JP7270362B2 - Water-based coating material composition and jointless finishing method for exterior walls using the same - Google Patents

Water-based coating material composition and jointless finishing method for exterior walls using the same Download PDF

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JP7270362B2
JP7270362B2 JP2018199695A JP2018199695A JP7270362B2 JP 7270362 B2 JP7270362 B2 JP 7270362B2 JP 2018199695 A JP2018199695 A JP 2018199695A JP 2018199695 A JP2018199695 A JP 2018199695A JP 7270362 B2 JP7270362 B2 JP 7270362B2
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water
coating material
based coating
wall
material composition
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JP2020066672A (en
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亮弥 松崎
祐司 齋藤
武 渡邊
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Aica Kogyo Co Ltd
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Description

本発明は、建物の外壁に2~5mm厚に塗付し、該外壁に様々な凹凸模様から成る意匠性と、断熱性を付与する一液型の水系塗材組成物に関し、また、複数の外壁材の側端部が突き合わせて下地に装着されている外壁の突き合わせ部分の表面に該水系塗材組成物を塗付することで外壁を目地の無い状態に仕上げることが可能な外壁の無目地仕上げ工法に関する。 The present invention relates to a one-liquid water-based coating composition that is applied to the outer wall of a building to a thickness of 2 to 5 mm, and imparts design properties and heat insulation properties consisting of various uneven patterns to the outer wall. A jointless exterior wall that can be finished without joints by applying the water-based coating material composition to the surface of the butted portion of the exterior wall where the side ends of the exterior wall materials are attached to the base. It relates to the finishing method.

従来、建物の屋根、外壁面、内壁面等その他の設備等を塗装するための組成物であって、特に断熱層を形成するための断熱性、防水性及び遮音性を備えた塗材として、中空ビーズと、アクリル系樹脂エマルジョンと、機能保持剤とを含む断熱性塗材であって、前記中空ビーズが全容量の45~50容量%であり、且つ前記機能保持剤として高沸点オイル、粘性調整剤、成膜助剤及び消泡剤を含むことを特徴とする断熱性塗材が提案されている(特許文献1)。 Conventionally, a composition for coating other facilities such as roofs, outer walls, and inner walls of buildings, especially as a coating material with heat insulation, waterproof and sound insulation for forming a heat insulation layer, A heat-insulating coating material comprising hollow beads, an acrylic resin emulsion, and a function-retaining agent, wherein the hollow beads account for 45 to 50% by volume of the total volume, and the function-retaining agent is a high-boiling oil and a viscous A heat-insulating coating material has been proposed which is characterized by containing a modifier, a film-forming aid and an antifoaming agent (Patent Document 1).

しかしながら、特許文献1に示される断熱性塗材は、中空ビーズの平均粒径が約5~15μmと極めて小さく(特許文献1の明細書段落0020)、塗材としての塗付厚みも0.6mm厚と示されていて(同段落0032)、該断熱性塗材では2~5mm厚みに塗付して意匠性を付与することが難しいという課題がある。 However, the heat-insulating coating material shown in Patent Document 1 has an extremely small average particle diameter of hollow beads of about 5 to 15 μm (paragraph 0020 of the specification of Patent Document 1), and the coating thickness as a coating material is 0.6 mm. 0032 of the same paragraph), it is difficult to apply the heat insulating coating material to a thickness of 2 to 5 mm to impart a design property.

一方、外壁の無目地構造として、複数の外壁材を,互いにその側端部を突き合せて下地材に装着すると共に,上記側端部の突き合せ部分の表面側には弾性目地処理材を被覆してなり,また,該弾性目地処理材の内部には,多数の穴を有し該弾性目地処理材が貫通可能な多穴シートを配置し,かつ上記弾性目地処理材の表面には弾性塗料を被覆してなる外壁の無目地構造であって,上記多穴シートは,上記外壁材の側端部を突き合せることによって形成される目地線に沿った長径部と,上記目地線に直交する方向に沿うと共に上記長径部よりも短い短径部とからなる開口部分を有し,かつ上記多穴シートにおける1cm2あたりの開口数は10~60個であることを特徴とする外壁の無目地構造が提案されている(特許文献2)。 On the other hand, as a jointless structure of the outer wall, a plurality of outer wall materials are attached to the base material with their side ends butted against each other, and the surface side of the butted part of the side ends is covered with an elastic joint treatment material. In addition, a multi-hole sheet having a large number of holes and through which the elastic joint treatment material can penetrate is arranged inside the elastic joint treatment material, and an elastic paint is applied to the surface of the elastic joint treatment material. The multi-hole sheet consists of a long diameter portion along the joint line formed by butting the side ends of the exterior wall material and a long diameter portion perpendicular to the joint line A jointless outer wall characterized by having an opening portion along the direction and having a short diameter portion shorter than the long diameter portion, and the number of openings per 1 cm 2 in the multi-hole sheet is 10 to 60. A structure has been proposed (Patent Document 2).

しかしながら、特許文献2に示される外壁の無目地構造は、弾性目地処理材を使用すると共に、該弾性目地処理材が貫通可能な特定の多穴シートを配置した上で弾性塗材で仕上げる必要があるため、施工に手間が掛かるという課題がある。 However, the jointless structure of the outer wall shown in Patent Document 2 requires the use of an elastic joint treatment material and the placement of a specific multi-hole sheet through which the elastic joint treatment material can penetrate, followed by finishing with an elastic coating material. Therefore, there is a problem that construction takes time.

特開2008-95031号公報JP-A-2008-95031 特開2002-146990号公報JP-A-2002-146990

本発明の課題は、外壁に2~5mm厚みに塗付して様々な凹凸模様から成る意匠性と、断熱性を付与することが出来ると共に、複数の外壁材が互いにその側端部を突き合わせて下地に装着されている外壁の該突き合わせ部分に塗付しても、突合せ部分の伸縮によってひび割れが生じることが無い水系塗材組成物を提供し、また、該水系塗材組成物を使用することで、複数の外壁材が互いにその側端部を突き合わせて下地に装着されている外壁において、該突き合わせ部分に弾性目地材、多穴シートを使用した上で弾性塗料で被覆するという複雑な仕様が不要で、施工が簡単な、外壁の無目地仕上げ工法を提供することにある。 It is an object of the present invention to apply a coating of 2 to 5 mm thickness to an outer wall to provide a design with various uneven patterns and heat insulation, and a plurality of outer wall materials can be butted against each other at their side ends. To provide a water-based coating material composition which does not cause cracks due to expansion and contraction of the butting parts even when applied to the butting parts of an outer wall attached to a base, and to use the water-based coating material composition. In the case of an outer wall in which a plurality of outer wall materials are attached to the base with their side ends butted against each other, there is a complicated specification in which elastic joint fillers and multi-hole sheets are used in the butted portions and then covered with elastic paint. To provide a jointless finishing method for an outer wall which is unnecessary and easy to construct.

上記課題を解決するため、請求項1記載の発明は、アクリル樹脂系エマルジョンと、充填材と、骨材と、顔料と、増粘剤と、成膜助剤と、無機中空フィラーと、長さ2~7mmのビニロン繊維と、水と、から成り、組成物全体100重量部に対して、無機中空フィラーは20~30重量部、ビニロン繊維は0.2~0.4重量部、アクリル樹脂系エマルジョン中の樹脂固形分は5~20重量部であり、塗付厚み2~5mmで塗付して凹凸模様から成る意匠性を付与することが可能であることを特徴とする水系塗材組成物を提供する。
In order to solve the above problems, the invention according to claim 1 provides an acrylic resin emulsion, a filler, an aggregate, a pigment, a thickener, a film formation aid, an inorganic hollow filler, and a length Composed of vinylon fibers of 2 to 7 mm and water, with respect to 100 parts by weight of the entire composition, 20 to 30 parts by weight of inorganic hollow filler, 0.2 to 0.4 parts by weight of vinylon fibers, acrylic resin A water-based coating material composition characterized in that the resin solid content in the emulsion is 5 to 20 parts by weight, and that it is possible to apply the composition with a coating thickness of 2 to 5 mm to impart a design property of an uneven pattern. I will provide a.

請求項2記載の発明は、前記無機中空フィラーは、火山性細粒ガラス質凝灰岩の球状発泡体とガラス発泡体とから成ることを特徴とする請求項1記載の水系塗材組成物を提供する。 The invention according to claim 2 provides the water-based coating material composition according to claim 1, wherein the inorganic hollow filler comprises a spherical foam of volcanic fine-grained vitreous tuff and a glass foam. .

請求項3記載の発明は、前記無機中空フィラーは、平均粒径が200~400μmの火山性細粒ガラス質凝灰岩の球状発泡体と、平均粒径が1.0~1.4mmのガラス発泡体とから成ることを特徴とする請求項1又は請求項2に記載の水系塗材組成物を提供する。 In the invention according to claim 3, the inorganic hollow filler is a spherical foam of volcanic fine-grain vitreous tuff with an average particle size of 200 to 400 μm and a glass foam with an average particle size of 1.0 to 1.4 mm. To provide a water-based coating material composition according to claim 1 or claim 2, comprising:

請求項4記載の発明は、複数の外壁材を、互いにその側端部を突き合わせて下地に装着し、該側端部の突き合わせ部分の表面に請求項1乃至請求項3のいずれかに記載の水系塗材組成物を塗付して無目地仕上げとする外壁の無目地仕上げ工法であって、突き合わせ部分の表面に必要によりシーラーを塗付し、次に請求項1乃至請求項3のいずれかに記載の水系塗材組成物を塗付厚み2~5mm塗付して突き合わせ部分の不陸を調整し、次に請求項1乃至請求項3のいずれかに記載の水系塗材組成物を塗付厚み2~5mm塗付して仕上げることを特徴とする外壁の無目地仕上げ工法を提供する。
According to a fourth aspect of the present invention, a plurality of exterior wall materials are mounted on a substrate with their side ends butted against each other, and the surfaces of the butted portions of the side ends are coated with the outer wall material according to any one of claims 1 to 3. A jointless finishing method for an outer wall in which a water-based coating composition is applied to provide a jointless finish, in which a sealer is applied to the surface of the butted portion if necessary, and then any one of claims 1 to 3. The water-based coating material composition according to any one of claims 1 to 3 is applied to a coating thickness of 2 to 5 mm to adjust the unevenness of the butted part, and then the water-based coating material composition according to any one of claims 1 to 3. To provide a jointless finishing method for an outer wall characterized by finishing by coating with a coating thickness of 2 to 5 mm.

請求項5記載の発明は、さらに砂壁状塗料組成物を塗付することを特徴とする請求項4に記載の外壁の無目地仕上げ工法を提供する。 The invention according to claim 5 provides a jointless finishing method for an outer wall according to claim 4, characterized in that a sand wall-like paint composition is further applied.

請求項6記載の発明は、砂壁状塗料組成物は遮熱性を有することを特徴とする請求項5記載の外壁の無目地仕上げ工法を提供する。 The invention according to claim 6 provides the jointless finishing method for an outer wall according to claim 5, wherein the sand wall-like coating composition has a heat shielding property.

本発明の水系塗材組成物は、外壁に2~5mm厚みに塗布して凹凸模様からなる意匠性と断熱性を付与する効果がある。また複数の外壁材が互いにその側端部を突き合わせて下地に装着されている外壁の該突き合わせ部分に塗付しても、突合せ部分の伸縮によってひび割れが生じることが無いという効果がある。 The water-based coating material composition of the present invention has the effect of imparting design properties and heat insulation by applying a 2 to 5 mm thickness to an outer wall. Also, even if a plurality of exterior wall materials are butted against each other at their side ends and applied to the abutted portions of the exterior walls attached to the substrate, there is an effect that cracks do not occur due to expansion and contraction of the abutted portions.

また、本発明の外壁の無目地仕上げ工法は、請求項1乃至請求項3のいずれかに記載の水系塗材組成物を外壁材の突き合わせ部分の表面に塗付することで外壁を無目地の状態に仕上げることが出来る効果があり、突き合わせ部分が伸縮しても水系塗材組成物によって形成された塗膜にひび割れが生じることがないという効果がある。 In addition, in the jointless finishing method for an outer wall of the present invention, the water-based coating material composition according to any one of claims 1 to 3 is applied to the surface of the butted portion of the outer wall material to make the outer wall jointless. There is an effect that it can be finished in a state, and there is an effect that even if the butted portion expands and contracts, the coating film formed by the water-based coating material composition does not crack.

以下、本発明について詳細に説明する。 The present invention will be described in detail below.

本発明の水系塗材組成物は、アクリル樹脂系エマルジョンと、充填材と、骨材と、顔料と、増粘剤と、成膜助剤と、無機中空フィラーと、長さ2~7mmのビニロン繊維と、水と、から成り、組成物全体100重量部に対して、無機中空フィラーは20~30重量部、ビニロン繊維は0.2~0.4重量部、アクリル樹脂系エマルジョン中の樹脂固形分は5~20重量部であり、塗付厚み2~5mmで塗付して凹凸模様から成る意匠性を付与することが可能であることを特徴とする水系塗材組成物であり、必要に応じて消泡剤や分散剤等を配合することが出来る。
The water-based coating material composition of the present invention comprises an acrylic resin emulsion, a filler, an aggregate, a pigment, a thickener, a film forming aid, an inorganic hollow filler, and vinylon having a length of 2 to 7 mm. Composed of fibers and water, with respect to 100 parts by weight of the entire composition, 20 to 30 parts by weight of inorganic hollow filler, 0.2 to 0.4 parts by weight of vinylon fiber, and resin solids in the acrylic resin emulsion It is a water-based coating material composition characterized in that the amount is 5 to 20 parts by weight and can be applied with a coating thickness of 2 to 5 mm to impart a design property consisting of an uneven pattern. An antifoaming agent, a dispersing agent, etc. can be blended accordingly.

[アクリル樹脂エマルジョン]
本発明のアクリル樹脂系エマルジョンには、アクリル酸エステル系共重合樹脂、酢酸ビニル・アクリル酸エステル系共重合樹脂、シリコン変性アクリル樹脂等のアクリル樹脂系エマルジョンを使用することができる。アクリル樹脂とするアクリル系単量体としては、メチルアクリレート、エチルアクリレート、n-プロピルアクリレート、イソプロピルアクリレート、n-ブチルアクリレート、イソブチルアクリレート、sec-ブチルアクリレート、t-ブチルアクリレート、ヘキシルアクリレート、2-エチルヘキシルアクリレート、オクチルアクリレート、ノニルアクリレート、デシルアクリレート、ドデシルアクリレート、n-アミルアクリレート、イソアミルアクリレート、ラウリルアクリレート、ステアリルアクリレート、メチル(メタ)アクリレート、エチル(メタ)アクリレート、n-プロピル(メタ)アクリレート、イソプロピル(メタ)アクリレート、n-ブチル(メタ)アクリレート、イソブチル(メタ)アクリレート、sec-ブチル(メタ)アクリレート、t-ブチル(メタ)アクリレート、ヘキシル(メタ)アクリレート、2-エチルヘキシル(メタ)アクリレート、オクチル(メタ)アクリレート、ノニル(メタ)アクリレート、デシル(メタ)アクリレート、ドデシル(メタ)アクリレート、n-アミル(メタ)アクリレート、イソアミル(メタ)アクリレート、ラウリル(メタ)アクリレート、ステアリル(メタ)アクリレート、シクロヘキシル(メタ)アクリレート、フェニル(メタ)アクリレート、ベンジル(メタ)アクリレート、メトキシエチル(メタ)アクリレート、エトキシエチル(メタ)アクリレート、メトキシプロピル(メタ)アクリレート、エトキシプロピル(メタ)アクリレート、等を使用することが出来る。他の不飽和単量体としては、スチレン、α-メチルスチレン、クロロスチレン、ビニルトルエン、メトキシスチレン等のスチレン誘導体;(メタ)アクリル酸、フマル酸、マレイン酸、無水マレイン酸、イタコン酸、無水イタコン酸、及びクロトン酸等のカルボキシル基含有単量体;(メタ)アクリル酸や、クロトン酸、イタコン酸;2-ヒドロキシエチル(メタ)アクリレートや、2(3)-ヒドロキシプロピル(メタ)アクリレート、4-ヒドロキシブチルアクリレート、アリルアルコール、多価アルコールのモノ(メタ)アクリル酸エステル等の水酸基含有単量体;(メタ)アクリルアミドや、マレインアミド等のアミド基含有単量体;2-アミノエチル(メタ)アクリレートや、ジメチルアミノエチル(メタ)アクリレート、3-アミノプロピル(メタ)アクリレート、2-ブチルアミノエチル(メタ)アクリレート、ビニルピリジン等のアミノ基含有単量体;グリシジル(メタ)アクリレートや、アリルグリシジルエーテル、2個以上のグリシジル基を有するエポキシ化合物と活性水素原子を有するエチレン性不飽和単量体との反応により得られるエポキシ基含有単量体やオリゴノマー;ビニルトリメトキシシラン、ビニルトリエトキシシラン、ビニルメチルジメトキシシラン、ビニルメチルジエトキシシラン、3-(メタ)アクリロキシプロピルトリメトキシシラン、3-(メタ)アクリロキシプロピルトリエトキシシラン、2-(メタ)アクリロキシエチルトリメトキシシラン、2-(メタ)アクリロキシエチルトリエトキシシラン、3-(メタ)アクリロキシプロピルメチルジメトキシシラン、3-(メタ)アクリロキシプロピルメチルジエトキシシラン、3-(メタ)アクリロキシプロピルメチルジプロポキシシラン、3-(メタ)アクリロキシブチルフェニルジメトキシシラン、3-(メタ)アクリロキシプロピルジメチルメトキシシラン、及び3-(メタ)アクリロキシプロピルジエチルメトキシシラン等のアルコキシシリル基含有単量体;その他、酢酸ビニル、塩化ビニル、更には、エチレン、ブタジエン、アクリロニトリル、ジアルキルフマレート等を使用することが出来る。
[Acrylic resin emulsion]
For the acrylic resin emulsion of the present invention, an acrylic resin emulsion such as an acrylic ester copolymer resin, a vinyl acetate/acrylic ester copolymer resin, or a silicone-modified acrylic resin can be used. Examples of acrylic monomers for acrylic resins include methyl acrylate, ethyl acrylate, n-propyl acrylate, isopropyl acrylate, n-butyl acrylate, isobutyl acrylate, sec-butyl acrylate, t-butyl acrylate, hexyl acrylate, and 2-ethylhexyl. Acrylate, octyl acrylate, nonyl acrylate, decyl acrylate, dodecyl acrylate, n-amyl acrylate, isoamyl acrylate, lauryl acrylate, stearyl acrylate, methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, isopropyl ( meth) acrylate, n-butyl (meth) acrylate, isobutyl (meth) acrylate, sec-butyl (meth) acrylate, t-butyl (meth) acrylate, hexyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, octyl ( meth)acrylate, nonyl (meth)acrylate, decyl (meth)acrylate, dodecyl (meth)acrylate, n-amyl (meth)acrylate, isoamyl (meth)acrylate, lauryl (meth)acrylate, stearyl (meth)acrylate, cyclohexyl ( Meth)acrylate, phenyl (meth)acrylate, benzyl (meth)acrylate, methoxyethyl (meth)acrylate, ethoxyethyl (meth)acrylate, methoxypropyl (meth)acrylate, ethoxypropyl (meth)acrylate, etc. can be used. I can. Other unsaturated monomers include styrene derivatives such as styrene, α-methylstyrene, chlorostyrene, vinyltoluene, methoxystyrene; (meth)acrylic acid, fumaric acid, maleic acid, maleic anhydride, itaconic acid, anhydride; Carboxyl group-containing monomers such as itaconic acid and crotonic acid; (meth)acrylic acid, crotonic acid, itaconic acid; 2-hydroxyethyl (meth)acrylate and 2(3)-hydroxypropyl (meth)acrylate, 4-Hydroxybutyl acrylate, allyl alcohol, hydroxyl group-containing monomers such as mono (meth) acrylic acid esters of polyhydric alcohols; (meth) acrylamide, amide group-containing monomers such as maleamide; 2-aminoethyl ( meth) acrylate, dimethylaminoethyl (meth) acrylate, 3-aminopropyl (meth) acrylate, 2-butylaminoethyl (meth) acrylate, amino group-containing monomers such as vinylpyridine; glycidyl (meth) acrylate, Allyl glycidyl ether, epoxy group-containing monomers and oligomers obtained by reacting an epoxy compound having two or more glycidyl groups with an ethylenically unsaturated monomer having an active hydrogen atom; vinyltrimethoxysilane, vinyltriethoxy silane, vinylmethyldimethoxysilane, vinylmethyldiethoxysilane, 3-(meth)acryloxypropyltrimethoxysilane, 3-(meth)acryloxypropyltriethoxysilane, 2-(meth)acryloxyethyltrimethoxysilane, 2 -(meth)acryloxyethyltriethoxysilane, 3-(meth)acryloxypropylmethyldimethoxysilane, 3-(meth)acryloxypropylmethyldiethoxysilane, 3-(meth)acryloxypropylmethyldipropoxysilane, 3 -Alkoxysilyl group-containing monomers such as (meth)acryloxybutylphenyldimethoxysilane, 3-(meth)acryloxypropyldimethylmethoxysilane, and 3-(meth)acryloxypropyldimethylmethoxysilane; in addition, vinyl acetate, Vinyl chloride, as well as ethylene, butadiene, acrylonitrile, dialkyl fumarate, etc. can be used.

アクリル樹脂系エマルジョン中の樹脂のガラス転移温度は-30~40℃が好ましい。ガラス転移温度が-30℃未満の場合は仕上がり表面にタックが生じて汚れやすくなり、40℃超の場合は成膜不良となる。本発明の水系塗材組成物全体中の樹脂固形分は5.0~20.0重量%が好ましく、5.0重量%未満では粘着性、塗付作業性が低下し、また20.0重量%超では粘度が低下し塗付作業性が低下すると共に表現できる意匠(パターン)数が低下する。市販のアクリル樹脂系エマルジョンとしては、アクロナールPS743(BASF社製、固形分55重量%)がある。 The glass transition temperature of the resin in the acrylic resin emulsion is preferably -30 to 40°C. If the glass transition temperature is less than −30° C., the finished surface becomes tacky and easily soiled, and if it exceeds 40° C., poor film formation occurs. The resin solid content in the entire water-based coating material composition of the present invention is preferably 5.0 to 20.0% by weight. %, the viscosity decreases, the coating workability decreases, and the number of designs (patterns) that can be expressed decreases. A commercially available acrylic resin emulsion is Acronal PS743 (manufactured by BASF, solid content: 55% by weight).

[充填材]
本発明に使用する充填材は、平均粒径D50(重量による積算50%の粒径)が100μm未満のものを言い、組成物の粘度や塗付性の調整を目的として配合し、重質炭酸カルシウム、クレー、カオリン、タルク、沈降性硫酸バリウム、炭酸バリウム、硅砂粉等が使用でき、重質炭酸カルシウムが安価でコスト的負担を軽減させることが出来る。充填材の配合量は塗材組成物全体に対して3~20重量%、好ましくは5~12重量%であり、3重量%未満では下地の色が透けるなどの隠蔽性が不足し、20重量%超では塗材粘度が高くなって塗付作業性が不良となる。3重量%未満では色調によっては隠蔽性が低下する場合があり、12重量%超では冬季等の低温度下では塗付作業性が低下する傾向にある。
[Filling material]
The filler used in the present invention has an average particle diameter D 50 (particle diameter of 50% accumulated by weight) of less than 100 μm, and is blended for the purpose of adjusting the viscosity and applicability of the composition. Calcium carbonate, clay, kaolin, talc, precipitated barium sulfate, barium carbonate, silica sand powder, etc. can be used, and heavy calcium carbonate is inexpensive and can reduce the cost burden. The amount of the filler compounded is 3 to 20% by weight, preferably 5 to 12% by weight, based on the total coating material composition. %, the viscosity of the coating material increases and the coating workability becomes poor. If it is less than 3% by weight, the opacity may be lowered depending on the color tone.

[骨材]
本発明に使用する充填材は、平均粒径D50(重量による積算50%の粒径)が100μm以上のものを言い、仕上がり表面に凹凸を付与することを目的として配合されるが、平均粒径が100μm以上であればその粒子径は任意に選択することができ、例えば硅砂,ガラス,シリカ,タルク,重質炭酸カルシウムなどが使用可能である市販の平均粒径が200μmの重質炭酸カルシウムとしてはK-250(商品名,旭鉱末(株)製)がある。骨材(B)の配合量は組成物全体に対して20~40重量%であり20重量%未満では意匠性(塗材の凹凸感)が不足し、40重量%超では作業性が低下する。
[aggregate]
The filler used in the present invention has an average particle size D 50 (particle size of 50% accumulated by weight) of 100 μm or more, and is blended for the purpose of imparting unevenness to the finished surface. If the diameter is 100 μm or more, the particle diameter can be arbitrarily selected. For example, silica sand, glass, silica, talc, heavy calcium carbonate, etc. can be used. As such, there is K-250 (trade name, manufactured by Asahi Komatsu Co., Ltd.). The amount of the aggregate (B) is 20 to 40% by weight based on the total composition. If it is less than 20% by weight, the design (roughness of the coating material) is insufficient, and if it exceeds 40% by weight, workability is reduced. .

[顔料]
顔料には、酸化チタン、酸化亜鉛、カーボンブラック、酸化第二鉄(弁柄)、クロム酸鉛、黄鉛、黄色酸化鉄等の無機系顔料等が使用できるが、中でも酸化チタンは下地の隠蔽性に優れ、白色であるため主たる顔料として使用することが出来る。
[Pigment]
As pigments, inorganic pigments such as titanium oxide, zinc oxide, carbon black, ferric oxide (rouge), lead chromate, yellow lead, and yellow iron oxide can be used. It can be used as a main pigment because it has excellent properties and is white.

[増粘剤]
増粘剤は、鏝塗り作業性や保水性の向上を目的として配合し、水溶性セルロースエーテル、ウレタン変性ポリエーテル、ポリカルボン酸等が使用できる。水溶性セルロースエーテルとしてはhiメトローズ90SH15000(信越化学株式会社製、商品名)がある。増粘剤の配合量は組成物全体100重量部に対して0.1~5.0重量部が好ましく、0.1重量部未満では十分な増粘効果が得られず塗材の凹凸模様が不十分となり、5.0重量部超では塗付作業性が低下する。
[Thickener]
The thickener is blended for the purpose of improving trowel coating workability and water retention, and water-soluble cellulose ether, urethane-modified polyether, polycarboxylic acid, and the like can be used. As a water-soluble cellulose ether, there is hi METOLOSE 90SH15000 (manufactured by Shin-Etsu Chemical Co., Ltd., trade name). The blending amount of the thickener is preferably 0.1 to 5.0 parts by weight per 100 parts by weight of the entire composition. If it exceeds 5.0 parts by weight, the coating workability is lowered.

[成膜助剤]
成膜助剤には、エマルジョンのポリマー粒子の融着を促進し、ポリマーによる均一な皮膜を形成させることを目的で配合し、エチレングリコールジエチルエーテル、ベンジルアルコール、ブチルセロソルブ、エステルアルコール等を使用することが出来る。成膜助剤の配合量は組成物全体100重量部に対して0.5~10重量部が好ましく、0.5重量部未満では低温での成膜が不十分となる場合があり、10重量部超では塗材の表面に汚れが付着し易くなる場合がある。
[Film formation aid]
Ethylene glycol diethyl ether, benzyl alcohol, butyl cellosolve, ester alcohol, etc. should be used as the film-forming aid to promote the fusion of polymer particles in the emulsion and form a uniform polymer film. can be done. The amount of the film formation aid is preferably 0.5 to 10 parts by weight with respect to 100 parts by weight of the entire composition. If the amount is more than 100%, dirt may easily adhere to the surface of the coating material.

[無機中空フィラー]
本発明に使用する無機中空フィラーは、本水系塗材組成物が塗付されて乾燥硬化した塗膜に断熱性を付与すると共に、複数枚の外壁材の側端部が突き合わされた状態で下地に装着されることによって形成された、略直線状の突き合わせ部分の隙間の真上に本組成物を塗付しても、目痩せを生じることなく、また該隙間が外壁材の温度変化や振動によって伸縮しても、その動きに追随可能な可撓性を付与することを目的として配合される。本発明においては、無機中空フィラーによって、単に断熱性を付与するだけでなく、上記可撓性を塗膜に付与することによって、外壁材(一般的にはサイディング材という)が縦横に下地に貼着されて形成された大面積の外壁を、隙間が無く、上記隙間部分でクラック等の不具合が生じない大きな一枚の外壁とすることに大きな特徴がある。
[Inorganic hollow filler]
The inorganic hollow filler used in the present invention imparts heat insulation to the coating film that has been applied with the water-based coating composition and dried and cured, and the side edges of a plurality of exterior wall materials are butted against each other. Even if the present composition is applied directly above the gap between the substantially straight butted parts formed by mounting on the outer wall material, it does not cause thinning, and the gap is not affected by temperature changes and vibrations of the outer wall material. It is blended for the purpose of imparting flexibility that can follow the movement even if it expands and contracts due to In the present invention, the inorganic hollow filler not only imparts thermal insulation properties, but also imparts flexibility to the coating film, so that the outer wall material (generally referred to as siding material) can be vertically and horizontally attached to the base. A major feature is that the large-area outer wall formed by bonding is made into a single large outer wall without any gaps and in which problems such as cracks do not occur in the gaps.

上記目的を達成するために、本発明では無機中空フィラーを組成物全体100重量部に対して20~30重量部と多めに配合し、この他に次に詳細に説明している長さ2~7mmのビニロン繊維を配合する。 In order to achieve the above object, in the present invention, an inorganic hollow filler is blended in a large amount of 20 to 30 parts by weight with respect to 100 parts by weight of the entire composition, and in addition, the length of 2 to 2 as described in detail below is added. A 7 mm vinylon fiber is compounded.

無機中空フィラーは、上記目的を達成するものであれば、どのような無機中空フィラーを使用しても良いが、好ましくは、どちらかというと壊れ難くて平均粒径が1.0~1.4mmで嵩比重が0.2~0.6g/ccのガラス発泡体と、これを塗材中に分散した際の該ガラス発泡体とガラス発泡体の隙間を、やや小径の平均粒径が200~400μmで嵩比重0.1~0.3g/ccの火山性細粒ガラス質凝灰岩の球状発泡体で埋めるようにして、該2種類の無機中空フィラーを併用することで、上記目的がより確実に達成される。ここでいう平均粒径とは重量累積が50%となる平均粒径D50を言う。 As the inorganic hollow filler, any inorganic hollow filler may be used as long as it achieves the above purpose. A glass foam having a bulk specific gravity of 0.2 to 0.6 g / cc and a gap between the glass foam when dispersed in a coating material are filled with a slightly small average particle size of 200 to 200. By using the two types of inorganic hollow fillers in combination so as to be filled with spherical foams of volcanic fine-grained vitreous tuff having a bulk density of 0.1 to 0.3 g/cc and a size of 400 μm, the above purpose can be achieved more reliably. achieved. The average particle size here means the average particle size D50 at which the weight accumulation is 50%.

ガラス発泡体の平均粒径が1.0mm未満では断熱性が不十分となり、1.4mm超では上記隙間の動きによって塗材にクラックが生じる場合がある。また火山性細粒ガラス質凝灰岩の球状発泡体の平均粒径が200μm未満では、断熱性が不十分となり、400μm超では、塗材にクラックが生じやすくなる。 If the average particle diameter of the glass foam is less than 1.0 mm, the heat insulating property is insufficient, and if it exceeds 1.4 mm, cracks may occur in the coating material due to movement of the gaps. If the average particle size of the spherical foam of volcanic fine-grained vitreous tuff is less than 200 µm, the thermal insulation is insufficient, and if it exceeds 400 µm, cracks tend to occur in the coating material.

[ビニロン繊維]
本発明に使用するビニロン繊維は、下地とした外壁材が熱や振動によって大きく動いた際に、上記隙間の上に塗付された本組成物にクラック等が生じることを防止することを目的として配合する。ビニロン繊維は長さが2~7mmのものを使用し、長さが2mm未満では塗膜にクラックが発生する場合があり、7mm超では塗材を下地に塗付する際の作業性が低下する。ビニロン繊維の繊度は組成物のクラック等が生じることを防止できれば一般的な繊維状であれば特に制限はなく、0.5~6dtexのビニロン繊維を使用することができる。
[Vinylon fiber]
The vinylon fiber used in the present invention is intended to prevent cracks or the like from occurring in the composition applied over the gaps when the outer wall material used as the base material is greatly moved due to heat or vibration. Blend. Vinylon fibers with a length of 2 to 7 mm are used. If the length is less than 2 mm, cracks may occur in the coating film. . The fineness of the vinylon fiber is not particularly limited as long as it can prevent cracks or the like from occurring in the composition, and vinylon fibers of 0.5 to 6 dtex can be used.

ビニロン繊維の配合量は組成物100重量部に対して0.2~0.4重量部であり、0.2重量部未満では塗膜にクラックが発生する場合があり、0.4mm超では塗材を下地に塗付する際の作業性が低下する。 The vinylon fiber content is 0.2-0.4 parts by weight per 100 parts by weight of the composition. If it is less than 0.2 parts by weight, cracks may occur in the coating film. The workability when applying the material to the substrate decreases.

本発明の水系塗材組成物は、モルタル下地等にも塗付することが出来るが、この場合はモルタル下地に微細なクラックが生じていても、該クラックの動きによって塗膜にクラックが発生しない。複数の外壁材が、互いにその側端部を突き合わせて下地に装着されて、該外壁材の表面に本水系塗材組成物を塗付する際には、突き合わせ部分の表面に必要により、次に塗る本発明である水系塗材組成物の吸い込みを防止するためのシーラーを塗付し、次に本水系塗材組成物を2~5mm厚みに塗付して突き合わせ部分の不陸を調整し、さらに同水系塗材組成物を2~5mm厚みに塗付して仕上げる。こうすることによって複数の外壁材によって縦横に形成された隙間目地を覆い隠すことができ、目地の無い、外壁の無目地仕上げ工法と成る。 The water-based coating material composition of the present invention can be applied to a mortar base, etc. In this case, even if fine cracks occur in the mortar base, cracks do not occur in the coating film due to the movement of the cracks. . When a plurality of exterior wall materials are attached to a substrate with their side ends butted against each other, and the water-based coating composition is applied to the surfaces of the exterior wall materials, the surfaces of the butted portions may be coated with the following if necessary. Apply a sealer to prevent the water-based coating composition of the present invention from being absorbed, then apply the water-based coating composition to a thickness of 2 to 5 mm to adjust the unevenness of the butted part, Furthermore, the same water-based coating material composition is applied to a thickness of 2 to 5 mm to finish. By doing so, the gap joints formed vertically and horizontally by a plurality of exterior wall materials can be covered and hidden, resulting in a jointless exterior wall finishing method.

本発明の水系塗材組成物の上層には例えば特許第4721935号公報 明細書段落0042 表1 実施例1乃至実施例5に提案されているような砂壁状塗料組成物を塗付することが出来、これにより、本組成物が経時により変色しても、該砂壁状塗料組成物を塗付することで、容易に美観を取り戻すことが出来る。また該砂壁状塗料組成物に遮熱性が付与されていれば、該遮熱性と本発明の水系塗材組成物の断熱性により、建築物内部の温度上昇がより強く抑制される。 As an upper layer of the water-based coating material composition of the present invention, for example, a sand wall-like coating composition as proposed in Japanese Patent No. 4721935, paragraph 0042, Table 1, Examples 1 to 5, can be applied. As a result, even if the present composition discolors over time, it is possible to easily recover the aesthetic appearance by applying the sand wall-like coating composition. Further, if the sand wall-like coating composition is imparted with a heat insulating property, the heat insulating property and the heat insulating property of the water-based coating material composition of the present invention further suppress the temperature rise inside the building.

本組成物には上記の配合成分の他に、塗材中の巻き込み等による泡を消失させるために消泡剤や、充填材や顔料等を均一に分散させるための分散剤が配合されることがある。 In addition to the above ingredients, the composition may contain an antifoaming agent to eliminate bubbles caused by entrainment in the coating material, and a dispersant to uniformly disperse fillers, pigments, etc. There is

本発明の水系塗材組成物は施工にあたっては、ローラー刷毛、パターンローラー、金鏝、吹き付けガン等を使用して、目的としている意匠となるように適切に施工器具を選択し、その意匠に適した塗付量で仕上げる。配合された水系塗材組成物の適正粘度としては、300~700Pa・sが好ましく、このような粘度とするには、適当量の水を加えることで調整することが出来る。 When applying the water-based coating composition of the present invention, a roller brush, pattern roller, iron trowel, spray gun, etc. are used to appropriately select a construction tool so as to achieve the desired design. Finish with a moderate amount of paint. Appropriate viscosity of the blended water-based coating composition is preferably 300 to 700 Pa·s, and such a viscosity can be adjusted by adding an appropriate amount of water.

また、本発明の水系塗材組成物の塗付厚みは2~5mmであり、上記ローラー刷毛、パターンローラー、金鏝、吹き付けガン等を使用して、目的とする意匠を付与する。 The coating thickness of the water-based coating material composition of the present invention is 2 to 5 mm, and the desired design is imparted using the roller brush, pattern roller, iron trowel, spray gun, or the like.

以下、実施例及び比較例にて具体的に説明する。 Examples and comparative examples will be described below in detail.

[材料の作製]
表1の配合に従って、配合A乃至配合Eの水系塗材組成物を作製した。表1において、アクリル樹脂系エマルジョンはアクロナールPS743(固形分:54~56%、樹脂のガラス転移温度:30℃、スチレン、アクリル酸エステル、メタクリル酸エステルの共重合体、BASF社製、商品名)を使用し、充填剤は硅砂粉#300(平均粒径25μm、株式会社トウチュウ製、商品名)を使用し、骨材は、東北硅砂7号(比重1.5、平均粒径150μm、東北硅砂株式会社製、商品名)を使用し、顔料には酸化チタンR-820(石原産業株式会社製、商品名)を使用し、増粘剤は水溶性セルロースエーテルhiメトローズ90SH-15000(信越化学株式会社製、商品名)を、成膜助剤はテキサノールCS-12(チッソ株式会社製、商品名)を、無機中空フィラーAは平均粒径が1.2mmで嵩比重が0.4g/ccのガラス発泡体JF-215(商品名、アイカ工業社製)を、無機中空フィラーBは平均粒径が300μmで嵩比重0.2g/ccの火山性細粒ガラス質凝灰岩の球状発泡体JF-216(商品名、アイカ工業社製)を、ビニロン繊維は、長さ4mm、繊度2.0dtexのビニロン繊維JF-214(商品名、アイカ工業社製)を使用した。この他には消泡剤及び分散剤を添加したが、これらは水系塗材用の市販品より適宜選択されるものを使用することが出来る。これらの原料を均一に混合分散させ、配合A乃至配合Eの水系塗材組成物とした。
[Preparation of materials]
According to the formulations in Table 1, water-based coating compositions of Formulations A to E were prepared. In Table 1, the acrylic resin emulsion is Acronal PS743 (solid content: 54 to 56%, glass transition temperature of resin: 30°C, copolymer of styrene, acrylic acid ester, and methacrylic acid ester, manufactured by BASF, trade name). The filler is silica sand powder #300 (average particle size 25 μm, manufactured by Tochu Co., Ltd., trade name), and the aggregate is Tohoku silica sand No. 7 (specific gravity 1.5, average particle size 150 μm, Tohoku silica sand Co., Ltd., trade name), titanium oxide R-820 (Ishihara Sangyo Co., Ltd., trade name) is used as the pigment, and the thickener is water-soluble cellulose ether hi Metrose 90SH-15000 (Shin-Etsu Chemical Co., Ltd. company's product name), the film forming aid is Texanol CS-12 (manufactured by Chisso Corporation, product name), and the inorganic hollow filler A has an average particle size of 1.2 mm and a bulk specific gravity of 0.4 g/cc. The glass foam JF-215 (trade name, manufactured by Aica Kogyo Co., Ltd.) is used, and the inorganic hollow filler B is a spherical foam JF-216 of volcanic fine-grained vitreous tuff having an average particle size of 300 μm and a bulk specific gravity of 0.2 g/cc. (trade name, manufactured by Aica Kogyo Co., Ltd.), and as the vinylon fiber, vinylon fiber JF-214 (trade name, manufactured by Aica Kogyo Co., Ltd.) having a length of 4 mm and a fineness of 2.0 dtex was used. In addition, an antifoaming agent and a dispersing agent are added, and these can be appropriately selected from commercially available products for water-based coating materials. These raw materials were uniformly mixed and dispersed to obtain formulations A to E of water-based coating material compositions.

Figure 0007270362000001
Figure 0007270362000001

[実施例及び比較例]
実施例1は表1の塗材配合Aの水系塗材組成物を使用して、下地に3.5mm厚みに2回塗付して計7.0mm厚みとした。実施例2は、実施例1の塗膜にさらに遮熱性を有する砂壁状塗料組成物 アイカジョリパットJQ-810(商品名、アイカ工業社製、特許第5721935号公報の段落0042表1に示される実施例1の酸化チタンR-820を、赤外線遮蔽酸化チタンJR-1000(テイカ社製、平均粒子径1.0μm)に置き換えたもの)を0.2~0.4kg/mで2回塗付した。実施例3は塗材配合Aの水系塗材組成物を使用して、下地に2.5mm厚みに2回塗付して計5.0mm厚みとして、さらに実施例2と同様に遮熱性を有する砂壁状塗料組成物 アイカジョリパットJQ-810を0.2~0.4kg/mで2回塗付した。比較例1は塗材配合Bの水系塗材組成物を使用して下地に3.5mm厚みに2回塗付して計7.0mm厚みとし、比較例2は塗材配合Cの水系塗材組成物を使用して下地に3.5mm厚みに2回塗付して計7.0mm厚みとし、比較例3は塗材配合Dの水系塗材組成物を使用して下地に3.5mm厚みに2回塗付して計7.0mm厚みとした。比較例4は塗材配合Eの水系塗材組成物を使用して2mm厚みに塗付した。
[Examples and Comparative Examples]
In Example 1, the water-based coating material composition of coating material formulation A in Table 1 was used, and the base was coated twice with a thickness of 3.5 mm to give a total thickness of 7.0 mm. Example 2 is a sand wall-like coating composition Aika Jollipat JQ-810 (trade name, manufactured by Aika Kogyo Co., Ltd., patent No. 5721935, paragraph 0042 shown in Table 1), which has heat-shielding properties in addition to the coating film of Example 1. Titanium oxide R-820 of Example 1 was replaced with infrared shielding titanium oxide JR-1000 (manufactured by Tayca, average particle size 1.0 μm)) was applied twice at 0.2 to 0.4 kg / m 2 bottom. Example 3 uses the water-based coating material composition of coating material formulation A, is applied twice to a thickness of 2.5 mm on the base to make a total thickness of 5.0 mm, and has heat shielding properties as in Example 2. Sand wall-like coating composition Aika Jollipat JQ-810 was applied twice at 0.2 to 0.4 kg/m 2 . Comparative Example 1 uses the water-based coating material composition of coating material formulation B and applies it twice to the base to a thickness of 3.5 mm to make a total thickness of 7.0 mm. Comparative Example 2 is a water-based coating material of coating material formulation C. Using the composition, apply twice to the base with a thickness of 3.5 mm to make a total thickness of 7.0 mm. was applied twice to give a total thickness of 7.0 mm. In Comparative Example 4, the water-based coating material composition of coating material formulation E was applied to a thickness of 2 mm.

実施例及び比較例について、以下に示す評価方法により評価した。 Examples and comparative examples were evaluated by the following evaluation methods.

[評価方法] [Evaluation method]

[塗付作業性]
900mm角のJISA5430規定のフレキシブルボードを垂直に設置し、実施例又は比較例の塗膜を作成する際に、水系塗材組成物を剣先ゴテで凹凸の差を付けながら塗付厚みが2~5mmと成るようにして扇型の柄をつける。その際に剣先ゴテをスムーズに移動させることが出来るものを○、剣先ゴテが多少移動させにくいものを△、剣先ゴテが明らかに移動させにくいものを×と評価した。
[Coating workability]
A 900 mm square flexible board conforming to JISA 5430 is installed vertically, and when creating a coating film of an example or a comparative example, the coating thickness is 2 to 5 mm while applying a water-based coating composition with a trowel tip to make a difference in unevenness. Attach a fan-shaped handle so that it becomes In this case, the case where the tip of the trowel can be moved smoothly was evaluated as ◯, the case where the tip of the trowel was somewhat difficult to move was evaluated as Δ, and the case where the tip of the trowel was clearly difficult to move was evaluated as x.

[意匠性]
900mm角のJISA5430規定のフレキシブルボードを垂直に設置し、実施例又は比較例の塗膜を作成する際に、水系塗材組成物を剣先ゴテで凹凸の差を付けながら塗付厚みが2~5mmと成るようにして扇型の柄をつけ、そのまま乾燥させる。硬化後、つけた柄がそのままの状態を保っているものを○、柄に崩れ(ダレ、レベリング)が多少ある場合は△、明らかな崩れがある場合を×と評価した。
[Creativity]
A 900 mm square flexible board conforming to JISA 5430 is installed vertically, and when creating a coating film of an example or a comparative example, the coating thickness is 2 to 5 mm while applying a water-based coating composition with a trowel tip to make a difference in unevenness. Attach a fan-shaped handle so that it will be like this, and dry it as it is. After curing, it was evaluated as ◯ when the applied pattern remained as it was, Δ when there was some deterioration (sagging, leveling) in the pattern, and × when there was obvious deterioration.

[断熱性]
300mm角のJISA5430既定のフレキシブルボードを下地として、実施例又は比較例の各塗膜を作製し23℃湿度50%RHで14日間養生し試験体とする。該試験体を水平に保持し、その中央真上25cmに投光器NT-200(200ワット、日動工業社製)を設置し、該投光機の光を塗膜表面に当て、30分後の塗膜表面温度及び塗膜裏面(フレキシルブルボードに接している塗膜面)温度を測定し、塗膜表面温度及び塗膜裏面温度の差が15℃以上である場合を、断熱性有り、と評価し、15℃未満を、断熱性無し、と評価した。
[Thermal insulation properties]
Using a 300 mm square JISA5430 standard flexible board as a substrate, each coating film of Examples or Comparative Examples is prepared and cured at 23° C. and 50% RH for 14 days to obtain a test specimen. The specimen is held horizontally, a projector NT-200 (200 watts, manufactured by Nichido Kogyo Co., Ltd.) is installed 25 cm above the center, the light of the projector is applied to the coating film surface, and the coating after 30 minutes The film surface temperature and the coating film back surface temperature (the coating film surface in contact with the flexible board) are measured, and if the difference between the coating film surface temperature and the coating film back surface temperature is 15 ° C or more, it is evaluated as having heat insulation. A temperature of less than 15°C was evaluated as having no heat insulating properties.

[ゼロスパン引張特性(突き付け目地)]
下地としてJISA5430規定のフレキシブルボード(100×100mm厚さ10mm)を使用し、当該下地2枚の木口同士を突き付け、その裏面を養生テープで仮止めする。下地のオモテ面にシーラーとして溶剤塩化ゴム系下塗り材(JS-410、アイカ工業株式会社製、商品名)を0.2kg/m塗布して、4時間以上乾燥させた後、実施例又は比較例の塗膜を作製し、気温23℃湿度50%RHで14日間養生して試験体とした。その後裏面の仮止めの養生テープをはがし、インストロン万能試験機にて、試験体の両端を2mm/分で引張り、突きつけ部にピンホールが発生した距離が1.8mm以上を○、1.8mm未満を×と評価した。
[Zero span tensile properties (butt joint)]
A flexible board (100×100 mm, 10 mm thick) stipulated in JISA5430 is used as the substrate, and the edges of the two substrates are pressed against each other, and the back surface is temporarily fixed with a curing tape. 0.2 kg/m 2 of a solvent chloride rubber undercoat material (JS-410, manufactured by Aica Kogyo Co., Ltd., trade name) is applied as a sealer to the front surface of the base, and dried for 4 hours or more. A coating film of the example was prepared and cured for 14 days at a temperature of 23° C. and a humidity of 50% RH to obtain a test specimen. After that, remove the temporary fixing curing tape on the back side, pull both ends of the test piece at 2 mm / min with an Instron universal tester, and the distance at which the pinhole occurs at the thrust part is 1.8 mm or more ○, 1.8 mm Less than was evaluated as x.

[ゼロスパン引張特性(10mm目地)]
下地としてJISA5430規定のフレキシブルボード(100×100mm厚さ10mm)を使用し、当該下地2枚の木口同士を10mm開けて目地とし、該目地に1成分形ポリウレタンシーリングを充填し23℃7日間養生し、実施例又は比較例の塗付下地とする。該塗付下地のオモテ面にシーラーとして溶剤塩化ゴム系下塗り材(JS-410、アイカ工業株式会社製、商品名)を0.2kg/m塗布して、4時間以上乾燥させた後、実施例又は比較例の塗膜を作製し、気温23℃湿度50%RHで14日間養生して試験体とした。その後、インストロン万能試験機にて、試験体の両端を2mm/分で引張、目地部分にピンホールが発生した距離が3.0mm以上を○、3.0mm未満を×と評価した。
[Zero span tensile properties (10 mm joint)]
A flexible board (100 x 100 mm, thickness 10 mm) specified in JISA 5430 was used as the base, and the ends of the two bases were opened by 10 mm to form a joint, and the joint was filled with a one-component polyurethane sealant and cured at 23 ° C for 7 days. , as a base for coating in Examples or Comparative Examples. 0.2 kg/m 2 of a solvent chloride rubber undercoat material (JS-410, manufactured by Aica Kogyo Co., Ltd., trade name) is applied as a sealer to the front surface of the base to be applied, dried for 4 hours or more, and then applied. A coating film of an example or a comparative example was prepared and cured for 14 days at a temperature of 23° C. and a humidity of 50% RH to obtain a test specimen. After that, both ends of the specimen were pulled at 2 mm/min using an Instron universal testing machine.

[耐疲労性(引張後に伸縮)]
下地としてJISA5430規定のフレキシブルボード(200×150mm厚さ8mm)を使用し、当該下地2枚の150mm部分の木口同士を10mm開けて目地とし、該目地に1成分形ポリウレタンシーリングを充填し23℃7日間養生し、実施例又は比較例の塗付下地とする。該塗付下地のオモテ面にシーラーとして溶剤塩化ゴム系下塗り材(JS-410、アイカ工業株式会社製、商品名)を0.2kg/m塗布して、4時間以上乾燥させた後、実施例又は比較例の塗膜を作製し、気温23℃湿度50%RHで14日間養生して試験体とした。
[Fatigue resistance (expansion after tension)]
A flexible board (200 x 150 mm, thickness 8 mm) specified by JISA 5430 is used as the base, and the ends of the 150 mm portions of the two bases are opened by 10 mm to form a joint. It is cured for a day and used as a coating base for Examples or Comparative Examples. 0.2 kg/m 2 of a solvent chloride rubber undercoat material (JS-410, manufactured by Aica Kogyo Co., Ltd., trade name) is applied as a sealer to the front surface of the base to be applied, dried for 4 hours or more, and then applied. A coating film of an example or a comparative example was prepared and cured for 14 days at a temperature of 23° C. and a humidity of 50% RH to obtain a test specimen.

試験方法はJISA1436「建築用皮膜材料の下地不連続部における耐疲労性試験方法 5.試験方法」に準拠し、試験体を長手方向に0.1mm引っ張ってムーブメントの開始点とした。次に、該開始点よりさらに0.1mm引っ張って開始点に戻すという伸縮を20℃にて500回、次に60℃で500回、次に-20℃で500回行い、これで塗膜に異常が観察されない場合は、前記開始点よりさらに0.2mm引っ張って開始点に戻すという伸縮を同様に20℃、60℃、-20℃でそれぞれ500回行う。これらを順次繰り返して、異常が無ければ開始点からの引っ張り距離を順次0.1mmプラスして伸縮を繰り返すという試験を連続して行い、開始点からの引っ張り長さが0.5mmで各温度での伸縮後に塗膜に異常が無いものを○と評価した。 The test method conformed to JISA 1436 "Test method for fatigue resistance in discontinuous part of substrate of architectural film material 5. Test method", and the specimen was pulled in the longitudinal direction by 0.1 mm to set the starting point of the movement. Next, it is stretched 500 times at 20° C., then 500 times at 60° C., and then 500 times at -20° C., by pulling 0.1 mm further from the starting point and returning to the starting point. When no abnormality is observed, the stretching is repeated 500 times each at 20°C, 60°C and -20°C by pulling 0.2 mm from the starting point and returning to the starting point. These were repeated in order, and if there were no abnormalities, the test was continuously performed by adding 0.1 mm to the pulling distance from the starting point and repeating the expansion and contraction, and the tensile length from the starting point was 0.5 mm at each temperature. A case where there was no abnormality in the coating film after expansion and contraction was evaluated as ◯.

[耐疲労性(圧縮後に伸縮)]
試験体は上記[耐疲労性(引張後に伸縮)]の試験体と同様とし、試験方法は同様にJISA1436「建築用皮膜材料の下地不連続部における耐疲労性試験方法 5.試験方法」に準拠し、試験体を長手方向に0.1mm圧縮してムーブメントの開始点とした。次に、該開始点から0.1mm引っ張って開始点に戻すという伸縮を20℃にて500回、次に60℃で500回、次に-20℃で500回行い、これで塗膜に異常が観察されない場合は、前記開始点よりさらに0.2mm引っ張って開始点に戻すという伸縮を同様に20℃、60℃、-20℃でそれぞれ500回行う。これらを順次繰り返して、異常が無ければ開始点からの引っ張り距離を順次0.1mmプラスして伸縮を繰り返すという試験を継続し、開始点からの引っ張り長さが0.3mmで各温度での伸縮後に塗膜に異常が無いものを○と評価した。
[Fatigue resistance (stretch after compression)]
The test specimen is the same as the test specimen for [Fatigue resistance (expansion after tension)], and the test method is also based on JISA 1436 “Fatigue resistance test method for discontinuous base of architectural coating material 5. Test method”. Then, the test body was compressed by 0.1 mm in the longitudinal direction to be the starting point of the movement. Next, the expansion and contraction of pulling 0.1 mm from the starting point and returning to the starting point is performed 500 times at 20°C, then 500 times at 60°C, and then 500 times at -20°C. If no is observed, the stretching is repeated 500 times each at 20°C, 60°C and -20°C by pulling 0.2 mm further from the starting point and returning to the starting point. These were repeated sequentially, and if there were no abnormalities, the test was continued in which the stretching distance from the starting point was increased by 0.1 mm in sequence and the stretching was repeated. Those with no abnormalities in the coating film afterward were evaluated as ◯.

[評価結果] [Evaluation results]

評価結果を表2に示す。 Table 2 shows the evaluation results.

Figure 0007270362000002
Figure 0007270362000002

Claims (6)

アクリル樹脂系エマルジョンと、充填材と、骨材と、顔料と、増粘剤と、成膜助剤と、無機中空フィラーと、長さ2~7mmのビニロン繊維と、水と、から成り、組成物全体100重量部に対して、無機中空フィラーは20~30重量部、ビニロン繊維は0.2~0.4重量部、アクリル樹脂系エマルジョン中の樹脂固形分は5~20重量部であり、塗付厚み2~5mmで塗付して凹凸模様から成る意匠性を付与することが可能であることを特徴とする水系塗材組成物。 A composition comprising an acrylic resin emulsion, a filler, an aggregate, a pigment, a thickener, a film forming aid, an inorganic hollow filler, vinylon fibers having a length of 2 to 7 mm, and water. With respect to 100 parts by weight of the whole product, the inorganic hollow filler is 20 to 30 parts by weight, the vinylon fiber is 0.2 to 0.4 parts by weight, and the resin solid content in the acrylic resin emulsion is 5 to 20 parts by weight. A water-based coating material composition characterized in that it can be applied in a coating thickness of 2 to 5 mm to impart a design with an uneven pattern. 前記無機中空フィラーは、火山性細粒ガラス質凝灰岩の球状発泡体とガラス発泡体とから成ることを特徴とする請求項1記載の水系塗材組成物。 2. A water-based coating material composition according to claim 1, wherein said inorganic hollow filler comprises a spherical foam of volcanic fine-grained vitreous tuff and a glass foam. 前記無機中空フィラーは、平均粒径が200~400μmの火山性細粒ガラス質凝灰岩の球状発泡体と、平均粒径が1.0~1.4mmのガラス発泡体とから成ることを特徴とする請求項1又は請求項2に記載の水系塗材組成物。 The inorganic hollow filler is characterized by comprising a spherical foam of volcanic fine-grain vitreous tuff with an average particle size of 200 to 400 μm and a glass foam with an average particle size of 1.0 to 1.4 mm. The water-based coating material composition according to claim 1 or 2. 複数の外壁材を、互いにその側端部を突き合わせて下地に装着し、該側端部の突き合わせ部分の表面に請求項1乃至請求項3のいずれかに記載の水系塗材組成物を塗付して無目地仕上げとする外壁の無目地仕上げ工法であって、突き合わせ部分の表面に必要によりシーラーを塗付し、次に請求項1乃至請求項3のいずれかに記載の水系塗材組成物を塗付厚み2~5mmで塗付して突き合わせ部分の不陸を調整し、次に請求項1乃至請求項3のいずれかに記載の水系塗材組成物を塗付厚み2~5mmで塗付して仕上げることを特徴とする外壁の無目地仕上げ工法。 A plurality of exterior wall materials are attached to a substrate with their side ends butted against each other, and the water-based coating material composition according to any one of claims 1 to 3 is applied to the surfaces of the butted portions of the side ends. A jointless finishing method for an outer wall to make a jointless finish, in which a sealer is applied to the surface of the butted part if necessary, and then the water-based coating material composition according to any one of claims 1 to 3 is applied with a coating thickness of 2 to 5 mm to adjust the unevenness of the butted part, and then the water-based coating material composition according to any one of claims 1 to 3 is applied with a coating thickness of 2 to 5 mm. A jointless finishing method for an outer wall characterized by finishing by attaching. さらに砂壁状塗料組成物を塗付することを特徴とする請求項4に記載の外壁の無目地仕上げ工法。 5. The jointless finishing method for an outer wall according to claim 4, further comprising applying a sand wall-like paint composition. 砂壁状塗料組成物は遮熱性を有することを特徴とする請求項5記載の外壁の無目地仕上げ工法。
6. The jointless finishing method for an outer wall according to claim 5, wherein the sand wall-like paint composition has heat shielding properties.
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