JP7322050B2 - エチレングリコールの製造のための連続的又は半連続的な方法、及びそれに使用するための触媒系 - Google Patents

エチレングリコールの製造のための連続的又は半連続的な方法、及びそれに使用するための触媒系 Download PDF

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JP7322050B2
JP7322050B2 JP2020548707A JP2020548707A JP7322050B2 JP 7322050 B2 JP7322050 B2 JP 7322050B2 JP 2020548707 A JP2020548707 A JP 2020548707A JP 2020548707 A JP2020548707 A JP 2020548707A JP 7322050 B2 JP7322050 B2 JP 7322050B2
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tungsten
reactor
heterogeneous catalyst
catalyst
ethylene glycol
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JP2021517571A (ja
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ヤン・コルネリス・ファン・デル・ヴァール
パウラ・デッケル
ジャグディープ・シン
ベンヤミン・マカーイ
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アバンティウム・ナレッジ・センター・ベー・フェー
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0213—Preparation of the impregnating solution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00033—Continuous processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C07C31/202—Ethylene glycol
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2020548707A 2018-03-14 2019-03-14 エチレングリコールの製造のための連続的又は半連続的な方法、及びそれに使用するための触媒系 Active JP7322050B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
NL2020584 2018-03-14
NL2020584 2018-03-14
PCT/EP2019/056509 WO2019175362A1 (en) 2018-03-14 2019-03-14 Continuous or semi-continuous process for the preparation of ethylene glycol and catalyst system for use therein

Publications (2)

Publication Number Publication Date
JP2021517571A JP2021517571A (ja) 2021-07-26
JP7322050B2 true JP7322050B2 (ja) 2023-08-07

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JP2020548707A Active JP7322050B2 (ja) 2018-03-14 2019-03-14 エチレングリコールの製造のための連続的又は半連続的な方法、及びそれに使用するための触媒系

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Country Link
US (1) US11059768B2 (pt)
EP (1) EP3765431B1 (pt)
JP (1) JP7322050B2 (pt)
CN (1) CN111868019B (pt)
BR (1) BR112020017094B8 (pt)
CA (1) CA3091470A1 (pt)
EA (1) EA202092100A1 (pt)
LT (1) LT3765431T (pt)
PL (1) PL3765431T3 (pt)
WO (1) WO2019175362A1 (pt)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2020356546A1 (en) 2019-09-24 2022-04-07 T.En Process Technology, Inc. Methods for operating continuous, unmodulated, multiple catalytic step processes
EP4107142B1 (en) 2020-02-17 2024-04-03 Avantium Knowledge Centre B.V. Process for preparing alkylene glycol mixture from a carbohydrate source with increased selectivity for glycerol
US11680031B2 (en) 2020-09-24 2023-06-20 T. EN Process Technology, Inc. Continuous processes for the selective conversion of aldohexose-yielding carbohydrate to ethylene glycol using low concentrations of retro-aldol catalyst
US11319269B2 (en) 2020-09-24 2022-05-03 Iowa Corn Promotion Board Continuous processes for the selective conversion of aldohexose-yielding carbohydrate to ethylene glycol using low concentrations of retro-aldol catalyst
CN115340440A (zh) * 2022-08-18 2022-11-15 山东能源集团有限公司 一种制备乙二醇的方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110313210A1 (en) 2011-07-28 2011-12-22 Uop Llc Catalytic process for continuously generating polyols
CN102643165A (zh) 2011-06-28 2012-08-22 中国科学院大连化学物理研究所 连续加氢裂解糖转化生产乙二醇及1,2-丙二醇的方法
JP2018501321A (ja) 2015-01-13 2018-01-18 アバンティウム・ナレッジ・センター・ベー・フェー 炭水化物源からエチレングルコールを製造するための連続法
JP2018502920A (ja) 2015-01-13 2018-02-01 アバンティウム・ナレッジ・センター・ベー・フェー 炭水化物源からエチレングルコールを製造する方法
JP2018502919A (ja) 2015-01-13 2018-02-01 アバンティウム・ナレッジ・センター・ベー・フェー 炭水化物源からエチレングルコールを製造する方法
JP2018502921A (ja) 2015-01-13 2018-02-01 アバンティウム・ナレッジ・センター・ベー・フェー 炭水化物源からエチレングルコールを製造する方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3356314B1 (en) 2015-09-29 2020-10-21 Shell International Research Maatschappij B.V. Process for the preparation of glycols
BR112018007830B1 (pt) * 2015-10-20 2021-09-21 Shell Internationale Research Maatschappij B.V. Método para produção de etilenoglicol a partir de uma alimentação de carboidrato
WO2017097847A1 (en) * 2015-12-09 2017-06-15 Shell Internationale Research Maatschappij B.V. Process for the preparation of glycols
CN106868305B (zh) * 2015-12-12 2019-05-28 中国科学院大连化学物理研究所 一种复杂反应底物中回收钨基催化剂的方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102643165A (zh) 2011-06-28 2012-08-22 中国科学院大连化学物理研究所 连续加氢裂解糖转化生产乙二醇及1,2-丙二醇的方法
US20110313210A1 (en) 2011-07-28 2011-12-22 Uop Llc Catalytic process for continuously generating polyols
JP2018501321A (ja) 2015-01-13 2018-01-18 アバンティウム・ナレッジ・センター・ベー・フェー 炭水化物源からエチレングルコールを製造するための連続法
JP2018502920A (ja) 2015-01-13 2018-02-01 アバンティウム・ナレッジ・センター・ベー・フェー 炭水化物源からエチレングルコールを製造する方法
JP2018502919A (ja) 2015-01-13 2018-02-01 アバンティウム・ナレッジ・センター・ベー・フェー 炭水化物源からエチレングルコールを製造する方法
JP2018502921A (ja) 2015-01-13 2018-02-01 アバンティウム・ナレッジ・センター・ベー・フェー 炭水化物源からエチレングルコールを製造する方法

Also Published As

Publication number Publication date
EP3765431B1 (en) 2022-05-04
EP3765431A1 (en) 2021-01-20
PL3765431T3 (pl) 2022-10-10
US11059768B2 (en) 2021-07-13
US20210002192A1 (en) 2021-01-07
CN111868019A (zh) 2020-10-30
CN111868019B (zh) 2023-06-30
LT3765431T (lt) 2022-10-10
EA202092100A1 (ru) 2021-01-18
CA3091470A1 (en) 2019-09-19
WO2019175362A1 (en) 2019-09-19
BR112020017094B8 (pt) 2024-03-05
BR112020017094A2 (pt) 2020-12-22
BR112020017094B1 (pt) 2023-07-25
JP2021517571A (ja) 2021-07-26

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