JP7299376B2 - Method for forming decorative film surface - Google Patents

Description

The present invention relates to a novel method for forming a decorative coated surface.

2. Description of the Related Art Conventionally, decorative coatings having various patterns have been formed on walls of buildings, civil engineering structures, and the like. An example of such a decorative coating is a decorative coating in which a plurality of coating materials are partially coated to form a pattern.

For example, Patent Literature 1 describes a method in which an undercoat paint is applied to the entire surface and a pattern is applied with a darker color paint (patterning paint) than the undercoat paint before the undercoat paint dries. However, in Patent Document 1, since the patterning paint is applied before the undercoat dries, the undercoat and patterning paint are likely to mix on the surface to be coated, and the contrast in color, texture, etc. may be reduced. There is

JP 2008-266911 A

SUMMARY OF THE INVENTION It is an object of the present invention to provide a method of forming a decorative film surface with contrast and high aesthetic appearance.

In order to solve such a problem, the present inventors have made extensive studies and found that at least two coating materials having a color difference (ΔE) of 20 or more and different glossiness are applied to the surface to be coated by a specific method. The present inventors have devised a method for forming a decorative film surface including the step of coating, and have completed the present invention.

That is, the present invention has the following features.
1. A method for forming a decorative coated surface in which at least two or more colored regions are mixed,
Using at least two types of coating materials having a color difference (ΔE) of 20 or more and different glossiness,
All of the above coating materials have a heating residue of 25% by weight or more,
on the surface to be coated,
A first step of applying the first coating material, a second step of applying the second coating material,
The heating residue of the second coating material is higher than that of the first coating material,
A method for forming a decorative coated surface, characterized in that after the first coating material becomes non-flowing, the second coating material is applied discontinuously so as to partially adhere .
2. 1. The first coating material is applied to the entire surface of the surface to be coated. The method for forming the decorative coating surface according to 1.
3. 1. The first coating material is applied discontinuously so as to partially adhere to the surface to be coated. The method for forming the decorative coating surface according to 1.

The present invention includes a step of using at least two coating materials having a color difference (ΔE) of 20 or more and different glossiness, and sequentially applying the two coating materials to the surface to be coated, After the coating material previously applied in the previous process has become non-flowing, the coating material in the next process is discontinuously applied to create a decorative coated surface in which at least two or more colored regions are mixed. It is possible to obtain a highly aesthetically pleasing decorative coating surface with contrast.

FIG. 1 is a front view showing an example of a decorative coated surface formed by the present invention. FIG. 2 is a cross-sectional view showing an example of a pressing tool that can be used in the present invention. FIG. 3 is a cross-sectional view showing an example of rollers that can be used in the present invention. FIG. 4 is a front view showing an example of the decorative coated surface formed by the present invention.

1. Decorative coating surface 1a. Colored area A
1b. Colored area B
1c. Colored area C
2. pressing tools 2a-2e. sponge material 2f. Height direction3. Rollers 3a-3e. sponge material 3f. Cylindrical outer peripheral surface 3g. Cylindrical outer diameter direction

EMBODIMENT OF THE INVENTION Hereinafter, the form for implementing this invention is demonstrated.

The present invention is a method for forming a decorative coated surface in which at least two or more types of colored regions are mixed, wherein at least two types of coating materials having a color difference (ΔE) of 20 or more and different glossiness are used. Including a step of sequentially applying the above two types of coating materials to the coated surface, and after the coating material previously applied in the previous step becomes non-flowing, the coating material in the next step is applied discontinuously. It is characterized by (partial) coating. When viewed from the front, the decorative coating film formed by the present invention has at least two or more colored regions (for example, colored region A, colored region B, etc.) mixed together. In addition, a discontinuously applied coating is formed on the front side of the decorative coating surface.

FIG. 1 shows an example (front view) of a decorative coating surface formed by the present invention. According to the method of forming the decorative coating surface of the present invention, when viewed from the front as shown in FIG. It is possible to form a highly aesthetically pleasing decorative coating surface.

The method for forming the decorative coated surface shown in FIG. 1 will be described below as an example.

In FIG. 1, two kinds of covering materials, a first covering material and a second covering material, are applied in order to form a decorative coated surface. As the first covering material and the second covering material, those having a color difference (ΔE) of 20 or more (preferably 25 or more) and having different glossiness are used. Although the upper limit of the color difference (ΔE) is not particularly limited, it is preferably 90 or less. The difference in gloss between these coating materials is preferably 2 or more, more preferably 3 or more, and even more preferably 5 or more. The upper limit of the difference in glossiness is preferably 90 or less, more preferably 60 or less. By setting the color difference (ΔE) and the difference in glossiness to specific values as described above, the contrast between the colored regions becomes clear, and the change in color, texture, etc. is large, and a gorgeous finish can be obtained. As a result, it is possible to form a coating having high contrast and high aesthetic appearance.

In addition, the color difference (ΔE) in the present invention is a value measured using a color difference meter. Specifically, each coating material was applied to a standard white paper using a film applicator with a gap of 250 μm, and the coated surface was placed horizontally and the It can be calculated by the following formula from the L ^* value, a ^* value, and b ^* value (average value of 3 or more measurement points) of the film when dried for a certain period of time.
<Formula> ΔE = {(L ^{* 1} - L ^{* 2} ) ² + (a ^{* 1} - a ^{* 2} ) ² + (b ^{* 1} - b ^{* 2} ) ² } ^0.5
(Wherein, L ^*1 , a ^*1 , b ^*1 are L ^* , a ^{* ,} b* of the first coating material, respectively. L*2, a ^*2 , b ^{* 2} are L*2 of the second coating material, respectively. ^* , a ^* , b ^* )

Further, "glossiness" is a value measured according to JIS K5600-4-7 "specular glossiness". Specifically, the coating material is applied to one side of the glass plate using a film applicator with a gap of 150 μm, and the coated surface is placed horizontally and dried for 48 hours under standard conditions. Specular glossiness (measurement angle 60 degrees) is a value obtained by measuring

As a method for forming the decorative coating surface shown in FIG. 1, for example,
A first step of applying the first coating material to the surface to be coated, and a second step of applying the second coating material,
(I) A method in which the first coating material is applied to the entire surface of the surface to be coated, and after the first coating material is in a non-flowing state, the second coating material is discontinuously applied.
(II) A method of discontinuously applying the first coating material to the surface to be coated, and discontinuously applying the second coating material after the first coating material becomes non-flowing,
etc.

In the above (I), the amount of the first coating material to be applied may be appropriately set in consideration of the type/condition of the surface to be coated, finish, etc., but is preferably 30 to 500 g/m ² , more preferably 80 g/m 2 . ~400 g/m ² , more preferably 90 to 300 g/m ² . When the coating amount of the first coating material satisfies the above range, a continuous film covering the entire surface to be coated is likely to be formed. In addition, the amount of application of the second coating material may be appropriately set according to the desired finish (pattern, etc.), but it is preferable that the amount of application of the second coating material is less than that of the first coating material. It is preferably 100 g/m ² or less, more preferably 5 to 90 g/m ² , still more preferably 10 to 80 g/m ² . When the coating amount of the second coating material satisfies the above range, a discontinuous coating is likely to be formed, and a decorative coated surface in which different colored regions are mixed can be stably formed. In the present invention, "a to b" is synonymous with "a or more and b or less".

In the above (II), the coating amount of at least one of the first coating material and the second coating material is preferably 100 g/m ² or less (more preferably 5 to 90 g/m ² , still more preferably 10 to 80 g /m ² ). Another type of coating material may be appropriately set in consideration of the type, condition, finish, etc. of the surface to be coated, but is preferably 500 g/m ² or less (more preferably 100 g/m ² or less, further preferably 5 to 90 g/m ² , particularly preferably 10 to 80 g/m ² ). In (II) above, the coating amounts of the first coating material and the second coating material are each preferably within a range of 100 g/m ² or less.

In (I) above, the coating amount of the coating material applied to the entire surface to be coated is preferably 10 to 500 g/m ² , more preferably 20 to 400 g/m in terms of solid content. ² . In addition, in the above (I) and (II), the coating amount of the coating material discontinuously applied to the surface to be coated is preferably 100 g/m ² or less, more preferably 1 to 100 g/m 2 in terms of solid content. 80 g/m ² , more preferably 5 to 40 g/m ² . In addition, in (I) above, it is preferable that the amount of the second coating material applied is less than the amount of the first coating material applied.

The coating material in the present invention can be diluted with various solvents at the time of application. The dilution ratio of the coating material is preferably 0 to 50% by weight (more preferably 0 to 30% by weight) relative to the coating material. In the present invention, it is preferable that the dilution ratio of the coating material in the second step (next step) is smaller than the dilution ratio of the coating material in the first step (previously applied coating material). In particular, in the above (I), a coating material having a large dilution ratio (preferably 1 to 50% by weight, more preferably 2 to 40% by weight) is applied to the entire surface to be coated as the first coating material, and the second coating It is preferable to discontinuously apply a coating material having a small dilution ratio (preferably 0 to 20% by weight, more preferably 0 to 10% by weight). In this case, colored areas of different colors coexist, and a highly aesthetically pleasing decorative coated surface having contrast can be formed more efficiently.

The viscosity of the coating material when applied is preferably 0.1 to 10 Pa·s, more preferably 0.5 to 9.5 Pa·s. In particular, in (I) above, the coating material in the first step (previously applied coating material) preferably has a viscosity at the time of application of 0.1 to 8 Pa s (more preferably 0.5 to 6 Pa s). s). In such a case, a continuous film covering the entire surface to be coated is likely to be formed, and excellent finishing can be ensured. On the other hand, the coating material in the second step (next step) preferably has a viscosity of 2 to 10 Pa·s (more preferably 2.5 to 9.5 Pa·s) when applied. In such a case, the spongy material contains an appropriate amount of the covering material, so that a discontinuous film is likely to be formed, the boundaries between the colored regions become clear, and the design can be enhanced. In particular, in (I) above, it is preferable that the viscosity of the coating material in the second step (next step) is higher than the viscosity of the coating material in the first step (previously applied coating material), and the difference in viscosity is preferably 1 to 8 Pa·s (more preferably 1.5 to 6 Pa·s). In this case, colored areas of different colors coexist, and a highly aesthetically pleasing decorative coated surface having contrast can be formed more efficiently.

In (II) above, the viscosity of the first coating material and the second coating material when applied is preferably 2 to 10 Pa·s (more preferably 2.5 to 9.5 Pa·s). In such a case, the spongy material contains an appropriate amount of the covering material, so that a discontinuous film is likely to be formed, the boundaries between the colored regions become clear, and the design can be enhanced. The viscosity is a value (guideline value for the fourth rotation) measured using a BH type viscometer (rotation speed: 20 rpm) under standard conditions (temperature: 23° C., relative humidity: 50%).

In addition, in (I) and (II) above, the timing of applying the second coating material is particularly limited as long as it is after the first coating material (previously applied coating material) becomes non-flowing. not. In the present invention, the "non-fluid state" refers to a state in which the fluidity of the film is lost after the first coating material is applied, specifically, after the second coating material is applied. It refers to the state in which the coating material is dried and hardened to the extent that it does not bleed or the coating materials do not mix with each other. The "non-fluid state" includes states such as dry to the touch, semi-cured and dried, and cured and dried as defined in JIS K5400. In the present invention, it is preferable to apply the second coating material after the first coating material is dried to the touch (more preferably after semi-curing and drying, more preferably after curing and drying). In the present invention, drying and curing are preferably carried out at room temperature (5 to 40°C).

Unlike the present invention, if the second coating material is applied while the first coating material is in a fluid state, the first coating material and the second coating material will gradually mix in the applicator during the coating process, resulting in formation of There is a possibility that the finish of the coated film may become unstable. Furthermore, the coating materials are mixed on the surface to be coated, and the contrast tends to be reduced. On the other hand, in the present invention, by discontinuously applying the second coating material after the first coating material becomes non-flowing, the coating materials are less likely to mix and a stable finish can be imparted. A highly aesthetically pleasing decorative coating having contrast can be obtained. In particular, a remarkable effect can be obtained when the surface to be coated has a large area.

Examples of applicator tools for applying the coating material include sprays, rollers, brushes (including brushes and the like), pressing tools (including tapping tools and the like), and the like. Examples of rollers include fibrous rollers and porous (spongy) rollers. Examples of pressing tools include those having sponge, felt, woven fabric, non-woven fabric, and the like.

When the coating material is applied to the entire surface to be coated as in (I) above, it is desirable to use, for example, a spray, a roller, a brush, or the like. As rollers, fibrous rollers are particularly suitable.

In the step of applying the coating material discontinuously as in the above (I) and (II), for example, the coating material is partially applied to the surface to be coated using a roller, a brush, a pressing tool, etc. It should be applied so that it does. In order to apply the coating material discontinuously, the applicator may be brought into intermittent (partial) contact with the surface to be coated. , a method of applying while rubbing, or the like can be employed. For discontinuous application of the coating material, applicator devices having a sponge material are particularly preferred, and rollers or presses having a sponge material are more preferred. In addition, when a roller having a sponge material is used, it is preferable to apply the composition by rolling it discontinuously, that is, to intermittently (partially) contact and roll the surface to be coated. At this time, the rollers are preferably brought into contact and rolled in random directions. By using such an applicator, it is possible to make the boundaries between the colored regions non-linear (intricate) while imparting contrast, thereby further enhancing aesthetics.

As the sponge material, for example, a resin such as an acrylic resin, a urethane resin, an ester resin, or an ethylene resin, which is porous like a sponge, can be used. The hardness of the sponge material is preferably 10-3000N, more preferably 20-2000N, still more preferably 30-1500N. The density of the sponge material is preferably 1-300 kg/m ³ , more preferably 3-200 kg/m ³ , more preferably 5-150 kg/m ³ . The "hardness" referred to here is a value of hardness (C method) measured from the force when a test piece is compressed to a thickness of 40% according to JIS K6400-2. In addition, "density" is a value of apparent density calculated from the weight and dimensions of a test piece according to JIS K7222.

The shape of the sponge material may be, for example, a polygonal shape such as a triangle, quadrangle, rhombus, pentagon, or hexagon; etc., or a combination of these shapes can be used. The size may be appropriately set depending on the desired pattern.

As the sponge material, one type of sponge material that satisfies the above conditions can be used. 2a to 2e) are randomly mixed, and at least two types of sponge materials (Fig. 3: 3a to 3e) having different hardness and / or density as shown in Fig. 3 are used on the outer peripheral surface of the cylinder (Fig. 3: It is preferred to apply by a roller mixed in 3f). In such an applicator, at least one (preferably two or more) sponge materials should satisfy the above conditions. By using such a specific applicator, it is possible to further improve the finish, beauty and the like.

In FIGS. 2 and 3, it is more preferable that the sponge material is fixed so as to be stacked. Furthermore, it is more preferable to have a form in which a large number of spongy materials are randomly mixed and compression-molded.

The sponge material shown in FIGS. 2 and 3 has an irregular three-dimensional shape, and the size of each piece is preferably 1 to 30 mm (more preferably 2 to 20 mm). In the present invention, it is preferable that a large number of sponge materials with different sizes are mixed. In such a case, since an irregular uneven shape is likely to be formed between the sponge materials, the effects of the present invention can be further enhanced. The "size" referred to here is the longest axis of the outer shape, and is measured by sieving with a sieve having squares of a predetermined size on one side, for example. The thickness of the sponge material (Fig. 2: thickness in 2f direction; Fig. 3: thickness in 3g direction) depends on the size of each sponge material, but is preferably 2 to 50 mm (more preferably 3 to 50 mm). 30 mm).

FIG. 4 shows another example (front view) of a decorative coated surface formed by the decorative coated surface forming method of the present invention. In FIG. 4, three types of coating materials, a first coating material, a second coating material, and a third coating material, are applied in order as coating materials, and a colored area A by the first coating material and a colored area A by the second coating material A decorative coated surface having a colored region B and a colored region C (FIG. 4: 1a to 1c) by the third coating material is formed. As a method for forming the decorative coating surface shown in FIG. 4, the same method as in the case of FIG. 1 may be used.
Applying the first coating material entirely or discontinuously to the surface to be coated (first step),
After the first coating material becomes non-flowing, discontinuously apply the second coating material (second step),
A method of discontinuously applying the third coating material after the second coating material becomes non-flowing (third step);
etc. can be formed.

When three types of coating materials are used, the color difference (ΔE) and gloss difference between at least two types of coating materials adjacent to each other on the decorative coated surface to be formed should satisfy the above conditions. As such an aspect, for example,
(X) a first covering material and a second covering material;
(Y) a first covering material and a third covering material;
(Z) a second coating material and a third coating material;
Among the combinations of , there are an aspect in which at least one combination satisfies the above conditions, an aspect in which two combinations satisfy the above conditions, and an aspect in which three combinations respectively satisfy the above conditions.

The coating amount of the third coating material is preferably 100 g/m ² or less (more preferably 2 to 80 g/m ² , still more preferably 5 to 60 g/m ² ). Furthermore, it is preferable that the amount of the third coating material applied is less than the amounts of the first and second coating materials applied. In addition, the coating amount of the third coating material applied discontinuously is preferably 100 g/m ² or less, more preferably 1 to 60 g/m ² , further preferably 2 to 30 g/m 2 in terms of solid content. ² , which is less than the coating amount of the first coating material and the second coating material. Also, when four or more different coating materials are used, the coating materials (first coating material, second coating material, third coating material, fourth coating material, etc.) are applied in the same manner as described above. 1 process, 2nd process, 3rd process, 4th process, etc.) to form a decorative coated surface having colored area A, colored area B, colored area C, colored area D, etc. good.

In the method of forming the decorative film surface of the present invention, a clear coating material is applied to the outermost surface for the purpose of surface protection, improvement of weather resistance, stain resistance, etc., as long as the effects of the present invention are not hindered. can also be provided. However, when a clear layer is provided, the contrast may be destroyed. In order to sufficiently obtain the effects of the present invention, it is preferable to adopt an embodiment in which no clear layer is provided.

<Paint surface>
The surface to be coated in the present invention is preferably a substrate surface of a building, a civil engineering structure, etc., particularly a substrate constituting a surface of an inner/outer wall, a ceiling, a fitting, or the like. Examples of such substrates include gypsum board, concrete, mortar, porcelain tile, brick, cement board, fiber-mixed cement board, cement calcium silicate board, perlite board, ALC board, siding board, extruded board, plywood, A wood plate, a steel plate, a plastic plate, a glass plate, and the like can be mentioned. The surface of these substrates may have been subjected to some surface treatment (for example, sealer, surfacer, filler, etc.), or may have a coating film already formed, or may have wallpaper attached. .

<Covering material>
As the coating material in the present invention, one containing a resin and a pigment can be used. In the present invention, the color, gloss, etc. can be set by adjusting the type of pigment, the mixing ratio, and the like. The mixing ratio of the resin and the pigment is preferably 5 to 500 parts by weight (more preferably 20 to 400 parts by weight, still more preferably 30 to 300 parts by weight) of the pigment per 100 parts by weight of the solid content of the resin.

Examples of resins include water-soluble resins, water-dispersible resins, solvent-soluble resins, solvent-free resins, non-aqueous-dispersible resins, and composites thereof. These may have cross-linking reactivity, and the form thereof is not particularly limited, and may be either a one-pack type or a two-pack type. A water-dispersible resin and/or a water-soluble resin are particularly preferably used in the present invention. Examples of resins that can be used include cellulose, polyvinyl alcohol, ethylene resin, vinyl acetate resin, polyester resin, alkyd resin, vinyl chloride resin, epoxy resin, silicone resin, acrylic resin, urethane resin, acrylic silicon resin, fluorine A resin or the like, or a composite system thereof, or the like can be mentioned. In the present invention, a hydraulic binder such as cement can be used as long as it does not impair the effects of the present invention, but it is desirable not to use it because it may limit the color of the film.

As the pigment, known coloring pigments, extender pigments and the like can be used. Among these, as coloring pigments, for example, titanium oxide, zinc oxide, carbon black, lamp black, bone black, graphite, black iron oxide, copper chromium black, cobalt black, copper manganese iron black, red iron oxide, molybdate orange, permanent red, permanent carmine, anthraquinone red, perylene red, quinacridone red, iron oxide yellow, titanium yellow, fast yellow, benzimidazolone yellow, chrome green, cobalt green, phthalocyanine green, ultramarine, navy blue, cobalt blue, phthalocyanine blue, quinacridone violet , dioxazine violet, aluminum pigments, pearl pigments, luster pigments, and the like. By using one or two or more of these coloring pigments, it is possible to color in an arbitrary hue. In the present invention, by including aluminum pigments, pearl pigments, luster pigments, etc. as coloring pigments, it imparts design properties such as metallic tone, rust tone, etc., and provides a decorative coating surface with high contrast and aesthetic appearance. can be formed.

Extender pigments include, for example, heavy calcium carbonate, cold water stone, slight calcium carbonate, white carbon, talc, kaolin, clay, china clay, china clay, diatomaceous earth, barite powder, barium sulfate, precipitated barium sulfate, silica sand, and silica stone. Powder, quartz powder, resin beads, glass beads, hollow balloons and the like can be mentioned, and one or more of these can be used. By appropriately setting the type of the extender pigment, the mixing ratio, etc., the coating material can be adjusted to have a desired glossiness.

In addition to the above components, the coating material of the present invention contains known additives such as aggregates, dyes, thickeners, wetting agents, antifreeze agents, and film-forming aids within a range that does not significantly impair the effects of the present invention. agents, preservatives, antifungal agents, anti-algae agents, antibacterial agents, dispersants, antifoaming agents, ultraviolet absorbers, light stabilizers, antioxidants, catalysts, dilution solvents and the like. The coating material can be produced by uniformly mixing the components described above by a conventional method.

The heating residue of the coating material is preferably 25% by weight or more, more preferably 30 to 80% by weight. If the heating residue of the coating material is within such a range, the time required for drying and curing can be shortened, and a non-flowing state can be obtained early. It is also suitable in terms of providing contrast and the like. The heating residue is a value measured by the method of JIS K5601-1-2, the heating temperature is 105° C., and the heating time is 60 minutes.

Furthermore, in the present invention, it is sufficient that the heating residue of the coating material satisfies the above range, but it is preferable to set the heating residue of the second coating material higher than that of the first coating material. Further, when three or more kinds of coating materials are used, it is preferable that the heating residue of the third coating material, the fourth coating material, etc. is higher than that of the first coating material. Thereby, the effect of the present invention can be enhanced. Note that the heating residue can also be set according to the dilution ratio of the coating material. For example, the coating material with a high dilution ratio can be used as the first coating material, and the coating material with a low dilution ratio can be used as the second coating material. . The difference in the heating residue between the first coating material and the second coating material is preferably 1-30% by weight, more preferably 2-25% by weight, and more preferably 3-20% by weight.

The hiding rate of the covering material is preferably 70% or higher, more preferably 80% or higher, and still more preferably 90% or higher. If the hiding rate of the covering material is within such a range, the formed film of the covering material can be made opaque, which is preferable in terms of imparting contrast and the like. The hiding rate was measured by applying the coating material to the hiding rate test paper with a film applicator (gap 150 μm) and drying it for 24 hours under standard conditions. It is a value calculated by the formula.
<Formula>
Hiding rate (%) = (luminous reflectance of coating film on black background) / (luminous reflectance of coating film on white background) x 100

Examples are shown below to further clarify the features of the present invention.

The following materials were prepared as coating materials.

・Covering material 1-1
Acrylic resin emulsion, pigment (titanium oxide, carbon black, yellow iron oxide, extender pigment) gray coating material (L ^* value: 60.0, a ^* value: -0.1, b ^* value: 0.3, glossiness: 12, heating residue: 54% by weight, viscosity: 3.5 Pa s, hiding rate: 97%, pigment ratio: 126 parts by weight per 100 parts by weight of resin solid content)

・Covering material 1-2
Acrylic resin emulsion, black coating material (L ^* value: 26.1, a ^* value: 0.1, b ^* value: 0.2, mainly composed of pigments (carbon black, yellow iron oxide, extender)) Glossiness: 1.5, Heating residue: 57% by weight, Viscosity: 5 Pa s, Concealing rate: 97%, Pigment ratio: 240 parts by weight per 100 parts by weight of resin solid content, Color difference from coating material 1-1 △E: 34)

・Covering material 2-1
Gray coating material (L ^* value: 54.3, a ^* value: -0.6, b ^* value: -1.2, glossiness: 30, heating residue: 42% by weight, viscosity: 2.1 Pa s, hiding rate: 98%, pigment ratio: 38 parts by weight per 100 parts by weight of resin solid content)

・Covering material 2-2
Dark brown coating material (L ^* value: 33.9, a ^* value: 4.0, b ^* Value: 7.5 Gloss: 9 Heating residue: 59% by weight Viscosity: 4.8 Pa s Hiding rate: 98% Pigment ratio: 142 parts by weight per 100 parts by weight of resin solid content Coating material Color difference ΔE from 2-1: 23)

・Covering material 3-1
Acrylic resin emulsion, gray coating material (L ^* value: 53.6, a ^* value: 0.8, b ^* Value: 1.6, Gloss: 2, Heating residue: 59% by weight, Viscosity: 6.4 Pa s, Hiding rate: 98%, Pigment ratio: 230 parts by weight per 100 parts by weight of resin solid content)

・Covering material 3-2
Acrylic resin emulsion, gray coating material (L ^* value: 49.1, a ^* value: 0.7, b ^* Value: 0.1, Gloss: 2, Heat residue: 59% by weight, Viscosity: 6.4 Pa s, Concealing rate: 98%, Pigment ratio: 230 parts by weight per 100 parts by weight of resin solid content, coating Color difference ΔE from material 3-1: 4.8)

・Covering material 3-3
Acrylic resin emulsion, metallic coating material (metallic) tone coating material (L ^* value: 82.6, a ^* value: 0.3, b ^* value: 1 .6 Gloss: 12 Heating residue: 24% by weight Viscosity: 5.0 Pa s Concealing rate: 94% Pigment ratio: 36 parts by weight per 100 parts by weight of resin solid content Coating material 3-1 Color difference ΔE: 29, Color difference ΔE with coating material 3-2: 34)

(Example 1)
As the first step, coating material 1-1 is applied to the entire substrate (slate plate) with a roller at a coating amount of 120 g/m ² (coating amount of 64.8 g/m ² ) (using a fibrous roller). , and dried for 2 hours so as to be at least dry to the touch. Next, in the second step, the coating material 1-2 is discontinuously applied with a coating amount of 40 g/m ² (a coating amount of 22.8 g/m ² ) [sponge material (hardness 110 to 140 N, density 15 to 50 kg/m ³ )] and dried for 24 hours. All coating and drying were performed under standard conditions. By the above method, a highly aesthetically pleasing decorative coated surface with a mixture of gray areas and black areas and clear contrast was obtained. In addition, the coating amount is a value in terms of solid content (the same shall apply hereinafter).

(Example 2)
As the first step, coating material 2-1 is applied to the entire substrate (slate plate) with a roller at a coating amount of 120 g/m ² (coating amount of 50.4 g/m ² ) (using a fibrous roller). , and dried for 2 hours so as to be at least dry to the touch. Next, in the second step, the coating material 2-2 is discontinuously applied with a coating amount of 50 g/m ² (a coating amount of 29.5 g/m ² ) [sponge material (hardness 75 to 110 N, density 15 to 30 kg/m ³ )] and dried for 24 hours. All coating and drying were performed under standard conditions. By the above method, a highly aesthetically pleasing decorative coated surface with a mixture of gray areas and dark brown areas and clear contrast was obtained.

(Example 3)
As the first step, coating material 2-1 is applied to the entire substrate (slate plate) with a roller at a coating amount of 120 g/m ² (coating amount of 50.4 g/m ² ) (using a fibrous roller). , and dried for 2 hours so as to be at least dry to the touch. Next, in the second step, the coating material 2-2 was discontinuously roller-coated at a coating amount of 50 g/m (a coating amount of 29.5 g/m ² ) (5 types of sponge materials as shown in FIG. 3 were applied. Sponge material 3a: Hardness 45-60 N, Density 50-100 kg/m ³ Sponge material 3b: Hardness 75-110 N, Density 15-30 kg/m ³ Sponge material 3c: Hardness 110-140 N , density 15 to 50 kg/m ³ , sponge material 3d: hardness 110 to 300 N, density 30 to 85 kg/m ³ , sponge material 3e: hardness 1000 to 1500 N, density 10 to 20 kg/m ³ ), dried for 24 hours. rice field. All coating and drying were performed under standard conditions. By the above method, a highly aesthetically pleasing decorative coated surface with a mixture of gray areas and dark brown areas and clear contrast was obtained.

( Reference example 4)
As a first step, the coating material 3-1 is diluted with water to a base material (slate plate) at a dilution rate of 15% (viscosity after dilution: 2.5 Pa s, heating residue after dilution: 51% by weight). , the coating amount was 120 g/m ² (coating amount: 61.2 g/m ² ), and the entire surface was coated with a roller (using a fibrous roller), and dried for 2 hours so as to be dry to the touch. Next, in the second step, the coating material 3-3 is discontinuously roller-coated with a coating amount of 50 g/m ² (a coating amount of 12 g/m ² ) [having five types of sponge materials as shown in FIG. Using a roller (as in Example 3). ], dried for 24 hours. All coating and drying were performed under standard conditions. By the above-described method, a highly aesthetically pleasing decorative coated surface having a mixture of gray areas and metallic areas and having a clear contrast was obtained.

(Example 5)
As a first step, the coating material 3-1 is diluted with water to a base material (slate plate) at a dilution rate of 15% (viscosity after dilution: 2.5 Pa s, heating residue after dilution: 51% by weight). , the coating amount was 120 g/m ² (coating amount: 61.2 g/m ² ), and the entire surface was coated with a roller (using a fibrous roller), and dried for 2 hours so as to be dry to the touch. Next, in the second step, the coating material 3-2 is discontinuously applied with a roller at a coating amount of 50 g/m ² (a coating amount of 29.5 g/m ² ) [5 kinds of sponge materials as shown in FIG. (similar to Example 3). ] and dried for 2 hours so as to be at least dry to the touch. Furthermore, in the third step, the coating material 3-3 was discontinuously applied with a coating amount of 30 g/m ² (a coating amount of 7.2 g/m ² ) (five kinds of sponge materials as shown in FIG. 2). sponge material 2a: hardness 45-60 N, density 50-100 kg/m ³ sponge material 2b: hardness 75-110 N, density 15-30 kg/m ³ sponge material 2c: hardness 110 140 N, density 15-50 kg/m ³ , sponge material 2d: hardness 110-300 N, density 30-85 kg/m ³ , sponge material 2e: hardness 1000-1500 N, density 10-20 kg/m ³ ), 24 hours dried. All coating and drying were performed under standard conditions. By the above method, a highly aesthetically pleasing decorative coated surface having a mixture of gray areas, dark gray areas, and metallic areas and having clear contrast was obtained.

In each of Examples 1 to 3 and Reference Example 4 , two types of colored regions, the coating formed in the first step and the coating formed discontinuously in the second step, are mixed, and the aesthetic appearance with clear contrast is obtained. A decorative coating surface of high quality was obtained. Further, in Example 5, three types of colored regions, the coating formed in the first step and the coating discontinuously formed in the second and third steps, were mixed, and the aesthetic appearance with clear contrast was obtained. A high decorative coating surface was obtained. In particular, in Example 3, Reference Example 4, and Example 5, the boundary between the colored regions can be made more complicated and non-linear (intricate pattern), and the decorative coating surface with higher finish and aesthetic appearance can be obtained. Got.

Claims (3)

A method for forming a decorative coated surface in which at least two or more colored regions are mixed,
Using at least two types of coating materials having a color difference (ΔE) of 20 or more and different glossiness,
All of the above coating materials have a heating residue of 25% by weight or more,
on the surface to be coated,
A first step of applying the first coating material, a second step of applying the second coating material,
The heating residue of the second coating material is higher than that of the first coating material,
A method for forming a decorative coated surface, characterized in that after the first coating material becomes non-flowing, the second coating material is applied discontinuously so as to partially adhere . 2. The method of forming a decorative coated surface according to claim 1, wherein the first coating material is applied to the entire surface of the coated surface. 2. The method of forming a decorative coated surface according to claim 1, wherein the first coating material is applied discontinuously so as to partially adhere to the surface to be coated.

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