JP7288646B2 - deodorant composition - Google Patents
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Description
本発明は、アルデヒド類、アンモニア、硫化水素等の悪臭に対する消臭組成物に関するものであり、特にアルデヒド類に対して高い消臭効果を示す消臭組成物に関する。さらに本発明は、前記消臭組成物を加工した不織布、壁紙、床材、天井材、繊維または繊維製品、建築用内装材、および壁紙の加工方法に関する。 TECHNICAL FIELD The present invention relates to a deodorant composition against offensive odors such as aldehydes, ammonia and hydrogen sulfide, and more particularly to a deodorant composition exhibiting a high deodorant effect against aldehydes. Furthermore, the present invention relates to a non-woven fabric, wallpaper, flooring material, ceiling material, fiber or textile product, interior material for construction, and a method for processing wallpaper, which are processed with the deodorant composition.
住宅環境において、建築用内装材から微量に発生するホルムアルデヒドやＶＯＣ等によってシックハウス症候群のような健康被害が起こることが知られている。また建築用内装材だけでなく、タバコ臭などが原因となってアセトアルデヒド、アンモニア、硫化水素、酢酸などの臭気が発生することがあり、室内環境の汚染や不快感を与え、ときには健康被害が発生することも考えられる。このように室内環境や車内環境からの、アルデヒド類を含むこれらの臭気を除去するために活性炭のような吸着剤や消臭剤が提案されており、また消臭剤を加工した壁紙、床材などの建築用内装材も提案されている。 In a residential environment, it is known that formaldehyde, VOCs, and the like generated in small amounts from building interior materials cause health hazards such as sick house syndrome. In addition to building interior materials, odors such as acetaldehyde, ammonia, hydrogen sulfide, and acetic acid may be generated due to tobacco odors, etc., polluting the indoor environment and causing discomfort, and sometimes causing health damage. It is also conceivable to Adsorbents such as activated charcoal and deodorants have been proposed to remove these odors containing aldehydes from indoor and vehicle environments, and wallpaper and flooring materials processed with deodorants have been proposed. Interior materials for construction such as are also proposed.
このうち活性炭のような吸着剤を用いて吸着除去する方法においては、臭気を吸着して飽和となった場合に消臭性能が低下してしまう問題がある。またアルデヒド類に関する消臭剤が提案されているが（特許文献１～３）、高い消臭性能を発揮する消臭剤がなく、より高い消臭性能を持つ消臭剤が要望されている。 Of these methods, the method of adsorbing and removing using an adsorbent such as activated carbon has a problem that the deodorant performance is lowered when the adsorbent becomes saturated with the odor. Although deodorants related to aldehydes have been proposed (Patent Documents 1 to 3), there are no deodorants that exhibit high deodorant performance, and deodorants with higher deodorant performance are desired.
また消臭剤を壁紙、床材、天井材等の建築用内装材に加工することによって消臭性能を有する建築用内装材を製造する場合、１５０℃を超える高温で加熱する工程があり、この工程によって消臭剤が分解や揮発する危険性があるものは使用が困難という問題があった。 In the case of manufacturing an interior building material having deodorant performance by processing a deodorant into a building interior material such as wallpaper, flooring, and ceiling material, there is a step of heating at a high temperature exceeding 150°C. There is a problem that it is difficult to use a deodorant that may decompose or volatilize depending on the process.
アルデヒド類、アンモニア、硫化水素等の悪臭に対する消臭組成物を提供すること、特に壁紙、床材、天井材等の建築内装用資材に加工するための消臭組成物であって、特にアルデヒド類に対して高い消臭性能を発揮する消臭組成物を提供することが本発明の課題である。 To provide a deodorant composition against bad odors such as aldehydes, ammonia and hydrogen sulfide, especially deodorant compositions for processing into building interior materials such as wallpaper, flooring and ceiling materials, especially aldehydes It is an object of the present invention to provide a deodorizing composition that exhibits high deodorizing performance against.
本発明者らはこのような課題を解決するため鋭意研究を行った結果、珪藻土、珪酸カルシウム、塩基性酸化ケイ素、活性白土から選択される少なくとも一種の化合物、およびアミノ変性シリコーンを含有する組成物が、高い消臭性能を発揮し、さらに壁紙、床材、天井材等の建築内装用部材に加工したときにも、特にアルデヒド類に対して高い消臭性能を発揮することを見出し、本発明を完成させた。 The present inventors have conducted intensive studies to solve such problems, and as a result, a composition containing at least one compound selected from diatomaceous earth, calcium silicate, basic silicon oxide, and activated clay, and an amino-modified silicone However, it has been found that it exhibits high deodorant performance, and that it exhibits high deodorant performance, especially against aldehydes, even when processed into building interior materials such as wallpaper, flooring, and ceiling materials. completed.
すなわち本発明は、
（１）珪藻土、珪酸カルシウム、塩基性酸化ケイ素、活性白土から選択される少なくとも一種の化合物、およびアミノ変性シリコーンを含有することを特徴とする消臭組成物であり、
（２）アミノ変性シリコーンの含有率が、１～７０重量％の範囲であることを特徴とする、（１）に記載の消臭組成物、
（３）（１）または（２）に記載の消臭組成物を加工した不織布、壁紙、床材、天井材、繊維または繊維製品、建築用内装材であり、
（４）（３）に記載の壁紙の加工方法であって、請求項１または請求項２に記載の消臭組成物を表面処理剤と混合し、壁紙に塗布した後、１５０℃以上で加熱する工程を有する壁紙の加工方法である。
That is, the present invention
(1) A deodorant composition comprising at least one compound selected from diatomaceous earth, calcium silicate, basic silicon oxide, and activated clay, and an amino-modified silicone,
(2) The deodorant composition according to (1), wherein the amino-modified silicone content is in the range of 1 to 70% by weight;
(3) Non-woven fabrics, wallpapers, flooring materials, ceiling materials, fibers or textile products, and building interior materials obtained by processing the deodorant composition according to (1) or (2),
(4) The wallpaper processing method according to (3), wherein the deodorant composition according to claim 1 or 2 is mixed with a surface treatment agent, applied to the wallpaper, and then heated at 150° C. or higher. A wallpaper processing method including a step of
本発明により、高い消臭性能を有する消臭組成物を提供することが可能となり、さらに本発明の消臭組成物を壁紙、床材、天井材等の建築用内装材に加工することにより、特にアルデヒド類に対して高い消臭性能を有する建築用内装資材を提供することが可能となる。 According to the present invention, it is possible to provide a deodorizing composition having high deodorizing performance. Further, by processing the deodorizing composition of the present invention into architectural interior materials such as wallpaper, flooring, and ceiling materials, In particular, it is possible to provide a building interior material having high deodorant performance against aldehydes.
以下、本発明につき更に詳しく説明する。
本発明の消臭組成物は、珪藻土、珪酸カルシウム、塩基性酸化ケイ素および活性白土から選択される少なくとも一種の化合物、およびアミノ変性シリコーンを含有してなる組成物である。
The present invention will be described in more detail below.
The deodorant composition of the present invention is a composition containing at least one compound selected from diatomaceous earth, calcium silicate, basic silicon oxide and activated clay, and amino-modified silicone.
本発明の消臭組成物に使用されるアミノ変性シリコーンは、シリコーンを変性することによってアミノ基を導入した化合物である。シリコーンはシロキサン結合によって結合し、重合した化合物の事を指し、一般的には直鎖のポリジメチルシロキサンと呼ばれる。アミノ基は、主鎖であるシリコーン分子鎖の側鎖に結合していても、主鎖であるシリコーン分子鎖の両末端に結合していても良い。 The amino-modified silicone used in the deodorant composition of the present invention is a compound into which an amino group is introduced by modifying silicone. Silicone refers to a polymerized compound linked by siloxane bonds, and is generally called linear polydimethylsiloxane. The amino group may be bonded to a side chain of the silicone molecular chain, which is the main chain, or may be bonded to both ends of the silicone molecular chain, which is the main chain.
アミノ変性シリコーンの分子量に特に制限はないが、１００～３００００が好ましく、さらに２００～５０００が好ましい。アミノ変性シリコーンの分子量が１００未満であると、耐熱性に乏しくなり高温で加工したときにアミノ変性シリコーンが揮発する恐れがあり、アミノ変性シリコーンの分子量が３００００を超えるとアミノ変性シリコーンの粘性が増大し、製剤や加工の作業が行いにくくなる。アミノ変性シリコーン中に含まれるアミノ基の量は、官能基当量（ｇ／ｍｏｌ）として、１００～５０００ｇ／ｍｏｌであるが、１００～１０００ｇ／ｍｏｌが好ましく、１００～５００ｇ／ｍｏｌがより好ましく、１００～４００ｇ／ｍｏｌがより好ましい。アミノ変性シリコーン中に含まれるアミノ基の官能基当量が５０００ｇ／ｍｏｌを超えると消臭効果が十分に発揮されなくなり、１００ｇ／ｍｏｌ未満であるとアミノ変性シリコーンの安定性が十分ではなくなる恐れがある。 Although the molecular weight of the amino-modified silicone is not particularly limited, it is preferably from 100 to 30,000, more preferably from 200 to 5,000. If the molecular weight of the amino-modified silicone is less than 100, the heat resistance is poor and the amino-modified silicone may volatilize when processed at high temperature. This makes it difficult to carry out formulation and processing operations. The amount of amino groups contained in the amino-modified silicone is 100 to 5000 g/mol as a functional group equivalent (g/mol), preferably 100 to 1000 g/mol, more preferably 100 to 500 g/mol. ~400 g/mol is more preferred. If the functional group equivalent of the amino group contained in the amino-modified silicone exceeds 5000 g/mol, the deodorant effect will not be sufficiently exhibited, and if it is less than 100 g/mol, the stability of the amino-modified silicone may not be sufficient. .
また本発明の消臭組成物は、珪藻土、珪酸カルシウム、塩基性酸化ケイ素、活性白土から選択される少なくとも一種の化合物を含有する。珪藻土は、珪藻と呼ばれる単細胞藻類が海底や湖底に堆積して化石となったものであり、主成分は珪酸塩であって多孔質な鉱物である。珪藻土は工業品が流通しており、例えば昭和化学工業のラジオライト等を挙げることができる。 The deodorant composition of the present invention also contains at least one compound selected from diatomaceous earth, calcium silicate, basic silicon oxide and activated clay. Diatomaceous earth is a fossil of single-celled algae called diatoms deposited on the bottom of the sea or lake, and its main component is silicate, which is a porous mineral. An industrial product of diatomaceous earth is distributed, for example, Radiolite manufactured by Showa Kagaku Kogyo.
珪酸カルシウムは珪酸塩類の一種であり、酸化カルシウムと二酸化ケイ素が種々の割合で結合した化合物の総称であり、珪藻土から得ることも可能である。塩基性酸化ケイ素は、粒子の表面がアルカリ性である酸化ケイ素であり、水に添加した５％分散液のｐＨを測定したときに７より大きい値を示す。活性白土は、モンモリロナイトと呼ばれる鉱物を熱酸処理して得られる鉱物であり、多孔質な構造を有する。珪酸カルシウム、塩基性酸化ケイ素、活性白土に関しても、種々の工業品が流通しており、いずれも使用することが可能である。 Calcium silicate is a kind of silicates, is a general term for compounds in which calcium oxide and silicon dioxide are combined in various proportions, and can be obtained from diatomaceous earth. Basic silicon oxide is silicon oxide in which the surface of the particles is alkaline and exhibits a value of greater than 7 when the pH of a 5% dispersion added to water is measured. Activated clay is a mineral obtained by thermal acid treatment of a mineral called montmorillonite, and has a porous structure. As for calcium silicate, basic silicon oxide, and activated clay, various industrial products are on the market, and any of them can be used.
本発明で使用する化合物の粒子径は、平均粒子径として１００μｍ以下のものが好ましく、さらに５０μｍ以下のものがより好ましい。平均粒子径が１００μｍを超えると、壁紙等に加工するときに表面の平滑性が失われる恐れがある。 The particle size of the compound used in the present invention is preferably 100 μm or less, more preferably 50 μm or less, as an average particle size. If the average particle size exceeds 100 μm, the smoothness of the surface may be lost when processed into wallpaper or the like.
本発明の消臭組成物におけるアミノ変性シリコーンの含有率は、１～７０重量％であり、１０～６０重量％が好ましく、さらに２０～５０重量％がより好ましい。１重量％未満であると消臭効果が十分に発揮されず、また７０重量％を超えるとアミノ変性シリコーンに珪藻土、珪酸カルシウム、塩基性酸化ケイ素または活性白土を含有させることが困難となる。 The content of amino-modified silicone in the deodorant composition of the present invention is 1 to 70% by weight, preferably 10 to 60% by weight, more preferably 20 to 50% by weight. If it is less than 1% by weight, the deodorizing effect is not sufficiently exhibited, and if it exceeds 70% by weight, it becomes difficult to incorporate diatomaceous earth, calcium silicate, basic silicon oxide or activated clay into the amino-modified silicone.
本発明の消臭組成物は、表面処理剤、コーティング剤、塗料等と混合し、塩ビ等の樹脂を用いた壁紙、天井材、合板等の木質材料、床材等の建築用内装材に塗布するなどして用いることができる。特に壁紙に加工を行う場合、消臭組成物と壁紙用の表面処理剤を混合したものを壁紙の最表面層に塗布した後、通常では１５０℃以上、場合によっては２００℃を超える高温で加熱されることが多いが、本発明の消臭組成物はこのような高温で加熱される場合でも消臭性能が低下することがない。このような理由から本発明の消臭組成物は、壁紙用途に好適に用いることができる。 The deodorant composition of the present invention is mixed with a surface treatment agent, a coating agent, a paint, etc., and applied to wallpaper using a resin such as vinyl chloride, ceiling materials, wooden materials such as plywood, and architectural interior materials such as flooring. It can be used by, for example, Especially when wallpaper is processed, after applying a mixture of a deodorant composition and a surface treatment agent for wallpaper to the outermost surface layer of the wallpaper, usually 150 ° C. or higher, in some cases heated at a high temperature exceeding 200 ° C. However, the deodorant composition of the present invention does not lose its deodorant performance even when heated at such high temperatures. For these reasons, the deodorant composition of the present invention can be suitably used for wallpaper.
表面処理剤は、壁紙の最表面に加工するための樹脂エマルジョンであり、水性の樹脂エマルジョンが使用されることが多い。水性の表面処理剤は、一般に工業用製品として市販されているものを使用することができる。このような表面処理剤は特に制限されるものではないが、澱粉、酵素変性澱粉等の各種変性澱粉、ポリビニルアルコール、ポリアクリルアミド、カルボキシメチルセルロース等の水溶性高分子が挙げられ、またアクリル系樹脂エマルジョン、酢酸ビニル系樹脂エマルジョン、アクリル－スチレン系樹脂エマルジョン、アクリル－酢酸ビニル系樹脂エマルジョン、塩化ビニル系樹脂エマルジョン、塩化ビニル－アクリル系樹脂エマルジョン、ウレタン系樹脂エマルジョン等の水性の樹脂エマルジョンが挙げられる。 A surface treatment agent is a resin emulsion for processing the outermost surface of wallpaper, and a water-based resin emulsion is often used. As the water-based surface treatment agent, commercially available products generally available for industrial use can be used. Such surface treatment agents are not particularly limited, but include starch, various modified starches such as enzyme-modified starch, water-soluble polymers such as polyvinyl alcohol, polyacrylamide, and carboxymethylcellulose, and acrylic resin emulsions. , vinyl acetate resin emulsion, acrylic-styrene resin emulsion, acrylic-vinyl acetate resin emulsion, vinyl chloride resin emulsion, vinyl chloride-acrylic resin emulsion, urethane resin emulsion and the like.
本発明の消臭組成物には、必要に応じて、界面活性剤、防ダニ剤、抗菌剤、キレート剤、防錆剤、香料、スケール防止剤、消泡剤、帯電防止剤、樹脂バインダー、増粘剤、柔軟加工剤等を加えることも可能である。 The deodorizing composition of the present invention may optionally contain a surfactant, an anti-mite agent, an antibacterial agent, a chelating agent, an antirust agent, a fragrance, an anti-scaling agent, an antifoaming agent, an antistatic agent, a resin binder, It is also possible to add thickeners, softening agents and the like.
本発明を実施例、試験例により更に詳しく説明するが、本発明がこれらによって限定されるものではない。なお、下記に示す％はすべて重量％である。 The present invention will be described in more detail with reference to Examples and Test Examples, but the present invention is not limited to these. In addition, all % shown below are weight %.
（実施例１）
珪藻土としてラジオライト（登録商標）＃９００（平均粒子径２９μｍ、昭和化学工業株式会社製）５８ｇ、官能基当量３５０ｇ／ｍｏｌの側鎖型アミノ変性シリコーンオイルＫＦ－３９３（信越化学工業株式会社製）を４２ｇ秤量した。ラジオライト＃９００を混合しながらＫＦ－３９３を滴下し、消臭組成物の実施例１を得た。
(Example 1)
As diatomaceous earth, Radiolite (registered trademark) #900 (average particle size 29 μm, manufactured by Showa Chemical Industry Co., Ltd.) 58 g, side chain type amino-modified silicone oil KF-393 (manufactured by Shin-Etsu Chemical Co., Ltd.) having a functional group equivalent of 350 g / mol 42 g of was weighed. KF-393 was added dropwise while Radiolite #900 was mixed to obtain Example 1 of the deodorant composition.
（実施例２）
珪藻土として実施例１のラジオライト＃９００の代わりにラジオライト＃２００（平均粒子径１３μｍ、昭和化学工業株式会社製）を用いて消臭組成物の実施例２を得た。
(Example 2)
Example 2 of a deodorant composition was obtained by using Radiolite #200 (average particle size 13 μm, manufactured by Showa Kagaku Kogyo Co., Ltd.) as diatomaceous earth instead of Radiolite #900 of Example 1.
（実施例３）
実施例１のアミノ変性シリコーンオイルＫＦ－３９３の代わりに官能基当量７９０ｇ／ｍｏｌのアミノ変性シリコーンオイルＫＦ－８５７を用いて消臭組成物の実施例３を得た。
(Example 3)
Example 3 of deodorant composition was obtained by using amino-modified silicone oil KF-857 having a functional group equivalent of 790 g/mol instead of amino-modified silicone oil KF-393 of Example 1.
（実施例４）
実施例１のアミノ変性シリコーンオイルＫＦ－３９３の代わりに官能基当量４３０ｇ／ｍｏｌのアミノ変性シリコーンオイルＫＦ－８０１０を用いて消臭組成物の実施例４を得た。
(Example 4)
Example 4 of deodorant composition was obtained by using amino-modified silicone oil KF-8010 having a functional group equivalent of 430 g/mol instead of amino-modified silicone oil KF-393 of Example 1.
（実施例５）
実施例１の珪藻土ラジオライト＃９００の代わりに、活性白土としてモンモリロナイトＫ１０（平均粒子径２５μｍ、ＡＬＤＲＩＣＨ社製）を用いて消臭組成物の実施例５を得た。
(Example 5)
A deodorant composition of Example 5 was obtained using montmorillonite K10 (average particle size: 25 μm, manufactured by ALDRICH) as activated clay instead of diatomaceous earth Radiolite #900 of Example 1.
（実施例６）
実施例１の珪藻土ラジオライト＃９００の代わりに、塩基性酸化ケイ素としてカープレックス（登録商標）＃１１２０（５％分散液のｐＨ１１、平均粒子径１２μｍ、エボニック社製）を用いて消臭組成物の実施例６を得た。
(Example 6)
A deodorant composition using Carplex (registered trademark) #1120 (5% dispersion pH 11, average particle size 12 μm, manufactured by Evonik) as basic silicon oxide instead of diatomaceous earth Radiolite #900 in Example 1. Example 6 of was obtained.
（実施例７）
珪藻土としてラジオライト＃９００を９０ｇと側鎖型アミノ変性シリコーンオイルＫＦ－３９３（信越化学工業株式会社製）１０ｇを秤量し、実施例１と同様の操作手順で消臭組成物の実施例７を得た。
(Example 7)
As diatomaceous earth, 90 g of Radiolite #900 and 10 g of side chain amino-modified silicone oil KF-393 (manufactured by Shin-Etsu Chemical Co., Ltd.) were weighed, and the deodorizing composition of Example 7 was prepared in the same manner as in Example 1. Obtained.
（比較例１）
側鎖型アミノ変性シリコーンオイルＫＦ－３９３を比較例１とした。
(Comparative example 1)
Side chain type amino-modified silicone oil KF-393 was used as Comparative Example 1.
（比較例２）
側鎖型アミノ変性シリコーンオイルＫＦ－８５７を比較例２とした。
(Comparative example 2)
Side chain type amino-modified silicone oil KF-857 was used as Comparative Example 2.
（比較例３）
両末端型アミノ変性シリコーンオイルＫＦ－８０１０を比較例３とした。
(Comparative Example 3)
A double-ended amino-modified silicone oil KF-8010 was used as Comparative Example 3.
（比較例４）
官能基当量３８ｇ／ｍｏｌの両末端型フェノール変性シリコーンオイルＫＦ－２２０１を比較例４とした。
(Comparative Example 4)
Comparative Example 4 was a double-ended phenol-modified silicone oil KF-2201 having a functional group equivalent of 38 g/mol.
（比較例５）
シリカ粉末（カープレックス８０、５％分散液のｐＨ５．９、平均粒子径１５μｍ、エボニック株式会社製）５８ｇと側鎖型アミノ変性シリコーンオイルＫＦ－３９３（信越化学工業株式会社製）を４２ｇを秤量し、実施例１と同様の操作手順で消臭組成物の比較例５を得た。
(Comparative Example 5)
58 g of silica powder (Carplex 80, 5% dispersion pH 5.9, average particle size 15 μm, manufactured by Evonik) and 42 g of side chain type amino-modified silicone oil KF-393 (manufactured by Shin-Etsu Chemical Co., Ltd.) were weighed. A deodorant composition of Comparative Example 5 was obtained in the same manner as in Example 1.
（比較例６）
シリカ粉末（カープレックス８０、エボニック株式会社製）５８ｇと側鎖型フェノール変性シリコーンオイルＫＦ－２２０１（信越化学工業株式会社製）４２ｇを秤量し、実施例１と同様の操作手順で消臭組成物の比較例６を得た。
(Comparative Example 6)
Silica powder (Carplex 80, manufactured by Evonik Co., Ltd.) 58 g and side chain type phenol-modified silicone oil KF-2201 (manufactured by Shin-Etsu Chemical Co., Ltd.) 42 g were weighed, and a deodorant composition was prepared in the same manner as in Example 1. Comparative Example 6 was obtained.
（比較例７）
珪藻土ラジオライト＃９００を比較例７とした。
(Comparative Example 7)
Diatomaceous Earth Radiolite #900 was used as Comparative Example 7.
（比較例８）
珪藻土ラジオライト＃２００を比較例８とした。
(Comparative Example 8)
Diatomaceous Earth Radiolite #200 was used as Comparative Example 8.
［塩ビ壁紙の調製］
塩ビ壁紙表面層液として、平均重合度７００の塩ビ粉末（ＰＱＢ８３、新第一塩ビ株式会社製）１００ｇ、可塑剤ジイソノニルフタレート（ＤＩＮＰ、田岡化学工業株式会社製）５０ｇ、安定剤としてアデカスタブ（登録商標）ＦＬ２３（株式会社ＡＤＥＫＡ製）３ｇ、イソパラフィン（ＩＰソルベント２０２８、出光興産株式会社製）７ｇを、混合した。基材層としてＡ４サイズのＰＰＣ用紙（Ｔｙｐｅ Ｆｗ）に、調製した表面層液を約２００ｇ／ｍ２となるように塗布し、１５０℃の乾燥機に入れて１分間加熱し、塩ビ壁紙を得た。
[Preparation of vinyl chloride wallpaper]
As the vinyl chloride wallpaper surface layer liquid, 100 g of vinyl chloride powder with an average degree of polymerization of 700 (PQB83, manufactured by Shin-Daiichi Vinyl Co., Ltd.), 50 g of plasticizer diisononyl phthalate (DINP, manufactured by Taoka Chemical Co., Ltd.), Adekastab (registered trademark) as a stabilizer ) 3 g of FL23 (manufactured by ADEKA Corporation) and 7 g of isoparaffin (IP Solvent 2028, manufactured by Idemitsu Kosan Co., Ltd.) were mixed. The prepared surface layer liquid was applied to A4 size PPC paper (Type Fw) as a base material layer so as to be about 200 g / m2, placed in a dryer at 150 ° C. and heated for 1 minute to obtain a vinyl chloride wallpaper. .
[消臭評価試料の調製]
表面処理剤として、塩化ビニル系樹脂エマルジョン（ビニブランＨＤ－０５７、信越化学工業株式会社製）に対し、実施例１～７、比較例１～８の消臭組成物を所定濃度となるように添加・混合し、コンラージ棒をもちいて上記にて作成した１２ｃｍ×１０ｃｍの塩ビ壁紙に７ｇ／ｍ２で塗布し、２２０℃の乾燥機に入れて２分間加熱して消臭評価用試料とした。
[Preparation of deodorant evaluation sample]
As a surface treatment agent, the deodorizing compositions of Examples 1 to 7 and Comparative Examples 1 to 8 were added to a vinyl chloride resin emulsion (Vinyblan HD-057, manufactured by Shin-Etsu Chemical Co., Ltd.) at a predetermined concentration.・The mixture was mixed and applied to the vinyl chloride wallpaper of 12 cm x 10 cm prepared above at 7 g/m 2 using a Conlarge stick.
[試験例１] アセトアルデヒドに対する消臭試験
アセトアルデヒドを、濃度が容積基準で１６ｐｐｍとなるように空気で希釈し、アセトアルデヒド希釈ガスを用意した。３Ｌ容量のテドラーバッグに消臭評価試料を封入し、アセトアルデヒド希釈ガス１Ｌを注入して栓をし、２５℃にて静置した。２時間経過後と２４時間経過後に、アセトアルデヒド用検知管（ガステック株式会社製）を用いてテドラーバッグ内のアセトアルデヒド濃度を測定した。消臭率を次式によって計算した。
[消臭率]＝（初期濃度－測定濃度）／（初期濃度）×１００
消臭率の結果を表１に示す。
[Test Example 1] Deodorant test against acetaldehyde Acetaldehyde was diluted with air to a concentration of 16 ppm on a volume basis to prepare an acetaldehyde-diluted gas. A deodorant evaluation sample was enclosed in a 3-liter Tedlar bag, 1 liter of acetaldehyde dilution gas was injected, the bag was stoppered, and the bag was allowed to stand at 25°C. After 2 hours and 24 hours, the acetaldehyde concentration in the Tedlar bag was measured using an acetaldehyde detection tube (manufactured by GASTEC CORPORATION). The deodorant rate was calculated by the following formula.
[Deodorant rate] = (initial concentration - measured concentration) / (initial concentration) x 100
Table 1 shows the deodorant rate results.
本発明の、珪藻土、珪酸カルシウム、塩基性酸化ケイ素、活性白土から選択される少なくとも一種と、アミノ変性シリコーンを含有する消臭組成物を使用することによって、硫化水素、アンモニア等の悪臭物質、特にアルデヒド類の臭気を低減させることができ、また上記消臭組成物を、壁紙、床材、天井材等の建築内装資材に加工することによって、消臭機能を有する建築内装資材を提供することができる。 By using the deodorant composition of the present invention containing at least one selected from diatomaceous earth, calcium silicate, basic silicon oxide and activated clay, and amino-modified silicone, malodorous substances such as hydrogen sulfide and ammonia, especially It is possible to reduce the odor of aldehydes, and to provide building interior materials having a deodorizing function by processing the deodorant composition into building interior materials such as wallpaper, flooring, and ceiling materials. can.
Claims (4)
3. The wallpaper processing method according to claim 3, wherein the deodorizing composition according to claim 1 or 2 is mixed with a surface treatment agent, applied to the wallpaper, and then heated at 150° C. or higher. A processing method for wallpaper having.
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Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000095980A (en) | 1998-09-21 | 2000-04-04 | Kansai Paint Co Ltd | Room pollution remedy water paint |
| JP2005255698A (en) | 2004-03-09 | 2005-09-22 | Basf Coatings Japan Ltd | Thermosetting coating composition for precoating |
| JP2006348430A (en) | 2005-06-17 | 2006-12-28 | Suminoe Textile Co Ltd | Deodorant wallpaper |
| JP2007291540A (en) | 2006-04-21 | 2007-11-08 | Kao Corp | Wrinkle-removing deodorizer composition |
| JP2008086436A (en) | 2006-09-29 | 2008-04-17 | Kao Corp | Deodorizing filter |
| JP2010022952A (en) | 2008-07-22 | 2010-02-04 | Toyobo Co Ltd | Agent and sheet for removing aldehyde |
| US20130071639A1 (en) | 2010-06-02 | 2013-03-21 | Lennart Larsson | Covering and method for trapping of emissions from surfaces |
| JP2013075070A (en) | 2011-09-30 | 2013-04-25 | Sumika Enviro-Science Co Ltd | Deodorant composition and deodorizing product |
| JP2014171970A (en) | 2013-03-08 | 2014-09-22 | Japan Enviro Chemicals Ltd | Adsorbent |
| JP2016075005A (en) | 2014-10-08 | 2016-05-12 | 住化エンバイロメンタルサイエンス株式会社 | Allergen-reducing wallpaper and manufacturing method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01226713A (en) * | 1988-03-07 | 1989-09-11 | Jgc Corp | Method for modifying surface of silicate compound |
| JPH08319471A (en) * | 1995-05-26 | 1996-12-03 | Mitsubishi Materials Corp | Use of inorganic powder having function as acidic compound acceptor |
-
2018
- 2018-10-04 JP JP2018189027A patent/JP7288646B2/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000095980A (en) | 1998-09-21 | 2000-04-04 | Kansai Paint Co Ltd | Room pollution remedy water paint |
| JP2005255698A (en) | 2004-03-09 | 2005-09-22 | Basf Coatings Japan Ltd | Thermosetting coating composition for precoating |
| JP2006348430A (en) | 2005-06-17 | 2006-12-28 | Suminoe Textile Co Ltd | Deodorant wallpaper |
| JP2007291540A (en) | 2006-04-21 | 2007-11-08 | Kao Corp | Wrinkle-removing deodorizer composition |
| JP2008086436A (en) | 2006-09-29 | 2008-04-17 | Kao Corp | Deodorizing filter |
| JP2010022952A (en) | 2008-07-22 | 2010-02-04 | Toyobo Co Ltd | Agent and sheet for removing aldehyde |
| US20130071639A1 (en) | 2010-06-02 | 2013-03-21 | Lennart Larsson | Covering and method for trapping of emissions from surfaces |
| JP2013075070A (en) | 2011-09-30 | 2013-04-25 | Sumika Enviro-Science Co Ltd | Deodorant composition and deodorizing product |
| JP2014171970A (en) | 2013-03-08 | 2014-09-22 | Japan Enviro Chemicals Ltd | Adsorbent |
| JP2016075005A (en) | 2014-10-08 | 2016-05-12 | 住化エンバイロメンタルサイエンス株式会社 | Allergen-reducing wallpaper and manufacturing method thereof |
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