JP7217745B2 - 地下地熱貯留層から水素を生産する方法 - Google Patents
地下地熱貯留層から水素を生産する方法 Download PDFInfo
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- 229910052739 hydrogen Inorganic materials 0.000 title claims description 59
- 239000001257 hydrogen Substances 0.000 title claims description 59
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 52
- 238000004519 manufacturing process Methods 0.000 title claims description 13
- 239000012528 membrane Substances 0.000 claims description 33
- 239000007789 gas Substances 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000012530 fluid Substances 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 238000002309 gasification Methods 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 238000006276 transfer reaction Methods 0.000 claims description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 7
- 239000010955 niobium Substances 0.000 claims description 4
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 3
- 229910001252 Pd alloy Inorganic materials 0.000 claims description 3
- 229910052758 niobium Inorganic materials 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 229910052715 tantalum Inorganic materials 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 3
- 238000010793 Steam injection (oil industry) Methods 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 claims description 2
- 230000005670 electromagnetic radiation Effects 0.000 claims description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229920005597 polymer membrane Polymers 0.000 claims description 2
- 230000005258 radioactive decay Effects 0.000 claims description 2
- 230000000638 stimulation Effects 0.000 claims description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 2
- 230000000476 thermogenic effect Effects 0.000 claims description 2
- 230000001939 inductive effect Effects 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910001092 metal group alloy Inorganic materials 0.000 claims 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 11
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 11
- 150000002431 hydrogen Chemical class 0.000 description 8
- 229910002090 carbon oxide Inorganic materials 0.000 description 7
- 239000000446 fuel Substances 0.000 description 7
- 229960004424 carbon dioxide Drugs 0.000 description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 230000005611 electricity Effects 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 229920000997 Graphane Polymers 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000004678 hydrides Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229920000557 Nafion® Polymers 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000005553 drilling Methods 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- -1 or both Substances 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000012824 chemical production Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000008398 formation water Substances 0.000 description 1
- 239000013529 heat transfer fluid Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910001026 inconel Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000009919 sequestration Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000001991 steam methane reforming Methods 0.000 description 1
- 239000004557 technical material Substances 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Images
Classifications
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B36/00—Heating, cooling or insulating arrangements for boreholes or wells, e.g. for use in permafrost zones
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/295—Gasification of minerals, e.g. for producing mixtures of combustible gases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/02—Subsoil filtering
- E21B43/08—Screens or liners
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/34—Arrangements for separating materials produced by the well
- E21B43/38—Arrangements for separating materials produced by the well in the well
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24T—GEOTHERMAL COLLECTORS; GEOTHERMAL SYSTEMS
- F24T10/00—Geothermal collectors
- F24T10/20—Geothermal collectors using underground water as working fluid; using working fluid injected directly into the ground, e.g. using injection wells and recovery wells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/10—Geothermal energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Mining & Mineral Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Hydrology & Water Resources (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Fuel Cell (AREA)
Description
貯留層は、ガス化及び水-ガス移行反応が貯留層内で起こるのに十分な周囲自然温度を有す場合があり得る。代わりに、貯留層は、限定されないが、注入を介しての発熱反応、電磁放射、ホトン若しくは音響刺激、スチーム注入、核反応、電気抵抗、又はマグマ移動を含めて、他の手段により加熱されてもよい。
貯留層が十分な温度である場合、ガス化及び水-ガス移行反応は、水素の連続発生とともに起こる。ガス構成成分は、貯留層内に集まる。
水素は、生産井内で水素専用メンブレンを通して貯留層から生産される。このようにして、硫化水素、一酸化炭素、二酸化炭素、スチーム、及び他のガス構成成分は、貯留層内に残存する。水素は貯留層から除去されるので、これにより、反応は促進されて、より多くの水素を発生する。
・「含む(comprise)」、「含むこと(comprising)」、などは、排他的又は網羅的な意味とは対照的に、包含的な意味で;すなわち、「包含するが、限定されない」の意味で解釈されるべきである。
Claims (8)
- 水を含む地熱貯留層から水素を生産する方法であって、
前記地熱貯留層内の前記水にガス化又は水-ガス移行反応の少なくとも1つを発生させ、水素を含むガスストリームを形成するステップと、
前記地熱貯留層に地表から坑井を提供するステップと、
パラジウム合金からなる少なくとも1種の水素透過性メンブレンを前記坑井内に配置するステップと、
前記少なくとも1種の水素透過性メンブレンが、前記ガスストリーム中の前記水素のみを前記地表へ通過させるように、前記ガスストリームを前記少なくとも1種の水素透過性メンブレンにかけるステップと
を含み、
前記水素を前記地表に生産するステップが、前記坑井内を循環する作動液に前記水素を移送することを含み、
前記地熱貯留層に隣接する前記坑井を通過する間、前記作動液が加熱されて加熱作動液を形成し、前記方法が、前記加熱作動液を、これが前記地表に生産される場合に熱源または電力源として使用するステップをさらに含む、
方法。 - 酸素が、酸化反応によって前記地熱貯留層内で捕捉される、請求項1に記載の方法。
- ガス化又は水-ガス移行反応の少なくとも1つを発生させるステップは、発熱反応、核反応、熱発生性放射性崩壊、ホトン若しくは音響刺激、スチーム注入、電磁放射、又は電気抵抗を介して前記地熱貯留層を十分な温度に誘導することを含む、請求項1に記載の方法。
- 前記少なくとも1種の水素透過性メンブレンが、バナジウム、タンタル、及びニオブのうちの少なくとも1種をさらに含む、請求項1に記載の方法。
- 前記少なくとも1種の水素透過性メンブレンが、パラジウム銅合金からなる、請求項1に記載の方法。
- 前記少なくとも1種の水素透過性メンブレンが、セラミック層及び/又は透過性若しくは非透過性構造金属若しくは金属合金層、及び/又はポリマーメンブレンをさらに含む、請求項1に記載の方法。
- 前記水素を前記地表に生産することで前記水-ガス移行反応による追加の水素の生成が促進されるように、前記水に前記水-ガス移行反応が発生して前記ガスストリームが形成され、前記方法が、前記追加の水素を前記地表に生産することをさらに含む、請求項1に記載の方法。
- 前記少なくとも1種の水素透過性メンブレンを前記坑井内に配置するステップは、前記少なくとも1種の水素透過性メンブレンを前記坑井の一部にすることを含む、請求項1に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201762520047P | 2017-06-15 | 2017-06-15 | |
US62/520,047 | 2017-06-15 | ||
PCT/CA2018/050724 WO2018227303A1 (en) | 2017-06-15 | 2018-06-14 | Process to produce hydrogen from underground geothermal reservoirs |
Publications (3)
Publication Number | Publication Date |
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JP2020525692A JP2020525692A (ja) | 2020-08-27 |
JP2020525692A5 JP2020525692A5 (ja) | 2020-10-08 |
JP7217745B2 true JP7217745B2 (ja) | 2023-02-03 |
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JP2020519162A Active JP7217745B2 (ja) | 2017-06-15 | 2018-06-14 | 地下地熱貯留層から水素を生産する方法 |
Country Status (17)
Country | Link |
---|---|
US (1) | US11708744B2 (ja) |
EP (1) | EP3638876B1 (ja) |
JP (1) | JP7217745B2 (ja) |
CN (1) | CN110914513A (ja) |
AR (1) | AR112194A1 (ja) |
AU (1) | AU2018286507A1 (ja) |
CA (1) | CA3067066A1 (ja) |
CL (1) | CL2019003665A1 (ja) |
CO (1) | CO2020000350A2 (ja) |
CR (1) | CR20200005A (ja) |
EC (1) | ECSP20001269A (ja) |
MX (1) | MX2019015186A (ja) |
NI (1) | NI201900127A (ja) |
PE (1) | PE20200682A1 (ja) |
PH (1) | PH12019502804A1 (ja) |
RU (1) | RU2768355C2 (ja) |
WO (1) | WO2018227303A1 (ja) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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PE20181475A1 (es) * | 2016-02-08 | 2018-09-13 | Proton Tech Inc | Proceso in situ para producir hidrogeno a partir de depositos de hidrocarburos subterraneos |
IT202100017711A1 (it) * | 2021-07-06 | 2023-01-06 | Geolog S R L | Metodo per installare un impianto geotermico, metodo per sfruttare energia geotermica, e impianto geotermico |
US20230050823A1 (en) * | 2021-07-30 | 2023-02-16 | Ohio State Innovation Foundation | Systems and methods for generation of hydrogen by in-situ (subsurface) serpentinization and carbonization of mafic or ultramafic rock |
WO2023044149A1 (en) * | 2021-09-20 | 2023-03-23 | Texas Tech University System | In-situ hydrogen generation and production from petroleum reservoirs |
CN114506817B (zh) * | 2022-03-03 | 2023-01-31 | 西南石油大学 | 一种利用地热能辅助加热的气藏原位转化制氢方法 |
US11828147B2 (en) | 2022-03-30 | 2023-11-28 | Hunt Energy, L.L.C. | System and method for enhanced geothermal energy extraction |
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AU2018286507A1 (en) | 2020-01-30 |
CA3067066A1 (en) | 2018-12-20 |
EP3638876B1 (en) | 2023-11-08 |
CR20200005A (es) | 2020-09-21 |
JP2020525692A (ja) | 2020-08-27 |
AR112194A1 (es) | 2019-10-02 |
PH12019502804A1 (en) | 2020-09-14 |
CN110914513A (zh) | 2020-03-24 |
CO2020000350A2 (es) | 2020-04-24 |
WO2018227303A1 (en) | 2018-12-20 |
AU2018286507A2 (en) | 2020-07-09 |
NI201900127A (es) | 2020-01-29 |
ECSP20001269A (es) | 2020-05-29 |
MX2019015186A (es) | 2020-08-03 |
CL2019003665A1 (es) | 2020-07-03 |
PE20200682A1 (es) | 2020-06-11 |
RU2019141847A3 (ja) | 2021-09-14 |
EP3638876A1 (en) | 2020-04-22 |
EP3638876A4 (en) | 2021-06-09 |
WO2018227303A8 (en) | 2020-01-02 |
RU2768355C2 (ru) | 2022-03-23 |
US20200182019A1 (en) | 2020-06-11 |
RU2019141847A (ru) | 2021-07-15 |
US11708744B2 (en) | 2023-07-25 |
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