリリース性(放出性)について評価する試験を行った。本発明における、パウダーリリース性(放出性)とは、化粧ブラシから塗布面への粉末状化粧料の吐き出し性能を示すものである。
(試験検体)
上記「化粧ブラシの使用性能の評価1」と同じ化粧ブラシAと市販の山羊毛(粗光峰)の化粧ブラシを使用した。山羊毛、特に、首から胸にかけての摩耗の少ない柔軟な原毛を原料とする山羊毛(粗光峰)の化粧ブラシは、粉末状化粧料を多く含み放出性も良好であるため、ファンデーションや頬紅などの広めの範囲の塗布から、アイシャドウのような細かい部分の塗布まで対応できる化粧ブラシとして、消費者から高い評価を得ているものである。
<Evaluation of usability of makeup brushes 2: Evaluation of powder release properties>
A test was conducted to evaluate the powder release properties of the cosmetic brush of the present invention. In the present invention, the term "powder release property" refers to the ability to spit powdered cosmetics from a makeup brush onto an application surface.
(Test sample)
The same makeup brush A as in "Evaluation 1 of performance in use of makeup brushes" and a commercially available goat hair (Sokoho) makeup brush were used. Cosmetic brushes made from goat hair, especially soft wool from the neck to the chest that is less abrasive, contain a large amount of powdered cosmetics and have good release properties, making them ideal for use with foundations and blushers. This makeup brush has received high praise from consumers as a makeup brush that can be used to apply everything from wide areas such as makeup to fine details such as eye shadow.

(パウダーリリース性の評価試験の準備)
試験台上水平に固定した粉末状化粧料(株式会社資生堂製:インテグレートミネラルグロープレストパウダー)表面に、試験検体である各化粧ブラシの穂先部が略直角に接するように、各試験検体を回転台に取り付け、試験台上に対して垂直となるように固定した。
各化粧ブラシの穂先部を粉末状化粧料の表面に対して、スイープさせて(速度:6rpm、回転半径:100mm、回転角度:90度)、各化粧ブラシの穂先部に粉末状化粧料を概略0.01gピックアップさせた。
本発明の化粧ブラシAは、5回のスイープにより粉末状化粧料を0.01g捕集できたのに対し、山羊毛(粗光峰)の化粧ブラシは、15回スイープさせないと粉末状化粧料を0.01g捕集することができなかった。
この結果からも、本発明の化粧ブラシ用毛材からなる化粧ブラシAは、山羊毛(粗光峰)の化粧ブラシに比べて、粉末状化粧料のキャッチ性(含み性)に極めて優れることが確認された。
(パウダーリリース性の評価試験)
塗布面として化粧スポンジを円柱台(直径:47mm)に貼付した。化粧スポンジ表面に、試験検体である粉末状化粧料をピックアップさせた化粧ブラシの穂先部が、略直角に接するように各試験検体をジグに取り付け固定した。
化粧ブラシの穂先部を塗布面に対して5、10、15、20回動かし(速度:6rpm、回転半径:100mm)、塗布面に粉末状化粧料を塗布した。
各試験検体のパウダーリリース性は、5、10、15、20回動かした後の化粧ブラシの重量を計測し、評価試験前の化粧ブラシとの重量差を各回のパウダーリリース量とし、このパウダーリリース量を評価試験前の捕集化粧料で除した値をパウダーリリース率(%)として評価した。
試験は3回行い、各試験検体のパウダーリリース率(%)の平均値を図7に示した。
(Preparation for powder release evaluation test)
Each test specimen was placed on a rotating table so that the tip of each makeup brush was in contact with the surface of the powdered cosmetic (Integrate Mineral Glow Presto Powder, manufactured by Shiseido Co., Ltd.) held horizontally at a right angle. and fixed it perpendicular to the test table.
Sweep the tip of each makeup brush against the surface of the powdered cosmetic (speed: 6 rpm, rotation radius: 100 mm, rotation angle: 90 degrees), and roughly apply the powdered cosmetic to the tip of each makeup brush. 0.01g was picked up.
The makeup brush A of the present invention was able to collect 0.01g of powdered cosmetics after 5 sweeps, whereas the goat hair (Sokoho) makeup brush could collect 0.01g of powdered cosmetics only after 15 sweeps. It was not possible to collect 0.01g of.
This result also shows that the makeup brush A made of the bristle material for makeup brushes of the present invention has extremely superior ability to catch (retain) powdered cosmetics compared to the makeup brush made of goat hair (Sokoho). confirmed.
(Powder release evaluation test)
A makeup sponge was attached to a cylindrical base (diameter: 47 mm) as an application surface. Each test specimen was attached to a jig and fixed so that the tip of the makeup brush, which had picked up the powdered cosmetic as the test specimen, touched the surface of the makeup sponge at a substantially right angle.
The tip of the makeup brush was moved against the application surface 5, 10, 15, and 20 times (speed: 6 rpm, rotation radius: 100 mm) to apply the powdered cosmetic to the application surface.
The powder release properties of each test sample were determined by measuring the weight of the makeup brush after moving it 5, 10, 15, and 20 times, and taking the difference in weight from the makeup brush before the evaluation test as the powder release amount each time. The amount divided by the collection cosmetic before the evaluation test was evaluated as the powder release rate (%).
The test was conducted three times, and the average powder release rate (%) of each test specimen is shown in FIG.

図7の結果より、本発明の化粧ブラシ用毛材からなる化粧ブラシAは、粉末状化粧料のキャッチ&リリース性が良好であることが知られている山羊毛(粗光峰)の化粧ブラシに比べて、リリース性(放出性)、特に、試験開始から5回塗布した初期のリリース性(放出性)が1.2倍以上優れていることが明らかとなった。この初期リリース性(放出性)に優れることは、化粧ブラシで肌を数回撫でるだけで化粧料を肌に塗布できることを意味し、頬紅やアイシャドウ等のポイントメイク化粧料を使用する場合に、優れた機能性が容易に得られることを示すものであり、化粧ブラシとしては非常に優位性の高い効果である。
本発明の化粧ブラシ用毛材は、撚りと特定の断面形状という2つの特異的な立体形状の組み合わせにより相乗効果を発揮し、山羊毛(粗光峰)の化粧ブラシに比べてパウダーキャッチ性(含み性)に優れ、容易に多くの化粧料を含むことができる化粧ブラシとし得るものであり、さらに、パウダーリリース性(放出性)においても、特に、初期のパウダーリリース性(放出性)に極めて優れた効果を発揮し、含んだ化粧料を素早く、かつ、確実に放出する化粧ブラシとし得ることが、この「化粧ブラシの使用性能の評価2」の結果より明らかとなった。
本発明の化粧ブラシ用毛材は、キャッチ性(含み性)とリリース性(放出性)の両性能に優れているため、液状または粉末状化粧料を無駄にすることなく余すことなく使用でき、しかも、他の液状または粉末状化粧料と色混じりを起こす心配が少ない等の、使用者にとって非常に使い勝手に優れた化粧ブラシとし得るものである。
From the results in FIG. 7, it can be seen that the makeup brush A made of the bristle material for makeup brushes of the present invention is a makeup brush made of goat hair (Sokoho), which is known to have good catch and release properties for powdered cosmetics. It was revealed that the release properties (release properties), especially the initial release properties (release properties) after applying 5 times from the start of the test, were 1.2 times or more superior. This excellent initial release property means that cosmetics can be applied to the skin just by stroking the skin several times with a makeup brush, and when using point makeup cosmetics such as blusher or eye shadow, This shows that excellent functionality can be easily obtained, and this is an extremely advantageous effect for a makeup brush.
The bristle material for makeup brushes of the present invention has a synergistic effect due to the combination of two unique three-dimensional shapes, namely twist and a specific cross-sectional shape, and has better powder catching properties than goat hair (Sokoho) makeup brushes. It can be used as a makeup brush that can easily contain a large amount of cosmetics, and has excellent powder release properties, especially in the initial powder release properties. The results of "Evaluation 2 of Usage Performance of Cosmetic Brush" revealed that it can be a cosmetic brush that exhibits excellent effects and quickly and reliably releases the cosmetics it contains.
The bristle material for cosmetic brushes of the present invention has excellent properties in both catching and releasing properties, so liquid or powdered cosmetics can be used without wasting them. In addition, the makeup brush can be made extremely easy to use for the user, as there is little fear of color mixing with other liquid or powder cosmetics.

本発明の化粧ブラシ用毛材は、撚りすなわちS撚りまたはZ撚りと、まゆ型形状の特定の断面形状との2つの特異的な立体形状を有することで、それぞれの立体形状の組み合わせにより相乗効果を発揮し、粉末状または液状化粧料に対するキャッチ&リリース性が、天然獣毛に比べて極めて優れた性能を発揮する。特に、初期リリース性(放出性)に優れているため、含んだ化粧料を素早く肌に塗布することができ、化粧ブラシとして好適に使用することができる。
さらに、テーパー状に形成された先細部を備えることにより、天然獣毛に匹敵する肌あたりと柔軟性を兼ね備えた化粧ブラシ用毛材とすることができる。
The bristle material for cosmetic brushes of the present invention has two specific three-dimensional shapes: twisted, that is, S-twist or Z-twist, and a specific eyebrow-shaped cross-sectional shape, so that the combination of the three-dimensional shapes can produce a synergistic effect. It exhibits extremely superior catch and release properties for powdered or liquid cosmetics compared to natural animal hair. In particular, since it has excellent initial release properties, the cosmetics contained therein can be quickly applied to the skin, and it can be suitably used as a makeup brush.
Furthermore, by providing the tapered end, the bristle material for a makeup brush can have both skin feel and flexibility comparable to natural animal hair.

Claims (7)

S撚りまたはZ撚りの合成樹脂製モノフィラメントからなり、
前記モノフィラメントの繊維軸と垂直方向の断面の全てが、曲線のみにより構成される流線形からなるくびれを有するまゆ型形状であることを特徴とする化粧ブラシ用毛材。
Consists of S-twisted or Z-twisted synthetic resin monofilament,
A bristle material for a makeup brush, characterized in that the entire cross section of the monofilament in a direction perpendicular to the fiber axis has an eyebrow-like shape with a streamlined constriction made only of curves .
前記モノフィラメントが、テーパー状に形成された先細部を備えていることを特徴とする請求項1記載の化粧ブラシ用毛材。 The bristle material for a makeup brush according to claim 1, wherein the monofilament has a tapered end. 前記テーパー状に形成された先細部が分岐していることを特徴とする請求項2記載の化粧ブラシ用毛材。 The bristle material for a cosmetic brush according to claim 2, wherein the tapered end portion is branched. 前記合成樹脂がポリエステル系樹脂であることを特徴とする請求項1~3の何れか1項に記載の化粧ブラシ用毛材。 The bristle material for a makeup brush according to any one of claims 1 to 3, wherein the synthetic resin is a polyester resin. 前記ポリエステル系樹脂が、ポリトリメチレンテレフタレート、ポリエチレンテレフタレート及びポリブチレンテレフタレートから選択された1 種または2 種以上であることを特徴とする請求項4 記載の化粧ブラシ用毛材。 The bristle material for a cosmetic brush according to claim 4, wherein the polyester resin is one or more selected from polytrimethylene terephthalate, polyethylene terephthalate, and polybutylene terephthalate. S撚り及びZ撚りの合成樹脂製モノフィラメントの混合集合体からなり、前記モノフィラメントの繊維軸と垂直方向の断面の全てが、曲線のみにより構成される流線形からなるくびれを有するまゆ型形状であることを特徴とする化粧ブラシ用毛材集合体。 Consisting of a mixed aggregate of S-twisted and Z-twisted synthetic resin monofilaments, all cross-sections of the monofilaments in the direction perpendicular to the fiber axis have a cocoon -shaped constriction consisting of streamlined shapes consisting only of curved lines. A bristle material assembly for makeup brushes characterized by: 請求項6に記載の化粧ブラシ用毛材集合体を、少なくとも一部に使用したことを特徴とする化粧ブラシ。 A makeup brush, characterized in that the bristle assembly for makeup brushes according to claim 6 is used in at least a portion thereof.
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